ANKEN 1. Vit CTCT v gi tn cc ng phn mch h ng vi cng thc C 4H8 ; C5H10 ; C6H12 .

Cho bit cng thc no c ng phn cis trans. 2. Vit y cc phng trnh phn ng theo s sau a) ru etylic
H2SO4c

+H2/Ni,to

+HCl

+Cl2(as)

b) etilen ru etylic etilen 1,2-ibrometan etan etylenclorua d) C2H5COONa C2H6 C2H4 C2H4(OH)2 C2H5Cl f) C3H8 C3H6 C3H7Cl C3H6(OH)2 (C3H6)n polietilen cacbonic

c) C2H5OH C2H4 C2H5OH C2H5Cl C2H4Br2 (-CH2 CH2- )n e) C2H5OH C2H4 C2H4Cl2 C2H6 C2H5Cl

3. Hon thnh cc phng trnh phn ng sau ( ghi r iu kin phn ng): a) C2H5COONa + NaOH A + Na2CO3 c) B + KOH C + KCl + H2O e) 3-metylpent-2-en + H2O g) CH2 = CH2 + HBr c) CH3 CH = CH2 + HI 4. a) Vit phng trnh phn ng iu ch cc hp cht sau y t nhng anken thch hp CH3CHBr CHBrCH3 ; CH3CHBr CBr(CH3)2 ; CH3CHBr CH(CH3)2 b) Vit cng thc cu to v gi tn cc anken iu ch c khi tch H2O t cc ancol sau: CH3 CHOH CH3 ; CH3 CH2 CH2OH ; CH3 CH2 CH2 CH2OH ; (CH3)3C OH c) Vit phn ng trng hp ca cc cht sau: 5. Bng phng php ha hc nhn bit: a) metan v etilen ; b) hex-2-en v xiclohexan a) C d/N2 = 2. c) H2, C2H6, C2H4 b) C 10H. 6. Vit ng phn v gi tn anken: CH2 = CH2 ; CH2 = C(CH3)2 ; CH2 = CHCl d) Vit phng trnh tc dng vi thuc tm v trng hp ca cc cht sau:etilen, propilen, isobuten. b) A + Cl2 xt,to d) C ? f) Propen B + HCl polyme

h) CH2 = CH2 + ? CH3 CH2OH

7. a) t chy 5,6 lt kh hirocacbon to thnh 16,8 lt CO2 v 13,5g H2O. Cc th tch kh ktc. Tm CTPT v vit CTCT ca hirocacbon. b) t 0,56 lt anken (0oC, 2 atm) sinh ra 3,6g H2O. CTPT v CTCT? c)Cho 5,6 lt anken (kc) i qua bnh dd Brm thy khi lng bnh tng 0,7g. CTPT ca anken? d) hiro ha 0,7g mt anken cn dng 246,4 ml H2 (27,3oC v 1 atm). nh CTPT ca anken. e) Cho 7g mt anken tc dng hon ton vi dd KMnO4 long thu c 10,4g cht hu c.CTPT? f) Cho 3,5g anken A phn ng vi 50g dd Br2 40% va . CTPT?

8. Cho 3 lt hh etan v etilen (kc) vo dd Brom thu c 4,7g 1,2 ibrometan. Tnh % khi lng mi cht trong hh. 9. t chy 5,8g hh etilen v etan thu c 17,6g kh CO2. Tnh khi lng mi cht trong hh u. 10. Mt hh A gm 2 anken lin tip nhau trong dy ng ng. Cho 1,792 lt hh A (0oC ; 2,5 atm) qua bnh dd Brm d ngi ta thy khi lng bnh tng thm 7g. a) Tm CTPT cc anken. b) %V ca mi cht trong hh A? c) Nu t chy cng th tch trn ca hh A v cho tt c sn phm vo 500 ml dd NaOH 1,8M th s thu c nhng mui g? Khi lng bao nhiu? 11. Cho 6,72 lt hh kh gm 2 anken li qua nc brom d thy khi lng bnh tng 16,8g. Xc nh CTPT mi anken bit s nguyn t C trong mi anken khng qu 5. 12. Cho 11,04g hh gm etan v propilen lm mt mu 136g dd brom 20%. a) %V mi kh trong hh? b) t chy cng lng hh Y ni trn, dn sn phm chy vo nc vi trong c d thu c bao nhiu gam kt ta? 13. Cho 16,24g hh hai anken lin tip lm mt mu 256g dd brom 20%. a) Xc nh CTPT mi anken. b) % khi lng mi anken trong hh? 14. Cho 11,2 lt hh gm propan v 1 anken qua bnh dd brom d thy khi lng bnh tng 11,2g. Mt khc nu t chy hon ton 11,2 lt hh trn th thu c 38,08 lt CO2 (kc). a) Tm CTPT ca anken. b) Tnh % khi lng hh ban u. 15. Khi t mt hirocacbon X lun thu c th tch CO2 bng th tch hi nc. Mt khc nu cho 200 ml X (o 0oC ; 851,2 mmHg) i qua bnh cha 80g dd Brom. Sau phn ng khi lng bnh nng 80,56g. Xc nh CTPT, CTCT v gi tn X. 16. t chy hon ton 0,0672 lt anken X (273oC v 1 atm). Ton b CO2 thu c dn vo dd KOH c 0,3g mui axit v 0,207g mui trung ha. Xc nh CTPT ca X? 17. Cho 4,48 lt hh kh A gm etan, propan, propilen i qua bnh cha dd Br2 thy bnh nng thm 6,3g. t chy kh cn li thu c 5,72g CO2. Tnh thnh phn % th tch mi kh trong hh u. 18. t chy hon ton 0,01 mol mt anken X .Hp th ton b lng CO2 to thnh vo bnh cha 30 ml dd Ca(OH)2 1M thu c 2 g kt ta. a) Xc nh CTPT c th c ca X. b) Xc nh CTCT ng ca X bit rng X tc dng vi HCl to ra ti a 2 sn phm. 19. t chy hon ton 10 lt hh X gm 2 anken ng ng k tip thu c 26 lt CO 2(ktc). Cc th tch kh o cng iu kin nhit v p sut.

a) Xc nh CTCT v gi tn hai anken. b) Tnh % khi lng mi anken trong hh. c) Hirat ha hon ton hh X thu c ti a bao nhiu ancol? 20. HH kh A gm H2 v hai olefin ng ng k tip. Cho 19,04 lt hh A (ktc) i qua bt Ni nung nng thu c hh kh B. Cho mt t hh kh B qua dd Brom thi dd Brom b nht mu. Mt khc t chy hh kh B th thu c 43,56g CO2 v 20,43g H2O. a) Vit CTCT v gi tn cc olefin. b) Tnh %V cc kh trong A. c) Tm t khi hi ca B so vi khng kh. 21. HH X gm ankan A v anken B (u th kh trong k thng) - t ht 0,1 mol X ( a mol A v b mol B) c lng CO2 ln hn lng H2O l 7,6g. - t ht 0,1 mol X ( b mol A v a mol B) c lng CO2 ln hn lng H2O l 6,2g. Tm CTPT ca A, B. Bit s nguyn t C trong B ln hn trong A. 22. X l hh 2 anken c s C lin tip, bit dX/H2 = 24,5. a) Tm CTPT mi anken v tnh % khi lng mi anken. b) Xc nh CTCT hai anken trn trong cc trng hp: - X cng H2O cho hh ancol trong c ancol bc III. - X cng HCl t l 1:1 cho 3 sn phm. 23. X l hh gm 1 ankan v 1 anken u th kh iu kin thng. t chy hon ton 12,22 lt kh X ( 136,5oC ; 1,1 atm) bng O2 va ri cho sn phm chy qua bnh ng nc vi trong d thy khi lng bnh tng 61,2g ng thi xut hin 90g kt ta. Tm CTPT cc hirocacbon. 24. Mt hh gm hai hirocacbon mch h. Cho 1680 ml hh trn i chm qua nc Brom d. Sau khi phn ng hon ton cn 1120 ml kh thot ra v lng Brom tham gia phn ng l 4g. Mt khc nu t chy hon ton 1680 ml hh trn ri cho ton b sn phm chy hp th vo nc vi trong d thu c 12,5g kt ta. Xc nh cng thc hai hirocacbon. Cc th tch kh ktc. 25. Mt hh gm hai hirocacbon mch h. Cho 1,568 lt hh trn i chm qua nc Brom d. Sau khi phn ng hon ton cn 448 cm3 v lng Brom tham gia phn ng l 8g. Mt khc nu t chy hon ton 1,568 lt hh trn ri cho ton b sn phm chy hp th vo nc vi trong thu c 15g kt ta, lc b kt ta ri un nc lc thu thm 2g kt ta na.(cc th tch o ktc) a) Xc nh cng thc hai hirocacbon. b) Tnh t khi hi ca X so vi H2. 26. Cho m gam anken A i qua bnh cha 120 ml dd brom 1M. Sau khi phn ng hon ton thy nng brom cn li trong bnh l 0,5M ng thi thy khi lng bnh tng 2,52g. a) Xc nh CTPT. CTCT v gi tn A.

b) Cho 8,4g A tc dng vi HCl. Sau khi phn ng kt thc thu c hai sn phm X v Y vi t l s mol nX: nY = 3:7. Xc nh CTCT v tnh khi lng ca X v Y. c) t chy hon ton a gam cht A. Hp th ton b sn phm chy vo bnh ng nc vi trong d thy khi lng bnh tng 5,58g v thu c b gam kt ta. Tm a v b? 27. Cho 3,36 lt (kc) mt ankan v 1 anken c cng s nguyn t C qua dd brom d th c 8 gam brom tham gia phn ng. Khi lng ca 3,36 lt hh X l 6,5 gam. Xc nh CTPT ca cc hirocacbon. 28. t chy hon ton 448ml hh kh gm ankan A v anken B c cng s nguyn t C ktc ri dn ton b sn phm vo nc vi trong d thu c 4 gam kt ta. Xc nh CTPT ca A v B. 29. Cho 6,72 lt (kc) mt ankan v 1 anken qua dd brom d th c 16 gam brom tham gia phn ng. Khi lng ca 6,72 lt hh X l 13 gam. Xc nh CTPT ca cc hirocacbon. ANKAIEN 27. Vit cc ng phn ankaien v gi tn theo danh php quc t ng vi cc CTPT sau: C4H6 ; C5H10. Nhng ankaien no l lin hp? 28. Vit phng trnh phn ng ca buta-1,3-ien v isopren vi: a) dd Br2 ( t l mol 1:1 v 1:2). a) cao su buna t ancol etylic. c) cao su isopren t isopentan. 30. Xc nh CTCT v vit phng trnh phn ng minh ha cc phn ng sau: A + 2H2 B C D E B C + D polipropilen E + H2 nha PE b) dd HCl ( t l 1:1). b) cao su cloropren t vi. c) trng hp. 29. Vit phng trnh iu ch (cc cht v c cn thit c ):

Bit A l mt ankaien lin hp, mch nhnh. 31. Xc nh CTCT c th c ca cc cht sau bit: a) T khi hi ca ankaien lin hp A i vi metan l 4,25. b) Cho mt ankaien B hp th hon ton vo dd brom d thy khi lng bnh tng ln 4g v khi lng brom tham gia phn ng l 32g. 32. Cho 5g hh gm but-1-en v 1 ankaien A chia thnh hai phn bng nhau: - P1: hp th hon ton bng 160g dd Br2 5% to thnh hp cht no. - P2: t chy hon ton, th tch O2 phn ng l 5,936 lt (kc). a) Xc nh CTPT v CTCT ca A bit A c hai nhm metyl gn vi mch C chnh. b) Tnh thnh phn % khi lng mi cht trong hh.

33. Mt hh X gm 1 anken v 1 ankaien c cng s nguyn t C: - t chy hon ton 1,0752 lt hh X (kc) th thu c 8,448g CO2. Xc nh CTPT ca cc hirocacbon. - Nu khi lng Brom cn dng phn ng vi hh X trn l 13,44g to hp cht no hon ton. Tnh t khi hi ca hh X so vi H2. ANKIN 34. Vit CTCT v gi tn cc ng phn ankin c CTPT: C4H6, C5H8, C6H10. Trong cc ng phn trn, ng phn no c th tham gia phn ng vi dung dch AgNO3 trong NH3? 35. Hon tt PTP theo t l mol 1:1 a) pent-1-in + Br2 a) H2 ( Pd/PbCO3, to) a) etan, eten, etin c) CH4, C2H4, C2H2, HCl e) n-butan, but-1-in, buta-1,3-dien, CO2 38. Thc hin chui chuyn ha sau, ghi r iu kin (nu c) a) CH3COONa CH4 C2H2 C4H4 C4H6 cao su buna C2Ag2 C2H2 C2H3Cl PVC b) CaCO3 CaO CaC2 C2H2 C6H6 HOOC-COOH c) Al4C3 CH4 C2H2 C2H4 C2H6 C2H5Cl C2H4 C2H5OH d) propan metan axetilen vinyl axetilen butan propilen PP 39. Xc nh cc CTCT ca A, B,C,D,E,F,J,H v hon thnh cc phn ng sau: C+A B
Ni, to

b) pent-2-in + HCl b) dd brom (d)

c) 3-metylbut-1-in + Cl2 c) dd AgNO3 trong NH3

36. Vit phn ng xy ra gia propin vi cc cht sau: 37. Bng phng php ha hc, phn bit cc cht sau: b) butan, but-1-in, but-2-in d) but-1-in, but-2-in, isobutan

B C + A D + E

1500oC lm lnh nhanh

C + AgNO3 + NH3 D + F A + C H 2C I + A J I J polime C + G H polime

40. Vit cc phng trnh iu ch cc cht sau ( ha cht ph c )

a) nhm cacbua PE, PP, PVC c) vi benzen thnh 20g kt ta trng.

b) natri axetat cao su buna, cao su isopren d) propan etan, n-butan

41. t chy 2,7g mt ankin A, sau cho sn phm vo dung dch nc vi trong d thy to a) Xc nh CTPT v gi tn cc ng phn ca A. b) Cho A tc dng vi HCl t l mol 1:1 ta ch thu c mt sn phm . Cho bit CTCT ng ca A. 42. t chy hon ton 0,02 mol mt hidrocacbon A sinh ra 2,64g CO2. Xc nh CTCT ca A bit A tc dng AgNO3/NH3 to kt ta vng nht. 43. t chy hon ton mt hn hp gm 2 ankin k tip trong dy ng ng thu c 4,4g CO2 v 1,26g H2O. Tm CTPT v tnh %V cc cht trong hn hp. 44. t chy hon ton mt hidrocacbon A thuc dy ng ng ca axetilen sinh ra 2,64g CO2. Ly cng lng A tc dng vi AgNO3/NH3 tch c 2,94 g kt ta. Xc nh CTPT v CTCT. 45. Dn 4,8g mt hidrocacbon X l ng ng ca axetilen qua dd AgNO3/NH3 n khi phn ng xy ra hon ton th c 17,64g kt ta. Tm CTPT, CTCT ca X v tnh s mol AgNO3 tham gia phn ng. 46. Hn hp C2H4 v C2H2 qua dd AgNO3/NH3 d thu c 2,4g kt ta. Nu cho hn hp trn qua dd Brom 1M to sn phm no hon ton th cn 25ml dd Brom. Tnh thnh phn %V hn hp u. 47. Hn hp X gm 1 anken A v 1 ankin B c cng s nguyn t H. t chy hon ton hn hp X thu c 11,2 lt CO2(kc) v 8,1g H2O. nh CTPT A, B bit t khi hi ca hn hp X so vi H2 l 23. 48. C mt hn hp gm etilen v axetilen. Chia hn hp lm 2 phn bng nhau: - P1: Cho tc dng vi dd Br2 thy khi lng bnh tng 0,68g. - P2: em t chy hon ton th cn 1,568 lt kh oxi (ktc). Xc nh %V cc kh trong hn hp X. 49. Mt hn hp kh Y gm metan, etilen, axetilen vi th tch l 1,12 lt (ktc) - Cho Y qua dung dch AgNO3/NH3 c d, th tch kh gim 0,56 lt. - t chy hon ton 1,12 lt hn hp, dn ton b kh CO2 thu c qua bnh ng nc vi trong c d thu c 8,125g kt ta. Xc nh thnh phn %V cc kh trong hn hp. 50. Mt hh kh A, B k tip nhau trong dy ng ng ca axetilen. Ly 14,7g hh chia lm hai phn bng nhau: - P1: tc dng ht vi 48g Brom. - P2: qua dd AgNO3/NH3 thy c kt ta. Ly kt ta cho vo dd HCl d thu c mt kt ta khc nng 7,175g. Xc nh CTCT ng v gi tn A, B. 51. a) Mt ankin A c dA/kk = 0,9. Tm CTPT ca A.

b) Hh kh gm A trn v 1 anken B cho qua bnh dung dch brom th tc dng va vi 280g dd brom 8% v khi lng bnh tng thm 3,56g. Nu em hh X t chy th cn 8,288 lt O2 (ktc). Tm CTPT anken B v tnh khi lng mi cht trong hh. 52. Cho hh X gm etan, eten, etin qua dd AgNO3/NH3 d th c 36g kt ta vng nht. Nu cho cng lng hh X trn tc dng vi 11,2 lt H2 ( Ni, to) th c 8,96 lt kh duy nht. Cc kh o ktc. Tnh %V mi kh trong hh X. 53. Mt hh X gm H2, mt ankan v mt ankin cng s nguyn t C. un nng 100 cm3 hh X vi Ni th c 70 cm3 mt hirocacbon duy nht. Nu t chy 100 cm3 hh X th thu c 210 cm3 CO2. Cc kh o cng iu kin.Tm CTPT mi hirocacbon v thnh phn %V mi kh trong hh. 54. t chy 60 cm3 hh 2 ankin lin tip nhau trong dy ng ng thu c 220 cm3 CO2 ( cng iu kin) a) Tm CTPT ca X, Y v %V ca chng. b) Ly 1,68 lt (kc) hh trn cho li qua dd AgNO3/NH3 th c 3,675g kt ta. Xc nh CTCT ca X v Y. 55. Cho 17,92 lt hh X gm H2 v axetilen trong bnh c sn t bt Ni. t nng bnh mt thi gian thu c hh kh Y. - Cho lng kh Y qua bnh ng dd AgNO3/NH3 d th c 1,2g kt ta vng nht. - Cho lng kh Y qua dd brom d th khi lng bnh brom tng thm 0,41g. Tnh th tch mi kh trong hh Y bit dX/H2 = 4. Cc th tch kh o ktc. 56. Hh X gm 1 anken A v 1 ankin B c cng s nguyn t C trong phn t. Bit t khi ca X so vi H2 bng 13,375. a) Xc nh CTCT ca A v B. b) Trn 4,28g hh X vi 0,28g H2 thu c hh Y. Nung Y vi Ni xc tc mt thi gian thu c hh Z. Dn hh Z qua bnh ng dd AgNO3/NH3 d thu c m gam kt ta vng nht v 3,584 lt hh kh T (kc) thot ra khi bnh. Bit t khi hi ca T so vi H2 bng 11. Tnh m. 57. Cho 4,48 lt hh X gm 1 ankin A v 1 hirocacbon B tc dng vi dd AgNO3/NH3 d thu c 14,7g kt ta mu vng nht. Kh cn li c th tch 2,24 lt c em t chy hon ton thu c 12g hh CO2 v hi nc c t khi hi so vi khng kh bng 1,07. Tm CTPT v CTCT ca A, B. Th tch cc kh o ktc. 58. Cho m gam hh kh X gm etilen v mt ng ng ca etilen A qua dd AgNO3/NH3 d. Sau phn ng thy khi lng bnh nng thm 2 gam v thu c 7,35g kt ta mu vng nht. Kh khng tham gia phn ng dn qua dd brom thy c 8 gam brom tham gia phn ng. Tnh m v xc nh CTCT ca A. 59. HH A gm 2 ankin u mch lin tip ( khng c axetilen) . Cho 3,22g hh A tc dng vi dd AgNO3/NH3 d thu c 10,71g cht rn mu vng.

a) Xc nh CTPT, CTCT v gi tn A. b) Tnh khi lng mi cht trong hh u. 60. t 3,4g mt hirocacbon A to ra 11g CO2. Mt khc khi cho 3,4g A tc dng vi lng d dd AgNO3/NH3 thy to thnh a gam kt ta. a) Xc nh CTPT ca A. b) Vit CTCT ca A bit khi A tc dng vi H2 d c xc tc Ni to thnh isopentan.