A/-L THUYT I/- Kin thc cn nm vng:

- Bit xc nh cht in li mnh, in li yu, khng in li, vit phng trnh in li - Xc nh axt, baz theo thuyt Areniut (hoc theo thuyt Bronsted SGK nng cao), Tnh pH

dd - Vit phng trnh phn t, ion, ion thu gn cc phn ng trong dd cht in li. - Nhn bit cc cht, cc ion trong dd, cc l kh mt nhn.
-Nm vng tnh cht ha hc: N2, NH3, mui amoni, axt HNO3, mui nitrat, P, axt photphoric, mui photphat, C, Si, CO, CO2,SiO2, H2CO3, mui cacbonat - Nm c cu to, tnh cht vt l, ng dng cc cht trn, cch iu ch v ng dng - iu ch v ng dng cc cht: N2, P,C, Si, NH3, CO, CO2, SiO2, axt HNO3, axt H3PO4, H2CO3, H2SiO3 - Tnh tan ca cc mui: NH4+, NO3-, PO43-, CO3-... - Nm c thnh phn, tnh cht , ng dng ca cc loi phn bn ha hc, thy tinh, gm, xi mng

II/- Luyn tp
Cu 1/- Cho cc hp cht sau: Na2SO4, HCl, H2S, HF,H2SO4, H2CO3, NaHCO3, Na2CO3, H3PO4, NaH2PO4, Na2HPO4, ,CH3COOH, C2H5OH, NaCl, CH3COONa, Zn(OH)2, Al(OH)3, HClO, HClO4, HNO3, NaOH, KOH, NH4OH, H2SO3, NH4Cl, (NH4)2SO4, H2S, K3PO4, 1/ Hy ch ra nhng cht sau y, cht no l in ly mnh, in li yu, khng in li: 2/ Vit phng trnh in li ca cc cht in li mnh, in li yu trn Cu 2/- Vit phng trnh phn t, phng trnh ion v ion thu gn t cc cp cht sau: 1. BaCl2 v AgNO3 2. NaHCO3 v HCl 3.NaOH v MgCl2 4.KOH v BaCl2 5. BaCl2 v Na2CO3 6. FeS v HCl 7. NaHCO3 v NaOH 8.FeCl3 v NaOH 9.Zn(OH)2 v NaOH 10. Al(OH)3 v HCl 11. Al(OH)3 v KOH 12. Ba(OH)2v NH4Cl Cu 3/- Hon thnh cc chui phn ng sau: 1/ NH4Cl --> NH3-->N2--> NO2--> HNO3--> NaNO3 --> NaNO2 2/ NO2 --> HNO3 --> Cu(NO3)2 --> Cu(OH)2 --> Cu(NO3)2 --> CuO--> Cu --> CuCl2 3 4 5 Fe(OH)3 Fe(NO3)3 Fe2O3 Fe(NO3)3 6 1 7 8 9 10 (NH4)2CO3 NH 3 NO NO2 HNO3 Al(NO3)3 Al2O3 12 13 14 HCl NH4Cl NH3 NH4HSO4

3/ Ca3(PO4)2-->H3PO4 --> NaH2PO4--> Na2HPO4 --> Na3PO4--> Ag3PO4 4/ P--> P2O5 --> H3PO4 --> Ca3(PO4)2 --> H3PO4 --> CO2
5/ CO-->CO2-->NaHCO3-->Na2CO3-->CaCO3-->CO2-->CO-->Cu-->Cu(NO3)2--> CuO

6/ C-->CO2--> Na2CO3-->NaOH-->Na2SiO3-->H2SiO3 Cu 4/ -So snh tnh cht ha hc ca cc cht sau: 1/ N2 , P, C v Si 2/ HNO3, H3PO4 , H2CO3 v H2SiO3 Cu 5/- Bng phng php ha hc nhn bit cc dung dch trong cc l mt nhn sau: 1/ NaCl, NaNO3, Na2S, K2SO4, K3PO4, NH4NO3 2/ Na2CO3, MgCl2, NaCl, Na2SO4 3/ NH4)2SO4, NH4NO3, FeSO4, MgCl2, Cu 6/- Bng PUHH chng minh s c mt cc ion trong dd: Ca2+, NH4+ Mg2+, SO42-, NO3-, PO43Cu 7/- Ch dng H2O v CO2 nhn bit cc cht rn: NaCl, Na2CO3, Na2SO4, BaCO3, BaSO4 Bi tp ho hc 11

Cu 8/- Bng phng php ha hc nhn bit cc kh trong cc l mt nhn sau: N2, O2, NO, NO2, NH3, CO2, H2S

Lu : Cc em n tp bm st ni dung SGK trc khi rn luyn lm cc dng l thuyt, bi tp theo cng hng dn n tp.

Chuc cac em on tap at ket qua tot

Cu 1/- Cho cc hp cht sau: Na2SO4, HCl, H2S, HF,H2SO4, H2CO3, NaHCO3, Na2CO3, H3PO4, NaH2PO4, Na2HPO4, ,CH3COOH, C2H5OH, NaCl, CH3COONa, Zn(OH)2, Al(OH)3, HClO, HClO4, HNO3, NaOH, KOH, NH4OH, H2SO3, NH4Cl, (NH4)2SO4, H2S, K3PO4, 1/ Hy ch ra nhng cht sau y, cht no l in ly mnh, in li yu, khng in li: 2/ Vit phng trnh in li ca cc cht in li mnh, in li yu trn

B/- BI TP
N TP Cu 1/-Trong cng iu kin v nhit v p sut, 0,29 g kh B c cng th tch vi 0,13 g axetylen. Tm MB Cu 2/- iu kin th nghim 17oC v 87cmHg, cho st kim loi ho tan v dd HCl 1M th thu c 360ml kh.Tm lng st phn ng v th tch dd HCl cn dng. Cu 3/-Cho 17,75 gam dd Na2SO4 8% tc dng vi 31,2 gam dd BaCl 2 10%. Sau khi loi b kt ta, dung dch cn li 40ml a/ Tnh khi lng ring ca dung dch b/Tnh CM cc cht trong dd sau phn ng. Cu 4/-Cho 6,2 gam hh Na v K vo 194 gam nc c 2,24 lt kh H2 (ktc) a/ Tnh khi lng mi kim loi b/ Tnh C% cc cht trong hh thu c? Cu 5/-Trn 2 lt dd HCl 4M vo vo mt lt dd HCl 0,5M. Tnh nng mol/l ca dd mi. Cu 6/-Trn 150 gam dd NaOH 10% vo 460 gam dd NaOH x% to thnh dd 6%.Tnh x Cu 7/- Trn 0,5 lt dd NaCl ( D=1,01 g/ml) vo 100 gam dd NaCl 10% ( D=1,1 g/ml). Tnh nng % v nng mol/l ca dd sau khi trn. Cu 8/- Ha tan hon ton 10,2 gam mt kim loi oxt ha tr 3 cn 331,8 gam dd H 2SO4 th va . Dung dch sau phn ng c nng 10%. a/ Tm tn kim loi b/ Tnh C% ca dung dch axt. Cu 9/- Ha tan 25 gam CaCl2.6H2O trong 300 ml nc. Dung dch thu c c khi lng ring 1,08 g/ml. Tnh nng % v nng mol/l ca dd. Cu 10/- Ha tan hn hp sau khi nung 26 gam CaCO3 bng dd HCl d, cho tt c cc kh thot ra hp th vo 400 ml dd NaOH nng a% (D=1,18 g/ml), sau thm lng d BaCl 2 to thnh 18,75 gam kt ta. Tnh a. Bi 11/- Cho hn hp Zn v Na2CO3 vo 200 ml dung dch HCl thy thot ra hn hp kh c t khi hi i vi H2 l 11,5. Tnh % khi lng hn hp u. Bit CM ca axt l 0,75 mol.

S IN LI Vit cng thc cc cht m khi in li to ra cc ion:

a/ K+ v CrO422+ C/ Mg v MnO4
3+

b/ Fe3+ v NO3d/ Al v SO42-

bit

* Cu 1/- Ha tan 58,8 g H2SO4 vo H2O c 300 ml dung dch. Tnh Cm ca cc ion trong dd =50% Cu 2/- Tnh CM cc ion trong dung dch mi khi: a/ Trn 200ml dd KCl 1M vi 300 ml dd K2SO4 0,05M b/ Trn 200 ml dd NaOH 30% (D=1,2 g/ml) vi 300 ml dd NaOH 2M

Bi tp ho hc 11

c/ trn 50 ml dd NaOH 0,5M vi 150 ml dd HCl 1M Cu 3/- Cn ly bao nhiu ml dd HCl 2M trn vi 180 ml dd H 2SO4 3M cdd mi c [H+] = 4,5 M ( gi s cc cht in li hon ton) Cu 4/- Tnh th tch dd KOH 14% (D=1,128 g/ml) cha s mol OH- bng s mol OH- trong 0,2 lt dd NaOH 0,5M Cu 5/- Ho tan 12,5 g CuSO4.5H2O vo nc to thnh 200ml dd. Tnh CM cc ion c trong dung dch. Cu 6/- Ha tan hon ton 1,32 g (NH4)2SO4 v 4,28 g NH4Cl vo H2O c 250 ml dd A. Tnh nng mol/l cc ion trong dung dch ( th tch thay i khng ng k) Cu 7/- Ho tan hh gm 1,7 gam Natri v 2,61 gam Ba(NO3)2 vo nc c 100 ml dung dch A. Tnh nng mol/l v nng mol/l ion cc cht trong dd A. Gi thit s in li xy ra hon ton. Cu 8/- Thm 500ml H2O vo 250 ml dd NaOH 20% ( D=1,2 g/ml). Tnh nng mol/l v nng % ca dd mi. Cu 9/- Tnh lng HCl cn ha tan trong 250 gam nc c dung dch 25%? Cu 10/- Phi ha tan bao nhiu ml dd HCl 1,6M vi 20 ml dung dch HCl 0,5 M c dd 0,6M Cu 11/- Cho 31,4 gam hn hp hai mui NaHSO3 v Na2CO3 vo 400 gam dung dch H2SO4 9,8% ng thi un nng dung dch thu c hn hp kh A c t khi hi so vi H 2 bng 28,66 v 1 dd X. Tnh C% cc cht trong dd X. Cu 12/- Tnh pH ca cc dung dch sau:( cc cht phn li hon ton) 1/ Dung dch HCl 0,01M 2/ Dung dch Ba(OH)2 0,005M Cu 13/-Mt dung dch H2SO4 c pH=4. Tnh nng mol/l ca cc ion trong dd. Cu 14/- Cho dd c pH=13. Hi s mol ion H+ cha trong 1ml dd trn l bao nhiu? Cu 15/-Dung ndch Ba(OH)2 c [Ba2+] = 5.10-4. Tnh pH cua dd

Cu 16/- Tnh nng mol/l ca cc ion c trong: 1/ Dung dch Ba(OH)2 0,02M 2/ 1,5 lt dd c 5,58 g NaCl v 11,1 g CaCl2 3/ Dung dch HNO310%( D=1,054 g/mol) Cu 17/- Cho 50ml dd Ba(OH)2 2M. Tnh nng mol ion OH- trong dd thu c khi: 1/ Thm vo dd trn 50cm3 nc. 2/ un nng dd trn th tch dd cn li mt na 3/ Thm vo dd trn 50ml dd NaOH 1M Cu 18/- Tnh nng mol ca cc ion khi trn 100ml BaCl20,5M vi 50g dd H2SO4 24,5% (D=1,25g/ml) Cu 19/- Trong dd cha a mol Ca2+, b mol Na+, c mol Cl- v d mol NO31/ Lp biu thc lin h gia a,b,c,d 2/ Nu a= 0,01, b= 0,02, c=0,02 th d bng bao nhiu. Cu 20/- Cho 60ml dd NaOH 8% ( D=1,109 g/ml) vo 50 ml dd HCl 10% (D=1,047g/ml) 1/ Tnh nng % dd thu c 2/ Tnh nng mol/l cc ion trong dd thu c ( gi s V khng i) Cu 21/-Trn ln 80ml dd KOH 0,45M vi 35 ml dd H2SO4 0,8M th thu c dd D 1/ Tnh nng mol/lt cc ion trong dd D 2/ Tnh th tch dd Ba(OH)2 0,6M cn trung ha dd D. Cu 22/-Trn ln 100ml dd H2SO4 0,05M vi 150ml dd HCl 0,1M ta c dd D. 1/ Tnh nng mol/l cc ion trong dd 2/ Tnh pH ca dd 3/ Trung ha 300ml dd D cn 100ml dd KOH. Tnh nng mol/l ca dd KOH dng Cau 1: Viet phng trnh phan t, phng trnh ion xay ra trong cac trng hp sau:
Bi tp ho hc 11

Al + ddHCl;

Fe + dd CuCl2;

CaCO3 + ddHCl;

ddNa2SO4 + dd BaCl2; ddNaOH + dd FeCl3. Zn(OH)2 + ddNaOH; Zn(OH)2 + HCl; Al(OH)3 + HCl; Al(OH)3 + KOH; Cu(OH)2 + H2SO4; Cu(OH)2 + NaOH c; CuCl2 + KOH; Cu 2: Vit phng trnh ion rt gn ca cc phn ng xy ra trong dung dch gia cc cp cht sau: a) Ca(HCO3)2 + Ca(OH)2. b) Ca(HCO3)2 + HCl. c) Pb(NO3)2 + H2S. d) Pb(OH)2 + NaOH. Cu 3: Vit phng trnh in li cc cht sau trong dung dch: Na2HPO4, K2S, KHS, Sn(OH)2, HNO2, H2SO3, NaHSO4. Cu 4: Dung dch cht no di y c mi trng kim? Gii thch. AgNO3, NaClO3, Na2CO3, SnCl2, K2SO4. Cu 5: Vit phng trnh in li cc cht sau: K3PO4; Pb(OH)2; HClO; NaH2PO4, [Ag(NH3)2]2SO4, [Cu(NH3)4]Cl2. Cu 6: Trong cc mui sau: Na2SO4, NaHSO4, Na2HPO3, Na2HPO4 mui no l mui axit, mui no l mui trung ha? Gii thch. Cu 7: Cho: Fe, Al2O3, Fe(OH)2, Na2CO3 ln lt tc dng vi dung dch axit HCl. Hy vit cc phn ng xy ra dng phn t v dng ion rt gn. Cu 8: Trong 2 dung dch mi trng hp sau y, dung dch no c pH ln hn. Gii thch ? a) Dung dch 0,1M ca mt axit mt nc c K = 1.10-4 v dung dch 0,1M ca mt axit mt nc c K = 4.10-5. b) Dung dch HCl 0,1M v dung dch HCl 0,01M. c) Dung dch CH3COOH 0,01M v dung dch HCl 0,01M. d) Dung dch H2SO4 0,01M v dung dch HCl 0,01M e) Dung dch NH3 0,01M v dung dch NaOH 0,01M. g) Dung dch Ba(OH)2 0,01M v dung dch NaOH 0,01M. Cu 9: Trn 200 ml dung HCl 1M vi 300 ml dung dch Ba(OH)2 1M th c dung dch A. a) Vit phng trnh phn ng xy ra (dng phn t v ion). b) Tnh nng mol/ l ca cc ion c trong dung dch sau phn ng. Cu 10: Dung dch CH3COOH 0,6% (d = 1). in li ca CH3COOH trong iu kin ny l 1%. a) Tnh nng mol ca ion H+ trong dung dch trn. b) Tnh hng s phn li Ka iu kin trn. S: [H+] = 0,001M; Ka = 10-5. Cu 11: Dung dch X cha HCl 1M v H2SO4 1M; dung dch Y cha NaOH 1M v Ba(OH)2 0,5M. a) Tnh nng mol ca cc ion trong dung dch X v trong dung dch Y. b) Trn 100 ml dung dch X vi 300 ml dung dch Y th c 400 ml dung dch Z v m gam kt ta. Hy tnh: + Nng mol ca cc ion trong dung dch Z. + Gi tr m. Cu 12: Trong 2 lt dung dch axit flohiric (HF) c cha 4 gam HF nguyn cht. in li ca axit ny l 8%. Hy tnh hng s phn li Ka ca axit ny. S: 6,9.10-4. Cu 13: Trn 50 ml dung dch NaCl 0,1M vi 150 ml dung dch CaCl2 0,2M. Tnh nng mol/lt ca ion Cl- trong dung dch sau khi trn. Cu 15: Cn bao nhiu gam NaOH pha ch 500,0 ml dung dch c pH = 11,0.
Bi tp ho hc 11

Cu 16: Ha tan hon ton 0,2044 gam mt mui kim loi ha tr hai MCO 3 trong 40,0 ml dung dch HCl 0,080M. trung ha lng HCl d cn 5,64 ml dung dch NaOH 0,20M. a) Vit cc phn ng ha hc xy ra. b) Xc nh kim loi M. Cu 17: Tnh nng mol ca cc ion H+ v OH- trong dung dch NaNO2 1,0M, bit rng hng s phn li baz l Kb = 2,5.10-11. Cu 18: Cho V lt dung dch NaOH 2M vo 500 ml dung dch ZnSO 4 1M, hy xc nh gi tr ca V trong cc trng hp sau y: a) To kt ta cc i. b) To 19,8 gam kt ta. c) Gi tr t nht ca V khng thu c kt ta. Cu 19: imetyl amin (CH3)2NH l mt baz mnh hn NH3. imetyl amin trong nc c phn ng thy phn: (CH3)2NH + H2O (CH3)2NH2+ + OH-. a) Vit biu thc tnh hng s phn li baz Kb ca imetyl amin. b) Tnh pH ca dung dch imetyl amin 1,5M, bit Kb = 5,9.10-4. Cu 20: Cho 2 dung dch H2SO4 c pH = 1 v pH = 2. Thm 100 ml dung dch KOH 0,1M vo 100 ml mi dung dch trn. Tnh nng mol / l ca cc dung dch thu c. ( p s : [K2SO4] = 0,025M ; [K2SO4] = 0,0025M ; [KOH] = 0,045M ) Cu 21: Cho dung dch A l hn hp H 2SO4 2.10-4 M v HCl 6.10-4 M . Cho dung dch B l hn hp NaOH 3.10-4 M v Ca(OH)2 3,5.10-4 M . a) Tnh pH ca dung dch A v dung dch B ? ( S : 3 ; 11 ) b) Trn 300 ml dung dch A vi 200 ml dung dch B c dung dch C. Tnh pH ca dung dch C ? ( S : 3,7 ) Cu 22: A l dung dch HCl 0,2M. B l dung dch H 2SO4 0,1M. Trn cc th tch bng nhau ca A v B c dung dch X. Tnh pH ca dung dch X. (p s : 0,7) Cu 23: Trn 3 dung dch H2SO4 0,1M , HNO3 0,2M , HCl 0,3M vi nhng th tch bng nhau ta c dung dch A. Ly 300 ml dung dch A cho tc dng vi mt dung dch B NaOH 0,2M v KOH 0,29 M. Tnh th tch dung dch B cn dng sau khi tc dng vi 300 ml dung dch A c dung dch c pH = 2. ( p s : 0,134 lt ). Cu 24: Thm t t 100 g dung dch H2SO4 98% vo nc v iu chnh c 1 lt dung dch A. a) Tnh [H+] trong dung dch A. b) Phi thm vo 1 lt dung dch A bao nhiu lt dung dch NaOH 1,8M thu c : -Dung dch c pH = 1. -Dung dch c pH = 13. ( p s : 2M ; 1 lt ; 1,235 lt ) Cu 25: Trn 250 ml dung dch hn hp gm HCl 0,08M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 a mol/l thu c m gam kt ta v 500 ml dung dch c pH = 12. Tnh a v m. ( S : 0,06M ; 0,5825 g ) Cu 26: a) Cn pha long dung dch NaOH c pH = 12 bao nhiu ln c dung dch NaOH mi c pH = 11. b) Cn pha long dung dch HCl c pH = 1 bao nhiu ln c dung dch HCl mi c pH=3 c) Phi ly mt dung dch HCl c pH = 1 v mt dung dch NaOH c pH = 12 theo t l th tch no c dung dch c : pH = 3 ; pH = 11 ; pH = 7. Cu 27: Phi ly bao nhiu gam H2SO4 thm vo 2 lt dung dch axit mnh c pH = 2 c dung dch c pH=1. Gi s th tch dung dch thay i khng ng k. ( S : 8,82 g ) Cu 28: Ha tan hon ton m gam BaO vo nc c 200 ml dung dch A c pH = 13. a) Tnh m ?
Bi tp ho hc 11

b) Cho 0,27 gam bt nhm v 0,51 gam bt nhm oxit tan ht trong 400 ml dung dch A trn c dung dch B. Tnh nng mol/l cc cht trong dung dch B.( S : 1,53 gam ; 0,025M ; baz d 0,025M ) Cu 29: Trn 150 ml dung dch HCl a mol/l vi 250 ml dung dch cha ng thi NaOH 0,5M v Ba(OH)2 0,1 M c dung dch mi c pH = 12. Tnh a? ( S : 1,14 M ) Cu 30: Cho a gam kim loi Na vo nc c 1,5 lt dung dch X c pH = 12. a) Tnh a ? ( S : 0,345 g ) b) Trung ha 1,5 lt dung dch X trn bng V lt dung dch cha ng thi HCl 0,1 M v H2SO4 0,05 M. Tnh V? ( S : 0,075 lt ) c) Tnh nng ca cc ion : H+ , HS- , S2- v pH ca dung dch bo ha H2S 0,1 M , bit H2S c K1 = 10 7 ; K2 = 1,3.10 13. d) Tnh pH ca dung dch H3PO4 0,1 M. Bit H3PO4 c K1 = 8.10-3, K2 = 6.10-8 , K3= 4.10-13. NIT-PHOTPHO
Bi 1/- T 68 tn NH3 sn xut c 160 tn HNO3 63%. Tnh hiu sut phn ng iu ch trn. Bi 2/- Ho tan ht 2,52gam Ag bng axt HNO3 21% (D=1,2 g/ml) thu c kh khng mu ha nu trong khng kh. Tnh th tch dd HNO3 cn cho phn ng trn Bi 3/ Ho tan ht 12gam hp kim Fe v Cu bng dd HNO 3 c , nng c 11,2 lt kh NO2(ktc). Tnh %m Fe trong hp kim. Bi 4/- Khi ho tan 40,0 g hh gm Cu v CuO trong dd HNO 3 1,00M ly d. thy thot ra 8,96 lt kh NO (ktc) . 1/ Tnh % khi lng trong hh u. 2/ Tnh V dd HNO3 cn dng cho phn ng. Bi 5/- Khi cho oxt ca mt kim loi ho tr n tc dng vi dd HNO3 d th to 68,0 g mui nitrat v 7,2 g nc. Xc nh tn oxt v khi lng axt p: Bi 6/- Cho 12,8 gam kim loi ha tr 2 tc dng va vi 110 gam dung dch HNO 3 c thu c 94,4 gam dung dch mui v V lt kh NO2 (ktc) 1/ xc nh tn kim loi 2/ Tnh % dung dch HNO3 dng. Bi 7/- Cho 19,2 g mt kim loi M tan hon ton trong dd HNO3 th thu c 4,48 lt kh NO (ktc). Xc nh tn kim loi M. Bi 8/- Ha tan hon ton m gam Al trong dd HNO3 th thu c 8,96 lt hn hp kh (ktc) gm NO v N2O c t khi vi H2 l 16,75. Tnh m? Bi 9/- Nhit phn hon ton 18,2 gam hh rn gm NaNO3 v Cu(NO 3)2 thu c hn hp kh c th tch 4,48lt (ktc) 1/ Vit phng trnh phn ng xy ra 2/ Tnh % khi lng mi mui trong hn hp. Bi 10/- Cho 62,0 gam Ca3(PO4)2 tc dng vi 49,0 gam dd H3PO4 64,0%. Lm bay hi dd thu c n c cn th c hh cht rn, bit rng cc phn ng u xy ra vi hiu xut 100%. Bi 11/- Cho 500ml dd c cha 21,84 g KOH v 10,65 g P2O5 . Hy tnh nng mol/l ca cc mui trong dd thu c. Bi 12/- Cho 200 ml dd H3PO4 1,5M tc dng vi 250 ml dd NaOH 2M. Sau phn ng mui thu c mui g? Tnh CM mi mui thu c. Bi 13/- Ho tan 12,8 gam kim loi ha tr II trong mt lng va dd HNO3 60,0%( D=1,365 g/ml), thu c 8,96 lt kh (ktc)mu nu . Xc nh tn kim loi v th tch dd HNO3 phn ng. Bi 14/- Rt dd cha 11,76 g H3PO4 vo dd cha 16,8 gam KOH. Sau phn ng cho dd bay hi n kh. Tnh khi lng mui khan thu c. Cu 15/- Cho 4 lt N2 v 14 lt H2 vo bnh phn ng. Hn hp thu c sau phn ng c th tch l 16,4 lt. Tnh V kh NH3 to thnh v hiu xut phn ng ( Bit cc cc kh o ktc) Cu 16/- Cho dung dch NH3 d vo 40ml dung dch Al2(SO4)3, lc ly kt ta cho vo 20ml dung dch NaOH 2M th kt ta tan ht. Tnh CM dung dch Al2(SO4)3 dng Cu 17/- Ngi ta dng dung dch NaOH 20% iu ch NH3 t 10,7g NH4Cl. Bi tp ho hc 11

1/ Tnh khi lng dung dch NaOH dng 2/ Ton b kh NH3 sinh ra cho vo 200ml dung dch H2SO4 1M. Tnh khi lng mui to thnh. Cu 18/- Cho dung dch Ba(OH)2 n d vo 50ml dung dch A cha cc ion NH4+, SO42-, NO3thy thot ra 11,65 g kt ta v 4,48 lt kh thot ra ktc 1/ Vit PTPU v PT ion thu gn 2/ Tnh CM mi mui trong dung dch A Cu 19/-Cho 23,9 gam hn hp gm NH4Cl v (NH4)2SO4 tc dng va vi 200ml dung dch NaOH 2M. 1/ Tnh % theo khi lng mi cht trong dung dch 2/ Tnh th tch kh bay ra ktc Cu 20/- Nhit phn 18,15 gam hn hp KCl v NH4Cl thu c 7,45 gam cht rn. 1/ Tnh % theo khi lng hn hp u 2/ Ly 100cm3 dd KOH v NH4OH tc dng va vi HCl iu ch hn hp trn. Tnh CM dd KOH v NH4OH dng. Cu 21/- Cho 13,5 gam Al tc dng va vi 2,2 lt dung dch HNO3 thu c hn hp 2 kh NO v N2O c dhh/H 2 =19,2 1/ Tnh s mol mi kh to ra 2/ Tnh CM dd axt ban u. Cu 22/- Cn ly bao nhiu gam NaOH cho vo dung dch cha 5,88 gam H 3PO4 thu c 2,84 gam Natri hirophotphat v 6,56 gam natri photphat. Cu 23/- Khi cho 10,7 gam NH4Cl tc dng vi dung dch NaOH 0,5M ngi ta thu c kh A. Ton b kh A c dn vo 500ml dung dch H3PO4 0,2M 1/ Tnh Vdd NaOH cn dng. 2/ Xc nh khi lng mui to thnh. Cu 24/-Nung mt lng Cu(NO3)2 sau mt thi gian dng li ngui v em cn thy khi lng gim i 54gam. 1/ Tnh khi lng Cu(NO3)2 b phn hu 2/ Tnh V kh thot ra ktc. Cu 25/-Nung 15,04 gam mui Cu(NO3)2 sau cng thy cn li 8,56 gam cht rn. 1/ Tnh % khi lng Cu(NO3)2 b phn hy. 2/ Xc nh khi lng cht rn cn li.
Cu 1: Nung hoan toan 180 g sat(II) nitrat th thu c bao nhieu lt kh ieu kien tieu chuan? A). 67,2 B). 44,8 C). 56 D). 50,4 Cu 2: Cho cac chat kh va hi sau: CO2, NO2, NO, H2O, CO, NH3, HCl, CH4, H2S. Kh nao co the b hap thu bi dung dch NaOH ac? A). CO2, SO2, NO2, H2O, HCl, H2S B). CO2, SO2, CO, H2S, H2O, NO C). CO2, SO2, CH4, HCl, NH3, NO D). CO2, SO2, NH3, CH4, H2S , NO2 Cu 3: San pham khi nhiet phan en hoan toan hon hp gom Ba(NO3)2 va Cu(NO3)2 la g? A). Mot muoi, mot oxit va 2 chat kh B). Hai oxit va hai chat kh C). Mot muoi, mot kim loai va 2 chat kh D). Mot oxit, mot kim loai va mot chat kh Cu 4: Cho 19,2 g kim loai M tan hoan toan trong dung dch HNO 3 th thu c 4,48 lit NO( ktc). Vay M la: A). Mg B). Cu C). Zn D). Fe t , xt , P Cu 5: Can bang N2 + 3H2 2NH3 H<0 se dch chuyen theo chieu thuan neu chu cac tac ong nao sau? A). Giam ap suat, giam nhiet o B). Tang ap suat, giam nhiet o C). Tang ap suat, tang nhiet o D). Giam ap suat, tang nhiet o
o

NIT-PHOTPHO

Bi tp ho hc 11

Cu 6: Bnh kn cha 0,5 mol H2 va 0,5 mol N2. Khi phan ng at can bang trong bnh co 0,02 mol NH3 c tao thanh. Hieu suat cua phan ng tong hp amoniac la A). 4% B). 2% C). 6% D). 5% Cu 7: Khi nung 54,2 g hon hp muoi nitrat cua kali va natri thu c 6,72 lit

kh (ktc). Xac nh thanh phan % khoi lng cua hon hp muoi? A. 52,73% NaNO3 va 47,27% KNO3 B. 72,73% NaNO3 va 27,27% KNO3 C. 62,73% NaNO3 va 37,27% KNO3 D. 62,73% KNO3 va 37,27% NaNO3

Cu 8: San pham khi nhiet phan en hoan toan hon hp gom Al(NO 3)3 va AgNO3 la g? A). Mot oxit, mot kim loai va 2 chat kh B). Hai oxit va 2 chat kh C). Mot oxit, mot kim loai va mot chat kh D). Mot oxit, mot muoi va 2 chat kh Cu 9:Co 4 lo cha 4 dung dch rieng biet sau: 1. NH3 2. FeSO4 3. BaCl2

4. HNO3 . Cac cap dung dch nao co the phan ng vi nhau? A. 1 va 4; 2 va 3; 2 va 4; 1 va 2 B. 1 va 3; 2 va 3; 3 va 4; 1 va 2 C. 1 va 4; 2 va 3; 3 va 4; 1 va 2 D. 1 va 3; 1 va 4; 2 va 4; 1 va 2 Cu 10: Phan ng nao sau ay dung e ieu che amoniac trong phong th nghiem? A. N2 + 3H2 2 NH3 B. 4Zn + NO3- +7 OH- --> 4ZnO22- + NH3 + 2H2O C. NH4+ + OH- -t0--> NH3 + H2O D. NH4Cl --t0--> NH3 + HCl Cu 11: Chat nao sau ay phan ng c vi dung dch amoniac? A. HCl, P2O5 , AlCl3, CuSO4 B. NaCl, N2O5 , H2SO4 , HNO3 C. Ba(NO3)2 , SO3 , ZnSO4 , H3PO4 D. FeSO4 , CuO, KCl, H2S Cu 12: Axit nitric ac co the phan ng c vi cac chat nao sau ay ieu kien thng? A. Fe, MgO, CaSO3 , NaOH B. Al, K2O, (NH4)2S , Zn(OH)2 C. Ca, SiO2 , NaHCO3, Al(OH)3 D. Cu, Fe2O3, Na2CO3, Fe(OH)2 Cu 13: Cht no sau y c th lm kh kh NH3? A. H2SO4 c B.CuSO4 khan C.HCl D.CaO Cu 14: Chat nao sau ay khong phan ng c vi HNO3 ? A. Fe2(SO4)3 B. S C. FeCl2 D. C Cu 15: Chat long nao sau ay co the hap thu hoan toan kh NO2 ( ieu kien thng) ? A. dung dch NaNO3 B. NaOH C. H2O D.dung dch HNO3 Cu 20: Cho 6,4gam Cu tan hoan toan trong 200ml dd HNO3 th giai phong mot hon hp kh gom NO va NO2 co co t khoi vi hiro la 18. Nong o mol/l cua dd HNO3 la: A.1,64M 1,54M C.1,44M D.1,34M Cu 21: Trong phan t HNO3 co bao nhieu nguyen to co the lam cho HNO3 the hien tnh oxi hoa? A. Chang co nguyen to nao B. 1 C. 3 D. 2 Cu 22: Phng phap nao sau ay dung e ieu che N2 trong phong th nghiem? A. Nhiet phan muoi amoni nitrit B. Phan huy amoniac bang tia la ien C. Cho C. Zn tac dung vi HNO3 rat loang D. ot chay NH3 trong oxi roi lam ngng tu nc Cu 24: Cho dd NH4NO3 tac dung va u vi dd hiroxit cua kim loai hoa tr II th thu c 4,48 lt khi (ktc) va 26,1 gam muoi khan khi co can sau phan ng. Kim loai hoa tr II la kim loai nao sau ay: A.Caxi B.Magie C.ong D.Bari
Cau 25: Photpho o va photpho trang khac nhau ve tnh chat vat ly v: A. Cau truc mang tinh the khac nhauB.P trang co the chuyen thanh P o

Bi tp ho hc 11

C. S nong chay va bay hi khac nhau D.Tan trong nc va dung moi khac nhau Cu 26; Phan ng nao sau ay minh hoa cho tnh kh cua NH3 ?

A. 4NH3 + CuCl2 ---> (Cu(NH3)4)Cl2 B. NH3 + H2O NH4+ + OHC. NH3 + H2SO4 ---> NH4HSO4 D. 2NH3 + 9Fe2O3 --->N2+6Fe3O4+ 3H2O Cu 27: Axit nitric ac nguoi co the phan ng c vi cac chat nao sau ay? A. P, Fe, Al2O3 , K2S, Ba(OH)2 B. S, Al, CuO, NaHCO3 , NaOH C. C, Ag, Fe3O4 , NaNO3, Cu(OH)2 D. C, Mg, FeO, Fe(NO3)2, Al(OH)3 Cu 28: Cac dung dch nao sau ay co the co hien tng boc khoi khi m nap lo ? A. Dung dch HCl loang, HNO3 loang B. Dung dch HCl ac, HNO3 ac C. Dung dch HCl ac, H3PO4 ac D. Dung dch HBr ac, H2SO4 ac Cu 29: Trong PTN phai dung bao nhieu gam natri nitrat cha 10% tap chat e ieu che 300g dd axit nitric 6,3% ? Coi hieu suat cua qua trnh /c 100%
A. 27,62 g B. 28,33 g C. 22,95 g D. 29,54 g Cu 30: Trong cong nghiep phai dung bao nhieu lit kh amoniac (ktc) e

ieu che 5 kg dd axit nitric 25,2 % ? Coi hieu suat cua qua trnh /c 100% A. 448 lit B. 672 lit C. 560 lit D. 336 lit
Cu 31: Xac nh muoi nao c tao ra khi 31 g Ca3(PO4)2 tac dung vi

49g dd H2SO4 32% ? A. CaHPO4 va Ca3(PO4)2 va CaSO4 B. Ca(H2PO4)2 va CaSO4 C. CaHPO4 va Ca(H2PO4)2 va CaSO4 D. Ca3(PO4)2 va Ca(H2PO4)2 va CaSO4 Cu 32: Hoa tan san pham thu c khi ot chay P trong khong kh d vao 500 ml dd H3PO4 85% (d = 1,7 g/ml), nong o cua axit trong dd tang them 7,6%. Tnh lng P a ot chay? A. 142 g B. 62g C. 31 g D. 124 g Cu 33: Cho ba dung dch mat nhan ng: axit clohidric, axit nitric, axit photphoric. Co the dung hoa chat nao sau ay lam thuoc th nhan biet? A. AgNO3 B. Zn C. Fe(OH)2 D. Tat ca cac chat a neu. Cu 34: Cho 80 lit (ktc) khong kh co lan 16,8% ( ve the tch) nit dioxit i qua 500 ml dd NaOH 1,6 M. Co can dd thu c bao nhieu g ba ran ? A. 59 g B. 54,2 g C. 59,6 g D. 46,2 g Cu 35: Khi nhiet phan muoi A thu c 21,6 g kim loai va 6,72 lit (ktc) hon hp cua hai kh. Xac nh cong thc muoi? A. Hg(NO3)2 B. AgNO3 C. Pb(NO3)2 D. Au(NO3)3 Cu 36: Ngi ta phai bao quan P trang bang cach e trong mot lo cha nc. Co the thay the nc bang chat nao sau ay? A. dau hoa B. Khong co chat nao thch hp. C. axit nitric D. benzen Cu 37: Dung dch NH3 co p/ vi nhng chat nao sau ay? 1. H3PO4 2. CuCl2 3.Fe(NO3)3 4. Fe3O4 5. H2O 6. Ba(OH)2 A. 1, 2, 4, 5, 6 B. 1, 2, 3, 6 C. 1, 2, 3, 4, 6 D. 1,2,3,4,5 Cau 38:Day nao sau ay c sap xep theo chieu tang dan so oxi hoa cua nit? A.NO<N2O<NH3<NO3-<NO2 B.NH4+, N2, N2O<NO<NO2 C.NH3<N2<NO2<NO<N2O D. NH3<NO<N2O<NO2<N2O5

CACBON-SILIC
Cu 1/-Hp th hon ton 4,48 lt kh CO2 (ktc) vo 500 ml dd NaOH thu c 17,9 gam mui. Tnh nng mol/l dd NaOH. Bi tp ho hc 11

Cu 2/-Nung 52,65 g CaCO3 1000oC, cho ton b kh sinh ra hp th ht vo 500ml dd NaOH 3,6M. Hi thu c nhng mui no? khi lng bao nhiu? bit hiu sut phn ng l 95%. Cu 3/-Cho hn hp gm C v Si c khi lng 30,0 gam tc dng vi lng d dd NaOH c nng, un nng. phn ng gii phng ra 20,16 lt kh hiro (ktc). Xc nh % khi lng Si trong hn hp. bit phn ng xy ra vi hiu sut 80%. Cu 4/-Cho hp th hon ton 1,12 lt kh CO2 (ktc) vo 100ml dd NaOH 0,75M. 1/ Tnh khi lng mui thu c sau phn ng. 2/ Tnh CM cc mui trong dd. ( Th tch thay i khng ng k) Cu 5/-Mt loi thy tinh cha 13% Na2O; 11,7% CaO v 75,3%SiO2 v khi lng. Hy xc nh cng thc ha hc ca loi thy tinh trn. Cu 6/- Cho 0,15 mol hn hp NaHCO3 v MgCO3 tc dng ht vi dd HCl. Kh thot ra c dn vo dd Ca(OH)2 d thu c m gam cht kt ta. Xc nh m. Cu 7/-Dn kh CO2 (ktc) c iu ch bng cch cho 100 gam CaCO3 tc dng vi dd HCl d qua dd c cha 60 gam NaOH. Hy tnh lng mui iu ch c Cu 8/-Ha tan ht 2,8 gam CaO vo nc c dd A. Cho 1,68 lt kh CO 2(ktc) vo dd A. Hi c bao nhiu gam mui to thnh. Cu 9/-Kh 32 gam Fe2O3 bng kh CO d, sn phm kh thu c cho vo bnh ng nc vi trong thu c a gam cht kt ta. Tnh a.

Bi tp ho hc 11