Chuyn Hirocacbon - Bch Phng

TRC NGHIM HIROCACBON

I. HIROCACBON NO Cu 1. t chy anken hoc xicloankan thu c A. s mol CO2 nh hn s mol H2O. B. s mol CO2 ln hn s mol H2O. C. s mol H2O bng s mol CO2 D. s mol H2O : s mol CO2 = 1: 2. Cu 2. Sn phm ca phn ng th clo (1:1, nh sng) vo 2,2- imetyl propan l : (1)CH3C(CH3)2CH2Cl; (2)CH3C(CH2Cl)2CH3 ; (3)CH2ClC(CH3)3 A. (1); (2) B. (2); (3) C. (2) D. (1) v (3) Cu 3. C bao nhiu ankan l cht kh iu kin thng khi phn ng vi clo (c nh sng, t l mol 1:1) to ra 2 dn xut monoclo? A 4 B 2 C 5 D 3 Cu 4. Hp cht hu c X c tn gi theo danh php quc t (danh php IUPAC) l: 2 Clo - 3 - metyl pentan. Cng thc cu to ca X l: A. CH3CH2CH(Cl)CH(CH3)2 B. CH3CH(Cl)CH(CH3)CH2CH3 D. CH3CH(Cl)CH2CH(CH3)CH3 C. CH3CH2CH(CH3)CH2CH2Cl Cu 5. C bao nhiu ankan ng phn cu to c cng thc phn t C5H12? A. 3 ng phn B. 4 ng phn C. 5 ng phn D. 6 ng phn Cu 6. Phn trm khi lng cacbon trong phn t ankan Y bng 83,33% . Cng thc phn t ca Y l : A. C2H6 B. C3H8 Cu 7. Phn ng c trng ca hidrocacbon no C. C4H10 D. C5H12 D. C A, B v C.

A. Phn ng tch B. Phn ng th C. Phn ng cng Cu 8. Trong phng th nghim c th iu ch metan bng cch no sau y? A.Nhit phn natri axetat vi vi ti xt B.Crackinh butan

C.T phn ng ca nhm cacbua vi nc D.chn A,C Cu 9. Cng thc n gin nht ca hidrocacbon M l CxH2x+1. M thuc dy ng ng no? A. ankan B. khng d kin xc nh C. ankan hoc xicloankan D. xicloankan Cu 10. . Tin hnh clo ha 3-metylpentan t l 1:1, c th thu c bao nhiu dn xut monoclo l ng phn ca nhau? A. 4 B. 5 C. 2 D. 3 Cu 11. . Hidrocacbon X c CTPT C5H12 khi tc dng vi Clo to c 3 dn xut monoclo ng phn ca nhau. X l: A. iso-pentan B. n-pentan C. neo-pentan D. 2-metyl butan Cu 12. Ankan Y td vi Brom to ra 2 dn xut monobrom c t khi hi so vi H2 bng 61,5. Tn ca Y l: A. butan B. propan C. isobutan D. 2-metylbutan Cu 13. Xicloankan ( ch c mt vng) A c t khi so vi nit bng 3. A tc dng vi clo c chiu sng ch cho mt dn xut monoclo duy nht, xc nh cng thc cu to cu A?
CH3
CH3

CH3

CH3 A. B. C. H3C D. H3C Cu 14. Khi cho ankan X (83,72% khi lng cacbon trong phn t) tc dng vi clo theo t l mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l

A. butan B. 2- metylpropan C. 2,3-imetylbutan D. 3-metylpentan. Cu 15. Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 2,2,3-trimetylpentan. B. 2,2-imetylpropan. C. 3,3-imetylhecxan. D. isopentan.
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Chuyn Hirocacbon - Bch Phng

II. HIROCACBON KHNG NO Cu 1. Sn phm ca phn ng etilen vi dung dch KMnO4 l :(1)etylen glicol; (2)glixerol; (3)etan-1,2-iol; (4)polietilen. A. (1); (2) B. (2); (3) C. (1); (3) D. (3); (4) Cu 2. Sn phm ca phn ng trng hp ivinyl l : (1)polibutaien; (2)cao su buna;(3) butaien; (4) cao su butaien. A. (1) ; (3) B. (1); (3) C. (3) ; (4) D. (1); (2); (4) Cu 3. Cng thc : CH2=C(CH3)CH=CH2 c gi l : (1)2-metylbutan-1,3-ien ; (2) isopren; (3) isopentan; (4)2-metylbuta-1,3-ien . A. (1); (2) B. (2); (3) C. (2); (4) D. (1); (4) Cu 4. Trong cng nghip etilen c iu ch bng cch A.tch HCl ca C2H5Cl B. cng H2 vo axetilen C. tch H2 t etan D. un etanol vi xc tc thch hp Cu 5. t chy hon ton m gam hn hp 3 ankin : etin, propin, but-1-in thu c 3,36 lt CO2 ktc v 1,8 gamH2O. S mol ca hn hp 3 ankin cho l A. 0,15 mol B.0,25 mol C. 0,08 mol D. 0,05 mol Cu 6. t chy hon ton hirocacbon A mch cacbon phn nhnh thu c CO2 v hi H2O theo t l 1,75 : 1 v th tch. A c cng cng thc phn t vi 1 cht l ng ng ca benzen.A tc dng vi Ag2O/dd NH3 to ra kt ta B, bit MB - MA = 214 vC. A c th c bao nhiu cng thc cu to? A 1 B 2 C 4 D 3 Cu 7. Nung 9,52 lit hn hp kh A (ktc) gm H2 v 2 anken k tip nhau trong bnh kn (c Ni) c hn hp kh B. t chy hon ton 1/2 hn hp B c 21,78 gam CO2 v 10,215 gam H2O. Cng thc phn t ca 2 anken l: A C4H8 v C5H10 B C3H6 v C4H8 C C5H10 v C6H12 D. C2H4 v C3H6 Cu 8. Hirocacbon X l cht kh iu kin thng, 1 mol X phn ng va vi 1 mol Ag2O/ dd NH3. t chy X to ra CO2 v H2O theo t l mol 2:1 ( cng iu kin t0, p sut). Cng thc ca X l: A C2H2 B. C4H2 C C4H4 D. C a v c u ng Cu 9. Mt hn hp X gm 2 ankin khi t chy hon ton to ra 39,6 gam CO2 v 10,8 gam H2O. Khi lng Br2 tc dng va vi lng hn hp X trn to thnh hp cht no l: A 24 gam B 12 gam C. 48 gam D 96 gam Cu 10. Cho cc cht: 1) (-CH2-CH=CH-CH2-)n 2) CH2Cl-C(CH3) = CH-CH3 3) Br-CH = CBr-CH3 4) CH2 = CCl - CH3 5) (CH3)2C=C(CH3)2 6) CH3 - CH = CH- CH3 Cc cht no c ng phn cis-trans: A 1, 2, 3, 4, 5 B. 2, 3, 6 C. 1, 2, 3, 4, 5, 6 D. 1, 2, 3, 6 Cu 11. Hirocacbon A mch h, l cht kh iu kin thng. t chy ht m gam A th thu c 8,8 gam CO2. Mt khc, m gam A phn ng va vi 16 gam Br2 to hp cht no hon ton. A l monome iu ch cao su tng hp. Cng thc ca A l: A C2H4 B C5H8 C C4H6 D C A v C u ng Cu 12. p dng qui tc Maccopnhicop vo trng hp no sau y? A Phn ng cng HBr vo anken i xng B Phn ng cng HBr vo anken bt i xng C Phn ng cng Br2 vo anken bt i xng D c A v B u ng Cu 13. Cho cc cht sau: CH2=CH2, CH3-CH=CH-CH3, CH2=CH-CH3, CH2=CH-C6H5, CH3-C C-CH3 C bao nhiu cht phn ng vi HCl (t l mol 1: 1) ch cho 1 sn phm (khng xt ng phn cis-trans) ? A 1 B 4 C 3 D 2 Cu 14. Khi iu ch etilen t ru etylic (c H2SO4 c, 1700C) thng c ln tp cht kh SO2. loi b SO2 c th dng A Dung dch NaOH B Dung dch KMnO4 C Dung dch nc brom D c a, b, c u ng
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Chuyn Hirocacbon - Bch Phng

Cu 15. loi b butin-1 ra khi hn hp kh gm butin-1 v butin-2 ta dng: A Dung dch brom B Dung dch thuc tmC Ag2O / dung dch NH3 D. c a, b, c u ng Cu 16. Dy cc cht no sau y u lm mt mu: dung dch brom trong nc ? A Propilen, isopren, stiren B Propin, propan, axetilen. C Butin-2, butan, stiren. D. Propin, etan, toluen Cu 17. X l monome dng trng hp thnh cao su isopren. Y l ng phn ca X v to kt ta vi Ag2O/ ddNH3. X v Y tc dng vi H2 to ra cng mt ankan. Tn ng ca X v Y theo danh php IUPAC l: A 2-Metylbutaien-1,2; 3-Metylbutin-1 B. 2-Metylbutaien-1,3; 2-Metylbutin-1 C. 2-Metylbutaien-1,3; 2-Metylbutin-3 D. 2-Metylbutaien-1,3; 3-Metylbutin-1 Cu 18. Vinylaxetilen ( CH C CH = CH 2 ) l hirocacbon c kh nng : A. Hiro ho (xc tc Pd) c butaien -1, 3 B. Lm mt mu nc brom C. To kt ta vng nht vi dd AgNO3/NH3 D. Tt c u ng Cu 19. iu ch etylen bng cch un ru etylic vi H2SO4 c. Bit hiu sut phn ng l 40%. Khi lng etylen thu c khi dng 230g ru etylic l: A. 350 g B. 56 g C. 196 g D. 140 g Cu 20. Cho 13,44 lit (ktc) C2H2 qua ng ng than nung nng 6000C thu c 14,04g bezen. Tnh hiu sut ca phn ng: A. 90% B. 80% C. 85% D. 95% Cu 21. Sn phm ca phn ng : C2H2 + HBr (d) l: A. CH2Br CHBr2 B. CHBr = CHBr C. CHBr2 CH3 D. CH2Br CH2Br Cu 22. Hidrocacbon X c tn gi thng thng etylmetylaxetylen. Tn gi ca X theo danh php quc t (IUPAC) A. Pent-2-in. B. 3-Metylbut-1-in C. Pent-1-in D. 3-Metylbut-2-in E. 2,3-diMetylbuten-1 Cu 23. Ankin X c cng thc cu to:
HC C CH CH3 C2H5

Danh php quc t (IUPAC) ca X l ? A. 3-Etylbut-1-in. B. 2-Etylbut-3-in C. 3-Metylpent-1-in D. 3-Metylpent-4-in E. iso-Butylaxetylen Cu 24. Hidrocacbon X khi tc dng vi AgNO3/NH3 d thu c 16,1g kt ta vng. Xc nh cng thc cu to ca X bit rng d X/H2 = 27 ? A. CH3-C CH. B. CH CH. C. CH C-CH2-CH3. D. CH3-C C-CH3. E. CH C-C CH. Cu 25. t chy hon ton 5,2g C2H2 ri hp th ton b sn phm vo bnh X cha dung dch Ca(OH)2 d. Khi lng dung dch trong bnh X tng hay gim bao nhiu gam ? A. tng 21,2g. B. gim 18,8g. C. gim 40g. D. tng 17,6g. E. gim 22,4 g. Cu 26. Cho 11,2 lt hn hp gm hai hidrocacbon c cng thc phn t l C3H4 v C4H6 li qua mt lng d dung dch AgNO3/NH3 thu c 76,3g kt ta vng (khng thy c kh thot ra khi dung dch). Thnh phn % v th tch cc kh trong hn hp ln lt l ? A. 60% v 40%. B. 50% v 50%. C. 40% v 60% D. 75% v 25%. E. 35% v 65%. Cu 27. Hn hp X gm 0,12 mol C2H2 v 0,18 mol H2. Cho X qua bt Ni nung nng, sau mt thi gian thu c hn hp kh Y. Dn hn hp Y qua dung dch Br2 d thy c 1,792 lt kh Z thot ra. Xc nh tng khi lng dung dch Br2 bit rng t khi hi ca hn hp Z so vi H2 l 16 ? A. 1,68 g. B. 0,92 g. C. 2,56 g. D. 3,12 g E. 1,8 g. Cu 28. Hn hp X gm CH4, C2H4 v C2H2 c t khi hi so vi H2 bng 11,4. Mt khc, cho 2,24 lt hn hp X qua dung dch AgNO3/NH3 d thy to ra 4,8g kt ta vng. 1. Thnh phn % v th tch mi kh trong hn hp ln lt l ? A. 40%, 40%, 20%. B. 20%, 40%, 40%. C. 30%, 30%, 40%. D. 35%, 45%, 20%. E. 45%, 35%, 20%. 2. Mt mol hn hp X lm mt mu ti a bao nhiu mol Br2 ? A. 1,2 mol B. 1,1 mol. C. 0,8 mol. D. 1,85 mol. E. 0,6 mol.
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Chuyn Hirocacbon - Bch Phng

3. t chy 8,96 lt hn hp X thu c khi lng CO2 v H2O tng ng ln lt l ? A. 26,4 g v 17,3 g. B. 28,16 g v 12,96 g. C. 28,16 g v 11,8 g. D. 29,92 g v 11,52 g. E. 29,04 g v 12,9 g. Cu 29. t chy hon ton hn hp 3 anken thu c (m + 14) gam H2O v (m + 40) gam CO2. gi tr ca m l : A. 9 g. B. 21 g. C. 6 g. D. 4 g. E. kq khc. Cu 30. Cng thc tng qut ca cc hirocacbon c dng CnH2n + 2 2a. i vi cht 2 metyl butadien 1,3. Tr s n v a l : A. a = 3; n = 2. B. a = 2; n = 5. C. a = 2; n = 3. D. a = n = 5. E. kqk Cu 31. Khi cho 0,2 mol mt ankin tc dng vi AgNO3 trong dung dch NH3 (d) thu c 29,4 gam kt ta. Cng thc phn t ca ankin l: A. C2H2. B. C3H4. C. C4H6. D. C5H8 Cu 32. t chy hon ton hn hp 3 anken ri dn sn phm chy ln lt qua bnh 1 ng dung dch H2SO4 c v bnh 2 ng dung dch nc vi trong d, thy khi lng bnh 1 tng m gam v khi lng bnh 2 tng (m + 5,2)gam. Gi tr ca m l: A. 1,8. B. 5,4. C. 3,6. D. 7,2. Cu 33. t chy hon ton 0,2 mol hn hp 2 ankin l ng ng k tip thu c 9,0 gam nc. Cng thc phn t ca 2 ankin l A. C2H2 v C3H4. B. C3H4 v C4H8. C. C4H6 v C5H10. D. C3H4 v C4H6. Cu 34. tch C2H2 ra khi hn hp gm C2H2 v C2H6, ngi ta c th s dng dung dch A. Br2. B. AgNO3 trong NH3. C. KMnO4. D. HgSO4, un nng Cu 35. Khi cho C2H2 tc dng vi HCl thu c vinylclorua vi hiu sut 60%. Thc hin phn ng trng hp lng vinylclorua trn thu c 60,0 kg PVC vi hiu sut 80%. Khi lng C2H2 ban u l A. 52,0 kg. B. 59,8 kg. C. 65,0 kg. D. 62,4 kg. Cu 36. Khi cho 2,4,4-trimetylpent-2-en tc dng vi H2O (H+), thu c sn phm chnh l A. 2,4,4-trimetylpentan-3-ol. B. 2,2,4-trimetylpetan-3-ol. C. 2,4,4-trimetylpentan-2-ol. D. 2,2,4-trimetylpetan-4-ol. Cu 37. Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C4H8. B. C3H6. C. C3H4. D. C2H4. III. HIROCACBON THM Cu 1. C th dng mt cht no trong cc cht sau y nhn bit ba cht lng ng trong cc l mt nhn: benzen, stiren, toluen? A. Dung dch Brom B. Dung dch KMnO4 C. t chy v quan st D. Dung dch AgNO3/NH3 Cu 2. Sn phm mononitrotoluen no c u tin to ra khi cho toluen tc dng vi HNO3 c/H2SO4 c, t0? A. o-nitrotoluen B. m-nitrotoluen C. p-nitrotoluen D. c a v c u ng Cu 3. Khi vng benzen c sn nhm ankyl phn ng th vo vng s(1)v u tin xy ra v tr (2). T thch hp cn thiu cu trn l: A. (1): d dng hn, (2): ortho v para. B. (1): d dng hn, (2): meta. C. (1): kh khn hn, (2): ortho v para. D. (1): d dng hn, (2): meta. Cu 4. Nhng tnh cht no thuc v tnh thm ca aren ? a) D tham gia phn ng th b) D tham gia phn ng cng c) Bn vng vi cc cht oxi ho d) C mi thm d chu , khng c Nhng tnh cht l: A. a, b, c, d B. a, c, d C.a, b, c D.a, c Cu 5. thu c m-bromnitrobenzen t benzen ta tin hnh theo trnh t no sau y? A Brom ha benzen ri nitro ha dn xut to thnhB Nitro ha benzen ri brom ha dn xut to thnh C C a v b u ng D Khng iu ch c Cu 6. Tnh thm ca benzen th hin phn ng : A. D tham gia phn ng th B. Kh tham gia phn ng cng
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Chuyn Hirocacbon - Bch Phng

C. Kh tham gia phn ng oxi ho kh D. Tt c u ng Cu 7. Trong cc cht sau y, cht no l ng ng ca benzen: 1, Toluen 2, etylbezen 3, pxylen 4, Stiren A. 1 B. 1, 2, 3, 4 C. 1, 2,3 D. 1, 2 Cu 8. Cho 5,2g stiren tc dng vi nc brom. khi lng brom ti a c th phn ng c l: A. 8 g B. 24 g C. 16 g D. 32 g Cu 9. Khi vit s ng phn mch h ca C5H10 ta c: A. 7 ng phn B. 4 ng phn C. 5 ng phn D. 6 ng phn Cu 10. Benzen phn ng c vi A. brom khan. B. dung dch brom. C. dung dch brom khi c Fe xc tc. D. brom khan khi c Fe xc tc. Cu 11. Trong phn ng nitro ho benzen A. H2SO4 m c ng vai tr l cht ht nc. B. H2SO4 m c ng vai tr l cht xc tc. C. H2SO4 m c ng vai tr l cht ht nc v l cht xc tc. D. khng cn H2SO4 m c, ch cn HNO3 c, nng. Cu 12. Cht no sau y c dng sn xut thuc n TNT? A. Benzen. B. Toluen. C. Stiren. D. Xilen. Cu 13. : Stiren (C6H5-CH=CH2) khng c kh nng phn ng vi A. dung dch brom. B. brom khan c Fe xc tc. C. dung dch KMnO4. D. dung dch AgNO3/NH3 Cu 14. Benzyl halogenua (C6H5-X) khi tham gia phn ng th vi (Br2/Fe; HNO3 c/H2SO4 c ) th nhm th th hai s c nh hng vo v tr A. o-. B. p-. C. m-. D. o- v p-. Xt s phn ng sau : A B TNT (tri-nitro-toluen). A, B ln lt l A. Toluen v heptan. B. Benzen v toluen. C. Hexan v toluen. D. Tt c u sai. Cu 15. Trong cc hirocacbon sau, nhng loi tham gia c phn ng th l A. Ankan. B. Ankin. C. Benzen. D. Ankan, Ankin, Benzen. Cu 16. Hirocacbon X l ng ng ca benzen c cng thc thc nghim (C3H4)n. X c cng thc phn t no di y? A. C12H16. B. C9H12. C. C15H20. D. C12H16 v C15H20. Cu 17. Khi cho toluen (C6H5-CH3) tc dng vi Cl2 theo t l mol 1:1 (askt) thu c sn phm th l cht no di y? A. C6H5-CH2Cl. B. o-Cl-C6H4-CH3. C. p-Cl-C6H4-CH3. D. o-Cl-C6H4-CH3 v p-Cl-C6H4-CH3. IV. TNG HP Cu 1. t chy hon ton 1,50 gam ca mi cht hu c A, B, D u thu c 1,12 lt CO2 ktc v 0,90 gam H2O. Cng thc n gin nht ca A, B, D l A. CH2 B. CHO C. CH2O D. C2H3O Cu 2. Cho cc cht sau: 1. propin; 2. propan; 3. toluen; 4. butaien-1,3; 5. benzen; 6. xiclohecxan. Nhng cht phn ng c vi H2 (khi c mt Ni, t0) l: A 1, 3, 4, 5, 6 B 1, 4, 5 C 1, 4, 5, 6 D 1, 3, 4, 5 Cu 3. t chy 4 hirocacbon ta thu c 2,24 lt kh CO2 (ktc) v 2,7 gam H2O th th tch O2 tham gia phn ng chy ktc l : A. 2.48 lt. B. 4,53 lt. C. 3,92 lt. D. 5,12 lt. E. kqk Cu 4. Xt cc cht sau: 1. Cloropren; 2. Bezen; 3. Propilen, 4. Butaien-1,3; 5. Isopren; 6. Toluen . Nhng cht khng c kh nng trng hp l: A 2, 6 B 1, 2, 6 C 2, 3, 6 D 1, 2, 3, 6 Cu 5. Mt hn hp X gm 3 hirocacbon A, B, C u khng c ng phn, thuc 3 h hirocacbon khc nhau. t chy hon ton mt lng X thu c hn hp CO2 v H2O theo t l mol 1:1. Dn V lit (ktc) X vo dung dch brom d, thy khi lng bnh brom
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Chuyn Hirocacbon - Bch Phng

tng 12,3 gam. Kh C cn li thot ra ngoi em t chy hon ton th thu c 13,2 gam CO2 v 8,1 gam H2O. V c gi tr l: A 13,44 lit B 8,96 lit C 6,72 lit D 4,48 lit Cu 6. Cho t n cha 80 % CaC2 tc dng vi H2O (d) (phn ng hon ton) thu c 8,96 lit axetilen (ktc). Khi lng t n cn ly c gi tr: A 64 gam B. 25,6 gam C. 12,8 gam D 32 gam Cu 7. t chy hon ton 1,29 mol hn hp A gm CnH2n-2 , CmH2m-2 v anken CxH2x thu c 1,892 mol CO2 v 1,302 mol H2O. S mol ca anken c trong hn hp A ln lt l : A 0,602 (mol). B 0,59 (mol). C 0,7 (mol). D Tt c u sai Cu 8. C hai bnh kh mt nhn mi bnh cha 1 kh: etan hoc etilen. Bng ha cht no c th nhn ra c kh cha trong bnh? A dung dch brom B dung dch KOH C dung dch thuc tm D c a v c u ng Cu 9. Hn hp A gm 3 hirocacbon ng phn, mch h, l cht kh iu kin thng. t chy hon ton hn hp A bng lng oxi va , hn hp kh v hi to thnh c dn vo bnh ng P2O5 d thy th tch hn hp gim i mt na. Nu t chy hon ton m gam hn hp trn, dn sn phm vo 1,4 lit dung dch NaOH 1M (d) ri c cn th thu c 71,6 gam rn. Gi tr ca m l: A 9,8 gam B 9,46 gam C 8,4 gam D Khng xc nh c Cu 10. . Cho s phn ng: C2H4 X PVC (polivinyl clorua). Vy X l: A. CH2=CHCl B. CH3CH3 C. CH3CH=CH2Cl D. CH2 = CHCH3 C l.n .l C ,600 N. M, N l: Cu 11. Cho 2 phn ng sau: CH4 M + H2; M A. C2H2, C4H6 B. C2H2, C2H4 C. C2H2, C6H6 D. C2H2, C4H4 Cu 12. Cht c kh nng lm mt mu dd KMnO4 l: A. Ankan, xicloankan, anken B. Anken, ankaien, ankin C. Anken, ankin, benzen D. Ankan, anken, ankin , Cu 13. Chn phn ng sai: 1. CH CH + H 2 Pd CH 2 CH 2 ; 2. CH 4 + Cl 2 as CH 3Cl + HCl ; t 1:1 3. CH 2 = CH 2 + HCl CH 3 CH 2 Cl ; 4.
0

CH CH + Ag 2 O ddNH 3 AgC CAg + H 2 O

B. 3 C. 4 D. 1 Cu 14. Cho 4,48 lt hn hp kh gm CH4 v C2H2 qua dung dch Br2 d thy dung dch nht mu v c 2,24 lt kh thot ra (cc kh o ktc). Thnh phn % ca CH4 trong hn hp l: A. 25% B. 50% C. 60% D. 37,5% Cu 15. t chy hon ton mt hirocacbon X ( l cht lng nhit thng) thu c CO2 v H2O c s mol theo t l 2 : 1. Cng thc phn t ca X c th l cng thc no sau y? A. C4H4 B. C5H12 C. C6H6 D.C2H2 Cu 16. Cht no c th tham gia c 4 phn ng: Phn ng chy, phn ng cng vi brom, phn ng cng vi H2 (xc tc Ni, to ), phn ng vi dd AgNO3 trong NH3? A. etan. B. etilen. C. axetilen. D. xiclopropan Cu 17. C bn cht: CH3-CH=CH2, CHC-CH3, CH2=CH-CH=CH2 v benzen. Khi xt kh nng lm mt mu dung dch brom ca bn cht trn, iu khng nh no sau y ng? A. c bn cht u c kh nng lm mt mu dung dch brom. B. c ba cht c kh nng lm mt mu dung dch brom. C. c hai cht c kh nng lm mt mu dung dch brom. D. ch c mt cht c kh nng lm mt mu dung dch brom. Cu 18. Dng nc brom lm thuc th c th phn bit cp cht no di y? A. Metan v etan. B. Toluen v stiren. C. Etilen v propilen. D. Etilen v stiren. Cu 19. Cho 800g t n tc dng ht vi nc thu c 100lt C2H2 27,3oC v 2,464 atm. Xc nh hm lng CaC2 trong t n ?A. 80%. B. 75%. C. 60% D. 40%. E. 20%.

A. 2

Chc cc em hc tt

Chuyn Hirocacbon - Bch Phng

Cu 20. t chy mt s mol nh nhau ba hidrocacbon X, X, Z thu c cng mt s mol CO2, t l s mol H2O v s mol CO2 i vi X, Y, Z ln lt l 0,5 ;1 ; 1,5. Xc nh cng thc phn t ca X, Y, Z (ch th t) A. CH4, C2H6, C2H4 . B. C2H2, C2H4, C2H6. C. C3H4, C3H6, C3H8. D. C2H2, C2H6, C2H4. E. C4H4, C4H8, C4H10. Cu 21. t chy hon ton 2,24 lt hn hp X gm hai hidrocacbon mch h thuc cng mt dy ng ng. Ton b sn phm c hp th vo dung dch Ba(OH)2 d thu c 68,95g kt ta v khi lng dung dch gim 49,05g. Hai hidrocacbon trn thuc dy ng ng no sau y ? A. Ankin. B. Anken. C. Ankadien. D. Ankin hoc ankadien. E. Ankan. Cu 22. t chy hon ton 24,64 lt (27,3oC, 1atm) hn hp X gm 3 hidrocacbon ng ng k tip. Sn phm chy c hp th ht vo bnh ng nc vi trong d th thy khi lng bnh tng ln 149,4g v khi lng dung dch trong bnh gim 120,6g. 1.Cng thc tng qut ca cc cht trong hn hp X l ? A. CnH2n+2. B. CnH2n . C. CnH2n-2 . D. CnH2n-6. E. Khng xc nh c. 2. Xc nh cng thc phn t ca 3 hidrocacbon ? A. C2H2, C3H4, C4H6. B. C2H6, C3H8, C4H10. C. C2H4, C3H6, C4H8. D. C6H6, C7H8, C8H10. E. C3H4, C4H6, C5H8. Cu 23. Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 d, thu c s gam kt ta l A. 30. B. 10. C. 20. D. 40. Cu 24. Cho cc cht sau: CH3CH=CHCH3 (X); CH3C CCH3 (Y); CH3CH=CHCH2CH3 (Z); Cl2C=CHCH3 (T) v (CH3)2C=CHCH3 (U). Cc cht c ng phn cis trans l A. X, Y, Z. B. Y, T, U. C. X, Z. D. X, Y. Cu 25. Chia 16,4 gam hn hp gm C2H4 v C3H4 thnh 2 phn bng nhau. Phn 1 tc dng va vi dung dch cha 56,0 gam Br2. Phn 2 cho tc dng ht vi H2 (Ni, tO), ri ly 2 ankan to thnh em t chy hon ton th thu c x gam CO2. Gi tr ca x l. A. 52,8. B. 58,2. C. 26,4. D. 29,1. Cu 26. Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng xy ra hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l. A. C2H2 v C3H8. B. C3H4 v C4H8. C. C2H2 v C4H6. D. C2H2 v C4H8. Cu 27. Mt hn hp X cha CH4 v C3H8 c s mol bng nhau .t chy ht hn hp ny ri cho sn phm chy qua bnh ng dung dch Ca(OH)2 d th khi lng bnh tng 56,8 gam . Th tch mi kh trong hn hp X v kt ta thu c trong bnh Ca(OH)2 l: A. 4,48 lt ; 80 gam B. 4,48 lt ; 60 gam C. 2,48 lt ; 80 gam D. 2,48 lt ; 60 gam Cu 28. t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H6 B. C2H4 C. CH4 D. C3H8 Cu 29. Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc). A. CH4 v C2H4 B. CH4 v C3H4 C. CH4 v C3H6 D. C2H6 v C3H6 V. HON THNH CC PTHH
Cu 1. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 CH3COONa CH4 metyl clorua metylen clorua clorofom cacbon tetraclorua
9 10 6 7 8 C2H6 C2H4 C2H4Cl2 C2H3Cl PVC

Chc cc em hc tt

Chuyn Hirocacbon - Bch Phng Cu 2 . Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 6 7 Tinh bt glucoz C2H5OH C2H4 C2H5Cl C3H8 C2H4 C2H4(OH)2 8 9 10 11 CH3CHO C2H5OH CH3COOH etyl axetat. Cu 3 . Vit PTHH theo s sau 1 2 3 4 5 6 7 Etan C2H5Cl C2H4 C2H5OH C2H4 C2H4Br2 C2H4(OH)2 CH3CHO 8 9 10 11 C2H5OH CH3COOH CH2=CHOCOCH3 PVA Cu 4. Vit phng trnh dng CTCT v ghi r iu kin
8 1 2 3 4 5 6 7 CaCO3 CaO CaC2 C2H2 C2H4 C2H6 C2H5Cl C2H4 1,2icloetan 9 10 11 12 C2H3Cl C2H4Cl2 anehit axetic amoni axetat.

Cu 5. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 6 7 Nhm cacbua metan C2H2 C2Ag2 C2H2 anehit axetic natri axetat axit axetic 8 9 10 vinylaxetilen C4H6 caosu buna S. Cu 6. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 6 Canxicacbua axetilen vinyl clorua 1,1icloetan axetilen kali oxalat axit oxalic 7 8 vinyl axetat poli(vinyl axetat) Cu 7. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 C2H4Cl2 C2H2 benzen nitrobenzen 1,3- initrobenzen 1,3,5-trinitrobenzen(TNB) 6 7 8 etylbenzen vinylbenzen polistiren(ps) Cu 8. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 toluen kali benzoat axit benzoic CO2
5 6 7 8 9 xiclohecxan benzen clobenzen natri phenolat phenol 2,4,4- trinitro 10

phenol. C6H6

12 13 11 C6H5C2H5 vinyl benzen etan-1,2- iol benzen. 14 15 toluen 2,4,6- trinitrotoluen(TNT) 16 17 stiren poli(butaien-stiren) hay caosubuna-S

Cu 9. Vit phng trnh dng CTCT v ghi r iu kin

3 4 benzen hecxacloxiclohexan(666) 5 1 2 6 7 Natri axetat metan etin vinyl axetilen clopren caosu clopren 9 8 10 11 bc axetinua axetilen etanal etanol.

Cu 10. Vit phng trnh dng CTCT v ghi r iu kin

3 5 4 6 7 cloetan propan 2-clopropan propilen PP 8 1 2 9 10 Natri propionat etan eten bromua etyl etilen etan- 1,2- iol 12 13 14 11 etan etyl clorua ancol etylic buta-1,3- ien.

Cu 11. Vit phng trnh dng CTCT v ghi r iu kin 1 2 3 4 5 CH3[CH2]2CH3 propen isopropyl clorua propan-2-ol propilen propan -1,2-iol
9 6 7 8 1,2- iclopropan propan -1,2-iol propilen propan-2-ol

Cu 12 . Vit phng trnh dng CTCT v ghi r iu kin

Chc cc em hc tt

Chuyn Hirocacbon - Bch Phng

1 3 5 7 11 9 10 C2H6 C2H4 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 2 4 6 8 12

C2H5OH

Chc cc em hc tt