CHNG V

OXI LU HUYNH
LY THUYET I. OXI OZON HYDRO PEOXIT 1. Viet 2 phng trnh phan ng cho moi trng hp sau: a. Oxi tac dung vi kim loa b. Oxi tac dung vi phi kim c. Oxi tac dung vi hp chat hu c d. 5 phng trnh phan ng co sinh ra kh oxi 2. Oxi tac dung c vi nhng chat nao sau nay, viet phng trnh phan ng minh hoa: H2, S, C, Cl2, Fe, Cu, Ag, Au, SO2, SO3, CH4, CO, CO2, FeO, Fe2O3. 3. Hay dan ra nhng phan ng hoa hoc chng minh: a. Oxi va ozon cung co tnh oxi hoa nhng ozon co tnh oxi hoa manh hn oxi. b. Nc va hydro peoxit cung co tnh oxi hoa nhng hydro peoxit co tnh oxi hoa manh hn nc 4. Neu hien tng, giai thch va viet phng trnh phan ng minh hoa khi cho kh O3 i qua dung dch kali iotua pha ho tinh bot. 5. Viet phng trnh phan ng minh hoa tnh kh va tnh oxi hoa cua hydro peoxit (moi tnh chat 2 phng trnh) 6. Viet phng trnh phan ng thc hien chuoi bien hoa sau, ghi ro ieu kien neu co H2O2 H2O2 KMnO4 O2 O3 O2 CO2 Na2CO3 NaNO3 O2 KClO3 7. Trnh bay phng phap nhan biet 3 lo ng kh mat nhan cha: oxi, ozon, kh cacbonic (khong s dung que om). II. LU HUYNH HYDRO SUNFUA HP CHAT CO OXI CUA LU HUYNH 1. Viet cac phng trnh hoa hoc cho moi trng hp sau: a. H2S the hien tnh kh ( 3 phng trnh ) b. SO2 the hien tnh kh, tnh oxi hoa, khong the hien tnh kh va tnh oxi hoa ( moi y 2 phng trnh)

2. Co cac dung dch loang cua cac muoi sau: NaCl, KNO3, Pb(NO3)2, FeCl2, CuSO4, FeCl3. Hay cho biet co hien tng g xay ra va giai thch khi cho: a. Dung dch Na2S vao moi dung dch tren b. Kh H2S i vao moi dung dch muoi tren. 3. Giai thch v sao khi ieu che H2S hoac SO2 t FeS hoac Na2SO3 ngi ta ch dung HCl hoac H2SO4 loang ma khong s dung HNO3 hay H2SO4 ac nong. Viet phng trnh phan ng minh hoa. 4. Dung phng phap hoa hoc hay nhan biet: a. Cac kh CO2, SO2, H2S. b. Cac dung dch NaCl, Na2SO4, Na2SO3, Na2CO3 c. HCl, H2SO4, K2SO4, K2SO3. d. Dung quy tm va mot thuoc th thch hp e nhan biet 4 dung dch: HCl, HI, K2S, NaNO3. e. Dung them 1 thuoc th phan biet 5 dung dch: BaCl2, MgSO4, Na2SO3, KNO3, K2S. f. Khong dung them thuoc th phan biet: NaCl, K2CO3, Na2SO4, HCl, Ba(NO3)2 5. Cho cac nguyen lieu: muoi an, quang pirit, nc va khong kh. Hay viet cac phng trnh ieu che: muoi sat (III) sunfat va sat (III) clorua. 6. Viet cac phng trnh phan ng theo chuoi bien hoa sau: a. FeS2 SO2 SO3 H2SO4 SO2 S FeS H2S SO2 S b. Na2SO3 SO2 H2SO4 S H2S H2SO4 FeSO4 Fe2(SO4)3 c. FeS H2S S SO2 H2SO4 S FeS Fe2(SO4)3. d. H2S S H2S K2S ZnS H2S H2SO4 H2S KCl KF 7. Bo tuc cac phan ng sau va goi ten cac chat: H2S + kh X ran A + long B A + X kh C B + C + kh D long E + long F Cu + E long G + C + B F + ran H H2S + ZnCl2. 8. Nhng cap chat nao sau ay co the ton tai c trong mot dung dch a. Na2SO4 + CuCl2 c. MgSO4 + BaCl2 b. HCl + H2SO4 loang d. Pb(NO3)2 + CuSO4

e. NaOH + H2SO4 f. BaCl2 + Na2S TOAN I. OXI OZON HYDRO PEOXIT

g. NaOH + (NH4)2SO4 h. Cu + FeCl3

1. Khi phan huy 136,7g hon hp kalo clorat va kali pemanganat thu c 24,64 lt oxi (ktc). Xac nh thanh phan phan tram cua hon hp ban au. 2. Hon hp kh ozon va oxi co t khoi hi oi vi hydro bang 18. Hay xac nh thanh phan phan tram theo the tch cua hon hp kh. 3. Dan 2,24 lt hon hp kh ktc gom oxi va ozon i qua dung dch KI d thay co 12,7g chat ran mau tm en. Tnh thanh phan phan tram theo the tch cac kh trong hon hp. 4. Sau khi ozon hoa mot the tch oxi thay the tch oxi giam i 5ml. Hoi co bao nhieu ml ozon c tao thanh. 5. Oxi hoa hoan toan 10,2g hon hp gom Al va Mg th can va u 5,6 lt oxi (kc) a. Tnh thanh phan % khoi lng moi kim loai trong hon hp tren b. Tnh khoi lng KClO3 can dung e ieu che lng oxi tren. 6. Co hon hp kh oxi va ozon. Sau mot thi gian, ozon b phan huy heat, ta c mot chat kh duy nhat co the tch tang them 2%. Xac nh thanh phan phan tram theo the tch cua hon hp kh ban au. Biet cac kh o cung ieu kien nhiet o va ap suat. II. LU HUYNH HYDRO SUNFUA HP CHAT CO OXI CUA LU HUYNH 1. Nung 5,6g sat va 1,6g bot lu huynh. San pham tao thanh cho vao 500 ml dung dch HCl thu c mot hon hp kh A va mot dd B. a. Tnh t khoi hi cua hon hp kh A oi vi hydro b. e trung hoa HCl con tha trong dung dich B phai dung 125ml dung dch NaOH 0,1M. Tnh nong o mol cua dd HCl a dung.

2. Nung hoan toan 9,6g bot lu huynh vi 6.75g bot nhom thu c hon hp ran A. Hoa tan hon hp ran A va dd axit HCl d thu c hon hp kh X. a. Tnh khoi lng moi chat ran trong A va the tch kh X ktc b. Neu cho toan bo kh X tren ay vao dung dch AgNO3 d, tnh khoi lng ket tua hnh thanh. 3. Hoa tan hon hp thu c khi nung bot Al va bot S (trong ieu kien khong co khong kh ) bang dung dch axit HCl d thay con lai 0,04g chat ran va co 1,344 lt kh thoat ra (ktc). Khi cho toan bo kh o i qua dung dch Pb(NO3)2 th tao thanh 7,17g ket tua en. a. a.Viet cac phng trnh phan ng co the xay ra. b. Tnh khoi lng Al, S trc khi em nung. 4. Cho hon hp Fe va FeS tac dung dung dch HCl (d) thu c 2,464 lt hon hp kh (ktc). Dan hon hp kh nay i qua dung dch Pb(NO3)2 d sinh ra 23,9g ket tua en. a. a.Viet phng trnh hoa hoc cua cac phan ng xay ra b. Tnh thanh phan % theo khoi lng cac chat trong hon hp ran ban au. 5. Tnh nong o mol cua cac muoi tao thanh trong dung dch sau phan ng khi cho: a. 2,24 lt kh H2S loi qua 30g dung dch NaOH 20% (D=1,225g/ml) b. 2,24 lt kh H2S loi qua 75ml dung dch NaOH 2M. (gia s the tch dung dch khong oi) 6. Tnh khoi lng cac muoi tao thanh sau phan ng khi cho: a. 12,8g SO2 tac dung vi 50ml dung dch NaOH 25% (D=1,28g/ml) b. Hap thu hoan toan 12,8g SO2 vao 250ml dung dch NaOH 1M. 7. Cho 20,8g hon hp Cu va CuO tac dung vi H2SO4 ac nong u th thu c 4,48 lt kh (ktc) a. Tnh khoi lng moi chat trong hon hp b. Tnh khoi lng dung dch H2SO4 80% can dung. 8. Hoa tan mot oxit kim loai hoa tr 2 bang mot lng va u dung dch axit H2SO4 10% thu c dung dch muoi co nong o 11,8%. Xac nh ten kim loai.

9. Hoa tan 1,12g hon hp gom Ag va Cu trong 19,6g dung dch H2SO4 ac, nong (dung dch A) thu c SO2 hap thu het vao nc Br2. Sau o them Ba(NO3)2 d th thu c 1,864g ket tua. a. Tnh khoi lng Ag, Cu ban au b. Tnh nong o % cua dung dch A biet rang ch co 10% H2SO4 trong dung dch A a phan ng vi Ag va Cu. 10. Trong cong nghiep, H2SO4 c ieu che t FeS2 a. Viet cac phng trnh ieu che H2SO4 t FeS2 b. Tnh lng axit 98% ieu che c t 1 tan quang cha 60% FeS2 biet hieu suat cua qua trnh la 70%. 11. Can bao nhieu tan quang pirit sat cha 35,6% FeS2 e san xuat 700 tan dung dch H2SO4 70% biet rang s hao hut trong san xuat la 4%. 12. Hoa tan hoan toan 13g mot kim loai A hoa tr (II) vao H2SO4 loang ta thu c 4,48 lt kh H2 (ktc) a. nh ten kim loai A b. nh the tch kh SO2 thu c (ktc) neu hoa tan 13g kim loai A vao H2SO4 ac nong. 13. Hoa tan 11,5g hon hp Cu, Mg, Al vao dung dch HCl th thu c 5,6 lt kh (ktc) va phan khong tan. Cho phan khong tan vao H2SO4 ac nong th thu c 2,24 lt kh (ktc). Xac nh % khoi lng moi kim loai trong hon hp. 14. Cho 4,98g hon hp Na2SO4, Na2SO3 va NaHSO3 vao dung dch H2SO4 d thu c 0,672 lt kh bay ra (ktc). Neu cho 2,49g hon hp ay vao 10ml dung dch NaOH 0,5M th phan ng xay ra va u. Tnh % theo khoi lng cac chat trong hon hp ban au.