150 CU HI L THUYT HA HU C

Cu 1. Cho cc ankan sau: Metan, propan, isobutan, 2,2- imetyl propan, 2- metylbutan, 2,3- imetyl pentan. C bao nhiu annkan khi tham gia phn ng monoclo ha ch thu c mt sn phm th? A. 1 B. 3 C. 4 D. 2 Cu 2. Cht no sau y khng th iu ch c metan bng mt phng trnh ha hc trc tip? A. A4C3 B. CaC2 C. CH3COONa D. C4H10 Cu 3. Anhit axetic khng iu ch trc tip t cht no sau y bng 1 phn ng: A. C2H2 B. C2H4 C. C2H5OH D. C2H5Br Cu 4. Khi monoclo ha mt ankan X th thu c hai dn xut mono halogenua c %Cl bng 38,378%. Tn gi ca X l: A. 2-metylpropan B. Propan C. 2,3-imetylbutan D. pentan Cu 5. Cho cc anken sau: etilen (1), propen (2), but-2-en (3), 2-metylpropen (4), 2,3-imetylbut-2-en (5). Cc anken khi cng nc( H+, to) cho 1 sn phm duy nht l: A. (1), (2), (3). B. (1), (3), (5). C. (1), (3), (4). D. (1), (4), (5). Cu 6. Cht no sau y khng th iu ch c etilen bng mt phng trnh ha hc A. C2H5OH. B. C2H2 C. C2H5Br D. CH3CHO Cu 7. Dy cc cht tc dng c vi etilen l: A. dd brom, kh hiro, kh oxi, dd axit clohiric,nc (H+),dd kalipemanganat B. dd natri hiroxit, kh hiro, dd natriclorua, dd kalipemanganat, nc vi trong C. dd brom, kh hiro, nc vi trong, dd axit bromhiric, kh oxi D. kh oxi, dd axit clohiric,nc (H+), dd natrihiroxit, dd brom Cu 8. Cn dng cc cht no sau y phn bit cc kh sau CO2, CH4, C2H4, C2H2 A. dd Ca(OH)2, dd Br2, dd HCl B. dd Ca(OH)2, dd AgNO3/NH3, dd Br2 C. dd AgNO3/NH3, dd NaOH, dd Br2 D. dd Br2, dd Ca(OH)2, Cu(OH)2/OHCu 9. Dy cc cht u lm mt mu dung dch Br2 l A. Axetilen, etan, butilen, xiclobutan B. Axetilen, xiclopropan, stiren, propen C. But-2-en, xiclobutan, propan, benzen D. Etilen, xiclohexan, stiren, butan Cu 10. Mt hiddrocacbon X c cng thc phn t l C4H8.Cho X tc dng vi H2O ( H2SO4 , to) ch thu c mt ancol. Tn gi ca X l: A. Xiclo butan B. But-1-en C.2-metylpropen D. But-2-en Cu 11. Kh axetilen c th iu ch trc tip bng mt phn ng t cht no sau y: A. CH4. B. CaC2 C. CHBr2-CHBr2 D. C A,B,C Cu 12. Cho s phn ng sau: CaC2 X Y CH3CHO X, Y c th l cc cht no sau y: A. CH4, C2H2 B. C2H4, C2H5OH C. C2H2, C2H4 D.C2H2, C2H6 Cu 13. Benzen khng tc dng vi cht no sau y; A. Br2 lng B.Kh Cl2 C. HNO3 c D. dd Br2 Cu 14. C th phn bit 3 cht lng: benzene, stiren, toluen bng mt thuc th l: A. giy qu tm. B. dd Br2 C. dd KMnO4 D.dd HCl Cu 15. Thnh phn chnh ca kh thin nhin v kh m du l : A. C2H4 B. CH4 C. C4H10 D. C2H2 Cu 16. Pht biu no sau y khng chnh xc: A. Tt c cc anken u lm mt mu dung dch Br2 B. Khi cng phn t bt i xng nh HBr, HCl, H2O vo anken u thu c 2 sn phm cng C. Ch c cc ank-1-in mi tc dng vi dung dch AgNO3/NH3 D. Khi cho cc cht Al4C3 v CaC2 vo nc th u thu c mt sn phm kh ging nhau Cu 17. Khi cho buta-1,3-ien tc dng vi HBr ( t l mol 1:1) th c th thu c ti a bao nhiu sn phm A. 2 B. 3 C. 4 D.5 Cu 18. Nguyn liu sn xut cao su Buna-S gm: 1

A. Stiren v buta-1,3-ien B. Buta-1,3-ien C. isopren D. buta-1,3-ien v vinylclorua Cu 19. C bao nhiu cng thc cu to c th c ca C5H11Br A. 5 B. 7 C. 6 D. 4 Cu 20. C bao nhiu ancol c cng thc phn t l C4H10O khi b oxi ha to thnh anhit: A. 2 B. 3 C. 1 D. 4 Cu 21. Hirat ha 2 anken ch to thnh 2 ancol. Hai anken l A.eten v but-2-en B. 2-metylpropen v but-1-en C. propen v but-2-en D. eten v but-1-en Cu 22. Cho iso-pentan tc dng vi Cl2 theo t l s mol 1:1, s sn phm monoclo ti a thu c l. A. 2. B. 3. C. 5. D. 4. Cu 23. Cho cc phn ng: to HBr + C2H5OH C2H4 + Br2 ; C2H4 + HBr S phn ng to ra C2H5Br l. A. 4. B. 3.
askt (1 : 1 mol) C2H6 + Br2

C. 2.

D. 1.

Cu 24. Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l. A. 3,3-imetylhecxan. B. isopentan. C. 2,2-imetylpropan. D. 2,2,3-trimetylpentan. Cu 25. Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th kh o cng k nhit v p sut); t khi ca Y so vi H2 bng 12. CTPT ca X l A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 26. Mt hirocacbon X cng axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. CTPT ca X l. A. C4H8. B. C3H6. C. C3H4. D. C2H4. Cu 27. Ba hirocacbon X, Y, Z l ng ng k tip, MZ = 2 MX. Cc cht X, Y, Z thuc dy ng ng. A. ankan. B. ankaien. C. anken. D. ankin. Cu 28. Cho cc cht sau: etylbromua, benzylclorua, ancol etylic,brombenzen, vinyclorua, axeton, metylacrylat, o-crezol, phenylamoni clorua, alanin, anilin, axit oxalic. C bao nhiu cht tc dng c vi dung dch NaOH long nng: A. 5 B. 6 C. 7 D. 9 Cu 29. Cho cc cht sau: axit fomic, axit axetic, axetilen, etyl fomat, anhit oxalic, natri fomat, amoni fomat, axit acrylic, etyl axetat. C bao hhieeu cht tc dng vi dung dch AgNO3/NH3, to A. 4 B. 7 C. 6 D. 3 Cu 30. Dy cc cht u c phn ng thy phn l; A. glucozo, saccarozo, etyl axetat, tristearin, tinh bt, fructozo B. Saccarozo, triolein, tinh bt, xenlulozo, mantozo C. Tinh bt, fructozo, triolein, etyl axetat, glucozo D. Mantozo, glucozo, tristeari, xenlulozo, tinh bt Cu 31. Dy cc cht c phn ng trng gng l: A. glucozo, fructozo, fomanhit, etyl fomat, amoni fomat, mantozo B. anhit axetic, axit fomic, etyl axetat, saccarozo, glucozo, axetilen C. Mantozo, anhit oxalic, ancol etylic, etyl fomat, fructozo D. Glucozo, fomanhit, phenol, metyl axetat, anlin, glixin, mantozo Cu 32. Dy gm cc cht tc dng vi Cu(OH)2/OH nhit thng l: A. Tinh bt, ancol etylic, axit axetic, glucozo, anhit axetic, mantozo B. Anhit axetic, fructozo, xenlulozo, glixerol, etanol, phenol C. Glucozo, fructozo, saccarozo, axit axetic, glixerol, axit fomic D. Fomanhit, etanol, axit fomic, xenlulozo, glucozo, mantozo Cu 33. Dy cc polime c iu ch bng phn ng trng hp l: 2

A. Cao su buna, nilon-6,6, t visco, polietilen, nha novolac B. Cao su buna, polistiren, poli ( metyl metacrylat), poli etilen C. t nilon-6, t olon, poli prpilen, poli( vnyl clorua), t axetat D. poli etilen, poli vinyl axetat, nilon-6,6, t axetat, t visco Cu 34. Trong cc t sau, t no l t tng hp: A. T visco B. T axetat C. T nilon-6,6 D. Xelulozo Cu 35. Dung dch NaOH c th tc dng vi cc loi polime no sau y; A. Poli ( vinyl clorua) B. Poli (vinyl axetat) C. Poli ( metyl metacrylat) D. c A, B, C Cu 36. Ghp cc cht ct A( tn monome) vi cc cht ct B ( polime tng ng) vi nhau cho ng Ct A Ct B CH2=CH2 Poli ( vinylclorua) C6H5-CH=CH2 Cao su buna CH2=CH-CH=CH2 Poli ( vinyl axetat) CH3COOCH=CH2 Poli etilen CH2=C(CH3)-COOCH3 Poli stiren CH2=CH-Cl Poli ( metyl metacrylat) Cu 37. Cht no sau y khng th iu ch c ancol etylic bng mt phn ng trc tip A. Etyl bromua v anhit axetic B. glucozo v etyl axetat C. etilen v glucozo D. metyl axetat v fructozo Cu 38. Dy cc cht tc dng vi dung dch Br2 l: A. Axit acrylic, axit fomic, anilin, phenol, stiren B. Axit axetic, axit fomic, glucozo, fructozo C. Phenol, alanin, axit axetic, benzen, hexan D. Anilin, axit acrylic, benzen, toluen, glucozo Cu 39. Este no sau y khi thy phn cho hai sn phm c phn ng trng gng: A. HCOOCH2-CH=CH2 B. CH3COOCH=CH2 C. HCOOCH=CH2 D. HCOOC(CH3)=CH2 Cu 40. Cho s phn ng sau: Toluen + Br2( 1:1) X + NaOH, to Y + CuO, to Z Cng thc cu to ca Z l: A. C6H5OH B. C6H5COOH C. C6H5CH2OH D. C6H5CHO Cu 41. Axit no X mch h c cng thc n gin nht C3H4O3. CTPT ca X l A. C6H8O6. B. C3H4O3. C. C4H6O4. D. C3H4O4. Cu 42. X c CTPT C3H6O v c kh nng lm mt mu dung dch brom. Hy cho bit cng thc cu to ca X? A. CH2=CH CH3. O B. CH2=CH 2OH. CH C. CH3CH2CHO. D. A, B v C Cu 43. Cho glixerin tc dng vi hn hp 2 axit stearic, panmitic th to ra ti a bao nhiu trieste? A. 4. B. 6. C. 7. D. 8. Cu 44. Hp cht hu c X c cng thc phn t C 3H6O3, X c th phn ng vi Na v Na 2CO3. Oxi ha X bng CuO thu c sn phm c phn ng trng gng. Cng thc ca X l CH 3 CH COOH I A. OH CH 2 CH 2 COOH B. OH C. HCOOCH2 CH3. D.CH3-CH(OH)-CO(OH) Cu 45. Hp cht no sau y khng phi l aminoaxit? CH 3 CH COOH I A. H2N CH2 CH2 COOH. B. NH 2 HOOC CH CH 2 COOH HCOO CH CH 2 COOH I I C. D. NH 2 NH 2 Cu 46. phn bit ba mu ha cht: phenol, axit acrylic, axit axetic c th dng 3

A. dung dch brom. C. dung dch AgNO3/ NH3. Cu 47. Cacbohirat Z tham gia chuyn ha:

B. dung dch Na2CO3. D. dung dch NaOH.

t Z Cu(OH)/ OH dung dch xanh lam kt ta gch. 2

Cacbohirat Z khng th l cht no trong cc cht cho di y? A. Mantoz B. Fructoz C. Glucoz D. Saccaroz Cu 48. : Phn ng no di y l phn ng lm gim mch polime? t OH t , A. cao su thin nhin + HCl B. poli (vinyl axetat) + H2O + t H ,t C. amiloz + H2O D. poli (vinyl clorua ) + Cl2

Cu 49. Cht X bng mt phn ng to ra C2H5OH v t C2H5OH bng mt phn ng to ra cht X .Trong cc cht C2H2, C2H4, C2H5COOCH3, CH3CHO, CH3COOH, CH3COOC2H5, C2H5ONa, C2H5Cl s cht ph hp vi X l: A. 5 B. 3 C. 4 D. 6 Cu 50. nhn bit cc cht etanol, propenol, etilenglicol, phenol c th dng cc cp cht: B. Nc Br2 v Cu(OH)2 A. Nc Br2 v NaOH C. KMnO4 v Cu(OH)2 D. NaOH v Cu(OH)2 Cu 51. Cho cc cht: CH3NH2, C6H5NH2, (CH3)2NH, (C6H5)2NH v NH3. Trt t tng dn tnh baz (theo chiu t tri qua phi) ca 5 cht trn l A. (C6H5)2NH, NH3, (CH3)2NH, C6H5NH2, CH3NH2 B. (C6H5)2NH, C6H5NH2, NH3, CH3NH2, (CH3)2NH C. (C6H5)2NH, NH3, C6H5NH2, CH3NH2, (CH3)2NH D. C6H5NH2, (C6H5)2NH, NH3, CH3NH2, (CH3)2NH. Cu 52. Ch dng mt thuc th no di y phn bit c etanal (anehit axetic), propan-2-on (axeton) v pent-1-in (pentin-1)? A. Dung dch brom. B. Dung dch AgNO3/NH3 d.
H SO

C. Dung dch Na2CO3.

D. H2 (Ni, to).

Cu 53. Cho dy chuyn ha sau:

Br2 (dd ) 2 4 CH 3CH 2CHOHCH3 E F , 170 oC

Bit E, F l sn phm chnh, cc cht phn ng vi nhau theo t l 1:1 v s mol. Cng thc cu to ca E v F ln lt l cp cht trong dy no sau y? A. CH3CH2CH=CH2, CH3CH2CHBrCH2Br. C. CH3CH=CHCH3, CH3CH2CBr2CH3. A. 12.000. B. 15.000. B. CH3CH=CHCH3, CH3CHBrCHBrCH3. D. CH3CH2CH=CH2, CH2BrCH2CH=CH2. C. 24.000. D. 25.000.

Cu 54. Phn t khi trung bnh ca PVC l 750.000. H s polime ha ca PVC l Cu 55. phn bit mantoz v saccaroz ngi ta lm nh sau: A. Cho cc cht ln lt tc dng vi AgNO3/NH3. B. Thu phn tng cht ri ly sn phm cho tc dng vi dung dch Br2. C. Thu phn sn phm ri ly sn phm cho tc dng vi Cu(OH)2/NH3. D. Cho cc cht ln lt tc dng vi Cu(OH)2. Cu 56. Mt hp cht c cng thc phn t C3H7O2N l cht lng tnh v lm mt mu dung dch brom. CTCT ca hp cht trn l A. H2N 2CH2COOH. CH B. CH3 CH(NH2)COOH. C. CH2=CH COONH4. D. A hoc B. 4

Cu 57. C8H10O c bao nhiu ng phn cha vng benzen. Bit rng cc ng phn ny u tc dng c vi Na nhng khng tc dng c vi NaOH? A. 4. B. 5. C. 8. D. 3 Cu 58. Trong cc cht : benzen, phenol, axit axetic, ru (ancol) etylic, cht c nhit si cao nht l : A. axit axetic. B. ru (ancol) etylic. C. phenol. D. benzen. Cu 59. Este no sau y khi thy phn trong mi trng kim khng to ra ancol: A. CH3COOCH=CH2 B. HCOOC6H5 C. CH2=CH-COOCH3 D. C A, B Cu 60. Cht no sau y khng c tnh cht lng tnh: A. H2NCH2COOH B.ClH3N-CH2COONa C. CH3COONH4 D. C6H5NH2 Cu 61. Cht no sau y dng iu ch phenol v axeton trong cng nghip: A. Cumen B. Toluen C. Stiren D. Naptalen Cu 62. Trong qu trnh ch bin du m ngi ta thng dng phng php no sau y bin cc hidrocacbon t mch cacbon khng nhnh thnh phn nhnh, t khng thm thnh thm: A. Crckinh B. Trng hp C. Rifominh D. Chng ct Cu 63. Mnh khng ng l: A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. Cu 64. Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic . B. etyl axetat . C. axit fomic. D. ru etylic Cu 65. Pht biu ng l: A. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol. C. Khi thy phn cht bo lun thu c C2H4(OH)2. D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch Cu 66. Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. Cu 67. C s phn ng: Cht Y l: A. CH3Cl Cu 68. Cho s sau:
0

OHC CH 2 CHO X Y CH OH 3
C. CH4 D. HCHO

B. CH2(COOCH3)2
2+

H 10 C 50 + CH 4 + Y NaOH M X 2O/Hg T Z

CH 4
D. C A, B, C u ng.

Cng thc cu to ca Z l A. C2H5OH. B. CH3COOH. Cu 69. : Cho s sau:

C. CH3COOC2H5.

C2H2 C2H 4Cl 2 X C 2H 4O CH 2 CHOOCCH 3 = 2

Cng thc cu to ca X l A. C2H4(OH)2. B. C2H5OH. C. CH3CHO. D. HOCH2CHO. Cu 70. Cng thc phn t tng qut ca este to bi ru no n chc v axit cacboxylic khng

no, c mt lin kt i C=C, n chc l: A. CnH2nO2. B. CnH2n+2O2.

5

C. CnH2n-2O2.

D. CnH2n+1O2.

Cu 71. Cho cc dy chuyn ha :

NaOH H l H l NaOH Glixin + A + C X Glixin + C B + Y. X v Y : A. u l ClH3NCH2COONa. B. ln lt l ClH3NCH2COOH v ClH3NCH2COONa. C. ln lt l ClH3NCH2COONa v H2NCH2COONa. D. ln lt l ClH3NCH2COOH v H2NCH2COONa Cu 72. Ch dng mt thuc th phn bit cc cht dng lng : phenol, stiren, ancol benzylic, th thuc th nn dng l : A. Cu(OH)2. B. Na kim loi. C. dung dch Br2. D. dung dch AgNO3/NH3. Cu 73. Pht biu no sau y khng ng ? A. nhit thng glucoz, fructoz, saccaroz u ho tan Cu(OH)2 to dung dch xanh lam B. Glucoz, fructoz u tc dng vi H2 (xc tc Ni, t) cho poliancol C. Glucoz, fructoz, saccaroz u tham gia phn ng trng gng D. Glucoz, fructoz, mantoz u b oxi ho bi Cu(OH)2 khi un nng cho kt ta gch Cu 74. Cc cht trong dy no sau y u to kt ta vi dung dch AgNO3/NH3 ? A. vinylaxetilen, glucoz, metyl fomiat, anehit axetic B. glucoz, metyl fomiat, imetylaxetilen, anehit axetic C. vinylaxetilen, glucoz, metyl fomiat, axit propionic D. vinylaxetilen, glucoz, metyl fomiat, imetylaxetilen Cu 75. Dy cc cht c xp theo chiu tng dn tnh axit l: A.HCl, C2H5OH, CH3COOH, C6H5OH, HCOOH B. C2H5OH, C6H5OH, CH3COOH, HCOOH, HCl C. C6H5OH, C2H5OH, HCOOH, CH3COOH, HCl D. C2H5OH, C6H5O, HCl, CH3COOH, HCOOH Cu 76. Dy cc cht c xp theo chiu tng dn tnh axit l: A. CH3COOH, CH2Cl-COOH, CCl3-COOH, CHCl2-COOH, HCOOH B. HCOOH, CH3COOH, CCl3-COOH, CHCl2-COOH, CH2Cl- COOH C. CH3COOH, HCOOH, CH2Cl- COOH, CHCl2-COOH, CCl3-COOH D. CCl3-COOH, CHCl2-COOH, CH2Cl-COOH, CH3COOH, HCOOH Cu 77. Hirocacbon X tc dng vi H2 ( Ni, to) theo t l mol 1: 4, tham gia phn ng cng Br 2 theo t l mol 1:1. Tn gi ca X l: A. toluen B. Benzen C. Stiren D. Cumen Cu 78. Cht no sau y khng tc dng vi dung dch Br2: A. Stiren B. Anhit benzoic C. Fructozo D. axeton Cu 79. Cht no sau y khng tc dng vi dd NaOH long nng: A. vinyl clorua B. Benzyl clorua C. Etyl axetat D. phenol Cu 80. Cht no sau y khng c phn ng trng hp: A. Axit acrylic B. Vinyl axetat C. Etyl benzen D. Stiren Cu 81.Cht no sau y c cc tnh cht sau: tc dng vi H2 v Br2 theo t l mol 1:2, c phn ng trng gng v phn ng trng hp. A. CHO-CHO B. CH2=CH-COOH C. HCHO D. CH2=CH-CHO Cu 82. X, Y, Z l cc hp cht hu c n chc, X, Y tc dng vi H2 d u to ra Z, X c phn ng trng hp, Z tc dng vi Na nhng khng tc dng vi NaOH. X, Y u c phn ng trng gng. X, Y, Z ln lt l: A. CH3CH2OH, CH2=CH-CHO, CH3CH2CHO B. C2H5COOH, CH2=CH-CHO, CH3-CH2CHO C. CH2=CH-CHO, CH3-CH2-CHO, CH3-CH2-CH2-OH D. CH2=CH2, CH3CHO, CHO-CHO Cu 83. Dng nhng ha cht no sau y c th nhn bit c 4 cht lng khng mu l glixerol, ancol etylic, glucoz, anilin? A. dung dch Br2 v Cu(OH)2. B. AgNO3/NH3 v Cu(OH)2. C. Na v dung dch Br2. D. Na v AgNO3/NH3.

Cu 84.Cht no sau y khng c phn ng trng gng: A. Axit fomic B. fomanhit C. natri fomat D. vinyl axetat Cu 85. Ancol etylic (C2H5OH) tc dng c vi tt c cc cht no trong cc dy sau A. Na, HBr, CuO. B. Na, HBr, Fe. C. CuO, KOH, HBr. D. Na, HBr, NaOH. Cu 86. Cng thc phn t C4H10O c s ng phn A. 2 ng phn thuc chc ete. B. 3 ng phn thuc chc ancol (ancol). C. 2 ng phn ancol (ancol) bc 1. D. tt c u ng. 0 Cu 87. Cht no sau y khi tc dng vi H2 (Ni, t ) to ra ancol etylic? A. HCOOCH3. B. C2H5OC2H5. C. CH3CHO. D. CH2=CHCHO. Cu 88. un ancol c cng thc CH3-CH(OH)-CH2-CH3 vi H2SO4 c 1700C, thu c sn phm chnh c cng thc cu to nh sau A. CH2=C(CH3)2. B. CH3-CH=CH-CH3. C. CH2=CH-CH2-CH3. D. CH3-CH2-O-CH2-CH3. Cu 89. un hn hp 2 ancol vi dung dch H2SO4 c nhit 1800C thu c hn hp 2 anken (olefin) k tip nhau trong dy ng ng. Hn hp 2 ancol l 2 ancol A. gm 1 ancol no n chc v 1 ancol khng no 1 ni i n chc. B. khng no 1 lin kt i n chc lin tip. C. no n chc k tip. D. tt c sai. Cu 90. Pht biu no sau y ng 1. phenol c tnh axit mnh hn C2H5OH v nhn benzen ht e ca nhm -OH, trong khi nhm -C 2H5 l nhm y e vo nhm -OH. 2. phenol c tnh axit mnh hn C2H5OH v c minh ho bng phn ng ca phenol tc dng vi dung dch NaOH cn C2H5OH th khng phn ng. 3. tnh axit ca phenol yu hn H2CO3, v khi sc kh CO2 vo dung dch C6H5ONa ta s thu c C6H5OH kt ta. 4. phenol trong nc cho mi trng axit, lm qu tm ho . A. 1, 2, 3. B. 1, 2. C. 3, 4. D. 2, 3. Cu 91. nh hng ca nhm -OH n nhn thm C6H5- trong phn t phenol lm cho phenol A. d tham gia phn ng th trong nhn thm. B. kh tan trong nc. C. tc dng c vi dung dch kim. D. c tnh c. Cu 92. Pht biu no sau y khng ng A. anilin khng lm i mu giy qu m. B. anilin l baz yu hn NH3, v nh hng ht e ca nhn ln nhm chc -NH2. C. nh c tnh baz m anilin tc dng c vi dung dch Br2. D. anilin tc dng c HBr v trn N cn i e t do. Cu 93. Cc baz sau c sp xp theo chiu tnh baz gim dn l A. C6H5NH2, NH3, CH3NH2. B. NH3, CH3NH2, C6H5NH2. C. C6H5NH2, CH3NH2, NH3. D. CH3NH2, NH3, C6H5NH2. Cu 94. Phn t C3H9N c s ng phn amin l A. 3. B. 4. B. 5. D. 6. Cu 95. phn bit anehit axetic (CH3CHO) vi ancol (ancol) etylic (C2H5OH) c th dng A. dung dch NaOH. B. giy qu tm. C. AgNO3 (Ag2O) trong dd NH3, un nng. D. dung dch NaCl. Cu 96.Anehitfomic (HCHO) phn ng c vi tt c cc cht trong dy no sau y? A. H2, C2H5OH, Ag2O/dd NH3. B. H2, Ag2O/dd NH3, C6H5OH. C. CH3COOH, Cu(OH)2/OH-, C6H5OH. D. CH3COOH, H2, Ag2O/dd NH3. Cu 97. Nha phenolfomanehit c iu ch bng cch un nng phenol (d) vi dung dch A. HCHO trong mi trng axit. B. CH3CHO trong mi trng axit. C. HCOOH trong mi trng axit. D. CH3COOH trong mi trng axit. 7

Cu 98. Cho hai phn ng ho hc sau CH3CHO + H2 CH3CH2OH 2CH3CHO + O2 2CH3COOH Cc phn ng trn chng minh tnh cht no sau y ca anehit? A. ch c tnh kh. B. ch c tnh oxi ho. C. va c tnh oxi ho, va c tnh kh. D. ch tc dng c vi H2 v O2. Cu 99. Trong cc mnh sau y, mnh no sai? A. Anehit l hp cht hu c trong phn t c nhm -CHO lin kt vi gc hirocacbon. B. Anehit l hp cht trung gian gia ancol (ancol) bc 1 v axit cacboxylic tng ng. C. Anehit no, n chc, mch h (tr HCHO) khi trng bc th t l nanehit:nAg = 1:2. D. xi ho ancol (ancol) n chc sn phm thu c l anehit n chc. Cu 100.X l mt anehit. t chy m gam X thu c s mol CO2 bng s mol H2O. X l A. anehit khng no, a chc mch h. B. anehit no, a chc, mch h. C. anehit khng no, n chc, mch h. D. anehit no, n chc, mch h. Cu 101. iu ch anehit axetic trong cng nghip ngi ta chn phng php c phn ng no sau y? A. CH3CH2OH + CuO t CH3CHO + Cu + H2O. B. CHCH + H2O HgSO CH3CHO. ,t C. CH3COOCH=CH2 + NaOH t CH3COONa + CH3CHO. D. CH3CHCl2 + 2NaOH t CH3CHO + 2NaCl + H2O. Cu 102. linh ng ca nguyn t H trong nhm -OH ca cc cht sau c sp xp theo th t tng dn l A. C2H5OH, C6H5OH, CH3COOH. B. CH3COOH, C6H5OH, C2H5OH. C. C6H5OH, CH3COOH, C2H5OH. D. C2H5OH, CH3COOH, C6H5OH. Cu 103. Axit acrylic (CH2=CH-COOH) tc dng c vi tt c cc cht trong dy no sau y? A. NaOH, H2, Na2SO4. B. Na, NaHCO3, NaCl. C. Br2, H2, Cu. D. NaOH, Na, Br2. Cu 104. Cht X c cng thc phn t C2H4O2, cho cht X tc dng vi dung dch NaOH to ra mui v nc. Cht X thuc loi A. este no, n chc. B. ancol no, a chc. C. axit no, n chc. D. axit khng no, n chc. Cu 105. Khi thu phn este G c cng thc phn t C4H8O2 sinh ra hai sn phm X v Y. X tc dng c vi Ag2O/dd NH3, cn Y tc dng vi CuO nung nng thu c mt anehit. Cng thc cu to ca G l A. CH3COOCH2-CH3. B. HCOO-CH(CH3)2. C. HCOO-CH2-CH2-CH3. D. CH3-CH2-COO-CH3. Cu 106. un nng hai cht hu c X l C2H4O2 v Y l C3H6O2 trong dung dch NaOH, u thu c mui CH3COONa. X v Y thuc loi chc ho hc no sau y? A. X l este, Y l axit cacboxylic. B. X v Y u l axit cacboxylic. C. X v Y u l este. D. X l axit cacboxylic, Y l este. Cu 107. C th dng Cu(OH)2 phn bit c cc cht trong nhm A. C3H5(OH)3, C2H4(OH)2. B. C3H7OH, CH3CHO. C. CH3COOH, C2H3COOH. D. C3H5(OH)3, C12H22O11 (saccaroz). Cu 108. Dy gm cc dung dch u tc dng c vi Cu(OH)2 l A. glucoz, glixerin, mantoz, ancol (ancol) etylic. B. glucoz, glixerin, anehit fomic, natri axetat. C. glucoz, glixerin, mantoz, axit axetic. D. glucoz, glixerin, mantoz, natri axetat. Cu 109. Cho cc hp cht sau (1) HOCH2CH2OH; (2) HOCH2CH2CH2OH; (3) HOCH2CHOHCH2OH; (4) CH3CH2OCH2CH3; (5) CH3CHOHCH2OH.
0

Cc hp cht va tc dng c vi Na, va tc dng vi Cu(OH)2 nhit thng l A. 1, 2, 3. B. 2, 3, 4. C. 1, 3, 4. D. 1, 3, 5. Cu 110. nhn bit hn hp gm axit axetic, anehit axetic, ancol (ancol) etylic v glixerin ngi ta dng A. Na kim loi. B. dd NaOH. C. Cu(OH)2. D. Ag2O (AgNO3)/dd NH3. Cu 111. Cho chuyn ha sau : CO2 A B C2H5OH Cc cht A,B l: A. Tinh bt, glucoz B. Tinh bt, Xenluloz C. Tinh bt, saccaroz D. Glucoz, Xenluloz Cu 112. Cho bin ha sau: Xenluloz A B C Caosubuna. A, B, C l nhng cht no. A. CH3COOH,C2H5OH, CH3CHO. B. C6H12O6(glucoz), C2H5OH, CH2=CH CH=CH2 C.C6H12O6(glucoz), CH3COOH, HCOOH D. CH3CHO, CH3COOH, C2H5OH. Cu 113. Trong cc polime sau y: Bng (1); T tm (2); Len (3); T visco (4); T enan (5); T axetat (6); T nilon (7); T capron (8) loi no c ngun gc t xenluloz? A. (1), (3), (7). B. (2), (4), (8). C. (3), (5), (7). D. (1), (4), (6). Cu 114. Trong cc cht sau, dung dch cht no khng lm chuyn mu qu tm? A. HOOC-CH2-CH2CH(NH2)COOH B. H2N-CH2-COOH C. H2N-CH2CH2CH2CH2-CH(NH2)-COOH D. CH3-CHOH-COOH Cu 115. Hp cht khng lm i mu giy qu m l. A. CH3NH2. B. H2NCH2COOH. C. C6H5ONa. D. H2NCH2CH(NH2)COOH. Cu 116. Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau:
CH3NH2, H2NCH2COOH, CH3COONH4, anbumin.

A. Qi tm, dung dch HNO3 c, dung dch NaOH. B. Dung dch AgNO3/NH3, dung dch Br2, dung dch HNO3 c. C. Cu(OH)2, qy tm, ung dch Br2. D. Dung dch Br2, dung dch HNO3 c, dung dch I2. Cu 117. . tinh ch anilin t hn hp phenol, anilin, benzen, cch thc hin no di y l hp l? A. Ha tan trong dung dch brom d, lc kt ta, tch halogen thu c anilin. B. Ha tan trong dung dch NaOH d, chit ly phn tan. Thi CO2 n d vo phn tan thu c trn s thu c anilin tinh khit. C. Ha tan trong dung dch HCl d, chit ly phn tan. Thm NaOH d vo phn tan thu c trn v chit ly anilin tinh khit. D. Dng dung dch NaOH tch phenol, sau dng brom tch anilin ra khi benzen.\ Cu 118. Nhn nh no sau y khng ng?
A. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH. B. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. D. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc.

Cu 119. Cht X cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch brom. X c cng thc cu to l A. H2N - CH2 - CH2 - COOH B. CH3 - CH(NH2) - COOH C. CH2 = CH - COONH4 D. CH3 - CH2 - CH2 - NO2 Cu 120. Nhn nh no sau y cha hp l? A. Do nhm -NH2 y electron nn anilin d tham gia phn ng th vo vng benzen v u tin vo v tr o-, p-. B. Amin bc 1 dy ankyl tc dng vi HNO2 0 - 50C cho mui iazoni. C. Metylamin v nhiu ng ng ca n lm xanh qu m, kt hp vi proton mnh hn NH3 v nhm ankyl c nh hng lm tng mt electron nguyn t N v do lm tng tnh baz. D. Tnh (lc) baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. Cu 121. Ch dng Cu(OH)2 c th phn bit dy no di y cha cc dung dch ring bit? 9

A. Glucoz, mantoz, glixerol, anehit axetic. ancol etylic. C. Saccaroz, glixerol, anehit axetic, ancol etylic. glixerol. Cu 122. Cho s chuyn ho sau:
(1)

B. Glucoz, lng trng trng, glixerol, D. Lng trng trng, glucoz, fructoz,

Benzen

Clobenzen

(2)

X Y

(3)

Phe nol Anilin

Nitrobenzen (5) (4)

(6)

X, Y ln lt l. A. C6H5NH3Cl, C6H5ONa. B. C6H5Br, C6H5CH2NH3Cl. C. C6H5ONa, C6H5CH2NH3Cl. D. C6H5ONa, C6H5NH3Cl. Cu 123. Cht X c cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch Brom. Cng thc cu to ca X l. A. H2NCH2CH2COOH. B. CH3CH2CH2NO2. C. CH2 = CHCOONH4. D. CH3CH(NH2)COOH. Cu 124. Cng thc n gin nht ca anehit no, mch h X l C2H3O. X c cng thc phn t l A. C2H3O. B. C4H6O2. C. C8H12O4. D. C12H18O6. Cu 125. Cho s phn ng sau: + NaOH + Cl2 , 500 o C + CuO, t o Propilen X Y propenal. Tn gi ca Y l A. propanol. B. propenol. C. axeton. D. axit propionic Cu 126. Cho s bin ho (gi s cc phn ng u hon ton): + HCl + NaOH t o , + H 2 , Ni, t o Triolein X X1 X2. Tn ca X2 l A. axit oleic. B. axit panmitic. C. axit stearic. D. axit linoleic. Cu 127. Cho phn ng: CH2CH2Br + NaOH (lo ng)
Br
H2O to

Y + NaBr

Cng thc cu to ca Y l: CH2CH2OH A. B.

CH2CH2Br

CH2CH2OH

CH2CH2OH

C.

D.

Br OH OH ONa Cu 128. Tnh cht c trng ca saccaroz l 1. tham gia phn ng hiro ho; 2. cht rn kt tinh, khng mu; 3. khi thu phn to ra glucoz v fructoz; 4. tham gia phn ng trng gng; 5. phn ng vi ng (II) hiroxit. Nhng tnh cht no ng? A. 3, 4, 5. B. 1, 2, 3, 5. C. 1, 2, 3, 4. D. 2, 3, 5. Cu 129. Fructoz khng phn ng vi cht no sau y? A. Dung dch Br2. B. H2 / Ni, to. C. Cu(OH)2 trong dung dch NaOH. D. Dung dch AgNO3 trong NH3.

10

Cu 130. Chn phn ng sai? A. Phenol + dung dch brom Axit picric + axit bromhiric. to B. Ru benzylic + ng (II) oxit Anehit benzoic + ng + nc. o t C. Propanol-2 + ng (II) oxit Axeton + ng + nc. D. Etilen glycol + ng (II) hiroxit Dung dch mu xanh thm + nc. Cu 131. Cho s chuyn ho sau: Br2 + NaOH CuO Cu(OH )2 + 2 NaOH C2H4 X1 X2 X3 X4 + H 2SO4 HOOC COOH X3, X4 ln lt l A. OHC 2OH, NaOOC 2OH. CH CH B. OHC CHO, CuC2O4. C. OHC CHO, NaOOC COONa. D. HOCH2 2OH, OHC CH CHO. Cu 132. Khi cho C6H14 tc dng vi clo (chiu sng) to ra ti a 5 sn phm ng phn cha mt nguyn t clo. Tn gi ca C6H14 l A. 2,3-imetylbutan. B. 2-metylpentan. C. n-hexan. D. 3-metylpentan. Cu 133. Ru X c cng thc phn t l C5H12O. un X vi H2SO4 c 170oC khng thu c anken. Tn gi ca X l A. pentanol. B. pentanol-2. C. 2,2-imetylpropanol-1. D. 2-metylbutanol-2. Cu 134. Hp cht hu c X tc dng vi AgNO3 trong NH3 d thu c sn phm Y. Cho Y tc dng vi dung dch H2SO4 long hoc dung dch NaOH u thu c kh v c. X l cht no trong cc cht sau y? A. HCHO. B. HCOOH. C. HCOONH4. D. A, B, C u ng. Cu 135. T kh thin nhin, cc cht v c v iu kin cn thit iu ch nha phenolfomanehit cn dng ti thiu bao nhiu phng trnh phn ng? A. 4. B. 5. C. 6. D. 7. Cu 136. Cng thc phn t C9H8O2 c bao nhiu ng phn axit l dn xut ca benzen, lm mt mu dung dch nc brom (k c ng phn hnh hc)? A. 5. B. 6. C. 7. D. 8. Cu 137. Cho cc hp cht: 1. C6H5NH2; 2. C2H5NH2; 3. (C6H5)2NH; 4. (C2H5)2NH; 5. NH3. Tnh baz ca chng bin i theo quy lut no sau y? A. 1 > 3 > 5 > 4 > 2. B. 2 > 1 > 5 > 3 > 4. C. 4 > 2 > 5 > 1 > 3. D. 5 > 2 > 4 > 1 > 3. Cu 138. Cho cc cht lng: axit axetic, axit acrylic, etylaxetat, vinylpropionat, alylfomiat ng trong cc l khc nhau. Dng cc ha cht no sau y nhn bit c tt c cc cht trn? A. dd AgNO3/NH3; dd Br2. B. dd AgNO3/NH3; qu tm, dd Br2. C. dd AgNO3/NH3; qu tm; Cu(OH)2. D. qu tm; Cu(OH)2. Cu 139. Hp cht hu c X c cng thc phn t l C 4H7O2Cl khi thy phn trong mi trng kim c cc sn phm, trong c 2 hp cht c kh nng tham gia phn ng trng gng. Cng thc cu to ng ca X l A. HCOO 2 CH CHCl 3. CH B. C2H5COO 2Cl. CH C. CH3COO CHCl 3. CH D. HCOO CHCl 2CH3. CH Cu 140. Dy cc cht no sau y u c kh nng tham gia phn ng trng gng (to kt ta Ag)? A. axetilen, anehit axetic, metylfomiat. B. metanal, etanal, axit axetic. C. metanal, etanal, axit foocmic, metylfomiat. D. axetilen, axit axetic, axit foocmic. Cu 141. C 5 cht lng ng trong 5 l mt nhn: 1. benzen, 2. axit axetic, 3. axit acrylic, 4. ru etylic, glixerin. Nu ch dng cc ha cht sau y: qu tm, nc brom, Cu(OH)2 iu kin thng th c th nhn bit c nhng cht no? A. Tt c. B. 3, 4, 5. C. 1, 3, 4. D. 2, 3 5. Cu 142.Trong cc dung dch sau: (1) saccaroz, (2) 3-monoclopropan-1,2-iol (3-MCPD), (3) etilenglycol , (4) ipeptit, (5) axit fomic, (6) tetrapeptit, (7) propan-1,3-iol. S dung dich c th ha tan Cu(OH)2 l 11

A. 6 B. 4 C. 5 D. 3 Cu 143. Axit fomic c th phn ng c vi tt c cc cht trong dy no sau y (cc iu kin phn ng coi nh ) A. CH3OH, K, C6H5NH3Cl, NH3 B. Cu(OH)2, Cu, NaCl, CH3NH2. C. NaOH, CuO, MgO, C2H5Cl D. AgNO3/NH3, NaOH, CuO Cu 144. Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3CCl3. CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc dng vi NaOH c d, nhit v p sut cao cho sn phm c 2 mui? A. 4 B. 6 C. 7 D. 5 Cu 145. Hp cht hu c X c cng thc phn t C 4H6O2. Bit t X c th iu ch cao su buna theo s :
+ H2 H2O Tr ng h p X Y C Cao su buna. S cng thc cu to c th c ca A l? Ni,to xt,to A. 4 B. 3 C. 1 D. 2 Cu 146. : Cp cht no sau y khng th phn bit c bng dung dch brom A. Stiren v toluen B. Glucoz v Fructoz C. Phenol v anilin D. axit acrylic v phenol Cu 147. Cho phenol phn ng ln lt vi cc cht: Na, NaOH, NaHCO 3, HCl, C2H5OH, Br2, HNO3. S phn ng xy ra l A. 6 B. 4 C. 3 D. 5 0 Cu 148. Cho hp cht thm: Cl-C6H4-CH2-Cl + dung dch KOH (long, d, t ) ta thu c cht no? A. HO-C6H4-CH2- OH. B. Cl-C6H4-CH2 -OH. C. HO-C6H4-CH2-Cl. D. KO-C6H4-CH2 -OH Cu 149. : Cho s phan ng sau: CH4 X Y Z T C6H5-OH. (X, Y, Z la cac cht hu c khac nhau). Z l A. C6H5-Cl. B. C6H5-NH2. C. C6H5-NO2. D. C6H5-ONa. Cu 150. Cho 3 cht : CH3CH2CH2Cl (1); CH2=CHCH2Cl (2) v Phenyl clorua (3). un tng cht vi dung dch NaOH d, sau gn ly lp nc v axit ho bng dung dch HNO3, sau nh vo dung dch AgNO3 th cc cht c xut hin kt ta trng l A. (1), (3). B. (2), (3). C. (1), (2), (3). D. (1), (2). Cu 151.Dy cc cht u tc dng vi dung dch HBr l: A. Xiclopropan, etilen, stiren, anilin, axetilen, metyl amin B. etilen, toluen, benzen, xiclohexan, anilin, phenol, ancol etylic C. Axetilen, ancol etylic, axit fomic, anilin, etan, glucozo, stiren D. Hex-1-en, xiclo butan, stiren, axit axetic, fomanhit, anilin Cu 152. Dy cc cht lng tnh l: A. glucozo, anilin, phenol, amoni axetat B. glixin, amoni axetat, amoni fomat C. axit glutamic, anilin, amoni axetat D. metyl amin, alanin, amoni fomat Cu 153. Cht no sau y khng tc dng vi dd Br2: A. Phenol B. Anilin C. Axit fomic D. Axit axetic Cu 154. C 5 cht lng ng trong 5 l mt nhn: 1. benzen, 2. axit axetic, 3. axit acrylic, 4. ru etylic, glixerin. Nu ch dng cc ha cht sau y: qu tm, nc brom, Cu(OH)2 iu kin thng th c th nhn bit c nhng cht no? A. Tt c. B. 3, 4, 5. C. 1, 3, 4. D. 2, 3 5. Cu 155. Dy cc cht no sau y u c kh nng tham gia phn ng trng gng (to kt ta Ag)? A. axetilen, anehit axetic, metylfomiat. B. metanal, etanal, axit axetic. C. metanal, etanal, axit foocmic, metylfomiat. D. axetilen, axit axetic, axit foocmic. Cu 156. Hp cht hu c X c cng thc phn t l C 4H7O2Cl khi thy phn trong mi trng kim c cc sn phm, trong c 2 hp cht c kh nng tham gia phn ng trng gng. Cng thc cu to ng ca X l A. HCOO 2 CH CHCl 3. CH B. C2H5COO 2Cl. CH

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C. CH3COO CHCl 3. CH D. HCOO CHCl 2CH3. CH Cu 157. Cho cc cht lng: axit axetic, axit acrylic, etylaxetat, vinylpropionat, alylfomiat ng trong cc l khc nhau. Dng cc ha cht no sau y nhn bit c tt c cc cht trn? A. dd AgNO3/NH3; dd Br2. B. dd AgNO3/NH3; qu tm, dd Br2. C. dd AgNO3/NH3; qu tm; Cu(OH)2. D. qu tm; Cu(OH)2. Cu 158. Du thc vt l A. hn hp cc hirocacbon trng thi rn. B. hn hp cc hirocacbon trng thi lng. C. este 3 ln este ca ru glixerin vi axit bo ch yu l axit bo khng no. D. este 3 ln este ca ru glixerin vi axit bo ch yu l axit bo no. Cu 159. Ru X c cng thc phn t l C5H12O. un X vi H2SO4 c 170oC khng thu c anken. Tn gi ca X l A. pentanol. B. pentanol-2. C. 2,2-imetylpropanol-1. D. 2-metylbutanol-2. Cu 160. C bao nhiu ng phn ankin c cng thc phn t C5H8? A. 2. B. 3. C. 4. D. 5. Cu 161. Hai anken c cng thc phn t C3H6 v C4H8 khi phn ng vi HBr thu c 3 sn phm, vy 2 anken l A. xiclopropan v but-1-en. B. propen v but-1-en. C. propen v but-2-en. D. propen v metyl propen. Cu 162. Chn cu sai trong s cc cu sau y? A. Etylamin d tan trong nc do c lin kt hiro. B. Tnh cht ha hc ca etylamin l phn ng to mui vi baz mnh. C. Etylamin tan trong nc to dung dch c kh nng sinh ra kt ta vi dung dch FeCl3. D. Etylamin c tnh baz do nguyn t nit cn cp electron cha lin kt c kh nng nhn proton. Cu 163. Anken thch hp iu ch 3-etylpentanol-3 bng phn ng hirat ha l A. 3-etylpenten-2. B. 3-etylpenten-1. C. 3-etylpenten-3. D. 3,3-imetylpenten-2. Cu 164. C bao nhiu ng phn cu to c cng thc phn t C4H11N? A. 8. B. 7. C. 6. D. 5. - HT-

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