S

GIO D C V O T O NG THP
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K THI CH N H C SINH GI I L P 12 THPT C P T NH NM H C 2011 - 2012

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thi chnh th c

Cu 1: (2 i m) 1) H p ch t A c t o ra t 4 nguyn t c a 2 nguyn t X v Y. T ng s h t mang i n trong h t nhn c a cc nguyn t trong m t phn t A l 18. Nguyn t c a nguyn t Y c 4 electron phn l p p. Xc nh cng th c ha h c c a A. Cho 3,4 gam A tc d ng h t v i h n h p dung d ch g m KMnO4 v H2SO4 d. Tnh th tch kh sinh ra 27oC, 380 mmHg. 2) Hon thnh cc phng trnh ph n ng sau: a) FexOy + H2SO4 c, nng SO2 + ? + ? b) Al + HNO3 NO + N2O + ? + ? Bi t: 13,4 gam h n h p kh NO v N2O chi m th tch b ng th tch c a 0,8 gam H2 cng i u ki n. Cu 2: (2 i m) 1) Cc ch t sau ph n ng c v i dung d ch Ba(HCO3)2: HNO3, Ca(OH)2, Na2SO4, KHSO4. Hy vi t cc ph n ng ha h c x y ra. 2) Cho 3 dung d ch sau c cng gi tr pH: NaOH C1(M); NH3 C2(M); Ba(OH)2 C3(M). Hy so snh cc gi tr C1, C2, C3. Gi i thch. Cu 3: (2 i m) 1) Cho 2 mol HCOOH tc d ng v i 2 mol CH3OH (xc tc l axit) th c hi n ph n ng este ho, l ng este l n nh t l 1,5 mol. t hi u su t c c i l 80% (tnh theo ancol, nhi t khng i) khi ti n hnh este ho 3 mol CH3OH c n s mol HCOOH l bao nhiu? 2) Cho ph n ng: 2N2O5 (kh) 4NO2 (kh) + O2 (kh) Gi tr t c u c a c a N2O5 t i 250C c cho trong b ng: Th nghi m 1 Th nghi m 2 [N2O5]: M 0,3 0,7 -1 -1 -4 T c : mol.l .phut 6,84 x 10 15,96 x 10-4 Hy tnh b c ph n ng cho ph n ng trn v tnh h ng s t c ph n ng. Cu 4: (2 i m) 1) Hon thnh cc phng trnh ph n ng sau: t0 Ca3(PO4)2 + SiO2 + C H2S + n c Cl2 ZnSO4 + dd NH3 (d) O3 + dd KI 2) D n h n h p kh X g m N2, O2, NO2 vo dung d ch NaOH d t o dung d ch D v th a 1 h n h p kh khng b h p th . Cho D vo dung d ch KMnO4 th mu tm b m t trong mi tr ng H2SO4, thu c dung d ch G. Cho v n Cu, thm H2SO4 long vo dung d ch G, r i un si s t o dung d ch mu xanh v thu c kh d ha nu ngoi khng kh. Hy vi t cc ph n ng ha h c x y ra. Cu 5: (2 i m) 1) Cho 200ml dung d ch A ch a HCl 1M v HNO3 2M tc d ng v i 300ml dung d ch B ch a NaOH 0,8M v KOH xM thu c dung d ch C. trung ha dung d ch C c n 60ml dung d ch HCl 1M. a) Tm gi tr c a x. b) Tnh kh i l ng ch t r n thu c khi c c n dung d ch C.

THI MN: HO H C Ngy thi: 09/10/2011 Th i gian lm bi: 180 pht (khng k th i gian pht ) ( thi g m c: 02 trang)

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2) Ha tan 7,68 gam Cu vo 150 ml dung d ch h n h p HNO3 0,8M v H2SO4 0,4M thu c dung d ch A v V lt kh NO duy nh t (ktc). a) Tnh gi tr c a V. b) C c n dung d ch A thu c bao nhiu gam mu i khan. Cu 6: (2 i m) S p x p s tng d n tnh axit, tnh baz (c gi i thch) c a cc ch t trong cc dy tng ng sau: 1) Tnh axit: CH3CHClCH2COOH; CH3CHClCHClCOOH; CH3CH2CHClCOOH; CH3CH2CH2COOH; CH3CHBrCHClCOOH 2) Tnh baz:

Cu 7: (2 i m) 1) Anethole c phn t kh i l 148,2 v hm l ng cc nguyn t 81,04% C; 8,16% H; 10,8% O; (bi t H = 1,008; C = 12,000; O = 15,999). Hy: a) Xc nh cng th c phn t c a anethole. b) Vi t cng th c c u t o c a anethole d a vo cc d ki n sau: + Anethole lm m t mu n c brom. + Anethole c hai ng phn hnh h c. + Anethole b oxi ha t o ra axit methoxybenzoic (M) v nitro ha (M) ch cho duy nh t axit methoxynitrobenzoic. 2) Khi un nng (brommetyl)xiclobutan v i dung d ch NaOH long (dung mi n c), ta thu c h n h p 5 s n ph m khc nhau. Gi i thch s t o thnh 5 s n ph m .
CH2Br

(brommetyl)xiclobutan

Cu 8: (2 i m) 1) Cho bi t d ng ion l ng c c chnh c a lysin. Gi i thch. 2) Hon thnh cc ph n ng ha h c sau (ghi r c u trc phn t ): HCl a) -D-Glucoz + CH3OH b) Mantoz + [Ag(NH3)2]OH c) Saccaroz + HIO4 Cu 9: (2 i m) 1) Xc nh cc ch t h u c A, B, C, D trong s sau:
+ancol isopropylic +HCN 2 2 4 CH3COCH 3 A B C D t0 xt, t 0 +H

H SO

2) T natri axetat v cc ho ch t v c c n thi t hy vi t s t ng h p cis-but-2-en. Cu 10: (2 i m) 1) Nu hi n t ng quan st c v vi t phng trnh ph n ng x y ra trong m i th nghi m sau: Th nghi m 1: Cho dung d ch KOH vo c c ng dung d ch Na2SO3, sau thm ti p dung d ch KMnO4 vo. Th nghi m 2: Cho n c brom vo c c ng dung d ch FeSO4, sau thm ti p dung d ch NaOH vo. 2) B ng phng php ha h c, hy tch r i m i ch t kh ra kh i h n h p kh g m N2 v NO.H T
H v tn th sinh: ________________________ Ch k GT1:_____________________________ S bo danh: ___________________________ Ch k GT2:____________________________

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