Hu c 11

BI TP TRC NGHIM HO HU C 11
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MC LC
Trang Phn 1: Bi tp
Chuyn 1 : i cng ho hu c Chuyn 2 : Hirocacbon no Chuyn 3 : Hirocacbon khng no Chuyn 4 : Hirocacbon thm - Ngun hirocacbon thin nhin Chuyn 5 : Dn xut halogen - Phenol - Ancol Chuyn 6 : Anehit - Xeton - Axitcacboxylic

2 - 62
3 10 15 27 32 45

Phn 2 : p n

63- 65

Phn 1: Bi tp
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CHUYN 1 : I CNG HA HC HU C
Cu 1: Thnh phn cc nguyn t trong hp cht hu c A. nht thit phi c cacbon, thng c H, hay gp O, N sau n halogen, S, P... B. gm c C, H v cc nguyn t khc. C. bao gm tt c cc nguyn t trong bng tun hon. D. thng c C, H hay gp O, N, sau n halogen, S, P. Cu 2: c im chung ca cc phn t hp cht hu c l 1. thnh phn nguyn t ch yu l C v H. 2. c th cha nguyn t khc nh Cl, N, P, O. 3. lin kt ha hc ch yu l lin kt cng ho tr. 4. lin kt ho hc ch yu l lin kt ion. 5. d bay hi, kh chy. 6. phn ng ho hc xy ra nhanh. Nhm cc ng l: A. 4, 5, 6. B. 1, 2, 3. C. 1, 3, 5. D. 2, 4, 6. Cu 3: Cu to ho hc l A. s lng lin kt gia cc nguyn t trong phn t. B. cc loi lin kt gia cc nguyn t trong phn t. C. th t lin kt gia cc nguyn t trong phn t. D. bn cht lin kt gia cc nguyn t trong phn t. Cu 4: Pht biu no sau c dng nh ngha cng thc n gin nht ca hp cht hu c ? A. Cng thc n gin nht l cng thc biu th s nguyn t ca mi nguyn t trong phn t. B. Cng thc n gin nht l cng thc biu th t l ti gin v s nguyn t ca cc nguyn t trong phn t. C. Cng thc n gin nht l cng thc biu th t l phn trm s mol ca mi nguyn t trong phn t. D. Cng thc n gin nht l cng thc biu th t l s nguyn t C v H c trong phn t. Cu 5: Cho cht axetilen (C2H2) v benzen (C6H6), hy chn nhn xt ng trong cc nhn xt sau : A. Hai cht ging nhau v cng thc phn t v khc nhau v cng thc n gin nht. B. Hai cht khc nhau v cng thc phn t v ging nhau v cng thc n gin nht. C. Hai cht khc nhau v cng thc phn t v khc nhau v cng thc n gin nht. D. Hai cht c cng cng thc phn t v cng cng thc n gin nht. Cu 6: c im chung ca cc cacbocation v cacbanion l: A. km bn v c kh nng phn ng rt kem. B. chng u rt bn vng v c kh nng phn ng cao. C. c th d dng tch c ra khi hn hp phn ng. D. km bn v c kh nng phn ng cao. Cu 7: Phn ng ha hc ca cc hp cht hu c c c im l: A. thng xy ra rt nhanh v cho mt sn phm duy nht. B. thng xy ra chm, khng hon ton, khng theo mt hng nht nh. C. thng xy ra rt nhanh, khng hon ton, khng theo mt hng nht nh. D. thng xy ra rt chm, nhng hon ton, khng theo mt hng xc nh. Cu 8: Pht biu no sau y l sai ? A. Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. B. Cc cht c cu to v tnh cht tng t nhau nhng v thnh phn phn t khc nhau mt hay nhiu nhm -CH2- l ng ng ca nhau. C. Cc cht c cng khi lng phn t l ng phn ca nhau. D. Lin kt ba gm hai lin kt v mt lin kt . Cu 9: Kt lun no sau y l ng ? A. Cc nguyn t trong phn t hp cht hu c lin kt vi nhau khng theo mt th t nht nh.

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B. Cc cht c thnh phn phn t hn km nhau mt hay nhiu nhm -CH2-, do tnh cht ha hc khc nhau l nhng cht ng ng. C. Cc cht c cng cng thc phn t nhng khc nhau v cng thc cu to c gi l cc cht ng ng ca nhau. D. Cc cht khc nhau c cng cng thc phn t c gi l cc cht ng phn ca nhau. Cu 10: Hin tng cc cht c cu to v tnh cht ho hc tng t nhau, chng ch hn km nhau mt hay nhiu nhm metylen (-CH2-) c gi l hin tng A. ng phn. B. ng v. C. ng ng. D. ng khi. Cu 11: Hp cht cha mt lin kt trong phn t thuc loi hp cht A. khng no. B. mch h. C. thm. D. no hoc khng no. Cu 12: Hp cht hu c c phn loi nh sau: A. Hirocacbon v hp cht hu c c nhm chc. B. Hirocacbon v dn xut ca hirocacbon. C. Hirocacbon no, khng no, thm v dn xut ca hirocacbon. D. Tt c u ng. Cu 13: Pht biu khng chnh xc l: A. Tnh cht ca cc cht ph thuc vo thnh phn phn t v cu to ha hc. B. Cc cht c cng khi lng phn t l ng phn ca nhau. C. Cc cht l ng phn ca nhau th c cng cng thc phn t. D. S xen ph trc to thnh lin kt , s xen ph bn to thnh lin kt . Cu 14: Nung mt hp cht hu c X vi lng d cht oxi ha CuO ngi ta thy thot ra kh CO2, hi H2O v kh N2. Chn kt lun chnh xc nht trong cc kt lun sau : A. X chc chn cha C, H, N v c th c hoc khng c oxi. B. X l hp cht ca 3 nguyn t C, H, N. C. Cht X chc chn c cha C, H, c th c N. D. X l hp cht ca 4 nguyn t C, H, N, O. Cu 15: Cho hn hp cc ankan sau : pentan (si 36oC), heptan (si 98oC), octan (si 126oC), nonan (si 151oC). C th tch ring cc cht bng cch no sau y ? A. Kt tinh. B. Chng ct C. Thng hoa. D. Chit. Cu 16: Cc cht trong nhm cht no di y u l dn xut ca hirocacbon ? A. CH2Cl2, CH2Br-CH2Br, NaCl, CH3Br, CH3CH2Br. B. CH2Cl2, CH2Br-CH2Br, CH3Br, CH2=CHCOOH, CH3CH2OH. C. CH2Br-CH2Br, CH2=CHBr, CH3Br, CH3CH3. D. HgCl2, CH2Br-CH2Br, CH2=CHBr, CH3CH2Br. Cu 17: Cho cc cht : C6H5OH (X) ; C6H5CH2OH (Y) ; HOC6H4OH (Z) ; C6H5CH2CH2OH (T). Cc cht ng ng ca nhau l: A. Y, T. B. X, Z, T. C. X, Z. D. Y, Z. Cu 18: Trong nhng dy cht sau y, dy no c cc cht l ng phn ca nhau ? A. C2H5OH, CH3OCH3. B. CH3OCH3, CH3CHO. C. CH3CH2CH2OH, C2H5OH. D. C4H10, C6H6. Cu 19: Cc cht hu c n chc Z1, Z2, Z3 c CTPT tng ng l CH2O, CH2O2, C2H4O2. Chng thuc cc dy ng ng khc nhau. Cng thc cu to ca Z3 l A. CH3COOCH3. B. HOCH2CHO. C. CH3COOH.D. CH3OCHO. Cu 20: Nhng cht no sau y l ng phn hnh hc ca nhau ?

A. (I), (II). B. (I), (III). C. (II), (III). D. (I), (II), (III). Cu 21: Cho cc cht sau : CH2=CHCCH (1) ; CH2=CHCl (2) ; CH3CH=C(CH3)2 (3) ;

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CH3CH=CHCH=CH2 (4) ; CH2=CHCH=CH2 (5) ; CH3CH=CHBr (6). Cht nao sau y co ng phn hinh hoc? A. 2, 4, 5, 6. B. 4, 6. C. 2, 4, 6. D. 1, 3, 4. Cu 22: Hp cht hu c no sau y khng c ng phn cis-trans ? A. 1,2-icloeten. B. 2-metyl pent-2-en. C. but-2-en. D. pent-2-en. Cu 23: Hp cht (CH3)2C=CHC(CH3)2CH=CHBr c danh php IUPAC l A. 1-brom-3,5-trimetylhexa-1,4-ien. B. 3,3,5-trimetylhexa-1,4-ien-1-brom. C. 2,4,4-trimetylhexa-2,5-ien-6-brom. D. 1-brom-3,3,5-trimetylhexa-1,4-ien. Cu 24: Hp cht (CH3)2C=CH-C(CH3)3 c danh php IUPAC l: A. 2,2,4- trimetylpent-3-en. B. 2,4-trimetylpent-2-en. C. 2,4,4-trimetylpent-2-en. D. 2,4-trimetylpent-3-en. Cu 25: Hp cht CH2=CHC(CH3)2CH2CH(OH)CH3 c danh php IUPAC l: A. 1,3,3-trimetylpent-4-en-1-ol. B. 3,3,5-trimetylpent-1-en-5-ol. C. 4,4-imetylhex-5-en-2-ol. D. 3,3-imetylhex-1-en-5-ol. Cu 26: Cho cng thc cu to sau : CH3CH(OH)CH=C(Cl)CHO. S oxi ha ca cc nguyn t cacbon tnh t phi sang tri c gi tr ln lt l: A. +1 ; +1 ; -1 ; 0 ; -3. B. +1 ; -1 ; -1 ; 0 ; -3. C. +1 ; +1 ; 0 ; -1 ; +3. D. +1 ; -1 ; 0 ; -1 ; +3. Cu 27: Trong cng thc CxHyOzNt tng s lin kt v vng l: A. (2x-y + t+2)/2. B. (2x-y + t+2). C. (2x-y - t+2)/2. D. (2x-y + z + t+2)/2. Cu 28: a. Vitamin A cng thc phn t C20H30O, co cha 1 vong 6 canh va khng co cha lin kt ba. S lin kt i trong phn t vitamin A la A. 7. B. 6. C. 5. D. 4. b. Licopen, cng thc phn t C40H56 la cht mau o trong qua ca chua, chi cha lin kt i va lin kt n trong phn t. Hiro hoa hoan toan licopen c hirocacbon C40H82. Vy licopen co A. 1 vong; 12 ni i. B. 1 vong; 5 ni i. C. 4 vong; 5 ni i. D. mach h; 13 ni i. Cu 29: Metol C10H20O va menton C10H18O chung u co trong tinh du bac ha. Bit phn t metol khng co ni i, con phn t menton co 1 ni i. Vy kt lun nao sau y la ung ? A. Metol va menton u co cu tao vong. B. Metol co cu tao vong, menton co cu tao mach h. C. Metol va menton u co cu tao mach h. D. Metol co cu tao mach h, menton co cu tao vong. Cu 30: Trong hp cht CxHyOz th y lun lun chn v y 2x+2 l do: A. a 0 (a l tng s lin kt v vng trong phn t). B. z 0 (mi nguyn t oxi to c 2 lin kt). C. mi nguyn t cacbon ch to c 4 lin kt. D. cacbon v oxi u c ha tr l nhng s chn. Cu 31: Tng s lin kt v vng ng vi cng thc C5H9O2Cl l: A. 0. B. 1. C. 2. D. 3. Cu 32: Tng s lin kt v vng ng vi cng thc C5H12O2 l: A. 0. B. 1. C. 2. D. 3. Cu 33: Cng thc tng qut ca dn xut iclo mch h c cha mt lin kt ba trong phn t l A. CnH2n-2Cl2. B. CnH2n-4Cl2. C. CnH2nCl2. D. CnH2n-6Cl2. Cu 34: Cng thc tng qut ca dn xut ibrom khng no mch h cha a lin kt l A. CnH2n+2-2aBr2. B. CnH2n-2aBr2. C. CnH2n-2-2aBr2. D. CnH2n+2+2aBr2. Cu 35: Hp cht hu c c cng thc tng qut CnH2n+2O2 thuc loi A. ancol hoc ete no, mch h, hai chc. B. anehit hoc xeton no, mch h, hai chc. C. axit hoc este no, n chc, mch h. D. hiroxicacbonyl no, mch h. Cu 36: Ancol no mch h c cng thc tng qut chnh xc nht l A. R(OH)m. B. CnH2n+2Om. C. CnH2n+1OH. D. CnH2n+2-m(OH)m. Cu 37: Cng thc tng qut ca anehit n chc mch h c 1 lin kt i C=C l:

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A. CnH2n+1CHO. B. CnH2nCHO. C. CnH2n-1CHO. D. CnH2n-3CHO. Cu 38: Anehit mch h c cng thc tng qut CnH2n-2O thuc loi A. anehit n chc no. B. anehit n chc cha mt lin kt i trong gc hirocacbon. C. anehit n chc cha hai lin kt trong gc hirocacbon. D. anehit n chc cha ba lin kt trong gc hirocacbon. Cu 39: Cng thc tng qut ca ancol n chc mch h c 2 ni i trong gc hirocacbon l A. CnH2n-4O. B. CnH2n-2O. C. CnH2nO. D. CnH2n+2O. Cu 40: Anehit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l: A. 0. B. 1. C. 2. D. 3. Cu 41: Cng thc phn t tng qut ca axit hai chc mch h cha mt lin kt i trong gc hirocacbon l: A. CnH2n-4O4. B. CnH2n-2O4. C. CnH2n-6O4. D. CnH2nO4. Cu 42: Axit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l: A. 0. B. 1. C. 2. D. 3. Cu 43: Tng s lin kt v vng trong phn t axit benzoic l: A. 3. B. 4. C. 5. D. 6. Cu 44: S lng ng phn ng vi cng thc phn t C6H14 A. 6. B. 7. C. 4. D. 5. Cu 45: S lng ng phn mch h ng vi cng thc phn t C5H10 l: A. 2. B. 3. C. 6. D. 5. Cu 46: S lng ng phn cu to ng vi cng thc phn t C5H10 l: A. 7. B. 8. C. 9. D. 10. Cu 47: S lng ng phn mch h ng vi cng thc phn t C5H8 l: A. 7. B. 8. C. 9. D. 10. Cu 48: S lng ng phn cha vng benzen ng vi cng thc phn t C9H12 l: A. 7. B. 8. C. 9. D. 10. Cu 49: S lng ng phn cha vng benzen ng vi cng thc phn t C9H10 l: A. 7. B. 8. C. 9. D. 6. Cu 50: S lng ng phn ng vi cng thc phn t C3H5Br3 l: A. 3. B. 4. C. 5. D. 6. Cu 51: S lng ng phn ng vi cng thc phn t C3H5Cl l: A. 3. B. 4. C. 5. D. 6. Cu 52: Hp cht C4H10O c s ng phn ancol v tng s ng phn l: A. 7 v 4. B. 4 v 7. C. 8 v 8. D.10 v 10. Cu 53: S lng ng phn mch h ng vi cng thc phn t C3H6O l: A. 2. B. 3. C. 4. D. 5. Cu 54: S lng ng phn mch h ng vi cng thc phn t C4H6O2 tc dng c vi NaHCO3 l: A. 2. B. 3. C. 4. D. 5. Cu 55: S lng ng phn ng vi cng thc phn t C4H11N l: A. 7. B. 8. C. 9. D. 10. Cu 56: Mt hp cht hu c X c khi lng phn t l 26. em t X ch thu c CO 2 v H2O. CTPT ca X l: A. C2H6. B. C2H4. C. C2H2. D. CH2O. Cu 57: Mt hp cht hu c A c M = 74. t chy A bng oxi thu c kh CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A? A. 4. B. 2. C. 3. D. A.1. Cu 58: Mt hp cht hu c A c t khi so vi khng kh bng bng 2. t chy hon ton A bng kh O2 thu c CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A ? A. 2. B. A. 1. C. 3. D. 4. Cu 59: Hp cht X c thnh phn % v khi lng : C (85,8%) v H (14,2%). Hp cht X l A. C3H8. B. C4H10. C. C4H8. D. kt qu khc.

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Cu 60: Hp cht X c %C = 54,54% ; %H = 9,1%, cn li l oxi. Khi lng phn t ca X bng 88. CTPT ca X l: A. C4H10O. B. C5H12O. C. C4H10O2. D. C4H8O2. Cu 61: Phn tch hp cht hu c X thy c 3 phn khi lng cacbon li c 1 phn khi lng hiro, 7 phn khi lng nit v 8 phn lu hunh. Trong CTPT ca X ch c 1 nguyn t S, vy CTPT ca X l A. CH4NS. B. C2H2N2S. C. C2H6NS. D. CH4N2S. Cu 62: a. Hp cht X c CTGN l CH3O. CTPT no sau y ng vi X ? A. C3H9O3. B. C2H6O2. C. C2H6O. D. CH3O. b. Cng thc thc nghim ca cht hu c c dng (CH3Cl)n th cng thc phn t ca hp cht l A. CH3Cl. B. C2H6Cl2. C. C2H5Cl. D. C3H9Cl3. Cu 63: Mt hp cht hu c gm C, H, O ; trong cacbon chim 61,22% v khi lng. Cng thc phn t ca hp cht l: A. C3H6O2. B. C2H2O3. C. C5H6O2. D. C4H10O. Cu 64: Cht hu c X c M = 123 v khi lng C, H, O v N trong phn t theo th t t l vi 72 : 5 : 32 : 14. CTPT ca X l: A. C6H14O2N. B. C6H6ON2. C. C6H12ON. D. C6H5O2N. Cu 65: t chy hon ton 0,6 gam hp cht hu c X ri cho sn phm chy qua bnh ng dung dch Ca(OH)2 d thy c 2 gam kt ta v khi lng bnh tng thm 1,24 gam. T khi ca X so vi H2 bng 15. CTPT ca X l: A. C2H6O. B. CH2O. C. C2H4O. D. CH2O2. Cu 66: Khi t 1 lt kh X cn 6 lt O2 thu c 4 lt CO2 v 5 lt hi H2O (cc th tch kh o cng iu kin nhit , p sut). CTPT ca X l: A. C4H10O. B. C4H8O2. C. C4H10O2. D. C3H8O. Cu 67: t chy hon ton 3 gam hp cht hu c X thu c 4,4 gam CO2 v 1,8 gam H2O. Bit t khi ca X so vi He (MHe = 4) l 7,5. CTPT ca X l: A. CH2O2. B. C2H6. C. C2H4O. D. CH2O. Cu 68: t chy 1 lt hi hirocacbon vi mt th tch khng kh (lng d). Hn hp kh thu c sau khi hi H2O ngng t c th tch l 18,5 lt, cho qua dung dch KOH d cn 16,5 lt, cho hn hp kh i qua ng ng photpho d th cn li 16 lt. Xc nh CTPT ca hp cht trn bit cc th tch kh o cng iu kin nhit , p sut v O2 chim 1/5 khng kh, cn li l N2. A. C2H6. B. C2H4. C. C3H8. D. C2H2. Cu 69: t 0,15 mol mt hp cht hu c thu c 6,72 lt CO2 (ktc) v 5,4 gam H2O. Mt khc t 1 th tch hi cht cn 2,5 th tch O2. Cc th tch o cng iu kin nhit , p sut. CTPT ca hp cht l: A. C2H6O2. B. C2H6O. C. C2H4O2. D. C2H4O. Cu 70: t chy hon ton mt hp cht hu c X (C, H, N) bng lng khng kh va (gm 1/5 th tch O2, cn li l N2) c kh CO2 , H2O v N2. Cho ton b sn phm chy qua bnh ng dung dch Ba(OH)2 d thy c 39,4 gam kt ta, khi lng dung dch gim i 24,3 gam. Kh thot ra khi bnh c th tch 34,72 lt (ktc). Bit d X O < 2. CTPT ca X l: A. C2H7N. B. C2H8N. C. C2H7N2. D. C2H4N2. Cu 71: Oxi ha hon ton 4,02 gam mt hp cht hu c X ch thu c 3,18 gam Na2CO3 v 0,672 lt kh CO2. CTGN ca X l: A. CO2Na. B. CO2Na2. C. C3O2Na. D. C2O2Na. Cu 72: t chy hon ton mt hirocacbon trong 0,5 lt hn hp ca n vi CO2 bng 2,5 lt O2 thu c 3,4 lt kh. Hn hp ny sau khi ngng t ht hi nc cn 1,8 lt, tip tc cho hn hp kh cn li qua dung dch kim d th cn li 0,5 lt kh. Cc th tch c o cng iu kin nhit , p sut. CTPT ca hirocacbon l: A. C4H10. B. C3H8. C. C4H8. D. C3H6. Cu 73: t chy hon ton 1,605 gam hp cht hu c A thu c 4,62 gam CO2 ; 1,215 gam H2O v 168 ml N2 (ktc). T khi hi ca A so vi khng kh khng vt qu 4. Cng thc phn t ca A l: A. C5H5N. B. C6H9N. C. C7H9N. D. C6H7N. Cu 74: Oxi ha hon ton 6,15 gam hp cht hu c X thu c 2,25 gam H2O ; 6,72 lt CO2 v 0,56 lt N2 (kc). Phn trm khi lng ca C, H, N v O trong X ln lt l:
2

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A. 58,5% ; 4,1% ; 11,4% ; 26%. B. 48,9% ; 15,8% ; 35,3% ; 0%. C. 49,5% ; 9,8% ; 15,5% ; 25,2%. D. 59,1 % ; 17,4% ; 23,5% ; 0%. Cu 75: Phn tch 0,31gam hp cht hu c X ch cha C, H, N to thnh 0,44 gam CO2. Mt khc, nu phn tch 0,31 gam X ton b N trong X chuyn thnh NH3 ri dn NH3 va to thnh vo 100 ml dung dch H2SO4 0,4M th phn axit d c trung ha bi 50 ml dung dch NaOH 1,4M. Bit 1 lt hi cht X (ktc) nng 1,38 gam. CTPT ca X l: A. CH5N. B. C2H5N2. C. C2H5N. D. CH6N. Cu 76: t chy 200 ml hi mt hp cht hu c X cha C, H, O trong 900 ml O2, th tch hn hp kh thu c l 1,3 lt. Sau khi ngng t hi nc ch cn 700 ml. Tip theo cho qua dung dch KOH d ch cn 100 ml kh bay ra. Cc th tch kh o cng iu kin nhit , p sut. CTPT ca Y l: A. C3H6O. B. C3H8O2. C. C3H8O. D. C3H6O2. Cu 77: Phn tch 1,5 gam cht hu c X thu c 1,76 gam CO2 ; 0,9 gam H2O v 112 ml N2 o 0oC v 2 atm. Nu ha hi cng 1,5 gam cht Z 127o C v 1,64 atm ngi ta thu c 0,4 lt kh cht Z. CTPT ca X l: A. C2H5ON. B. C6H5ON2. C. C2H5O2N. D. C2H6O2N. Cu 78: t chay hoan toan mt th tich hi hp cht hu c A cn 10 th tich oxi (o cung iu kin nhit v p sut), san phm thu c chi gm CO2 va H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A co cng thc phn t la: A. C4H6O. B. C8H8O. C. C8H8. D. C2H2. Cu 79: Cho 400 ml mt hn hp gm nit v mt hirocacbon vo 900 ml oxi (d) ri t. Th tch hn hp thu c sau khi t l 1,4 lt. Sau khi cho nc ngng t cn 800 ml hn hp, ngi ta cho li qua dung dch KOH thy cn 400 ml kh. Cc th tch kh u o cng iu kin nhit , p sut. Cng thc phn t ca cht hu c l: A. C3H8. B. C2H4. C. C2H2. D. C2H6. Cu 80: t chy 0,282 gam hp cht hu c X, cho sn phm i qua cc bnh ng CaCl2 khan v KOH d. Thy bnh ng CaCl2 tng thm 0,194 gam cn bnh ng KOH tng thm 0,8 gam. Mt khc nu t chy 0,186 gam cht X th thu c 22,4 ml kh N2 ( ktc). Bit rng hp cht X ch cha mt nguyn t nit. Cng thc phn t ca hp cht X l: A. C6H6N2. B. C6H7N. C. C6H9N. D. C5H7N. Cu 81: t chy hon ton hp cht hu c cha C, H, Cl sinh ra 0,22 gam CO2, 0,09 gam H2O. Mt khc khi xc nh clo trong hp cht bng dung dch AgNO3 ngi ta thu c 1,435 gam AgCl. T khi hi ca hp cht so vi hiro bng 42,5. Cng thc phn t ca hp cht l: A. CH3Cl. B. C2H5Cl. C. CH2Cl2. D. C2H4Cl2. Cu 82: t chy hon ton 0,4524 gam hp cht A sinh ra 0,3318 gam CO2 v 0,2714 gam H2O. un nng 0,3682 gam cht A vi vi ti xt chuyn tt c nit trong A thnh amoniac, ri dn kh NH3 vo 20 ml dung dch H2SO4 0,5 M. trung ho axit cn d sau khi tc dng vi NH3 cn dng 7,7 ml dung dch NaOH 1M. Bit MA= 60. Cng thc phn t ca A l: A. CH4ON2. B. C2H7N. C. C3H9N. D. CH4ON. Cu 83*: t chy hon ton 0,01 mol cht hu c X cn va 0,616 lt O2. Sau th nghim thu c hn hp sn phm Y gm : CO2, N2 v hi H2O. Lm lnh ngng t hi H2O ch cn 0,56 lt hn hp kh Z (c t khi hi vi H2 l 20,4). Bit th tch cc kh u o ktc. Cng thc phn t X l: A. C2H5ON. B. C2H5O2N. C. C2H7O2N. D. A hoc C. Cu 84: X la mt ancol no, mach h. t chay 0,05 mol X cn 4 gam oxi. X co cng thc l: A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C4H8(OH)2. Cu 85: Khi t chy hon ton mt amin n chc X, thu c 16,80 lt kh CO2 ; 2,80 lt N2 (cc th tch o ktc) v 20,25 gam H2O. CTPT ca X l: A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. Cu 86: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO2, 12,6 gam H2O v 69,44 lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chim 20% th tch khng kh. X c cng thc l: A. C2H5NH2. B. C3H7NH2. C. CH3NH2. D. C4H9NH2.

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Hu c 11
Cu 87: Trong mt binh kin cha hi este no n chc h A va mt lng O2 gp i lng O2 cn thit t chay ht A nhit 140oC va ap sut 0,8 atm. t chay hoan toan A ri a v nhit ban u, ap sut trong binh luc nay la 0,95 atm. A co cng thc phn t la: A. C2H4O2. B. C3H6O2. C. C4H8O2. D. C5H10O2. Cu 88: t chy hon ton 0,12 mol cht hu c X mch h cn dng 10,08 lt kh O2 (ktc). Dn ton b sn phm chy (gm CO2, H2O v N2) qua bnh ng dung dch Ba(OH)2 d, thy khi lng bnh tng 23,4 gam v c 70,92 gam kt ta. Kh thot ra khi bnh c th tch 1,344 lt (ktc). Cng thc phn t ca X l: A. C2H5O2N. B. C3H5O2N. C. C3H7O2N. D. C2H7O2N. Cu 89: t chy hon ton 0,1 mol cht X cn 6,16 lt kh O2 (ktc), thu c 13,44 lt (ktc) hn hp CO2, N2 v hi nc. Sau khi ngng t ht hi nc, cn li 5,6 lt kh (ktc) c t khi so vi hiro l 20,4. Cng thc phn t ca X l: A. C2H7O2N. B. C3H7O2N. C. C3H9O2N. D. C4H9N. Cu 90: t chy hon ton 0,1 mol mt ancol mch h ba ln cha mt lin kt ba trong gc hirocacbon thu c 0,6 mol CO2. Cng thc phn t ca ancol l: A. C6H14O3. B. C6H12O3. C. C6H10O3. D. C6H8O3. Cu 91: t chy hon ton 1,18 gam cht Y (CxHyN) bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH) 2 d, thu c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. Bit khng kh cha 20% oxi v 80% nit v th tch. Cng thc phn t ca Y l: A. C2H7N. B. C3H9N. C. C4H11N. D. C4H9N. Cu 92: Phn tch 1,47 gam cht hu c Y (C, H, O) bng CuO th thu c 2,156 gam CO 2 v lng CuO gim 1,568 gam. CTGN ca Y l: A. CH3O. B. CH2O. C. C2H3O. D. C2H3O2. Cu 93: t chy hon ton mt hp cht hu c n chc X thu c sn phm chy ch gm CO2 v H2O vi t l khi lng tng ng l 44 : 27. Cng thc phn t ca X l: A. C2H6. B. C2H6O. C. C2H6O2. D. C2H4O. Cu 94: Mt hp cht hu c Y khi t chy thu c CO 2 v H2O c s mol bng nhau v lng oxi cn dng bng 4 ln s mol ca Y. Cng thc phn t ca Y l: A. C2H6O. B. C4H8O. C. C3H6O. D. C3H6O2. Cu 95: t chy hon ton 0,2 mol mt axit cacboxylic no 2 ln thu c 1,2 mol CO2. Cng thc phn t ca axit l: A. C6H14O4. B. C6H12O4. C. C6H10O4. D. C6H8O4. Cu 96: t chy hon ton 5,8 gam mt hp cht hu c n chc X cn 8,96 lt kh O 2 (ktc), thu c CO2 v H2O c s mol bng nhau. CTGN ca X l: A. C2H4O. B. C3H6O. C. C4H8O. D. C5H10O. Cu 97: t chay hoan toan 0,2 mol hirocacbon X. Hp thu toan b san phm chay vao nc vi trong c 20 gam kt tua. Loc bo kt tua ri un nong phn nc loc lai co 10 gam kt tua na. Vy X khng th la: A. C2H6. B. C2H4. C. CH4. D. C2H2. Cu 98: Hn hp X gm mt s hirocacbon l ng ng k tip. Tng khi lng phn t ca cc hirocacbon trong A l 252, trong khi lng phn t ca hirocacbon nng nht bng 2 ln khi lng phn t ca hirocacbon nh nht. Cng thc phn t ca hirocacbon nh nht v s lng hirocacbon trong X l: A. C3H6 v 4. B. C2H4 v 5. C. C3H8 v 4. D. C2H6 v 5. Cu 99: t chy hon ton 5,80 gam cht X thu c 2,65 gam Na2CO3 ; 2,26 gam H2O v 12,10 gam CO2. Cng thc phn t ca X l: A. C6H5O2Na. B. C6H5ONa. C. C7H7O2Na. D. C7H7ONa. Cu 100: t chy hon ton 1,88 gam hp cht hu c Z (cha C, H, O) cn 1,904 lt kh O 2 (ktc), thu c CO2 v H2O vi t l mol tng ng l 4 : 3. Cng thc phn t ca Z l: A. C4H6O2. B. C8H12O4. C. C4H6O3. D. C8H12O5.

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CHUYN 2 :

HIROCACBON NO

Cu 1: Hp cht hu c X c tn gi l: 2 - clo - 3 - metylpentan. Cng thc cu to ca X l: A. CH3CH2CH(Cl)CH(CH3)2. B. CH3CH(Cl)CH(CH3)CH2CH3. C. CH3CH2CH(CH3)CH2CH2Cl. D. CH3CH(Cl)CH3CH(CH3)CH3. Cu 2: C bao nhiu ng phn cu to c cng thc phn t C5H12 ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn Cu 3: C bao nhiu ng phn cu to c cng thc phn t C6H14 ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn Cu 4: C bao nhiu ng phn cu to c cng thc phn t C4H9Cl ? A. 3 ng phn. B. 4 ng phn. C. 5 ng phn. D. 6 ng phn. Cu 5: C bao nhiu ng phn cu to c cng thc phn t C5H11Cl ? A. 6 ng phn. B. 7 ng phn. C. 5 ng phn. D. 8 ng phn. Cu 6: Phn trm khi lng cacbon trong phn t ankan Y bng 83,33%. Cng thc phn t ca Y l: A. C2H6. B. C3H8. C. C4H10. D. C5H12. Cu 7: Cng thc n gin nht ca hirocacbon M l CnH2n+1. M thuc dy ng ng no ? A. ankan. B. khng d kin xc nh. C. ankan hoc xicloankan. D. xicloankan. Cu 8: a. 2,2,3,3-tetrametylbutan c bao nhiu nguyn t C v H trong phn t ? A. 8C,16H. B. 8C,14H. C. 6C, 12H. D. 8C,18H. b. Cho ankan c CTCT l: (CH3)2CHCH2C(CH3)3. Tn gi ca ankan l: A. 2,2,4-trimetylpentan. B. 2,4-trimetylpetan. C. 2,4,4-trimetylpentan. D. 2-imetyl-4-metylpentan. Cu 9: Phn ng c trng ca hirocacbon no l A. Phn ng tch. B. Phn ng th. C. Phn ng cng. D. C A, B v C. Cu 10: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l: A. 2. B. 3. C. 5. D. 4. Cu 11: Iso-hexan tac dung vi clo (co chiu sang) co th tao ti a bao nhiu dn xut monoclo ? A. 3. B. 4. C. 5. D. 6 Cu 12: Khi cho 2-metylbutan tc dng vi Cl2 theo t l mol 1:1 th to ra sn phm chnh l: A. 1-clo-2-metylbutan. B. 2-clo-2-metylbutan. C. 2-clo-3-metylbutan. D.1-clo-3metylbutan. Cu 13: Khi clo ha C5H12 vi t l mol 1:1 thu c 3 sn phm th monoclo. Danh php IUPAC ca ankan l: A. 2,2-imetylpropan. B. 2-metylbutan. C. pentan. D.2imetylpropan. Cu 14: Khi clo ha metan thu c mt sn phm th cha 89,12% clo v khi lng. Cng thc ca sn phm l: A. CH3Cl. B. CH2Cl2. C. CHCl3. D. CCl4. Cu 15: Cho 4 cht: metan, etan, propan v n-butan. S lng cht to c mt sn phm th monoclo duy nht l: A. 1. B. 2. C. 3. D. 4. Cu 16: khi clo ha mt ankan c cng thc phn t C 6H14, ngi ta ch thu c 2 sn phm th monoclo. Danh php IUPAC ca ankan l: A. 2,2-imetylbutan. B. 2-metylpentan. C. n-hexan. D.2,3imetylbutan. Cu 17: Khi clo ha hn hp 2 ankan, ngi ta ch thu c 3 sn phm th monoclo. Tn gi ca 2 ankan l: A. etan v propan. B. propan v iso-butan. C. iso-butan v n-pentan. D. neo-pentan v etan.

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Hu c 11
Cu 18: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l: A. 3,3-imetylhecxan. C. isopentan. B. 2,2-imetylpropan. D. 2,2,3-trimetylpentan Cu 19: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l: A. 3-metylpentan. B. 2,3-imetylbutan. C. 2-metylpropan. D. butan. Cu 20: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l: A. 3. B. 4. C. 2. D. 5. Cu 21: Khi tin hnh phn ng th gia ankan X vi kh clo c chiu sng ngi ta thu c hn hp Y ch cha hai cht sn phm. T khi hi ca Y so vi hiro l 35,75. Tn ca X l A. 2,2-imetylpropan. B. 2-metylbutan. C. pentan. D. etan. Cu 22: Ankan no sau y ch cho 1 sn phm th duy nht khi tc dng vi Cl2 (as) theo t l mol (1 : 1): CH3CH2CH3 (a), CH4 (b), CH3C(CH3)2CH3 (c), CH3CH3 (d), CH3CH(CH3)CH3(e) A. (a), (e), (d). B. (b), (c), (d). C. (c), (d), (e). D. (a), (b), (c), (e), (d) Cu 23: Khi th monoclo mt ankan A ngi ta lun thu c mt sn phm duy nht. Vy A l: A. metan. B. etan C. neo-pentan D. C A, B, C u ng. Cu 24: Sn phm ca phn ng th clo (1:1, nh sng) vo 2,2- imetyl propan l : (1) CH3C(CH3)2CH2Cl; (2) CH3C(CH2Cl)2CH3 ; (3) CH3ClC(CH3)3 A. (1); (2). B. (2); (3). C. (2). D. (1) Cu 25: C bao nhiu ankan l cht kh iu kin thng khi phn ng vi clo (c nh sng, t l mol 1:1) to ra 2 dn xut monoclo ? A. 4. B. 2. C. 5. D. 3. Cu 26: Ankan Y phn ng vi brom to ra 2 dn xut monobrom c t khi hi so vi H2 bng 61,5. Tn ca Y l: A. butan. B. propan. C. Iso-butan. D. 2-metylbutan. Cu 27: t chy mt hn hp gm nhiu hirocacbon trong cng mt dy ng ng nu ta thu c s mol H2O > s mol CO2 th CTPT chung ca dy l: A. CnHn, n 2. B. CnH2n+2, n 1 (cc gi tr n u nguyn). C. CnH2n-2, n 2. D. Tt c u sai. Cu 28: t chay cac hirocacbon cua day ng ng nao di y thi ti l mol H 2O : mol CO2 giam khi s cacbon tng. A. ankan. B. anken. C. ankin. D. aren Cu 29: Khi t chy ankan thu c H2O v CO2 vi t l tng ng bin i nh sau: A. tng t 2 n + . B. gim t 2 n 1. C. tng t 1 n 2. D. gim t 1 n 0. Cu 30: Khng th iu ch CH4 bng phn ng no ? A. Nung mui natri malonat vi vi ti xt. B. Canxicacbua tc dng vi nc. C. Nung natri axetat vi vi ti xt. D. in phn dung dch natri axetat. Cu 31: Trong phng th nghim c th iu ch metan bng cch no sau y ? A. Nhit phn natri axetat vi vi ti xt. B. Crackinh butan C. T phn ng ca nhm cacbua vi nc. D. A, C. Cu 32: Thnh phn chnh ca kh thin nhin l: A. metan. B. etan. C. propan. D. n-butan. Cu 33: Xicloankan (ch c mt vng) A c t khi so vi nit bng 3. A tc dng vi clo c chiu sng ch cho mt dn xut monoclo duy nht, xc nh cng thc cu to ca A ?
CH3
CH3

CH3

A.

B.

C.

H3C

D.

H3C

CH3

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Hu c 11
Cu 34: Hai xicloankan M v N u c t khi hi so vi metan bng 5,25. Khi tham gia phn ng th clo (as, t l mol 1:1) M cho 4 sn phm th cn N cho 1 sn phm th. Tn gi ca cc xicloankan N v M l: A. metyl xiclopentan v imetyl xiclobutan. B. Xiclohexan v metyl xiclopentan. C. Xiclohexan v n-propyl xiclopropan. D. C A, B, C u ng. Cu 35: (A) l cht no trong phn ng sau y ? A + Br2 Br-CH2-CH2-CH2-Br A. propan. B. 1-brompropan. C. xiclopopan. D. A v B u ng. Cu 36: Dn hn hp kh A gm propan v xiclopropan i vo dung dch brom s quan st c hin tng no sau y : A. Mu ca dung dch nht dn, khng c kh thot ra. B. Mu ca dung dch nht dn, v c kh thot ra. C. Mu ca dung dch mt hn, khng cn kh thot ra. D. Mu ca dung dch khng i. Cu 37: Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: n A : nB = 1 : 4. Khi lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan A v B ln lt l: A. C2H6 v C4H10. B. C5H12 v C6H14. C. C2H6 v C3H8. D. C4H10 v C3H8 Cu 38: Khi tin hnh craking 22,4 lt kh C4H10 (ktc) thu c hn hp A gm CH4, C2H6, C2H4, C3H6, C4H8, H2 v C4H10 d. t chy hon ton A thu c x gam CO 2 v y gam H2O. Gi tr ca x v y tng ng l: A. 176 v 180. B. 44 v 18. C. 44 v 72. D. 176 v 90. Cu 39: Craking n-butan thu c 35 mol hn hp A gm H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn butan cha b craking. Gi s ch c cc phn ng to ra cc sn phm trn. Cho A qua bnh nc brom d thy cn li 20 mol kh. Nu t chy hon ton A th thu c x mol CO2. a. Hiu sut phn ng to hn hp A l: A. 57,14%. B. 75,00%. C. 42,86%. D. 25,00%. b. Gi tr ca x l: A. 140. B. 70. C. 80. D. 40. Cu 40: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l: A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 41: Khi crackinh hon ton mt ankan X thu c hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 29. Cng thc phn t ca X l: A. C6H14. B. C3H8. C. C4H10. D. C5H12 Cu 42: Craking 8,8 gam propan thu c hn hp A gm H 2, CH4, C2H4, C3H6 v mt phn propan cha b craking. Bit hiu sut phn ng l 90%. Khi lng phn t trung bnh ca A l: A. 39,6. B. 23,16. C. 2,315. D. 3,96. Cu 43: Craking 40 lit n-butan thu c 56 lit hn hp A gm H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn n-butan cha b craking (cc th tch kh o cng iu kin nhit v p sut). Gi s ch c cc phn ng to ra cc sn phm trn. Hiu sut phn ng to hn hp A l: A. 40%. B. 20%. C. 80%. D. 20%. Cu 44: Craking m gam n-butan thu c hp A gm H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn butan cha b craking. t chy hon ton A thu c 9 gam H2O v 17,6 gam CO2. Gi tr ca m l A. 5,8. B. 11,6. C. 2,6. D. 23,2. Cu 45: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO 2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 70,0 lt. B. 78,4 lt. C. 84,0 lt. D. 56,0 lt. Cu 46: t chy mt hn hp hirocacbon ta thu c 2,24 lt CO2 (ktc) v 2,7 gam H2O th th tch O2 tham gia phn ng chy (ktc) l: A. 5,6 lt. B. 2,8 lt. C. 4,48 lt. D. 3,92 lt. Cu 47: Hn hp kh A gm etan v propan. t chy hn hp A thu c kh CO2 v hi H2O theo t l th tch 11:15. Thnh phn % theo khi lng ca hn hp l:

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A. 18,52% ; 81,48%. B. 45% ; 55%. C. 28,13% ; 71,87%. D. 25% ; 75%. Cu 48: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo thu c 4 sn phm monoclo. Tn gi ca X l: A. 2-metylbutan. B. etan. C. 2,2-imetylpropan. D. 2-metylpropan. Cu 49: Mt hn hp 2 ankan lin tip trong dy ng ng c t khi hi vi H2 l 24,8. a. Cng thc phn t ca 2 ankan l: A. C2H6 v C3H8. B. C4H10 v C5H12. C. C3H8 v C4H10. D. Kt qu khc b. Thnh phn phn trm v th tch ca 2 ankan l: A. 30% v 70%. B. 35% v 65%. C. 60% v 40%. D. 50% v 50% Cu 50: iu kin tiu chun c 1 hn hp kh gm 2 hirocacbon no A v B, t khi hi ca hn hp i vi H2 l 12. a. Khi lng CO2 v hi H2O sinh ra khi t chy 15,68 lt hn hp ( ktc). A. 24,2 gam v 16,2 gam.B. 48,4 gam v 32,4 gam.C. 40 gam v 30 gam. D. Kt qu khc. b. Cng thc phn t ca A v B l: A. CH4 v C2H6.B. CH4 v C3H8. C. CH4 v C4H10. D. C A, B v C. 3 3 Cu 51: t 10 cm mt hirocacbon bng 80 cm oxi (ly d). Sn phm thu c sau khi cho hi nc ngng t cn 65 cm3 trong c 25 cm3 oxi d. Cc th tch trong cng iu kin. CTPT ca hirocacbon l: A. C4H10. B. C4H6. C. C5H10. D. C3H8 Cu 52: t chay hoan toan hn hp X gm hai ankan k tip trong day ng ng c 24,2 gam CO 2 va 12,6 gam H2O. Cng thc phn t 2 ankan la: A. CH4 va C2H6.B. C2H6 va C3H8. C. C3H8 va C4H10. D. C4H10 va C5H12 Cu 53: X la hn hp 2 ankan. t chay ht 10,2 gam X cn 25,76 lit O2 (ktc). Hp thu toan b san phm chay vao nc vi trong d c m gam kt tua. a. Gi tri m l: A. 30,8 gam. B. 70 gam. C. 55 gam. D. 15 gam b. Cng thc phn t ca A v B l: A. CH4 v C4H10. B. C2H6 v C4H10. C. C3H8 v C4H10. D. C A, B v C. Cu 54: Hirocacbon X chay cho th tich hi nc gp 1,2 ln th tich CO 2 (o cung k). Khi tac dung vi clo tao mt dn xut monoclo duy nht. X co tn la: A. isobutan. B. propan. C. etan. D. 2,2- imetylpropan. Cu 55: t chay hoan toan hn hp X gm 2 hirocacbon la ng ng lin tip, sau phn ng thu c VCO2:VH2O =1:1,6 (o cung k). X gm: A. CH4 va C2H6. B. C2H4 va C3H6. C. C2H2 va C3H6. D. C3H8 va C4H10. Cu 56: t chay hoan toan 0,2 mol hirocacbon X. Hp thu toan b san phm chay vao nc vi trong c 20 gam kt tua. Loc bo kt tua ri un nong phn nc loc lai co 10 gam kt tua na. Vy X khng th la: A. C2H6. B. C2H4. C. CH4. D. C2H2 Cu 57: n gian ta xem xng la hn hp cac ng phn cua hexan va khng khi gm 80% N 2 va 20% O2 (theo th tich). Ti l th tich xng (hi) va khng khi cn ly la bao nhiu xng c chay hoan toan trong cac ng c t trong ? A. 1: 9,5. B. 1: 47,5. C. 1:48. D. 1:50 Cu 58: t chy hon ton hn hp hai hirocacbon ng ng c khi lng phn t hn km nhau 28 vC, ta thu c 4,48 l CO2 (ktc) v 5,4 gam H2O. CTPT ca 2 hirocacbon trn l: A. C2H4 v C4H8. B. C2H2 v C4H6. C. C3H4 v C5H8. D. CH4 v C3H8. Cu 59: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc) cha 12% C 2H2 ;10% CH4 ; 78%H2 (v th tch). Gi s ch xy ra 2 phn ng: 2CH4 C2H2 + 3H2 (1) CH4 C + 2H2 (2) Gi tr ca V l: A. 407,27. B. 448,00. C. 520,18. D. 472,64.

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Cu 60: t chy hon ton 2,24 lt hn hp A (ktc) gm CH 4, C2H6 v C3H8 thu c V lt kh CO2 (ktc) v 7,2 gam H2O. Gi tr ca V l: A. 5,60. B. 6,72. C. 4,48. D. 2,24. Cu 61: t chy hon ton 6,72 lt hn hp A (ktc) gm CH4, C2H6, C3H8, C2H4 v C3H6, thu c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Tng th tch ca C2H4 v C3H6 (ktc) trong hn hp A l: A. 5,60. B. 3,36. C. 4,48. D. 2,24. Cu 62: t chy hon ton hn hp A gm CH4, C2H2, C3H4, C4H6 thu c x mol CO2 v 18x gam H2O. Phn trm th tch ca CH4 trong A l: A. 30%. B. 40%. C. 50%. D. 60%. Cu 63: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng ng k tip thu c 96,8 gam CO2 v 57,6 gam H2O. Cng thc phn t ca A v B l: A. CH4 v C2H6.B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12 Cu 64: Hn hp kh X gm 2 hirocacbon A v B l ng ng k tip. t chy X vi 64 gam O 2 (d) ri dn sn phm thu c qua bnh ng Ca(OH)2 d thu c 100 gam kt ta. Kh ra khi bnh c th tch 11,2 lt 0oC v 0,4 atm. Cng thc phn t ca A v B l: A. CH4 v C2H6.B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12 Cu 65: Khi t chy hon ton V lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 44 gam CO2 v 28,8 gam H2O. Gi tr ca V l: A. 8,96. B. 11,20. C. 13,44. D. 15,68. Cu 66: Khi t chy hon ton 7,84 lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 16,8 lt kh CO2 (ktc) v x gam H2O. Gi tr ca x l: A. 6,3. B. 13,5. C. 18,0. D. 19,8. Cu 67: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c 7,84 lt kh CO 2 (ktc) v 9,0 gam H2O. Cng thc phn t ca 2 ankan l: A. CH4 v C2H6.B. C2H6 v C3H8. C. C3H8 v C4H10. D. C4H10 v C5H12. Cu 68: Np mt hn hp kh c 20% th tch ankan A v 80% th tch O2 (d) vo kh nhin k. Sau khi cho n ri cho hi nc ngng t nhit ban u th p sut trong kh nhin k gim i 2 ln. Thit lp cng thc phn t ca ankan A. A. CH4. B. C2H6. C. C3H8 . D.C4H10. Cu 69: t chy mt s mol nh nhau cua 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v t l s mol nc v CO2 i vi s mol ca K, L, M tng ng l 0,5 : 1 : 1,5. Xc nh CT K, L, M (vit theo th t tng ng): A. C2H4 , C2H6 , C3H4. B. C3H8 , C3H4 , C2H4. C. C3H4 , C3H6 , C3H8.D. C2H2 , C2H4 , C2H6 Cu 70: Nung m gam hn hp X gm 3 mui natri ca 3 axit no n chc vi NaOH d thu c cht rn D v hn hp Y gm 3 ankan. T khi ca Y so vi H2 l 11,5. Cho D tc dng vi H2SO4 d thu c 17,92 lt CO2 (ktc). a. Gi tr ca m l: A. 42,0. B. 84,8. C. 42,4. D. 71,2. b. Tn gi ca 1 trong 3 ankan thu c l: A. metan. B. etan. C. propan. D. butan.

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CHUYN 3 : HIROCACBON KHNG NO

BI TP V ANKEN
Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l A. isohexan. B. 3-metylpent-3-en. C. 3-metylpent-2-en. D. 2-etylbut-2-en. Cu 2: S ng phn ca C4H8 l A. 7. B. 4. C. 6. D. 5. Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 4: Hp cht C5H10 c bao nhiu ng phn anken ? A. 4. B. 5. C. 6. D. 7. Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 6: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankin. B. ankan. C. ankaien. D. anken. Cu 7: Anken X c c im: Trong phn t c 8 lin kt xch ma. CTPT ca X l A. C2H4. B. C4H8. C. C3H6. D. C5H10. Cu 8: Vitamin A cng thc phn t C20H30O, co cha 1 vong 6 canh va khng co cha lin kt ba. S lin kt i trong phn t vitamin A la A. 7. B. 6. C. 5. D. 4. Cu 9: Licopen, cng thc phn t C40H56 la cht mau o trong qua ca chua, chi cha lin kt i va lin kt n trong phn t. Hiro hoa hoan toan licopen c hirocacbon C40H82. Vy licopen co A. 1 vong; 12 ni i. B. 1 vong; 5 ni i. C. 4 vong; 5 ni i. D. mach h; 13 ni i. Cu 10: Cho cc cht sau: 2-metylbut-1-en (1); 3,3-imetylbut-1-en (2); 3-metylpent-1-en (3); 3-metylpent-2-en (4); Nhng cht no l ng phn ca nhau ? A. (3) v (4). B. (1), (2) v (3). C. (1) v (2). D. (2), (3) v (4). Cu 11: Hp cht no sau y c ng phn hnh hc ? A. 2-metylbut-2-en. B. 2-clo-but-1-en. C. 2,3- iclobut-2-en. D. 2,3- imetylpent-2en. Cu 12: Nhng hp cht no sau y c ng phn hnh hc (cis-trans) ? CH3CH=CH2 (I); CH3CH=CHCl (II); CH3CH=C(CH3)2 (III); C2H5C(CH3)=C(CH3)C2H5 (IV); C2H5 C(CH3)=CClCH3 (V). A. (I), (IV), (V). B. (II), (IV), (V). C. (III), (IV). D. (II), III, (IV), (V). Cu 13: Cho cc cht sau: CH2=CHCH2CH2CH=CH2; CH2=CHCH=CHCH2CH3; CH3C(CH3)=CHCH2; CH2=CHCH2CH=CH2; CH3CH2CH=CHCH2CH3; CH3C(CH3)=CHCH2CH3; CH3CH2C(CH3)=C(C2H5)CH(CH3)2; CH3CH=CHCH3. S cht c ng phn hnh hc l: A. 4. B. 1. C. 2. D. 3. Cu 14: p dng quy tc Maccopnhicop vo trng hp no sau y ? A. Phn ng cng ca Br2 vi anken i xng. C. Phn ng cng ca HX vo anken i xng. B. Phn ng trng hp ca anken. D. Phn ng cng ca HX vo anken bt i xng.

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Cu 15: Khi cho but-1-en tc dng vi dung dch HBr, theo qui tc Maccopnhicop sn phm no sau y l sn phm chnh ? A. CH3-CH2-CHBr-CH2Br. C. CH3-CH2-CHBr-CH3. B. CH2Br-CH2-CH2-CH2Br . D. CH3-CH2-CH2-CH2Br. Cu 16: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis -but-2-en v xiclobutan. Cu 18: Cho hn hp tt c cc ng phn mch h ca C 4H8 tc dng vi H2O (H+,to) thu c ti a bao nhiu sn phm cng ? A. 2. B. 4. C. 6. D. 5 Cu 19: C bao nhiu anken th kh (kt) m khi cho mi anken tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 21: Anken thch hp iu ch ancol sau y (CH3 CH2)3C-OH l A. 3-etylpent-2-en. B. 3-etylpent-3-en. C. 3-etylpent-1-en. D. 3,3- imetylpent-1en. Cu 22: Hirat ha hn hp X gm 2 anken thu c ch thu c 2 ancol. X gm A. CH2=CH2 v CH2=CHCH3. B. CH2=CH2 v CH3CH=CHCH3. C. B hoc D. D. CH3CH=CHCH3 v CH2=CHCH2CH3. Cu 23: S cp ng phn cu to anken th kh (kt) tho mn iu kin: Khi hirat ho to thnh hn hp gm ba ancol l A. 6. B. 3. C. 5. D. 4. Cu 24: S cp ng phn anken th kh (kt) tho mn iu kin: Khi hirat ho to thnh hn hp gm ba ancol l: A. 6. B. 7. C. 5. D. 8. Cu 25: Hp cht X c CTPT C3H6, X tc dng vi dung dch HBr thu c mt sn phm hu c duy nht. Vy X l: A. propen. B. propan. C. ispropen. D. xicloropan. Cu 26: Hai cht X, Y c CTPT C3H6 v C4H8 v u tc dng c vi nc brom. X, Y l A. Hai anken hoc xicloankan vng 3 cnh. C. Hai anken hoc xicloankan vng 4 cnh. B. Hai anken hoc hai ankan. D. Hai anken ng ng ca nhau. Cu 27: C hai ng nghim, mi ng cha 1 ml dung dch brom trong nc c mu vng nht. Thm vo ng th nht 1 ml hexan v ng th hai 1 ml hex-1-en. Lc u c hai ng nghim, sau yn hai ng nghim trong vi pht. Hin tng quan st c l: A. C s tch lp cc cht lng c hai ng nghim. B. Mu vng nht vn khng i ng nghim th nht C. ng nghim th hai c hai lp cht lng u khng mu. D. A, B, C u ng. Cu 28: Trng hp eten, sn phm thu c c cu to l: A. (-CH2=CH2-)n . B. (-CH2-CH2-)n . C. (-CH=CH-)n. D. (-CH3-CH3-)n . Cu 29: Oxi ho etilen bng dung dch KMnO4 thu c sn phm l: A. MnO2, C2H4(OH)2, KOH. C. K2CO3, H2O, MnO2. B. C2H5OH, MnO2, KOH. D. C2H4(OH)2, K2CO3, MnO2. Cu 30: X la h n h p g m 2 hirocacbon. t cha y X c nCO2 = nH2O. X co th g m A. 1xicloankan + anken.B. 1ankan + 1ankin. C. 2 anken. D. A hoc B hoc C.

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Cu 31: iu ch etilen trong phng th nghim t C2H5OH, (H2SO4 c, 170oC) thng ln cc oxit nh SO2, CO2. Cht dng lm sch etilen l: A. dd brom d. B. dd NaOH d. C. dd Na2CO3 d. D. dd KMnO4 long d. Cu 32: Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ? A. 3-Metylbut-1-en. B. 2-Metylbut-1en. C. 3-Metylbut-2-en. D. 2-Metylbut-2-en. Cu 33: Khi tch nc t ru (ancol) 3-metylbutanol-1 (hay 3-metylbutan-1-ol), sn phm chnh thu c l: A. 2-metylbuten-3 (hay 2-metylbut-3-en). B. 3-metylbuten-2 (hay 3-metylbut-2-en). C. 3-metylbuten-1 (hay 3-metylbut-1-en). D. 2-metylbuten-2 (hay 2-metylbut-2-en). Cu 34: Hp cht 2-metylbut-2-en l sn phm chnh ca phn ng tch t cht no ? A. 2-brom-2-metylbutan.B. 2-metylbutan -2- ol. C. 3-metylbutan-2- ol.D. Tt c u ng. Cu 35: Khi lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu sut phn ng t 40% l: A. 56 gam. B. 84 gam. C. 196 gam. D. 350 gam. Cu 36: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau phn ng khi lng bnh brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l: A. 0,05 v 0,1. B. 0,1 v 0,05. C. 0,12 v 0,03. D. 0,03 v 0,12. Cu 37: 2,8 gam anken A lam mt mau va u dung dich cha 8 gam Br2. Hirat hoa A chi thu c mt ancol duy nht. A co tn la: A. etilen. B. but - 2-en. C. hex- 2-en. D. 2,3-dimetylbut-2-en. Cu 38: 0,05 mol hirocacbon X lam mt mau va u dung dich cha 8 gam brom cho ra san phm co ham lng brom at 69,56%. Cng thc phn t cua X la: A. C3H6. B. C4H8. C. C5H10. D. C5H8. Cu 39: Dn t t 8,4 gam hn hp X gm but-1-en v but-2-en li chm qua bnh ng dung dch Br2, khi kt thc phn ng thy c m gam brom phn ng. m c gi tr l: A. 12 gam. B. 24 gam. C. 36 gam. D. 48 gam. Cu 40: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. Thnh phn phn % v th tch ca hai anken l: A. 25% v 75%. B. 33,33% v 66,67%. C. 40% v 60%. D. 35% v 65%. Cu 41: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho hn hp X i qua bnh ng nc brom d, khi lng bnh tng ln 9,8 gam. % th tch ca mt trong 2 anken l: A. 50%. B. 40%. C. 70%. D. 80%. Cu 42: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. CTPT ca 2 anken l: A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. Cu 43: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho X qua nc Br2 d thy khi lng bnh Br2 tng 15,4 gam. Xc nh CTPT v s mol mi anken trong hn hp X. A. 0,2 mol C2H4 v 0,3 mol C3H6. B. 0,2 mol C3H6 v 0,2 mol C4H8. C. 0,4 mol C2H4 v 0,1 mol C3H6. D. 0,3 mol C2H4 v 0,2 mol C3H6. Cu 44: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom tng ln 2,8 gam; th tch kh cn li ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v khi lng ca hn hp X l: A. C4H10, C3H6 ; 5,8 gam. B. C3H8, C2H4 ; 5,8 gam. C. C4H10, C3H6 ; 12,8 gam. D. C3H8, C2H4 ; 11,6 gam. Cu 45: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh ktc. Cho hn hp X i qua nc Br2 d th th tch kh Y cn li bng na th tch X, cn khi lng Y bng 15/29 khi lng X. CTPT A, B v thnh phn % theo th tch ca hn hp X l A. 40% C2H6 v 60% C2H4. B. 50% C3H8v 50% C3H6 C. 50% C4H10 v 50% C4H8. D. 50% C2H6 v 50% C2H4

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Cu 46 : Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung dch brom d thy c 1 cht kh bay ra, t chy hon ton kh ny thu c 5,544 gam CO2. Thnh phn % v th tch metan v olefin trong hn hp X l: A. 26,13% v 73,87%. B. 36,5% v 63,5%. C. 20% v 80%. D. 73,9% v 26,1%. Cu 47: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phn ng thy khi lng bnh brom tng 22,4 gam. Bit X c ng phn hnh hc. CTCT ca X l: A. CH2=CHCH2CH3. B. CH3CH=CHCH3. C. CH3CH=CHCH2CH3. D. (CH3)2C=CH2. Cu 48: a. Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l: A. but-1-en. B. but-2-en. C. Propilen. D. Xiclopropan. b. Hirocacbon X cng HCl theo ti l mol 1:1 tao san phm co ham lng clo la 55,04%. X co cng thc phn t l: A. C4H8. B. C2H4. C. C5H10. D. C3H6. Cu 49: Hn hp X gm metan v anken, cho 5,6 lt X qua dung dch brom d thy khi lng bnh brom tng 7,28 gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l: A. C4H8. B. C5H10. C. C3H6. D. C2H4 Cu 50: Dn 3,36 lt (ktc) hn hp X gm 2 anken l vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. CTPT ca 2 anken l: A. C2H4 v C4H8. B. C3H6 v C4H8. C. C4H8 v C5H10. D. A hoc B. Cu 51: Cho 10 lt hn hp kh (54,6oC; 0,8064 atm) gm 2 olefin li qua bnh dung dch brom d thy khi lng bnh brom tng 16,8 gam. CTPT ca 2 anken l (Bit s C trong cc anken khng vt qu 5) A. C2H4 v C5H10. B. C3H6 v C5H10. C. C4H8 v C5H10. D. A hoc B. Cu 52: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l: A. C3H6. B. C4H8. C. C2H4. D. C5H10. Cu 53: Cho hn hp X gm etilen v H2 c t khi so vi H2 bng 4,25. Dn X qua bt niken nung nng (hiu sut phn ng 75%) thu c hn hp Y. T khi ca Y so vi H 2 (cc th tch o cng iu kin) l: A. 5,23. B. 3,25. C. 5,35. D. 10,46. Cu 54: Cho H2 v 1 olefin c th tch bng nhau qua Niken un nng ta c hn hp A. Bit t khi hi ca A i vi H2 l 23,2. Hiu sut phn ng hiro ho l 75%. Cng thc phn t olefin l A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 55: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l: A. CH3CH=CHCH3. B. CH2=CHCH2CH3. C. CH2=C(CH3)2. D. CH2=CH2. Cu 56: Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i qua bt niken nung nng n khi phn ng xy ra hon ton, thu c hn hp Y c t khi so vi heli l 4. CTPT ca X l: A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 57: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l: A. 20%. B. 25%. C. 50%. D. 40%. Cu 58: t chy hon ton a gam hn hp eten, propen, but-2-en cn dng va b lt oxi ( ktc) thu c 2,4 mol CO2 v 2,4 mol nc. Gi tr ca b l: A. 92,4 lt. B. 94,2 lt. C. 80,64 lt. D. 24,9 lt. Cu 59: t chy hon ton V lt (ktc) hn hp X gm CH 4, C2H4 thu c 0,15 mol CO2 v 0,2 mol H2O. Gi tr ca V l: A. 2,24. B. 3,36. C. 4,48. D. 1,68.

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Cu 60: t chy hon ton 0,1 mol hm hp gm CH4, C4H10 v C2H4 thu c 0,14 mol CO2 v 0,23mol H2O. S mol ca ankan v anken trong hn hp ln lt l: A. 0,09 v 0,01. B. 0,01 v 0,09. C. 0,08 v 0,02. D. 0,02 v 0,08. Cu 61: Mt hn hp kh gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v c cng s mol. Ly m gam hn hp ny th lm mt mu va 80 gam dung dch 20% Br2 trong dung mi CCl4. t chy hon ton m gam hn hp thu c 0,6 mol CO 2. Ankan v anken c cng thc phn t l: A. C2H6 v C2H4. B. C4H10 v C4H8. C. C3H8 v C3H6. D. C5H12 v C5H10. Cu 62: t chy hon ton 10ml hirocacbon X cn va 60 ml kh oxi, sau phn ng thu c 40 ml kh cacbonic. Bit X lm mt mu dung dch brom v c mch cacbon phn nhnh. CTCT ca X A. CH2=CHCH2CH3. B. CH2=C(CH3)2. C. CH2=C(CH2)2CH3. D. (CH3)2C=CHCH3. Cu 63: Cho 0,2 mol hn hp X gm etan, propan v propen qua dung dch brom d, thy khi lng bnh brom tng 4,2 gam. Lng kh cn li em t chy hon ton thu c 6,48 gam nc. Vy % th tch etan, propan v propen ln lt l: A. 30%, 20%, 50%. B. 20%, 50%, 30%. C. 50%, 20%, 30%. D. 20%, 30%, 50%. Cu 64: Mt hn hp X gm 2 hirocacbon A, B c cng s nguyn t cacbon. A, B ch c th l ankan hay anken. t chy 4,48 lt (kc) hn hp X thu c 26,4 gam CO2 v 12,6 gam H2O. Xc nh CTPT v s mol ca A, B trong hn hp X. A. 0,1 mol C3H8 v 0,1 mol C3H6. B. 0,2 mol C2H6 v 0,2 mol C2H4. C. 0,08 mol C3H8 v 0,12 mol C3H6. D. 0,1 mol C2H6 v 0,2 mol C2H4. Cu 65: Mt hn hp X gm 1 anken A v 1 ankin B, A v B c cng s nguyn t cacbon. X c khi lng l 12,4 gam, c th tch l 6,72 lt. Cc th tch kh o ktc. CTPT v s mol A, B trong hn hp X l: A. 0,2 mol C2H4 v 0,1 mol C2H2. B. 0,1 mol C3H6 v 0,1 mol C3H4. C. 0,2 mol C3H6 v 0,1 mol C3H4. D. 0,1 mol C2H4 v 0,2 mol C2H2. Cu 66: Mt hn hp A gm 2 hirocacbon X, Y lin tip nhau trong cng dy ng ng. t chy 11,2 lt hn hp X thu c 57,2 gam CO2 v 23,4 gam CO2. CTPT X, Y v khi lng ca X, Y l: A. 12,6 gam C3H6 v 11,2 gam C4H8. B. 8,6 gam C3H6v 11,2 gam C4H8. C. 5,6 gam C2H4 v 12,6 gam C3H6. D. 2,8 gam C2H4 v 16,8 gam C3H6. Cu 67: t chy hon ton 0,05 mol mt anken A thu c 4,48 lt CO 2 (ktc). Cho A tc dng vi dung dch HBr ch cho mt sn phm duy nht. CTCT ca A l: A. CH2=CH2. B. (CH3)2C=C(CH3)2. C. CH2=C(CH3)2. D. CH3CH=CHCH3. Cu 68: Hn hp X gm propen l ng ng theo t l th tch 1:1. t 1 th tch hn hp X cn 3,75 th tch oxi (cng k). Vy B l: A. eten. B. propan. C. buten. D. penten. Cu 69: em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu c CO2 v nc c khi lng hn km nhau 6,76 gam. CTPT ca 2 anken l: A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. Cu 70: X, Y, Z la 3 hirocacbon k tip trong day ng ng, trong o MZ = 2MX. t chay hoan toan 0,1 mol Y ri hp thu toan b san phm chay vao 2 lit dung dich Ba(OH)2 0,1M c mt lng kt tua la: A. 19,7 gam. B. 39,4 gam. C. 59,1 gam. D. 9,85 gam. Cu 71: Chia hn hp gm C3H6, C2H4, C2H2 thnh hai phn u nhau. Phn 1: t chy hon ton thu c 2,24 lt CO2 (ktc). Phn 2: Hiro ho ri t chy ht th th tch CO2 thu c (ktc) l bao nhiu ? A. 1,12 lt. B. 2,24 lt. C. 4,48 lt. D. 3,36 lt. Cu 72: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh H2 l: A. 12,9. B. 25,8. C. 22,2. D. 11,1 Cu 73: t chy hon ton 0,1 mol anken X thu c CO2 v hi nc. Hp th hon ton sn phm bng 100 gam dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH ch cn 5%. Cng thc phn t ng ca X l:

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A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 74: X la hn hp gm hirocacbon A va O2 (ti l mol tng ng 1:10). t chay hoan toan X c hn hp Y. Dn Y qua binh H SO4 c d c hn Z co ti khi so vi hiro la 19. A co cng thc phn 2 t la: A. C2H6. B. C4H8. C C4H6. D. C3H6. Cu 75: m gam hn hp gm C3H6, C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO2 (ktc). Nu hiro ho hon ton m gam hn hp trn ri t chy ht hn hp thu c V lt CO 2 (ktc). Gi tr ca V l: A. 3,36. B. 2,24. C. 4,48. D. 1,12. Cu 76: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4.B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. Cu 77: Hn hp X gm C3H8 va C3H6 co ti khi so vi hiro la 21,8. t chay ht 5,6 lit X (ktc) thi thu c bao nhiu gam CO2 va bao nhiu gam H2O ? A. 33 gam va 17,1 gam.B. 22 gam va 9,9 gam. C. 13,2 gam va 7,2 gam.D. 33 gam va 21,6 gam. Cu 78: Hin nay PVC c iu ch theo s sau: C2H4 CH2ClCH2Cl C2H3Cl PVC. Nu hiu sut ton b qu trnh t 80% th lng C2H4 cn dng sn xut 5000 kg PVC l: A. 280 kg. B. 1792 kg. C. 2800 kg. D. 179,2 kg. Cu 79: Thi 0,25 mol kh etilen qua 125 ml dung dch KMnO4 1M trong mi trng trung tnh (hiu sut 100%) khi lng etylen glicol thu c bng A. 11,625 gam. B. 23,25 gam. C. 15,5 gam. D. 31 gam. Cu 80: kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l: A. 2,240. B. 2,688. C. 4,480. D. 1,344. Cu 81: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Z, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l: A. 20. B. 40. C. 30. D. 10. Cu 82: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l: A. 18,60 gam. B. 18,96 gam. C. 20,40 gam. D. 16,80 gam. Cu 83: X la hn hp C4H8 va O2 (ti l mol tng ng 1:10). t chay hoan toan X c hn hp Y. Dn Y qua binh H2SO4 c d c hn Z. Ti khi ca Z so vi hiro la A.18. B. 19. C. 20. D. 21. Cu 84: Hn hp X gm 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc t chy hon ton hn hp X dng ht 24,64 lt O2 (ktc). Cng thc phn t ca 2 anken l: A. C2H4 v C3H6. B. C2H4 v C4H8. C. C3H6 v C4H8. D. A v B u ng. Cu 85: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v t l s mol nc v CO2 i vi s mol ca K, L, M tng ng l 0,5 ; 1 ; 1,5. CTPT ca K, L, M (vit theo th t tng ng) l: A. C2H4, C2H6, C3H4. B. C3H8, C3H4, C2H4. C. C3H4, C3H6, C3H8. D. C2H2, C2H4, C2H6.

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BI TP V ANKAIEN -TECPEN - ANKIN

Cu 1: S ng phn thuc loi ankaien ng vi cng thc phn t C5H8 l A. 4. B. 5. C. 6. D. 7. Cu 2: C5H8 c bao nhiu ng phn ankaien lin hp ? A. 2. B. 3. C. 4. D. 5. Cu 3: Trong cc hirocacbon sau: propen, but-1-en, but-2-en, penta-1,4- ien, penta-1,3- ien hirocacbon cho c hin tng ng phn cis - trans ? A. propen, but-1-en. B. penta-1,4-dien, but-1-en. C. propen, but-2-en. D. but-2-en, penta-1,3- ien. Cu 4: Cng thc phn t ca buta-1,3-ien (ivinyl) v isopren (2-metylbuta-1,3-ien) ln lt l A. C4H6 v C5H10. B. C4H4 v C5H8. C. C4H6 v C5H8. D. C4H8 v C5H10. Cu 5: Hp cht no trong s cc cht sau c 9 lin kt xch ma v 2 lin kt ? A. Buta-1,3-ien. B. Penta-1,3- ien. C. Stiren. D. Vinyl axetilen. Cu 6: Hp cht no trong s cc cht sau c 7 lin kt xch ma v 3 lin kt ? A. Buta-1,3-ien. B. Tuloen. C. Stiren. D. Vinyl axetilen. Cu 7: Cho phn ng gia buta-1,3-ien v HBr -80oC (t l mol 1:1), sn phm chnh ca phn ng l A. CH3CHBrCH=CH2. B. CH3CH=CHCH2Br. C. CH2BrCH2CH=CH2.D. CH3CH=CBrCH3. Cu 8: Cho phn ng gia buta-1,3-ien v HBr 40oC (t l mol 1:1), sn phm chnh ca phn ng l A. CH3CHBrCH=CH2. B. CH3CH=CHCH2Br. C. CH2BrCH2CH=CH2.D. CH3CH=CBrCH3. Cu 9: 1 mol buta-1,3-ien c th phn ng ti a vi bao nhiu mol brom ? A. 1 mol. B. 1,5 mol. C. 2 mol. D. 0,5 mol. Cu 10: Isopren tham gia phn ng vi dung dch Br2 theo t l mol 1:1 to ra ti a bao nhiu sn phm ? A. 4. B. 1. C. 3. D. 2. Cu 11: Isopren tham gia phn ng vi dung dch HBr theo t l mol 1:1 to ra ti a bao nhiu sn phm cng ? A. 8. B. 5. C. 7. D. 6. Cu 12: Cht no sau y khng phi l sn phm cng gia dung dch brom v isopren (theo t l mol 1:1) ? A. CH2BrC(CH3)BrCH=CH2. B. CH2BrC(CH3)=CHCH2Br. C. CH2BrCH=CHCH2CH2Br. D. CH2=C(CH3)CHBrCH2Br. Cu 13: Ankaien A + brom (dd) CH3C(CH3)BrCH=CHCH2Br. Vy A l A. 2-metylpenta-1,3-ien. B. 2-metylpenta-2,4-ien. C. 4-metylpenta-1,3-ien. D. 2-metylbuta-1,3-ien. CH2ClC(CH3)=CH-CH2Cl-CH3. Vy A l Cu 14: Ankaien B + Cl2 A. 2-metylpenta-1,3-ien. B. 4-metylpenta-2,4-ien. C. 2-metylpenta-1,4-ien. D. 4-metylpenta-2,3-ien. Cu 15: Cho 1 Ankaien A + brom(dd) 1,4-ibrom-2-metylbut-2-en. Vy A l A. 2-metylbuta-1,3-ien. C. 3-metylbuta-1,3-ien. B. 2-metylpenta-1,3-ien. D. 3-metylpenta-1,3-ien. Cu 16: Trng hp ivinyl to ra cao su Buna c cu to l ? A. (-C2H-CH-CH-CH2-)n. B. (-CH2-CH=CH-CH2-)n. C. (-CH2-CH-CH=CH2-)n. D. (-CH2-CH2-CH2-CH2-)n. Cu 17: ng trng hp ivinyl v stiren thu c cao su buna-S c cng thc cu to l

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A. (-CH2-CH=CH-CH2-CH(C6H5)-CH2-)n. B. (-C2H-CH-CH-CH2-CH(C6H5)-CH2-)n. C. (-CH2-CH-CH=CH2- CH(C6H5)-CH2-)n. D. (-CH2-CH2-CH2-CH2- CH(C6H5)-CH2-)n . Cu 18: ng trng hp ivinyl v acrylonitrin (vinyl xianua) thu c cao su buna-N c cng thc cu to l A. (-C2H-CH-CH-CH2-CH(CN)-CH2-)n. B. (-CH2-CH2-CH2-CH2- CH(CN)-CH2-)n. C. (-CH2-CH-CH=CH2- CH(CN)-CH2-)n. D. (-CH2-CH=CH-CH2-CH(CN)-CH2-)n . Cu 19: Trng hp isopren to ra cao su isopren c cu to l A. (-C2H-C(CH3)-CH-CH2-)n . C. (-CH2-C(CH3)-CH=CH2-)n . B. (-CH2-C(CH3)=CH-CH2-)n. D. (-CH2-CH(CH3)-CH2-CH2-)n . Cu 20: Tn gi ca nhm hirocacbon khng no c cng thc chung l (C5H8)n (n 2) l A. ankaien. B. cao su. C. anlen. D. tecpen. Cu 21: Caroten (licopen) l sc t mu ca c rt v c chua chn, cng thc phn t ca caroten l A. C15H25. B. C40H56. C. C10H16. D. C30H50. Cu 22: Oximen c trong tinh du l hng qu, limonen c trong tinh du chanh. Chng c cng cng thc phn t l A. C15H25. B. C40H56. C. C10H16. D. C30H50. Cu 23: C4H6 c bao nhiu ng phn mch h ? A. 5. B. 2. C. 3. D. 4. Cu 24: C bao nhiu ankin ng vi cng thc phn t C5H8 ? A. 1. B. 2. C. 3. D. 4 Cu 25: Ankin C4H6 c bao nhiu ng phn cho phn ng th kim loi (phn ng vi dung dch cha AgNO3/NH3) A. 4. B. 2. C. 1. D. 3. Cu 26: C bao nhiu ng phn ankin C5H8 tc dng c vi dung dch AgNO3/NH3 to kt ta A. 3. B. 2. C. 4. D. 1. Cu 27: Ankin C6H10 c bao nhiu ng phn phn ng vi dung dch AgNO3/NH3 ? A. 3. B. 4. C. 5. D. 6. Cu 28: Trong phn t ankin X, hiro chim 11,111% khi lng. C bao nhiu ankin ph hp A. 1. B. 2. C. 3. D. 4 Cu 29: Cho ankin X c cng thc cu to sau : CH3C C CH CH3 Tn ca X l CH3 A. 4-metylpent-2-in. B. 2-metylpent-3-in. C. 4-metylpent-3-in. D. 2-metylpent-4-in. Cu 30: Cho phn ng : C2H2 + H2O A A l cht no di y A. CH2=CHOH. B. CH3CHO. C. CH3COOH.D. C2H5OH. Cu 31: Cho s phn ng sau: CH3-CCH + AgNO3/ NH3 X + NH4NO3 X c cng thc cu to l? A. CH3-CAgCAg. B. CH3-CCAg. C. AgCH2-CCAg.D. A, B, C u c th ng. Cu 32: Trong s cc hirocacbon mch h sau: C4H10, C4H6, C4H8, C3H4, nhng hirocacbon no c th to kt ta vi dung dch AgNO3/NH3 ? A. C4H10 ,C4H8. B. C4H6, C3H4. C. Ch c C4H6. D. Ch c C3H4. Cu 33: Hn hp A gm hiro v cc hirocacbon no, cha no. Cho A vo bnh c niken xc tc, un nng bnh mt thi gian ta thu c hn hp B. Pht biu no sau y sai ? A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v s mol nc khi t chy hon ton hn hp B. B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon ton hn hp B. C. S mol A - S mol B = S mol H2 tham gia phn ng. D. Khi lng phn t trung bnh ca hn hp A bng khi lng phn t trung bnh ca hn hp B.

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Cu 34: Cht no trong 4 cht di y c th tham gia c 4 phn ng: Phn ng chy trong oxi, phn ng cng brom, phn ng cng hiro (xc tc Ni, to), phn ng th vi dd AgNO3 /NH3 A. etan. B. etilen. C. axetilen. D. xiclopropan. Cu 35: Cu no sau y sai ? A. Ankin c s ng phn t hn anken tng ng. B. Ankin tng t anken u c ng phn hnh hc. C. Hai ankin u dy khng c ng phn. D. Butin c 2 ng phn v tr nhm chc. Cu 36: Cho cc phn ng sau: (2) C2H4 + H2 (3) 2 CHCH (4) 3 CHCH (5) C2H2 + Ag2O (6) Propin + H2O S phn ng l phn ng oxi ho kh l: A. 2. B. 3. C. 4. D. 5. A B C Cao su buna. Cng thc phn t ca B Cu 37: Cho dy chuyn ho sau: CH4 l A. C4H6. B. C2H5OH. C. C4H4. D. C4H10. Cu 38: C chui phn ng sau: KH O H l D N + H2 B D C E (spc) Xc nh N, B, D, E bit rng D l mt hidrocacbon mch h, D ch c 1 ng phn. A. N : C2H2 ; B : Pd ; D : C2H4 ; E : CH3CH2Cl. B. N : C4H6 ; B : Pd ; D : C4H8 ; E : CH2ClCH2CH2CH3. C. N : C3H4 ; B : Pd ; D : C3H6 ; E : CH3CHClCH3. D. N : C3H4 ; B : Pd ; D : C3H6 ; E : CHCH2CH2Cl. Cu 39: Cht no sau y khng iu ch trc tip c axetilen ? A. Ag2C2. B. CH4. C. Al4C3. D. CaC2. Cu 40: lm sch etilen c ln axetilen ta cho hn hp i qua dd no sau y ? A. dd brom d. B. dd KMnO4 d. C. dd AgNO3 /NH3 d. D. cc cch trn u ng. Cu 41: nhn bit cc bnh ring bit ng cc kh khng mu sau y: SO2, C2H2, NH3 ta c th dng ho cht no sau y ? A. Dung dch AgNO3/NH3.B. Dung dch Ca(OH)2 C. Qu tm m. D. Dung dch NaOH Cu 42: X l mt hirocacbon kh ( ktc), mch h. Hiro ho hon ton X thu c hirocacbon no Y c khi lng phn t gp 1,074 ln khi lng phn t X. Cng thc phn t X l A. C2H2. B. C3H4. C. C4H6. D. C3H6. Cu 43: Cht hu c X c cng thc phn t C6H6 mch thng. Bit 1 mol X tc dng vi AgNO3 d trong NH3 to ra 292 gam kt ta. CTCT ca X c th l A. CH CCCCH2CH3. C. CHCCH2CH=C=CH2. B. CHCCH2CCCH3. D. CHCCH2CH2CCH. Cu 44: Mt hirocacbon A mch thng c CTPT C6H6. Khi cho A tc dng vi dung dch AgNO 3/NH3 d thu c hp cht hu c B c MB - MA=214 vC. Xc nh CTCT ca A ? A. CHCCH2CH2CCH. B. CH3C CCH2CCH. C. CHCCH(CH3)CCH. D. CH3CH2CCCCH. Cu 45: A la hirocacbon mach h, th khi (kt), bit A 1 mol A tac dung c ti a 2 mol Br2 trong dung dich to ra hp cht B (trong B brom chim 88,88% v khi lng. Vy A co cng thc phn t la A. C5H8. B. C2H2. C. C4H6. D. C3H4. Cu 46: 4 gam mt ankin X c th lm mt mu ti a 100 ml dung dch Br2 2M. CTPT X l A. C5H8 . B. C2H2. C. C3H4. D. C4H6. Cu 47: X l mt hirocacbon khng no mch h, 1 mol X c th lm mt mu ti a 2 mol brom trong nc. X c % khi lng H trong phn t l 10%. CTPT X l A. C2H2. B. C3H4. C. C2H4. D. C4H6. Cu 48: X l hn hp gm 2 hirocacbon mch h (thuc dy ng ng ankin, anken, ankan). Cho 0,3 mol X lm mt mu va 0,5 mol brom. Pht biu no di y ng A. X c th gm 2 ankan. B. X c th gm2 anken.
1:1 (1) C H4 + C2 l a skt

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Hu c 11
C. X c th gm1 ankan v 1 anken. D. X c th gm1 anken v mt ankin. Cu 49: Hn hp X gm 1 ankin th kh v hiro c t khi hi so vi CH 4 l 0,425. Nung nng hn hp X vi xc tc Ni phn ng hon ton thu c hn hp kh Y c t khi hi so vi CH4 l 0,8. Cho Y i qua bnh ng dung dch brom d, khi lng bnh tng ln bao nhiu gam ? A. 8. B. 16. C. 0. D. Khng tnh c. Cu 50: Hn hp A gm C2H2 v H2 c dA/H2 = 5,8. Dn A (ktc) qua bt Ni nung nng cho n khi cc phn ng xy ra hon ton ta c hn hp B. Phn trm th tch mi kh trong hn hp A v dB/H2 l A. 40% H2; 60% C2H2; 29. B. 40% H2; 60% C2H2 ; 14,5. C. 60% H2; 40% C2H2 ; 29. D. 60% H2; 40% C2H2 ; 14,5. Cu 51: Mt hn hp gm etilen v axetilen c th tch 6,72 lt (ktc). Cho hn hp qua dung dch brom d phn ng xy ra hon ton, lng brom phn ng l 64 gam. Phn % v th tch etilen v axetilen ln lt l A. 66% v 34%. B. 65,66% v 34,34%. C. 66,67% v 33,33%. D. Kt qu khc. Cu 52: Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2 (Ni, to). Sau khi phn ng xy ra hon ton thu c 16 lt hn hp kh (cc kh u o cng iu kin nhit p sut). Th tch ca CH 4 v C2H2 trc phn ng l A. 2 lt v 8 lt. B. 3 lt v 7 lt. C. 8 lt v 2 lt. D. 2,5 lt v 7,5 lt. Cu 53: Cho 28,2 gam hn hp X gm 3 ankin ng ng k tip qua mt lng d H 2 (to, Ni) phn ng xy ra hon ton. Sau phn ng th tch th tch kh H2 gim 26,88 lt (ktc). CTPT ca 3 ankin l A. C2H2, C3H4, C4H6. B. C3H4, C4H6, C5H8. C. C4H6, C5H8, C6H10. D. C A, B u ng. Cu 54: Hn hp X gm propin v mt ankin A c t l mol 1:1. Ly 0,3 mol X tc dng vi dung dch AgNO3/NH3 d thu c 46,2 gam kt ta. A l A. But-1-in. B. But-2-in. C. Axetilen. D. Pent-1-in. Cu 55: Trong bnh kn cha hirocacbon X v hiro. Nung nng bnh n khi phn ng hon ton thu c kh Y duy nht. cng nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut trong bnh sau khi nung. t chy mt lng Y thu c 8,8 gam CO 2 v 5,4 gam nc. Cng thc phn t ca X l A. C2H2. B. C2H4. C. C4H6. D. C3H4. Cu 56: t chy hon ton mt ankin X th kh thu c H2O v CO2 c tng khi lng l 23 gam. Nu cho sn phm chy i qua dung dich Ca(OH)2 d, c 40 gam kt ta. Cng thc phn t ca X l A. C3H4. B. C2H2. C. C4H6. D. C5H8. Cu 57: t chy hon ton 5,4 gam mt hirocacbon A ri cho sn phm chy i qua bnh 1 ng dd H2SO4 c, d; bnh 2 ng dung dch Ba(OH)2 d thy khi lng bnh 1 tng 5,4 gam; bnh 2 tng 17,6 gam. A l cht no trong nhng cht sau ? (A khng tc dng vi dd AgNO3/NH3) A. But-1-in. B. But-2-in. C. Buta-1,3-ien. D. B hoc C. Cu 58: Hn hp X gm C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tc thch hp, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom thy khi lung bnh tng 10,8 gam v thot ra 4,48 lt kh Z (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 33,6 lt. B. 22,4 lt. C. 16,8 lt. D. 44,8 lt. Cu 59: Cho 17,92 lt hn hp X gm 3 hirocacbon kh l ankan, anken v ankin ly theo t l mol 1:1:2 li qua bnh ng dd AgNO3/NH3 ly d thu c 96 gam kt ta v hn hp kh Y cn li. t chy hon ton hn hp Y thu c 13,44 lt CO2. Bit th tch o ktc. Khi lng ca X l A. 19,2 gam. B. 1,92 gam. C. 3,84 gam. D. 38,4 gam. Cu 60: Mt hn hp gm 2 ankin khi t chy cho ra 13,2 gam CO2 v 3,6 gam H2O. Tnh khi lng brom c th cng vo hn hp trn A. 16 gam. B. 24 gam. C. 32 gam. D. 4 gam. Cu 61: Cho canxi cacbua k thut (ch cha 80% CaC2 nguyn cht) vo nc d, th thu c 3,36 lt kh (ktc). Khi lng canxi cacbua k thut dng l A. 9,6 gam. B. 4,8 gam C. 4,6 gam. D. 12 gam

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Hu c 11
Cu 62: C 20 gam mt mu CaC2 (c ln tp cht tr) tc dng vi nc thu c 7,4 lt kh axetilen (20oC, 740mmHg). Cho rng phn ng xy ra hon ton. tinh khit ca mu CaC2 l A. 64%. B. 96%. C. 84%. D. 48%. Cu 63: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 40%. B. 20%. C. 25%. D. 50%. Cu 64: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,1 mol C3H6 v 0,2 mol C3H4. C. 0,2 mol C2H4 v 0,1 mol C2H2. D. 0,2 mol C3H6 v 0,1 mol C3H4. Cu 65: Trong mt binh kin cha hirocacbon A th khi (kt) va O2 (d). Bt tia la in t chay ht A a hn hp v iu kin ban u trong o % th tich cua CO2 va hi nc ln lt la 30% va 20%. Cng thc phn t cua A va % th tich ca hirocacbon A trong hn hp la A. C3H4 va 10%. B. C3H4 va 90%. C. C3H8 va 20%. D. C4H6 va 30%. Cu 66: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o trong cng iu kin nhit v p sut). Cng thc phn t ca X l A. C2H4. B. CH4. C. C2H6. D. C3H8. Cu 67: Hn hp X c t khi so vi H2 l 21 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 18,60 gam. B. 18,96 gam. C. 20,40 gam. D. 16,80 gam. Cu 68: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 224,0. B. 448,0. C. 286,7. D. 358,4. Cu 69: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam. Cu 70: t chy hon ton m gam hirocacbon th kh, mch h, nng hn khng kh thu c 7,04 gam CO2. Sc m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l A. 2 gam. B. 4 gam. C. 10 gam D. 2,08 gam Cu 71: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04 gam CO 2. Sc m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l A. 2 gam. B. 4 gam. C. 2,08 gam. D. A hoc C. Cu 72: Dn V lt ( ktc) hh X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dd NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z c 2,24 lt kh CO2 (ktc) v 4,5 gam H2O. Gi tr ca V bng A. 11,2. B. 13,44. C. 5,60. D. 8,96. Cu 73: Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi p hon ton, s mol Br2 gim i mt na v m bnh tng thm 6,7 gam. CTPT ca 2 hirocacbon l A. C3H4 v C4H8. B. C2H2 v C3H8. C. C2H2 v C4H8. D. C2H2 v C4H6. Cu 74: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dd brom (d). Sau khi phn ng hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2 (ktc). CTPT ca hai hirocacbon l A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. Cu 75: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn % v s mol ca X v Y trong hn hp M ln lt l A. 35% v 65%. B. 75% v 25%. C. 20% v 80%. D. 50% v 50%.

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Hu c 11
Cu 76: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc kh o cng iu kin to, p). T khi ca X so vi kh hiro l A. 25,8. B. 12,9. C. 22,2. D. 11,1. Cu 77: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H 2 c hn hp Y. Khi cho Y qua Pt nung nng th thu c kh Z c t khi i vi CO 2 bng 1 (phn ng cng H2 hon ton). Bit rng VX = 6,72 lt v VH = 4,48 lt. CTPT v s mol A, B trong hn hp X l (Cc th tch kh o kc) A. 0,1 mol C2H6 v 0,2 mol C2H2. B. 0,1 mol C3H8 v 0,2 mol C3H4. C. 0,2 mol C2H6 v 0,1 mol C2H2. D. 0,2 mol C3H8 v 0,1 mol C3H4. Cu 78: Mt hn hp X gm C2H2, C3H6, CH4. t chy hon ton 11t hn hp X thu c 12,6 gam H2O. Nu cho 11,2 lt hn hp X (ktc) qua dung dch brom d thy c 100 gam brom phn ng. Thnh phn % th tch ca X ln lt l A. 50%; 25% ; 25%. B. 25% ; 25; 50%. C.16% ; 32; 52%. D. 33,33%; 33,33; 33,33%. Cu 79: Dn 4,032 lt (ktc) hn hp kh A gm C2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dc AgNO3 trong NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2 gam kt ta. Khi lng bnh 2 tng thm 1,68 gam. Th tch (ktc) hn hp A ln lt l: A. 0,672 lt; 1,344 lt; 2,016 lt. B. 0,672 lt; 0,672 lt; 2,688 lt. C. 2,016; 0,896 lt; 1,12 lt. D. 1,344 lt; 2,016 lt; 0,672 lt. Cu 80: X, Y, Z l 3 hirocacbon th kh trong iu kin thng, khi phn hu mi cht X, Y, Z u to ra C v H2, th tch H2 lun gp 3 ln th tch hirocacbon b phn hu v X, Y, Z khng phi l dng phn. CTPT ca 3 cht l A. C2H6 ,C3H6 C4H6. B. C2H2 ,C3H4 C4H6. C. CH4 ,C2H4 C3H4. D. CH4 ,C2H6 C3H8. Cu 81: Hn hp X gm 0,1 mol C2H2; 0,15 mol C2H4 ; 0,2 mol C2H6 v 0,3 mol H2. un nng X vi bt Ni xc tc 1 thi gian c hn hp Y. t chy hon ton hn hp Y c s gam CO2 v H2O ln lt l A. 39,6 v 23,4. B. 3,96 v 3,35. C. 39,6 v 46,8. D. 39,6 v 11,6. Cu 82: Hn hp ban u gm 1 ankin, 1 anken, 1 ankan v H2 vi p sut 4 atm. un nng bnh vi Ni xc tc thc hin phn ng cng sau a bnh v nhit ban u c hn hp Y, p sut hn hp Y l 3 atm. T khi hn hp X v Y so vi H2 ln lt l 24 v x. Gi tr ca x l A. 18. B. 34. C. 24. D. 32. Cu 83: Hn hp A gm H2, C3H8, C3H4. Cho t t 12 lt A qua bt Ni xc tc. Sau phn ng c 6 lt kh duy nht (cc kh o cng iu kin). T khi hi ca A so vi H2 l A. 11. B. 22. C. 26. D. 13. Cu 84: un nng hn hp X gm 0,1 mol C3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc c hn hp Y. Dn ton b Y qua bnh ng dung dch KMnO4 d, thy thot ra 6,72 l hn hp kh Z (ktc) c t khi so vi H2 l 12. Bnh ng dung dch KMnO4 tng s gam l: A. 17,2. B. 9,6. C. 7,2. D. 3,1. Cu 85: t chy m gam hn hp C2H6, C3H4, C3H8, C4H10 c 35,2 gam CO2 v 21,6 gam H2O. Gi tr ca m l A. 14,4. B. 10,8. C. 12. D. 56,8. Cu 86: t chy 1 hirocacbon A c 22,4 lt kh CO2 (ktc) v 27 gam H2O. Th tch O2 (ktc) (l) tham gia phn ng l: A. 24,8. B. 45,3. C. 39,2. D. 51,2. Cu 87: Mt hn hp X gm 1 ankin v H2 c V = 8,96 lt (kc) v mX = 4,6 gam. Cho hn hp X i qua
2

Ni nung nng, phn ng hon ton cho ra hn hp kh Y, c t khi

= 2. S mol H2 phn ng; khi

lng; CTPT ca ankin l A. 0,16 mol; 3,6 gam; C2H2. B. 0,2 mol; 4 gam; C3H4. C. 0,2 mol; 4 gam; C2H2. D. 0,3 mol; 2 gam; C3H4. Cu 88: t chy mt hirocacbon M thu c s mol nc bng s mol CO2 v s mol CO2 nh hn hoc bng 5 ln s mol M. Xc nh CTPT v CTCT ca M bit rng M cho kt ta vi dung dch AgNO3/NH3.

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A. C4H6 v CH3CH2C CH. C. C3H4 v CH3C CH.

B. C4H6 v CH2=C=CHCH3. D. C4H6 v CH3C CCH3.

CHUYN 4 : HIROCACBON THM NGUN HIROCACBON THIN NHIN

Cu 1: Trong phn t benzen, cc nguyn t C u trng thi lai ho : A. sp. B. sp2. C. sp3. D. sp2d. Cu 2: Trong vng benzen mi nguyn t C dng 1 obitan p cha tham gia lai ho to ra : A. 2 lin kt pi ring l. B. 2 lin kt pi ring l. C. 1 h lin kt pi chung cho 6 C. D. 1 h lin kt xigma chung cho 6 C. Cu 3: Trong phn t benzen: A. 6 nguyn t H v 6 C u nm trn 1 mt phng. B. 6 nguyn t H nm trn cng 1 mt phng khc vi mt phng ca 6 C. C. Ch c 6 C nm trong cng 1 mt phng. D. Ch c 6 H mm trong cng 1 mt phng. Cu 4: Cho cc cng thc :
H

(1) (2) (3) Cu to no l ca benzen ? A. (1) v (2). B. (1) v (3). C. (2) v (3). D. (1) ; (2) v (3). Cu 5: Dy ng ng ca benzen c cng thc chung l: A. CnH2n+6 ; n 6. B. CnH2n-6 ; n 3. C. CnH2n-6 ; n 6. D. CnH2n-6 ; n 6. Cu 6: Cng thc tng qut ca hirocacbon CnH2n+2-2a. i vi stiren, gi tr ca n v a ln lt l: A. 8 v 5. B. 5 v 8. C. 8 v 4. D. 4 v 8. Cu 7: Cng thc tng qut ca hirocacbon CnH2n+2-2a. i vi naptalen, gi tr ca n v a ln lt l: A. 10 v 5. B. 10 v 6. C. 10 v 7. D.10 v 8. Cu 8: Cht no sau y c th cha vng benzen ? A. C10H16. B. C9H14BrCl. C. C8H6Cl2. D. C7H12. Cu 9: Cht no sau y khng th cha vng benzen ? A. C8H10. B. C6H8. C. C8H10. D. C9H12. Cu 10: Cho cc cht: C6H5CH3 (1) p-CH3C6H4C2H5 (2) C6H5C2H3 (3) o-CH3C6H4CH3 (4) Dy gm cc cht l ng ng ca benzen l: A. (1); (2) v (3). B. (2); (3) v (4). C. (1); (3) v (4). D. (1); (2) v (4).
CH3

Cu 11: Cht cu to nh sau c tn gi l g ? A. o-xilen. B. m-xilen. Cu 12: CH3C6H2C2H5 c tn gi l: A. etylmetylbenzen. B. metyletylbenzen. Cu 13: (CH3)2CHC6H5 c tn gi l: A. propylbenzen. B. n-propylbenzen. Cu 14: iso-propyl benzen cn gi l: A.Toluen. B. Stiren. Cu 15: Cu to ca 4-cloetylbenzen l:

CH3

C. p-xilen.

D. 1,5-imetylbenzen.

C. p-etylmetylbenzen. D. p-metyletylbenzen. C. iso-propylbenzen. D. imetylbenzen. C. Cumen. D. Xilen.

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C2H5
C2H5

C2H5
C2H5 Cl

Cl A. Cl B. C. D. Cu 16: Ankylbenzen l hirocacbon c cha : A. vng benzen. B. gc ankyl v vng benzen. C. gc ankyl v 1 benzen. D. gc ankyl v 1 vng benzen. Cu 17: Gc C6H5-CH2- v gc C6H5- c tn gi l: A. phenyl v benzyl. B. vinyl v anlyl. C. anlyl v Vinyl. D. benzyl v phenyl. Cu 18: iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen ? A. v tr 1, 2 gi l ortho. B. v tr 1,4 gi l para. C. v tr 1,3 gi l meta. D. v tr 1,5 gi l ortho. Cu 19: Mt ankylbenzen A c cng thc C9H12, cu to c tnh i xng cao. Vy A l: A. 1,2,3-trimetyl benzen. B. n-propyl benzen. C. iso-propyl benzen. D. 1,3,5-trimetyl benzen. Cu 20: Mt ankylbenzen A (C12H18) cu to c tnh i xng cao. A l: A. 1,3,5-trietylbenzen. B. 1,2,4-tri etylbenzen. C. 1,2,3-tri metylbenzen. D. 1,2,3,4,5,6-hexaetylbenzen. Cu 21: C7H8 c s ng phn thm l: A. 1. B. 2. C. 3. D. 4. Cu 22: ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen ? A. 2. B. 3. C. 4. D. 5. Cu 23: ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen ? A. 6. B. 7. C. 8. D. 9. Cu 24: S lng ng phn cha vng benzen ng vi cng thc phn t C9H10 l A. 7. B. 8. C. 9. D. 6. Cu 25: A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A l: A. C3H4. B. C6H8. C. C9H12. D. C12H16. Cu 26: Cho cc cht (1) benzen ; (2) toluen; (3) xiclohexan; (4) hex-5-trien; (5) xilen; (6) cumen. Dy gm cc hirocacbon thm l: A. (1); (2); (3); (4). B. (1); (2); (5; (6). C. (2); (3); (5) ; (6). D. (1); (5); (6); (4). Cu 27: Hot tnh sinh hc ca benzen, toluen l: A. Gy hi cho sc khe. B. Khng gy hi cho sc khe. C. Gy nh hng tt cho sc khe. D. Ty thuc vo nhit c th gy hi hoc khng gy hi. Cu 28: Tnh cht no sau y khng phi ca ankyl benzen A. Khng mu sc. B. Khng mi v. C. Khng tan trong nc. D. Tan nhiu trong cc dung mi hu c. Cu 29: Phn ng no sau y khng xy ra: A. Benzen + Cl2 (as). B. Benzen + H2 (Ni, p, to). C. Benzen + Br2 (dd). D. Benzen + HNO3 () /H2SO4 (). Cu 30: Tnh cht no khng phi ca benzen ? A. D th. B. Kh cng. C. Bn vi cht oxi ha. D. Km bn vi cc cht oxi ha. Cu 31: Cho benzen + Cl2 (as) ta thu c dn xut clo A. Vy A l: A. C6H5Cl. B. p-C6H4Cl2. C. C6H6Cl6. D. m-C6H4Cl2. Cu 32: Phn ng chng minh tnh cht no; khng no ca benzen ln lt l: A. th, cng. B. cng, nitro ho. C. chy, cng. D. cng, brom ho. Cu 33: Tnh cht no khng phi ca benzen A. Tc dng vi Br2 (to, Fe). B. Tc dng vi HNO3 () /H2SO4(). C. Tc dng vi dung dch KMnO4. D. Tc dng vi Cl2 (as). etyl benzen. Vy X l Cu 34: Benzen + X A. axetilen. B. etilen. C. etyl clorua. D. etan.
Cl

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Hu c 11
Cu 35: Tnh cht no khng phi ca toluen ? A. Tc dng vi Br2 (to, Fe). B. Tc dng vi Cl2 (as). C. Tc dng vi dung dch KMnO4, to. D. Tc dng vi dung dch Br2. Cu 36: So vi benzen, toluen + dung dch HNO3()/H2SO4 (): A. D hn, to ra o nitro toluen v p nitro toluen. B. Kh hn, to ra o nitro toluen v p nitro toluen. C. D hn, to ra o nitro toluen v m nitro toluen. D. D hn, to ra m nitro toluen v p nitro toluen. Cu 37: Toluen + Cl2 (as) xy ra phn ng: A. Cng vo vng benzen. B. Th vo vng benzen, d dng hn. C. Th nhnh, kh khn hn CH4. D. Th nhnh, d dng hn CH4. as Cu 38: 1 mol Toluen + 1 mol Cl2 A . A l: A. C6H5CH2Cl. B. p-ClC6H4CH3. C. o-ClC6H4CH3. D. B v C u ng. Cu 39: Tin hnh th nghim cho nitro benzen tc dng vi HNO3 ()/H2SO4 (), nng ta thy: A. Khng c phn ng xy ra. B. Phn ng d hn benzen, u tin v tr meta. C. Phn ng kh hn benzen, u tin v tr meta. D. Phn ng kh hn benzen, u tin v tr ortho. Cu 40: Khi trn vng benzen c sn nhm th -X, th nhm th hai s u tin th vo v tr o- v p- . Vy -X l nhng nhm th no ? A. -CnH2n+1, -OH, -NH2. B. -OCH3, -NH2, -NO2. C. -CH3, -NH2, -COOH D. -NO2, -COOH, -SO3H. Cu 41: Khi trn vng benzen c sn nhm th -X, th nhm th hai s u tin th vo v tr m - . Vy -X l nhng nhm th no ? A. -CnH2n+1, -OH, -NH2. B. -OCH3, -NH2, -NO2.C. -CH3, -NH2, -COOH.D. -NO2, -COOH, -SO3H. H 2 SO4 d Cu 42: 1 mol nitrobenzen + 1 mol HNO3 B + H2O. B l: to A. m-initrobenzen. B. o-initrobenzen. C. p-initrobenzen. D. B v C u ng. Cu 43: C2H2 A B m-brombenzen. A v B ln lt l: A. benzen ; nitrobenzen. B. benzen,brombenzenC.nitrobenzen;benzen. D.nitrobenzen; brombenzen. Cu 44: Benzen A o-brom-nitrobenzen. Cng thc ca A l: A. nitrobenzen. B. brombenzen. C. aminobenzen. D. o-ibrombenzen. Cu 45: 1 ankylbenzen A(C9H12),tc dng vi HNO3 c (H2SO4 ) theo t l mol 1:1 to ra 1 dn xut mononitro duy nht . Vy A l: A. n-propylbenzen. B. p-etyl,metylbenzen. D. iso-propylbenzen D.1,3,5-trimetylbenzen. trung / hop Cu 46: Cho phn ng A 1,3,5-trimetylbenzen . A l: A. axetilen. B. metyl axetilen. C. etyl axetilen. D. imetyl axetilen. Cu 47: Stiren khng phn ng c vi nhng cht no sau y ? A. dd Br2. B. khng kh H2 ,Ni,to. C. dd KMnO4. D. dd NaOH. Ni , p ,t o Cu 48: A + 4H2 etyl xiclohexan. Cu to ca A l: A. C6H5CH2CH3. B. C6H5CH3. C. C6H5CH2CH=CH2. D. C6H5CH=CH2. Cu 49: Phn ng no sau y khng dng iu ch benzen ? A. tam hp axetilen. B. kh H2 ca xiclohexan. C. kh H2, ng vng n-hexanD. tam hp etilen. Cu 50: Phn ng no khng iu ch c toluen ? AlCl3 ;t o A. C6H6 + CH3Cl B. kh H2, ng vng benzen C. kh H2 metylxiclohexan D. tam hp propin xt ,t o Cu 51: A toluen + 4H2. Vy A l: A. metyl xiclo hexan. B. metyl xiclo hexen. C. n-hexan. D. n-heptan. Cu 52: ng dng no benzen khng c: A. Lm dung mi. B. Tng hp monome. C. Lm thuc n. D. Dng trc tip lm dc phm. Cu 53: Thuc n TNT c iu ch trc tip t A. benzen. B. metyl benzen. C. vinyl benzen. D. p-xilen. Cu 54: phn bit benzen, toluen, stiren ta ch dng 1 thuc th duy nht l:

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Hu c 11
A. Brom (dd). B. Br2 (Fe). C. KMnO4 (dd). D. Br2 (dd) hoc KMnO4(dd). Cu 55: phn bit c cc cht Hex-1-in, Toluen, Benzen ta dng 1 thuc th duy nht l: A. dd AgNO3/NH3. B. dd Brom. C. dd KMnO4. D. dd HCl. Cu 56: A l dn xut benzen c cng thc nguyn (CH) n. 1 mol A cng ti a 4 mol H 2 hoc 1 mol Br2 (dd). Vy A l: A. etyl benzen. B. metyl benzen. C. vinyl benzen. D. ankyl benzen. Cu 57: a. Mt hn hp X gm 2 aren A, R u c M < 120, t khi ca X i vi C2H6 l 3,067. CTPT v s ng phn ca A v R l A. C6H6 (1 ng phn) ; C7H8 (1 ng phn). B. C7H8 (1 ng phn) ; C8H10 (4 ng phn). C. C6H6 (1 ng phn) ; C8H10 (2 ng phn). D. C6H6 (1 ng phn) ; C8H10 (4 ng phn). b. Mt hp cht hu c c vng benzen c CTGN l C3H2Br v M = 236. Gi tn hp cht ny bit rng hp cht ny l sn phm chnh trong phn ng gia C6H6 v Br2 (xc tc Fe) A. o-hoc p-ibrombenzen. B. o-hoc p-ibromuabenzen. C. m-ibromuabenzen. D. m-ibrombenzen. Cu 58: Hn hp C6H6 v Cl2 c t l mol 1 : 1,5. Trong iu kin c xc tc bt Fe, to, hiu sut 100%. Sau phn ng thu c cht g ? bao nhiu mol ? A.1 mol C6H5Cl ; 1 mol HCl ; 1 mol C6H4Cl2. B. 1,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5mol C6H4Cl2. C. 1 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2. D. 0,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2. Cu 59: Cho 100 ml bezen (d = 0,879 g/ml) tac dung vi mt lng va u brom long (xuc tac bt st, un nong) thu c 80 ml brombenzen (d = 1,495 g/ml). Hiu sut brom hoa at la A. 67,6%. B. 73,49%. C. 85,3%. D. 65,35% Cu 60: Cho benzen vo 1 l ng Cl2 d ri a ra nh sng. Sau khi phn ng xy ra hon ton thu c 5,82 kg cht sn phm. Tn ca sn phm v khi lng benzen tham gia phn ng l: A. clobenzen; 1,56 kg. B. hexacloxiclohexan; 1,65 kg. C. hexacloran; 1,56 kg. D. hexaclobenzen; 6,15 kg. Cu 61: A c cng thc phn t l C8H8, tc dng vi dung dich KMnO4 nhit thng to ra ancol 2 chc. 1 mol A tc dng ti a vi: A. 4 mol H2; 1 mol brom. B. 3 mol H2; 1 mol brom. C. 3 mol H2; 3 mol brom. D. 4 mol H2; 4 mol brom. Cu 62: A la hirocacbon co %C (theo khi lng) la 92,3%. A tac dung vi dung dich brom d cho san phm co %C (theo khi lng) la 36,36%. Bit MA < 120. Vy A co cng thc phn t la A. C2H2. B. C4H4. C. C6H6. D. C8H8. Cu 63: Tin hanh trung hp 10,4 gam stiren c hn hp X gm polistiren va stiren (d). Cho X tac dung vi 200 ml dung dich Br2 0,15M, sau o cho dung KI d vao thy xut hin 1,27 gam iot. Hiu sut trung hp stiren l A. 60%. B. 75%. C. 80%. D. 83,33%. Cu 64: hiro ho etylbenzen ta c stiren; trng hp stiren ta c polistiren vi hiu sut chung 80%. Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l: A.13,52 tn. B. 10,6 tn. C. 13,25 tn. D. 8,48 tn. Cu 65: a. t chy hon ton m gam A (CxHy), thu c m gam H2O. Cng thc nguyn ca A l: A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n. b. t chy hon ton 1,3 gam A (CxHy) to ra 0,9 gam H2O. Cng thc nguyn ca A l: A. (CH)n. B. (C2H3)n. C. (C3H4)n. D. (C4H7)n. Cu 66: t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon ton 5,06 gam X thu c mt th tch hi ng bng th tch ca 1,76 gam oxi trong cng iu kin. Nhn xt no sau y l ng i vi X ? A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng. B. X tc dng vi dung dch Br2 to kt ta trng. C. X c th trng hp thnh PS. D. X tan tt trong nc. Cu 67: t chy hon ton m gam hirocacbon A, thu c m gam H2O. Cng thc phn t ca A (150 < MA < 170) l:

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Hu c 11
A. C4H6. B. C8H12. C. C16H24. D. C12H18. Cu 68: t chy hon ton 6 gam cht hu c A, ng ng ca benzen thu c 10,08 lt CO 2 (ktc). Cng thc phn t ca A l: A. C9H12. B. C8H10. C. C7H8. D. C10H14. Cu 69: t chy hon ton 0,1 mol CxHy thu c 20,16 lt CO2 (ktc) v 10,8 gam H2O (lng). Cng thc ca CxHy l: A. C7H8. B. C8H10. C. C10H14. D. C9H12. Cu 70: A (CxHy) l cht lng iu kin thng. t chy A to ra CO2 v H2O v mCO2 : mH2O = 4,9 : 1. Cng thc phn t ca A l: A. C7H8. B. C6H6. C. C10H14. D. C9H12. Cu 71: t chy hon ton hi A (CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi. Cng thc phn t ca A l: A. C7H8. B. C8H10. C. C10H14. D. C9H12. Cu 72: Cho a gam cht A (CxHy) chy thu c 13,2 gam CO2 v 3,6 gam H2O. Tam hp A thu c B, mt ng ng ca ankylbenzen. Cng thc phn t ca A v B ln lt l: A. C3H6 v C9H8. B. C2H2 v C6H6. C. C3H4 v C9H12. D. C9H12 v C3H4. Cu 73: 1,3 gam cht hu c A chy hon ton thu c 4,4 gam CO2 v 0,9 gam H2O. T khi hi ca A i vi oxi l d tha mn iu kin 3<d<3,5. Cng thc phn t ca A l: A. C2H2. B. C8H8. C. C4H4. D. C6H6. Cu 74: t chay hoan toan mt th tich hi hp cht hu c A cn 10 th tich oxi (o cung iu kin nhit v p sut), san phm thu c chi gm CO2 va H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A co cng thc phn t la A. C4H6O. B. C8H8O. C. C8H8. D. C2H2. Cu 75: t chy ht m gam 2 ng ng ca benzen A, B thu c 4,05 gam H2O v 7,728 lt CO2 (ktc). Gi tr ca m v s tng s mol ca A, B l: A. 4,59 v 0,04. B. 9,18 v 0,08. C. 4,59 v 0,08. D. 9,14 v 0,04. Cu 76: t chy ht 9,18 gam 2 ng ng ca benzen A, B thu c 8,1 gam H 2O v V lt CO2 (ktc). Gi tr ca V l: A. 15,654. B. 15,465. C. 15,546. D. 15,456. Cu 77: t chy ht 2,295 gam 2 ng ng ca benzen A, B thu c 2,025 gam H 2O v CO2. Dn ton b lng CO2 vo 250 ml dung dch NaOH 1M thu c m gam mui. Gi tr ca m v thnh phn ca mui A. 16,195 (2 mui). B. 16,195 (Na2CO3). C. 7,98 (NaHCO3) D. 10,6 (Na2CO3). Cu 78: t chy ht 9,18 gam 2 ng ng k tip thuc dy ca benzen A, B thu c H 2O v 30,36 gam CO2. Cng thc phn t ca A v B ln lt l: A. C6H6 ; C7H8. B. C8H10 ; C9H12. C. C7H8 ; C9H12. D. C9H12 ; C10H14. Cu 79: t 0,13 gam mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 gam H2O. T khi hi ca A so vi B l 3; t khi hi ca B so vi H2 l 13. Cng thc ca A v B ln lt l: A. C2H2 v C6H6. B. C6H6 v C2H2. C. C2H2 v C4H4. D. C6H6 v C8H8. Cu 80: A, B, C la ba cht hu c co %C, %H (theo khi lng) ln lt la 92,3% va 7,7%, ti l khi lng mol tng ng la 1: 2 : 3. T A co th iu ch B hoc C bng mt phan ng. C khng lam mt mau nc brom. t 0,1 mol B ri dn toan b san phm chay qua binh ng dung dich nc vi trong d. a. Khi lng binh tng hoc giam bao nhiu gam ? A. Tng 21,2 gam. B. Tng 40 gam. C. Giam 18,8 gam. D. Giam 21,2 gam. b. Khi lng dung dch tng hoc giam bao nhiu gam ? A. Tng 21,2 gam. B. tng 40 gam. C. giam 18,8 gam. D. giam 21,2 gam.

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CHUYN 5 : DN XUT HALOGEN - PHENOL - ANCOL

Cu 1 : S ng phn ca C4H9Br l A. 4. B. 2. C. 3. D. 5. Cu 2: S ng phn dn xut halogen bc I c CTPT C4H9Cl l A. 2. B. 3. C. 4. D. 5. Cu 3: S ng phn mch h (k c ng phn hnh hc) ca cht c CTPT l C3H5Br l A. 2. B. 3. C. 4. D. 5. Cu 4: Mt hp cht hu c Z c % khi lng ca C, H, Cl ln lt l : 14,28% ; 1,19% ; 84,53%. CTPT ca Z l A. CHCl2. B. C2H2Cl4. C. C2H4Cl2. D. mt kt qu khc. Cu 5: Dn xut halogen khng c ng phn cis-trans l A. CHCl=CHCl. B. CH2=CH-CH2F. C. CH3CH=CBrCH3.D. CH3CH2CH=CHCHClCH3. Cu 6: Danh php IUPAC ca dn xut halogen c cng thc cu to : ClCH2CH(CH3)CHClCH3 l A. 1,3-iclo-2-metylbutan. B. 2,4-iclo-3-metylbutan. C. 1,3-iclopentan. D. 2,4-iclo-2-metylbutan. Cu 7: Cho cc cht sau: C6H5CH2Cl ; CH3CHClCH3 ; Br2CHCH3 ; CH2=CHCH2Cl. Tn gi ca cc cht trn ln lt l A. benzyl clorua ; isopropyl clorua ; 1,1-ibrometan ; anlyl clorua. B. benzyl clorua ; 2-clopropan ; 1,2-ibrometan ;1-cloprop-2-en. C. phenyl clorua ; isopropylclorua ; 1,1-ibrometan ; 1-cloprop-2-en. D. benzyl clorua ; n-propyl clorua ; 1,1-ibrometan ; 1-cloprop-2-en. Cu 8: Cho cc dn xut halogen sau : C2H5F (1) ; C2H5Br (2) ; C2H5I (3) ; C2H5Cl (4) th t gim dn nhit si l A. (3)>(2)>(4)>(1). B. (1)>(4)>(2)>(3). C. (1)>(2)>(3)>(4). D. (3)>(2)>(1)>(4). Cu 9: Nh dung dch AgNO3 vo ng nghim cha mt t dn xut halogen CH2=CHCH2Cl, lc nh. Hin tng xy ra l A. Thot ra kh mu vng lc. B. xut hin kt ta trng. C. khng c hin tng. D. xut hin kt ta vng. Cu 10: a. Sn phm chnh ca phn ng tch HBr ca CH3CH(CH3)CHBrCH3 l A. 2-metylbut-2-en. B. 3-metylbut-2-en. C. 3-metyl-but-1-en. D. 2-metylbut-1-en. b. San phm chinh tao thanh khi cho 2-brombutan tc dng vi dung dich KOH/ancol, un nong A. metylxiclopropan. B. but-2-ol. C. but-1-en. D. but-2-en. Cu 11: un nng 13,875 gam mt ankyl clorua Y vi dung dich NaOH, tch b lp hu c, axit ha phn cn li bng dung dich HNO3, nh tip vo dd AgNO3 thy to thnh 21,525 gam kt ta. CTPT ca Y l A. C2H5Cl. B. C3H7Cl. C. C4H9Cl. D. C5H11Cl. Cu 12: S tch hiro halogenua ca dn xut halogen X c CTPT C4H9Cl cho 3 olefin ng phn, X l cht no trong nhng cht sau y ? A. n- butyl clorua. B. sec-butyl clorua. C. iso-butyl clorua. D. tert-butyl clorua. Cu 13: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (long, d, to) ta thu c cht no ? A. HOC6H4CH2OH. B. ClC6H4CH2OH. C. HOC6H4CH2Cl. D. KOC6H4CH2OH. Cu 14: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (c, d, to, p) ta thu c cht no? A. KOC6H4CH2OK. B. HOC6H4CH2OH. C. ClC6H4CH2OH. D. KOC6H4CH2OH. Cu 15: Thy phn dn xut halogen no sau y s thu c ancol ? (1) CH3CH2Cl. (2) CH3CH=CHCl. (3) C6H5CH2Cl. (4) C6H5Cl. A. (1), (3). B. (1), (2), (3). C. (1), (2), (4). D.(1), (2), (3), (4). Cu 16: a. un si dn xut halogen X vi nc mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X l A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Br. D. A hoc C. b. un si dn xut halogen X vi dung dch NaOH long mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X khng th l

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A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Cl. D. C6H5Cl. Cu 17: Khi un nng dn xut halogen X vi dung dch NaOH to thnh hp cht anehit axetic. Tn ca hp cht X l A. 1,2- ibrometan. B. 1,1- ibrometan. C. etyl clorua. D. A v B ng. Cu 18: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c (to cao, p cao) thu c cht Y c CTPT l C7H7O2Na. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 5. C. 4. D. 2. Cu 19: Cho s phn ng sau:

CH3

Br2/as

o Br2/Fe, t

dd NaOH

NaOH n/c,o,t p

X, Y, Z, T c cng thc ln lt l A. p-CH3C6H4Br, p-CH2BrC6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH. B. CH2BrC6H5, p-CH2Br-C6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH. C. CH2Br-C6H5, p-CH2Br-C6H4Br, p-CH3C6H4OH, p-CH2OHC6H4OH. D. p-CH3C6H4Br, p-CH2BrC6H4Br, p-CH2BrC6H4OH, p-CH2OHC6H4OH. Cu 20: Cho s phan ng sau : CH4 X Y Z T C6H5OH. (X, Y, Z la cac cht hu c khac nhau). Z l A. C6H5Cl. B. C6H5NH2. C. C6H5NO2. D. C6H5ONa. Cu 21: X l dn xut clo ca etan. un nng X trong NaOH d thu c cht hu c Y va tc dng vi Na va tc dng vi Cu(OH)2 nhit thng. Vy X l A. 1,1,2,2-tetracloetan. B. 1,2-icloetan. C. 1,1-icloetan. D. 1,1,1-tricloetan. Cu 22: Cho 5 cht: CH3CH2CH2Cl (1); CH2=CHCH2Cl (2); C6H5Cl (3); CH2=CHCl (4); C6H5CH2Cl (5). un tng cht vi dung dch NaOH long, d, sau gn ly lp nc v axit ho bng dung dch HNO3, sau nh vo dung dch AgNO3 th cc cht c xut hin kt ta trng l A. (1), (3), (5). B. (2), (3), (5). C. (1), (2), (3), (5). D. (1), (2), (5). Cu 23: Cho s chuyn ho : Benzen A B C A axit picric. B l A. phenylclorua. B. o Crezol. C. Natri phenolat. D. Phenol. + Cl , 500 C + NaOH Cu 24: Cho s phn ng : X Y ancol anlylic. X l cht no sau y ? A. Propan. B. Xiclopropan. C. Propen. D. Propin. ,e Cl Cu 25: Cho s sau : C2H5Br M gte A C O2 B +H C. C c cng thc l A. CH3COOH. B. CH3CH2COOH. C. CH3CH2OH. D. CH3CH2CH2COOH. Cu 26: Cho bt Mg vo ietyl ete khan, khuy mnh, khng thy hin tng g. Nh t t vo etyl bromua, khuy u th Mg tan dn thu c dung dch ng nht. Cc hin tng trn c gii thch nh sau: A. Mg khng tan trong ietyl ete m tan trong etyl bromua. B. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh etyl magiebromua tan trong ete. C. Mg khng tan trong ietyl ete nhng tan trong hn hp ietyl ete v etyl bromua. D. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh C2H5Mg tan trong ete. Cu 27: Cho s : C6H6 X Y Z m-HOC6H4NH2. X, Y, Z tng ng l A. C6H5NO2, m-ClC6H4NO2, m-HOC6H4NO2. B. C6H5NO2, C6H5NH2, m-HOC6H4NO2. C. C6H5Cl, m-ClC6H4NO2, m-HOC6H4NO2. D. C6H5Cl, C6H5OH, m-HOC6H4NO2. Cu 28: Cng thc dy ng ng ca ancol etylic l A. CnH2n + 2O. B. ROH. C. CnH2n + 1OH. D. Tt c u ng. Cu 29: Cng thc no di y l cng thc ca ancol no, mch h chnh xc nht ? A. R(OH)n. B. CnH2n + 2O. C. CnH2n + 2Ox. D. CnH2n + 2 x (OH)x. Cu 30: un nng mt ancol X vi H2SO4 c nhit thch hp thu c mt olefin duy nht. Cng thc tng qut ca X l (vi n > 0, n nguyn) A. CnH2n + 1OH. B. ROH. C. CnH2n + 2O. D. CnH2n + 1CH2OH. Cu 31: Tn quc t ca hp cht c cng thc CH3CH(C2H5)CH(OH)CH3 l A. 4-etyl pentan-2-ol. B. 2-etyl butan-3-ol. C. 3-etyl hexan-5-ol. D. 3-metyl pentan-2-ol.
2 0

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Cu 32: Mt ancol no c cng thc thc nghim l (C2H5O)n. CTPT ca ancol c th l A. C2H5O. B. C4H10O2. C. C4H10O. D. C6H15O3. Cu 33: Ancol no, n chc c 10 nguyn t H trong phn t c s ng phn l A. 5. B. 3. C. 4. D. 2. Cu 34: Mt ancol no n chc c %H = 13,04% v khi lng. CTPT ca ancol l A. C6H5CH2OH.B. CH3OH. C. C2H5OH. D. CH2=CHCH2OH. Cu 35: Mt ancol no n chc c %O = 50% v khi lng. CTPT ca ancol l A. C3H7OH. B. CH3OH. C. C6H5CH2OH. D. CH2=CHCH2OH. Cu 36: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18% ? A. 2. B. 3. C. 4. D. 5. Cu 37: Co bao nhiu ng phn c cng thc phn t l C4H10O ? A. 6. B. 7. C. 4. D. 5. Cu 38: Co bao nhiu ancol bc III, co cng thc phn t C6H14O ? A. 1. B. 2. C. 3. D. 4. Cu 39: Co bao nhiu ancol thm, cng thc C8H10O ? A. 5. B. 6. C. 7. D. 8. Cu 40: Co bao nhiu ancol thm, cng thc C8H10O khi tac dung vi CuO un nong cho ra anehit? A. 2. B. 3. C. 4. D. 5. Cu 41: Co bao nhiu ancol C5H12O khi tach nc chi tao mt anken duy nht? A. 1. B. 2. C. 3. D. 4. Cu 42: S ng phn ancol ng vi CTPT C5H12O l A. 8. B. 7. C. 5. D. 6. Cu 43: S ng phn ancol ti a ng vi CTPT C3H8Ox l A. 4. B. 5. C. 6. D. khng xc nh c. Cu 44: X l ancol mch h c cha 1 lin kt i trong phn t. khi lng phn t ca X nh hn 60. CTPT ca X l A. C3H6O. B. C2H4O. C. C2H4(OH)2. D. C3H6(OH)2. Cu 45: A, B, D la 3 ng phn co cung cng thc phn t C3H8O. Bit A tac dung vi CuO un nong cho ra andehit, con B cho ra xeton. Vy D la A. Ancol bc III. B. Cht co nhit si cao nht. C. Cht co nhit si thp nht. D. Cht co kha nng tach nc tao anken duy nht. Cu 46: X, Y, Z la 3 ancol lin tip trong day ng ng, trong o MZ = 1,875MX. X co c im l A. Tach nc tao 1 anken duy nht. B. Hoa tan c Cu(OH)2. trong phn t. C. Cha 1 lin kt D. Khng co ng phn cung chc hoc khac chc. Cu 47: Ancol X n chc, no, mch h c t khi hi so vi hiro bng 37. Cho X tc dng vi H2SO4 c un nng n 180oC thy to thnh mt anken c nhnh duy nht. X l A. propan-2-ol. B. butan-2-ol. C. butan-1-ol. D. 2-metylpropan-2-ol. Cu 48: Mt ancol n chc X mch h tc dng vi HBr c dn xut Y cha 58,4% brom v khi lng. un X vi H2SO4 c 170oC c 3 anken. Tn X l A. pentan-2-ol. B. butan-1-ol. C. butan-2-ol. D. 2-metylpropan-2-ol. Cu 49: Mt cht X c CTPT l C4H8O. X lm mt mu nc brom, tc dng vi Na. Sn phm oxi ha X bi CuO khng phi l anehit. Vy X l A. but-3-en-1-ol. B. but-3-en-2-ol. C. 2-metylpropenol. D. tt c u sai. Cu 50: Bc ca ancol l A. bc cacbon ln nht trong phn t. B. bc ca cacbon lin kt vi nhm -OH. C. s nhm chc c trong phn t. D. s cacbon c trong phn t ancol. Cu 51: Bc ancol ca 2-metylbutan-2-ol l A. bc 4. B. bc 1. C. bc 2. D. bc 3. Cu 52: Cc ancol c phn loi trn c s A. s lng nhm OH. B. c im cu to ca gc hirocacbon. C. bc ca ancol. D. Tt c cc c s trn. Cu 53: Cc ancol (CH3)2CHOH ; CH3CH2OH ; (CH3)3COH c bc ancol ln lt l

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A. 1, 2, 3. B. 1, 3, 2. C. 2, 1, 3. D. 2, 3, 1. Cu 54: Cu no sau y l ng ? A. Hp cht CH3CH2OH l ancol etylic. B. Ancol l hp cht hu c trong phn t nhm -OH. C. Hp cht C6H5CH2OH l phenol. D. Tt c u ng. Cu 55: Ancol etylic tan tt trong nc v c nhit si cao hn hn so vi ankan v cc dn xut halogen c khi lng phn t xp x vi n v A. Trong cc hp cht trn ch c ancol etylic tc dng vi Na. B. Trong cc hp cht trn ch c ancol etylic c lin kt hiro vi nc. C. Trong cc hp cht trn ch c ancol etylic c lin kt hiro lin phn t. D. B v C u ng. Cu 56: A, B, C la 3 cht hu c co cung cng thc CxHyO. Bit % O (theo khi lng) trong A la 26,66%. Cht co nhit si thp nht trong s A, B, C la A. propan-2-ol. B. propan-1-ol. C. etylmetyl ete. D. propanal. Cu 57: Ancol etylic c ln mt t nc, c th dng cht no sau y lm khan ancol ? A. CaO. B. CuSO4 khan. C. P2O5. D. tt c u c. Cu 58: Phng php iu ch ancol etylic t cht no sau y l phng php sinh ha ? A. Anehit axetic. B. Etylclorua. C. Tinh bt. D. Etilen. Cu 59: Anken thch hp iu ch 3-etylpentan-3-ol bng phn ng hirat ha l A. 3,3-imetyl pent-2-en. B. 3-etyl pent-2-en. C. 3-etyl pent-1-en. D. 3-etyl pent-3-en. Cu 60: Hirat ha 2-metyl but-2-en thu c sn phm chnh l A. 2-metyl butan-2-ol. B. 3-metyl butan-1-ol.C. 3-metyl butan-2-ol.D. 2-metyl butan-1-ol. Cu 61: Hirat ha propen v mt olefin A thu c 3 ancol c s C trong phn t khng qu 4. Tn ca A l A. etilen. B. but-2-en. C. isobutilen. D. A, B u ng. Cu 62: X la hn hp gm hai anken ( th khi trong k thng). Hirat hoa X c hn hp Y gm 4 ancol (khng co ancol bc III). X gm A. propen va but-1-en. B. etilen va propen. C. propen va but-2-en. D. propen v 2-metylpropen. Cu 63: Hirat hoa 2 anken c hn hp Z gm 2 ancol lin tip trong day ng ng. t chay hoan toan 0,53 gam Z ri hp thu toan b san phm chay vao 2 lit dung dich NaOH 0,05M c dung dich T trong o nng cua NaOH la 0,025M (Gi s th tch dung dch thay i khng ng k). Cng thc cu tao cua2 anken la A. CH2=CH2 va CH2=CHCH3. B. CH2=CHCH3 va CH2=CHCH2CH3. C. CH2=CHCH3 va CH3CH=CHCH3. D. CH2=CHCH3 va CH2=C(CH3)2. Cu 64: Mt chai ng ancol etylic c nhn ghi 25o c ngha l A. c 100 ml nc th c 25 ml ancol nguyn cht. B. c 100 gam dung dch th c 25 ml ancol nguyn cht. C. c 100 gam dung dch th c 25 gam ancol nguyn cht. D. c 75 ml nc th c 25 ml ancol nguyn cht. Cu 65: Pha a gam ancol etylic (d = 0,8 g/ml) vao nc c 80 ml ancol 25o. Gia tri a la A. 16. B. 25,6. C. 32. D. 40. Cu 66: Dy gm cc cht u tc dng vi ancol etylic l A. HBr (to), Na, CuO (to), CH3COOH (xc tc). B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). D. Na2CO3, CuO (to), CH3COOH (xc tc), (CHCO)2O. Cu 67: Cho cc hp cht sau : (a) HOCH2CH2OH. (b) HOCH2CH2CH2OH. (c) HOCH2CH(OH)CH2OH. (d) CH3CH(OH)CH2OH. (e) CH3CH2OH. (f) CH3OCH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l A. (a), (b), (c). B. (c), (d), (f). C. (a), (c), (d). D. (c), (d), (e). Cu 68: a. Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng) : Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l A. CH3COOH, CH3OH. B. C2H4, CH3COOH. C. C2H5OH, CH3COOH. D. CH3COOH, C2H5OH.

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b. Cho s chuyn ho : Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH=CH. B. CH3CH2OH v CH3CHO. C. CH3CHO v CH3CH2OH. D. CH3CH(OH)COOH v CH3CHO. Cu 69: Cho Na tc dng va vi 1,24 gam hn hp 3 ancol n chc X, Y, Z thy thot ra 0,336 lt kh H2 (kc). Khi lng mui natri ancolat thu c l A. 2,4 gam. B. 1,9 gam. C. 2,85 gam. D. 3,8 gam. Cu 70: Cho 7,8 gam hn hp 2 ancol n chc k tip nhau trong day ng ng tac dung ht vi 4,6 gam Na c 12,25 gam cht rn. o la 2 ancol A. CH3OH va C2H5OH. B. C2H5OH va C3H7OH. C. C3H5OH va C4H7OH. D. C3H7OH va C4H9OH. Cu 71: 13,8 gam ancol A tac dung vi Na d giai phong 5,04 lit H2 ktc, bit MA < 100. Vy A co cng thc cu tao thu gon la A. CH3OH. B. C2H5OH. C. C3H6(OH)2. D. C3H5(OH)3. Cu 72: Co hai thi nghim sau : TN 1: Cho 6 gam ancol no, mch h, n chc A tac dung vi m gam Na, thu c 0,075 gam H2. TN 2: Cho 6 gam ancol no, mch h, n chc A tac dung vi 2m gam Na, thu c khng ti 0,1 gam H2. A co cng thc la A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H7OH. Cu 73: Cho 12,8 gam dung dch ancol A (trong nc) c nng 71,875% tc dng vi lng Na d thu c 5,6 lt kh (ktc). Cng thc ca ancol A l A. CH3OH. B. C2H4 (OH)2. C. C3H5(OH)3. D. C4H7OH. Cu 74: Ancol A tac dung vi Na d cho s mol H2 bng s mol A a dung. t chay hoan toan A c mCO2 = 1,833mH2O. A co cu tao thu gon la A. C2H4(OH)2. B. C3H6(OH)2. C. C3H5(OH)3. D. C4H8(OH)2. Cu 75: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng thu c 11 gam este. Hiu sut ca phn ng este ho l A. 55%. B. 50%. C. 62,5%. D. 75%. Cu 76: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. o Cu 77: Khi un nng butan-2-ol vi H2SO4 c 170 C th nhn c sn phm chnh l A. but-2-en. B. ibutyl ete. C. ietyl ete. D. but-1-en. Cu 78: Khi un nng 2 trong s 4 ancol CH4O, C2H6O, C3H8O vi xc tc, nhit thch hp ch thu c 1 olefin duy nht th 2 ancol l A. CH4O v C2H6O. B. CH4O v C3H8O. C. A, B ng. D. C3H8O v C2H6O. Cu 79: Khi tach nc cua ancol C4H10O c hn hp 3 anken ng phn cua nhau (tinh ca ng phn hinh hoc). Cng thc cu tao thu gon cua ancol la A. CH3CHOHCH2CH3. B. (CH3)2CHCH2OH. C. (CH3)3COH. D. CH3CH2CH2CH2OH. Cu 80: Hp cht hu c X co cng thc phn t la C5H12O, khi tach nc tao hn hp 3 anken ng phn (k ca ng phn hinh hoc). X co cu tao thu gon la A. CH3CH2CHOHCH2CH3. B. (CH3)3CCH2OH. C. (CH3)2CHCH2CH2OH. D. CH3CH2CH2CHOHCH3. Cu 81: Khi un nng hn hp ancol etylic v ancol isopropylic vi H2SO4 c 140oC c th thu c s ete ti a l A. 2. B. 4. C. 5. D. 3. o Cu 82: Khi un nng hn hp gm C2H5OH v C3H7OH vi H2SO4 c 140 C c th thu c s ete ti a l A. 6. B. 4. C. 5. D. 3. Cu 83: un nong hn hp gm 3 ancol la AOH, BOH va ROH vi H2SO4 c 140oC thi thu c ti a bao nhiu ete ? A. 3. B. 4. C. 5. D. 6.

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Cu 84: un nong hn hp n ancol n chc khac nhau vi H2SO4 c 140oC thi s ete thu c ti a la A.
n(n +1) 2 2n(n +1) . 2
2 C. n .

B.

NaOH l Cu 85: Cho s chuyn ha : But-1-en +H C A + B E Tn ca E l A. propen. B. ibutyl ete. C. but-2-en. D. isobutilen. Cu 86: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 87: un nng t t hn hp etanol v propan-2-ol vi H2SO4 c c th thu c ti a s sn phm hu c l A. 3. B. 2. C. 5. D. 4. Cu 88: Co bao nhiu ng phn ng vi cng thc phn t C8H10O, u la dn xut cua benzen, khi tach nc cho san phm co th trung hp tao polime ? A. 1. B. 2. C. 3. D. 4. Cu 89: A la ancol n chc co % O (theo khi lng) la 18,18%. A cho phan ng tach nc tao 3 anken. A co tn la A. Pentan-1-ol. B. 2-metylbutan-2-ol. C. pentan-2-ol. D. 2,2-imetyl propan-1ol. Cu 90: hirat ha 14,8 gam ancol thu c 11,2 gam anken. CTPT ca ancol l A. C2H5OH. B. C3H7OH. C. C4H9OH. D. CnH2n + 1OH. Cu 91: un nong hn hp X gm 2 ancol n chc lin tip trong day ng ng vi H2SO4 c 140oC. Sau phan ng c hn hp Y gm 5,4 gam nc va 19,4 gam 3 ete. Hai ancol ban u la A. CH3OH va C2H5OH. B. C2H5OH va C3H7OH. C. C3H5OH va C4H7OH. D. C3H7OH va C4H9OH. Cu 92: un nong hn hp X gm 0,1 mol CH3OH va 0,2 mol C2H5OH vi H2SO4 c 140oC, khi lng ete thu c la A. 12,4 gam. B. 7 gam. C. 9,7 gam. D. 15,1 gam. o Cu 93: un nng ancol n chc X vi H2SO4 c 140 C thu c Y. T khi hi ca Y i vi X l 1,4375. X l A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 94: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH2=CHCH2OH. B. C2H5OH v CH3OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CHCH2OH. Cu 95: Khi un nng mt ancol n chc no A vi H2SO4 c iu kin nhit thch hp thu c sn phm B c t khi hi so vi A l 0,7. Vy cng thc ca A l A. C4H7OH. B. C3H7OH. C. C3H5OH. D. C2H5OH. Cu 96: un nng mt ru (ancol) n chc X vi dung dch HSO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. Cu 97: Chi ra dy cc cht khi tach nc tao 1 anken duy nht ? A. Metanol ; etanol ; butan -1-ol. B. Etanol; butan -1,2-iol ; 2-metylpropan-1-ol. C. Propanol-1; 2-metylpropan-1-ol; 2,2 imetylpropan-1-ol. D. Propan-2-ol ; butan -1-ol ; pentan -2-ol. Cu 98: Ancol X tach nc chi tao mt anken duy nht. t chay mt lng X c 11 gam CO2 va 5,4 gam H2O. X co th co bao nhiu cng thc cu tao phu hp ? A. 2. B. 3. C. 4. D. 5.

2 o + H 2SO 4 C c , 170

D. n!

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Cu 99: un nong hn hp X gm 2 ancol n chc no (co H2SO4 c lam xuc tac) 140oC. Sau khi phan ng c hn hp Y gm 21,6 gam nc va 72 gam ba ete co s mol bng nhau. Cng thc 2 ancol noi trn la A. CH3OH va C2H5OH. B. C2H5OH va C3H7OH. C. C2H5OH va C3H7OH. D. C3H7OH va C4H9OH. Cu 100: un nng V (ml) ancol etylic 95o vi H2SO4 c 170oC c 3,36 lt kh etilen (ktc). Bit hiu sut phn ng l 60% v ancol etylic nguyn cht c d = 0,8 g/ml. Gi tr ca V (ml) l A. 8,19. B. 10,18. C. 12. D. 15,13. Cu 101: Ancol no b oxi ha to xeton ? A. propan-2-ol. B. butan-1-ol. C. 2-metyl propan-1-ol.D. propan-1-ol. Cu 102: Ancol no n chc tc dng c vi CuO to anehit l A. ancol bc 2. B. ancol bc 3. C. ancol bc 1. D. ancol bc 1 v ancol bc 2. Cu 103: Oxi ha 6 gam ancol no X thu c 5,8 gam anehit. CTPT ca ancol l A. CH3CH2OH. B. CH3CH(OH)CH3. C. CH3CH2CH2OH. D. Kt qu khc. Cu 104: Cho m gam ancol n chc, no, mch h qua binh ng CuO (d) nung nong. Sau khi phan ng xay ra hoan toan, khi lng cht rn trong binh giam 0,32 gam. Hn hp thu c co ti khi hi i vi H2 la 19. Gia tri m la A. 1,48 gam. B. 1,2 gam. C. 0,92 gam. D. 0,64 gam. Cu 105*: Oxi hoa 4 gam ancol n chc A bng oxi khng khi (co xuc tac va un nong) thu c 5,6 gam hn hp anehit, ancol d va nc. A co cng thc la A. CH3OH. B. C2H5OH. C. C3H5OH. D. C3H7OH. Cu 106: Oxi hoa 6 gam ancol n chc A bng oxi khng khi (co xuc tac va un nong) thu c 8,4 gam hn hp anehit, ancol d va nc. Phn trm A bi oxi hoa la A. 60%. B. 75%. C. 80%. D. 53,33%. Cu 107: Dn m gam hi ancol n chc A qua ng ng CuO (d) nung nong. Sau khi phan ng hoan toan thy khi lng cht rn trong ng giam 0,5m gam. Ancol A co tn la A. metanol. B. etanol. C. propan-1-ol. D. propan-2-ol. Cu 108: Dn hi C2H5OH qua ng ng CuO nung nong c hn hp X gm anehit, ancol d va nc. Cho X tac dung vi Na d c 4,48 lit H2 ktc. Khi lng hn hp X l (bit chi co 80% ancol bi oxi hoa) A. 13,8 gam B. 27,6 gam. C. 18,4 gam. D. 23,52 gam. Cu 109: Dn hi C2H5OH qua ng ng CuO nung nong c 11,76 gam hn hp X gm anehit, ancol d va nc. Cho X tac dung vi Na d c 2,24 lit H2 ( ktc). % ancol bi oxi ho l A. 80%. B. 75%. C. 60%. D. 50%. n H 2 O > n CO 2 . Kt lun no sau y l ng nht? Cu 110: t chy mt ancol X c A. X l ancol no, mch h. B. X l ankaniol. C. X l ankanol n chc. D. X l ancol n chc mch h. Cu 111: Khi t chy ng ng ca ancol n chc thy t l s mol n CO : n H O tng dn. Ancol trn thuc dy ng ng ca A. ancol khng no. B. ancol no. C. ancol thm. D. khng xc nh c. Cu 112: t chay hoan toan m gam ancol n chc A c 6,6 gam CO2 va 3,6 gam H2O. Gia tri m la A. 10,2 gam. B. 2 gam. C. 2,8 gam. D. 3 gam. Cu 113: t chy mt ancol n chc, mch h X thu c CO2 v hi nc theo t l th tch VCO 2 : VH 2O = 4 : 5 . CTPT ca X l A. C4H10O. B. C3H6O. C. C5H12O. D. C2H6O. Cu 114: t chy mt ancol a chc thu c H2O v CO2 c t l mol n H O : n CO = 3 : 2 . Vy ancol l A. C3H8O2. B. C2H6O2. C. C4H10O2. D. tt c u sai. Cu 115: Khi t chy mt ancol a chc thu c nc v kh CO2 theo t l khi lng m H 2O : m CO 2 = 27 : 44 . CTPT ca ancol l A. C5H10O2. B. C2H6O2. C. C3H8O2. D. C4H8O2.
2 2 2 2

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Cu 116: t chy hon ton 5,8 gam ancol n chc X thu c 13,2 gam CO2 v 5,4 gam H2O. Xc nh X A. C4H7OH. B. C2H5OH. C. C3H5OH. D. tt c u sai. Cu 117: Ba ancol X, Y, Z u bn v c khi lng phn t khc nhau. t chy mi cht u sinh ra CO2 v H2O theo t l mol n CO 2 : n H 2O = 3 : 4. Vy CTPT ba ancol l A. C2H6O ; C3H8O ; C4H10O. B. C3H8O ; C3H8O2 ; C3H8O3. C. C3H8O ; C4H10O ; C5H10O. D. C3H6O ; C3H6O2 ; C3H6O3. Cu 118: t chay ru A bng O2 va u nhn thy: nCO2 : nO2 : nH2O = 4 : 5: 6. A co cng thc phn t la A. C2H6O. B. C2H6O2. C. C3H8O. D. C4H10O. Cu 119: t chay ancol ch cha mt loi nhm chc A bng O2 va u nhn thy : nCO2 : nO2 : nH2O = 6: 7: 8. A co c im l A. Tac dung vi Na d cho nH2 = 1,5nA. B. Tac dung vi CuO un nong cho ra hp cht a chc. C. Tach nc tao thanh mt anken duy nht. D. Khng co kha nng hoa tan Cu(OH)2. Cu 120: Ancol n chc A chay cho mCO2 : mH2O = 11: 9. t chay hoan toan 1 mol A ri hp thu toan b san phm chay vao 600 ml dung dich Ba(OH)2 1M thi lng kt tua la A. 11,48 gam. B. 59,1gam. C. 39,4gam. D. 19,7gam. Cu 121: X la mt ancol no, mach h. t chay 0,05 mol X cn 4 gam oxi. X co cng thc l A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C4H8(OH)2. Cu 122: t chay hoan toan ancol X c CO2 va H2O co ti l mol tng ng la 3: 4, th tich oxi cn dung t chay X bng 1,5 ln th tich CO2 thu c (o cung k). X la A. C3H8O. B. C3H8O2. C. C3H8O3. D. C3H4O. Cu 123: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C3H7OH. Cu 124*: X la hn hp 2 ancol n chc, cung day ng ng, co ty l khi lng 1:1. t chay ht X c 21,45 gam CO2 va 13,95 gam H2O. Vy X gm 2 ancol l A. CH3OH va C2H5OH. B. CH3OH va C4H9OH. C. CH3OH va C3H7OH. D. C2H5OH va C3H7OH. Cu 125: t chay hoan toan a gam ancol X ri hp thu toan b san phm chay vao binh nc vi trong d thy khi lng binh tng b gam va co c gam kt tua. Bit b = 0,71c va c = 1,02 . X co cu tao thu gon la A. C2H5OH. B. C2H4(OH)2. C. C3H5(OH)3. D. C3H6(OH)2. Cu 126: t chay hon toan a gam hn hp gm metanol va butan-2-ol c 30,8 gam CO2 va 18 gam H2O. Gia tri a la A. 30,4 gam. B. 16 gam. C. 15,2 gam. D. 7,6 gam. Cu 127: t chay hoan toan 0,4 mol hn hp X gm ancol metylic, ancol etylic va ancol isopropylic ri hp thu toan b san phm chay vao nc vi trong d c 80 gam kt tua. Th tich oxi (ktc) ti thiu cn dung la A. 26,88 lit. B. 23,52 lit. C. 21,28 lit. D. 16,8 lit. Cu 128: t chay hn hp X gm 2 ancol co s mol bng nhau thu c hn hp CO2 va H2O theo l mol tng ng 2 : 3. X gm A. CH3OH va C2H5OH. C. C2H5OH va C2H4(OH)2. B. C3H7OH va C3H6(OH)2. D. C2H5OH va C3H7OH. Cu 129: t chay hoan toan a mol ancol A c b mol CO2 va c mol H2O. Bit a = c - b. Kt lun nao sau y ung ? A. A la ancol no, mach vong. B. A la ancol no, mach h. C. A la 2ancol cha no. C. A la ancol thm. Cu 130: t chay mt lng ancol A cn va u 26,88 lit O2 ktc, thu c 39,6 gam CO2 va 21,6 gam H2O. A co cng thc phn t l A. C2H6O. B. C3H8O. C. C3H8O2. D. C4H10O.
a +b

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Cu 131: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. C. C2H4(OH)2 v C4H8(OH)2. D. C2H4(OH)2 v C3H6(OH)2. Cu 132: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2( ktc) v a gam H2O. Biu thc lin h gia m, a v V l A. m = 2a - V/22,4. B. m = 2a - V/11,2. C. m = a + V/5,6. D. m = a - V/5,6. Cu 133: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. Cu 134: a. Kh CO2 sinh ra khi ln men ru mt lng glucoz c dn vo dung dch Ca(OH)2 d to c 40g kt ta. Khi lng ancol etylic thu c l A. 18,4 gam. B. 16,8 gam. C. 16,4 gam. D. 17,4 gam. b. Nu hiu sut phn ng ln men l 80% th khi lng glucoz dng l bao nhiu gam ? A. 45 gam. B. 90 gam. C. 36 gam. D. 40 gam. Cu 135: Cho m gam tinh bt ln men thanh C2H5OH vi hiu sut 81%, hp thu ht lng CO2 sinh ra vao dung dich Ca(OH)2 c 55 gam kt tua va dung dich X. un nong dung dich X lai co 10 gam kt tua na. Gia tri m la A. 75 gam. B. 125 gam. C. 150 gam. D. 225 gam. o Cu 136: Th tich ancol etylic 92 cn dung la bao nhiu iu ch c 2,24 lit C2H4 (ktc). Cho bit hiu sut phan ng at 62,5% va d = 0,8 g/ml. A. 8 ml. B. 10 ml. C. 12,5ml. D. 3,9 ml. Cu 137: i t 150 gam tinh bt se iu ch c bao nhiu ml ancol etylic 46o bng phng phap ln men ancol? Cho bit hiu sut phan ng at 81% va d = 0,8 g/ml. A. 46,875 ml. B. 93,75 ml. C. 21,5625 ml. D. 187,5 ml. Cu 138: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 139: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 d to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l A. 60. B. 58. C. 30. D. 48. Cu 140: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 20,0. B. 30,0. C. 13,5. D. 15,0. Cu 141: X la hn hp gm phenol va ancol n chc A. Cho 25,4 gam X tac dung vi Na (d) c 6,72 lit H2 ( ktc). A la A. CH3OH. B. C2H5OH. C. C3H5OH. D. C4H9OH. Cu 142: Co bao nhiu hp cht hu c C7H8O va tac dung vi Na, va tac dung vi NaOH ? A. 1. B. 2. C. 3. D. 4. Cu 143: A la hp cht co cng thc phn t C7H8O2. A tac dung vi Na d cho s mol H2 bay ra bng s mol NaOH cn dung trung hoa cung lng A trn. Chi ra cng thc cu tao thu gon cua A. A. C6H7COOH. B. HOC6H4CH2OH. C. CH3OC6H4OH. D. CH3C6H3(OH)2. Cu 144: Khi t chay 0,05 mol X (dn xut benzen) thu c di 17,6 gam CO 2. Bit 1 mol X phan ng va u vi 1 mol NaOH hoc vi 2 mol Na. X co cng thc cu tao thu gon la A. CH3C6H4OH.B. CH3OC6H4OH. C. HOC6H4CH2OH. D.C6H4(OH)2. Cu 145: Hoa cht nao di y dung phn bit 2 lo mt nhan cha dung dich phenol va benzen. 1. Na. 2. dd NaOH. 3. nc brom. A. 1 va 2. B. 1 va 3. C. 2 va 3. D. 1, 2 va 3.

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Cu 146: A la hp cht hu c cng thc phn t la C7H8O2. A tac dung vi NaOH theo ti l 1 : 2. Vy A thuc loai hp cht nao di y ? A. i phenol. B. Axit cacboxylic C. Este cua phenol. D. Va ancol, va phenol. Cu 147: Co bao nhiu ng phn (cha vong bezen), cng thc phn t C8H10O, khng tac dung vi Na? A. 2. B. 3. C. 4. D. 5. Cu 148: A la cht hu c co cng thc phn t CxHyO. t chay hoan toan 0,1 mol A ri hp thu toan b san phm chay vao nc vi trong thy co 30 gam kt tua. Loc bo kt tua em un nong phn nc loc thy co 20 gam kt tua na. Bit A va tac dung Na, va tac dung NaOH. Chi ra cng thc phn t cua A. A. C6H6O. B. C7H8O. C. C7H8O2. D. C8H10O. Cu 149: Chi ra th t tng dn mc linh cua nguyn t H trong nhom -OH cua cac hp cht sau: phenol, etanol, nc. A. Etanol < nc < phenol. C. Nc < phenol < etanol. B. Etanol < phenol < nc. D. Phenol < nc < etanol. Cu 150: T 400 gam bezen co th iu ch c ti a bao nhiu gam phenol. Cho bit hiu sut toan b qua trinh at 78%. A. 376 gam. B. 312 gam. C. 618 gam. D. 320 gam. Cu 151: Hoa cht nao di y co th dung phn bit cac lo mt nhan cha cac dung dich : C6H5ONa, NaCl, BaCl2, Na2S, Na2CO3 l A. dd NaOH. B. dd HCl. C. Na. D dd KCl. Cu 152: So vi etanol, nguyn t H trong nhom -OH cua phenol linh ng hn vi : A. Mt electron vong benzen tng ln, nht la cac vi tri o va p. B. Lin kt C-O cua phenol bn vng. C. Trong phenol, cp electron cha tham gia lin kt cua nguyn t oxi a tham gia lin hp vao vong benzen lam lin kt -OH phn cc hn. D. Phenol tac dung d dang vi nc brom tao kt tua trng 2, 4, 6-tri brom phenol. Cu 153: Co bao nhiu phan ng xay ra khi cho cac cht C6H5OH ; NaHCO3 ; NaOH ; HCl tac dung vi nhau tng i mt ? A. 3. B. 4. C. 5. D. 6. Cu 154: Dy gm cc cht u phn ng vi phenol l A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, axit axetic, dung dch NaOH. C. nc brom, anhirit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH. Cu 155: Hin tng ln lt xay ra khi nho vai giot dung dich HCl c vao ng nghim cha mt it dung dich HCOONa va mt it dung dich C6H5ONa ri lc manh la A. Co s phn lp ; dung dich trong sut hoa uc. B. Dung dich trong sut hoa uc. C. Co phn lp ; dung dich trong sut. D. Xut hin s phn lp ca 2 ng nghim. Cu 156: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. C. nc Br2. D. H2 (Ni, nung nng). Cu 157: Cht co cng thc phn t nao di y co th tac dung c ca Na, ca NaOH ? A. C5H8O. B. C6H8O. C. C7H10O. D. C9H12O. Cu 158: Ba hp cht thm X, Y, Z u c cng thc phn t C7H8O. X tc dng vi Na v NaOH ; Y tc dng vi Na, khng tc dng NaOH ; Z khng tc dng vi Na v NaOH Cng thc cu to ca X, Y, Z ln lt l A. C6H4(CH3)OH ; C6H5OCH3 ; C6H5CH2OH.B. C6H5OCH3 ; C6H5CH2OH ; C6H4(CH3)OH. C. C6H5CH2OH ; C6H5OCH3 ; C6H4(CH3)OH. D. C6H4(CH3)OH ; C6H5CH2OH ; C6H5OCH3. Cu 159: Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH, C6H5Cl vo dung dch NaOH long un nng. Hi my cht c phn ng ? A. C bn cht. B. Mt cht. C. Hai cht. D. Ba cht. Cu 160: a. S ng phn ca C3H5Cl3 l

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A. 5. B. 6. C. 3. D. 4. b. Trong s cc ng phn ca C3H5Cl3 c th c bao nhiu ng phn khi thu phn trong mi trng kim cho sn phm phn ng c c vi Na v dung dch AgNO3/NH3 to ra Ag ? A. 1. B. 4. C. 3. D. 2. Cu 161: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c, to cao, p cao thu c cht Y c CTPT l C7H6O. Hy cho bit X c bao nhiu CTCT? A. 3. B. 1. C. 4. D. 2. Cu 162: Cho cc hp cht sau : (I) CH3CH2OH. (II) C6H5OH. (III) NO2C6H4OH. Chn pht biu sai A. C 3 cht u c nguyn t H linh ng. B. C 3 u phn ng c vi dung dch baz iu kin thng. C. Cht (III) c nguyn t H linh ng nht. D. Th t linh ng ca nguyn t H c sp xp theo chiu nh sau : III > II > I. Cu 163: Cho cc cht sau A : CH4O ; B: C2H6O2 ; C: C3H8O3. iu no sau y lun ng ? A. A, B, C l cc ancol no, mch h. B. A, B, C u lm mt mu dd thuc tm. C. A, B, C l cc hp cht hu c no. D. A, B, C u l este no, n chc. Cu 164: Cho 2 phn ng :(1) 2CH3COOH + Na2CO3 2CH3COONa + H2O + CO2 (2) C6H5ONa + CO2 + H2O C6H5OH + NaHCO3 Hai phn ng trn chng t lc axit theo th t CH3COOH, H2CO3, C6H5OH, HCO3- l A. Tng dn. B. Gim dn. C. Khng thay i. D. Va tng va gim. Cu 165: Cho dy cc cht : phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 4. B. 3. C. 1. D. 2. Cu 166: X la hn hp gm phenol va metanol. t chay hoan toan X c nCO2 = nH2O. Vy % khi lng metanol trong X la A. 25%. B. 59,5%. C. 50,5%. D. 20%. Cu 167: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. Cu 168: Cho X l hp cht thm ; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HOC6H4COOCH3. B. CH3C6H3(OH)2. C. HOC6H4COOH. D. HOCH2C6H4OH. Cu 169: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X tc dng c vi NaOH theo t l s mol 1 : 2. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. CH3C6H3(OH)2. C. CH3OC6H4OH. D. C. HOCH2C6H4OH. Cu 170: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Th tch dung dch thay i khng ng k) A. C4H9OH v C5H11OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C2H5OH v C4H9OH. Cu 171: t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l A. C3H6O, C4H8O. B. C2H6O, C3H8O. C. C2H6O2, C3H8O2. D. C2H6O, CH4O. Cu 172: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l

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A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. Cu 173: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu : Tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 3. B. 4. C. 2. D. 1. Cu 174: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l B. CH3COCH3. A. CH3CHOHCH3. C. CH3CH2CH2OH. D. CH3CH2CHOHCH3. Cu 175: Mt hp cht hu c A gm C, H, O c 50% oxi v khi lng. Ngi ta cho A qua ng ng 10,4 gam CuO nung nng thu c 2 cht hu c v 8,48 gam cht rn. Mt khc cho hn hp 2 cht hu c trn tc dng vi dung dch AgNO3(d) trong NH3 to ra hn hp 2 mui v 38,88 gam Ag. Khi lng ca A cn dng l A. 1,28 gam. B. 4,8 gam. C. 2,56 gam. D. 3,2 gam. Cu 176: un nng ancol A vi hn hp NaBr v H2SO4 c thu c cht hu c B, 12,3 gam hi cht B chim mt th tch bng th tch ca 2,8 gam N2 cng nhit 560oC ; p sut 1 atm. Oxi ho A bng CuO nung nng thu c hp cht hu c c kh nng lm mt mu dung dch nc brom. CTCT ca A l A. CH3OH. B. C2H5OH. C. CH3CHOHCH3. D. CH3CH2CH2OH. Cu 177: un mt ancol A vi dung dch hn hp gm KBr v H2SO4 c th trong hn hp sn phm thu c c cht hu c B. Hi ca 12,5 gam cht B ni trn chim 1 th tch ca 2,80 gam nit trong cng iu kin. Cng thc cu to ca A l A. C2H5OH. B. CH3CH2CH2OH. C. CH3OH. D. HOCH2CH2OH. Cu 178: Anken X c cng thc phn t l C5H10. X khng c ng phn hnh hc. Khi cho X tc dng vi KMnO4 nhit thp thu c cht hu c Y c cng thc phn t l C5H12O2. Oxi ha nh Y bng CuO d thu c cht hu c Z. Z khng c phn ng trng gng. Vy X l A. 2-metyl buten-2. B. But-1-en. C. 2-metyl but-1-en. D. But-2-en. Cu 179: t chy hon ton 1 th tch hi ancol no n chc A thu c CO 2 v H2O c tng th tch gp 5 ln th tch hi ancol A dng ( cng iu kin). Vy A l A. C2H5OH. B. C4H9OH. C. CH3OH. D. C3H7OH. Cu 180: Cho 30,4 gam hn hp gm glixerol v mt ru n chc, no A phn ng vi Na th thu c 8,96 lt kh (ktc). Nu cho hn hp trn tc dng vi Cu(OH)2 th ho tan c 9,8 gam Cu(OH)2. Cng thc ca A l A. C2H5OH. B. C3H7OH. C. CH3OH. D. C4H9OH. Cu 181: Hn hp X gm ancol metylic v mt ancol no, n chc A, mch h. Cho 2,76 gam X tc dng vi Na d thu c 0,672 lt H2 (ktc), mt khc oxi ha hon ton 2,76 gam X bng CuO (t o) thu c hn hp anehit. Cho ton b lng anehit ny tc dng vi dung dch AgNO 3/NH3 d thu c 19,44 gam cht kt ta. Cng thc cu to ca A l A. C2H5OH. B. CH3CH2CH2OH. C. CH3CH(CH3)OH. D. CH3CH2CH2CH2OH. Cu 182: Ancol no mch h A cha n nguyn t C v m nhm OH trong cu to phn t. Cho 7,6 gam A tc dng ht vi Na cho 2,24 lt H2 (ktc). Mi quan h gia n v m l A. 2m = 2n + 1. B. m = 2n + 2. C. 11m = 7n + 1. D. 7n = 14m + 2. Cu 183: Cht hu c X mch h c to ra t axit no A v etylen glicol. Bit rng a gam X th hi chim th tch bng th tch ca 6,4 gam oxi cng iu kin nhit v p sut; a gam X phn ng ht vi xt to ra 32,8 gam mui. Nu cho 200 gam A phn ng vi 50 gam etilenglicol ta thu c 87,6 gam este. Tn ca X v hiu sut phn ng to X l A. Etylen glicol iaxetat ; 74,4%. B. Etylen glicol ifomat ; 74,4%. C. Etylen glicol iaxetat ; 36,3%. D. Etylen glicol ifomat ; 36,6%. Cu 184: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d, thu c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120 ml. Hiu sut phn ng oxi ho ancol etylic l: A. 42,86%. B. 66,7%. C. 85,7%. D. 75%.

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Hu c 11
Cu 185: t chy hon ton mt lng hn hp 2 ancol no n chc X, Y l ng ng lin tip thu c 11,2 lt CO2 cng vi lng hn hp trn cho phn ng vi Na d th thu c 2,24 lt H 2 ( ktc). Cng thc phn t ca 2 ancol trn l A. C2H5OH; C3H7OH. B. CH3OH; C3H7OH. C. C4H9OH; C3H7OH. D. C2H5OH ; CH3OH. Cu 186*: Oxi ho 9,2 gam ancol etylic bng CuO un nng thu c 13,2 gam hn hp gm anehit, axit, ancol d v nc. Hn hp ny tc dng vi Na sinh ra 3,36 lt H 2 ( ktc). Phn trm ancol b oxi ho l A. 25%. B. 50%. C. 75%. D. 90%. Cu 187: Thc hin cc th nghim sau: TN 1 : Trn 0,015 mol ru no X vi 0,02 mol ru no Y ri cho tc dng ht vi Na th thu c 1,008 lt H2. TN 2 : Trn 0,02 mol ru X vi 0,015 mol ru Y ri cho hp tc dng ht vi Na th thu c 0,952 lt H2. Th nghim 3 : t chy hon ton mt lng hn hp ru nh trong th nghim 1 ri cho tt c sn phm chy i qua bnh ng CaO mi nung, d thy khi lng bnh tng thm 6,21 gam. Bit th tch cc khi o ktc. Cng thc 2 ru l A. C2H4(OH)2 v C3H6(OH)2. B. C2H4(OH)2 v C3H5(OH)3. C. CH3OH v C2H5OH. D. Khng xc nh c.

CHUYN 6: ANEHIT-XETON-AXIT CACBOXYLIC

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Hu c 11
Cu 1: Mt anehit c cng thc tng qut l CnH2n + 2 2a m (CHO)m. Cc gi tr n, a, m ln lt c xc nh l A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 2: Co bao nhiu ng phn cu tao C5H10O co kha nng tham gia phan ng trang gng ? A. 2. B. 3. C. 4. D. 5. Cu 3: Co bao nhiu xeton co cng thc phn t l C5H10O ? A. 1. B. 2. C. 3. D. 4. Cu 4: Co bao nhiu ng phn cu tao C6H12O tham gia phan ng trang gng ? A. 6. B. 7. C. 8. D. 9. Cu 5: Co bao nhiu ancol C5H12O khi tac dung vi CuO un nong cho ra anehit ? A. 1. B. 2. C. 3. D. 4. Cu 6: CTGN ca 1 anehit no, a chc, mch h l C2H3O. CTPT ca n l A. C8H12O4. B. C4H6O. C. C12H18O6. D. C4H6O2. Cu 7: CTGN ca anehit no, a chc, mch h l C2H3O. Anehit c s ng phn l A. 2. B. 4. C. 1. D. 3. Cu 8: (CH3)2CHCHO c tn l A. isobutyranehit. B. anehit isobutyric. C. 2-metyl propanal. D. A, B, C u ng. Cu 9: CTPT ca ankanal c 10,345% H theo khi lng l A. HCHO. B. CH3CHO. C. C2H5CHO. D. C3H7CHO. Cu 10: Anehit A (ch cha mt loi nhm chc) co %C va %H (theo khi lng) ln lt la 55,81 va 6,97. Chi ra phat biu sai A. A la anehit hai chc. B. A con co ng phn la cac axit cacboxylic. C. A la anehit no. D. Trong phan ng trang gng, mt phn t A chi cho 2 electron. Cu 11: Trong cung iu kin nhit va ap sut, 1 lit hi anehit A co khi lng bng khi lng 1 lit CO2. A la A. anehit fomic. B. anehit axetic. C. anehit acrylic. D. anehit benzoic. Cu 12: t chay hoan toan p mol anehit X c q mol CO2 va t mol H2O. Bit p = q - t. Mt khac 1 mol X trang gng c 4 mol Ag. X thuc day ng ng anehit A. n chc, no, mch h. C. hai chc cha no (1 ni i C=C). B. hai chc, no, mch h. D. nhi chc cha no (1 ni ba CC). Cu 13: Anehit a chc A chay hoan toan cho mol CO2 - mol H2O = mol A. A la A. anehit no, mch h. B. anehit cha no. C. anehit thm. D. anehit no, mch vong. Cu 14: t chay anehit A c mol CO2 = mol H2O. A la A. anehit no, mch h, n chc. B. anehit n chc, no, mch vong. C. anehit n chc co 1 ni i, mch h. D. anehit no 2 chc, mch h. Cu 15: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z ; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. no, hai chc. B. khng no (cha mt ni i C=C), hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc. Cu 16: Cho cac cht : HCN, H2, dung dich KMnO4, dung dich Br2/H2O, dung dich Br2/CH3COOH a. S cht phan ng c vi (CH3)2CO iu kin thch hp la A. 2. B. 3. C. 4. D. 5. b. S cht phan ng c vi CH3CH2CHO iu kin thch hp la A. 4. B. 2. C. 3. D. 5. Cu 17: CH3CHO c th to thnh trc tip t A. CH3COOCH=CH2. B. C2H2. C. C2H5OH. D. Tt c u ng. Cu 18: Qu trnh no sau y khng to ra anehit axetic ? A. CH2=CH2+ H2O (to, xc tc HgSO4). B. CH2=CH2 + O2 (to, xc tc). C. CH3COOCH=CH2 + dung dch NaOH (to). D. CH3CH2OH + CuO (t0).

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Hu c 11
Cu 19: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l A. C2H5OH, C2H2, CH3COOC2H5. B. HCOOC2H3, C2H2, CH3COOH. C. C2H5OH, C2H4, C2H2. D. CH3COOH, C2H2, C2H4. Cu 20: Mt axit cacboxylic c cng thc tng qut l C nH2n + 2 2a m (COOH)m. Cc gi tr n, a, m ln lt c xc nh l A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 21: A la axit no h, cng thc CxHyOz. Chi ra mi lin h ung A. y = 2x-z +2. B. y = 2x + z-2. C. y = 2x. D. y = 2x-z. Cu 22: A la axit cacboxylic mach h, cha no (1 ni i C=C), cng thc CxHyOz. Chi ra mi lin h ung A. y = 2x. B. y = 2x + 2-z. C. y = 2x-z. D. y = 2x + z-2. Cu 23: Axit khng no, n chc c mt lin kt i trong gc hirocacbon c cng thc ph hp l A. CnH2n+1-2kCOOH ( n 2). B. RCOOH. C. CnH2n-1COOH ( n 2). D. CnH2n+1COOH ( n 1). Cu 24: Axit cacboxylic A co cng thc n gian nht la C3H4O3. A co cng thc phn t l A. C3H4O3. B. C6H8O6. C. C18H24O18. D. C12H16O12. Cu 25: CTGN ca mt axit hu c X l CHO. t chy 1 mol X thu c di 6 mol CO2. CTCT ca X l A. CH3COOH. B. CH2=CHCOOH. C. HOOCCH=CHCOOH. D.Kt qu khc. Cu 26: Mt axit no A c CTGN l C2H3O2. CTPT ca axit A l A. C6H9O6. B. C2H3O2. C. C4H6O4. D. C8H12O8. Cu 27: C4H6O2 c s ng phn mch h thuc chc axit l A. 4. B. 3. C. 5. D. tt c u sai. Cu 28: Axit cacboxylic n chc mach h phn nhanh (A) co % O (theo khi lng) la 37,2. Chi ra phat biu sai A. A lam mt mau dung dich brom. B. A la nguyn liu iu ch thuy tinh hu c. C. A co ng phn hinh hoc. D. A co hai lin trong phn t. Cu 29: Axit hu c A c thnh phn nguyn t gm 40,68% C ; 54,24% O. trung ha 0,05 mol A cn 100ml dung dch NaOH 1M. CTCT ca A l A. HOOCCH2CH2COOH. B. HOOCCH(CH3)CH2COOH. C. HOOCCH2COOH. D. HOOCCOOH. Cu 30: Hp cht CH3CH2(CH3)CH2CH2CH(C2H5)COOH c tn quc t l A. axit 2-etyl-5-metyl hexanoic. B. axit 2-etyl-5-metyl nonanoic. C. axit 5-etyl-2-metyl hexanoic. D. tn gi khc. Cu 31: Gim n la dung dich axit axetic co nng la A. 2% 5%. B. 59%. C. 912%. D. 1215%. Cu 32: Axit axetic tc dng c vi dung dch no ? A. natri etylat. B. amoni cacbonat. C. natri phenolat. D. C A, B, C. Cu 33: Trong dy ng ng ca cc axit n chc no, HCOOH l axit c mnh trung bnh, cn li l axit yu (in li khng hon ton). Dung dch axit axetic c nng 0,001 mol/l c pH l A. 3 < pH < 7. B. < 3. C. 3. D. 10-3 Cu 34: in li ca 3 dung dch CH3COOH 0,1M ; CH3COOH 0,01M v HCl c sp xp theo th t tng dn l A. CH3COOH 0,01M < HCl < CH3COOH 0,1M. B. CH3COOH 0,01M < CH3COOH 0,1M < HCl. C. HCl < CH3COOH 0,1M < CH3COOH 0,01M. D. CH3COOH 0,1M < CH3COOH 0,01M < HCl. Cu 35: Th t sp xp theo s tng dn tnh axit ca CH3COOH ; C2H5OH ; CO2 v C6H5OH l A. C6H5OH < CO2 < CH3COOH < C2H5OH. B. CH3COOH < C6H5OH < CO2 < C2H5OH. C. C2H5OH < C6H5OH < CO2 < CH3COOH. D. C2H5OH < CH3COOH < C6H5OH < CO2.

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Cu 36: Cho 3 axit ClCH2COOH , BrCH2COOH, ICH2COOH, dy sp xp theo th t tng dn tnh axit l A. ClCH2COOH < ICH2COOH < BrCH2COOH. B. ClCH2COOH < BrCH2COOH < ICH2COOH. C. ICH2COOH < BrCH2COOH < ClCH2COOH. D. BrCH2COOH < ClCH2COOH < ICH2COOH. Cu 37: Gi tr pH ca cc axit CH3COOH, HCl, H2SO4 c sp xp theo th t tng dn l A. H2SO4, CH3COOH, HCl. B. CH3COOH, HCl , H2SO4. C. H2SO4, HCl, CH3COOH. D. HCl, CH3COOH, H2SO4. Cu 38: Trong cc phn ng este ha gia ancol v axit hu c th cn bng s chuyn dch theo chiu thun khi ta A. dng cht ho nc tch nc. B. chng ct ngay tch este ra. C. cho ancol d hoc axit d. D. tt c u ng. Cu 39: t chay hoan toan hn hp X gm 2 axit cacboxylic c mol CO2 = mol H2O. X gm A. 1 axit n chc, 1 axit a chc. B. 1 axit no, 1 axit cha no. C. 2 axit n chc no mach vong D. 2 axit no, mch h n chc. Cu 40: trung hoa 0,2 mol hn hp X gm 2 axit cacboxylic cn 0,3 mol NaOH. X gm co A. 2 axit cung day ng ng. B. 1 axit n chc, 1 axit hai chc. C. 2 axit a chc. D. 1 axit n chc, 1 axit a chc. Cu 41: t chay hoan toan axit cacboxylic A bng lng va u oxi c hn hp (khi va hi) co ti khi so vi H2 la 15,5. A la axit A. n chc no, mch h B. n chc co 1 ni i (C = C), mch h. C. a chc no, mch h. D. axit no,mch h, hai chc, Cu 42: t chy ht 1 th tch hi axit A thu c 2 th tch CO2 o cng iu kin, A l A. HCOOH. B. HOOCCOOH. C. CH3COOH.D. B v C ng. Cu 43: C th iu ch CH3COOH t A. CH3CHO. B. C2H5OH. C. CH3CCl3. D. Tt c u ng. Cu 44: Cho cc cht : CaC2 (I), CH3CHO (II), CH3COOH (III), C2H2 (IV). S chuyn ha ng iu ch axit axetic l A. I IV II III. B. IV I II III. C. I II IV III. D. II I IV III. Cu 45: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. Cu 46: Cho s chuyn ha : CH3CH2Cl + KCN X (1); X + H3O+ (un nng) Y(2) Cng thc cu to ca X, Y ln lt l A. CH3CH2NH2, CH3CH2COOH. B. CH3CH2CN, CH3CH2CHO. C. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4. Cu 47: Cht c nhit si cao nht l A. CH3CHO. B. C2H5OH. C. CH3COOH. D. C2H6. Cu 48: Nhit si ca mi cht tng ng trong dy cc cht sau y, dy no hp l nht ? C2H5OH HCOOH CH3COOH A. 118,2oC 78,3oC 100,5oC B. 118,2oC 100,5oC 78,3oC o o o C. 100,5 C 78,3 C 118,2 C o D. 78,3 C 100,5oC 118,2oC Cu 49: Chi ra th t tng dn nhit si ca cc cht ? A. CH3CHO; C2H5OH ; CH3COOH. C. C2H5OH ; CH3COOH ; CH3CHO. B. CH3CHO ;CH3COOH ; C2H5OH. D. CH3COOH ; C2H5OH ; CH3CHO. Cu 50: Nhit si ca cc cht c sp xp theo th t tng dn l A. CH3OH < CH3CH2COOH < NH3 < HCl. B. C2H5Cl < CH3COOH < C2H5OH. C. C2H5Cl < CH3COOCH3 < C2H5OH < CH3COOH.

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D. HCOOH < CH3OH < CH3COOH < C2H5F. Cu 51: Cho cac cht CH3CH2COOH (X) ; CH3COOH ( Y) ; C2H5OH ( Z) ; CH3OCH3 (T). Day gm cac cht c sp xp tng dn theo nhit si la A. T, X, Y, Z. B. T, Z, Y, X. C. Z, T, Y, X. D. Y, T, Z, X. Cu 52: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l A. IV > I > III > II. B. IV > III > I > II. C. II > III > I > IV. D. I > II > III > IV. Cu 53: A la ancol n chc no h, B la axit cacboxylic no h n chc. Bit MA=MB. Phat biu ung l A. A, B la ng phn B. A, B co cung s cacbon trong phn t. C. A hn B mt nguyn t cacbon. D. B hn A mt nguyn t cacbon. Cu 54: Hai hp cht hu c X v Y c cng CTPT C3H4O2. X tc dng vi CaCO3 to ra CO2. Y tc dng vi dung dch AgNO3/NH3 to Ag. CTCT thu gn ph hp ca X, Y ln lt l A. HCOOCH=CH2, CH3COOCH3. B. CH3CH2COOH, HCOOCH2CH3. C. HCOOCH=CH2, CH3 CH2COOH. D. CH2=CHCOOH, HOCCH2CHO. CH O X axit axetic + H Y. Cu 55: Cho chui phn ng : C2H6O CTCT ca X, Y ln lt l A. CH3CHO, CH3CH2COOH. B. CH3CHO, CH3COOCH3. C. CH3CHO, CH2(OH)CH2CHO. D. CH3CHO, HCOOCH2CH3. Cu 56: Cho s phn ng sau : H H CH CH 2H CO butin-1,4-iol H x t Y -O Z , Y v Z ln lt l A. HOCH2CH2CH2CH3 ; CH2=CHCH=CH2. B. HOCH2CH2CH2CH2OH ; CH2=CHCH2CH3. C. HOCH2CH2CH2CH2OH ; CH2=CHCH = CH2. D. HOCH2CH2CH2CH2OH ; CH3CH2CH2CH3. Cu 57: Cho s chuyn ha sau: CH O Hirocacbon 2A CH2 rs B N aH C Cu O D O , Mn HOOCCH2COOH. Vy A l B ,a
3 2 2 2
2 2+

CH2

A. B. C3H8. C. CH2=CHCH3. D. CH2=CHCOOH. Cu 58: Cho chui phn ng sau C3H6 H , i B1 C l s B2 (spc) OH O B3 O ,u B4 . Vy B4 l N ,a C /H A. CH3COCH3. B. A v C ng. C. CH3CH2CHO. D. CH3CHOHCH3. Cu 59: Xt cc chui bin ha sau: - H 2O, - H 2 , xt a. A H i B C cao su Buna. , N CTCT ca A l A. OHCCH2CH2CHO. B. CH3CHO. C. OHC(CH2)2CH2OH. D. A, B, C u ng. b. A H i B C cao su Buna. , N CTCT ca A l A. OHCCH2CH2CHO. B. CH3CHO. C. HOC(CH2)2CH2OH. D. A, B, C u ng. Cu 60: Cho s chuyn ha sau : C2H6 B rs A OH O B O ,u C O , Mn D. Vy D l ,a C /H A. CH3CH2OH. B. CH3CHO. C. CH3COCH3. D. CH3COOH. Cu 61: Cho s chuyn ha sau Br2 C2H4 , NaOH O A1 N aO H A2 Cu O A3 Cu(OH) A4 H S A5. Chn cu tr li sai A. A5 c CTCT l HOOCCOOH. B. A4 l mtianehit. C. A2 l mt iol. D. A5 l mt iaxit. Cu 62: Cho chui bin ha sau :
2 2
2

2+

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C2H5OH

C2H5OH

C2H5OH

a. Cht A c th l A. natri etylat. B. anehit axetic. C. etyl axetat. D. A, B, C u ng. b. Cht B c th l A. etilen. B. tinh bt. C. glucoz. D. A, B, C u sai. c. Cht C c th l A. etanal. B. axetilen. C. etylbromua. D. A, C u ng. Cu 63: Mt hp cht c thnh phn l 40% C ; 6,7% H v 53,3% O. Hp cht c CTGN l A. C6H8O. B. C2H4O. C. CH2O. D. C3H6O. Cu 64: Pht biu ng l A. Axit cha no khi chy lun cho s mol CO2 ln hn s mol H2O. B. anehit tc dng vi H2 (xc tc Ni) lun to ancol bc nht. C. anehit va c tnh kh va c tnh oxi ha. D. A, B, C u ng. Cu 65: Cho cc cht sau : (1) CH2=CHCH2OH ; (2) CH3CH2CHO ; (3) CH3COCH3. Pht biu ng l A. 1, 2, 3 l cc ng phn. B. 3 tc dng vi H2 (xc tc Ni) to 1 ancol bc 2. C. 1, 2 tc dng vi H2 (xc tc Ni) u to ra 1 ancol. D. A, B, C u ng. Cu 66: Cho 4 hp cht c CTPT l M : C3H6O ; N : C3H6O2 ; P : C3H4O ; Q : C3H4O2. Bit : M v P cho phn ng trng gng ; N v Q phn ng c vi dung dch NaOH ; Q phn ng vi H2 to thnh N ; oxi ha P thu c Q. a. M v P theo th t l A. C2H5COOH ; CH2=CHCOOH. B. C2H5CHO ; CH2=CHCHO. C. CH2=CHCOOH ; C2H5COOH . D. CH2=CHCHO ; C2H5CHO. b. N v Q theo th t l A. C2H5COOH ; CH2 = CHCOOH. B. CH2=CHCOOH ; C2H5COOH. C. C2H5CHO ; CH2=CHCHO. D. CH2=CHCHO ; C2H5CHO. Cu 67: Cho cc cht sau: (1) CH2=CHCH2OH ; (2) HOCCH2CHO ; (3) HCOOCH=CH2. Pht biu ng l A. 1, 2, 3 tc dng c vi Na. B. Trong A, B, C c 2 cht cho phn ng trng gng. C. 1, 2, 3 l cc ng phn. D. 1, 2, 3 chy u cho s mol H2O b hn s mol CO2. Cu 68: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na ; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2OCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. Cu 69: Cho dy cc cht : HCHO, CH3COOH, HCOONa, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. Cu 70: Cho cc cht sau : phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 3. C. 2. D. 1. Cu 71: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l A. CH3COOH, CH3COOCH3. B. (CH3)2CHOH, HCOOCH3. C. HCOOCH3, CH3COOH. D. CH3COOH, HCOOCH3.

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Cu 72: Cho tt c cc ng phn mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi : Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 5. C. 4. D. 3. Cu 73: Cho cc cht sau : CH3CH2CHO (1) ; CH2=CHCHO (2) ; CHCCHO (3) ; CH2=CHCH2OH (4) ; (CH3)2CHOH (5). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l A. (2), (3), (4), (5). B. (1), (2), (4), (5). C. (1), (2), (3). D. (1), (2), (3), (4). Cu 74: Cho cc hp cht hu c : C2H4 ; C2H2 ; CH2O ; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. a. S cht tc dng c vi dung dch AgNO3/NH3 to ra Ag l A. 2. B. 4. C. 3. D. 5. b. S cht tc dng c vi dung dch AgNO3/NH3 to ra kt ta l A. 2. B. 4. C. 3. D. 5. Cu 75: Co th phn bit 3 lo mt nhan cha: HCOOH ; CH3COOH ; C2H5OH vi hoa cht nao di y ? A. dd AgNO3/NH3. B. NaOH. C. Na. D. Cu(OH)2/OH-. Cu 76: Chi dung thuc th nao di y co th phn bit 4 lo mt nhan cha : fomon ; axit fomic ; axit axetic ; ancol etylic ? A. dd AgNO3/NH3. B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 77: Chi dung thuc th nao di y co th phn bit 4 lo mt nhan cha : etylen glicol ; axit fomic ; fomon ; ancol etylic ? A. dd AgNO3/NH3 B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 78: Chi dung quy tim va nc brom co th phn bit c nhng cht no sau y ? A. axit fomic ; axit axetic ; axit acrylic ; axit propionic. B. Axit axetic; axit acrylic; anilin; toluen; axit fomic. C. Ancol etylic; ancol metylic; axit axetic; axit propionic. D. Ancol etylic; ancol metylic ; phenol ; anilin. Cu 79: phn bit 3 mu ha cht ring bit : phenol, axit acrylic, axit axetic bng mt thuc th, ngi ta dng thuc th A. dung dch Na2CO3. B. CaCO3. C. dung dch Br2. D. dung dch AgNO3/NH3. Cu 80: phn bit axit propionic v axit acrylic ta dng A. dung dch Na2CO3. B. dung dch Br2. C. dung dch C2H5OH. D. dung dch NaOH. Cu 81: C th phn bit CH3CHO v C2H5OH bng phn ng vi A. Na. B. Cu(OH)2/NaOH. C. AgNO3/NH3. D. Tt c u ng. Cu 82: phn bit 3 dung dch ring bit : axit axetic, axit acrylic, axit fomic ngi ta dng theo th t cc thuc th sau A. dung dch Br2/CCl4. B. dung dch Br2/H2O. C. dung dch Na2CO3. D. dung dch AgNO3/NH3 d. Cu 83: phn bit HCOOH v CH3COOH ta dng A. Na. B. AgNO3/NH3. C. CaCO3. D. NaOH. Cu 84: Trng gng hon ton hp cht hu c X bng AgNO3/NH3 thu c hn hp sn phm ch gm cc cht v c. X c cu to A. HCHO. B. HCOONH4.C. HCOOH. D. Tt c u ng. Cu 85: C th phn bit HCOOCH3 v CH3COOH bng A. AgNO3/NH3 B. CaCO3. C. Na. D. Tt c u ng. Cu 86: Cht to c kt ta gch khi un nng vi Cu(OH)2 l A. HCHO. B. HCOOCH3. C. HCOOH. D. Tt c u ng. Cu 87: Ch dng 1 ha cht no sau y phn bit cc dung dch : ancol etylic, glixerol, fomalin ? A. Cu(OH)2 , toC. B. Na. C. AgNO3 / NH3. D. A, B, C u ng. Cu 88: Hiro hoa hoan toan 2,9 gam mt anehit A c 3,1 gam ancol. A co cng thc phn t la A. CH2O. B. C2H4O. C. C3H6O. D. C2H2O2. Cu 89: Th tch H2 (0oC v 2 atm) va tc dng vi 11,2 gam anehit acrylic l A. 4,48 lt. B. 2,24 lt. C. 0,448 lt. D. 0,336 lt. Cu 90: Cho 14,6 gam hn hp 2 anehit n chc, no lin tip tc dng ht vi H2 to 15,2 gam hn hp 2 ancol.

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a. Tng s mol 2 ancol l A. 0,2 mol. B. 0,4 mol. C. 0,3 mol. D. 0,5 mol. b. Khi lng anehit c KLPT ln hn l A. 6 gam. B. 10,44 gam. C. 5,8 gam. D. 8,8 gam. Cu 91: Cho 7 gam cht A c CTPT C4H6O tc dng vi H2 d c xc tc to thnh 5,92 gam ancol isobutylic. a. Tn ca A l A. 2-metyl propenal. B. 2-metylpropanal. C. but-2-en-1-ol. D. but-2-en-1-al. b. Hiu sut ca phn ng l A. 85%. B. 75%. C. 60%. D. 80%. Cu 92: Oxi ha 1,76 gam mt anehit n chc c 2,4 gam mt axit tng ng. Anehit l A. anehit acrylic. B. anehit axetic. C. anehit propionic. D. anehit fomic. Cu 93: Oxi hoa 17,4 gam mt anehit n chc c 16,65 gam axit tng ng (H = 75%). Anehit co cng thc phn t la A. CH2O. B. C2H4O. C. C3H6O. D. C3H4O. Cu 94: t chy a mol mt anehit A thu c a mol CO2. Anehit ny c th l A. CH3CHO. B. HCHO. C. C2H5CHO. D. A, B, C u ng. Cu 95: t chy hon ton 1,46 gam hn hp 2 anehit no, n chc ng ng k tip thu c 1,568 lt CO2 (ktc). a. CTPT ca 2 anehit l A. CH3CHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H5CHO v C3H7CHO. D. Kt qu khc. b. Khi lng gam ca mi anehit l A. 0,539 v 0,921. B. 0,88 v 0,58. C. 0,44 v 1,01. D. 0,66 v 0,8. Cu 96: t chay hoan toan mt anehit n chc no, mch h A cn 17,92 lit O2 (ktc). Hp thu ht san phm chay vao nc vi trong c 40 gam kt tua va dung dich X. un nong dung dich X lai co 10 gam kt tua na. Cng thc phn t A la A. CH2O. B. C2H4O. C. C3H6O. D. C4H8O. Cu 97: X, Y, Z, T la 4 anehit no h n chc ng ng lin tip, trong o MT = 2,4MX. t chay hoan toan 0,1 mol Z ri hp thu ht san phm chay vao binh ng dung dich Ca(OH) 2 d thy khi lng dung dich tng hay giam bao nhiu gam? A. tng 18,6 gam. B. tng 13,2 gam. C. Giam 11,4 gam. D. Giam 30 gam. Cu 98: t chay hoan toan mt lng aehit A cn va u 2,52 lit O2 (ktc), c 4,4 gam CO2 va 1,35 gam H2O. A co cng thc phn t la A. C3H4O. B. C4H6O. C. C4H6O2. D. C8H12O. Cu 99: t chy hon ton 1 anehit A mch h, no thu c CO2 v H2O theo t l n A : n CO 2 : n H 2O = 1 : 3 : 2 . Vy A l A. CH3CH2CHO. B. OHCCH2CHO. C. HOCCH2CH2CHO. D. CH3CH2CH2CH2CHO. Cu 100: Cho 1,97 gam dung dch fomalin tc dng vi dung dch AgNO3/NH3 d thu c 10,8 gam Ag. Nng % ca anehit fomic trong fomalin l A. 49%. B. 40%. C. 50%. D. 38,07%. Cu 101: Hp cht A cha 1 loi nhm chc v phn t ch cha cc nguyn t C, H, O trong oxi chim 37,21% v khi lng, 1 mol A trng gng hon ton cho 4 mol Ag. Vy A l A. C2H4(CHO)2. B. HCHO. C. HOCCH2CHO. D. CH3CHO. Cu 102: Cho 10,4 gam hn hp gm metanal v etanal tc dng vi mt lng va d AgNO3/NH3 thu c 108 gam Ag. Khi lng metanal trong hn hp l A. 4,4 gam. B. 3 gam. C. 6 gam. D. 8,8 gam. Cu 103: Cho bay hi ht 5,8 gam mt hp cht hu c X thu c 4,48 lt hi X 109,2oC v 0,7 atm. Mt khc khi cho 5,8 gam X phn ng ca AgNO3/NH3 d to 43,2 gam Ag. CTPT ca X l A. C2H2O2. B. C3H4O2. C. CH2O. D. C2H4O2. Cu 104: Cho 5,8 gam anehit A tc dng ht vi mt lng d AgNO3/NH3 thu c 43,2 gam Ag. Tm CTPT ca A

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A. CH3CHO. B. CH2=CHCHO. C. OHCCHO. D. HCHO. Cu 105: Cho 8,7 gam anehit X tac dung hoan toan vi lng dung dich AgNO3/NH3 (d) c 64,8 gam Ag. X co cng thc phn t la A. CH2O. B. C2H4O. C. C2H2O2. D. C3H4O. Cu 106: 8,6 gam anehit mach khng nhanh A tac dung vi lng (d) dung dich AgNO3/NH3 tao 43,2 gam Ag. A co cng thc phn t la A. CH2O. B. C3H4O. C. C4H8O. D.C4H6O2. Cu 107: X la hn hp gm 2 anehit ng ng lin tip. Cho 0,1 mol X tac dung vi lng d dung dich AgNO3/NH3 c 25,92 gam bac. % s mol anehit co s cacbon nho hn trong X la A. 20%. B. 40%. C. 60%. D. 75%. Cu 108: Cho 0,1 mol mt anehit X tac dung ht vi dung dich AgNO 3/NH3 (d) c 43,2 gam Ag. Hiro hoa hoan toan X c Y. Bit 0,1 mol Y tac dung va u vi Na va u c 12 gam rn. X co cng thc phn t la A. CH2O. B. C2H2O2. C. C4H6O. D. C3H4O2. Cu 109: X la hn hp 2 anehit n chc. Chia 0,12 mol X thanh hai phn bng nhau : - t chay ht phn 1 c 6,16 gam CO2 va 1,8 gam H2O. - Cho phn 2 tac dung vi lng d dung dich AgNO3/NH3 c 17,28 gam bac. X gm 2 anehit co cng thc phn t la A. CH2O va C2H4O. B. CH2O va C3H6O. C. CH2O va C3H4O. D. CH2O va C4H6O. Cu 110: Oxi ha 48 gam ancol etylic bng K2Cr2O7 trong H2SO4 c, tch ly sn phm hu c ra ngay khi mi trng v dn vo dung dch AgNO3/NH3 d thy c 123,8 gam Ag. Hiu sut ca phn ng oxi ha l A. 72,46 %. B. 54,93 %. C. 56,32 %. D. Kt qu khc. Cu 111: Dn m gam hi ancol etylic qua ng ng CuO d un nong. Ngng tu phn hi thoat ra c hn hp X gm anehit, ancol etylic va H2O. Bit lng X tac dung vi Na (d) giai phong 3,36 lit H2 ( ktc), con 1/2 lng X con lai tac dung vi d dung dich AgNO3/NH3 tao c 25,92 gam Ag. a. Gia tri m la A. 13,8 gam B. 27,6 gam C. 16,1 gam D. 6,9 gam b. Hiu sut phn ng oxi ho ancol etylic l A. 20%. B. 40%. C. 60%. D. 75%. Cu 112: Cho m gam ancol n chc no (h) X qua ng ng CuO (d) nung nong. Sau khi phan ng hoan toan thy khi lng cht rn trong ng giam 0,32 gam. Hn hp hi thu c (gm hi anehit va hi nc) co ti khi so vi H2 la 19. Gia tri m la A. 1,2 gam. B. 1,16 gam. C. 0,92 gam. D.0,64 gam. Cu 113: X la hn hp 2 ancol n chc ng ng lin tip. Cho 0,3 mol X tac dung hoan toan vi CuO un nong c hn hp Y gm 2 anehit. Cho Y tac dung vi lng dung dich AgNO3/NH3 c 86,4 gam Ag. X gm A. CH3OH va C2H5OH. B. C3H7OH va C4H9OH. C. C2H5OH v C3H7OH. D. C3H5OH va C4H7OH. Cu 114: Dn 4 gam hi ancol n chc A qua ng ng CuO, nung nong. Ngng tu phn hi thoat ra c hn hp X. Cho X tac dung vi lng d dung dich AgNO3/NH3 c 43,2 gam bac. A la A. ancol metylic. B. ancol etylic. C. ancol anlylic. D. ancol benzylic. Cu 115: X la hn hp gm mt ancol n chc no, mch h A va mt anehit no, mch h n chc B (A va B co cung s cacbon). t chay hoan toan 13,4 gam X c 0,6 mol CO2 va 0,7 mol H2O. S nguyn t C trong A, B u la A. 1. B. 2. C. 3. D. 4. Cu 116: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 117: Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l

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A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. Cu 118: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < My), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 50,56%. B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%. Cu 119: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. OHCCHO. C. CH3CHO. D. CH3CH(OH)CHO. Cu 120: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HCOOCH3 v HCOOCH2CH3. D. HOCH(CH3)CHO v HOOCCH2CHO. Cu 121: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOCH3. C. HOOCCHO. D. OHCCH2CH2OH. Cu 122: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 10,5. B. 8,8. C. 24,8. D. 17,8. Cu 123: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 8,8. C. 7,4. D. 9,2. Cu 124: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. HCHO. C. C4H9CHO. D. C2H5CHO. Cu 125: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. Cu 126: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n(CHO)2 (n 0). Cu 127: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 35,00%. B. 65,00%. C. 53,85%. D. 46,15%. Cu 128: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 13,5. B. 8,1. C. 8,5. D. 15,3.

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Cu 129: 1,72 gam hn hp anehit acrylic v anehit axetic tham gia phn ng cng va 1,12 lt H 2 (ktc). Cho thm 0,696 gam anehit B l ng ng ca anehit fomic vo 1,72 gam hn hp 2 anehit trn ri cho hn hp thu c tham gia phn ng trng bc hon ton c 10,152 gam Ag. Cng thc cu to ca B l A. CH3CH2CHO. B. C4H9CHO. C. CH3CH(CH3)CHO. D. CH3CH2CH2CHO. Cu 130*: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO3 trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong hn hp X l A. C2H3CHO v HCHO. B. C2H5CHO v HCHO. C. CH3CHO v HCHO. D. C2H5CHO v CH3CHO. Cu 131: A la axit cacboxylic n chc cha no (1 ni i C=C). A tac dung vi brom cho san phm cha 65,04% brom (theo khi lng). Vy A co cng thc phn t la A. C3H4O2. B. C4H6O2. C. C5H8O2. D. C5H6O2. Cu 132: Mun trung ha 6,72 gam mt axit hu c A cn dng 200 gam dung dch NaOH 2,24%. A l A. CH3COOH. B. CH3CH2COOH. C. HCOOH. D. CH2=CHCOOH. Cu 133: trung hoa 40 ml gim n cn 25 ml dung dich NaOH 1M. Bit khi lng ring cua gim la 1 g/ml. Vy mu gim n nay co nng la A. 3,5%. B. 3,75%. C. 4%. D. 5%. Cu 134: Trung hoa 9 gam axit cacbonxylic A bng NaOH va u c can dung dich c 13,4 gam mui khan. A co cng thc phn t la A. C2H4O2. B. C2H2O4. C. C3H4O2. D. C4H6O4. Cu 135: Trung hoa 2,7 gam axit cacboxylic A cn va u 60 ml dung dich NaOH 1M. A co cng thc phn t la A. C2H4O2. B. C3H4O2. C. C4H6O4. D. C2H2O4. Cu 136: Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va ri c cn dung dch sau phn ng c 2,46 gam mui khan. Axit l A. HCOOH. B. CH2=CHCOOH. C. CH3CH2COOH. D. CH3COOH. Cu 137: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH. Cu 138: A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X. trung ha ht X cn 90 ml dung dch NaOH 1M. A, B ln lt l A. Axit propionic, axit axetic. B. axit axetic, axit propionic. C. Axit acrylic, axit propionic. D. Axit axetic, axit acrylic. Cu 139: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 400 ml dung dch NaOH 1M. Tng khi lng mui thu c sau phn ng l A. 3,54 gam. B. 4,46 gam. C. 5,32 gam. D. 11,26 gam. Cu 140: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH2=CHCOOH. B. CH3COOH. C. HCCCOOH. D. CH3CH2COOH. Cu 141: Cho 0,1 mol axit hu c X tc dng vi 11,5 gam hn hp Na v K thu c 21,7 gam cht rn v thy thot ra 2,24 lt kh H2 (ktc). Cng thc cu to ca X l A. (COOH)2. B. CH3COOH. C. CH2(COOH)2. D. CH2=CHCOOH. Cu 142: Cho 16,6 gam hn hp gm HCOOH, CH3COOH tc dng ht vi Mg thu c 3,36 lt H2 (ktc). Khi lng CH3COOH l A. 12 gam. B. 9 gam. C. 6 gam. D. 4,6 gam. Cu 143: X la hn hp gm HCOOH va CH3COOH (ti l mol 1:1). Ly 21,2 gam X tac dung vi 23 gam C2H5OH (xuc tac H2SO4 c, un nong) thu c m gam hn hp este (hiu sut este hoa u at 80%). Gia tri m la A. 40,48 gam. B. 23,4 gam. C. 48,8 gam. D. 25,92 gam. Cu 144: un nong 6 gam CH3COOH vi 9,2 gam C2H5OH (co H2SO4 c lam xuc tac) n khi phan ng at ti trang thai cn cn bng thi c 5,5 gam este. Hiu sut phan ng este hoa la

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A. 55%. B. 62,5%. C. 75%. D. 80%. Cu 145: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l A. CH3COOH, H% = 68%. B. CH2=CHCOOH, H%= 78%. C. CH2=CHCOOH, H% = 72%. D. CH3COOH, H% = 72%. Cu 146: Oxi ho anehit OHCCH2CH2CHO trong iu kin thch hp thu c hp cht hu c X. un nng hn hp gm 1 mol X v 1 mol ancol metylic vi xc tc H2SO4 c thu c 2 este Z v Q (MZ < MQ) vi t l khi lng mZ : mQ = 1,81. Bit ch c 72% ancol chuyn thnh este. S mol Z v Q ln lt l A. 0,36 v 0,18. B. 0,48 v 0,12. C. 0,24 v 0,24. D. 0,12 v 0,24. Cu 147: t chy hon ton 2,22 gam mt axit hu c no A thu c 1,62 gam H2O. A l A. C3H7COOH. B. C2H5COOH. C. HCOOH. D. CH3COOH. Cu 148: t chay hoan toan 0,1 mol axit n chc cn V lit O2 ktc, thu c 0,3 mol CO2 va 0,2 mol H2O. Gia tri V la A. 6,72 lit. B. 8,96 lit. C. 4,48 lit. D. 5,6 lit. Cu 149: t chay hoan toan mt axit A thu c 0,2 mol CO2 va 0,15 mol H2O. A co cng thc phn t la A. C3H4O4. B. C4H8O2. C. C4H6O4. D. C5H8O4. Cu 150: t chy hon ton 4,38 gam mt axit E no, mch thng thu c 4,032 lt CO 2 (kc) v 2,7 gam H2O. CTCT ca E l A. CH3COOH. B. C17H35COOH. C. HOOC(CH2)4COOH. D. CH2=C(CH3)COOH. Cu 151: t chay hoan toan 0,1 mol axit cacboxylic A thu c cha n 8 gam hn hp CO2 va H2O. A la A. axit fomic. B. axit axetic. C. axit acrylic. D. axit oxalic. Cu 152: Z l mt axit hu c. t chy 0,1 mol Z cn 6,72 lt O2 (ktc). CTCT ca Z l A. CH3COOH. B. CH2=CHCOOH. C. HCOOH. D. Kt qu khc. Cu 153: t chy ht 1 th tch hi axit hu c A c 3 th tch hn hp CO2 v hi nc khi o cng iu kin. CTPT ca A l A. HCOOH. B. CH3COOH. C. HOOCCOOH. D. HOOCCH2COOH. Cu 154: t chy hon ton 0,44 gam mt axit hu c, sn phm chy cho hp th hon ton vo bnh 1 ng P2O5, bnh 2 ng dung dch KOH. Sau th nghim thy khi lng bnh 1 tng 0,36 gam v bnh 2 tng 0,88 gam. CTPT ca axit l A. C4H8O2. B. C5H10O2. C. C2H6O2. D. C2H4O2. Cu 155: t chy ht 10ml th tch hi mt hp cht hu c A cn dng 30 ml O 2, sn phm thu c ch gm CO2 v H2O c th tch bng nhau v u bng th tch O2 phn ng. CTPT ca A l A. C2H4O2. B. C3H6O3. C. C3H6O2. D. C4H8O2. Cu 156: X la hn hp 2 axit cacboxylic no, h, phn t mi axit cha khng qua 2 nhom -COOH. t chay hoan toan 9,8 gam X c 11 gam CO2 va 3,6 gam H2O. X gm A. HCOOH va CH3COOH. B. HCOOH va HOOCCH2COOH. C. HCOOH va HOOCCOOH. D. CH3COOH va HOOCCH2COOH. Cu 157: Cc sn phm thu c khi t chy hon ton 3 gam axit hu c X c dn ln lt qua bnh 1 ng H2SO4 c v bnh 2 ng dung dch NaOH. Sau th nghim thy khi lng bnh 1 tng 1,8 gam v khi lng bnh 2 tng 4,4 gam. CTCT ca A l A. HCOOH. B. C2H5COOH. C. CH3COOH.D. A hoc B hoc C. Cu 158: Oxi hoa 0,125 mol ancol n chc A bng 0,05 mol O2 (xt, to) c 5,6 gam hn hp X gm axit cacboxylic ; anehit ; ancol d va nc. A co cng thc phn t la A. CH4O. B. C2H6O. C. C3H6O. D. C3H8O. Cu 159: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOCCOOH v 42,86%. B. HOOCCOOH v 60,00%.

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C. HOOCCH2COOH v 70,87%. D. HOOCCH2COOH v 54,88%. Cu 160: Cht A c ngun gc t thc vt v thng gp trong i sng (cha C, H, O), mch h. Ly cng s mol ca A cho phn ng ht vi Na2CO3 hay vi Na th thu c s mol CO2 bng 3/4 s mol H2. Cht A l A. axit malic : HOOCCH(OH)CH2COOH. B. axit xitric : HOOCCH2C(OH)(COOH)CH2COOH. C. axit lauric : CH3(CH2)10COOH. D. axit tactaric : HOOCCH(OH)CH(OH)COOH. Cu 161: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. axit 3-hiroxipropanoic. D. etylen glicol. Cu 162: Chia 0,3 mol axit cacobxylic A thanh hai phn bng nhau. - t chay phn 1 c 19,8 gam CO2. - Cho phn 2 tac dung hoan toan vi 0,2 mol NaOH, thy sau phan ng khng con NaOH. Vy A co cng thc phn t la A. C3H6O2. B. C3H4O2. C. C3H4O4. D. C6H8O4. Cu 163: Cho 10 gam hn hp X gm HCHO va HCOOH tac dung vi lng (d) dung dich AgNO3/NH3 c 99,36 gam bac. % khi lng HCHO trong hn hp X la A. 54%. B. 69%. C. 64,28%. D. 46%. Cu 164: trung hoa a mol axit cacboxylic A cn 2a mol NaOH. t chay hoan toan a mol A thu c 3a mol CO2. A co cng thc phn t la A. C3H4O2. B. C3H6O2. C. C6H10O4. D. C3H4O4. Cu 165: t chay hoan toan 3,12 gam axit cacboxylic A c 3,96 gam CO2. Trung hoa cung lng axit nay cn 30 ml dung dich NaOH 2M. A co cng thc phn t la A. C2H4O2. B. C4H6O2. C. C3H4O2. D. C3H4O4. Cu 166: Hn hp X gm 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt CO2 (kc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. CTCT ca 2 axit l A. HCOOH v C2H5COOH. B. CH3COOH v C2H5COOH. C. HCOOH v HOOCCOOH. D. CH3COOH v HOOCCH2COOH. Cu 167: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol A c 2a mol CO2. A l A. CH3COOH. B. HOOCCOOH. C. axit n chc no. D. axit n chc khng no. Cu 168: Hp cht hu c E mch h c CTPT C 3H6O3 c nhiu trong sa chua. E c th tc dng vi Na v Na2CO3, cn khi tc dng vi CuO nung nng th to ra hp cht hu c khng tham gia phn ng trng gng. CTCT ca E l A. CH3COOCH2OH. B. CH3CH(OH)COOH. C. HOCH2COOCH3. D. HOCH2CH2COOH. Cu 169: t chy hon ton 0,1 mol cht X l mui Na ca mt axit hu c thu c 0,15 mol CO 2, hi H2O v Na2CO3. CTCT ca X l A. C3H7COONa. B. CH3COONa. C. CH3COONa. D. HCOONa. Cu 170: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO 2, hi nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. C2H5COONa v C3H7COONa. B. C3H7COONa v C4H9COONa. C. CH3COONa v C2H5COONa. D. CH3COONa v C3H7COONa. Cu 171: Khi lng axit axetic thu c khi ln men 1 lit ancol etylic 8 o la bao nhiu ? Cho d = 0,8 g/ml va hiu sut phan ng at 92%. A. 76,8 gam. B. 90,8 gam. C. 73,6 gam. D. 58,88 gam. Cu 172: Thc hin phn ng oxi ha m gam ancol etylic nguyn cht thnh axit axetic (hiu sut phn ng t 25%) thu c hn hp Y, cho Y tc dng vi Na d thu c 5,6 lt H2 (ktc). Gi tr ca m l A. 18,4 gam. B. 9,2 gam. C. 23 gam. D. 4,6 gam. Cu 173: Cho s phn ng sau: + HCN + H3O+, to + H2SO4 , to xt, to, p

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CH3CH=O A B C3H4O2 C C3H4O2 c tn l A. axit axetic. B. axit metacrylic. C. axit acrylic. D. anehit acrylic. M g e te , CO 2 B +HCl C . Cu 174: Cho s sau : C2H5Br A C c cng thc l A. CH3COOH. B. CH3CH2COOH. C. CH3CH2OH. D. CH3CH2CH2COOH. (C O O H2) B D C2H5O H Cu 175: Cho s chuyn ho sau: H C O O N a A Cc cht A, B, D c th l A. H2 ; C4H6 ; C2H4(OH)2. B. H2 ; C2H4 ; C2H4(OH)2. C. CH4 ; C2H2 ; (CHO)2. D. C2H6 ; C2H4(OH)2. Cu 176 : Cho 19,8 gam mt anehit n chc A phan ng hoan toan vi dung dich AgNO3/NH3 (d). Lng Ag sinh ra phan ng ht vi dung dich HNO 3 loang c 6,72 lit NO ktc. A co cng thc phn t la A. C2H4O. B. C3H6O. C. C3H4O. D. C4H8O. Cu 177: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H2 hon ton th khi lng sn phm cui cng l A. 11,1 gam. B. 7,4 gam. C. 11,2 gam. D. 11,0 gam. Cu 178: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dd NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l A. 35,24%. B. 45,71%. C. 19,05%. D. 23,49%. Cu 179: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO 3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l A. HCOOH, C3H7COOH. B. CH3COOH, C2H5COOH. C. CH3COOH, C3H7COOH. D. HCOOH, C2H5COOH. Cu 180: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l A. 3,0 gam. B. 4,6 gam. C. 7,4 gam. D. 6,0 gam.

CHUYN 8: ESTE LIPIT CHT GIT RA

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Cu 1: Hy chn nh ngha ng trong cc nh ngha sau: A. Este l nhng hp cht hu c trong phn t c nhm chc COO- lin kt vi cc gc R v R B Este l hp cht sinh ra khi th nhm OH trong nhm COOH ca phn t axit bng nhm OR. C. Este l sn phm phn ng khi cho ru tc dng vi axit cacboxylic D. Este l sn phm phn ng khi cho ru tc dng vi axit. Cu 2: Cng thc tng qut ca este no, n chc l A. RCOOR B. CxHyOz C. CnH2 nO2 D. CnH2 n-2O2 Cu 3: Trong phn t este no, n chc c s lin kt pi l : A. 0 B. 1 C. 2 D. 3 Cu 4: Cng thc phn t ca este X mch h l C4H6O2 . X thuc loi este: A. No, a chc B. Khng no,n chc C. No, n chc D. Khng no, c mt ni i, n chc Cu 5: Tn gi ca este c CTCT thu gn : CH3COOCH(CH3)2 l: A. Propyl axetat B. iso-propyl axetat C. Sec-propyl axetat D. Propyl fomat Cu 6: S ng phn ti a ca este c CTPT C4H8O2 l: A. 2 B. 3 C. 4 D. 5 Cu 7: S ng phn ti a ca este c CTPT C4H6O2 l: A. 4 B. 3 C. 6 D. 5 Cu 8: Phn ng este ho gia ancol etylic v axit axetic to thnh este c tn gi l: A. Metylaxetat B. Axetyletylat C. Etylaxetat D. Axyletylat Cu 9: Metyl propylat l tn gi ca hp cht no sau y? A. HCOOC3H7 B. C2H5COOCH3 C. C3H7COOH D. C2H5COOH Cu 10: Este c to thnh t axit no, n chc vi ancol no, n chc c cng thc no sau y? A. CnH2n + 1COOCmH2m +1 B. CnH2n - 1COOCmH2m -1 C. CnH2n - 1COOCmH2m +1 D. CnH2n + 1COOCmH2m -1 Cu 11: Trong cc cht sau cht no khng phi l este: A.CH3COOC2H5 B.HCOOC3H7 C.C2H5ONO2 D.CH3-OC2H4OCH3 E. C C v D u ng. Cu 12: Mt este hu c n chc c thnh phn khi lng mC : mO = 9 : 8 .CTCT thu gn ca este? A. HCOOC=CH B. HCOOCH-CH2 hoc CH3COOCH3 C. HCOOC2H5 D. C A, B, C u ng Cu 13: Trong phn t este no, n chc, mch h X c cha 36,36 % oxi v khi lng. S cng thc cu to tho mn cng thc phn t ca este X l: A. 4 B. 3 C. 5 D. 6 Cu 14: Mt este c cng thc phn t l C3H6O2, c tham gia phn ng trng bc. CTCT ca este l: A. HCOOC2H5 B. CH3COOCH3 C. HCOOC3H7 D. C2H5COOCH3 Cu 15: Khi thu phn vinyl axetat trong mi trng axit thu c cht g? A. Axit axetic v anehit axetic B. Axit axetic v ancol vinylic C. Axit axetic v ancol etylic D. Axetat v ancol vinylic Cu 16: Mt este c CTPT C4H8O2. Khi thu phn trong mi trng axit thu c ancol etylic. CTCT ca este l: A. C3H7COOH B. CH3COOC2H5 C. HCOOC3H7 D. C2H5COOCH3 Cu 17: Thu phn este C4H8O2 thu c axit X v ancol Y. Oxi ho Y vi xc tc thch hp thu c X. Este c CTCT l: A. CH3COOC2H5 B. HCOOCH2-CH2-CH3 C. C2H5COOCH3 D. HCOOCH(CH3)2 Cu 18: Thy phn 8,8 g este X c CTPT l C4H8O2 bng dung dch NaOH va thu c 4,6 g ancol Y v mui c khi lng l: A. 4,1 g B. 4,2 g C. 8,2 g D. 3,4 g Cu 19: Este X c CTPT C7H12O4. Khi cho 16 g X tc dng vi 200 g dd NaOH 4% th thu c mt ancol Y v 17,8 g hn hp 2 mui. CTCT thu gn ca X l: A. HCOOCH2CH2CH2CH2OOC- CH3 B. CH3COOCH2CH2CH2-OOC-CH3 C. C2H5COOCH2CH2CH2OOC-H D. CH3COOCH2CH2-OOC-C2H5 Cu 20: Cht hu c Y c CTPT l C4H8O2. 0,1 mol Y tc dng hon ton vi dung dch NaOH thu c 8,2 g mui. Y l: A. HCOOC3H7 B. CH3COOC2H5 C. C2H5COOCH3 D. C3H7COOH Cu 21: Cho 3,52 g cht A c cng thc phn t C4H8O2 tc dng vi 0,6 lt dung dch NaOH 0,1 M. Sau phn ng c cn dung dch thu c 4,08 g cht rn. Vy A l:

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A. C3H7COOH B. HCOOC3H7 C. C2H5COOCH3 D. CH3COOC2H5 Cu 22: Thy phn este E c cng thc phn t C4H8O2 vi xc tc axit v c long, thu c hai sn phm hu c X, Y (ch cha cc nguyn t C, H, O). T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Cht X l: A. Axit axetic B. Ru etylic C. Etyl axetat D. Axit fomic Cu 23: Mt este c cng thc phn t l: C4H6O2. Khi thu phn phn trong mi trng axit thu c xeton. CTCT thu gn ca este l: A. HCOOCH=CH- CH3 B. CH3COOCH= CH2 C. HCOOC(CH3)= CH2 D. CH2= CH- COO-CH3 Cu 24: Este X n chc tc dng va vi NaOH thu c 9,52 g mui natri fomat v 8,4 ancol. Vy X l: A. metyl fomat B. etyl fomat C. propyl fomat D. butyl fomat Cu 25: Cho 14,8 gam mt este no n chc A tc dng va vi 100ml dung dch NaOH 2M. Tm CTCT ca A bit rng A c tham gia phn ng trng gng: A. CH3COOCH=CH2 B.HCOOCH3 C. CH2=CH-COOH D. HCOOCH2CH3 Cu 26: khng inh no sau y l sai: A. Phn ng este ho l phn ng thun nghch B. Phn ng trung ho gia axit v baz l phn ng khng thun nghch C. Phn ng thu pn este l phn ng khng thun nghch D. Etyl axetat kh tan trong nc hn axit axetc Cu 27: Mt hp cht hu c X c cng thc phn t C7H12O4. Bit X ch c 1 loi nhm chc, khi cho 16 gam X tc dng va 200 gam dung dch NaOH 4% th thu c mt ru Y v 17,80 gam hn bp 2 mui. Xc nh cng thc cu to thu gn ca X. A. CH3OOC-COOC2H5 B. CH3COO-( CH2)2-OOC2H5 C. CH3COO-(CH2)2-OOC2H5 D. Tt c u sai . Cu 28: Cho 21,8 gam cht hu c X ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6 gam mui v 0,1 mol ru Y. Lng NaOH d c th trung ha ht 0,5 lt dung dch HCl 0,4M. CTCT thu gn ca X l? A. (CH3COO)3C3H5 B. (HCOO)3C3H5 C. (C2H5COO)3C3H5 D. Kt qu khc Cu 29: Mt este n chc X (cha C, H, O v khng c nhm chc khc). T khi hi ca X i vi oxi bng 3,125.Cho 20 gam X tc dng vi 300ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 23,2 gam b rn. CTCT thu gn ca X trong trng hp ny l : A. CH3COOCH3 B. CH3COOCH=CH2 C. C2H5COOCH=CH2 D. HCOOCH=CH2 Cu 30: Mt este n chc, mch h c khi lng l 12,9 gam tc dng vi 150ml dung dch KOH 1 M. Sau phn ng thu mt mui v anehit. Cng thc cu to ca este l: A. HCOOCH=CH-CH3 B. CH3COOCH=CH2 C. C2H5COOCH=CH2 D. HCOOH=CH-CH3 v CH3COOCH=CH2 Cu 31: x phng ha 17,4 gam mt este no n chc cn dng 300ml dung dch NaOH 0,5M.Cng thc phn t ca este l: A. C6H12O2 B. C3H6O2 C. C5H10O2 D. C4H10O2 Cu 32: Phn ng thu phn este trong mi trng kim khi un nng c gi l g? A. X phng ho B. Hirat ho C. Crackinh D. S ln men Cu 33: Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c a g mui v 0,1 mol ancol. Lng NaOH d c th trung ho ht bi 0,5 lt dung dch HCl 0,4M. A c CTTQ l: A. RCOOR1 B. (RCOO)2R1 C. (RCOO)3R1 D. R(COOR1)3 Cu 34: X phng ho hon ton 9,7 g hn hp 2 este n chc X, Y cn 100 ml dung dch NaOH 1,5M. Sau phn ng, c cn dung dch thu c hn hp 2 ancol l ng ng k tip v mt mui duy nht. CTCT ca 2 este l: A. HCOOCH3 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H5COOCH3 v C2H5COOC2H5 D. C3H7COOCH3 v C4H9COOC2H5 Cu 35: Mt este to bi axit n chc v ancol n chc c t khi so vi CO2 l 2. Khi un nng este ny vi dung dch NaOH to ra mui c khi lng ln hn este phn ng. CTCT ca este l: A. CH3COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. C2H5COOCH3 Cu 36: Mt este to bi axit n chc v ancol n chc c t khi so vi CO2 l 2. Khi un nng este ny vi dung dch NaOH to ra mui c khi lng bng 17/22 khi lng este phn ng. CTCT ca este l: A. CH3COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. C2H5COOCH3 Cu 37: Mt este to bi axit n chc v ancol n chc c t khi so vi CO2 l 2. Khi un nng este ny vi dung dch NaOH to ra mui c khi lng = 93,18% khi lng este phn ng. CTCT ca este l: A. CH3COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. C2H5COOCH3 Cu 38: Cht X c CTPT l C4H8O2 khi tc dng vi dung dch NaOH sinh ra cht Y c CTPT l C2H3O2Na v cht Z c cng thc l C2H6O. X thuc loi no sau y?

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A. Axit B. Anehit C. Este D. Ancol Cu 39: X phng ho hon ton 22,2 g hn hp 2 este l HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M. Th tch dung dch NaOH cn dng l: A. 300 ml B. 400 ml C. 500 ml D. Kt qu khc Cu 40: un nng 1,1 g este n chc M vi dung dch KOH d ngi ta thu c 1,2 g mui. Bit M c khi lng phn t l 88. M c CTCT l: A. C2H5COOCH3 B. CH3COOC2H5 C. HCOOC3H7 D.CH3COOCH3 Cu 41: X l este c to bi ancol l ng ng ca ancol etylic v axit l ng ng ca axit axetiC. Thu phn hon ton 13,2 g X cn 0,15 mol NaOH. X c CTCT l: A. CH3COOC2H5 B. CH3COOCH3 C. HCOOCH3 D. CH3COOC3H7 Cu 42: Cho 12,9 g mt este n chc, mch h tc dng ht vi 150 ml dung dch KOH 1M. Sau phn ng thu c mt mui v anehit. CTCT ca este l: A. HCOOCH=CH-CH3 B. CH3COOCH= CH2 C. C2H5COOCH=CH2 D. A, B u ng Cu 43: X l este ca mt axit hu c n chc v ru n chC. thu phn hon ton 6,6 g cht X ngi ta dng 34,1 ml dung dch NaOH 10 % ( d = 1,1 g/ml) ( lng NaOH d 25% so vi lng NaOH cn dng cho phn ng). CTCT ca X l: A. CH3COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. c B, C u ng Cu 44: Cho hn hp X gm 2 este c cng thc phn t l C4H8O2 v C3H6O2 tc dng vi dung dch NaOH d thu c 6,14 g hn hp 2 mui v 3,68 g ancol B duy nht c t khi hi so vi oxi l 1,4375. Khi lng mi este trong hn hp X ln lt l: A. 2,22 g v 4,4 g B. 3,33 g v 6,6 g C. 4,44 g v 8,8 g D. 5,6 g v 11,2 g Cu 45: Cho 4,4 g cht X tc dng va vi 50 ml dung dchNaOH 1M th to ra 4,8 g mui. X c CTCT l: A. C2H5COOCH3 B. CH3COOCH3 C. C2H5COOC2H5 D. HCOOC3H7 Cu 46: Thy phn 4,3 g este X n chc, mch h (c xc tc axit) n kh phn ng hon ton thu c hn hp 2 andehit .Cho Yv Z phn ng trng gng thu c 21,6 g Ag. CTCT ca X l: A. CH3COOCH=CH2 B. HCOOCH=CH-CH3 C. HCOOCH2CH=CH2 D. HCOOC(CH3)=CH2 Cu 47: un nng 0,01 mol mt cht Y vi dung dch NaOH d thu c 1,34 g mui ca mt axit hu c Z v 0,92 g ancol n chc. Nu cho ancol bay hi th chim th tch l 0,448 lt (ktc). Y c CTCT l: A. (COOC2H5)2 B. CH2(COOCH3)2 C. CH3COOC2H5 D. CH3COOC3H7 Cu 48:A l C3H6O2, B l C2H4O2 tc dng va vi dung dch NaOH thu c 1 mui v 1 ancol. A, B l: A. A l axit, B l este B. A l este, B l axit C. A, B u l este D. A, B u l axit Cu 49: t chy hon ton 1 mol este no, n chc, mch h X cn 3,5 mol O2. CTCT ca X l: A. CH3COOCH3 B. HCOOCH3 C. CH3COOCH2CH3 D. CH3CH2COOCH3 Cu 50: t chy hon ton 0,09 g este n chc Y thu c 0,132 g CO2 v 0,054 g H2O. CTPT ca Y l A.C2H4O2 B. C3H6O2 C. CH2O2 D. C4H8O2 Cu 51: t chy hon ton 0,2 mol este X ri dn sn phm chy vo dung dch Ca(OH)2 d thu c 40 g kt ta. X c CTPT l: A. HCOOC2H5 B. CH3COOCH3 C. HCOOCH3 D. Khng xc nh c Cu 52: t chy hon ton 3 g este X thu c 2,24 lt CO2 (ktc) v 1,8 g nc. CTPT ca este X l: A. C2H4O2 B. C3H6O2 C. C4H8O2 D. Kt qu khc Cu 53: t chy a g mt este, sau phn ng thu c 9,408 lt CO2 (ktc) v 7,56 g noc. Th tch kh oxi cn dng l 11,76 lt (ktc). CTPT ca este l: A. C4H8O2 B. C3H6O2 C. C2H4O2 D. C5H10O2 Cu 54: t chy a gam mt este sau phn ng thu c 9,408 lt CO2 v 7,56g H2O, th tch oxi cn dng l 11,76 lt (th tch cc kh o ktc). Bit este ny do mt axit n chc v ru n chc to nn. Cho bit cng thc phn t ca este: A.C4H8O2 B. C3H6O2 C. C2H4O2 D. C5H10O2 Cu 55: Hn hp gm mt ancol n chc v mt axit n chc b este ho hon ton thu c mt este. t chy hon ton 0,11 g este ny th thu c 0,22 g CO2 v 0,09 g nc. Vy CTPT ca ancol v axit l: A. CH4O v C2H4O2 B. C2H6O v C2H4O2 C. C2H6O v CH2O2 D. C2H6O v C3H6O2 Cu 56: t chy 1,7 gam este X cn 2,52 lt oxi (ktc), ch sinh ra CO2 v H2O vi t l s mol nCO2 : nH2O = 2. un nng 0,01 mol X vi dung dch NaOH thy 0,02 mol NaOH tham gia phn ng. X khng c chc ete, khng phn ng vi Na trong iu kin bnh thng v khng kh c AgNO3, trong amoniac ngay c khi un nng. Bit Mx < 140 vC. Hy xc nh cng thc cu to ca X? A. HCOOC6H5 B. CH3COOC6H5 C. C2H5COOC6H5 D. C2H3COOC6H5 Cu 57: t chy hon ton mt lng hn hp 2 este, cho sn phm phn ng chy qua bnh ng P2O5 d, khi lng bnh tng thm 6,21 gam, sau cho qua tip dung dch Ca(OH)2 d, thu c 34,5 gam kt ta. Cc este

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trn thuc loi g? A. Este no, a chc B. Este khng no, n chc C. Este no, n chc D. Este khng no, a chc Cu 58: t chy hon ton 3,225 g hn hp 2 este ng phn X v Y ta thu c 3,36 lt kh CO2 (ktc) v 2,7 g nC. X, Y c cng thc cu to l: A. CH2= CH- COOCH3 v HCOOCH2- CH= CH2 B. CH3COOCH3 v CH3COOCH2- CH= CH2 C. CH2=CH- COOCH3 v CH3COOCH2CH= CH2 D. Kt qu khc Cu 59: C hai este l ng phn ca nhau v u do cc axit no mt ln v ru no mt ln to thnh. x phng ha 22,2 gam hn hp hai este ni trn phi dng ht 12 gam NaOH nguyn cht. Cc mui sinh ra sau khi x phng ha c sy n khan v cn c 21,8 gam (gi thit l hiu sut phn ng t 100%). Cho bit cng thc cu to ca hai este? A. CH3COOC2H5 v C2H5COOCH3 B. HCOO C2H5 v CH3COO CH3 C. C3H7COO CH3 v CH3COOC3H7 D. A,B,C u sai. Cu 60: Hn hp Y gm hai este n chc mch h l ng phn ca nhau. Cho m gam hn hp Y tc dng va vi 100ml dung dch NaOH 0,5M, thu c mt mui ca mt axit cacboxylic v hn hp hai ru. Mt khc t chy hon ton m gam hn hp Y cn dng 5,6 lt O2 v thu c 4,48 lt CO2 (cc th tch kh o iu kin tiu chun). Cng thc cu to ca 2 este trong hn hp Y l: A.CH3COOCH3 v HCOOC2H5 B.CH3COOCH3 v CH3COOC2H5 C.C2H5COOCH3 v HCOOCH3 D. p n khc. Cu 61: Hn hp A gm 2 este l ng phn ca nhau v u to thnh t cc axit n chc v ru n chc khc nhau. Cho 2,2 gam hn hp A bay hi 136,50C v 1 atm th thu c 840 ml este. Mt khc em thy phn hon ton 26,4 gam hn hp A bng dung dch NaOH ri em c cn th thu c 21,8 gam cht rn khan. Cng thc cu to 2 este l: A. HCOOC3H7 v CH3COO C2H5 B.HCOOC3H7 v C2H5COOCH3 C. Cp A v Cp B D.p n khc Cu 62: X l hn hp hai este ng phn c to thnh t mt ru n chc, mch cacbon khng phn nhnh vi axit n chc. T khi hi ca X so vi hiro bng 44. Cng thc phn t ca X l: A. C3H6O2 B. C4H8O2 C. C5H10O2 D. C6H12O2 Cu 63: t chy hon ton 6,7 gam hh hai este no, n chc l ng ng k tip nhau ,thu c 5,6 lt CO2 (ktc). CTPT hai este l: A. C2H4O2 v C3H6O2 B. C4H8O2 v C3H6O2 C. C4H8O2 v C5H10O2 D. Tt c u ng Cu 64: Thu phn ht 13,4 gam hh hai este no, n chc cn va 200 ml dd NaOH 1M, thu c mt mui natri ca axit hu c v hh hai ancol ng ng k tip. CTPT hai este l A. C2H4O2 v C3H6O2 B. C4H8O2 v C3H6O2 C. C4H8O2 v C5H10O2 D. Khng xc nh c CTPT Cu 65: Ho hi ht 8,375 gam hh hai este ng ng k tip thu c th tch ng bng th tch ca 4 gam Oxi cng iu kin nhit , p sut. CTPT hai este l A. C2H4O2 v C3H6O2 B. C4H8O2 v C5H10O2 C. C4H8O2 v C3H6O2 D. C2H4O2 v C5H10O2 Cu 66: Chia m gam hh hai este no, n chc thnh hai phn bng nhau.Thu phn ht phn mt cn va 200 ml dd NaOH 1M. t chy ht phn hai , thu c 11,2 lt CO2 (ktc). CTPT hai este l A. C2H4O2 v C3H6O2 B. C3H6O2 v C4H8O2 . C. C4H8O2 v C5H10O2 D. C6H12O2 v C5H10O2 Cu 67: t chy ht 1,62 gam hh hai este n chc , no ng ng k tip cn va 1,904 lt Oxi (ktc). CTPT hai este l. A. C2H4O2 v C3H6O2 B. C4H8O2 v C5H10O2 C. C4H8O2 v C3H6O2 D. C2H4O2 v C5H10O2 Cu 68: Thu phn hon ton 26,8 gam hh hai este no, n chc cn va 200 ml dd NaOH 2M, thu c m gam mt mui natri ca axit hu c v hh hai ancol ng ng k tip. t chy ht hh ancol , thu c 13,44 lt CO2 (ktc). CTPT hai este l A. C2H4O2 v C3H6O2 B. C3H6O2 v C4H8O2 C. C4H8O2 v C5H10O2 D. C6H12O2 v C5H10O2 Cu 69: phn bit cc este sau: vinyl axetat(CH3COO-CH=CH2), ankyl fomiat(HCOOCnH2n+1), metyl acrylat (CH2=CH-COOCH3) ta c th tin hnh theo trnh t sau: A. dung dch NaOH, un nh, dung dch Br2, dung dch axit H2SO4 long B. dung dch NaOH, dung dch AgNO3/NH3, dung dch Br2, C. dung dch AgNO3/NH3, dung dch Br2, dung dch axit H2SO4 long D. dung dch Br2 , dung dch H2SO4 , dd AgNO3/NH3 Cu 70: un 12 g axit axetic vi mt lng d ancol etylic ( H2SO4 c, xc tc). n khi phn ng t trng thI cn bng th thu c 11g este. Hiu sut phn ng este ho l: A. 70% B. 75% C. 62,5% D. 50% Cu 71: Tnh khi lng este metyl metacrylat thu c khi un nng 215 g axit metaacrylic vi 100 g ancol metylic. Gi s hiu sut phn ng l 60%. A. 125 g B. 175 g C. 150 g D. 200 g

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Cu 72: un axit oxalic vi hn hp gm ancol n-propinic v ancol iso propylic cso mt cht xc tc H2SO4 c th thu c ti a bao nhiu este? A. 2 B. 3 C. 4 D. 5 Cu 73: t chy hon ton a g C2H5OH thu c 0,2 mol CO2. t chy hon ton b g CH3COOH thu c 0,2 mol CO2. Cho a g C2H5OH tc dng vi b g CH3COOH ( c xc tc). gi s hiu sut phn ng l 100% th thu c m g este. m c gi tr l: A. 6,8 B. 8,8 C. 7,8 D. 10,8 Cu 74: Kt lun no sau y sai: A.Este si nhit thp hn axit tng ng B.Este thng t tan trong nc C.Phn ng thu phn este thng xy ra nhanh D. tng tc phn ng este ho cn tng tc ca axit hoc ru Cu 75: Mt hn hp gm hai este u n chc, c 3 nguyn t C, H, O. Ly 0,25 mol hai este ny phn ng vi 175ml dung dch NaOH 2M un nng th thu c mt anehit no mch h v 28,6 gam hai mui hu c. Cho bit khi lng mui ny bng 1,4655 ln khi lng mui kia. Phn trm khi lng ca oxi trong anehit l 27,58%. Xc nh cng thc cu to ca hai este. A. CH3COOCH=CH2 v HCOOC6H5 B. HCOOCH-CH2 v CH3COOC6H5 C. HCOOCH=CH-CH3 v HCOOC6H5 D. HCOOCH=CH-CH2-CH3 v CH3COOC6H5 Cu 76: t chy hon ton 0,1 mol este X thu c 0,3 mol CO2 v 0,3 mol H2O. Nu cho 0,1 mol X tc dng ht vi dung dch NaOH th thu c 8,2 g mui. X c CTCT l: A. CH3COOCH3 B. HCOOCH3 C. CH3COOC2H5 D. HCOOC2H5 Cu 77: Oxi ho 1,02 g cht Y thu c 2,2 g CO2 v 0,9 g nc. T khi hi ca Y so vi khng kh bng 3,52. Cho 5,1 g Y tc dng vi dung dch NaOH d thu c 4,8 g mui v mt ancol. Y c CTCT l: A. CH3COOC2H5 B. HCOOC2H5 C. C3H7COOC2H5 D. C2H5COOC2H5 Cu 78: (TN BT2007):Este etyl axetat c cng thc l : A. CH3COOC2H5. B. CH3COOH. C. CH3CHO. D. CH3CH2OH. Cu 79: (TN KPB2007): Thy phn este X trong mi trng kim, thu c natri axetat v ru etylic. Cng thc ca X l A. C2H3COOC2H5. B. C2H5COOCH3. C. CH3COOC2H5. D. CH3COOCH3. Cu 80: (TN PB2007): Khi x phng ha tristearin ta thu c sn phm l A. C15H31COONa v etanol. B. C17H35COOH v glixerol. C. C15H31COOH v glixerol. D. C17H35COONa v glixerol. Cu 81: (TN BT2008): un nng este CH3COOC2H5 vi mt lng va dung dch NaOH, sn phm thu c l A. CH3COONa v CH3OH. B. CH3COONa v C2H5OH. C. HCOONa v C2H5OH. D. C2H5COONa v CH3OH. Cu 82: (TN KPB2008): un nng este HCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l A. CH3COONa v C2H5OH. B. HCOONa v CH3OH. C. HCOONa v C2H5OH. D. CH3COONa v CH3OH. Cu 83: (CD A2007) Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (Cho H = 1; C = 12; O =16; Na = 23) A. etyl propionat. B. metyl propionat. C. isopropyl axetat. D. etyl axetat. Cu 84: (CD A2007) Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A.C2H5COO-CH=CH2. B. CH2=CH-COO-C2H5. C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3. Cu 85: (CD A2007) Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH=CH2. B. CH3COOCH=CH2. C. HCOOCH3. D. CH3COOCH=CHCH3. Cu 86: (CD A2007) S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l : A. 5. B. 3. C. 6. D. 4. Cu 87: (CD A2007) Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? A. 2. B. 5. C. 3. D. 4. Cu 88: (CD A2007) un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16) A. 55%. B. 50%. C. 62,5%. D. 75%.

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Cu 89: (CD B2007) Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (Cho H = 1; C = 12; O =16; Na = 23) A. isopropyl axetat. B. etyl propionat. C. metyl propionat. D. etyl axetat. Cu 90: (DH A2007) Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c etanal(andehit). Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2. Cu 91: (DH B2007) X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1, C =12, O = 16, Na = 23) A. HCOOCH(CH3)2. B. CH3COOC2H5. C. C2H5COOCH3. D. HCOOCH2CH2CH3. Cu 92: (DH B2007) Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y A. HCOOCH2CH2CH3 v CH3COOC2H5. B. C2H5COOCH3 v HCOOCH(CH3)2. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOC2H5 v CH3COOCH3. Cu 93: (DH B2007) Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l : A. 3. B. 5. C. 6. D. 4. Cu 94: (DH B2007) Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru etyliC. B. axit fomic. C. ru metylic. D. etyl axetat. Cu 95: CD A2008) Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 27,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-CH2-COO-CH3. B. CH2=CH-COO-CH2-CH3. C. CH3 -COO-CH=CH-CH3. D. CH3-CH2-COO-CH=CH2. Cu 96: CD A2008) X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 400 ml. B. 300 ml. C. 150 ml. D. 200 ml. Cu 97: CD A2008) Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng NA. Cng thc cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. Cu 98: DH B2008) X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l : A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Cu 99: DH B2008) Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l: A. metyl fomiat. B. etyl axetat. C. n-propyl axetat. D. metyl axetat. Cu 100:Cho 12,2 g A c CTPT l C7H6O2 mnh h p vi 0,2 mol KOH . Thy p xy ra va . Sn phm s c mui. A.HCOOK B.C2H5COOK C.CH3COOK D.C7H5O2K Cu 101:Este c CTPT C4H6O2 c gc ru l metyl(CH3-) th axit to este l: A.HCOOH B.C2H5COOH C.CH3COOH D.CH2=CH-COOH Cu 102:Cho 20g X p vi 0,3 mol NaOH. Sau p thu c 22,8g rn. CTPT ca X l A.CH3-COO CH = CH-CH3 B.CH2=CH-COO-CH2-CH3 C.CH3-CH=CH-COO-CH3 D.C2H5-COO-CH=CH2 Cu 103:Cho 0,12 mol este n p ht vi NaOH => 11,52 g mui. CTCT ca X l A.CH3-COO-CH=CH-CH3 B.CH2=CH-COO-CH2-CH3 C.CH3-CH=CH-COO-CH3 D.CH3-CH2 COO-CH2 = CH Cu 104: Cho 0,1 mol glixerin (C3H5(OH)3) p vi 0,15 mol axit acrylic (CH2 = CHCOOH) c H2SO4 c vi Hiu sut l 60% thu c m g este B(ko cha chc #). m c gi tr l A.7,62g B.15,24g C.21,167g D.9,62g Cu 105:Cho 0,1 mol glixerin (C3H5(OH)3) p vi 0,15 mol axit acrylic (CH2 = CHCOOH) c H2SO4 c vi Hiu sut l 60% thu c m g este B(Cha chc khc, bi thng khng ghi g) . m c gi tr l . A.9,72g B.8,16g C.7,92g D.6,56g

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Cu 106:Cho 0,1 mol C3H5(OH)3 p vi Axit n chc c H2SO4 (H% = 60%) . Thu c 7,92g este B. CTCT ca este l : A.HCOOH B.CH3COOH D.C2H5COOH D.CH2=CH-COOH

CHUYN 9: CACBOHIDRAT
Cu 1: Thy phn 1 kg sn cha 20% tinh bt trong mi trng axit. Vi hiu sut phn ng 85%. Lng glucoz thu c l A. 261,43 g. B. 200,8 g. C. 188,89 g. D. 192,5 g. Cu 2: Cho m g tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO 2 sinh ra c hp th hon ton vo dd Ca(OH)2, thu c 550 g kt ta v dd X. un k dd X thu thm c 100 g kt ta. Gi tr ca m l A. 650. B. 550. C. 810. D. 750. Cu 3: Th tch dd HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 70 lt. B. 49 lt. C. 81 lt. D. 55 lt. Cu 4: Ln men m g glucoz vi hiu sut 90%. Lng CO2 sinh ra c hp th vo dd Ca(OH)2 thu c 10 g kt ta v khi lng dd gim 3,4 g. Gi tr ca m l A. 30. B. 15. C. 17. D. 34. Cu 5: Thy phn hon ton 62,5 g dd saccaroz 17,1% trong mi trng axit (va ) c dd X. Cho dd AgNO3/NH3 vo X un nh c m g Ag. Gi tr ca m l A. 6,75. B. 13,5. C. 10,8. D. 7,5. Cu 6: Cho 34,2 g hn hp saccaroz c ln mantoz phn ng hon ton dd AgNO3/NH3 d thu c 0,216 g bc. tinh khit ca saccaroz l A. 1%. B. 99%. C. 90%. D. 10%. Cu 7: Kh cacbonic chim t l 0,03% th tch khng kh. Mun to ra 500g tinh bt th cn bao nhiu lt khng kh ( ktc) cung cp CO2 cho phn ng quang hp? A. 1382716 lt. B. 1382600 lt. C. 1402666,7 lt. D. 1382766 lt. Cu 8: Cho xenluloz phn ng vi anhirit axetic (C H2SO4 c lm xc tc) thu c 11,1g hn hp X gm xenluloz triaxetat, xenluloz iaxetat v 6,6g CH3COOH. Thnh phn phn trm theo khi lng ca xenluloz triaxetat v xenluloz iaxetat trong X ln lt l A. 77% v 23%. B. 77,84% v 22,16%. C. 76,84% v 23,16%. D. 70% v 30%. Cu 9: Ln men m g glucoz vi hiu sut 72%. Lng CO2 sinh ra c hp th hon ton vo 500 ml dd hn hp gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra 9,85 g kt ta. Gi tr ca m l A. 25,00. B. 12,96. C. 6,25. D. 13,00. Cu 10: Thy phn 324 g tinh bt vi hiu sut ca phn ng l 75%, khi lng glucoz thu c l A. 360 g. B. 270 g. C. 250 g. D. 300 g. Cu 11: Cho 360 g glucoz ln men thnh ancol etylic v cho ton b kh CO 2 sinh ra hp th vo dd NaOH d c 318 g mui. Hiu sut phn ng ln men l A. 50,0%. B. 62,5%. C. 75,0%. D. 80,0%. Cu 12: Cho m g glucoz v fructoz tc dng vi lng d dd AgNO3/NH3 to ra 43,2 g Ag. Cng m g hn hp ny tc dng va ht vi 8 g Br2 trong dd. S mol glucoz v fructoz trong hn hp ny ln lt l A. 0,05 mol v 0,15 mol. B. 0,10 mol v 0,15 mol. C. 0,2 mol v 0,2 mol. D. 0,05 mol v 0,35 mol. Cu 13: c 29,7 kg xenluloz trinitrat, cn dng dd cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l A. 30. B. 10. C. 21. D. 42. m H2O :m CO2 = 33 : 88. CTPT ca X l Cu 14: Khi t chy mt cacbohrat X c A. C6H12O6. B. C12H22O11. C. (C6H10O5)n. D. Cn(H2O)m. Cu 15: Phn ng no sau y chng t glucoz c cu to mch vng? A. Phn ng CH3OH/HCl. B. Phn ng vi Cu(OH)2.

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C. Phn ng vi dd AgNO3 / NH3. D. Phn ng H2/Ni,t0. Cu 16: Phn ng vi cht no sau y c th chuyn ho glucoz, fructoz thnh nhng sn phm ging nhau? A. Phn ng H2 /Ni, t0. B. Phn ng vi Cu(OH)2. C. Dd AgNO3. D. Phn ng vi Na. Cu 17: Chn cu ni ng A. Xenluloz c phn t khi ln hn nhiu so vi tinh bt. B. Xenluloz v tinh bt c phn t khi nh. C. Xenluloz c phn t khi nh hn tinh bt. D. Xenluloz v tinh bt c phn t khi bng nhau. Cu 18: Da vo tnh cht no kt lun tinh bt v xenluloz l nhng polime thin nhin c cng thc (C6H10O5)n: A. Tinh bt v xenluloz khi b t chy u cho CO2 v H2O theo t l s mol 6:5. B. Tinh bt v xenluloz khi b thu phn n cng u cho glucoz. C. Tinh bt v xenluloz u tan trong nc. D. Tinh bt v xenluloz u c th lm thc n cho ngi v gia sc. Cu 19: Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l A. tinh bt. B. saccaroz. C. xenluloz. D. protit. Cu 20: Khi thu phn saccaroz, sn phm thu c l A. glucoz v fructoz. B. ch c glucoz. C. ch c fructoz. D. ch c mantoz. Cu 21: Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. tinh bt. B. xenluloz. C. saccaroz. D. mantoz. Cu 22: C th phn bit xenluloz vi tinh bt nh phn ng A. vi axit H2SO4. B. vi kim. C. vi dd it. D. thu phn. Cu 23: Mt cacbohirat (Z) c cc phn ng din ra theo s chuyn ha sau: Cu(OH) /NaOH t0 Z 2 dd xanh lam kt ta gch Vy Z khng th l A. glucoz. B. saccaroz. C. fructoz. D. Tt c u sai. Cu 24: Nhm cc cht u tham gia phn ng trng bc v phn ng kh Cu(OH)2 thnh Cu2O l A. glucoz v mantoz. B. glucoz v xenluloz. C. glucoz v saccaroz. D. saccaroz v mantoz. Cu 25: Cho cc dd sau: CH3COOH, C2H4(OH)2, C3H5(OH)3, glucoz, saccaroz, C2H5OH. S lng dd c th ho tan c Cu(OH)2 l A. 4. B. 5. C. 6. D. 3. Cu 26: Dy cht m tt c cc cht u tc dng c vi dd AgNO3/NH3 l A. CH3CHO, C2H2, saccaroz. B. CH3CHO, C2H2, anilin. C. CH3CHO, C2H2, saccaroz, glucoz. D. HCOOH, CH3CHO, C2H2, glucoz. Cu 27: Cho khi lng ring ca cn nguyn cht l D = 0,8 g/ml. Hi t 10 tn v bo (cha 80% xenluloz) c th iu ch c bao nhiu lt cn thc phm 40 (bit hiu sut ca ton b qu trnh iu ch l 64,8%)? A. 294 lt. B. 920 lt. C. 368 lt. D. 147,2 lt. Cu 28: Xenluloz tc dng vi (CH3CO)2O (xc tc H2SO4 c) to ra 9,84 g este axetat v 4,8 g CH3COOH. CTPT ca este axetat l A. [C6H7O2(OOCCH3)3]n. B. [C6H7O2(OOCCH3)2OH]n. C. [C6H7O2(OOCCH3)(OH)2]n. D. [C6H7O2(OOCCH3)3]n v [C6H7O2(OOCCH3)OH]n. Cu 29: Cho 10 kg glucoz cha 10% tp cht ln men thnh ancol. Tnh th tch ancol 46 thu c. Bit ancol nguyn cht c khi lng ring 0,8 g/ml v trong qu trnh ch bin ancol b hao ht mt 5%. A. 11,875 lt. B. 2,785 lt. C. 2,185 lt. D. 3,875 lt.
Cu 30: Trong phn t ca cacbohyrat lun c A. nhm chc axit. B. nhm chc xeton. Cu 31: Cht thuc loi isaccarit l A. glucoz. B. saccaroz. C. nhm chc ancol. C. xenluloz. D. nhm chc anehit. D. fructoz.

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Cu 32: Hai cht ng phn ca nhau l A. glucoz v mantoz. B. fructoz v glucoz. C. fructoz v mantoz. Cu 33: Tm t thch hp in vo ch trng trong on vn sau: D. saccaroz v glucoz.

dng mch h glucoz v fructoz u c nhm cacbonyl, nhng trong phn t glucoz nhm cacbonyl nguyn t C s , cn trong phn t fructoz nhm cacbonyl nguyn t C s. Trong mi trng baz, fructoz c th chuyn ho thnh v A. 1, 2, glucoz, ngc li. B. 2, 2, glucoz, ngc li. C. 2, 1, glucoz, ngc li. D. 1, 2, glucoz, mantoz. Cu 34: Cacbohirat l g? A. Cacbohirat l nhng hp cht hu c a chc v a s chng c cng thc chung l Cn(H2O)m. B. Cacbohirat l nhng hp cht hu c tp chc v a s chng c cng thc chung l Cn(H2O)m. C. Cacbohirat l nhng hp cht hu c tp chc. D. Cacbohirat l nhng hp cht hu c a chc v a s chng c cng thc chung l Cn(H2O)n. Cu 35: C my loi cacbohirat quan trng? A. 1 loi. B. 2 loi. C. 3 loi. D. 4 loi. Cu 36: Nhng th nghim no chng minh c cu to phn t ca glucoz? A. phn ng vi Na v vi dung dch AgNO3 trong amoniac. B. phn ng vi NaOH v vi dung dch AgNO3 trong amoniac. C. phn ng vi CuO v vi dung dch AgNO3 trong amoniac. D. phn ng vi Cu(OH)2 v vi dung dch AgNO3 trong amoniac. Cu 37: trng bc mt chic gng soi, ngi ta phi un nng dung dch cha 36g glucoz vi lng va dung dch AgNO3 trong amoniac. Khi lng bc sinh ra bm vo mt knh ca gng v khi lng AgNO3 cn dng ln lt l (bit cc phn ng xy ra hon ton) A. 68,0g; 43,2g. B. 21,6g; 68,0g. C. 43,2g; 68,0g. D. 43,2g; 34,0g. Cu 38: Phng n no di y c th phn bit c saccaroz, tinh bt v xenluloz dng bt? A. Cho tng cht tc dng vi dung dch HNO3/H2SO4. B. Cho tng cht tc dng vi dung dch iot. C. Ho tan tng cht vo nc, sau un nng v th vi dung dch iot. D. Cho tng cht tc dng vi vi sa Ca(OH)2. Cu 39: phn bit cc dung dch glucoz, saccaroz v anehit axetic c th dng cht no trong cc cht sau lm thuc th ? A. Cu(OH)2/OH . B. NaOH. C. HNO3. D. AgNO3/NH3. C bn l mt nhn cha: Glixerol, ancol etylic, glucoz v axit axetic. Thuc th no sau y c th dng phn bit cc dung dch trong tng l trn ? A. [Ag(NH3)2]OH. B. Na kim loi. C. Cu(OH)2 trong mi trng kim. D. Nc brom. phn bit cc cht: Glucoz, glixerol, anehit axetic, lng trng trng v ru etylic, c th ch dng mt thuc th no sau y? A. dung dch HNO3. B. Cu(OH)2/OH . C. dung dch AgNO3/NH3. D. dung dch brom. Cu 40: Chn cch phn bit cc dung dch sau y: Lng trng trng, h tinh bt, glixerol. A. Iot lm h tinh bt ho xanh, glixerol tc dng vi Cu(OH)2 nhit thng to dung dch xanh lam c trng, cn li lng trng trng. B. Glixerol tc dng Cu(OH)2 nhit thng to dung dch xanh lam c trng, lng trng trng tc dng Cu(OH)2 cho mu xanh tm, cn li h tinh bt. C. Iot lm h tinh bt ho xanh, khi un nng lng trng trng ng t, cn li glixerol.

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D. C B, C u ng. Cu 41: C 4 dung dch long khng mu gm: Lng trng trng, glixerol, KOH v axit axetic. Ch dng mt thuc th no sau y phn bit chng. A. dung dch HCl. B. dung dch CuSO4. C. dung dch KMnO4. D. dung dch HNO3 c. Cu 42: Chn cu pht biu sai: A. Saccaroz l mt isaccarit. B. Tinh bt v xenluloz u l polisaccarit, ch khc nhau v cu to ca gc glucoz. C. Khi thu phn n cng saccaroz, tinh bt v xenluloz u cho mt loi monosaccarit. D. Khi thu phn n cng, tinh bt v xenluloz u cho glucoz. Cu 43: Cng l cht rn kt tinh, khng mu, khng mi, d tan trong nc, c v ngt l tnh cht vt l v trng thi t nhin ca nhm cht no sau y? A. glucoz v saccaroz. B. glucoz v tinh bt. C. glucoz v xenluloz. D. saccaroz v tinh bt. Cu 44: Cho cc cht glucoz, fructoz, saccaroz, tinh bt, xenluloz. Cht va c tnh cht ca ancol a chc, va c tnh cht ca anehit l A. ch c glucoz. B. glucoz v fructoz. C. glucoz, fructoz v saccaroz. D. tt c cc cht cho. Cu 45: trng bc mt s rut phch, ngi ta phi dng 100g saccaroz. Khi lng AgNO 3 cn dng v khi lng Ag to ra ln lt l (gi thit rng, s chuyn ho ca fructoz l khng ng k v hiu sut cc phn ng u t 90%) A. 88,74g; 50,74g. B. 102,0g; 52,5g. C. 52,5g; 91,8g. D. 91,8g; 64,8g. Cu 46: Khi t chy hon ton mt hp cht hu c thu c hn hp kh CO 2 v hi nc c t l mol l 1:1. Cht ny c th ln men ru (ancol). Cht l cht no trong cc cht sau ? A. axit axetic. B. glucoz. a. C. sacacroz. D. hex-3-en. Cu 47: Khi thu phn 1kg bt go c 80% tinh bt, th khi lng glucoz thu c l bao nhiu ? Gi thit rng, phn ng xy ra hon ton. A. 0,80kg. B. 0,90kg. C. 0,99kg. D. 0,89kg. Cu 48: Tnh khi lng glucoz to thnh khi thu phn 1kg mn ca c 50% xenluloz. Gi thit hiu sut phn ng l 80%. A. 0,555kg. B. 0,444kg. C. 0,500kg. D. 0,690kg. Cu 49: Nhm gluxit u tham gia phn ng thu phn l A. Saccaroz, mantoz, glucoz. B. Saccaroz, fructoz, xenluloz. C. Mantoz, tinh bt, xenluloz. D. Saccaroz, glucoz, tinh bt. Cu 50: Nhm gluxit u c kh nng tham gia phn ng trng gng l A. Glucoz, fructoz, saccaroz. B. Glucoz, fructoz, tinh bt. C. Glucoz, fructoz, xenluloz. D. Glucoz, fructoz, mantoz. Cho glucoz ln men to thnh ancol, kh CO2 to thnh c dn qua dung dch nc vi trong d, thu c 50g kt ta, bit hiu sut ln men l 80%, khi lng ancol thu c l A. 23,0g. B. 18,4g. C. 27,6g. D. 28,0g. Chn s phn ng ng ca glucoz

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A. C6H12O6 + Cu(OH)2 kt ta gch n B. C6H12O6 m e CH3CH(OH)COOH C. C6H12O6 + CuO Dung dch mu xanh n D. C6H12O6 me C2H5OH + O2 Nhm gluxit khi thu phn hon ton u ch to thnh glucoz l: A. Saccaroz, mantoz, tinh bt. B. Saccaroz, mantoz, xenluloz. C. Mantoz, tinh bt, xenluloz. D. Saccaroz, mantoz, tinh bt, xenluloz. Pht biu no sau y khng ng ? A. Glucoz v fructoz l ng phn cu to ca nhau. B. Metyl - glucozit khng th chuyn sang dng mch h. C. Trong dung dch, glucoz tn ti dng mch vng u tin hn dng mch h. D. C th phn bit glucoz v fructoz bng phn ng trng bc. Bit CO2 chim 0,03% th tch khng kh, th tch khng kh (ktc) cn cung cp cho cy xanh quang hp to 162g tinh bt l A. 112.103 lt. B. 448.103 lt. C. 336.103 lt. D. 224.103 lt. Glucoz tc dng c vi tt c cht trong nhm cht no sau y? A. H2/Ni , nhit ; Cu(OH)2; [Ag(NH3)2]OH; H2O/H+, nhit . B. [Ag(NH3)2]OH; Cu(OH)2; H2/Ni, un nng; CH3COOH/H2SO4 c, un nng. C. H2/Ni , nhit ; [Ag(NH3)2]OH; NaOH; Cu(OH)2. D. H2/Ni , nhit ; [Ag(NH3)2]OH; Na2CO3; Cu(OH)2. Cu 51: Chn cu pht biu sai: A. Phn bit glucoz v saccaroz bng phn ng trng gng. B. Phn bit mantoz v saccaroz bng phn ng trng gng. C. Phn bit tinh bt v xenluloz bng I2. D. Phn bit saccaroz v glixerol bng Cu(OH)2. Cu 52: Chn cu pht biu ng: A. Phn bit glucoz v fructoz bng phn ng trng gng. B. Tinh bt c cu trc phn t mch khng phn nhnh. C. Dung dch mantoz c tnh kh v b thu phn thnh glucoz. D. Phn bit saccaroz v glixerol bng phn ng thu phn.
asmt Cu 53: Phng trnh: 6nCO2 + 5nH2O (C6H10O5)n + 6nO2, l phn ng ho hc chnh ca Clorofin

qu trnh no sau y? A. qu trnh h hp. B. qu trnh quang hp. C. qu trnh kh. D. qu trnh oxi ho. Cu 54: Cho s phn ng: Thuc sng khng khi X Y sobit. Tn gi X, Y ln lt l A. xenluloz, glucoz. B. tinh bt, etanol. C. mantoz, etanol. D. saccaroz, etanol. Cu 55: Phn ng kh glucoz l phn ng no sau y ? A. Glucoz + H2/Ni , to. B. Glucoz + Cu(OH)2. men C. Glucoz + [Ag(NH3)2]OH. D. Glucoz etanol.

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Cu 56: iu ch 45g axit lactic t tinh bt v qua con ng ln men lactic, hiu sut thu phn tinh

bt v ln men lactic tng ng l 90% v 80%. Khi lng tinh bt cn dng l A. 50g. B. 56,25g. C. 56g. D. 60g. Cu 57: Phn ng chuyn glucoz, fructoz thnh nhng sn phm ging nhau l A. phn ng vi Cu(OH)2. B. phn ng trng gng. o C. phn ng vi H2/Ni. t . D. phn ng vi kim loi Na. Cu 58: Thuc th phn bit glucoz vi fructoz l A. [Ag(NH3)2]OH. B. Cu(OH)2. C. dung dch Br2. D. H2. Cu 59: Cacbohirat (gluxit) l nhng hp cht hu c tp chc v c cng thc chung l A. Cn(H2O)m. B. C.nH2O. C. CxHyOz. D. R(OH)x(CHO)y. Cu 60: Cng thc phn t v cng thc cu to ca xenluloz ln lt l A. (C6H12O6)n, [C6H7O2(OH)3]n. B.(C6H10O5)n, [C6H7O2(OH)3]n. C. [C6H7O2(OH)3]n, (C6H10O5)n. D. (C6H10O5)n, [C6H7O2(OH)2]n. Cu 61: Mt polisaccarit (C6H10O5)n c khi lng phn t l 162000u, n c gi tr l A. 900. B. 950. C. 1000. D. 1500. Cu 62: Gluxit khng th thu phn c na l A. Glucoz, mantoz. B. Glucoz, tinh bt. C. Glucoz, xenluloz. D. Glucoz, fructoz. Cu 63: Cacbohirat khi thu phn to ra 2 phn t monosaccarit l A. Saccaroz, tinh bt. B. saccaroz, xenluloz. C. Mantoz, saccaroz. D.Saccaroz, glucoz. Cu 64: Saccaroz v glucoz c c im ging nhau l A. u ly t c ci ng. B. u tham gia phn ng trng gng. C. u ho tan Cu(OH)2 nhit thng to dung dch mu xanh c trng. D. u c trong bit dc huyt thanh ngt. Cu 65: Polisaccarit khi thu phn n cng to ra nhiu monosaccarit l A. Tinh bt, amiloz. B. Tinh bt, xenluloz. C. Xenluloz, amiloz. D. Xenluloz, amilopectin. Cu 66: Cht khng phn ng vi glucoz l A. [Ag(NH3)2]OH. B. Cu(OH)2. C. H2/Ni. D. I2. Cu 67: Trong mu ngi, nng ca glucoz c gi tr hu nh khng i l A. 0,1%. B. 0,2%. C. 0,3%. D. 0,4%. Cu 68: xc nh trong nc tiu ca ngi b bnh tiu ng c cha mt lng nh glucoz, c th dng 2 phn ng ho hc l A. phn ng trng gng, phn ng cng hiro. B. phn ng trng gng, phn ng ln men ru etylic. C. phn ng trng gng, phn ng kh Cu(OH)2.

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D. phn ng trng gng, phn ng thu phn. Cu 69: Sobit (sobitol) l sn phm ca phn ng A. kh glucoz bng H2/Ni, to. B. oxi ho glucoz bng [Ag(NH3)2]OH. C. ln men ru etylic. D. glucoz tc dng vi Cu(OH)2. Cu 70: Gluxit chuyn ho thnh glucoz trong mi trng kim l A. saccaroz. B. mantoz. C. fructoz. D. tinh bt. Cu 71: Tinh bt trong go np cha khong 98% l A. amiloz. B. amilopectin. C. glixerol. D. alanin. Cu 72: Phn ng chng t glucoz c nhiu nhm OH cc nguyn t cacbon lin tip nhau l phn ng vi A. dung dch AgNO3 trong dung dch NH3. B. Cu(OH)2 nhit thng. C. tc dng vi axit to este c 5 gc axit. D. Cu(OH)2 nhit cao. Cu 73: Phn ng chng minh glucoz c nhm chc anehit l A. tc dng vi Cu(OH)2 to dung dch c mu xanh c trng. B. tc dng vi axit to sobitol. C. phn ng ln men ru etylic. D. phn ng trng gng. Cu 74: Phn t glucoz tc dng vi Cu(OH)2 cho , vy trong phn t Tng t nh glucoz, cng vi hiro cho , b oxi ho bi trong mi trng baz. Cacbohirat l nhng v a s chng c cng thc chung l (1) dung dch mu xanh lam; (2) c nhiu nhm OH; (3) v tr k nhau; (4) fructoz; (5) poliancol; (6) phc bc amoniac; (7) hp cht hu c tp chc; (8) Cn(H2O)m. T hay cm t thch hp nhng ch trng trong cc cu on vn trn ln lt l A. (2), (3), (1), (4), (5), (6), (7), (8). B. (1), (2), (4), (5), (3), (6), (7), (8). C. (1), (2), (3), (4), (5), (6), (7), (8). D. (1), (2), (3), (4), (8), (6), (7), (5). Cu 75: Khi no bnh nhn c truyn trc tip dung dch glucoz (cn c gi vi bit danh huyt thanh ngt). A. Khi bnh nhn c lng glucoz trong mu > 0,1%. B. Khi bnh nhn c lng glucoz trong mu < 0,1%. C. Khi bnh nhn c lng glucoz trong mu = 0,1%. D. Khi bnh nhn c lng glucoz trong mu t 0,1% 0,2%. Cu 76: Phng php iu ch etanol no sau y ch dng trong phng th nghim ? A. Ln men glucoz. B. Thu phn dn xut etyl halogenua trong mi trng kim. C. Cho etilen tc dng vi dung dch H2SO4 long, nng. D. Cho hn hp etilen v hi nc qua thp cha H3PO4.

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Cu 77: Fructoz khng phn ng vi cht no sau y?

A. H2/Ni, to. B. Cu(OH)2. C. dung dch brom. D. AgNO3/NH3. Cu 78: Phn ng no sau y chng t glucoz c dng mch vng? A. phn ng vi Cu(OH)2. B. phn ng vi AgNO3/NH3. o C. phn ng vi H2/Ni, t . D. phn ng vi CH3OH/HCl. Cu 79: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng l 2813kJ cho mi mol glucoz to thnh. 6CO2 + 6H2O C6H12O6 + 6O2 Nu trong mt pht, mi cm2 l xanh nhn c khong 2,09J nng lng mt tri, nhng ch 10% c s dng vo phn ng tng hp glucoz. Vi mt ngy nng (t 6h00 17h00) din tch l xanh l 1m2, lng glucoz tng hp c bao nhiu? A. 88,26g. B. 88.32g. C. 90,26g. D. 90,32g. Cu 80: Cho 10kg glucoz cha 10% tp cht, ln men thnh ancol etylic. Trong qu trnh ch bin, ancol b hao ht 5%. Khi lng ancol etylic thu c bng bao nhiu? A. 4,65kg. B. 4,37kg. C. 6,84kg. D. 5,56kg. Cu 81: Ln men a g glucoz, cho ton b lng CO2 sinh ra hp th vo dung dch nc vi trong to thnh 10g kt ta. Khi lng dung dch so vi ban u gim 3,4g. Bit hiu sut ca qu trnh ln men l 90%, gi tr ca a l A. 12. B. 13. C. 14. D. 15. Cu 82: Cho 4 cht hu c X, Y, Z, T. Khi oxi ho hon ton tng cht u cho cng kt qu: C to ra 4,4g CO2 th km theo 1,8g H2O v cn mt th tch oxi va ng bng th tch CO2 thu c. T l phn t khi ca X, Y, Z, T ln lt l 6:1:3:2 v s nguyn t cacbon trong mi cht khng nhiu hn 6. Cng thc phn t ca X, Y, Z, T ln lt l A. C6H12O6, C3H6O3, CH2O, C2H4O2. B. C6H12O6, C3H6O3, C2H4O2, CH2O. C. C6H12O6, CH2O, C3H6O3, C2H4O2. D. C6H12O6, CH2O, C2H4O2, C3H6O3. Cu 83: Saccaroz u tc dng c vi nhm cht no sau y ? (1) H2/Ni, to; (2) Cu(OH)2; (3) [Ag(NH3)2]OH; (4) CH3COOH (H2SO4 c) A. (1), (2). B. (2), (4). C. (2), (3). D. (1), (4). Cu 84: Mt cacbohirat (Z) c cc phn ng din ra theo s chuyn ho sau Cu(OH)2/NaOH dung dch xanh lam to kt ta gch Z Vy Z khng th l A. glucoz. B. saccaroz. C. fructoz. D. mantoz. Cu 85: t chy hon ton 0,01 mol mt cacbohirat (X), thu c 5,28g CO2 v 1,98g H2O. Bit rng, t l khi lng H v O trong X l 0,125:1. Cng thc phn t ca X l A. C6H12O6. B. C12H24O12. C. C12H22O11. D. (C6H10O5)n. Cu 86: Cho m g tinh bt ln men sn xut ancol etylic, ton b lng CO 2 sinh ra cho qua dung dch Ca(OH)2 d, thu c 750,0g kt ta. Bit hiu sut mi giai on ln men l 80%. Gi tr m cn dng l bao nhiu ?

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A. 940,0. B. 949,2. C. 950,5. D. 1000,0. Cu 87: Cho s chuyn i sau (E, Q, X, Y, Z l hp cht hu c, mi mi tn biu th mt phn ng ho hc). Cng thc ca E, Q, X, Y, Z ph hp vi s sau l Q X
E CO2 C2H5OH Z Y

A. B. C. D.

E Q C12H22O11 C6H12O6 (C6H10O5)n C6H12O6 (C6H10O5)n C6H12O6 A, B, C u sai.

X CH3COOH CH3CHO CH3CHO

Y CH3COOC2H5 CH3COOH CH3COONH4

Z CH3COONa CH3COOC2H5 CH3COOH

Cu 88: Xenluloz trinitrat l cht d chy v n mnh, c u ch t xenluloz v axit nitric. Mun

iu ch 29,70kg xenluloz trinitrat (hiu sut 90%) th th tch axit nitric 96% (D=1,52 g/ml) cn dng l bao nhiu ? A. 14,39 lt. B. 15,00 lt. C. 15,39 lt. D. 24,39 lt. Cu 89: Chn cu ng trong cc cu sau: A. Xenluloz v tinh bt c phn t khi nh. B. Xenluloz c phn t khi nh hn tinh bt. C. Xenluloz v tinh bt c phn t khi gn bng nhau. D. Xenluloz v tinh bt u c phn t khi rt ln, nhng phn t khi ca xenluloz ln hn nhiu so vi tinh bt. Cu 90: sn xut ancol etylic ngi ta dng nguyn liu l mn ca v v bo t g cha 50% xenluloz. Nu mun iu ch mt tn ancol etylic, hiu sut qu trnh l 70% th khi lng nguyn liu xp x A. 5031kg. B. 5000kg. C. 5100kg. D. 6200kg. Cu 91: Chn pht biu sai: A. C th phn bit mantoz v ng nho bng v gic. B. Tinh bt v xenluloz khng th hin tnh kh v trong phn t khng c nhm chc anehit (CH=O). C. Tinh bt c phn ng mu vi iot do tinh bt c cu to mch dng xon c l rng. - o D. C th phn bit glucoz v saccaroz bng phn ng vi Cu(OH)2/OH , t . Cu 92: Cho xenluloz phn ng vi anhirit axetic (xc tc H2SO4 c), thu c 11,1g hn hp X gm xenluloz triaxetat, xenluloz iaxetat v 6,6g CH3COOH. Thnh phn % theo khi lng ca xenluloz triaxetat v xenluloz iaxetat trong X ln lt l A. 77% v 23%. B. 77,84% v 22,16%. C. 76,84% v 23,16%. D. 70% v 30%. Cu 93: Ln men 1 tn tinh bt cha 5% tp cht tr thnh ancol etylic, hiu sut ca mi qu trnh ln men l 85%. Khi lng ancol thu c l A. 400kg. B. 398,8kg.

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C. 389,8kg. D. 390kg. o Cu 94: Pha long 389,8kg ancol etylic thnh ancol 40 , bit khi lng ring ca ancol etylic l 0,8 g/cm3. Th tch dung dch ancol thu c l A. 1206,25 lt. B. 1246,25 lt. C. 1218,125 lt. D. tt c u sai. Cu 95: Kh cacbonic chim t l 0,03% th tch khng kh. Mun to ra 500g tinh bt th cn bao nhiu lt khng kh (ktc) cung cp lng CO2 cho phn ng quang hp? Gi thit hiu sut qu trnh l 100% A. 1382666,7 lt. B. 1382600 lt. C. 1402666,7 lt. D. tt c u sai. Cu 96: t chy hon ton 0,0855g mt cacbohirat X. Sn phm c dn vo nc vi trong thu c 0,1g kt ta v dung dch A, ng thi khi lng dung dch tng 0,0815g. un nng dung dch A li c 0,1g kt ta na. Bit khi lm bay hi 0,4104g X thu c th tch kh ng bng th tch 0,0552g hn hp hi ancol etylic v axit fomic o trong cng iu kin. Cng thc phn t ca X l A. C12H22O11. B. C6H12O6. C. (C6H10O5)n. D. C18H36O18.

CHUYN 10: AMIN AMINOAXIT PROTEIN

Cu 1: Anilin v phenol u p vi: A.dd HCl B.dd NaOH Cu 2: Cho s : NH3 C.dd Br2 Y D. dd NaCL

CH3I 1:1

HNO2

CuO to

Bit Z c kh nng tham gia p trng gng. Y v Z ln lt l A.C2H5OH, HCHO B.C2H5OH, CH3CHO C.CH3OH, HCHO D.CH3OH, HCOOH Cu 3: Dy gm cc cht u lm qu tm m chuyn sang mu xanh l A. anilin, metyl amin, amoniac B.amoni clorua, metyl amin, natri hidroxit C. anilin, aminiac, natri hidroxit D. metyl amin , amoniac, natri axetat. Cu 4: C 3 cht lng: benzen , anilin, stiren ng ring bit trong 3 l mt nhn . Thuc th phn bit 3 cht lng trn l : A. dd phenolphtalein B.dd Br2 C.dd NaOH D. Qu tm Cu 5: Cho cc cht: etyl axetat, etanol , axit acrylic , phenol , anilin , phenyl amoni clorua, ancol benzylic, p crezol. Trong cc cht trn , s cht p vi NaOH l : A.3 B.4 C.5. D.6 Cu 6: NHn nh no sau y ko ng ? A.cc amin u c kh nng nhn proton. B.Tnh bazo ca cc amin u mnh hn NH3. C.Metyl amin c tnh bazo mnh hn anilin D.CT TQ ca amino , mnh h l : CnH2n+2+2Nk Cu 7: dd metyl amin khng tc dng vi cht no sau y? A.dd HCl B.dd Br2/CCL4 C.dd FeCL3 D. HNO2 Cu 8: tch ring hh kh CH4 v CH3NH2 ta dng : A.HCL B. HCl, NaOH C. NaOH , HCL D.HNO2 Cu 9: phn bit cc dd : CH3NH2, C6H5OH , CH3COOH , CH3CHO khng th dng A.qu tm , dd Br2 B.Qu tm , AgNO3/NH3 C.dd Br2 , phenolphtalein D. Qu tm, Na kim loi Cu 10: Cho anilin tc dng vi cc cht sau: dd Br2 , H2 , CH3I , dd HCl , dd NaOH , HNO2. S p xy ra l : A.3 B.4 C.5 D.6 Cu 11: Cho cc cht sau: (1) NH3 ; (2) CH3NH2; (3) (CH3)2NH ; (4) C6H5NH2 ; (5) (C6H5)2NH . Th t tng dn tnh bazo ca cc cht trn l : A.(4) < (5) < (1) < (2) < (3) B.(1) < (4) < (5) < (2) < (3) C.(5) < (4) < (1) < (2) < (3) D.(1) < (5) < (2) < (3) < (4)

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Cu 12: Cho s chuyn ha sau :

+CH3OH/HCL

+NH3

+HNO2

Alanin X Y Z Cht Z l : A.CH3 CH(OH) COOH B.H2N CH2 COOCH3 C.CH3 CH(OH) COOCH3 D.H2N CH(CH3) COOCH3 Cu 13: chng minh glyxin C2H5O2N l mt amino axit , ch cn cho p vi A.NaOH B.HCL C.CH3OH/HCL D. HCL v NaOH Cu 14: ng vi CT C3H7O2N c bao nhiu ng phn amino axit ? A.2 B.3 C.4 D.5 Cu 15: Hp cht khng lm i mu giy qu m l : A.CH3NH2 B.C6H5ONa C.H2N CH2 CH(NH2) COOH D. H2NCH2 COOH Cu 16: Cht X c CT l C3H7O2N . X c th tc dng vi NaOH , HCl v lm mt mu dd Br. CT ca X l: A.CH2 = CH COONH4 B.CH3CH(NH2)COOH C.H2NCH2CH2COOH D.CH3CH2CH2NO2 Cu 17: dd cht no sau y ko lm chuyn mu qu tm. ? A.H2N(CH2)2CH(NH2)COOH. B.CH3CH(OH)COOH C.H2NCH2COOH D.C6H5NH3Cl Cu 18: Axit glutamic (HCOO(CH2)2CH(NH2)COOH) l cht A. Ch c tnh axit B.ch c tnh bazo C.Lng tnh D.trung tnh. Cu 19: Cho cc loi hp cht : amino axit(X) , mui amoni ca axit cacboxylic(Y) , amin(Z) este ca amino axit(T) , dy gm cc hp cht u p vi NaOH v dd HCl l : A.X, Y,Z , T B.X,Y,T C.X,Y,Z D.Y,Z,T Cu 20: Trong cc cht sau cht no c lin kt peptit? A.alanin B.Protein C.Xenlulozo D.Glucozo Bi 21: Cho 0,1 mol A ( amino axit H2N-R-COOH) phn ng ht vi HCl to 11,15 gam mui. A l A.Valin B.Phenylalani C.Alanin D.Glyxin Bi 22: Amino axit X cha mt nhm COOH v 2 nhm NH2.Cho 1 mol X tc dng ht vi dung dch NaOH, thu c 154 gam mui. Cng thc phn t ca X l: A.C4H10N2O2 B.C5H10N2O2 C.C5H12N2O2 D.C6H14N2O2 Bi 23: Hp cht no sau y khng phi l Amino axit A.H2NCH2COOH B.CH3CH2CONH2 C.CH3NHCH2COOH D.HCOOCCH2CH(NH2)COOH Bi 24: C 3 cht: butylamin, anilin v amoniaC. Th t tng dn lc baz l A.NH3 < C6H5NH2 < C4H9NH2 B.C6H5NH2 < NH3 < C4H9NH2 C.C4H9NH2 < NH3 < C6H5NH2 D.C4H9NH2 < C6H5NH2 < NH3 Bi 25: Hp cht hu c X c mch cacbon khng phn nhnh, bc nht (cha C, H, N), trong nit chim 23,73% v khi lng. Bit X tc dng c vi HCl vi t l s mol . Cng thc phn t ca X l A. CH3 NH2 B.CH3 CH2 NH CH3 C.CH3 CH(CH3) NH2 D.CH3 CH2 CH2 NH2 Bi 26: Cho 20 gam hn hp gm 3 amin no, n chc l ng ng k tip nhau tc dng va vi dung dch 1M, c cn dung dch thu c 31,68 gam mui. Th tch dung dch dng l A.16ml B.32ml C.160ml D.320ml Bi 27: t chy hon ton 1 amin no n chc, bc 2, mch h X thu c v hi nc theo t l s mol tng ng l 2 : 3. Cng thc cu to ca X l A.CH3 NH CH3 B.CH3 NH C2H5 C.CH3 CH2 CH2 NH2 D.C2H5 NH C2H5 Bi 28: t chy hon ton hn hp 2 amin no n chc ng ng lin tip, thu c . Hai amin c cng thc phn t l: A.C2H5NH2 v C3H7NH2 B.CH3NH2 v C2H5NH2 C.C3H7NH2 v C4H9NH2 D.C4H9NH2 v C5H11NH2 Bi 29: T l th tch ca CO2 : H2O khi t chy hon ton mt ng ng X ca glixin l 6 : 7 (phn ng chy sinh ra ). X tc dng vi glixin cho sn phm ipeptit. Cng thc cu to ca X l: A.CH3CH(NH2)COOH B.NH2CH2CH2COOH C.C2H5CH(NH2)COOH D. A v B ng

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Bi 30: Hy chn trnh t tin hnh no trong cc trnh t sau phn bit dung dch cc cht: CH3NH2, H2NCOOH, CH3COONH4, anbumin. A..Dng qu tm, dng dd HNO3 c , dng dd NaOH B.Dng qu tm, dng Ca(OH)2 C.Dng Cu(OH)2 , dng phenolphtalein, dng dd NaOH D.Dng qu tm, dng dd CuSO4, dng dd NaOH Bi 31: X l mt no ch cha mt nhm -NH2v mt nhm COOH. Cho 13,1g X tc dng vi dung dch HCl d, ta thu c 16,75g mui clohirat ca X. X c cng thc cu to no sau y? A.CH3CH2(NH2)COOH B.H2N(CH2)3COOH C.CH3(CH2)4(NH2)COOH D.H2N(CH2)5COOH Bi 32: Mt hp cht hu c X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dung dch NaOH v HCl. Cht hu c X c cng thc cu to l: A.H2N CH = CH COOH B.CH2 = CH COONH4 C.H2N CH2 CH2 COOH D. A v B ng Bi 33: Hp cht hu c X c phn t khi nh hn phn t khi ca benzen, ch cha C, H, O, N trong H chim 9,09%, N chim 18,18%. t chy 7,7g X, thu c 4,928 lt kh o , 1 atm. X tc dng vi dung dch NaOH cho mui ca axit hu c. X c cng thc cu to no sau y? A.CH3COONH4 B.HCOONH3CH3 C.H2NCH2CH2COOH D. A v B ng Bi 34: Hy sp xp cc cht sau y theo trnh t tnh baz tng dn t tri sang phi: amoniac, anilin, pnitroanilin, p-nitrotoluen, metylamin, imetylamin. A.C6H5NH2 < O2NC6H4NH2 < H3CC6H4NH2 < NH3 < CH3NH2 < (CH3)2NH B.O2NC6H4NH2 < C6H5NH2 < H3CC6H4NH2 < NH3 < CH3NH2 < (CH3)2NH C.O2NC6H4NH2 < H3CC6H4NH2 < C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. Tt c u sai Bi 35: t chy ht a mol mt aminoaxit c 2a mol CO2v a/2mol N2. Aminoaxit trn c cng thc cu to l: A.H2NCH2COOH B.H2N(CH2)2COOH C.H2N(CH2)3COOH D.H2NCH(COOH)2 Bi 36: t chy mt amin X n chc no, thu c v c t l s mol nCO2:nH2O = 2:3 . Amin X c tn gi l: A.Etyl amin B. Metyl etyl amin C. Trimetyl amin D.Kt qu khc Bi 37: C hai amin bc mt: X (ng ng ca anilin) v Y (ng ng ca metylamin). t chy hon ton 3,21g amin X sinh ra kh CO2 v hi nc v 336 cm3 kh nit (ktc). Khi t chy hon ton amin Y cho nCO2: nH2O = 2:3 Cng thc phn t ca amin l: A.CH3C6H4NH2, CH3CH2CH2NH2 B.C2H5C6H4NH2 , CH3CH2CH2NH2 C.CH3C6H4NH2 , CH3(CH2)4 NH2 D. A v B ng Bi 38: t chy hon ton mt amin thm X thu c 3,08g CO2v 0,9g H2Ov 336ml N2(o ktc). trung ho 0,1 mol X cn dng 600ml HCl 0,5M. Cng thc phn t ca X l cng thc no sau y: A.C7H11N B.C7H8NH2 C.C7H11N3 D.C8H9NH2 Bi 39: t chy hon ton 6,2g mt amin no n chc cn dng 10,08 lt kh oxi (ktc). Cng thc phn t ca amin l: A.C2H5NH2 B.C3H7NH2 C.CH3NH2 D.C4H9NH2 Bi 40: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6g CO2v 12,6g H2O v 69,44 lt nit. Gi thit khng kh ch gm nit v xi, trong oxi chim 20% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: A.C2H5NH2 B.C3H7NH2 C.CH3NH2 D.C4H9NH2 Bi 41: Cho 20 gam hn hp 3 amin no, n chc, ng ng k tip, tc dng vi dung dch va , sau c cn thu c 31,68 hn hp mui. Nu 3 amin trn trn theo th t khi lng mol tng dn vi s mol c t l 1: 10: 5 th amin c khi lng phn t nh nht c cng thc phn t l: ACH3NH2 B.C2H5NH2 C.C3H7NH2 D.C4H11NH2 Bi 42: Cng thc phn t ca amin cha 23,73% khi lng nit? A.C2H5NH2 B.C6H5NH2 C.(CH3)2NH D.(CH3)3N Bi 43: Cho 9,85 gam hn hp 2 amin, n chc, bc 1 tc dng va vi dung dch HCl thu c 18,975 gam mui. Khi lng HCl phi dng l A.9,521 B.9,125 C.9,215 D.9,512 Bi 44: X l hp cht hu c mch h, cha cc nguyn t C, H, N, trong N chim 31,11%% v khi lng. X tc dng vi dung dch HCl theo t l 1:1. X c s ng phn l: A.2 B.3 C.4 D.5

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Bi 45: trung ha 200ml dung dch aminoaxit X 0,5M cn 100g dung dch NaOH 8%. C cn dung dch thu c 16,3g mui khan. X c cng thc cu to l: A.H2NCH(COOH)2 B.H2NCH2CH(COOH)2 C.(H2N)2CHCH2(COOH)2 D.Av B ng Bi 46: Hp cht X gm cc nguyn t C, H, O, N vi t l khi lng tng ng l 3:1:4:7. Bit phn t ch c 2 nguyn t nit. X c cng thc phn t l: A.CH4ON2 B.C3H8ON2 C.C3H10O2N2 D.C4H12O2N2 Bi 47: A l -amioaxit (c cha 1 nhm NH2). t chy 8,9g A bng O2va c 13,2g CO2; 6,3g H2Ov 1,12 lt N2(ktc). A c cng thc phn t l : A.C2H5NO2 B.C3H7NO2 C.C4H9NO2 D.C6H9NO4 Bi 48: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A.H2NCH2CH2COOOH B.CH3CH(NH2)COOH C.H2NCH2COOH D.CH3CH2CH(NH2)COOH Bi 49: C7H9N c s ng phn cha nhn thm la. A. 6. B. 5. C. 4. D. 3. Bi 50: Hp cht Y l mt amin n chc cha 20,89% N theo khi lng. Y c cng thc phn t l A.C4H5N B.C4H7N C.C4H9N D.C4H11N Bi 51: A l hp cht hu c cha C,H,O,N . t chy 1 mol A c 2 mol CO2 ; 2,5 mol H2O; 0,5 mol N2. ng thi phi dng 2,25 mol O2. A c CT phn t: A.C2H5NO2 B.C3H5NO2 C.C6H5NO2 D.C3H7NO2 Bi 52: t chy hon ton mt amin thm X thu c 0,07 mol CO2 , 0,99g H2O v 336 ml N2(ktc). trung ha 0,1 mol X cn 600 mldd HCl 0,5M. Bit X l amin bc 1 . X c cng thc l, A.CH3-C6H2(NH2)3 B.C6H3(NH2)3 C.CH3 NH C6H3(NH2) D.NH2 C6H2(NH2)2 Bi 53: trung ha ht 3,1 g mt amin n chc cn dng 100ml dd HCl 1M. amin l; A.CH5N B.C2H7N C.C3H3N D.C3H9N Bi 54: C 3 dd sau.H2N CH2 CH2 COOH ; CH3 CH2 COOH ; CH3 (CH2)3 NH2 phn bit cc dd trn ch cn dng thuc th l: A.dd NaOH B.dd HCl C. Qu tm D. phenolphtalein Bi 55: Mt este c CT C3H7O2N, bit este c iu ch t amino axit X v ru metylic. Cng thc cu to ca amino axit X l: A.CH3 CH2 COOH B.H2N CH2 COOH C.NH2 CH2 CH2 COOH D. CH3 CH(NH2) COOH Bi 56: Amin c cha 15,05% N v khi lng c CT l : A.C2H5NH2 B.CH3 CH2 NH2 C.C6H5NH2 D.(CH3)3N Bi 57: Cho 9,3 g mt ankyl amin X tc dng vi dd FeCl3 d thu c 10,7g kt tA. Cng thc cu to ca X l: A.CH3NH2 B.C2H5NH2 C.C3H7NH2 D.C4H9NH2 Bi 58: Ba cht A, B, C (CxHyNz) c thnh phn % theo khi lng N trong A, B, C ln lt l 45,16%; 23,73% ; 15,05% ;A , B, C tc dng vi axit cho mui amoni R NH3Cl CT ca A, B, C ln lt l: A.CH3NH2 , C3H7NH2, C4H9NH2 B.CH3NH2, C3H7NH2, C6H5NH2 C.CH3NH2 , C4H9NH2, C6H5NH2 D.CH3NH2 , C6H5NH2 , C2H5NH2 Bi 59: Hp cht C3H7O2N tc dng vi NaOH , H2SO4 v lm mt mu dd Br2 nn CT cu to hp l ca hp cht l: A.CH3 CH(NH2) COOH B.CH2(NH2) CH2 COOH C. CH2 = CH COONH4 D.CH3 CH2 COONH4 Bi 60: Cht X c %C = 40,45% ; %H = 7,86% ; %N = 15,73% cn li Oxi. MX <100 . Khi X p vi NaOH cho mui C3H6O2Na . Cng thc phn t ca X l A. C4H9O2N B.C3H7O2N C.C2H5O2N D.CH3O2N Bi 61: Cho 1 este A c iu ch t aminoaxit B v ancol Metylic. T khi hi ca A so vi H2 = 44,5. t chy hon ton 8,9 g este A thu c 13,2 g CO2 ; 6,3 g H2O ; 1,12 lt N2 (ktc).Cng thc cu to ln lt ca A v B l : A.H2N-CH2-COO-CH3 vH2NCH2-COOH B.H2N-CH2-CH2-COOCH3 v H2N-CH2-COOH C.H2N-CH2-COO-CH3 v CH3 CH2 COOH D. H2N CH(CH3) COO- CH3 V H2N-CH2-COOH Bi 62: Mt aminoaxit no X tn ti trong t nhin gm ( ch cha 1 nhm NH2 v mt nhm COOH). Cho 0,89 g X p va vi HCl to ra 1,255 g mui . Cng thc cu to ca X l: A.H2N CH2 COOH B.CH3 CH(NH2)- COOH C.H2N-CH2-CH2-COOH D.B,C ng Bi 63: trung ha 50 ml dd metyl amin cn 40 ml dd HCl 0,1 M . CM ca metyl amin dng l :

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A.0,08M B.0,04M C.0,02M D.0,06M Bi 64: Hp cht X cha cc nguyn t C,H,O,N v c MX = 89. Khi t chy 1 mol X thu c 3 mol CO2 v 0,5 mol N2. Bit hp cht lng tnh v tc dng vi nc Br2. X l A.H2N CH = CH COOH B.CH2 = CH(NH2) COOH C.CH2 = CH COONH4 D.CH2 = CH CH2 NO2 Bi 65: Cho m g anilin tc dng vi dd HCl c d, c cn dung dch sau p thu c 15,54 g mui khan. Hiu sut p t 80% . m c gi tr l : A.13,95g B.8,928g C.11,16g D.12,5g Bi 66: Cho 20 g hh 3 amin: metyl amin , etyl amin, anlyl amin tc dng va vi V ml dd HCl 1M . Sau p c cn dd thu c 31,68 g mui khan. Gi tr ca V l: A.120ml B.160ml C.240ml D.320 ml Bi 67: Cho 4,41 g mt amino axit X tc dng vi dd NaOH d thu c 5,73 g mui . Mt khc cng lng X trn nu cho tc dng vi HCl d thu c 5,505 g mui clorua . Cng thc cu to ca X l: A.HCOOC CH2 CH2 CH(NH2) COOH B.CH3 CH(NH2) COOH C.HOOC CH2 CH(NH2)CH2 COOH D. C A v C Bi 68: S ng phn amin c cng thc phn t C2H7N l

A. 2.

B. 4. C. 5. D. 3. Bi 69: Cho cc phn ng: H2N - CH2 - COOH + HCl => H3N+- CH2 - COOH Cl-. H2N - CH2 - COOH + NaOH => H2N - CH2 - COONa + H2O. Hai phn ng trn chng t axit aminoaxetic A. c tnh cht lng tnh. B. ch c tnh axit. C. ch c tnh baz. D. va c tnh oxi ho, va c tnh kh. Bi 70: Anilin (C6H5NH2) c phn ng vi dung dch A. NaOH. B. Na2CO3. C. NaCl. D. HCl. Bi 71: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. HCOOH3NCH=CH2. B. H2NCH2CH2COOH. C. CH2=CHCOONH4. D. H2NCH2COOCH3. Bi 72: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A.4. B. 2. C. 3. D. 5. Bi 73: Cht no sau y khng kh nng tham gia phn ng trng ngng : A. CH3CH(NH2)COOH B. HCOOCH2CH2CH2NH2 C. CH3CH(OH)COOH D. HOCH2 - CH2OH Bi 74: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc CH3CH(NH3Cl)COOH + Ba(OH)2 => (CH3CH(NH3)COO)2Ba + BaCL2 + H2O Bi 75: Cho 22,15 g mui gm CH2NH2COONa v CH2NH2CH2COONa tc dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch th lng cht rn thu c l : A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc Bi 76: Cho 13,35 g hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l A. 100 ml B. 150 ml C. 200 ml D. 250 ml Bi 77: Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3CHNH2COOH) tc dng vi 450 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 200 ml dung dch NaOH. Phn trm khi lng ca mi cht trong X l: A. 55,83 % v 44,17 % B. 53,58 % v 46,42 % C. 58,53 % v 41,47 % D. 52,59 % v 47,41% Bi 78: Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy hon ton a mol X thu c 6,72 (l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l : A. CH2NH2COOH B. CH2NH2CH2COOH C. CH3CH(NH2)COOH D. C B v C

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Bi 79: Xc nh th tch O2 (ktc) cn t chy ht 22,455 g hn hp X gm (CH3CH(NH2)COOH

v CH3COOCH(NH2)CH3. Bit sn phm chy c hp th ht vo bnh ng dung dch NaOH th khi lng bnh tng 85,655 g. A. 44,24 (l) B. 42,8275 (l) C. 128,4825 (l) D. Kt qu khc Bi 80: Mt amino axit no X ch cha mt nhm -NH2 v mt nhm -COOH. Cho 0,89 g X phn ng va vi HCl to ra 1,255 g mui. CTCT ca X l: A. H2N-CH2-COOH B. CH3-CH(NH2)-CH2-COOH C. H2N-CH2-CH2-COOH D. B, C, u ng. Bi 81: Nhng cht no sau y lng tnh : A. NaHCO3 B. H2N-CH2-COOH C. CH3COONH4 D. C A, B, C Bi 82: Cho qu tm vo dung dch mi hp cht di y, dung dch no s lm qu tm ho : (1) H2N - CH2 COOH; (4) H2N(CH2)2CH(NH2)-COOH; (2) Cl.NH3+- CH2COOH; (5) HOOC(CH2)2CH(NH2) COOH; (3) H2N - CH2 - COONa A. (2), (5) B. (1), (4) C. (1), (5) D. (2) Bi 83: l mt hp cht hu c c CTPT C5H11O2N. un (A) vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c (B). Cho hi qua CuO/t0 thu c cht hu c (D) c kh nng cho phn ng trng gng. CTCT ca A l : A. CH2 = CH-COONH3-C2H5 B. CH3(CH2)4NO2 C. H2NCH2-CH2-COOC2H5 D. NH2CH2COO-CH2- CH2-CH3 Bi 84: Bit rng khi t chy hon ton 0,1 mol X thu c 1,12 lt N2; 6,72 lt CO2 v 6,3 gam H2O. CTPT ca X A. C3H5O2N B. C3H7O2N C. C3H5O2N D. C4H9O2N Bi 85: cho 0,1 mol cht X (C2H8O3N2) tc dng vi dd cha 0,2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m t v dd Y. c cn dd Y thu c m gam cht rn khan. Gi tr ca m l A. 5,7 B. 12,5 C. 15 D. 21,8 Bi 86: aminoaxit X cha 1 nhm COOH v 2 nhm NH2. cho 1 mol X tc dng ht vi dd NaOH thu c 154 gam mui. CTCT ca X l A. H2NCH2CH(NH2)CH2COOH B. H2NCH2CH2CH2(NH2)COOH C. H2N(CH2)3CH(NH2)COOH D. H2NCH=CHCH(NH2)COOH Bi 87: t chy ht a mol mt aminoaxit c 2a mol CO2 v a/2 mol N2. amonoaxit trn c CTPT l A. H2NCH2COOH B. H2N(CH2)2COOH C. H2N[CH2]3COOH D. H2NCH[COOOH]2 Bi 88: A l mt -aminoaxit no, c mch cacbon khng phn nhnh, cha mt nhm-NH2 v 2 nhm COOH. Khi t chy hon ton 1 mol A th thu c hh kh trong c 4,5 mol <nCO2 < 6 mol. CTCT ca A l A. H2NCH(COOH)-CH(COOH)-CH3 B. H2NCH(COOH)-CH2-CH2COOH C. HOOC-CH(NH2)-CH2COOH D. HOOCCH2-CH(NH2)-CH2COOH Bi 89: cho 100 ml dd aminoaxit A 0,2M tc dng va vi 80 ml dd NaOH 0,25M. mt khc 100 ml dd A trn tc dng vag vi 80 ml dd HCl 0,5M. Bit d A/H2 = 52 . CTPT ca A l A. (H2N)2C2H3COOH B. H2NC2H3(COOH)2 C. (H2N)2C2H2(COOH)2 D. H2NC3H5(COOH)2 Bi 90: Cho X l mt aminoaxit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dd HCl 0,125M v thu c 1,835 gam mui khan. Cn cho 0,01 mol X tc dng vi dd NaOH th cn dng 25 gam dd NaOH 3,2%. CTCT ca X l A. H2NC3H6COOH B. H2NC2H4COOH C. H2NC3H5(COOH)2 D. (H2N)2C3H4(COOH)2 Bi 91: t chy hon hon ton cht hu c X thu c 3,36 lt kh CO2 v 0,56 lt N2 (u o ktc) v 3,15 gam H2O. khi cho X tc dng vi dd NaOH thu c sn phm c mui H2NCH2COONa. CTCT thu gn ca X l A. H2NCH2CH2COOH B. H2NCH2COOC3H7 C. H2NCH2COOC2H5 D. H2NCH2COOCH3 Bi 92: este A c iu ch t aminoaxit B v CH3OH, dA/H2= 44,5. t chy hon ton 8,9 gam A thu c 13,2gam CO2; 6,3gam H2O v 1,12 lt N2 (ktc). CTCT ca A l A. H2NCH2COOCH3 B. H2NC2H4COOCH3

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C. H2NC3H6COOCH3 D. H2NC2H2COOCH3 Bi 93: hp cht X mch h c CT: CxHyOzNt. trong X c 15,7303%N v 35,955%O. bit X tc dng vi dd HCl ch to ra mui ROzNH3Cl (HS rn k nng: l gc hirocacbon) v tham gia phn ng trng ngng. CTCT ca X l A. H2NC2H4COOH B. H2NCH2COOH C. H2NC2H2COOH D. H2NC3H6COOH Bi 94: hp cht X c CTPT trng vi CTGN va tc dng vi dd NaOH va tc dng vi dd HCl. trong X c thnh phan cc nguyn t C, H, N ln lt l 40,449%; 7,865%; 15,73% v cn li l oxi. Cn khi cho 4,45 gam X phn ng vi dd NaOH (va ) thu c 4,85 gam mui khan. CTCT ca X l A. CH2=CH COONH4 B. H2NC2H4COOH C. H2NCOOCH2CH3 D. H2NCH2COOCH3 Bi 95: Hp cht CH3 NH CH2CH3 c tn ng l A. imetylamin. B. EtylMetylamin. C. N-Etylmetanamin. D. imetylmetanamin. Bi 96: Cht no l amin bc 2 ? A. H2N CH2 NH2. B. (CH3)2CH NH2. C. CH3 NH CH3. D. (CH3)3N. Bi 97: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 8,15 gam B. 0,85 gam C. 7,65 gam D. 8,10 gam Bi 98: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4g tribormanilin l A. 164,1ml. B. 49,23ml. C. 146,1ml. D. 16,41ml. Bi 99: Khi lng anilin cn dng tc dng vi nc brom thu c 6,6g kt ta trng l A. 1,86g. B. 18,6g. C. 8,61g. D. 6,81g. Bi 100: Mt amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl . Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui . X c th l : A. axit glutami B. valin. C. glixin D. alanin. Bi 101: chng minh tnh lng tnh ca NH2-CH2-COOH (X) , ta cho X tc dng vi A. HCl, NaOH. B. Na2CO3, HCl. C. HNO3, CH3COOH. D. NaOH, NH3. Bi 102: Cho cc phn ng : H2N CH2 COOH + HCl Cl-H3N+ CH2 COOH. H2N CH2 COOH + NaOH H2N CH2 COONa + H2O. Hai phn ng trn chng t axit amino AxetiC. A. C tnh axit B. C tnh cht lng tnh C. C tnh baz D. C tnh oxi ha v tnh kh Bi 103: Cho cc cht: (1) amoniac; (2) metylamin; (3) anilin; (4) dimetylamin. Tnh baz tng dn theo th t no sau y? A. (1) < (3) < (2) < (4). B. (3) < (1) < (2) < (4).C. (1) < (2) < (3) < (4).D. (3) < (1) < (4) < (2) Bi 104: Mt amin A thuc cng dy ng ng vi metylamin c hm lng cacbon trong phn t bng 68,97%. Cng thc phn t ca A l.: A. C2H7N. B. C3H9N. C. C4H11N. D. C5H13N. Bi 105: Hp cht no sau y khng phi l amino axit : A. CH3CONH2 B. CH3CH(NH2)CH(NH2)COOH C. HOOC-CH(NH2)CH2COOH D. CH3CH(NH2)COOH Bi 106: Axit amino axetic khng tc dng vi cht : A. CaCO3 B. H2SO4 long C. KCl D. CH3OH Bi 107: Aminoaxit c kh nng tham gia phn ng este ha v : A. Aminoaxit l cht lng tnh B. Aminoaxit chc nhm chc COOH C. Aminoaxit chc nhm chc NH2 D. Tt c u sai Bi 108: Khi thy phn n cng protein thu c cc cht : A. -Gucoz v -Glucoz B. Axit C. Amin D. Aminoaxit Bi 109: Trong cc cht sau : X1: H2N CH2 COOH X3: C2H5OH X2: CH3 NH2 X4: C6H5NH2 Nhng cht c kh nng th hin tnh baz l : A. X1,X3 B. X1,X2 C. X2,X4 D. X1,X2,X3 Bi 110: Khi un nng dung dch protein xy ra hin tng no trong s cc hin tng sau ? A. ng t B. Bin i mu ca dung dch C. Tan tt hn D. C kh khng mu bay ra

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Bi 111: nhn bit dung dch glixin , h tinh bt , lng trng trng , ta c th tin hnh theo th t

no sau y : A. Dng qu tm dng dung dch iot B. Dng dung dch iot , dng dung dch HNO3 C. Dng qu tm , dng dng dung dch HNO3 D. Dng Cu(OH)2 , dng dung dch HNO3 Bi 112: Mt amino axit A c 40,4% C ; 7,9% H ; 15,7 % N; 36%O v MA = 89. Cng thc phn t ca A l : A. C4H9O2N B. C3H5O2N C. C2H5O2N D. C3H7O2N Bi 113: Cho 0,01 mol amino axit A tc dng va 80 ml dung dch HCl 0,125 M.C cn dung dch thu c 1,835 gam mui . Khi lng ca A l : A. 9,7 B. 1,47 C. 1,2 D. 1,5 Bi 114: Cho 0,1 mol A (aminoaxit dng H2NRCOOH) phn ng ht vi HCl to 11,15 gam mui. A l cht no di y? A. Valin B. Glixin C. Alanin D. Phenylalanin Bi 115: Cho 0,01 mol amino axit X phn ng ht vi 40 ml dung dch HCl 0,25M to thnh 1,115gam mui khan . X c CTCT no sau : A. NH2-CH2-COOH B. NH2-(CH2)2-COOH C. CH3COONH4 D. NH2(CH2)3-COOH
Bi 116: 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. Cng thc ca

A c dng nh th no? A. (H2N)2R(COOH)2 B. (H2N)2RCOOH C. H2NRCOOH D. H2NR(COOH)2 Bi 117: Tn gi no sai so vi CT tng ng: A. H2N-CH2-COOH : glixin B. CH3-CH(NH2)-COOH : -Alanin C. HOOC - CH2 - CH2 - CH(NH2) - COOH : axit glutamic D. H2N - (CH2)4 - CH(NH2) - COOH: Lisin Bi 118: Cho cc cht sau y: (1) CH3-CH(NH2)-COOH (2) OH-CH2-COOH (3) CH2O v C6H5OH (4) C2H4(OH)2 v p - C6H4(COOH)2 (5) (CH2)6(NH2)2 v (CH2)4(COOH)2 Cc trng hp c kh nng tham gia phn ng trng ngng? A. 1, 2 B. 3, 5 C. 3, 4 D. 1, 2, 3, 4, 5. Bi 119: Poli peptit l hp cht cao phn t c hnh thnh t cc : A. Phn t axit v ru .B. Phn t amino axit . C. Phn t axit v andehit . D. Phn t ru v amin . Bi 120: t chy hon ton hn hp 2 amin no n chc l ng ng k tip thu c 2,24lit kh CO2 (ktc) v 3,6gam H2O. Cng thc ca hai amin l A. CH3NH2 v C2H5NH2. B. C2H5NH2 v C3H7NH2. C. C3H7NH2 v C4H9NH2. D. C5H11NH2 v C6H13NH2. Bi 121: Khi t chy hon ton mt amin n chc X thu c 10,125gam H2O, 8,4 lit CO2(ktc) v 1,4lit N2. S ng phn ng vi cng thc phn t ca X l A. 2. B. 3. C. 4. D. 5. Bi 122: Dung dch X gm HCl v H2SO4 c pH = 2. trung ho hon ton 0,59gam hn hp hai amin no n chc, bc 1 ( c s nguyn t C nh hn hoc bng 4 th phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin l A. CH3NH2 v C4H9NH2. B. C3H7NH2 v C4H9NH2.C. C2H5NH2 v C4H9NH2. D. A v C. Bi 123: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A.8,2. B. 10,8. C. 9,4. D. 9,6. CH2 =CH COO NH3 CH3 + NaOH => CH2 = CH COO Na + CH3NH2 + H2O Bi 124: Pht biu no sau y l ng? A. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. B. Benzen lm mt mu nc brom nhit thng. C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.

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D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. Bi 125: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2 . Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2 B. C2H5OH v N2 C. CH3OH v NH3 D. CH3NH2 v NH3 Bi 126: : Cht X c cng thc phn t C4H9O2N . Bit : X + NaOH Y + CH4O; Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH C. H2NCH2COOC2H5 v ClH3NCH2COOH D. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH Bi 127: S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 2 B. 5 C. 4 D. 3 Bi 128: Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. axit -aminopropionic B. mety aminoaxetat C. axit - aminopropionic D. amoni acrylat Bi 129: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vc th s mt xch alanin c trong phn t X l A. 453 B. 382 C. 328 D. 479 Bi 130: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. CH3CH2COONH4. B. CH3COONH3CH3. C. HCOONH2(CH3)2. D. HCOONH3CH2CH3. Bi 131: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 2. B. 4. C. 5. D. 3. Bi 132: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NC2H4COOH. C. H2NC4H8COOH. D. H2NCH2COOH. Bi 133: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l : A. H2N-CH2-COOH, H2H-CH2-CH2-COOH B. H3N+-CH2-C, H3N+-CH2-CH2-COOHClOOHCl C. H3N+-CH2-C, H3N+-CH(CH3)-COOOHClOHCl D. H2N-CH2-COOH, H2N-CH(CH3)-COOH Bi 134: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l : A. HCOOH3NCH=CH2 B. H2NCH2CH2COOH C. CH2=CHCOONH4 D. H2NCH2COOCH3 Bi 135: Khi t chy cc ng ng ca metylamin, t l s mol a = nCO2 / nH2O bin i trong khong no A. 0,4 < a < 1,2. B. 1 < a< 2,5. C. 0,4 < a < 1. D. 0,75 < a < 1. Bi 136: Amino axit X cha mt nhm chc amino trong phn t. t chy han tan mt lng X thu c CO2 v N2 theo t l th tch 4:1. X c tn gi l A. Axit aminoetanonic. B. Axit 3-amino propanoic. C. Axit 2,2-iaminoetanoic. D. Axit -4-aminobutanoic. Bi 137: Hp cht X cha cc nguyn t C, H, O, N v c phn t khi l 89. Khi t chy han ton 1 mol X thu c hi nc, 3mol CO2 v 0,5mol N2. Bit rng X l hp cht lng tnh v tc dng c vi nc Br2. X c CTCT l

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A. H2N-CH=CH-COOH. B. CH2=CH(NH2)COOH. C. CH2=CH-COONH4. D. CH3-CH(NH2)-COOH. Bi 138: Hai hp cht hu c X v Y c cng CTPT l C2H7NO2. Bit X + NaOH => A + NH3 + H2O Y + NaOH => B + CH3-NH2 + H2O. A v B c th l A. HCOONa v CH3COONa. B. CH3COONa v HCOONa. C. CH3NH2 v HCOONa. D. CH3COONa v NH3. Bi 139: X l mt -aminoaxit no ch cha mt nhm NH2 v mt nhm COOH. Cho 14,5gam X tc dng vi dung dch HCl d thu c 18,15gam mui clorua ca X. CTCT ca X c th l A. CH3CH(NH2)COOH. B. H2NCH2COOH. C.CH3CH2CH(NH2)COOH. D. CH3[CH2]4CH(NH2)COOH. Bi 140: X l mt -aminoaxit. Cho 0,01mol X tc dng va vi 80ml dung dch HCl 0,125M, sau em c cn dung dch thu c 1,835gam mui. Phn t khi ca X l A. 174. B. 147. C. 197. D. 187. Bi 141: Cho cc cht : (1)C6H5-NH2; (2) C2H5NH2; (3) (C2H5)2NH; (4) NaOH; (5): NH3. Dy c sp xp theo chiu tng ca lc baz l A. (1)< (5)< (2)< (3)< (4). B. (1)< (2)< (5)< (3)< (4). C. (1)< (5)< (3)< (2)< (4). D. (2)< (1)< (3)< (5)< (4). Bi 142: trung ha 200ml dung dch amino axit X cn 100g dung dch NaOH 8%, c cn dung dch c 16,3g mui khan. X c CTCT l A. NH2CH2CH2COOH. B. H2NCH(COOH)2. C. (H2N)2CHCOOH. D. H2NCH2CH(COOH)2. Bi 143: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 85 B. 68 C. 45 D. 46 C O3 => C gc NO3 => NH2-C2H5-NO3 +NaOH => C2H5NH2(amin) + NaNO3(Mui) + H2O Bi 144: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NCOO-CH2CH3. C. H2NCH2COO-CH3. D. H2NC2H4COOH. Bi 145: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH. B. H2NCH2COOH. C. CH3CH(NH2)COOH. D. CH3CH2CH(NH2)COOH. Bi 146: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l : A. 8,9 gam. B. 15,7 gam. C. 16,5 gam. D. 14,3 gam. ADCT Tnh s pi = (2x y + 2 + s nito)/2 = 0 => l Mui amoni => C gc NH4 CT A , B : CH3COONH4 hoc HCOO NH3-CH3 (To ra NH3 , CH3NH2 Qu Xanh) P : CH3COONH4 + NaOH => CH3COONa + NH3 + H2O HCOO-NH3-CH3 + NaOH => HCOONa + CH3NH2 + H2O Bi 147: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2NCH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-CH3. C. H2N-CH2-COO-C2H5. D. H2N-CH2-CH2-COOH. Bi 148: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun cha chc hiroxyl. B. protit lun cha nit. C. protit lun l cht hu c no. D. protit c khi lng phn t ln hn.

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Bi 149: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca

aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. Bi 150: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A.. dung dch NaCl. B. dung dch HCl. C. Cu(OH)2 trong mi trng kim. D. dung dch NaOH. Bi 151: Este A c iu ch t amino axit B v ru metylic. T khi hi ca A so vi hiro l 44,5. t chy hon ton 8,9gam este A thu c 13,2gam kh CO2, 6,3gam H2O v 1,12 lit N2(ktc). CTCT ca A v B l A. NH2-CH2-COOCH3 v NH2-CH2-COOH. B. NH2-CH2-CH2-COOCH3 v NH2-CH2-COOH C. CH3COOCH3 v NH2-CH2-COOH. D. NH2-CH2-COOH v NH2-CH2-CH2-COOH Bi 152: Cho qu tm vo mi dung dch hn hp di y, dung dch no lm qu tm ha ? (1) H2N - CH2 COOH; (2) Cl - NH3+ . CH2 COOH; (3) NH2 - CH2 COONa (4) H2N- CH2-CH2-CHNH2- COOH; (5) HOOC- CH2-CH2-CHNH2- COOH A. (2), (4) B. (3), (1) C. (1), (5) D. (2), (5). Bi 153: Cho dung dch cha cc cht sau :X1 : C6H5 - NH2; X2 : CH3 - NH2; X3 : NH2 - CH2 COOH; X4 : HOOC-CH2-CH2-CHNH2COOH; X5 : H2N- CH2-CH2-CH2-CHNH2COOH. Dung dch no lm qu tm ha xanh ? A. X1, X2, X5 B. X2, X3, X4 C. X2, X5 D. X1, X3, X5 Bi 154: Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dd brom, CTCT ca n l A. CH3-CHNH2 -COOH B. H2N-CH2 - CH2 COOH C. CH2 = CH - COONH4 D. A v B ng. Bi 155: X l mt amino axit no ch cha mt nhm NH2 v mt nhm -COOH. Cho 0,89 gam X phn ng va vi HCl to ra 1,255 gam mui. CTCT ca X l : A. NH2-CH2-COOH B. CH3-CHNH2COOH C. CH3-CHNH2-CH2- COOH D. CH3-CH2-CH2-CHNH2COOH Bi 156: T l VCO2 : VH2O sinh ra khi t chy hon ton mt ng ng X ca glixin l 6 : 7 (phn ng sinh ra kh N2). X tc dng vi glixin cho sn phm l ipeptit. X l : A. NH2-CH2-COOH B. NH2-CH2-CH2-COOH C. CH3-CH2-CH2-CHNH2COOH D. Kt qu khc Bi 157: Dung dch ca cht no sau y khng lm i mu qu tm : A. Glixin (CH2NH2-COOH) B. Lizin (H2NCH2-[CH2]3CH(NH2)-COOH) C. Axit glutamic (HOOCCH2CHNH2COOH) D. Natriphenolat (C6H5ONa) Bi 158: Cht no sau y ng thi tc dng c vi dung dch HCl v dung dch NaOH. A. C2H3COOC2H5 B. CH3COONH4 C. CH3CH(NH2)COOH D. C A, B, C Bi 159: Cc cht X, Y, Z c cng CTPT C2H5O2N. X tc dng c c vi HCl v Na2O. Y tc dng c vi H mi sinh to ra Y1. Y1 tc dng vi H2SO4 to ra mui Y2. Y2 tc dng vi NaOH ti to li Y1. Z tc dng vi NaOH to ra mt mui v kh NH3. CTCT ng ca X, Y, Z l : A.X (HCOOCH2NH2), Y (CH3COONH4), Z (CH2NH2COOH) B.X(CH3COONH4), Y (HCOOCH2NH2), Z (CH2NH2COOH) C.X (CH3COONH4), Y (CH2NH2COOH), Z (HCOOCH2NH2) D.X (CH2NH2COOH), Y (CH3CH2NO2), Z (CH3COONH4) Bi 160: Mt cht hu c X c CTPT C3H9O2N. Cho tc dng vi dung dch NaOH un nh, thu c mui Y v kh lm xanh giy qu tm t. Nung Y vi vi ti xt thu c kh etan. Cho bit CTCT ph hp ca X ? A. CH3COOCH2NH2 B. C2H5COONH4. C. CH3COONH3CH3 D. C A, B, C Bi 161: Tng ng vi CTPT C2H5O2N c bao nhiu ng phn c cha 3 nhm chc : A. 1 B. 2 C. 3 D. 4 Bi 162: Mt hp cht hu c X c CTPT C3H7O2N. X phn ng c vi dung dch Br2, X tc dng c vi NaOH v HCl. CTCT ng ca X l : A. CH(NH2)=CHCOOH B. CH2= C(NH2)COOH D. CH2=CHCOONH4 D. C A, B, C Bi 163: Cho cc cht: (1) amoniac. (2) metylamin. (3) anilin. (4) dimetylamin. Tnh baz tng dn theo th t no sau y?

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A. (1) < (3) < (2) < (4). B. (3) < (1) < (2) < (4). C. (1) < (2) < (3) < (4). D. (3) < (1) < (4) < (2). Bi 164: Cho 0,76 gam hn hp gm amin ng ng lin tip tc dung va u vi V ml dung dich HNO3 0,5M th thu c 2,02 gam hn hp mui khan. Hai amin trn l A.Etylamin v propylamin B. Metylamin v etylamin C.Anilin va benzylamin D.Anilinva metametylanilin Bi 165: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. NH2CH2CH2COOH B. CH3CH(NH2)COOH C. NH2CH2COOH D. CH3CH2CH(NH2)COOH Bi 166: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l A. metyl amin, amoniac, natri axetat B. anilin, metyl amin, amoniac C. anilin, amoniac, natri hiroxit D. amoni clorua, metyl amin, natri hiroxit Bi 167: Amin ng vi cng thc phn t C4H11N c my ng phn mch khng phn nhnh ? A. 4 B.5 C. 6 D.7 Bi 168: Amin thm ng vi cng thc phn t C7H9N c my ng phn ? A. 3 B. 4 C. 5 D. 6 Bi 169: Cho cc cht c cu to nh sau : (1) CH3 - CH2 - NH2 (2) CH3 - NH - CH3 (3) CH3 - CO - NH2 (4) NH2 - CO - NH2 (5) NH2 - CH2 - COOH(6) C6H5 - NH2 (7) C6H5NH3Cl (8) C6H5 - NH - CH3 (9) CH2 = CH NH2. Cht no l amin ? A. (1); (2); (6); (7); (8) B. (1); (3); (4); (5); (6); (9) C. (3); (4); (5) D. (1); (2); (6); (8); (9). Bi 170: Anilin tc dng c vi nhng cht no sau y ? (1) dung dch HCl (2) dung dch H2SO4 (3) dung dch NaOH (4) dung dch brom (5) dung dch CH3 - CH2 - OH (6) dung dch CH3COOC2H5 A. (1), (2), (3) B. (4), (5), (6) C. (3), (4), (5) D. (1), (2), (4) Bi 171: Pht biu no sau y sai ? A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn benzen ln nhm - NH2 bng hiu ng lin hp. B. Anilin khng lm thay i mu giy qu tm m. C. Anilin t tan trong H2O v gc C6H5 - k nc. D. Nh c tnh baz , anilin tc dng c vi dung dch brom. Bi 172: Phng php no thng dng iu ch amin ? A. Cho dn xut halogen tc dng vi NH3 B. Cho ru tc dng vi NH3 C. Hiro ho hp cht nitrin D. Kh hp cht nitro bng hiro nguyn t . Bi 173: Ru v amin no sau y cng bc ? A. (CH3)3COH v (CH3)3CNH2 B. C6H5NHCH3 v C6H5CHOHCH3 C. (CH3)2CHOH v (CH3)2CHNH2 D. (CH3)2CHOH v (CH3)2CHCH2NH2. Bi 174: Tm pht biu sai trong cc pht biu sau ? A. Etylamin d tan trong H2O do c to lin kt H vi nc B. Nhit si ca ru cao hn so vi hirocacbon c phn t khi tng ng do c lin kt H gia cc phn t ru. C. Phenol tan trong H2O v c to lin kt H vi nc. D. Metylamin l cht lng c mi khai, tng t nh amoniac. Bi 175: Trong s cc cht sau : C2H6 ; C2H5Cl; C2H5NH2; CH3COOC2H5; CH3COOH; CH3CHO; CH3OCH3 cht no to c lin kt H lin phn t ? A. C2H6 B. CH3COOCH3 C. CH3CHO ; C2H5Cl D. CH3COOH ; C2H5NH2 Bi 176: Metylamin d tan trong H2O do nguyn nhn no sau y ? A. Do nguyn t N cn cp electron t do d nhn H+ ca H2O. B. Do metylamin c lin kt H lin phn t.

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C. Do phn t metylamin phn cc mnh. D. Do phn t metylamin to c lin kt H vi H2O. Bi 177: Nguyn nhn gy nn tnh baz ca amin l : A. Do amin tan nhiu trong H2O. B. Do phn t amin b phn cc mnh. C. Do nguyn t N c m in ln nn cp e chung ca nguyn t N v H b ht v pha N. D. Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton. Bi 178: Dy sp xp ng theo th t gim dn tnh baz l dy no ? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. (1) > (3) > (5) > (4) > (2) > (6) B. (5) > (6) > (2) > (1) > (2) > (4) C. (5) > (4) > (3) > (5) > (1) > (2) D. (5) > (4) > (2) > (6) > (1) > (3) Bi 179: Trong bnh kn cha 35 ml hn hp gm H2, mt amin n chc v 40 ml O2. Bt tia la in phn ng chy xy ra hon ton ri a hn hp v iu kin ban u, th tch cc cht to thnh bng 20 ml gm 50% l CO2, 25% l N2 v 25% l O2. CTPT no sau y l ca amin cho ? A. CH5N B. C2H7N C. C3H6N D. C3H5N Bi 180: Nhiu phn t amino axit kt hp c vi nhau bng cch tch -OH ca nhm - COOH v -H ca nhm -NH2 to ra cht polime (gi l phn ng trng ngng). Polime c cu to mch : (- HN - CH2 - CH2 - COO - HN - CH2 - CH2 - COO - )n Monome to ra polime trn l : A. H2N - CH2 - COOH B. H2N - CH2 - CH2COOH C. H2N - CH2 - CH2 - CH2 - COOH D. Khng xc nh c Bi 181: S ng phn ca amino axit, phn t cha 3 nguyn t C l : A. 1 B. 2 C. 3 D. 4 Bi 182: X l mt amino axit no ch cha mt nhm NH2 v mt nhm -COOH. Cho 0,89 gam X phn ng va vi HCl to ra 1,255 gam mui. CTCT ca X l : CH3 CH COOH | A. NH2-CH2-COOH B. NH2 CH3 CH CH 2 COOH CH3 CH 2 CH 2 CH COOH | | D. NH2 NH2 Bi 183: T l sinh ra khi t chy hon ton mt ng ng X ca glixin l 6 : 7 (phn ng sinh ra kh N2). X tc dng vi glixin cho sn phm l ipeptit. X l : CH3 CH COOH CH3 CH 2 CH COOH | | A. B. NH2-CH2-CH2-COOH C. D. Kt qu khc NH2 NH2 Bi 184: Gi tn hp cht c CTCT nh sau theo danh php thng thng. CH3 CH 2 CH 2 CH 2 N CH 2 CH 3 | CH3 A. Etylmetyl amino butan C. n-butyletyl metyl amin B. Metyletyl amino butan D. metyletylbutylamin Bi 185: Gi tn hp cht c CTCT nh sau theo danh php thng thng : C.

A. 1-amino-3-metyl benzen. C. m-toludin. B. m-metylanilin. D. C B, C. Bi 186: Amin no sau y c tnh baz ln nht : A. CH3CH=CH-NH2 C. CH3CH2CH2NH2 B.CH3C = C-NH2 D. CH3CH2NH2 Bi 187: Cho cc cht sau : CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3). Tnh baz tng dn theo dy : A. (1) < (2) < (3) B. (2) < (3) < (1) C. (3) < (2) < (1) D. (3) < (1) < (2)

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Bi 188: Cho cc cht sau: p-CH3C6H5NH2(1), m-CH3C6H5NH2 (2), C6H5NHCH3 (3), C6H5NH2

(4). Tnh baz tng dn theo dy : A. (1) < (2) < (4) < (3) B. (4) < (2) < (1) < (3) C. (4) < (3) < (2) < (1) D. (4) < (3) < (1) < (2) Bi 189: Cho cc cht sau : p-NO2C6H4NH2 (1), p-ClC6H5NH2 (2), p-CH3C6H5NH2 (3). Tnh baz tng dn theo dy : A. (1) < (2) < (3) B. (2) < (1) < (3) C. (1) < (3) < (2) D. (3) < (2) < (1) Bi 190: C bao nhiu ng phn amin ng vi CTPT C4H11N ? A. 5 B. 6 C. 7 D. 8 Bi 191: Cho cc cht sau : Ru etylic (1), etylamim (2), metylamim (3), axit axetic (4). Sp sp theo chiu c nhit si tng dn : A. (2) < (3) < (4) < (1) B. (2) < (3) < (4) < (1) C. (3) < (2) < (1) < (4) D. (1) < (3) < (2) < (4) Bi 192: Cho cc dung dch : 1) HNO2 2) FeCl2 3) CH3COOH 4) Br2 Cc dung dch tc dng c vi anilin l : A. (1), (4) B. (1), (3) C. (1), (3), (4) D. C 4 cht Bi 193: Cho phn ng : X + Y => C6H5NH3Cl X + Y c th l : A. C6H5NH2 + Cl2. C. C6H5NH2 + HCl B. (C6H5)2NH + HCl. D. C A, B, C Bi 194: Cho s : (X) => (Y) => (Z) => M (trng). Cc cht X, Y, Z ph hp s trn l : A. X (C6H6), Y (C6H5NO2), Z (C6H5NH2) B. X (C6H5CH(CH3)2), Y (C6H5OH), Z (C6H5NH2) C. X (C6H5NO2), Y (C6H5NH2), Z (C6H5OH) D. C A v C Bi 195: Hy chn thuc th thch hp phn bit 3 cht kh sau : imetyl amin, metylamin, trimetyl amin. A. Dung dch HCl B. Dung dch FeCl3 C. Dung dch HNO2 D. C B v C Bi 196: Thuc th thch hp phn bit 3 cht lng : phenol, anilin, benzen l : A. Dung dch HNO2 B. Dung dch FeCl3 C. Dung dch H2SO4 D. Nc Br2 Bi 197: Phn ng no sau y sai ? C6H5NH2 + H2O => C6H5NH3OH (1) (CH3)2NH + HNO2 => 2CH3OH + N2 (2) C6H5NO2 + 3Fe + 7 HCl => C6H5NH3Cl + 3FeCl2 + 2H2O. (3)

(4) A. (1) (2) (4) B. (2) (3) (4) C. (2) (4) D. (1) (3) Bi 198: ti to li anilin t dung dch phenyl amoniclorua phi dng dung dch cht no sau y : A. Dung dch HCl B. Dung dch NaOH C. Dung dch Br2 D. C A, B, C Bi 199: t chy mt amin no n chc mch thng ta thu cCO2 v H2O c t l mol 8 : 11 .CTCT ca X l A. (C2H5)2NH B. CH3(CH2)3NH2 C. CH3NHCH2CH2CH3 D. C A , B , C Bi 200: Cho 11,8 g hn hp X gm 3 amin : n-propyl amin, etylmetylamin, trimetyl amin. Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l : A. 100ml B. 150 ml C. 200 ml D. Kt qu khc Bi 201: t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 (l) CO2 (ktc) v 7,2 g H2O. Gi tr ca a l : A. 0 ,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol Bi 202: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v 14,4 g H2O. CTPT ca hai amin l : A. CH3NH2 v C2H7N B. C3H9N v C4H11N C. C2H7N v C3H9N D. C4H11N v C5H13 N

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Bi 203: Cht no sau y ng thi tc dng c vi dung dch HCl v dung dch NaOH.

A. C2H3COOC2H5 B. CH3COONH4 C. CH3CHNH2COOH D. C A, B, C Bi 204: Mt hp cht hu c X c CTPT C2H7O2N. X d dng phn ng vi dung dch NaOH v dung dch HCl. CTCT ph hp ca X l : A. CH2NH2COOH C. HCOONH3CH3 B. CH3COONH4 D. C A, B v C Bi 205: Tng ng vi CTPT C3H9O2N c bao nhiu ng phn cu to va tc dng c vi dung dch NaOH va tc dng vi dung dch HCl. A. 3 B. 9 C.12 D.15 Bi 206: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc Bi 207: Cho 22,15 g mui gm CH2NH2COONa v CH2NH2CH2COONa tc dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch th lng cht rn thu c l : A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc Bi 208: Cho 13,35 g hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l : A. 100 ml B. 150 ml C. 200 ml D. 250 ml Bi 209: Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3CHNH2COOH) tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH 1M . Phn trm khi lng ca mi cht trong X l: A. 55,83 % v 44,17 % C. 53,58 % v 46,42 % B. 58,53 % v 41,47 % D. 52,59 % v 47,41% Bi 210: Cho 4,41 g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73 g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. Xc nh CTCT ca X. A. HOOC-CH2CH2CH(NH2)COOH B. CH3CH(NH2)COOH C. HOOCCH2CH(NH2)CH2COOH D. C A v C Bi 211: Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy hon ton a mol X thu c 6,72 (l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l : A. CH2NH2COOH B. CH2NH2CH2COOH C. CH3CH(NH2)COOH D. C B v C Bi 212: Cht no sau y c tnh baz mnh nht ? A. NH3 B. C6H5NH2 C. CH3-CH2-CH2-NH2 D. CH3-CH(CH3)-NH2 Bi 213: Mt amino axit no X ch cha mt nhm -NH2 v mt nhm -COOH. Cho 0,89 g X phn ng va vi HCl to ra 1,255 g mui. CTCT ca X l: A. H2N-CH2-COOH B. CH3-CH(NH2)-CH2-COOH C. H2N-CH2-CH2-COOH D. B, C, u ng. Bi 214: A + HCl => RNH3Cl. Trong ( A) (CxHyNt) c % N = 31,11% CTCT ca A l : A. CH3 - CH2 - CH2 - NH2 B. CH3 - NH - CH3 C. C2H5NH2 D. C2H5NH2 v CH3 - NH - CH3 Bi 215: L do no sau gii thch tnh baz ca monoetylamin mnh hn amoniac : A. Nguyn t N cn i electron cha to lin kt B. nh hng y electron ca nhm -C2H5 C. Nguyn t N c m in ln D. Nguyn t nit trng thi lai ho Bi 216: Nhng cht no sau y lng tnh : A. NaHCO3 B. H2N-CH2-COOH C. CH3COONH4 D. C A, B, C Bi 217: Ngi ta iu ch anilin bng cch nitro ho 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu bit rng hiu sut mi giai on u t 78%. A. 362,7 g B. 463,4 g C. 358,7 g D. 346,7 g Bi 218: 9,3 g mt ankylamin cho tc dng vi dung dch FeCl3 d thu c 10,7 g kt tA. CTCT l : A. C2H5NH2 B. C3H7NH2 C. C4H9NH2 D. CH3NH2 Bi 219: (A) l mt hp cht hu c c CTPT C5H11O2N. un (A) vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c (B). Cho hi qua CuO/t0 thu c cht hu c (D) c kh nng cho phn ng trng gng. CTCT ca A l :

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A. CH2 = CH - COONH3 - C2H5 B. CH3(CH2)4NO2 C. H2N- CH2 - CH2 - COOC2H5 D. NH2 - CH2COO - CH2 - CH2 - CH3 Bi 220: Dung dch etylamin c tc dng vi dung dch ca mui no di y : A. FeCl3 B. NaCl C. Hai mui FeCl3 v NaCl D. AgNO3 Bi 221: Sp xp cc hp cht sau y theo th t gim dn tnh baz : (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. (5) > (4) > (2) > (1) > ( 3) > (6) B. (1) > (3) > (5) > (4) > (2) > (6) C. (4) > (5) > ( 2) > (6) > ( 1) > (3) D. (5) > (4) > (2) > (6) > (1) > (3) Bi 222: Nhit si ca C4H10 (1), C2H5NH2 (2), C2H5OH (3) tng dn theo th t: A. (1) < (2) < (3) B. (1) < (3) < (2) C. (2) < ( 3) < (1) D. ( 2) < ( 1) < (3)

Phn 2: p n
CHUYN 1 : I CNG HA HC HU C
1A 11A 21B 31B 41A 51B 61D 71A 81C 91B 2B 12D 22B 32A 42C 52B 62BA 72B 82A 92B 3C 13B 23D 33B 43C 53C 63C 73C 83D 93B 4B 14A 24C 34B 44D 54C 64D 74A 84C 94C 5B 15B 25C 35A 45C 55B 65B 75A 85D 95C 6D 16B 26A 36D 46D 56C 66A 76A 86A 96B 7B 17A 27A 37C 47D 57C 67D 77C 87B 97C 8C 18A 28CD 38B 48B 58C 68A 78C 88C 98A 9D 19D 29A 39B 49A 59C 69D 79D 89A 99B 10C 20C 30D 40B 50C 60D 70A 80B 90C 100D

CHUYN 2 :
1B 11C 21A 31D 41C 51B 61D 2A 12B 22B 32A 42B 52C 62C 3C 13C 23D 33B 43A 53BD 63B 4B 14C 24D 34B 44A 54D 64A 5D 15B 25D 35C 45A 55A 65C

HIROCACBON NO
6D 16D 26C 36A 46D 56C 66D 7A 17A 27B 37A 47A 57B 67B 8DA 18B 28A 38D 48A 58D 68B 9B 19B 29B 39BC 49CC 59A 69D 10D 20C 30B 40D 50BD 60B 70DA

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CHUYN 3 : HIROCACBON KHNG NO

BI TP V ANKEN
1C 11C 21A 31B 41A 51D 61C 71B 81B 2C 12B 22C 32D 42B 52A 62B 72A 82B 3B 13A 23C 33C 43C 53A 63D 73A 83B 4C 14D 24B 34D 44D 54C 64A 74B 84D 5D 15C 25D 35A 45D 55A 65C 75C 85D 6D 16A 26A 36A 46A 56D 66C 76C 7C 17A 27D 37B 47B 57C 67D 77A 8C 18B 28B 38C 48AB 58C 68A 78C 9D 19C 29A 39B 49A 59A 69A 79A 10D 20C 30D 40B 50D 60A 70A 80D

BI TP V ANKAIEN -TECPEN - ANKIN

1D 11C 21B 31B 41C 51C 61D 71D 81A 2B 12C 22C 32B 42C 52C 62B 72A 82D 3D 13C 23D 33D 43D 53D 63D 73C 83A 4C 14A 24C 34C 44A 54A 64D 74C 84D 5A 15A 25C 35B 45D 55A 65B 75D 85C 6D 16B 26B 36C 46C 56C 66C 76B 86C 7A 17A 27B 37C 47B 57D 67A 77D 87B 8B 18D 28B 38C 48D 58A 68B 78A 88A 9C 19B 29A 39C 49C 59A 69D 79A 10A 20D 30B 40C 50D 60C 70A 80A

CHUYN 4 : HIROCACBON THM NGUN HIROCACBON THIN NHIN

1B 11B 21A 31C 41D 51D 61A 71B 2C 12A 22C 32A 42A 52D 62D 72C 3D 13C 23C 33C 43A 53B 63B 73B 4D 14C 24A 34B 44B 54C 64C 74C 5D 15A 25C 35D 45D 55C 65BA 75A 6A 16D 26B 36A 46C 56C 66A 76D 7C 17D 27A 37C 47D 57DA 67D 77A 8C 18D 28B 38A 48D 58D 68A 78B 9B 19D 29C 39C 49D 59A 69D 79B 10D 20A 30D 40A 50D 60C 70B 80AC

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CHUYN 5 : DN XUT HALOGEN-PHENOL-ANCOL

1A 11C 21B 31D 41D 51D 61D 71D 81D 91A 101A 111B 121C 131C 141A 151B 161B 171B 181B 2A 12B 22D 32B 42A 52D 62A 72D 82A 92C 102C 112D 122A 132D 142C 152C 162B 172A 182C 3C 13B 23C 33C 43B 53C 63A 73C 83D 93A 103C 113A 123A 133B 143B 153B 163A 173B 183A 4B 14D 24C 34C 44A 54A 64D 74B 84A 94D 104B 114B 124C 134AA 144C 154C 164B 174A 184D 5B 15A 25B 35B 45C 55D 65A 75C 85C 95B 105A 115B 125B 135A 145D 155B 165D 175D 185A 6A 16DD 26B 36B 46D 56C 66A 76B 86A 96B 106C 116C 126C 136B 146A 156C 166C 176D 186A 7A 17B 27A 37B 47D 57D 67C 77A 87C 97C 107A 117B 127A 137D 147D 157D 167D 177D 187B 8A 18A 28C 38C 48C 58C 68CB 78C 88B 98C 108D 118B 128C 138D 148B 158D 168D 178A 9C 19B 29D 39A 49B 59B 69B 79A 89C 99A 109A 119A 129B 139D 149A 159C 169B 179A 10AD 20A 30D 40C 50B 60A 70B 80D 90C 100D 110A 120C 130C 140D 150A 160AD 170C 180B

CHUYN 6 : ANEHIT-XETON-AXIT CACBOXILIC

1B 11B 21A 31A 41A 51B 61B 71D 81D 91AD 101A 111BB 121A 131B 141C 151A 161C 171A 2C 12B 22C 32D 42D 52B 62DAD 72B 82B 92B 102C 112A 122D 132A 142A 152B 162C 172A 3C 13A 23C 33A 43D 53C 63C 73D 83B 93C 103A 113A 123A 133B 143D 153C 163A 173C 4C 14A 24B 34D 44A 54D 64D 74CB 84D 94B 104C 114A 124A 134B 144B 154A 164D 174B 5D 15A 25C 35C 45C 55B 65D 75D 85D 95AB 105C 115B 125B 135D 145C 155B 165D 175B 6D 16BD 26C 36C 46C 56C 66BA 76C 86D 96C 106D 116C 126B 136D 146A 156B 166C 176A 7A 17D 27A 37C 47C 57A 67B 77C 87A 97C 107A 117B 127D 137B 147B 157C 167B 177A 8D 18A 28C 38D 48D 58A 68D 78B 88A 98C 108D 118A 128C 138B 148A 158A 168B 178C 9C 19C 29A 39D 49A 59BD 69C 79C 89A 99B 109C 119B 129A 139D 149C 159A 169B 179A 10D 20B 30A 40D 50C 60D 70A 80B 90CC 100D 110B 120A 130A 140A 150C 160B 170A 180D

CHUYN 7 : ANEHIT-XETON-AXIT CACBOXILIC

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1B 11B 21A 31A 41A 51B 61B 71D 81D 91AD 101A 111BB 121A 131B 141C 151A 161C 171A

2C 12B 22C 32D 42D 52B 62DAD 72B 82B 92B 102C 112A 122D 132A 142A 152B 162C 172A

3C 13A 23C 33A 43D 53C 63C 73D 83B 93C 103A 113A 123A 133B 143D 153C 163A 173C

4C 14A 24B 34D 44A 54D 64D 74CB 84D 94B 104C 114A 124A 134B 144B 154A 164D 174B

5D 15A 25C 35C 45C 55B 65D 75D 85D 95AB 105C 115B 125B 135D 145C 155B 165D 175B

6D 16BD 26C 36C 46C 56C 66BA 76C 86D 96C 106D 116C 126B 136D 146A 156B 166C 176A

7A 17D 27A 37C 47C 57A 67B 77C 87A 97C 107A 117B 127D 137B 147B 157C 167B 177A

8D 18A 28C 38D 48D 58A 68D 78B 88A 98C 108D 118A 128C 138B 148A 158A 168B 178C

9C 19C 29A 39D 49A 59BD 69C 79C 89A 99B 109C 119B 129A 139D 149C 159A 169B 179A

10D 20B 30A 40D 50C 60D 70A 80B 90CC 100D 110B 120A 130A 140A 150C 160B 170A 180D

CHUYN 8 : ESTE LIPIT CHT GIT RA

1 B 11 D 21 D 31 A 41 A 51 C 61 C 71 C 81 B 91 C 101 D 2 C 12 D 22 B 32 A 42 D 52 A 62 B 72 A 82 B 92 D 102 B 3 B 13 A 23 C 33 C 43 D 53 A 63 A 73 D 83 B 93 C 103 D 4 D 14 A 24 C 34 A 44 A 54 A 64 A 74 D 84 C 94 A 104 A 5 B 15 A 25 D 35 D 45 A 55 B 65 A 75 C 85 B 95 A 105 C 6 C 16 B 26 C 36 B 46 B 56 B 66 A 76 C 86 D 96 B 106 D 7 17 27 37 47 57 67 77 87 97 C C D C A C C D D D 8 18 28 38 48 58 68 78 88 98 C C A C C A A A C A 9 19 29 39 49 59 69 79 89 99 B D C B A B D C C A 10 A 20 B 30 D 40 A 50 B 60 A 70 C 80 D 90 D 100 A

CHUYN 9: CACBOHIDRAT
1 C 11 C 21 D 31 B 41 B 51 C 61 B 71 C 81 D 91 B 101 C 2 D 12 A 22 C 32 B 42 D 52 D 62 A 72 C 82 C 92 B 102 C 3 A 13 C 23 B 33 A 43 B 53 A 63 A 73 B 83 B 93 C 103 A 4 B 14 B 24 A 34 B 44 C 54 B 64 B 74 D 84 B 94 B 104 A 5 A 15 A 25 B 35 C 45 A 55 C 65 C 75 A 85 C 95 B 105 6 B 16 A 26 D 36 D 46 A 56 D 66 C 76 C 86 D 96 A 106 7 A 17 A 27 B 37 C 47 A 57 B 67 A 77 A 87 A 97 D 107 8 B 18 B 28 A 38 C 48 B 58 B 68 B 78 C 88 B 98 A 108 9 A 19 A 29 A 39 A 49 D 59 D 69 C 79 B 89 D 99 A 109 10 B 20 A 30 C 40 C 50 B 60 C 70 D 80 B 90 C 100 B 110

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CHUYN 10: AMIN AMINOAXIT PROTEIN

1.C 9.D 17.C 25.D 33.D 41.B 49.B 57.A 65.A 73.C 81.D 89.A 97.A 105.A 113.B 121.C 129.B 137.C 145.D 153.C 161.B 169.D 177.D 185.D 193.C 201.B 209.A 217.A 2.C 10.C 18.C 26.D 34.B 42.D 50.A 58.B 66.D 74.C 82.A 90.C 98.A 106.C 114.B 122.D 130.B 138.B 146.D 154.C 162.D 170.D 178.D 186.C 194.D 202.C 210.D 218.D 3.D 11.C 19.B 27.B 35.A 43.B 51.A 59.C 67.D 75.A 83.D 91.D 99.A 107.B 115.A 123.C 131.B 139.D 147.B 155.B 163.B 171.D 179.A 187.C 195.D 203.D 211.A 219.D 4.B 12.B 20.B 28.B 36.C 44.A 52.A 60.B 68.A 76.D 84.B 92.A 100.D 108.D 116.B 124.C 132.D 140.B 148.B 156.B 164.B 172.D 180.B 188.B 196.B 204.A 212.C 220.A 5.C 13.D 21.D 29.B 37.A 45.A 53.A 61.A 69.A 77.A 85.B 93.A 101.A 109.B 117.B 125.C 133. 141.A 149.B 157.A 165.D 173.B 181.D 189.A 197.D 205.C 213.C 221.D 6.B 14.A 22.C 30.A 38.B 46.A 54.C 62.D 70.D 78.A 86.C 94.D 102.B 110.A 118.D 126.B 134.D 142.B 150.C 158.D 166.A 174.D 182.B 190.D 198.B 206.C 214.C 222.B 7.B 15.D 23.B 31.D 39.C 47.B 55.B 63.A 71.D 79. 87.A 95.C 103.B 111.B 119.B 127.C 135.C 143.C 151.A 159.D 167.B 175.D 183.B 191.C 199.D 207.A 215.B 8.B 16.A 24.B 32.B 40.A 48.D 56.C 64.C 72.C 80.C 88.D 96.C 104.D 112.D 120.A 128.D 136.A 144.C 152.D 160.B 168.C 176.A 184.C 192.A 200.C 208.D 216.D

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