S GD&T Ngh An TRNG THPT ANH SN 3 chnh

K thi chn hc sinh gii CP TRNG Nm hc 2009- 2010 Mn thi: Ha lp 12 THPT- bng A

Thi gian: 180 pht (khng k thi gian giao )

Cu 1. Cho 0,15 mol Este n chc X phn ng vi dung dch NaOH. Sau phn ng thu c 21 gam mui. Xc nh cng thc phn t ca X. bit rng X c s nguyn t C nh hn 6. Cu 2. Ha tan ht 2,25 gam hn hp X gm 2 kim loi A (ha tr 1) v B (ha tr 2) trong lng d dung dch hn hp HNO3, H2SO4 thu c 2,205 gam hn hp kh Y gm NO2 v mt kh Z; Y chim th tch 1,008 lt (ktc). Hy tnh khi lng mui khan to thnh. Cu 3. Ti sao t khi hi ca axit axetic so vi khng kh xp x bng 4 m khng phi l 2,07 ? Cu 4. Cho 0,25 mol hn hp X gm hai ankanal A, B tc dng vi dung dch AgNO3 trong NH3 d thu c 86,4 gam Ag kt ta v khi lng dung dch AgNO3 gim 77,5 gam. a) Xc nh A, B v s mol mi cht. b) T A v B vit phng trnh iu ch este c cng thc C3H6O2. Cu 5. Cho cc mui sau: Na2HPO3, NaH2PO2, Na2HPO4, NaH2PO4. Mui no l mui axit? Mui no l mui trung ha? Gii thch? Cu 6. Vit phng trnh ha hc chng minh: a) kh NH3 c tnh Oxi ha b) Dung dch H3PO4 c tnh Oxi ha c) Anehit axetic c tnh kh d) Axitaxetic c tnh axit manh hn axitcacbonic Cu 7. Cho X l dn xut ca benzen c CTPT C9H8O2. bit X phn ng vi dd brom theo t l mol 1:1, khi phn ng vi dd NaOH cho 2 mui v nc. Xc nh CTCT c th c ca X. Cu 8. Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Xc nh cng thc cu to ca anken Cu 9. A l mt este c to bi axit X v ancol Y u no mch h. Trong A c hai vng c lp, A c CTGN l C9H11O6. Tm mt CTCT ca A? Cu 10. Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Xc nh phn trm khi lng ca NaX trong hn hp ban u . ..Ht..

S GD&T Ngh An

K thi chn hc sinh gii CP TRNG

TRNG THPT ANH SN 3 chnh Mn thi: Ha

Nm hc 2008- 2009 lp 12 THPT- bng A

Thi gian: 180 pht (khng k thi gian giao )

Cu 1(5,0 im): 1. Nu hin tng, vit phng trnh phn ng xy ra trong cc trng hp sau: a) Cho kim loi Na vo dung dch AgNO3 b) Cho t t dung dch Na2CO3 vo dung dch HCl v ngc li 2. Tnh pH ca dung dch CH3COONa 0,1M. Cho pka = 4,75 3. Cho s sau: A B C D C + SiO2 Xc nh A,B,C,D (bit D l thnh phn chnh ca qung apatit) v vit cc phng trnh phn ng Cu2 (6,0 im ) 1. Vit cc phng trnh khi cho C3H6O2 tc dng vi: Na, NaOH, AgNO3 trong NH3 un nng. 2. Mt cht hu c A mch thng c cng thc phn t: C3H10O2N2.Khi A tc dng vi kim to NH3. Mt khc A tc dng vi axit to thnh mui amin bc 1. Xc nh cng thc cu to ca A. 3. Hn hp X gm 2 axit no: A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt kh CO2(ktc). trung ho 0,3 mol X cn 500ml dung dch NaOH 1M. Tm cng thc cu to ca 2 axit trn Cu3 (5,0 im). Kh hon ton 8,12g mt oxit kim loi bng CO nhit cao thnh kim loi. Dn ton b kh sinh ra vo bnh ng 1lt dung dich gm NaOH 0,1M v Ba(OH)2 0,15M, thy to thnh 27,58 g kt ta. Nu ly lng kim loi sinh ra ho tan ht vo dung dch HCl d th thu c 2,352 lt kh H2(ktc). a) Xc nh cng thc oxit kim loi trn. b) Cho 16,24g oxit trn tc dng 100ml dung dch HCl 6M thu c dung dch B.Cho dung dch B tc dng va vi dung dch NaOH 6M c kt ta C,nung C trong chn khng thu c cht rn D.Tnh th tch dung dch NaOH cn dng v khi lng cht rn D. Cu4 (4,0 im) 1.Nu hin tng khi cho imetylxeton vo dung dch brom c mt axitaxetic v vit phng trnh phn ng xy ra. 2.Cho hp cht hu c A tc dng vi dung dch NaOH thu c dung dch B v C. Kh C bng hiro co Ni xc tc thu c D. hirat D thu c propen. Xc nh cng thc cu to ca A,B,C,D. Vit phng trnh phn ng xy ra. Bit B tham gia phn ng trng gng , C khng tham gia phn ng trng gng. 3. Trn D vi mt ancol E c 21g F ri cho tc dng vi Na d thu c 3,92 lt kh (ktc).Mt khc oxi ho 10,5g hn hp F thu c hn hp G.

Cho G tc dng vi AgNO3 trong NH3 thu c 27g Ag. Xc nh cng thc cu to ca E.Bit rng KLNT ca E nh hn 120. (Cho Fe = 56; Na = 23; O = 16; N= 14; Ag = 108; H = 1;Cl= 35,5; C= 12; Br= 80) (Th sinh khng c s dng bt c ti liu no)