S GIO DC V O TO GIA LAI TRNG THCS V THPT KP KLNG

CNG N TP HC K II
MN : HA HC LP 10 A. L THUYT Cu 1: a) T c im cu to, nu tnh cht ha hc c bn ca cc nguyn t halogen. Vit phng trnh HH minh ha? b) So snh tnh oxi ho gia cc halogen. Vit phng trnh HH chng minh? Cu 2: T thnh phn v c im cu to ca HCl, c th kt lun g v tnh cht ha hc c bn ca HCl ?. Vit phng trnh ha hc chng minh. Cu 3: vit phng trnh iu ch Cl2, HCl trong phng th nghim v trong cng nghip (nu r iu kin ca phn ng). Cu 4: a) T cc ha cht : NaClrn , MnO2 (rn) , NaOHdd , CaCO3 , H2O, H2SO4 (m c) . Vit s iu ch cc cht sau : Nc Javen, kaliclorat, clorua vi. b) Gii thch tnh ty trng ca kh clo m, nc Javen v clorua vi? Cu 5: Nu v tr, thnh phn, c im cu to ca cc nguyn t trong nhm VIA (oxi v lu hunh). T suy ra khuynh hng nhng, nhn electron ca nguyn t cc nguyn t nhm VIA. Cu 6: a) So snh tnh cht ha hc ca oxi v lu hunh? Gii thch. Vit PTHH chng minh. b) So snh tnh cht ha hc ca oxi v ozon? Gii thch. Vit PTHH chng minh. c) Phng php iu ch oxi trong PTN v trong CN ? Cu 7: T thnh phn phn t v c im cu to, c kt lun g v tnh cht ha hc c bn ca H2S, SO2 ?. Vit phng trnh ha hc chng minh. Cu 8: Nu tnh cht ha hc ca H2SO4 (long, m c). Vit phng trnh HH minh ha? Cu 9: Th no l tc ca phn ng ha hc? Biu thc tnh tc ca phn ng. Nu cc yu t nh hng n tc phn ng? Cu 10: Th no l cn bng ha hc? Ti sao ni cn bng ha hc l mt cn bng ng? Cu 11: a) Th no l s dch chuyn cn bng ha hc? Cc yu t nh hng n cn bng ha hc? b) p dng nguyn l chuyn dch cn bng l-sa-t-li- cho trng hp c th c th? B. BI TP Dng 1: B tc, hon thnh s phn ng. V d 1.1: Hon thnh s chuyn ha sau: A (Mi trng thi) X + D D + Br2 O2 ,t o X B Y + Z
+Y E hoac Z A + G V d 1.2: xc nh cc cht v hon thnh chui phn ng sau: FeS + A B (kh) + C B + CuSO4 D ( en) + E B + F G ( vng) + M V d 1.3: KClO3 KClO3 KCl K2Cr2O7 Cl2 HCl FeCl2 FeCl3 AgCl Cl2 Nc giaven KMnO4 CaOCl2 CaCl2 Cl2

Gio vin: Ng Thanh H

Dng 2: Nhn bit, tch, tinh ch. Yu cu: - Nm c phn ng c trng ca cc cht: O3, H2S v mui Sunfua tan, kh SO2, ion SO32-, SO42-, Cl- , I2 . - Tnh tan ca cc mui clorua, sunfua, sunfit, sunfat. V d 2.1 : Nhn bit cc cht sau: a) NaCl, Na2SO4, Na2SO3, Na2CO3 v Na2S. b) Cc kh: H2S, Cl2, O2, HCl v O3. V d 2.2 : Bi tp 5,6/113; 10,11/114; 3/1435.6/147 SGK Dng 3: Tc phn ng v cn bng ha hc V d 3.1: Cho phn ng: 2SO2 + O2 2SO3 ; Phn ng ta nhit. ( D H < O) Cho bit cn bng phn ng trn chuyn dch theo chiu no khi gim nhit ? Khi tng p sut? Khi thm cht xc tc? Gii thch? V d 3.2: Trong sn xut H2SO4, giai on oxi ha SO2 thnh SO3 c biu din: 2SO2 (k) + O2 (k) 2SO3 (k) ; Phn ng ta nhit. ( D H < O) Cn bng ha hc s chuyn di v pha to ra sn phm l SO3 nu A.Tng nng kh oxi v tng p sut B.Gim nng kh oxi v gim p sut C.Tng nhit v gim p sut C.Gim nhit v gim nng kh SO2. V d 3.3: Cc bi tp trang 168; 169 SGK. Dng 4: Bi tp c tnh ton. 1 - Bi ton Tnh nng , xc nh thnh phn %, tnh lng d V d 4.1 : 7/114; 6, 11,12/119; 4/132; 8/139; SGK 6.15/47; 6.41/54 SBT V d 4.2 : 6/128 SGK 2 - Bi ton oleum, pha trn dung dch, nng dung dch. VD 4.3 : Ha tan 200 gam SO3 vo m gam dung dch H2SO4 49% ta c dung dch H2SO4 78,4%. Gi tr ca m l: A. 133,3 B. 146,9 C. 272,2 D. 300,0 VD 4.4 : 7/106; 6/143 SGK 3 - Bi ton xc nh cng thc ha hc. V d 4.4 : 8/96; 8/114; 9/139 SGK V d 4.5 : Ha tan 13 gam kim loi M bng dung dch H2SO4 long thu c 4,48 lt H2 (ktc). Xc nh kim loi M ? V d 4.6 : Ha tan 1,92 gam kim loi R bng dung dch H2SO4 c, nng, va thu c 0,672 lt kh SO2 (ktc) v dung dch A. Xc nh kim loi R ? Hng dn: t ha tr kim loi l n (n nhn gi tr t 1 4) 5 - Bi ton lin quan n hiu sut phn ng. V d 4.7 : 9/114 SGK - Gii theo s mol v phng trnh phn ng . V d: hu ht cc bi ton ha hc. V d: BT 7/101; 1, 7/106; 5/108 SGK V d 4.8 : T 120 kg FeS2 c th iu ch c ti a bao nhiu lt dung dch H2SO4 98% (d = 1,84 g/ml) ? - Phng php bo ton khi lng, tng gim khi lng. - p dng s ng cho. V d 4.8; 6.9, 6.10/46 SBT

Gio vin: Ng Thanh H