BI TP PIN IN - IN PHN

Bai 1:
2+

Cho cc in cc sau: Cu| Cu (1 M); Pt| Fe2+ (0,4M), Fe3+ (0,6 M); Ag, AgCl| Cl- (0,1 M); Pt, H2 (p = 0,5 atm)| H+(0,1 M); Pt, Cl2 (p = 2 atm)| Cl- (0,5 M). 1. Tnh th in cc ca cc in cc 25oC. ( Eo(AgCl/Ag, Cl-) = + 0,224 V). 2. Vi cc in cc cho, c th lp c nhng pin no? (Vit s pin theo qui c ca IUPAC). Tnh sc in ng ca pin. Vit cc phn ng in cc v phn ng xy ra khi pin hot ng. Bai 2: C 2 bnh: bnh 1 ng 0,5 lit dung dch hn hp Fe2+ 0,2 M v Fe3+ 0,1 M; bnh 2 ng 1,0 lit dung dch hn hp Fe2+ 0,1 M v Fe3+ 0,2 M. Nhng 2 thanh Pt vo 2 bnh v cho cu mui tip xc vi 2 dung dch (ngi ta thit lp mt pin nng ). 1. Ch r cc tnh ca 2 in cc. 2. Vit s pin in v tnh sc in ng ca pin . Ni 2 in cc bng dy dn 3. Vit cc phn ng in cc v phn ng xy ra khi pin hot ng. 4. Tnh nng ion Fe2+ v Fe3+ trong cc bnh khi pin ngng hot ng v in lng i qua dy dn. Bai 3: Cho cc phn ng sau xy ra trong cc pin in: 1. Zn + Br2 (aq) Zn2+ (aq) + 2 Br- (aq) 2. Pb + 2 Ag+ (aq) Pb2+ (aq) + 2 Ag + 3+ 2+ 3. Cu (aq) + Fe (aq) Cu (aq) + Fe2+ (aq) 4. Cu2+(aq) + H2 (aq) Cu + 2 H+ (aq) 5. Ag+ (aq) + Cl- (aq) AgCl (r) 6. 2Ag (r) + Cl2 (k) 2AgCl (r) Hy vit s pin in v cho bit chiu ca dng in mch ngoi. Bai 4: D on chiu ca cc phn ng oxi ho - kh sau: 1. Fe + Cu2+ Fe2+ + Cu 2. 2Fe2+ + Cu2+ 2Fe3+ + Cu 2+ + 3. Fe + Ag Fe3+ + Ag 4. 2 MnO4- + 10 Cl- + 16 H+ 2Mn2+ + 5Cl2 + 8H2O 3+ 2+ 5. 2 Fe + 2 Cl 2 Fe + Cl2 3+ 6. 2 Fe + 2 I 2 Fe2+ + I2 Bai 5: iu ch Cl2 trong phng th nghim, ngi ta cho dung dch HCl c tc dng vi K2Cr2O7 m khng dng dung dch HCl long. Gii thch ti sao? Bai 6: Tin hnh in phn mt mui clorua kim loi nng chy, thu c 7,8 gam kim loi anot v 2,24 lt kh (ktc) anot. Xc nh mui em in phn. Bai 7: Tin hnh in phn 100 ml dung dch hn hp Cu(NO 3)2 0,1 M v AgNO3 0,15 M (in cc tr) vi cng dng in l 1 A. Tnh khi lng cc cht thu c anot v catot khi thi gian in phn l: a) 16 pht 5 giy; b) 32 pht 10 giy; c) 64 pht 20 giy. Bai 8: Tin hnh in phn 3 bnh in phn mc ni tip (in cc tr): bnh 1 ng dung dch CuSO4; bnh 2 ng dung dch NaCl (c mng ngn gia 2 in cc); bnh 3 ng dung dch AgNO3. Hi khi catot bnh 1 thot ra 1,6 gam kim loi th cc in cc cn li thot ra nhng cht g? bao nhiu gam? Bit cc cht ban u trong cc bnh in phn cha ht.

Bai 9:

(HSG QG 2001-2002) trang 1 / 3

Cho dng in 0,5A i qua dung dch mui ca mt axit hu c trong 2 gi. Kt qu sau qu trnh in phn l trn catt to ra 3,865 gam mt kim loi v trn ant c kh etan v kh cacbonic thot ra. 1. Cho bit mui ca kim loi no b in phn? Bit rng 5,18 gam ca kim loi y c 1,59 gam Cu t dung dch ng sunfat. 2. Cho bit mui ca axit hu c no b in phn? 3. Vit cc phng trnh phn ng xy ra trn cc in cc. Bai 10: (HSG QG 2002-2003) 1. Phn ng gia AgNO3 vi KCl trong dung dch to thnh kt ta AgCl v gii phng nng lng. Ta c th to ra mt t bo in ho (pin) sinh cng in nh phn ng . a) Vit cng thc ca t bo in ho theo quy tc IUPAC v cc na phn ng in cc ti anot v catot. 0 b) Tnh G298 ca phn ng kt ta AgCl v E 0 8 ca t bo in ho. 29 0 10 Cho: TAgCl 25 C bng 1,6. 10 . Bai 11: (HSG QG 2004-2005) pH = 0 v 25oC th in cc tiu chun Eo ca mt s cp oxi ho - kh c cho nh sau: 2IO4 / I2 (r) 1,31 V ; 2IO3 / I2 (r) 1,19 V ; 2HIO/ I 2 (r) 1,45 V ; I 2 (r)/ 2I 0,54 V. (r) ch cht trng thi rn. 1. Vit phng trnh na phn ng oxi ho - kh ca cc cp cho. 2. Tnh Eo ca cc cp IO4 / IO3 v IO3 / HIO 3. V phng din nhit ng hc th cc dng oxi ho - kh no l bn, cc dng no l khng bn? Ti sao? 4. Thm 0,40 mol KI vo 1 lt dung dch KMnO4 0,24 M pH = 0 a) Tnh thnh phn ca hn hp sau phn ng. b) Tnh th ca in cc platin nhng trong hn hp thu c so vi in cc calomen bo ho. 5. Tnh Eo ca cp IO3 / I2(H2O). I2(H2O) ch it tan trong nc. 2+ MnO Cho bit: Eo4 / Mn = 1,51 V ; E ca in cc calomen bo ho bng 0,244 V ; 25oC,
RT ln = 0,0592 lg ; F

tan ca it trong nc bng 5,0.10 4 M.

Bai 12:

(HSG QG 2005-2006) Ngi ta m niken ln mu vt kim loi bng phng php m in trong b m cha dung dch niken sunfat. in p c t ln cc in cc ca b m l 2,5 V. Cn m 10 mu vt kim loi hnh tr; mi mu c bn knh 2,5cm, cao 20cm..Ngi ta ph ln mi mu mt lp niken dy 0,4 mm. Hy: a) Vit phng trnh cc phn ng xy ra trn cc in cc ca b m in. b) Tnh in nng (theo kWh) phi tiu th. Cho bit: Niken c khi lng ring D = 8,9 g/cm3; khi lng mol nguyn t l 58,7(g/mol); hiu sut dng bng 90% ; 1 kWh = 3,6.106J. Bai 13: (HSG QG 2006 - 2007) Mui KClO4 c iu ch bng cch in phn dung dch KClO3. Thc t khi in phn mt in trang 2 / 3

cc, ngoi na phn ng to ra sn phm chnh l KClO 4 cn ng thi xy ra na phn ng ph to thnh mt kh khng mu. in cc th hai ch xy ra na phn ng to ra mt kh duy nht. Hiu sut to thnh sn phm chnh ch t 60%. 1. Vit k hiu ca t bo in phn v cc na phn ng anot v catot. 2. Tnh in lng tiu th v th tch kh thot ra in cc (o 25 0C v 1atm) khi iu ch c 332,52g KClO4.

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