Bi tp tinh th

1.St alpha kt tinh theo mng lp phng tm khi.Xc nh bn knh ca nguyn t Fe trong st alpha bit t trng ca n bng 7,86. Cho Fe = 55,8 g/mol. 2. Bn knh ca nguyn t Na bng 0,190 nm. Tnh t trng ca Na kim loi (mng lp phng tm khi).Cho Na = 23,0 g/mol. 3. Cu kim loi kt tinh theo mng lp phng tm din. T trng ca n bng 8,96. Tnh bn knh nguyn t ca Cu. Cu = 63,5. 4. Cho thng s mng tinh th ca 2 dng th hnh ca Fe: - Fe alpha: lp phng tm khi; a = 0,286 nm. - Fe gamma: lp phng tm din; a = 0,356 nm. Tnh bn knh nguyn t v t trng ca Fe trong mi trng hp.Fe = 55,8 g/mol. 5. Mg kt tinh theo mng lc phng cht kht.Bit a = b = 0,320 nm.Tnh c. T kt qu thu c hy tnh t khi ca Mg. Mg = 24,3 g/mol. 6. Ti kt tinh theo mng lc phng cht kht. a) M t t bo n v ca Ti. b) Tnh bn knh nguyn t ca Ti, bit khi lng ring ca Ti bng 4,51 g/cm3.Ti = 47,90 g/mol. 7. T trng ca NaCl bng 2,165.Tnh tng bn knh ca 2 ion Na+ v Cl-.MNaCl = 58,44 g/mol. 8. Trong tinh th CaF2 cc ion Ca2+ nm trn mt mng lp phng tm din, cn cc ion F- chim tt c cc l trng t din. Bn knh ca cc ion Ca2+ v F- tng tng bng 0,099 v 0,133 nm.Tnh: - Thng s mng a. - c kht p. - T trng ca CaF2 MCaF2 = 78 g/mol. 9. Trong kiu cu trc blend ca ZnS cc ion S2- nm trn mt mng lp phng tm din, cn cc ion Zn2+ chim mt na s l trng t din theo 4 gc cho nhau ca t bo n v. Tnh t s nh nht ca r+/r10. Bn knh nguyn t ca C r = 0,077 nm. Tnh t trng v c kht ca kim cng. C = 12,01 g/mol. 11. FeO c cu trc kiu NaCl vi a = 0,430 nm. Gi tr ny c ph hp vi cc bn knh ion: r(Fe2+) = 0,075 nm; r(O2-) = 0,140 nm?

12. Cu2O kt tinh theo mng lp phng trong cc ion O2- to thnh mt mng lp phng tm khi, cn cc ion Cu2+ nm im gia ca 4/8 na ng cho ca hnh lp phng. Xc nh: - Kiu phi tr v s phi tr ca cc ion. - S phn t Cu2O trong 1 t bo. - Thng s a ca t bo nu khi lng ring l 6,00 g/cm3 13. Dng th hnh cristobalit ca SiO2 c cu trc nh sau: Cc nguyn t Si sp xp cc v tr ging nh cc nguyn t C trong kim cng v gia 2 nguyn t Si l mt nguyn t O. - V cu trc ca cristobalit. - Xc nh s phi tr ca Si v O. - Xc nh thng s a bit khi lng ring l 2,32 g/cm3.MSiO2 = 60,1 g/mol. 14. Xc nh nng lng mng li tinh th ca NaCl, bit (kJ/mol): delta H (NaCl) = -411,2; delta Ho (th Na) = 107,3; delta Ho (pl Cl2) = 240; delta Ho (ionh Na) = 496; delta Ho (al Cl) = -349. 15. Mt mu oxit st (II) FexO iu ch trong phng th nghim c t khi 5,71 g/cm3. Bit rng oxit st (II) c cu trc kiu NaCl. Gc teta ca phn x bc nht t h mt 200 bng 9,56o khi dng bc x Kalpha ca Mo vi lamda l 71,07 pm. Xc nh: - thng s ca mng tinh th - Gi tr ca x trong FexO - T l Fe2+ v Fe3+ trong oxit - Cng thc ha hc ch r ha tr ca st trong hp cht. 16. Mg kt tinh theo mng lc phng cht kht. Bit a = b = 0,320 nm.Tnh c. T kt qu thu c hy tnh t khi ca Mg. Mg = 24,3 g/mol. 17. Ti kt tinh theo mng lc phng cht kht. a) M t t bo n v ca Ti. b) Tnh bn knh nguyn t ca Ti, bit khi lng ring ca Ti bng 4,51 g/cm3.Ti = 47,90 g/mol. 18. Trong tinh th CaF2 cc ion Ca2+ nm trn mt mng lp phng tm din, cn cc ion F- chim tt c cc l trng t din. Bn knh ca cc ion Ca2+ v F- tng tng bng 0,099 v 0,133 nm. Tnh: - Thng s mng a.

- c kht p. - T trng ca CaF2 MCaF2 = 78 g/mol. 19. Trong kiu cu trc blend ca ZnS cc ion S2- nm trn mt mng lp phng tm din, cn cc ion Zn2+ chim mt na s l trng t din theo 4 gc cho nhau ca t bo n v. Tnh t s nh nht ca r+/r20. St alpha kt tinh theo mng lp phng tm khi. Xc nh bn knh ca nguyn t Fe trong st alpha bit t trng ca n bng 7,86. Cho Fe = 55,8 g/mol. 21. Bn knh ca nguyn t Na bng 0,190 nm. Tnh t trng ca Na kim loi (mng lp phng tm khi). Cho Na = 23,0 g/mol. 22. Cu kim loi kt tinh theo mng lp phng tm din. T trng ca n bng 8,96. Tnh bn knh nguyn t ca Cu. Cu = 63,5. 23. Cho thng s mng tinh th ca 2 dng th hnh ca Fe: - Fe alpha: lp phng tm khi; a = 0,286 nm. - Fe gamma: lp phng tm din; a = 0,356 nm. Tnh bn knh nguyn t v t trng ca Fe trong mi trng hp. Fe = 55,8 g/mol. 24. Mg kt tinh theo mng lc phng cht kht. Bit a = b = 0,320 nm. Tnh c. T kt qu thu c hy tnh t khi ca Mg. Mg = 24,3 g/mol. 25. Ti kt tinh theo mng lc phng cht kht. a) M t t bo n v ca Ti. b) Tnh bn knh nguyn t ca Ti, bit khi lng ring ca Ti bng 4,51 g/cm3 Ti = 47,90 g/mol. 26. T trng ca NaCl bng 2,165. Tnh tng bn knh ca 2 ion Na+ v ClMNaCl = 58,44 g/mol. 27. Trong tinh th CaF2 cc ion Ca2+ nm trn mt mng lp phng tm din, cn cc ion F- chim tt c cc l trng t din.

Bn knh ca cc ion Ca2+ v F- tng tng bng 0,099 v 0,133 nm. Tnh: - Thng s mng a. - c kht p. - T trng ca CaF2 MCaF2 = 78 g/mol. 28. Trong kiu cu trc blend ca ZnS cc ion S2- nm trn mt mng lp phng tm din, cn cc ion Zn2+ chim mt na s l trng t din theo 4 gc cho nhau ca t bo n v. Tnh t s nh nht ca r+/r29. Bn knh nguyn t ca C r = 0,077 nm. Tnh t trng v c kht ca kim cng. C = 12,01 g/mol. 30. FeO c cu trc kiu NaCl vi a = 0,430 nm. Gi tr ny c ph hp vi cc bn knh ion: r(Fe2+) = 0,075 nm; r(O2-) = 0,140 nm? 31. Cu2O kt tinh theo mng lp phng trong cc ion O2- to thnh mt mng lp phng tm khi, cn cc ion Cu2+ nm im gia ca 4/8 na ng cho ca hnh lp phng. Xc nh: - Kiu phi tr v s phi tr ca cc ion. - S phn t Cu2O trong 1 t bo. - Thng s a ca t bo nu khi lng ring l 6,00 g/cm3 32. Dng th hnh cristobalit ca SiO2 c cu trc nh sau: Cc nguyn t Si sp xp cc v tr ging nh cc nguyn t C trong kim cng v gia 2 nguyn t Si l mt nguyn t O. - V cu trc ca cristobalit. - Xc nh s phi tr ca Si v O. - Xc nh thng s a bit khi lng ring l 2,32 g/cm3 MSiO2 = 60,1 g/mol. 33. Xc nh nng lng mng li tinh th ca NaCl, bit (kJ/mol): delta H (NaCl) = -411,2; delta Ho (th Na) = 107,3; delta Ho (pl Cl2) = 240; delta Ho (ionh Na) = 496; delta Ho (al Cl) = -349.

34. Mt mu oxit st (II) FexO iu ch trong phng th nghim c t khi 5,71 g/cm3. Bit rng oxit st (II) c cu trc kiu NaCl. Gc teta ca phn x bc nht t h mt 200 bng 9,56o khi dng bc x K alpha ca Mo vi lamda l 71,07 pm. Xc nh: - thng s ca mng tinh th - Gi tr ca x trong FexO - T l Fe2+ v Fe3+ trong oxit - Cng thc ha hc ch r ha tr ca st trong hp cht.