Ha Hc 11

CHUYN : S IN LI B. BI TON DNG 1: TNH NNG MOL ION TRONG DUNG DCH Tnh nng ion trong dung dch cht in li mnh Cu 1: a. b. c. d. e. f. Cu 2: a. b. c. d. e. f. Tnh nng ca cc ion c trong cc dung dch sau: Dung dch: KOH 0,2M; HNO3 0,5M; K2SO4 0,3M; (NH4)2S 0,5M; Na2HPO4 0,1M. Dung dch HNO3 7% (Bit D=0,36g/ml). Dung dch cha HCl 0,1M v H2SO4 0,3M. (Gi s H2SO4 phn li hon ton c hai nc) 2 lt dung dch c ha tan 17,4g K2SO4 tan trong nc. 0,5 lt dung dch c ha tan 13,05 g Ba(NO3)3 200 ml dung dch c cha 1,32 g (NH4)2SO4 Tnh nng mol/l ca cc ion c trong dung dch thu c khi: Trn 300 ml dung dch HCl 0,5 M vi 200 ml dung dch H2SO4 0,25M. Trn 300 ml dung dch KOH 0,1M vi 100 ml dung dch Ca(OH)2 0,2M. Trn 400 ml dd Fe2(SO4)3 0,2M vi 100 ml dd FeCl3 0,3M. Trn 200 ml dd cha 12g MgSO4 v 300ml dd cha 34,2 g Al2(SO4)3. Trn 200 ml dung dch KOH 0,05M vi 200ml dung dch HCl 0,1M. Trn 200ml dung dch Na2SO4 0,1M vi 100ml dung dch Ba(NO3)2 0,3M.

Cu 3: Ha tan 34,2 gam Ba(OH)2 vo nc c 500 ml dung dch. a. Tnh nng mol ca cc ion c trong dung dch. b. Tnh th tch dung dch H2SO4 0,2M cn trung ha hon ton dung dch trn. Cu 4: a. b. c. Cu 5: a. b. c. Cu 6: a. b. s: Cu 7: a. b. Cu 8: Ha tan 24 gam MgSO4 vo nc c 800 ml dung dch. Tnh nng mol ca MgSO4 v ca cc ion c trong dung dch. Tnh th tch dung dch KOH 0,5M cn lm kt ta ht ion Mg2+. 2Tnh th tch dung dch BaCl2 0,5M cn lm kt ta ht ion SO 4 . Ngi ta ha tan 80,5 gam ZnSO4 vo nc c 1500 ml dung dch. Tnh nng mol ca ZnSO4 v ca cc ion c trong dung dch. Tnh th tch dung dch Na2S 0,5M cn lm kt ta ht ion Zn2+. 2Tnh th tch dung dch BaCl2 0,8M cn lm kt ta ht ion SO 4 . Ha tan 12,5g tinh th CuSO4.5H2O trong nc thnh 200ml dd. Tnh CM cc ion trong dd thu c. Ha tan 8,08g Fe(NO3)3.9H2O trong nc thnh 500 ml dd. Tnh CM cc ion trong dd thu c. a. [Cu2+] = [SO42-] = 0,25M b. 0,04M; 0,12M. Tnh V dd HCl 0,5M c cha s mol H+ bng s mol H+ c trong 0,3 lt dung dch HNO3 0,2M. Tnh V dd KOH 14% (D=1,12g/ml) c cha s mol OH- bng s mol OH- c trong 0,2 lt dd NaOH 0,5M. Trn 400 ml dung dch HNO3 10,5% (D= 1,2g/ml) vi 300 ml dung dch HNO3 14% (D= 1,08g/ml). Tnh

nng mol/lt ca cc ion trong dung dch thu c? (Gi s th tch dung dch khng thay i). Cu 9: Trn ln 100ml dd AlCl3 1M vi 200ml dd BaCl2 2M v 300ml dd KNO3 0,5M. Tnh nng mol/l cc ion c trong dung dch sau khi trn. Cu 10: Trn ln 80ml dd KOH 0,45M vi 35ml dd H2SO4 0,8M th thu c dung dch D. a. Tnh nng mol/l cc ion c trong dung dch D.(Bit phn ng xy ra hon ton) b. Tnh th tch dung dch Ba(OH)2 1,2M cn trung ho dung dch D. Cu 11: Cho 100 ml dd H2SO4 1M vo 200 ml dd hn hp gm KOH 1M v Ca(OH)2 0,5M. Tnh nng mol ca cc ion trong dung dch thu c.

Gv: L Th Thanh Hng

Ha Hc 11

Tnh nng ion trong dung dch cht in li yu (*) Da vo in li : Cu 1: Tnh nng cc ion trong dung dch HClO 0,1M bit in li = 0, 0014%. Cu 2: Tnh nng mol/l ion H+ v CH3COO- trong cc trng hp sau: a. Dung dch CH3COOH 0,01M, = 4,25% b. Dung dch CH3COOH 0,1M, = 1,34% c. Dung dch CH3COOH 0,2M, = 0,95% d. Dung dch CH3COOH 1%, D = 1g/ml, = 1% Da vo hng s phn li: Cu 3: Tnh nng cc ion v in li ca dung dch HClO 0,1M bit Ka = 5.10-8 Cu 4: Tnh nng cc ion v in li

ca dung dch HCN 0,05M bit Ka = 7.10-10.

Cu 5: Ha tan 6 g axit axetic vo nc c 1 lt dung dch A. Tnh nng ion H+ v in li dch A bit Ka = 1,8.10-5. .... DNG 2 (*): XC NH IN LI CA CHT IN LI YU Cu 1: Cu 2: Tnh in li ca dung dch HClO. Bit 1000 phn t 200 phn t b in li. Trong 500 ml dung dch HCN 0,01 M c 2. 1019 phn t b in li. Tnh in li .

ca dung

Cu 3: Trong 1 lt dung dch CH3COOH 0,01M c 6,26.1021 phn t cha phn li v ion. Tnh in li ca CH3COOH nng ? (Bit s Avogaro = 6,02.1023 ) Cu 4: Dung dch HClO 0,2M c nng H+ bng 0,008M. Tnh in li

ca HClO trong dung dch.

Cu 5: Tnh in li : a. Axit HClO (hipoclor) trong dung dch 0,2M bit Ka = 4.10-8. b. HCOOH 0,46% (D = 1) nu dung dch ca axit c pH =3. Cu 6: Tnh nng H+ (mol/l) trong cc dung dch sau: a. CH3COONa 0,1 M Bit Kb ca CH3COO- l 5,71 .10-10. b. NH4Cl 0,1 M . Bit Ka ca NH4+ l 5,56 .10-10. Cu 7: C hai dung dch sau: a. CH3COOH 0,10M (Ka= 1,75.10-5). Tnh nng mol ca ion H+. b. NH3 0,10M (Kb= 1,80.10-5). Tnh nng mol cu ion OH Cu 8: Tnh nng mol ca cc ion H+ v OH- trong dung dch NaNO2 1M. Bit rng hng s phn li baz ca NO2- l Kb = 2,5 .10-11. .... DNG 3: TNH pH CA DUNG DCH CHT IN LI MNH pH ca dung dch n axit Cu 1: Tnh pH ca cc dung dch sau: a. Dung dch HCl 10-4 M . c. Dung dich HClO4 1,6.10-7M

b. Dung dch HNO3 0,001M d. Dd H2SO4 0,005 M (gi s nc 2 phn li hon ton)

Cu 2: Ha tan 448 ml HCl (ktc) vo 2 lt nc thu c dd X. Tnh pH dd trn bit th tch dung dch thay i khng ng k. (pH = 2) pH ca dung dch n baz Cu 3: Tnh pH ca cc dung dch sau : a. Dung dich KOH 0,001M. c. Dung dch Ca(OH)2 0,001M

b. Dung dich Ba(OH)2 5.10-4M. d. 500 ml dd cha 0,2 g NaOH.

pH ca dung dch gm nhiu axit/baz (khng c p xy ra) Gv: L Th Thanh Hng 2

Ha Hc 11

Cu 4: a. b. c. Cu 5: a. b. c. d.

Tnh pH ca cc dung dch sau: Dung dch A cha HCl 2.10-4M v H2SO4 4.10-4M. Dung dch B cha KOH 0,06M v NaOH 0,04M Dung dch C cha NaOH 0,016M v Ba(OH)2 0,005M. Tnh pH ca cc dung dch thu c khi: Trn 200 ml dd H2SO4 0,05M vi 300 ml dd HCl 0,1M Trn 20 ml dd HNO3 0,05M vi 20 ml dd H2SO4 0,075M Trn 200 ml dd KOH 1M vi 100 ml dd Ca(OH)2 0,5M Trn 100 ml dd Ba(OH)2 1M vi 200 ml dd NaOH 2M thu c dd A. thu c dd B. thu c dd C. thu c dd D.

pH ca dung dch khi trn ln axit + baz (c p xy ra) Cu 6: Tnh pH ca cc dung dch sau: a. Trn 15 ml dung dch NaOH 2M vi 50 ml dung dch H 2SO4 0,5M thu c dd X (coi H2SO4 in li hon ton c hai nc). Tnh pH dd X b. Trn 100 ml dd H2SO4 0,1M vi 150 ml dd NaOH 0,2M to dd Y. Tnh pH ca dd Y. c. Trn 100ml dd Ba(OH)2 0,5 M va 100ml dd KOH 0,5 M thu c dung dich Z. Cho Z tac dung 100ml dd H2SO4 1M. Tnh pH ca dung dch thu c sau phn ng. d. Trn 200 ml hn hp dung dch NaOH 1M v Ca(OH)2 0,5M vi 200 ml hn hp dung dch HCl 1M vo H2SO4 0,5M. Tnh pH ca dung dch thu c. Bi ton tng hp nng cao Cu 7: Trn 200ml dd H2SO4 0,05M vi 300ml dd HCl 0,1M ta c dd A. Tinh pH cua dd A. (pH = 1) Cu 8: Trn ln 100ml dd Ba(OH)2 0,06M vi 400ml dd HCl 0,02M. Tnh pH ca dd to thnh. (pH = 12,9) Cu 9: Cho 2 lt dung dch A gm: HCl 0,1M v H2SO4 0,15M phn ng vi 2 lt dung dch NaOH 0,2M. Tnh pH ca dung dch sau phn ng hon ton. (pH = 1) Cu 10: Cho 2 lt dung dch hn hp gm: HCl 1M v H 2SO4 0,5M phn ng vi 1 lt dung dch hn hp gm: NaOH 3M v KOH 4M. Sau khi phn ng hon ton thu c dung dch B. Tnh pH dung dch B. (pH = 14) Cu 11: a. Dung dch H2SO4 c pH = 2. Tnh nng mol/l ca ion H+ v H2SO4. Cho 0,24 g Mg vo 0,6 lit dd trn. Tnh th tch kh thot ra. (6,72.10-2 lit). b. Trn 50ml dung dch HCl vi 50ml dung dch NaOH c pH = 13 thu c dung dch X c pH = 2. Tnh s mol v nng mol/l ca dung dch HCl ban u. (6.10-3 mol; 0,12M) Cu 12: A l dd Ba(OH)2 c pH = 13. a. Tnh nng mol/l ca Ba(OH)2.(0,05M) b. Nu pha long dd A 5 ln th pH dd mi l bao nhiu? (CT pha long C1V1 = C2V2 pH = 12,3) Cu 13: c dung dch c pH = 9, cn pha long dung dch KOH 0,001M vi nc bao nhiu ln? (100 ln) Cu 14: C 10 ml dung dch axit HCl c pH = 3. Cn thm bao nhiu ml nc ct thu c dd c pH = 4? A. 90 ml B. 100 ml C.10 ml D. 40 ml. (pp ng cho) Cu 15: Pha long 10 ml dung dch HCl vi nc thnh 250 ml dung dch. Dung dch thu c c pH = 3. Nng mol/l ca dung dch HCl trc khi pha long? (10.C1 = 250.10-3 C1 = 0,025M) Cu 16: Trn 250 ml dd cha HCl 0,08M v H2SO4 0,01 M vi 250 ml dd Ba(OH)2 x mol/l thu m gam kt ta v 500 ml dd c pH= 12 (coi Ba(OH)2 in li hon ton c hai nc). m v x c gi tr? (0,5825g v 0,06 mol/l) Cu 17: X l dung dch HCl, Y l dd NaOH. Ly 10 ml X pha long bng nc thnh 1000 ml th thu c dd HCl c pH bng 2. trung ho 100 gam Y cn 150 ml dd X. Tnh nng % ca Y (6%) Cu 18: X l dung dch H2SO4, c nng ca ion H+ l 2 mol/l. thu c dung dch Y c pH = 1 phi thm vo 1 lt dung dch X mt th tch dung dch NaOH 1,8M l: A. 1 lt B. 1,5 lt C. 2 lt. D. 3 lt ( nH
+

= 2.1 = 2 mol ; n H +

(d)

= 0,1 mol ; n H

(p)

= 1.9 mol ; 1,8.V = 1,9.(1+V) V = 1)

Cu 19: Dd HCl c pH =5 (V1) cho vo dd KOH pH = 9 (V2). Tnh V1/V2 dd mi c pH=8 (9/11) Cu 20: Dd A c pH=5, dd B c pH=10. Trn V1 lit dd A vi V2 lit dd B thu c dd C c pH=8. T l V1/V2 l bao nhiu? (9) Gv: L Th Thanh Hng 3

Ha Hc 11

Cu 21: Trn V1 lt dung dch H2SO4 c pH=3 vi V2 lit dung dch NaOH c pH=12 c dung dch c pH=4, th t l V1: V2 c gi tr bao nhiu? (101:9) Cu 22: Ha tan 0,31 gam mt oxit kim loi vo nc c 1000 ml dd c pH = 12. Cng thc ca oxit l? (Na2O) Cu 23: (H khi B 2002). Cho hai dung dch H2SO4 c pH = 1 v pH = 2. Thm 100 ml dung dch KOH 0,1M vo 100 ml mi dung dch trn. Tnh nng mol/lt ca dung dch thu c? Cu 24: ( thi TSH khi A 2004). Cho 40 ml dung dch HCl 0,75 M vo 160 ml dung dch cha ng thi Ba(OH)2 0,08 M v KOH 0,04 M. Tnh pH ca dung dch thu c. Cu 25: ( thi TSH SP 2001). Tnh th tch dd Ba(OH)2 0,04M cn cho vo 100ml dd gm HNO3 0,1M v HCl 0,06 M thu c dung dch c pH =2. Cu 26: (H Quc Gia H Ni 2000) a. Trn 250 ml dung dch hn hp gm HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch NaOH a M thu c 500ml dung dch c pH = 12. Tnh a. b. Trn 300 ml dung dch HCl 0,05 M vi 200 ml dung dch Ba(OH)2 amol/lt thu c 500ml dung dch c pH = 12. Tnh a Cu 27: (H khi B 2003). Trn 250 ml dung dch hn hp gm HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 a M thu c m gam kt ta v 500ml dung dch c pH = 12 . Tnh m v a Cu 28: (H S Phm H Ni I 2001).Tnh th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch gm HNO3 v HCl c pH = 1 thu c dung dch c pH = 2. Cu 29: (H khi B 2008). Trn 100 ml dung dch c pH = 1 gm HCl v HNO vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dd [H ][OH ]=10-14) Cu 30: Cn trn dd HCl 0,6M (A) vi dd HCl 1,6M (B) theo t l th tch (VA/VB) th no c dd HCl 1M. DNG 4: TNH pH CA DUNG DCH CHT IN LI YU Cu 1: Dung dch CH3COOH 0,043M c in li l 2%. Xc nh pH ca dung dch . (3,065) Cu 2: (H Y H Ni 1999). in li ca axit axetic (CH3COOH ) trong dung dch CH3COOH 0,1M lM 1%. Tnh pH ca dung dch axit ny. Cu 3: Tnh pH ca dung dch CH3COOH 0,1M, bit hng s phn li axit Ka = 1,75.10-5. (1,32.10-3- Ha 11NC) Cu 4: Tnh pH ca dung dch NH3 0,1M, bit hng s phn li baz Kb = 1,8.10-5. (1,34.10-3- Ha 11NC)
3 + -

Gv: L Th Thanh Hng