GII CHI TIT

THI TUYN SINH CAO NG NM 2009

Mn thi : HO, khi B - M : 472
H = 1; He = 4; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39;
Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137; Au = 197
PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1 : Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dung dch l :
+
3+

2
+
+

A. H , Fe , NO3 ,SO4
B. Ag , Na , NO3 , Cl
2+
+
2
3
3+
+

C. Mg , K ,SO 4 , PO4
D. Al , NH 4 , Br , OH
Cu 2 : Trong thc t, phenol c dng sn xut
A. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric
B. nha rezol, nha rezit v thuc tr su 666
C. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D
D. nha rezit, cht dit c 2,4-D v thuc n TNT
Cu 3 : Cho m gam hn hp X gm FeO, Fe 2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu
c dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn
mt thu c m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu
c m2 gam mui khan. Bit m2 - m1 = 0,71. Th tch dung dch HCl dng l
A. 160 ml
B. 80 ml
C. 240 ml
D. 320 ml
Hng dn:
2Fe2++Cl2=2Fe3++2Cl- m2-m1=0,71=mCl2 s mol Cl2=0,71:71=0,01(mol) s mol Fe2+=0,02(mol)
S mol Fe3+=0,04(mol) Tng s mol HCl ban u=2. [2nFe2++3nFe3+]=2. [0,04+0,12]=0,32(mol)
VHCl=0,32:2=0,16(lt)
Cu 4 : Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl 3; 0,016 mol
Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A. 4,128
B. 2,568
C. 1,560
D. 5,064
=
Hng dn: nOH- 0,26(mol), nFe3+=0,024(mol), nAl3+=0,032(mol), nH+=0,08(mol)
H++OH-=H2O Fe3++3OH-=Fe(OH)3 Al3++3OH-=Al(OH)3
0,08 0,08
0,024 0,072 0,024 0,032 0,096 0,032
Tng OH-=0,08+0,072+0,096=0,248(mol) nOH- d=0,26-0,248=0,012(mol)
Al(OH)3+OH-=[Al(OH)4]0,032
0,012
s mol Al(OH)3 cn=0,02(mol)
m=0,02.78+0,024.107=4,128(g)
Cu 5 : Ch dng dng dch KOH phn bit c cc cht ring bit trong nhm no sau y ?
A. Zn, Al2O3, Al
B. Mg, K, Na
C. Mg, Al2O3, Al
D. Fe, Al2O3, Mg
Hng dn:
Al tan v c kh , Al2O3 tan v khng c kh thot ra
Cu 6 : Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu
c 3,36 gam cht rn. Gi tr ca m l
A. 5,04
B. 4,32
C. 2,88
D. 2,16
Hng dn:
Mg+2FeCl3=MgCl2+2FeCl2 Mg+FeCl2=MgCl2+Fe
0,06 0,12
0,12
0,06 0,06
0,06(mol) m=(0,06+0,06).24=2,88(g)
Cu 7 : Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau
phn ng thu c m gam kt ta. Gi tr ca m l
A. 17,1
B. 19,7
C. 15,5
D. 39,4
Hng dn:
s mol Ba(OH)2=s mol Ba2+= 0,2(mol); s mol CO32-=0,1(mol)
Ba2++CO32-=BaCO3 Khi lng kt ta =197.0,1=19,7(gam)
0,2 0,1
0,1

Cu 8 : Nguyn tc chung c dng iu ch kim loi l

A. cho hp cht cha ion kim loi tc dng vi cht kh.
B. kh ion kim loi trong hp cht thnh nguyn t kim loi.

C. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi
D. cho hp cht cha ion kim loi tc dng vi cht oxi ho.
Cu 9 : Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c
vi dung dch AgNO3 ?
A. Zn, Cu, Mg
B. Al, Fe, CuO
C. Fe, Ni, Sn
D. Hg, Na, Ca
Cu 10 : Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu
c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l
A. 25%
B. 20%
C. 50%
D. 40%
Hng dn:
Xt trong 1 mol X: mX=1.4.3,75=15(g); s molH2=x : 2x+28(1-x)=15, x=0,5(mol)
nY=15: [4.5]=0,75(mol)
s mol H2 p=1-0,75=0,25(mol)=nC2H4
H=(0,25:0,5).100=50%
Cu 11 : Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg
xenluloz trinitrat (hiu sut 80%) l
A. 34,29 lt
B. 42,86 lt
C. 53,57 lt
D. 42,34 lt
Ta c s : 3nHNO3[C6H7O2(NO3)3]n
189n
297n
x
59,4
x=37,8(kg)
H=80% x=37,8.100:80=47,25(kg)
VHNO3=(47,25.100): (63.1,4)=53,57(lt)
Cu 12 : Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l
A. O2, H2O, NH3
B. H2O, HF, H2S
C. HCl, O3, H2S
D. HF, Cl2, H2O
Cu 13 : Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l :
A. NaHCO3, ZnO, Mg(OH)2
B. Mg(OH)2, Al2O3, Ca(HCO3)2
C. NaHCO3, MgO, Ca(HCO3)2
D. NaHCO3, Ca(HCO3)2, Al2O3
Cu 14 : Cht X c cng thc phn t C4H9O2N . Bit :
X + NaOH Y + CH4O
Y + HCl (d) Z + NaCl
Cng thc cu to ca X v Z ln lt l
A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH
B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH
C. H2NCH2COOC2H5 v ClH3NCH2COOH
D. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH
Hng dn:
X l este ca CH3OH vi amino axit
X: CH3CH(NH2)COOCH3+NaOHCH3CH(NH2)COONa(Y)+CH3OH
CH3CH(NH2)COONa+HClCH3CH(NH2)COOH(Z)+NaCl
Cu 15 : Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca
nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X
v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l
A. kh him v kim loi
B. kim loi v kim loi
C. kim loi v kh him
D. phi kim v kim loi
Hng dn:
X c e mc nng lng cao nht 3p suy ra l 3p3 X: 3s23p3 X l phi kim
Y : c cu hnh lp ngoi: 3s23p1 : Y l kim loi
Cu 16 : Cht dng lm kh kh Cl2 m l
A. dung dch H2SO4 m c
B. Na2SO3 khan
C. CaO
D. dung dch NaOH c
Hng dn: CaO+H2O=Ca(OH)2 Ca(OH)2+Cl2=CaOCl2+H2O
Na2SO3+Cl2+H2O=Na2SO4+2HCl
2NaOH+Cl2=NaCl+NaClO+H2O
Cu 17 : phn bit CO2 v SO2 ch cn dng thuc th l
A. dung dch Ba(OH)2
B. CaO
C. dung dch NaOH
D. nc brom
Hng dn: SO2+Br2+2H2O=H2SO4+2HBr SO2 lm mt mu nc brom
Cu 18 : Pht biu no sau y sai ?

A. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn.

B. Nhit si ca este thp hn hn so vi ancol c cng phn t khi
C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.
D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol
Cu 19 : kh hon ton 200 ml dung dch KMnO4 O,2M to thnh cht rn mu nu en cn V lt
kh C2H4 ( ktc). Gi tr ti thiu ca V l
A. 1,344
B. 4,480
C. 2,240
D. 2,688
Hng dn:
S mol KMnO4=0,2.0,2=0,04(mol)
2KMnO4+3C2H4+4H2O2KOH+2MnO2+3C2H4(OH)2
0,04
0,06
V=0,06.22,4=1,344(lt)
Cu 20 : S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l
A. 2
B. 5
C. 4
D. 3
Cu 21 : Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc
phn ng xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d
dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l
A. 8,10 v 5,43
B. 1,08 v 5,16
C. 0,54 v 5,16
D. 1,08 v 5,43
Hng dn: Theo bi ra Al cn d
2Al+6HCl=2AlCl3+3H2
0,01
0,015
3+
Al=Al +3e
Ag++1e = Ag
Cu2+ + 2e = Cu
x
3x
0,03 0,03 0,03
0,03 0,06
0,03
p dng bo ton e x=0,03(mol) .Tng s mol Al=0,04(mol)
m 1=27.0,04=1,08(g)
m2=mAl+mCu+mAg=0,01.27+0,03.108+0,03.64=5,43(g)
Cu 22 : Trong cc cht : FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi
ho v tnh kh l
A. 5
B. 4
C. 2
D. 3
Cu 23 : S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc dng c vi
dung dch NaOH nhng khng tc dng c vi Na l
A. 2
B. 1
C. 3
D. 4
Cu 24 : Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm thnh v c th
c dng lm cht ty mu. Kh X l
A. NH3
B. O3
C. SO2
D. CO2
Cu 25 : Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c
dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ho nu
trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng
c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l
A. 12,80%
B. 15,25%
C. 10,52%
D. 19,53%
Hng dn:
Y chc chn c NO(30)
MY=5,18:0,14=37 30(NO)<MY=37<kh cn li l N2O d dng c c nNO=0,07 nN2O=0,07
X tc dng naOH d khng c kh thot ra chng t khng sinh ra NH4NO3
Ta c cc qu trnh oxi ho v qu trnh kh
Mg=Mg2++2e Al=Al3++3e N+5+3e=NO 2N+5+8e=N2O
x
2x y
3y
0,21 0,07
0,56 0,07(mol)
p dng bo ton e ta c h
2x+3y=0,77
x=0,322
24x+27y=8,862
y=0,042
%mAl=(0,042.27):8,862=12,8%
Cu 26 : Cho cc cn bng sau :
xt,t o

2SO3 (k)
(1) 2SO 2 (k) + O2 (k)

xt,t

2NH3 (k)
(2) N 2 (k) + 3H 2 (k)

CO(k) + H2 O(k)
(3) CO 2 (k) + H 2 (k)

H 2 (k) + I 2 (k)
(4) 2HI(k)

Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l

A. (1) v (3)
B. (2) v (4)
C. (3) v (4)
D. (1) v (2)
Hng dn: Tng h s trc v sau phn ng bng nhau vi (3) v (4)
Cu 27 : Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH
1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l
A. CH3COOCH=CHCH3
B. CH2=CHCH2COOCH3
C. CH2=CHCOOC2H5
D. C2H5COOCH=CH2
Hng dn:
X: MX=100 nn d thy X l este n chc RCOOR nX=0,2(mol) nNaOH=0,3(mol)
RCOOR+NaOH RCOONa+ROH
0,2
0,2
0,2
m cht rn=mmui+mNaOH d 23,2=0,2(R+67)+0,1.40 R=29(C2H5)
R=27(C2H3 hay CH2=CH-)
X l C2H5COOCH=CH2
Cu 28 : Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l
A. axit -aminopropionic
B. mety aminoaxetat
C. axit - aminopropionic
D. amoni acrylat
X l : CH2=CH-COONH4
Cu 29 : Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l :
A. C2H4(OH)2, CH3OH, CH3CHO
B. CH3CHO, C2H5OH, C2H5COOCH3
C. CH3OH, C2H5OH, CH3CHO
D. CH3CHO, C6H12O6 (glucoz), CH3OH
Cu 30 : Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc
cht c sp xp theo tnh axit tng dn (t tri sang phi) l :
A. (X), (Z), (T), (Y) B. (Y), (T), (Z), (X)
C. (Y), (T), (X), (Z) D. (T), (Y), (X), (Z)
Cu 31 : t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn
hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6
lt ( ktc). Kim loi M l
A. Be
B. Cu
C. Ca
D. Mg
HD:mKh=23-7,2=15,8(g)
M=Mn++ne
Cl2 +2e =2Cl- O2+4e = 2O2a
na b
2b
c 4c
na=2b+4c
b+c=0,25
b=0,2
71a+32b=15,8
c=0,05
suy ra na=0,6 nn M=7,2:a=12n(n=2, M=24_Mg)
Cu 32 : Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung
dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta.
Gi tr ca m v a ln lt l :
A. 13,3 v 3,9
B. 8,3 v 7,2
C. 11,3 v 7,8
D. 8,2 v 7,8
HD: Thu c cht tan duy nht
Na2O+H2O=2NaOH 2NaOH+Al2O3=2NaAlO2+H2O
a
2a
2a
a
2a
2a=0,2.0,5 suy ra a=0,05 thi CO2 vo dung dch CO2+NaAlO2+H2O=Al(OH)3+NaHCO3
0,1
0,1
mkt ta=78.0,1=7,8(g)
m=62.0,05+102.0,05=8,2(g)
Cu 33 : Cho cc cht : xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm
cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l :
A. 2-metylpropen, cis-but-2-en v xiclobutan B. but-1-en, 2-metylpropen v cis-but-2-en
C. xiclobutan, cis-but-2-en v but-1-en
D. xiclobutan , 2-metylbut-2-en v but-1-en
Cu 34 : Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc
Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch
brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l
A. 32,0
B. 8,0
C. 3,2
D. 16,0
HD: mX=0,3.2+0,1.52=5,8(g) Theo bo ton khi lng mX=mY nY=5,8:29=0,2(mol) s mol H2
d=0,1 (mol) nH2 phn ng =0,3-0,1=0,2(mol)
C4H4+2H2C4H8
C4H8+Br2C4H8Br2
0,1
0,2 0,1
0,1 0,1
mBr2=160.0,1=16(g)

Cu 35 : Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng

thu c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l
A. FeO v 0,224
B. Fe2O3 v 0,448
C. Fe3O4 v 0,448
D. Fe3O4 v 0,224
HD:
nO(trong oxit)=nCO2)=0,02=nCO nFe=0,84:56=0,015(mol)
FexOy: x:y=0,015:0,02=3:4 X l Fe3O4
V=0,02.22,4=0,448(lt)
Cu 36 : Mt nguyn t ca nguyn t X c tng s ht proton, electron l 52 v c s khi l 35. S
hiu nguyn t ca nguyn t X l
A. 15
B. 17
C. 23
D. 18
HD: ta c h 2p+n=52 v p+n=35 p=17(s proton), n=18
Cu 37 : Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d.
Cho ton b X tc dng vi dung dch NaHCO 3 (d) thu c 0,56 lt kh CO2 ( ktc). Khi lng
etanol b oxi ho to ra axit l
A. 4,60 gam
B. 1,15 gam
C. 5,75 gam
D. 2,30 gam
HD: CH3COOH+NaHCO3CH3COONa+CO2+H2O
0,025
0,025
mancol=46.0,025=1,15(g)
Cu 38 : Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X.
Cho ton b X tc dng vi 200 ml dung dch Ba(OH) 2 1M, sau phn ng thu c m gam kt ta. Gi
tr ca m l
A. 46,6
B. 54,4
C. 62,2
D. 7,8
HD:nphn=0,1(mol) nAl3+=0,1 nSO4(2-)=0,2 nBa2+=0,2 nOH-=0,4
Ba2++SO42-=BaSO4 Al3+3OH-=Al(OH)3 Al(OH)3+OH-=[Al(OH)4]0,2 0,2
0,2
0,1 0,3 0,1
0,1
0,1
mkt ta=mBaSO4=0,2.233=46,6(g)
Cu 39 : Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch
NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3
un nng th thu c 21,6 gam Ag. Tn gi ca X l
A. axit acrylic
B. axit propanoic
C. axit etanoic
D. axit metacrylic
HD: nHCOOH=1/2nAg=0,1(mol) mRCOOH=8,2-0,1.46=3,6(g)
HCOOH+NaOHHCOONa+H2O RCOOH+NaOH RCOONa+H2O
0,1
0,1
0,05
0,05
R+45=72 R=27(C2H3)
Cu 40 : Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng
ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai
anehit trong X l
A. CH3CHO v C2H5CHO
B. HCHO v CH3CHO
C. HCHO v C2H5CHO
D. C2H3CHO v C3H5CHO
nAg=0,3(mol) nAg/nanehit>2 chng t c HCHO v CH3CHO
II. PHN RING [10 cu]
Th sinh ch c chn lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41 : Phn bn nitrophotka (NPK) l hn hp ca
A. (NH4)2HPO4 v KNO3
B. (NH4)2HPO4 v NaNO3
C. (NH4)3PO4 v KNO3 D. NH4H2PO4 v KNO3
Cu 42 : Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200
ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton,. Lc dung dch, em c cn thu c
18,8 gam mui khan. Kim loi M l
A. Mg
B. Zn
C. Cu
D. Fe
HD:
s mol AgNO3=0,2(mol) khi lng mui AgNO3 l 170.0,2=34(g). Khi lng mui sau phn ng
gim 34-18,8=15,2(g)
2AgNO3M(NO3)2
2 mol khi lng gim (216-M)g
0,2 mol khi lng gim 15,2g
M=64(Cu)

Cu 43 : Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng
100.000 vC th s mt xch alanin c trong phn t X l
A. 453
B. 382
C. 328
D. 479
HD:
X

nH2N-C2H4-COOH
1250:105
0,0125(mol)
n=425:(0,0125.89)=382(mt xch)
Cu 44 : Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch
cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng
ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l
A. mt este v mt axit
B. mt este v mt ancol
C. hai axit
D. hai este
HD:
Trong X c ancol hoc axit
nKOH=11,2:56=0,2(mol)
THA: n(axit)=2nH2=0,3 suy ra s mol KOH tc dng vi axit l 0,3 mol trong khi tng KOH l 0,2
mol loi
THD: hai este khng tc dng vi Na
THC: naxit>nKOH
Cu 45 : Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung
dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X
l
A. H2SO4 c
B. H3PO4
C. H2SO4 long
D. HNO3.
HD: Khi un NaOH vi Y to kh T khng mu th ch c th l NH4NO3
Nh vy Zn phi tan trong HNO3 nn X l HNO3
Cu 46 : Cho cc chuyn ho sau
o

xc tc, t
X + H 2 O
Y
o

Ni, t
Y + H 2
Sobitol
o

t
Y + 2AgNO3 + 3NH3 + H2 O
Amoni gluconat + 2Ag + 2NH4 NO3
xc tc
Y
E + Z
a
nhsa
ng
Z + H2O
X +G
cha
tdie
pluc

X, Y v Z ln lt l :
A. tinh bt, glucoz v ancol etylic
B. tinh bt, glucoz v kh cacbonic
C. xenluloz, glucoz v kh cacbon oxit
D. xenluloz, frutoz v kh cacbonic
Cu 47 : iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca
phn ng l 90% th khi lng bt nhm cn dng ti thiu l
A. 81,0 gam
B. 40,5 gam
C. 45,0 gam
D. 54 gam
HD:
2Al+Cr2O3Al2O3+2Cr
54g
104g
xg
78g x=40,5(g) do H=90% x=45(g)
Cu 48 : Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu
trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu
trnh ln men l 75% th gi tr ca m l
A. 48
B. 60
C. 30
D. 58
HD:
C6H12O6 2CO2 2CaCO3
180g
200g
xg
40g
x=36(g) do H=75% x=48(g)
Cu 49 : Qu trnh no sau y khng to ra anehit axetic?
A. CH2=CH2 + H2O (to, xc tc HgSO4)
B. CH2=CH2 + O2 (to, xc tc)
o
C. CH3-CH2OH + CuO (t )
D. CH3-COOCH=CH2 + dung dch NaOH (to)
Cu 50 : Cho cn bng (trong bnh kn) sau :

CO2 (k) + H2 (k) H < 0

CO (k) + H 2 O (k)

Trong cc yu t : (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H2; (4) tng
p sut chung ca h; (5) dng cht xc tc.
Dy gm cc yu t u lm thay i cn bng ca h l :
A. (1), (4), (5)
B. (1), (2), (4)
C. (1), (2), (3)
D. (2), (3), (4)
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51 : Cho tng cht H 2 N CH 2 COOH, CH3 COOH, CH3 COOCH3 ln lt tc dng vi
dung dch NaOH (t0). S phn ng xy ra l
A. 3
B. 5
C. 6
D. 4
Cu 52 : Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO 3 2M, thu c m
gam kt ta. Gi tr ca m l
A. 34,44
B. 47,4
C. 12,96
D. 30,18
HD:
S mol Fe2+=0,12(mol) s mol Ag+=0,4(mol) s mol Cl-=0,24(mol)
Ag++Cl-=AgCl
Fe2++Ag+=Fe3++Ag
0,24 0,24 0,24
0,12 0,16
0,12
m=143,5.0,24+108.0,12=47,4(g)
Cu 53 : Cho cc cn bng sau :

2HI (k)
(1) H 2 (k) + I2 (k)

1
1

HI (k)
(2) H 2 (k) + I2 (k)

2
2

1 H 2 (k) + 1 I2 (k)
(3) HI (k)

2
2

H 2 (k) + I2 (k)
(4) 2HI (k)

A.
B.
C.
D.

2HI (k)
(5) H 2 (k) + I2 (r)

nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn bng

A. (5)
B. (2)
C. (3)
D. (4)
Cu 54: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi
Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to
ca X v Y ln lt l
A. C2H5COOH v CH3CH(OH)CHO.
B. C2H5COOH v HCOOC2H5.
C. HCOOC2H5v HOCH2CH2CHO.
D. HCOOC2H5 v HOCH2COCH3.
Cu 55: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C 3H9O2N tc dng
va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam
mui khan. Cng thc cu to thu gn ca X l
A. CH3CH2COONH4.
B. CH3COONH3CH3.
C. HCOONH2(CH3)2.
D. HCOONH3CH2CH3.
HD: X l este c dng RCOOR s mol=0,02(mol)
RCOOR+NaOH RCOONa+ROH
0,02
0,02
suy ra R+67=1,64:0,02=82 R=15 (CH3) R=32(NH3CH3)
CH3COONH3CH3
Cu 56: Dy gm cc cht u tc dng vi ancol etylic l:
NaOH, K, MgO, HCOOH (xc tc).
Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O.
Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH.
HBr (to), Na, CuO (to), CH3COOH (xc tc).
Cu 57: Hiro ha hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau
trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1
gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln
lt l
A. HCHO v 32,44%
B. HCHO v 50,56%
C. CH3CHO v 67,16%
D. CH3CHO v 49,44%.
HD: mH2=1(g) nH2=0,5(mol)
nCO2=0,7(mol) n =0,7:0,5=1,4 Hai andehit l HCHO a mol v CH3CHO bmol
a+b=0,5
a=0,3

a+2b=0,7
b=0,2
%mHCHO=(30.0,3.100): (30.0,3+44.0,2)=50,56%
Cu 58: Th t mt s cp oxi ha kh trong dy in ha nh sau: Mg2+/Mg; Fe2+/Fe; Cu2+/Cu;
Fe3+/Fe2+; Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l:
A. Mg, Fe, Cu.
B. Mg,Cu, Cu2+.
C. Fe, Cu, Ag+
. D. Mg, Fe2+, Ag.
Cu 59: Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3
CH =CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l
A. 1.
B. 3.
C. 4.
D. 2.
Cu 60: Nung nng 16,8 gam hn hp Au, Ag, Cu, Fe, Zn vi mt lng d kh CO2, n khi cc
phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn
ng vi cht rn X l
A. 600 ml.
B. 200 ml.
C. 800 ml.
D. 400 ml.
HD:
Theo bo ton khi lng
mO=23,2-16,8=6,4(g) nO=6,4:16=0,4(mol)
nHCl=2nO trong oxit=0,8(mol)
VHCl=0,8:2=0,4(lt)=400(ml)
GV gii Bi Th Lin lien.buithi@yahoo.com