K THI TUYN SINH CAO NG NM 2011

Mn thi : HO HC; khi A,B - M : 812

Cho bit nguyn t khi (theo vC) ca cc nguyn t
H = 1;Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr =
52, Mn = 55; Fe = 56; Cu = 64; Zn = 65; Rb = 85,5; Ag=108; I = 127; Cs = 133; Ba = 137.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic. Trong cc cht trn,
s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH)
2
iu kin thng l
A. 3 B. 2 C. 4 D. 5
Gi : glucoz , frutoz, axit fomic. Andehit axetic khng c v n cn c nhit .
Cu 2: Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H
2

(ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l:
A. 7,0 B. 14,0 C. 10,5 D.21,0
Gi : nH
2
=0.1 mol.
A mol phenol, b mol etanol ta c h:]
0.5( o + b) = 0.1
o = 0.1
]
o = 0.1
b = 0.1
m= (0.1)x(94+46)=14g
Cu 3: Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to
thnh ancol etylic l:
A. 60% B. 40% C. 80% D. 54%
Gi : C
6
H
12
O
6
2CO
2
+ 2C
2
H
5
OH
180 92 H=
92.180
92.300
= 60%
Cu 4: Ho tan hon ton hn hp X gm 0,2 mol Fe v 0,2 mol Fe
2
O
3
vo dung dch axit H
2
SO
4
long (d), thu
c 2,24 lt kh (ktc) v dung dch Y. Cho lng d dung dch NaOH vo dung dch Y, sau khi phn ng xy ra
hon ton thu c m gam kt ta. Gi tr nh nht ca m l:
A. 54,0 B. 59,1 C. 60,8 D. 57,4
Gi : nH
2
=0.1 mol < 0.2 mol cn d Fe do oxit s phn ng trc.
Fe + 2Fe
3+
3Fe
2+

0.1 0.2 0.3 ]
0.2 mol Fc
3+
0.4 mol Fc
2+
m= 0.2(107)+0.4(90)=57.4
Cu 5: Cho cc polime : (1) polietilen , (2) poli (metyl metacrylat), (3) polibutaien, (4) polistiren, (5) poli(vinyl
axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch
kim l:
A. (2),(3),(6) B. (2),(5),(6) C. (1),(4),(5) D. (1),(2),(5)
Gi : polime c th b thu phn trong dung dch axit v dung dch kim phi l polime trng ngng (2),(5),(6)
Cu 6: Pht biu no sau y khng ng?
A. Mui AgI khng tan trong nc, mui AgF tan trong nc
B. Flo c tnh oxi ho mnh hn clo.
C. Trong cc hp cht, ngoi s oxi ho -1, flo v clo cn c s oxi ho +1, +3, +5, +7
D. Dung dch HF ho tan c SiO
2

Cu 7: t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c 30,2 gam hn hp oxit. Th
tch kh oxi (ktc) tham gia phn ng l:
A. 17,92 lt B. 4,48 lt C. 11,20 lt D. 8,96 lt
Gi : V=
30.217.4
32
. 22,4 = 8.96
Cu 8: Cho cc cht : KBr, S, SiO
2
, P, Na
3
PO
4
, FeO, Cu v Fe
2
O
3
. Trong cc cht trn, s cht c th oxi ho bi
dung dch axit H
2
SO
4
c nng l:
A. 4 B. 5 C. 7 D. 6
Gi : FeO, C, P, S, KBr (to Br
2
)
Cu 9: Mc phn cc ca lin kt ho hc trong cc phn t c sp xp theo th t gim dn t tri sang
phi l:
A. HBr, HI, HCl B. HI, HBr, HCl
C. HCl , HBr, HI D. HI, HCl , HBr
Gi : V m im gim dn t Cl > Br > I lc ht gim dn trong lin kt s phn cc gim dnC
Cu 10: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M
x
< M
Y
) cn va 300
ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit hu c v m
gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO
2
(ktc) v 5,4 gam H
2
O. Cng thc ca
Y l :
A. CH
3
COOC
2
H
5
B. CH
3
COOCH
3

C. CH
2
=CHCOOCH
3
D. C
2
H
5
COOC
2
H
5
Gi : nNaOH= 0.3 mol= n mui
nCO
2
=0.2 mol v nH
2
O= 0.3 mol ru no v lp t l ta c :
nC
nH
=
0.2
0.3.2
=
2
6
ancol etylic
V thu 1 mui duy nht phi cng gc acid M mui=
24.6
0.3
= 82 CH
3
COONa A
Cu 11: Ho tan hon ton 6,645 gam hn hp mui clorua ca hai kim loi kim thuc hai chu k k tip nhau
vo nc c dung dch X. Cho ton b dung dch X tc dng hon ton vi dung dch AgNO
3
(d), thu c
18,655 gam kt ta. Hai kim loi kim trn l:
A. Na v K B. Rb v Cs C. Li v Na D. K v Rb
nCl= nAgCl=
18.655
143.5
= 0.13 ]
nKl = 0.13
mKl = 6.645 4.615 = 2.03
Mtb=
2.03
0.13
=15.61 Li v Na

Cu 12: nhn ra ion NO
3
-
trong dung dch Ba(NO
3
)
2
, ngi ta un nng nh dung dch vi:
A. dung dch H
2
SO
4
long B. kim loi Cu v dung dch Na
2
SO
4

C. kim loi Cu v dung dch H
2
SO
4
long D. kim loi Cu

Gi : to kh NO bay ra ha nu ngoi khng kh.
Cu 13: Cht no sau y c ng phn hnh hc?
A. CH
2
=CH-CH=CH
2
B. CH
3
-CH=CH-CH=CH
2

C. CH
3
-CH=C(CH
3
)
2
D. CH
2
=CH-CH
2
-CH
3

Cu 14: Amino axit X c dng H
2
NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch
HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l:
A. phenylalanin B. alanin C. valin D.glyxin
C mX= 11.15 0.1(36.5)=7.5 M=75 R=14 Glyxin
Cu 15: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt
bt st) l
A. o-bromtoluen v p-bromtoluen B. benzyl bromua
C. p-bromtoluen v m-bromtoluen D. o-bromtoluen v m-bromtoluen
Gi : c xc tc bt Fe th vo nhn do toluen c gc CH3- cho in tch th vo ortho v para
Cu 16: Cho cn bng ho hc : N
2
(k) +3H
2
(k) 2NH
3
(k) H 0
Cn bng trn chuyn dch theo chiu thun khi:
A. tng p sut ca h phn ng B. tng nhit ca h phn ng
C. gim p sut ca h phn ng D. thm cht xc tc vo h phn ng
Gi : CB theo chiu thun gim s mol kh tng p sut
Cu 17: Dy gm cc kim loi u c cu to mang tinh th lp phng tm khi l:
A. Na, K, Ca, Ba B. Li, Na, K, Rb C. Li, Na, K , Mg D. Na, K, Ca, Be
Cu 18: t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu c 6,72 lt kh
CO
2
(ktc) v 9,90 gam H
2
O. Nu un nng cng lng hn hp X nh trn vi H
2
SO
4
c nhit thch hp
chuyn ht thnh ete th tng khi lng ete thu c l:
A. 6,45 gam B. 5,46 gam C. 7,40 gam D. 4,20 gam

Ta c nH
2
O=0.55, nCO
2
=0.3 ru no n ru = 0.25 nCtb= 0.3 : 0.25 = 1.2 Mtb= 34.8
mete = 0.25(34.8) (0.5x0.25 x18)= 6.45
Cu 19: S ancol ng phn cu to ca nhau c cng thc phn t C
5
H
12
O, tc dng vi CuO un nng sinh ra
xenton l:
A. 4 B. 2 C. 5 D. 3
Gi thit to xeton Ru bc II 3 ctct C-C(OH)-C-C-C, C-C-C(OH)-C-C. C-C(C)-C(OH)-C
Cu 20: Nung hn hp gm 10,8 gam Al v 16,0 gam Fe
2
O
3
(trong iu kin khng c khng kh), sau khi phn
ng xy ra hon ton thu c cht rn Y. Khi lng kim loi trong Y l:
A. 5,6 gam B. 22,4 gam C. 11,2 gam D.16,6 gam
nAl =0.4, n Fe
2
O
3
= 0.1 2Al + Fe
2
O
3
2Fe + 2Al
2
O
3

0.2 0.1 0.2
m = (0.2x27) +( 0.2x56) = 16.6
Cu 21: Cng thc ca triolein l:
A. (CH
3
[CH
2
]
16
COO)
3
C
3
H
5
B. (CH
3
[CH
2
]
7
CH=CH[CH
2
]
5
COO)
3
C
3
H
5
C. (CH
3
[CH
2
]
7
CH=CH[CH
2
]
7
COO)
3
C
3
H
5
D. (CH
3
[CH
2
]
14
COO)
3
C
3
H
5

Cu 22: Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng
thc ca hp cht to thnh 2 nguyn t trn c dng l:
A. X
3
Y
2
B. X
2
Y
3
C. X
5
Y
2
D. X
2
Y
5
Cu 23: Pht biu no sau y l ng?
A. Amino axit l hp cht c tnh lng tnh.
B. Trong mi trng kim, ipetit mch h tc dng c vi Cu(OH)
2
cho hp cht mu tm.
C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit.
D. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit
Cu 24: ho tan hon ton 6,4 gam hn hp gm kim loi R (ch c ho tr II) v oxit ca n cn va 400
ml dung dch HCl 1M. Kim loi R l:
A. Ba B. Ca C. Be D. Mg
Gi : nhh= 0.5 nH
+
= 0.2 Mtb= 32 R<32<R+16 16< R< 32 Mg
Cu 25: C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha mt trong cc dung dch
AgNO
3
, ZnCl
2
, HI, Na
2
CO
3
. Bit rng:
- Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh.
- Dung dch trong ng nghim 2 v 4 khng phn ng c vi nhau.
Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l:
A. AgNO
3
, Na
2
CO
3
, HI, ZnCl
2
B. ZnCl
2,
HI, Na
2
CO
3
, AgNO
3
C. ZnCl
2
, Na
2
CO
3
, HI, AgNO
3
D. AgNO
3
, HI, Na
2
CO
3
, ZnCl
2

Cu 26: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (M
X
<M
Y
<82). C X v Y u c kh nng
tham gia phn ng trng bc v u phn ng c vi dung dch KHCO
3
sinh ra kh CO
2
. T khi hi ca Y so vi
X c gi tr l:
A. 1,47 B. 1,61 C. 1,57 D. 1,91
Gi : C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO
3
sinh
ra kh CO
2
HCOOH v HOOC-CHO d= 74: 46 = 1.608
Cu 27: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng
hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l:
A. CH
3
COOC
2
H
5
B. C
2
H
5
COOCH
3

C. CH
2
=CHCOOCH
3
D. CH
3
COOCH=CH
2
nNaOH= 0.1 mol Mancol = 32 CH
3
OH, Macid= (9.6 : 0.1) -23 +1 = 74 C
2
H
5
COOH
Cu 28: Cho s phn ng:

o o o
X(xt ,t ) Z( xt ,t ) M(xt,t )
4 3
CH Y T CH COOH


(X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng).
Cht T trong s trn l:
A. C
2
H
5
OH B. CH
3
COONa C. CH
3
CHO D. CH
3
OH
X l O
2
, Y l HCHO, Z l H
2
, T l CH
3
OH, M l CO
Cu 29: x phng ho hon ton 52,8 gam hn hp hai este no, n chc , mch h l ng phn ca nhau cn
va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai
este l
A. CH
3
COOC
2
H
5
v HCOOC
3
H
7
B. C
2
H
5
COOC
2
H
5
v C
3
H
7
COOCH
3

C. HCOOC
4
H
9
v CH
3
COOC
3
H
7
D. C
2
H
5
COOCH
3
v CH
3
COOC
2
H
5
neste= n KOH = 0.6 Mtb= 88 C
4
H
8
O
2
, c hai este ny u khng tham gia phn ng trng bc D
Cu 30: Hp cht hu c X c cng thc phn t l C
4
H
8
O
3
. X c kh nng tham gia phn ng vi Na, vi dung
dch NaOH v phn ng trng bc. Sn phm thu phn ca X trong mi trng kim c kh nng ho tan Cu(OH)
2

to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l:
A. CH
3
CH(OH)CH(OH)CHO B. HCOOCH
2
CH(OH)CH
3

C. CH
3
COOCH
2
CH
2
OH. D. HCOOCH
2
CH
2
CH
2
OH
Cu 31: Cho 3,16 gam KMnO
4
tc dng vi dung dch HCl (d), sau khi phn ng xy ra hon ton th s mol
HCl b oxi ho l
A. 0,02 B. 0,16 C. 0,10 D. 0,05
nHCl =
3.16
158
. 5 = 0.1
Cu 32: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn
A. km ng vai tr catot v b oxi ho B. st ng vai tr anot v b oxi ho
C. km ng vai tr anot v b oxi ho D. st ng vai tr catot v ion H
+
b oxi ho
Cu 33: Dy gm cc oxit u b Al kh nhit cao l:
A. FeO, CuO, Cr
2
O
3
B. PbO, K
2
O, SnO
C. FeO, MgO, CuO D. Fe
3
O
4
, SnO, BaO
Cu 34: Tin hnh cc th nghim sau
(1) Sc kh H
2
S vo dung dch FeSO
4

(2) Sc kh H
2
S vo dung dch CuSO
4

(3) Sc kh CO
2
(d) vo dung dch Na
2
SiO
3

(4) Sc kh CO
2
(d) vo dung dch Ca(OH)
2

(5) Nh t t dung dch NH
3
n d vo dung dch Al
2
(SO
4
)
3

(6) Nh t t dung dch Ba(OH)
2
n d vo dung dch Al
2
(SO
4
)
3
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l:
A. 3 B. 6 C. 4 D. 5
Gi : (2), (3), (5), (6)
Cu 35: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy
hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)
2
th vn thu c kt ta. Thu phn X
bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi
lng ca oxi trong X l:
A. 43,24% B. 53,33% C. 37,21% D. 36,36%
Gi : C
n
H
2n
O
2
, nCa = 0.22 nOH= 0.44, vn thu kt ta nC < 2. nCa nC= 0.44 s C < hay = 4, este thu
hn hp 2 cht hu c c s mol bng nhau s C chn 2C hay 4 C % O = 53.33% hay 36.36% m khng
c phn ng trng bc loi 2C 36.36%
Cu 36: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc dng vi dung dch HNO
3

c , ngui l:
A. Fe, Al, Cr B. Cu, Fe, Al C. Fe, Mg, Al D. Cu, Pb, Ag
Cu 37: in phn 500 ml dung dch CuSO
4
O,2M (in cc tr) cho n khi catot thu c 3,2 gam kim loi th
th tch kh (ktc) thu c anot l:
A. 3,36 lt B. 1,12 lt C. 0,56 lt D. 2,24 lt
Gi :I =
3.2
64
.
2
4
. 22.4 = 0.56 l = > C
Cu 38: Cho cc dung dch : C
6
H
5
NH
2
(amilin), CH
3
NH
2
, NaOH, C
2
H
5
OH v H
2
NCH
2
COOH. Trong cc dung
dch trn, s dung dch c th lm i mu phenolphtalein l
A. 3 B. 2 C. 4 D. 5
Gi CH
3
NH
2
, NaOH

Cu 39: Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH = 3,0 thu c dung dch Y c
pH = 11,0. Gi tr ca a l:
A. 0,12 B. 1,60 C. 1,78 D. 0,80
Gi : 0.01a= 0.001x8 + (a+8)0.001 a= 1.777l
Cu 40: Mt cc nc c cha cc ion : Na
+
(0,02 mol), Mg
2+
(0,02 mol), Ca
2+
(0,04 mol), Cl
-
(0,02 mol), HCO
3
-

(0,10 mol) v SO
4
2-
(0,01 mol) . un si cc nc trn cho n khi phn ng xy ra hon ton th nc cn li
trong cc
A. c tnh cng ton phn B. c tnh cng vnh cu
C. l nc mm D. c tnh cng tm thi
V nung th 2HCO
3
-
CO
3
2-
+ H
2
O + CO
2
n CO
3
2-
= 0.05 Cn li dd sau p l Mg, Ca, Na, SO4-
II.PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A.Theo chung trnh chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohecxan, xiclopropan v xiclopentan. Trong cc
cht trn, s cht phn ng uc vi dung dch brom l:
A. 4. B. 3. C. 5. D. 6.
Gi : axetilen, vinylaxetilen, stiren, xiclopropan
Cu 42: Hai cht no sau y u tc dng uc vi dung dch NaOH lang?
A. ClH
3
NCH
2
COOC
2
H
5
. v H
2
NCH
2
COOC
2
H
5
.

B. CH
3
NH
2
v H
2
NCH
2
COOH.

C. CH
3
NH
3
Cl v CH
3
NH
2
.

D. CH
3
NH
3
Cl v H
2
NCH
2
COONa.

Cu 43: Cho phn ng
6FeSO
4
+ K
2
Cr
2
O
7
+ 7H
2
SO
4
3Fe
2
(SO
4
)
3
+ Cr
2
(SO
4
)
3
+ K
2
SO
4
+7H
2
O
Trong phn ng trn, cht oxi ha v cht kh ln lt l
A. FeSO
4
v K
2
Cr
2
O
7
. B. K
2
Cr
2
O
7
v FeSO
4
.
C. H
2
SO
4
v FeSO
4
. D. K
2
Cr
2
O
7
v H
2
SO
4.

Cu 44: Dy gm cc ion u oxi ha c kim loi Fe l
A. Cr
2+
, Au
3+
, Fe
3+
. B. Fe
3+
, Cu
2+
, Ag
+
. C. Zn
2+
, Cu
2+
, Ag
+
. D. Cr
2+
, Cu
2+
, Ag
+
.
Cu 45: Hn hp G gm hai anehit X v Y, trong M
x
< M
y
< 1,6 M
x
. t chy hn hp G thu c CO
2
v
H
2
O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO
3
trong NH
3
thu c 0,25 mol Ag. Tng
s cc nguyn t trong mt phn t Y l
A. 10 B. 7. C. 6. D. 9.
Thu CO
2
v H
2
O c s mol bng nhau Andehit no , n chc C
n
H
2n
O
0,10 mol hn hp G vo dung dch AgNO
3
trong NH
3
thu c 0,25 mol Ag c HCHO
30< My<48 CH3CHO B
Cu 46: Kh no sau y khng b oxi ha bi nuc Gia-ven.
A. HCHO. B. H
2
S. C. CO
2
. D. SO
2
.
Cu 47: Cho hn hp X gm Cu, Ag, Fe, Al tc dng vi oxi d khi un nng c cht rn Y. Cho Y vo dung
dch HCl d, khuy k, sau ly dung dch thu c cho tc dng vi dung dch NaOH long, d. Lc ly kt ta
to thnh em nung trong khng kh n khi lng khng i thu c cht rn Z. Bit cc phn ng xy ra han
tan. Thnh phn ca Z gm:
A. Fe
2
O
3
, CuO, Ag. B. Fe
2
O
3
, CuO, Ag
2
O.
C. Fe
2
O
3
, Al
2
O
3
. D. Fe
2
O
3
, CuO.
Cu 48: un si hn hp propyl bromua, kali hiroxit v etanol thu c sn phm hu c l
A. propin. B. propan-2-ol. C. propan. D. propen.
Cu 49: S hp cht ng phn cu to ca nhau c cng thc phn t C
8
H
10
O, trong phn t c vng benzen, tc
dng c vi Na, khng tc dng c vi NaOH l
A. 4. B. 6. C. 7. D. 5.
Cu 50: Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y. C cn
dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan han tan 2m gam hn hp X vo nc thu
c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl
3
1M n phn ng han tan thu c kt
ta c khi lng l
A. 54,0 gam. B. 20,6 gam. C. 30,9 gam. D. 51,5 gam.
Gi : nCl=n X = 0.9 = nOH
2m vo nc nOH= 1.8, nCr=0.5
Gi a mol Cr(OH)
3
, b mol Cr(OH)
4
-
, ta c h ]
o + b = 0.5
3o + 4b = 1.8
a=0.2, b=0.3 m= 0.2(103) =20.6

B Theo chng trnh nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho phn ng: H
2
(k) + I
2
(k) 2HI (k)
nhit 430
0
C, hng s cn bng K
C
ca phn ng trn bng 53,96. un nng mt bnh kn dung tch khng i
10 lt cha 4,0 gam H
2
v 406,4 gam I
2
. Khi h phn ng t trng thi cn bng 430
0
C, nng ca HI l
A. 0,275M. B. 0,320M. C. 0,225M. D. 0,151M.
Gi y: 53.96 =
2ux10
( 2-u) ( 1.6-u)
a= 1.125 M=
2.1,125
10
= 0.225
Cu 52: Amin X c phn t khi nh hn 80. Trong phn t X nit chim 19,18% v khi lng. Cho X tc dng
vi dung dch hn hp gm KNO
2
v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht
biu no sau y ng?
A. Tch nc Y ch thu c mt anken duy nht.
B. Trong phn t X c mt lin kt .
C. Tn thay th ca Y l propan-2-ol.
D. Phn t X c mch cacbon khng phn nhnh.
Gi : X tc dng vi dung dch hn hp gm KNO
2
v HCl thu c ancol Y amin boI , Oxi ha khng hon
ton Y thu c xeton Z ru bc II
M<80, X nit chim 19,18% v khi lng nN<1.096 amin n
CxHyN , 19.18 =
14.100
12x++14
C
4
H
9
N D
Cu 53: Khi cho lng d dung dch KOH vo ng nghim ng dung dch kali icromat, dung dch trong ng
nghim
A. Chuyn t mu da cam sang mu xanh lc.
B. Chuyn t mu da cam sang mu vng.
C. Chuyn t mu vng sang mu .
D. Chuyn t mu vng sang mu da cam.
Cu 54: Cht X tc dng vi benzen (xt, t
0
) to thnh etylbenzen. Cht X l
A. CH
4
.
B. C
2
H
2
.
C. C
2
H
4.

D. C
2
H
6
.
Cu 55: Cho s chuyn ha: CH
3
CH
2
Cl X Y
Trong s trn, X v Y ln lt l
A. CH
3
CH
2
CN v CH
3
CH
2
OH
B. CH
3
CH
2
NH
2
v CH
3
CH
2
COOH
C. CH
3
CH
2
CN v CH
3
CH
2
COOH
D. CH
3
CH
2
CN v CH
3
CH
2
COOH
Cu 56: Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. HCOOH, CH
3
COOH, CH
3
CH
2
COOH
B. CH
3
COOH, HCOOH, (CH
3
)
2
CHCOOH
C. C
6
H
5
OH, CH
3
COOH, CH
3
CH
2
OH
D. CH
3
COOH, CH
2
ClCOOH, CHCl
2
COOH
Cu 57: Cho gi tr th in cc chun ca mt s cp oxi ha - kh:

Cp oxi ha/ kh
2
M
M

2
X
X

2
Y
Y

2
Z
Z

E
0
(V) -2,37 -0,76 -0,13 +0,34
Phn ng no sau y xy ra?
A. A. X + Z
2+
X
2+
+ Z B. X + M
2+
X
2+
+ M
B. C. Z + Y
2+
Z
2+
+ Y D. Z + M
2+
Z
2+
+ M
Cu 58: Dn mu kh thi ca mt nh my qua dung dch Pb(NO
3
)
2
d th thy xut hin kt ta mu en. Hin
tng chng t trong kh thi nh my c kh no sau y?
A. SO
2
B. CO
2
C. H
2
S D. NH
3

Cu 59: C mt s nhn xt v cacbonhirat nh sau:
(1) Saccaroz, tinh bt v xenluloz u c th b thy phn
(2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)
2
v c kh nng tham gia phn ng trng
bc
KCN KCN
H
3
O
+
, t
0
(3) Tinh bt v xenluloz l ng phn cu to ca nhau
(4) Phn t xenluloz c ccu to bi nhiu gc -glucoz
(5) Thy phn tinh bt trong mi trng axit sinh ra fructoz
Trong cc nhn xt trn, s nhn xt ng l
A. 2 B. 5 C. 4 D. 3
Cu 60: Ha tan hon ton 13,00 gam Zn trong dung dch HNO
3
long, d thu c dung dch X v 0,448 lt kh
N
2
(ktc). Khi lng mui trong dung dch X l
A. 18,90 gam B. 37,80 gam C. 39,80 gam D. 28,35 gam
Gi : nZn= 0.2, nNito = 0.02 cn amoninitrat
n amoninitrat =
0.4-0.2
8
= 0.025 m= (02x 189) +(0.025x80) = 39.8

Bi gii chi tit ny s dng file word gii nhng khng chi tit ca bo Tui tr do thy Nguyn nh
- ng Trng nh.