Cm nang gii ton trc nghim Ha hc Cao C Gic GV su tm: Nguyn Quang Vinh

BI TP ESTE MI
Cu 1: t chy hon ton 0.1 mol este X ri cho sn phm chy vo dd Ca(OH)2 d thu c 20g kt ta. CTPT ca X l: A. HCOOCH3 B. CH3COOCH3 C. HCOOC2H5 C. CH3COOC2H5 Cu 2: Khi t chy 1 este cho s mol CO2 v H2O bng nhau. Thy phn hon ton 6g este ny th cn dd cha 0.1mol NaOH. CTPT ca este ny? A. C2H4O2 B. C3H6O2 C. C4H8O2 D. C5H10O2 Cu 3: Cho axit axetic tc dng va vi 1 ancol trong dy ng ng ca ancol etylic(xc tc H2SO4 un nng, H=100%) th phi ly ancol no c s mol bng s mol axit axetic v khi lng cng bng khi lng axit ? A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH Cu 4: t chy hon ton 0,1 mol este X thu c 0,3 mol CO2 v 0,3 mol H2O.Nu cho 0,1 mol X tc dng ht vi NaOH to ra 8,2g mui.Cng thc cu to ca X l: A. HCOOCH3 B. CH3COOCH3 C. CH3COOC2H5 D.HCOOC2H5 Cu 5:Hn hp A gm hirocacbon X v 1,16 g este sec-butyl axetat.t chy ht A thu c 5,28g CO2 v 2,52g H2O.Hirocacbon X l: A. C2H6 B. C3H8 C. C3H6 D. C4H10 Cu 6: Cho 0,1mol este X tc dng va vi dd cha 0,2 mol NaOH thu c hh 2 mui ca axit hu c u n chc v 6,2g mt ancol Y. Anocl Y l: A. C2H4(OH)2 B. CH2(CH2OH)2 C. C3H5(OH)3 D. CH3CH2CH2OH Cu 7: t chy hon ton 4,4g cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ktc v 3,6g nc. nu cho 4,4g X tc dng va vi dd NaOH thu c 4,8g mui ca axit hc c Y v hp cht hu c Z. tn ca X l? A. ispropyl axetat B. etyl propionat C. metyl propionat D. etyl axetat Cu 8: X phng ha 8,8g etyl axetat bng 200ml dd NaOH 0,2M. sau khi phn ng xy ra hon ton, c cn dd thu c cht rn khan co khi lng l? A. 5,12g B. 8,20g C. 3,28g D. 8,56g Cu 9: X l 1 este no n chc c t khi so vi metan l 5,5. Nu un 2,2g este X vi dd NaOH d thu c 2,05g mui. CTCT ca X. A. C2H5COOCH3 B. HCOOCH2CH2CH3 C. CH3COO C2H5 D. CH3COOCH(CH3)2 Cu 10: X phng ha hon ton 19,4g hh 2 este n chc cn 200ml dd NaOH 1,5M. Sau khi p hon hon thu c hh 2 ancol ng ng k tip nhau v m gam mt mui khan x duy nht. Cng thc 2 ancol v gi tr m l? A. CH3OH, C2H5OH v 20,4g B. C2H5OH, C3H7OH v 20,4g C. C2H5OH, C3H5OH v 24,4g D. CH3OH, C2H5OH v 24,4g Cu 11: Khi phn hy hon ton 0,05 mol este ca 1 axit a chc vi 1 ancol n chc cn dng 5,6g KOH. Mt khc khi thy phn 5,475g este th cn 4,2g KOH v thu c 6,225g mui. Cng thc ca este l: A. (COOCH3)2 B. (COOC2H5)2 C. (COOCH2CH2CH3)2 D. CH2(COOC2H5)2 Cu 12: t chy hon ton 20,1g hh X gm 2 este n chc k tip cn 146,16 lt khng kh (ktc) thu c 46,2g cacbonic. Cng thc ca 2 este l? A. C4H6O2 v C5H8O2 B. C3H4O2 v C4H6O2 C. C5H8O2 v C6H10O2 D. C5H10O2 v C6H12O2 Cu 13: Thy phn hon ton 444g mt cht bo thu c 46g glixerol v 2 loi axit bo l: A. C17H33COOH v C17H35COOH B. C17H31COOH v C17H33COOH C. C15H31COOH v C17H35COOH D. C17H33COOH v C15H31COOH Cu 14: Hn hp X gm 2 axit HCOOH v CH3COOH c s mol bng nhau. Ly 5,3g X tc dng vi 5,75g C2H5OH ( c xt H2SO4 c) thu c m gam hh este( hiu sut cc phn ng este ha u bng 80%). Gi tr m cn tm l: A. 16,2g B. 6,48g C. 8,10g D. 10,12g

Cm nang gii ton trc nghim Ha hc Cao C Gic GV su tm: Nguyn Quang Vinh Cu 15: Este X khng no, mch h c t khi so vi oxi bng 3,125 v khi tham gia phn ng x phng ha to ra 1 anehit v 1 mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? A. 2 B. 4 C. 5 D. 3 Cu 16: Mt hh X gm 2 cht hu c n chc. Cho X phn ng va vi dd KOH 1M. Sau phn ng thu c hh Y gm 2 mui ca 2 axit cacboxylic v 1 ancol. Cho ton b ancol thu c trn tc dng vi Na d, thu c 3,36 lt H2 (ktc). Hn hp X gm: A. 1 este v 1 ancol B. 1 axit v 1 este C. 1 axit v 1 ancol D. 2 este Cu 17: Cho 8,6g este X bay hi thu c 4,48 lt hi X 2730C v 1 atm. Mt khc cho 8,6g X tc dng va vi dd NaOH th thu c 8,2g mui. CTCT ng ca X l? A. HCOOCH2CH=CH2 B. CH3COOCH2CH3 C. HCOOCH2CH2CH3 D. CH3COOCH=CH2 Cu 18: Hn hp X gm 2 este hn km nhau 1 nhm CH2-. Cho 6,6g hh X tc dng va d vi 100 ml dd NaOH 1M thu c 7,4g hh 2 mui. CTCT 2 este? A. CH3COOC2H5 v HCOOC2H5 B. CH3COOCH=CH2 v HCOOCH=CH2 C. CH3COOC2H5 v CH3COOCH3 D. HCOOCH3 v CH3COOCH3 Cu 19: un nng 18g axit axetic vi 9,2g ancol etylic c mt H2SO4 c lm xc tc,sau phn ng thu c 12,32g este. Hiu sut ca phn ng este ha l: A. 35,42% B. 46,67% C. 70,00% D. 92,35% Cu 20: Chia m gam este X thnh 2 phn bng nhau. t chy hon ton phn I thu c 4,48 lt kh CO2 (ktc) v 3,6g H2O. Phn II tc dng va vi 100 ml dd NaOH 0,5M. Gi tr m l? A. 2,2 B. 6,4 C. 4,4 D. 8,8 Cu 21: t chy hon ton 1g este X n chc, mch h c 1 ni i C=C thu c 1,12 lt kh CO2 (ktc) v 0,72g H2O. CTPT ca X l A. C4H8O2 B. C4H6O2 C. C5H8O2 D. C5H10O2 Cu 22: Lm bay hi 10,2g mt este A p sut p1 thu c 1 th tch hi bng th tch ca 6,4g O2 cng nhit , p sut P2(bit p2=2p1). CTPT ca A L A. C3H6O2 B. C2H4O2 C. C3H2O4 D. C5H10O2 Cu 23: Thy phn hon ton 0,1 mol este (RCOO)3R bng dd NaOH thu c 28,2g mui v 9,2g ancol. CTPT ca este l A. (C2H5COO)3C3H5 B. (C2H3COO)3C3H5 C. (C2H3COO)3C4H7 D. (C3H7COO)3C3H5 Cu 24: Thy phn este E c CTPT C4H8O2 ( c mt H2SO4 long) thu c 2 sp hu c X v Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l: A. metyl propionat B. propyl fomiat C. ancol etylic D. etyl axetat Cu 25: Thy phn hon ton hh gm 2 este n chc X v Y l ng phn cu to ca nhau cn 100 ml dd NaOH 1M thu c 7,85g hh 2 mui ca 2 axit l ng ng k tip v 4,95g 2 ancol bc 1. CTCT v % khi lng ca 2 este: A. HCOOCH2CH2CH3 75%; CH3COOC2H5 25% B. HCOOCH2CH3 45%; CH3COOCH3 55% C. HCOOCH2CH3 55%; CH3COOCH3 45% D. HCOOCH2CH2CH3 25%; CH3COOC2H5 75% Cu 26: Este X c cng thc n gin nht l C2H4O. un si 4,4g X vi 200g dd NaOH 3% n khi phn ng xy ra hon ton. C can dd sau phn ng thu c 8,1g cht rn khan. CTCT ca X l: A. CH3CH2COOCH3 B. CH3COOCH2CH3 C. HCOOCH2CH2CH3 D. HCOOCH(CH3)2 Cu 27: Thy phn 4,3g este Xn chc, mch h(xc tc axit) n khi phn ng hon ton thu c hh 2 cht hu c Y v Z. Cho Y v Z phn ng vi lng d dd AgNO3/NH3 thu c 21,6g Ag. CTCT ca X l? A. HCOOCH=CHCH3 B. HCOOCH2CH=CH2 C. CH3COOCH=CH2 D. HCOOC(CH3)=CH2

Cm nang gii ton trc nghim Ha hc Cao C Gic GV su tm: Nguyn Quang Vinh Cu 28: un 20,4g cht hu c A n chc vi 300 ml dd NaOH 1M thu c mui B v cht hu c C. Cho C tc dng vi Na d thot ra 2,24 lt kh H2 (ktc). Bit nung B vi NaOH rn c kh K c t khi so vi O2 bng 0,5. Hp cht hu c C n chc khi b oxi ha bi CuO un nng to ra sn phm D khng tham gia phn ng trng bc. CTCT ca A: A. CH3COOCH(CH3)2 B. CH3COOCH2CH2CH3 C. CH3CH2COOCH(CH3)2 D. Kt qu khc Cu 29: Hp cht hu c X n chc cha (C,H,O). t chy hon ton X thu c VCO2 = VO2 = 1,5.VH2O. X c phn ng vi dd NaOH v tham gia phn ng trng bc. Cng thc cu to ca X l: A. CH2=CH-COOH B. HCOOCH=CH2 C. HCOOCH2CH=CH2 D. HCOOCH=CHCH3 Cu 30: Hai este X v Y l 2 dn xut ca benzen c CTPT C9H8O2. X, Y u cng vi brom theo t l 1:1. X tc dng vi dd NaOH cho 1 mui v 1 andehit, Y tc dng vi dd NaOH d cho 2 mui v nc, cc mui u c khi lng mol ln hn CH3COONa. CTCT X v Y? A. C6H5COOCH=CH2 v C6H5CH=CHCOOH B. HCOOC6H4CH=CH2 v HCOOHCH=CHC6H5 C. C6H5COOCH=CH2 v CH=CHCOOC6H5 D. HCOOC6H4CH=CH2 v C6H5COOCH=CH2 Cu 31: X l 1 este ca 1 axit hu c n chc v mt ancol n chc. Thy phn hon ton 7,04g X ngi ta dng 100 ml dd NaOH 1M ly d 25%. S CTCT tha mn ca X? A. 2 B. 3 C. 4 D. 5 Cu 32: X phng ha hon ton 0,2 mol metyl axetat bng dd NaOH d 20% so vi lng phn ng thu c dd X. C cn dd X thu c bao nhiu gam cht rn? A. 18,4 B. 24,4 C. 18,0 16,4 Cu 33: Cho 0,15 mol hh 2 ste n chc phn ng va vi 0,25 mol NaOH thu c hh 2 mui v 1 ancol c khi lng tng ng l 21,8g v 2,3g. Hai este l? A. CH3COOC6H5 v CH3COOC2H5 B. CH3COOC6H5 v CH3COOCH3 C. HCOOC6H5 v CH3COOC2H5 D. HCOOC6H5 v CH3COOCH3 Cu 34: Hn hp X n chc, mch h l ng phn ca nhau. Cho m gam X tc dng va vi 100 ml dd NaOH 1M thu c mt mui ca axit cabonxylic v hh 2 ancol. Mt khc t chy m gam X thu c 8,96g CO2 v 7,2g H2O. CTCT 2 este? A. CH3COOCH2CH2CH3 v CH3COOCH(CH3)2 B. HCOOCH(CH3)2 v HCOOCH2CH2CH3 C. CH3COOCH2CH2CH2CH3 v CH3COOCH(CH3)CH2CH3 D. CH3COOCH(CH3)CH2CH3 v CH3COOCH(CH2CH3)2 Cu 35: Thy phn hon ton este a ca 1 axit hu c n chc v 1 ancol n chc bng lng NaOH va . Lm bay hi hon ton dd sau thy phn. Phn hi c dn qua bnh (1) ng CuSO4 khan d. Hi kh cn li ngng t ht vo bnh 2 ng Na d, thy c kh G bay ra v khi lng 2 tng thm 6,2g. Dn kh G qua bnh 3 ng CuO d, un nng thu c 6,4g Cu. Lng este A ban u tc dng vi dd brom d th c 32g brom phn ng thu c sn phm trong brom chim 65,04% khi lng phn t. Tn gi A l? A. metyl arcrylat B. metyl axetat C. vinyl axetat D. metyl metacrylat