THI MN HA (M 109)

Cu Kh 1,6 gam hn hp 2 andehit no bng kh H2 thu c hn hp 2 ancol. un nng hn hp hai 1 : ancol ny vi H2SO4 c 180oC thu c hn hp 2 olefin l ng ng k tip. t chy hai olefin ny c 3,52gam CO2. Bit cc phn ng xy ra hon ton. Cng thc ca hai andehit l A. CH3CHO, C2H5CHO B. CH3CHO, CH2(CHO)2 C. C2H5CHO, C3H7CHO D. HCHO, CH3CHO Cu Cho cc cht: amoniac (1) ; anilin (2) ; p-nitroanilin (3) ; p-metylanilin (4) ; metylamin (5) ; 2 : imetylamin (6). Hy chn s sp xp cc cht trn theo th t lc baz tng dn A. (2) > (3) > (4) > (1) > (5) > (6) B. (2) < (3) < (4) < (1) < (5) < (6) C. (3) < (1) < (4) < (2) < (5) < (6) D. (3) < (2) < (4) < (1) < (5) < (6) Cu C hn hp 3 kim loi Al, Fe, Zn. Ho cht c th dng tch Fe khi hn hp l : 3: A. Dung dch HNO3 c, ngui B. Dung dch kim C. Dung dch Fe2(SO4)3 D. Dung dch H2SO4 c, ngui Cu Khi un nng HI xy ra phn ng: 2HI(k) <----> I2(h) + H2(k) 4 : nhit no , hng s cn bng ca phn ng bng 1/64. Phn trm HI b phn hy l: A. 10% B. 20% C. 25% D. 15% Cu Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu 5 : tng ca in tch ht nhn nguyn t th: A. tnh kim loi tng dn, m in tng dn B. m in gim dn, tnh phi kim tng dn C. tnh phi kim gim dn, bn knh nguyn t tng dn D. tnh kim loi tng dn, bn knh nguyn t gim dn Cu Thy phn 68,4 gam mantoz vi hiu sut 50%. Ly dung dch thu c cho tc dng vi 6 : AgNO3/NH3 d th thu c m gam kt ta. Gi tr ca m l: A. 32,4 gam B. 64,8 gam C. 48,6 gam D. 43,2 gam Cu Sau khi ozon ha 100 mol kh oxi ri a v trng thi trc phn ng th p sut gim 5% so vi p 7 : sut ban u. Thnh phn % v khi lng ca ozon trong hn hp sau phn ng l: A. 20% B. 10% C. 5% D. 15% Cu Ha tan 10 gam hn hp mui khan FeSO4 v Fe2(SO4)3 . Dung dch thu c phn ng hon ton 8 : vi 1,58 gam KMnO4 trong mi trng axit H2SO4 . Thnh phn % theo khi lng ca Fe2(SO4)3 trong hn hp ban u ? ( Fe = 56 . K = 39 , S = 32 , O = 16 , Mn = 55 , H = 1 ) A. 38% B. 24% C. 76% D. 62% Cu Cho 672 ml kh clo ( ktc) i qua 200 ml dung dch KOH C (mol/l) 100oC. Sau khi phn ng xy 9 : ra hon ton thu c dung dch X (c pH = 13). C cn dung dch X thu c bao nhiu gam cht rn khan ? A. 6,07 B. 1,97 C. 4,95 D. 3,09 Cu Dn 4,48 lt (ktc) hn hp gm 2 ankin l ng ng k tip qua dung dch brom d thy khi 10 : lng bnh brom tng 9,4 gam. Bit 8,96 lt hn hp trn tc dng vi dung dch AgNO3/NH3 d th khi lng kt ta thu c khng qu 29,4 gam. 2 ankin l A. propin v but-1-in B. propin v but-2-in C. but-1-in v pent-1-in D. axetilen v propin Cu Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c xp theo chiu tng dn t 11 : tri sang phi l: A. phenyl clorua, propyl clorua, anlyl clorua B. phenyl clorua, anlyl clorua, propyl clorua C. anlyl clorua, phenyl clorua, propyl clorua D. anlyl clorua, propyl clorua, phenyl clorua Cu Cho cc kim loi: Cr, W, Fe, Cu, Cs. Sp xp theo chiu tng dn cng t tri sng phi l 12 : A. Cu < Cs < Fe < W < Cr B. Cu < Cs < Fe < Cr < W 1

C. Cu 13 : A. C. Cu 14 : A. Cu 15 : A. Cu 16 : A. Cu 17 : A. Cu 18 : A. Cu 19 : A. Cu 20 : A. Cu 21 : A.

Cs < Cu < Fe < W < Cr D. Cs < Cu < Fe < Cr < W Cho hn hp kim loi Mg, Zn, Fe vo dung dch cha AgNO3 v Cu(NO3)2. Sau khi phn ng xy ra hon ton thu c dung dch X gm 3 mui v cht rn Y gm ba kim loi. Ba mui trong X l Mg(NO3)2, Fe(NO3)3, AgNO3 B. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2 Mg(NO3)2, Zn(NO3)2, Fe(NO3)2 D. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3 Cho triolein ln lt tc dng vi cc cht sau: Na; H2; I2; H2O; dung dch NaOH; CaCO3, Cu(OH)2. Trong iu kin thch hp, s phn ng xy ra l: 4 B. 5 C. 3 D. 6 Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO, CO2, N2 v H2. Gi tr ca x l 0,36 B. 0,60 C. 0,45 D. 0,54 Cho cc dung dch: CrCl2, CrCl3, ZnSO4, Al(NO3)3, AgNO3. Ln lt nh t t dung dch NH3 v dung dch Ba(OH)2 vo mi dung dch trn cho n d. C bao nhiu trng hp sau khi kt thc th nghim thu c kt ta ? 6 B. 5 C. 4 D. 7 Ly 0,54 gam but-1-in trn vi kh hiro (xc tc Ni) , ri un nng n phn ng xy ra hon ton th thu c hn hp X. Thi X qua dung dch AgNO3 d trong NH3 thy xut hin 0,4025 gam kt ta, phn kh cn li phn ng va ht vi 0,395 gam KMnO4 trong dung dch. Th tch kh H2 (ktc) trn vo bng 0,056 lt B. 0,252 lt C. 0,140 lt D. 0,084 lt Ha tan hn hp hai kim loi kim th thuc hai chu k lin tip nhau trong bng tun hon vo dung dch HCl d thu c 13,95 gam mui v 3,36 lt H2 (ktc). Hai kim loi kim th l Mg v Ca B. Sr v Ba C. Be v Mg D. Ca v Sr S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l: 5; 3; 9 B. 4; 2; 6 C. 3; 5; 9 D. 4; 3; 6 nhn bit 3 l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt thuc th duy nht l Nc brom B. Ca(OH)2 Nc clo c tnh ty mu v st trng l do C. Dung dch NaOH D. Na

C cha axit hipoclor l tc nhn oxy ha mnh C. Clo l cht oxy ha mnh

B. Clo l cht kh tan trong nc

Cu 22 : A. Cu 23 : A. Cu 24 : A. Cu 25 : A. C. Cu 26 :

D. C cha oxi nguyn t l tc nhn oxy ha mnh Hn hp X gm Na v Al. Cho m gam X vo mt lng nc th thot ra V lt kh. Nu cng m gam X vo dung dch NaOH (d) th thu c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l 77,31% B. 39,87% C. 29,87% D. 49,87% Thm 3 gam MnO2 vo 197 gam hn hp KCl, KClO3 trn k v un nng n phn ng hon ton thu c 142,4 gam cht rn. % khi lng KClO3 trong hn hp mui ban u l: 73,5 B. 61,25 C. 74,6 D. 62,18 Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: Na2SO4, FeSO4, MgSO4, H2S, HCl (c), BaCl2. S trng hp c xy ra phn ng oxi ha - kh l 5 B. 4 C. 6 D. 3 Dy cc cht u lm mt mu dung dch thuc tm l

Benzen, but-1-en, axit fomic, p-xilen B. Axeton, etilen, anehit axetic, cumen Xiclobutan, but-1-in, m-xilen, axit axetic D. Etilen, axetilen, anehit fomic, toluen Cho cc phn ng sau : 1. St t oxit + dung dch HNO3 2. St (III) oxit + dung dch HNO3 3. Mg( kim loi ) + HCl 4. St(II) oxit + dung dch HNO3 5. HCl + NaOH 6. Cu + dung dch H2SO4 c nng Phn ng oxi ha kh l : A. 1, 4, 6 B. 1, 3, 4, 6 C. 1, 2, 3, 4 D. 4, 5, 6 Cu Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l 2

27 : A. C. Cu 28 :

Gly, Ala, Glu, Tyr B. Gly, Ala, Glu, Lys Gly, Val, Lys, Ala D. Gly, Val, Tyr, Ala Trn 100 ml dd A gm KHCO3 1M v K2CO3 1M vo 100 ml dd B gm NaHCO3 1M v Na2CO3 1M thu c dd C. Nh t t 100 ml dd D gm H2SO4 1M v HCl 1M vo dd C thu c V lt CO2 (ktc) v dd E. Cho dd Ba(OH)2 ti d vo dd E thu c m gam kt ta. Gi tr ca m v V l: A. 82,4 v 5,6 B. 34 v 5,6 C. 34 v 1,12 D. 82,4 v 2,24 Cu Trong cc cch di y, cch no khng th tch vng ra khi qung? 29 : A. Ngm qung vng trong dung dch NaCN c thi khng kh B. Ngm qung vng trong hn hp cng thy C. Ngm qung vng trong dung dch HNO3 c nng D. Trn ln qung vng vi thy ngn kim loi Cu Cho dung dch Ca(OH)2 d vo 100 ml dung dch Mg(HCO3)2 1,5M thu c kt ta X. Lc kt ta 30 : X em nung nng trong khng kh n khi lng khng i th thu c m gam cht rn. Gi tr ca m l A. 14,4 B. 18,2 C. 22,8 D. 25,2 Cu Thc hin phn ng crackinh hon ton m gam isobutan, thu c hn hp A gm hai hirocacbon. 31 : Cho hn hp A i qua dung dch nc brom c ha tan 11,2 gam Br2. Brom b mt mu hon ton. C 2,912 lt kh (ktc) thot ra khi bnh brom, kh ny c t khi so vi CO2 bng 0,5. Gi tr ca m l: A. 5,22 gam B. 5,80 gam C. 6,96 gam D. 4,64 gam Cu Cho triolein ln lt tc dng vi cc cht sau: Na; H2; I2; H2O; dung dch NaOH; CaCO3, Cu(OH)2. 32 : Trong iu kin thch hp, s phn ng xy ra l: A. 3 B. 4 C. 5 D. 6 Cu t chy hon ton mt hn hp A (glucoz, anehit fomic, axit axetic) cn 2,24 lt O2 (ktc). Dn 33 : sn phm chy qua bnh ng dung dch Ca(OH)2, thy khi lng bnh tng m gam. Gi tr ca m l A. 12,4 B. 3,10 C. 4,40 D. 6,20 Cu Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy 34 : ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. HCOOCH3 v 6,7. B. CH3COOCH3 v 6,7. C. HCOOC2H5 v 9,5. D. (HCOO)2C2H4 v 6,6. Cu Pht biu no sau y l khng ng 35 : A. KMnO4 dng iu ch O2 trong phng th nghim do phn ng: 2KMnO4 ---> K2MnO4 + MnO2 + O2 B. Nc javen c tnh oxi ha mnh do to c HClO theo phn ng: NaClO + CO2 + H2O ---> NaHCO3 + HClO C. Axit flohiric c dng khc thy tinh do phn ng: 4HF + SiO2 ---> SiH 4 + 2H2O D. AgBr trc y c dng ch to phim nh do phn ng: 2AgBr --> 2Ag + Br2 Cu Pht biu no sau y l ng 36 : A. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng B. Theo chiu tng ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit nng chy gim dn C. Kim loi xesi c dng ch to t bo quang in D. Kim loi magie c kiu mng tinh th lp phng tm khi Cu Cho kh CO qua 30,40 gam hn hp A gm Fe2O3 v FeO t nng mt thi gian, ngi ta thu c 37 : hn hp cht rn B. Ha tan hon ton B trong lng va dung dch HNO3 thu c dung dch D. Nhng thanh Cu vo dung dch D n phn ng hon ton th thy khi lng Cu gim 12,80 gam. Phn trm khi lng cc cht trong A ln lt l: A. 75,0% v 25,0% B. 52,6% v 47,4% C. 61,3% v 38,7% D. 33,3% v 66,7% 3

Cu 38 : A. Cu 39 : A. Cu 40 :

A. Cu 41 : A. Cho mt inh st c nh ra sch vo ng nghim cha dung dch CuSO4, thy b mt Fe chuyn sang mu , dung dch thu c nht mu xanh B. Thm vi git dung dch H2S vo ng nghim cha dung dch FeCl3, thy xut hin kt ta en v dung dch nht mu vng nu C. Nh t t dung dch KMnO4 vo ng nghim cha dung dch hn hp FeSO4 v H2SO4, thy thuc tm mt mu v dung dch thu c c mu vng nu D. Ct mt ming Na kim loi trong khng kh, thy b mt Na chuyn t trng bc sang mu xm v c si bt kh Cu Hn hp X gm 0,1 mol anlyl clorua; 0,3 mol benzyl bromua; 0,1 mol hexyl clorua 0,15 mol phenyl 42 : bromua. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l A. 70,75 B. 14,35 C. 28,7 D. 57,4 Cu Hn hp X gm 1 mol amino axit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng 43 : ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 7 v 1,5 B. 8 v 1,5 C. 8 v 1,0 D. 7 v 1,0 Cu Dy no sau y xp theo chiu gim dn bn knh ion 44 : A. O2-, F-, Na+, Mg2+, Al3+ B. Al3+, Mg2+, Na+, F-, O22+ 23+ + C. Mg , O , Al , F , Na D. Al3+, Mg2+, Na+, O2-, FCu Hiro c iu ch bng cch in phn nc, H c 2 ng v 1H v 2H. Bit khi lng nguyn t 45 : trung bnh ca H l 1,008 v ca oxi l 16. Hi trong 100 gam nc ni trn c bao nhiu ng v 2H A. 3,00.1023 B. 6,02.1023 C. 6,50.1023 D. 5,35.1022 Cu Cho phng trnh ha hc: 46 : Al + HNO3 ----> Al(NO3)3 + NO + N2O + H2O (bit th l th tch N2O : NO = 1 : 3). Sau khi cn bng phng trnh ha hc trn vi h s cc cht l nhng s nguyn, ti gin th h s ca HNO3 l: A. 64 B. 60 C. 66 D. 62 Cu Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO42- v x mol OH-. Dung dch Y c cha ClO4-, NO347 : v y mol H+; tng s mol ClO4- v NO3- l 0,04. Trn X v Y c 100 ml dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l A. 13 B. 12 C. 1 D. 2 Cu Dy polime no sau y c ngun gc t thin nhin: 48 : A. t tm, amiloz, cao su buna-S, len B. xenluloz, amilopectin, t visco, t tm C. t axetat, t visco, t nilon-6, bng D. t capron, tinh bt, cao su isopren, bng

Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l axit etanoic B. axit propanoic C. axit metanoic D. axit butanoic Hirat ha hn hp hai olefin ng ng lin tip thu c hn hp ancol A. t chy ht A, ri hp th sn phm chy vo dung dich Ca(OH)2 thy xut hin 20 gam kt ta v khi lng bnh tng 34,6 gam. Thm NaOH d vo dung dch thu c li xut hin thm 15 gam kt ta na. Trong A c th c 1 ancol B. 2 ancol C. 4 ancol D. 3 ancol Mt hn hp gm anehit acrylic v mt anehit n chc X. t chy hon ton 1,72 gam hn hp trn cn va ht 2,296 lt O2 (ktc). Cho ton b sn phm chy hp th ht vo dung dch Ca(OH)2 d, c 8,5 gam kt ta. Cng thc cu to ca X l: HCHO B. C2H5CHO C. C3H5CHO D. CH3CHO Hin tng no di y c m t khng ng:

P N
CU 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 M 109 A D B B C B D B A B A C C A D A B C A A A C C D D B D D C C B B D A C C B A D D B A D A D C C B