1) Dng 1: kim loi tc dng vi axit

a. Vi axit th hin tnh oxi ho bng H+( HCl, H2SO4l)

Cu 1: Ho tan 1,19 gam hn hp A gm Al, Zn bng dung dch HCl va thu c dung dch X v
V lt kh Y (ktc). C cn dung dch X c 4,03 gam mui khan. Gi tr ca V l
A. 0,224.
B. 0,448.
C. 0,896.
D. 1,792.
Cu 2: Cho hn hp Fe, Mg tc dng vi 400 ml dung dch hn hp HCl 1M + H2SO4 0.4 M lm thot
ra V l kh H2 v dung dch X. X tc dng va ht vi 11 g CaCO3. Tnh V lt kh H2 (ktc):
A. 5.6 l
B. 4.48 l
C. 6.72 l
D. 4.32 l
Cu 3: (A-07): Cho m gam hh Mg, Al vo 250ml dd cha hh HCl 1M v H2SO4 0,5M thu c 5,32 lt
kh H2 (ktc) v dd Y. Coi th tch dd khng i. Dung dch Y c pH l
A. 1. B. 6. C. 2.
D. 7.
Cu 4: Cho 3,87gam hh X gm Mg v Al vo 250ml dd X gm HCl 1M v H2SO4 0,5M thu c dd B
v 4,368 lt H2(ktc). Phn trm khi lng Mg l A. 37,21%
B. 62,79% . C. 45,24% . D.
54,76%
Cu 5: Ho tan hon ton 15,8 gam hn hp Mg, Fe, Al trong dd H2SO4 long d thu c 13,44 lt kh
H2 (ktc) v dd X. Cho X tc dng vi dd NaOH thu c lng kt ta ln nht l m gam. Gi tr ca
m l
A. 20,6
B. 26,0.
C. 32,6.
D. 36,2.
Cu 6: Cho 5,35 gam hn hp X gm Mg, Fe, Al vo 250ml dung dch Y gm H2SO4 0,5M v HCl 1M
thu c 3,92lt kh (ktc) v dd A. C cn dd A trong iu kin khng c khng kh, thu c m gam
cht rn khan. Gi tr ca m l:
A. 20,900.
B. 26,225.
C. 26,375.
D. 28,600.
Cu 7: Chia m gam hn hp 2 kim loi X v Y c ho tr khng i thnh 2 phn bng nhau. Phn 1
ho tan ht trong dung dch H2SO4 long thu c 1,792 kt kh H2 (ktc). Phn 2 nung trong oxi n
khi lng khng i thu c 2,84 gam hn hp oxit. Gi tr ca m l: A. 1,56.
B. 2,20.
C. 3,12. D. 4,40.
Cu 8: Ho tan hon ton 2,17 gam hn hp 3 kim loi A, B, C trong dung dch HCl d thu c 2,24
lt kh H2 (ktc) v m gam mui. Gi tr ca m l:
A. 9,27.
B. 5,72.
C. 6,85.
D. 6,48.
Cu 9: t chy m g hn hp Al, Fe, Cu trong khng kh thu c m + 2,4 g cht rn X l cc oxit.
Dng 600 ml dung dch hn hp HCl 0,2M v H2SO4 0,15M ho tan hn hp X. Khi lng mui
thu c sau phn ng l:
A. m + 18,42
B. m + 17,42
C. m + 17,92
D. m + 12,9
Cu 10: Ho tan hon ton a gam hh X gm Fe v Fe2O3 trong dd HCl thu c 2,24 lt kh H2 (ktc)
v dd B. Cho dd B tc dng vi dd NaOH d, lc ly kt ta, nung trong khng kh n khi lng
khng i thu c 24 gam cht rn. Gi tr ca a l:
A. 13,6g
B. 17,6 g
C.
21,6g
D. 29,6g
Cu 11: Ha tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt
H2( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l
A. 3,92 lt.
B. 1,68 lt
C. 2,80 lt
D. 4,48 lt

Cu 6: Cho 2,54g hn hp Y gm 3 oxit FeO, MgO, Al2O3 tan va trong

300ml dung dch H2SO4 0,2M. C cn dung dch thu c m gam mui
khan. Gi tr ca m l:
A. 7,34g
B. 5,82g
C. 2,94g
D. 6,34g
V d 1: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10 %, thu c 2,24 lt kh H2 (
ktc). Khi lng dung dch thu c sau phn ng l:
A. 101,68 gam
B. 88,20 gam
C. 101,48 gam
D. 97,80 gam

V d 4: Cho 0,10 mol Ba vo dung dch cha 0,10 mol CuSO4 v 0,12 mol HCl. Sau khi cc phn ng xy ra hon ton, lc ly kt
ta nung nhit cao n khi lng khng i thu c m gam cht rn. Gi tr ca m l:
A. 23,3 gam
B. 26,5 gam
C. 24,9 gam
D. 25,2 gam
Cu 3: Ho tan ht hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c dung
dch Y. Nng ca FeCl2 trong dung dch Y l 15,757%. Nng phn trm ca MgCl2 trong dung dch
Y l
A. 11,787%. B. 84,243%.

C. 88,213%.

D. 15,757%.

Cu 13: Chia 16,9 gam hn hp Mg, Fe, Zn thnh 2 phn bng nhau. Phn 1 tc dng va vi dung
dch HCl, thu c 4,48 lt kh H2 (ktc). Phn 2 tc dng va vi dung dch H2SO4 long, thu c m
gam mui. Gi tr ca m l
A. 17,86.

B. 18,05.

C. 26,50.

D. 27,65.

Cu 17: Cho 6,88 gam hn hp X gm Mg, Na v Ca tc dng hon ton vi 200 ml dung dch Y gm HCl
1M v H2SO4 0,5M, thu c dung dch Z v 0,18 mol H2. C cn dung dch Z, thu c m gam cht rn
khan. Gi tr ca m l
A. 23,58.

B. 23,62.

C. 22,16.

D. 16,48.

b. Vi axit th hin tnh oxi ho bng gc axit trong mi trngH+ ( HNO3, H2SO4)
* Mt kim loi to mt sn phm kh:
Cu 12: hoa tan va ht 9,6 gam Cu cn phai dung V ml dung dich HNO3 2M, sau phan ng thu c
V1 lit khi NO ( ktc). Bit phan ng khng tao ra NH4NO3. Vy V va V1 co gia tri la:
A. 100 ml va 2,24 lit B. 200 ml va 2,24 lit C. 150 ml va 4,48 lit D. 250 ml va 6,72 lit
Cu 13: Cho 11,2 gam mt kim loai Z tan trong mt lng HNO3 va u, sau phan ng thu c dd A va
4,48 lit khi NO ( ktc) la san phm kh duy nht. C can dd A thu c mui khan co khi lng
bng:
A. 55,6 gam
B. 48,4 gam
C. 56,5 gam
D. 44,8 gam
Cu 14: Cho m gam Mg tan hoan toan trong dd HNO3, phan ng lam giai phong ra khi N2O (duy nht) va
dd sau phan ng tng 3,9 gam. Vy m co gia tri la:
A. 2,4 gam B. 3,6 gam
C. 4,8 gam
D. 7,2 gam
Cu 15: Ho tan hon ton 14,0 gam Fe trong 400ml dd HNO3 2M thu c dd X cha m gam mui v
kh NO (l sn phm kh duy nht). Gi tr ca m l
A. 48,4.
B. 60,5.
C.
51,2. D. 54,0.

* To hn hp sn phm kh
Cu 16: Ha tan ht 10,8 gam Al trong dd HNO3 d thu c hn hp khi X gm NO va NO2. Bit ti
khi cua X so vi H2 bng 19. Vy th tich cua mi khi trong hn hp X bng:
A. 4,48 lit ; 4,48 lit B. 6,72 lit ; 6,72 lit C. 2,24 lit ; 4,48 lit D. 2,24 lit ; 2,24 lit
Cu 17: Cho m gam Al tac dung va u vi 2,0 lit dd HNO3 aM thu c 5,6 lit hn hp khi X ( ktc)
gm N2O va khi Y ( sn phm kh khng cha mui amoni). Bit ti khi cua X so vi H2 bng 22,5.
a. Khi lng Al (m) em dung la: A. 10,125 gam
B. 10,800 gam
C. 8,100 gam
D. 5,4 gam
b. Gi tr ca a l
A. 0,4375
B. 0,5625
C. 0,75
D. 0,5
Cu 18: Ha tan hon ton 4,59 gam Al bng dung dch HNO3 thu c hh kh Z gm NO v N2O, Z c
t khi so vi Hiro bng 16,75. Vy th tch ca ca NO v N2O trong Z ln lt l:
A. 2,24 lt v 6,72 lt B. 2,016 lt v 0,672 lt
C. 0,672 lt v 2,016 lt
D. 1,972 lt v 0,448
lt

* Hn hp kim loi to mt sn phm kh

Cu 19: Cho 38,7 gam hn hp kim loai Cu va Zn tan ht trong dung dich HNO3, sau phan ng thu c
8,96 lit khi NO ( ktc) va khng tao ra NH4NO3. Vy khi lng cua mi kim loai trong hn hp se
la:
A. 19,2 g va 19,5 g B. 12,8 g v 25,9 g C. 9,6 g va 29,1 g
D. 22,4 g va 16,3 g
Cu 20: Cho 1,86 gam hn hp kim loai gm Mg va Al tan ht trong dd HNO3 thu c 560 ml khi N2O
( ktc) thoat ra va dung dich A (khng cha mui amoni). C can dd A thu c lng mui khan
bng:
A. 41,26 gam
B. 14,26 gam
C. 24,16 gam
D. 21,46 gam

Cu 21: Ho tan hon ton 10,4 gam hn hp A gm Fe v kim loi R (c ha tr khng i) bng dung
dch HCl thu c 6,72 lt H2 (ktc). Mt khc, nu cho A tc dng hon ton vi dung dch HNO3
long d th thu c 1,96 lt N2O duy nht (ktc) v khng to ra NH4NO3. Kim loi R l: A. Al.
B. Mg. C. Zn. D. Ca.
Cu 22: Ho tan 23,4 gam G gm Al, Fe, Cu bng mt lng va dd H2SO4 c, nng, thu c 15,12
lt kh SO2 (ktc) v dd cha m gam mui. Gi tr ca m l
A. 153,0.
B. 95,8.
C.
88,2. D. 75,8.

* Hn hp kim loi to hn hp sn phm kh

Cu 23: Ho tan hh gm Mg, Al, Zn trong V lt dd HNO3 2M va thu c 1,68lit hh kh X (ktc)
gm N2O v N2. T khi ca X so vi H2 l 17,2. Gi tr ca V l A. 0,42.
B. 0,84.
C.
0,48. D. 0,24.
Cu 24: Cho 3,76 gam hn hp X gm Mg, Fe, Cu tc dng vi dung dch HNO3 d thu c 1,344 lt
kh NO (ktc) v dung dch Y. Cho Y tc dng vi dung dch NaOH d thu c m gam kt ta. Gi tr
ca m l
A. 7,84.
B. 4,78.
C. 5,80.
D. 6,82.
Cu 25: Cho 18,2 gam hn hp A gm Al, Cu vo 100 ml dd B cha HNO3 2M v H2SO412M v un
nng thu c dd C v 8,96 lt hn hp kh D (ktc) gm NO v SO2, t khi ca D so vi H2 l 23,5.
Khi lng ca Al trong 18,2 gam A l
A. 2,7g.
B. 5,4g.
C.
8,1g.
D. 10,8g.
Cu 26: Cho 1,35 gam hh gm Mg, Al, Cu tac dung ht vi HNO3 thu c hh khi gm 0,01 mol NO va
0,04 mol NO2. C can dd sau phan ng thu c hh mui vi khi lng la:
A. 5,69 gam
B. 5,5 gam
C. 4,98 gam
D. 4,72 gam
* Kim loi phn ng vi NO3- trong mi trng H+.
Cu 27: Thc hin 2 th nghim sau:
1. Cho 9,6 g Cu tc dng vi 180 ml dd HNO3 1M thu c V1 l kh NO v dd A.
2. Cho 9,6 g Cu tc dng vi 180 ml dd hn hp gm HNO3 1M v H2SO4 0,5M (long) th thu c V2 lt kh
NO v dd B. Quan h gia V1 v V2 l:
A. 2V1 = V2
B. V1 = 2V2
C. 0,5V1 = V2
D. V1 = V2
Cu 28: Cho 11,28 gam hn hp A gm Cu, Ag tc dng va vi 200ml dung dch B gm HNO3 1M
v H2SO4 0,2M thu c kh NO duy nht v dung dch C cha m gam cht tan. Gi tr ca m l
A. 19,34.
B. 15,12.
C. 23,18.
D. 27,52.
Cu 29: Cho m g hn hp X gm Zn, Fe, Mg vo dung dch HCl d thu c dung dch Y. thm tip
KNO3 d vo dung dch Y th thu c 0.672l kh NO duy nht (ktc). Vy khi lng Fe c trong mg
hn hp X l:
A. 1.68g
B. 3.36g
C. 5.04g
D. 6.72g
Cu 30: Dung dch X c cha 0.4 mol HCl v 0.12 mol Cu(NO3)2. Khi thm m g bt Fe vo dung dch X,
sau khi kt thc thu dc hn hp kim loi c khi lng ) bng 5 m. Gi tr ca m l:
A. 1,92g
B. 20,48g
C. 9,28g
D. 14,88g
V d 7: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau
khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo
dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l:
A. 360 ml
B. 240 ml
C. 400 ml
D. 120 ml

Bi 2. Cho 1,92 gam Cu vo 100 ml dung dch cha ng thi KNO3 0,16 M v H2SO4 0,4 M thy sinh ra
mt cht kh X c t khi hi so vi H2 bng 15 v dung dch Y. Th tch dung dch NaOH
0,5 M ti thiu cn dng kt ta ton b cation Cu2+ trong dung dch Y
A. 0,032 lt
B. 0,32 lit
C. 0,0128 lt
D. 0,128 lit
Cau 3. (HKB 2010) Cho 0,3 mol bot Cu va 0,6 mol Fe(NO3)2 vao dung dch cha
0,9 mol H2SO4
(loang). Sau khi cac phan ng xay ra hoan toan, thu c V lt
kh NO (san pham kh duy
nhat, ktc). Gia tr cua V la
A. 6,72
B. 8,96
C. 4,48
D. 10,08
Cu 4 (HKA 2011) Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc
phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th
khi lng mui khan thu c l
A. 20,16 gam.
B. 19,76 gam.
C. 19,20 gam.
D. 22,56 gam.

Cu 5 (HKB 2011) Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml

dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a
mol kh NO
(sn phm kh duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O2 thu c hn
hp kh Y. Cho ton
b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z
l:
A. 1
B. 3
C. 2
D. 4 .
* Trng hp to mui amoni
Cu 31: (KA 09) Ha tan hon ton 12,42 gam Al bng dd HNO3 long (d), thu c dd X v 1,344 lt
( ktc) hh kh Y gm hai kh l N2O v N2. T khi ca hh kh Y so vi kh H2 l 18. C cn dd X, thu
c m gam cht rn khan. Gi tr ca m l
A. 97,98.
B. 106,38. C. 38,34.
D.
34,08.
Cu 32: ( KB 08) Cho 2,16 gam Mg tc dng vi dd HNO3 (d). Sau khi phn ng xy ra hon ton thu
c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung
dch X l
A. 13,32 gam.
B. 6,52 gam.
C. 8,88 gam.
D. 13,92 gam.
Cu 3. Cho m gam Al tc dng vi 0,5 lt dung dch HNO3 0,5M thu c dung dch X v 0,448 lit (ktc) hn
hp Y gm N2O v NO. T khi ca hn hp Y so vi H2 l 18,5. Cho dung dch Y tc dng vi NaOH d thy
thot ra 112 ml kh (ktc). Gi tr ca m l
A. 0,99 gam
B. 1,35 g
C. 1,035 g
D. 2,025 g

* Tng hp
Al (NO 3 )3 + N 2O + N
Cu 33: Cho phng trinh phan ng sau: Al + HNO 3
2 + H O
2
Nu ti l mol cua N2O va N2 la 2:3 thi sau khi phan ng c cn bng thi h s cua Al, N2O va N2 la:
A. 23 : 8 : 6
B. 46 : 6 : 9
C. 46 : 2 : 3
D. 20 : 2 : 3
Cu 34: Vng cng nh bch kim ch b ha tan trong nc cng toan (vng thy), l dd gm mt
th tch HNO3 v ba th tch HCl m c. 34,475 gam thi vng c ln tp cht tr c ha tan ht
trong nc cng toan, thu c 3,136 lt kh NO duy nht (ktc).Phn trm khi lng vng c trong
thi vng trn l:
A. 90%
B. 80%
C. 70%
D. 60%
Cu 35: Cho 5,76 g Cu tc dng vi 100ml dung dch A cha HNO3 1M; HCl 0,5M; H2SO4 0,4M. Hi
sau khi c cn dung dch sau phn ng thu c nhng mui g:
A. CuSO4
B. Cu(NO3)2
C. CuSO4; Cu(NO3)2
D. CuSO4; Cu(NO3)2;
CuCl2
Cu 36: Cho 7,6g hn hp gm Fe v 3 oxit Fe tc dng vi HNO3 va to ra dung dch A cha 1
mui St III v 1,12l NO (ktc). C cn A c bao nhiu g mui Fe3+:
A. 26,62
B. 32,84
C. 12,1
D. 24,2
Cu 37: em nung hn hp A gm 2 kim loi: x mol Fe v 0,15 mol Cu trong khng kh mt thi gian,
thu c 63,2g hn hp B gm 2 kim loi trn v hn hp cc oxit ca chng. em ho tan ht lng
hn hp B bng dung dch H2SO4 c nng d th thu c 0,3 mol SO2. x l:
A. 0,6 mol
B. 0,4 mol
C. 0,7 mol
D. 0,5 mol
Cu 38: Cho m g hn hp gm FeCO3 v Fe phn ng vi 1 l dung dch HNO3 (a mol/l) thu c hn
hp kh A gm 2 kh c t khi so vi H2 bng 22,8 v dung dch B. Cho dung dch B phn ng vi
dung dch NaOH. Lc kt ta nung n khi lng khng i thu c 24 g cht rn. Tnh a v m:
A. 1,5M v 28,8 g
B. 1,6M v 28,8g
C. 1,4M v 22,8g
D. 1,5M v 25,8g
Cu 39: (H KB 2009)Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu
c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c
m gam mui sunfat khan. Gi tr ca m l A. 52,2.
B. 48,4.
C. 54,0.
D. 58,0.

H Khi B 2009
Cu 40: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau
khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm
kh duy nht, ktc). Gi tr ca m v V ln lt l
A. 17,8 v 4,48.
B. 17,8 v 2,24.
C. 10,8 v 4,48.
D. 10,8 v 2,24.
Cu 41: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dd HNO3 long, un nng v khuy
u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc),
dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca
m l
A. 151,5.
B. 97,5.
C. 137,1.
D. 108,9.

Cu 42: Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dd HNO3 c, nng thu c 1,344 lt
kh NO2 (sn phm kh duy nht, ktc) v dd Y. Sc t t kh NH3 (d) vo dd Y, sau khi phn ng
xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr
ca m ln lt l
A. 21,95% v 0,78
B. 78,05% v 0,78 C. 78,05% v 2,25
D. 21,95% v 2,25

H Khi A 2009
Cu 43: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh
NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A. NO v Mg.
B. N2O v Al
C. N2O v Fe.
D. NO2 v Al.
Cu 44: Cho 6,72 gam Fe vo 400ml dd HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO
(sn phm kh duy nht) v dung dch X. Dung dch X c th ha tan ti a m gam Cu. Gi tr ca m l
A. 1,92.
B. 0,64.
C. 3,84.
D. 3,20.

H Khi B 2008
Cu 45: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra
3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo lng d axit nitric (c ngui), sau khi kt
thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 15,6.
B. 11,5.
C. 10,5.
D. 12,3.
Cu 46: Th tch dung dch HNO3 1M (long) t nht cn dng ha tan hon ton mt hn hp gm
0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 0,6 lt.
B. 1,2 lt.
C. 0,8 lt.
D. 1,0 lt.
Cu 47: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3
long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung
dch X thu c m gam mui khan. Gi tr ca m l
A. 49,09.
B. 34,36.
C. 35,50.
D. 38,72.
Cu 48: (KA 08)Cho 3,2 gam bt Cu tc dng vi 100 ml dd hn hp gm HNO3 0,8M v H2SO4
0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht,
ktc).Gi tr ca V l :
A. 0,746.
B. 0,448.
C. 0,672.
D. 1,792.
Cu 49: C 2008Chia m gam Al thnh hai phn bng nhau:
- Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh H2;
- Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm kh
duy nht). Quan h gia x v y l : A. x = 2y.
B. y = 2x.
C. x = 4y.
D. x = y.
Cu 50: C 2008Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X
A. N2O.
B. NO2.
C. N2.
D.
(sn phm kh duy nht, ktc). Kh X l :
NO.
Cu 51: C 2009 Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu
c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ho nu
trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng
c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l
A. 12,80%
B. 15,25%
C. 10,52%
D. 19,53%

3) Dng 3: Kim loi tc dng vi dd mui

1. Nhng mt l kim loi M (ha tr II) nng 56 gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng
xy ra hon ton. Lc dung dch, em c cn c 18,8 gam mui khan. Kim loi M l A. Mg
B. Zn
C. Cu
D. Fe
Cu 52: (KB 09)Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M
v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi
thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 2,16 gam
B. 0,84 gam
C. 1,72 gam
D. 1,40 gam
Cu 3. Cho m(gam) hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc
b dung dch thu c m (gam) cht rn. Thnh phn % theo khi lng ca Zn trong hn hp ban u l
A. 90,27%
B. 82,20%
C. 85,30%
D. 12,67%
Cu 4. Nhng 1 inh st vo 150 ml dung dch CuSO4. Sau khi phn ng xy ra hon ton, ly inh st sy kh,
thy khi lng tng ln 1,2 gam. Vy nng ban u ca CuSO4 l
A. 1M
B. 1,5M
C. 2M
D. 0,5M

Cu 5. Ngm 1 vt bng Cu c khi lng 15 gam trong 340 gam dung dch AgNO3 6%. Sau mt thi gian ly
vt ra thy lng AgNO3 trong dung dch gim 25%. Khi lng ca vt sau phn ng l
A. 3,24 g
B. 2,28 g
C. 17,28 g
D. 24,12 g
Cu 53: Nhng thanh kim loi M ho tr 2 vo dd CuSO4, sau 1 thi gian ly thanh kim loi ra thy khi
lng gim 0,05%. Mt khc,nhng thanh kim loi trn vo dung dch Pb(NO3)2, sau mt thi gian thy
khi lng tng 7,1%. Bit rng s mol CuSO4 v Pb(NO3)2 tham gia hai trng hp l nh nhau.
Kim loi M l
A. Zn
B. Fe
C. Mg
D. Ni
V d 1: Nhng mt thanh kim loi M ha tr II nng m gam vo dung dch Fe(NO3)2 th khi lng thanh kim loi gim 6 % so vi
ban u. Nu nhng thanh kim loi trn vo dung dch AgNO3 th khi lng thanh kim loi tng 25 % so vi ban u. Bit gim
s mol ca Fe(NO3)2 gp i gim s mol ca AgNO3 v kim loi kt ta bm ht ln thanh kim loi M. Kim loi M l:
A. Pb
B. Ni
C. Cd
D. Zn

Cu 54: Ho tan 0,72g bt Mg vo 200ml dung dch hn hp AgNO3 0,15M v Fe(NO3) 0,1M. Khuy
u n khi phn ng xy ra hon ton thu c m (gam) cht rn. Gi tr ca m l:
A. 3,52g
B. 3,8g
C. 3,36g
D. 4,36g
Cu 55: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M.
Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l
A. 2,80.
B. 4,08.
C. 2,16.
D. 0,64.
Cu 56: Cho 11,34g Al vo 300 ml dd hn hp gm FeCl3 1,2M v CuCl2 a M sau khi phn ng kt thc
thu c dd X v 21,9g hn hp hai kim loi. a c gi tr l:
A. 0,4
B. 0.5 C. 0,8.
D. 1
Cu 57: Cho 6,72g Fe tc dng vi 384ml dd AgNO3 1M sau khi phn ng kt thc thu c dd A v m
gam cht rn. dd A tc dng ti a vi bao nhiu gam Cu?
A. 4,608
B. 9,600
C.
7,680 D. 6,144
Cu 58: ( KB 08)Cho mt lng bt km vo dd Z gm FeCl2, CuCl2. Khi lng cht rn sau khi cc
phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau
phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l
A. 13,1 gam.
B. 17,0 gam.
C. 19,5 gam.
D. 14,1 gam.
Cu 59: ( KA 08)Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M.
Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong
3+ 2+
+
dy th in ho: Fe /Fe ng trc Ag /Ag) A. 64,8.
B. 54,0.
C.
59,4.
D. 32,4.
Cu 60: Cho 1,152g hn hp Fe, Mg tc dng vi dd AgNO3 d. Sau khi phn ng xong thu c 8,208g
kim loi. Vy % khi lng Mg l
A. 63,542% B. 41,667% C. 72,92%
D. 62,50%
Cu 61: Cho m gam hn hp bt cc kim loi Ni v Cu vo dung dch AgNO3 d. Khuy k cho n khi phn ng kt thc
thu c 54 gam kim loi. Mt khc cng cho m gam hn hp bt cc kim loi trn vo dung dch CuSO4 d, khuy k cho
n khi phn ng kt thc, thu c kim loi c khi lng bng (m + 0,5) gam. Gi tr ca m l:
A. 15,5 gam
B. 16 gam
C. 12,5 gam
D. 18,5 gam
Cu 62: Ha tan hn hp bt kim loi gm 8,4 gam Fe v 6,4 gam Cu vo 350 ml dung dch AgNO3 2M. Sau khi phn ng
xy ra hon ton thu c m gam cht rn. Gi tr ca m l:
A. 70,2 gam
B. 54 gam
C. 75,6 gam
D. 64,8 gam

Cu 63: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu
c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 long d. Sau khi cc
phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c chit cha mt mui
duy nht. Phn trm khi lng ca Fe trong X l
A. 58,52%

B. 51,85%

C. 48,15%

D. 41,48%

V d 5: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi cc phn ng xy ra hon
ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn:
A. 1,8
B. 1,5
C. 1,2
D. 2,0

Cu 64: Cho m (g) hn hp Y gm 2,8g Fe v 0,81g Al vo 200ml dd C cha AgNO3 v Cu(NO3)2. Khi
phn ng kt thc c dd D v 8,12g rn E gm 3 kim loi. Cho rn E tc dng vi dd HCl d th
c 0,672 lt H2(ktc). Tnh nng mol cc cht trong dung dch C.
A. [AgNO3]=0,15M, [Cu(NO3)2]=0,25M
B. [AgNO3]=0,1M, [Cu(NO3)2]=0,2M

C. [AgNO3]=0,5M, [Cu(NO3)2]=0,5M
D. [AgNO3]=0,05M, [Cu(NO3)2]=0,05M
Cu 65: Cho 100 gam ddX gm Cu(NO3)2 11,28% v AgNO3 3,4%. Cho 3,14 gam bt Zn v Al vo
ddX. Sau khi phn ng xong thu c cht Y v ddZ (cha 2 mui). Ngm cht rn Y trong H2SO4 long
khng c kh thot ra. Tnh % khi lng mi kim loi.
A. 17,2 v 82,8
B. 12,7 v 87,3
C. 27,2 v 72,8
D. 38,2 v 61,8
Cu 66: Cho 1,3365g hn hp gm Mg v Zn tan va trong 2,5 lt dung dch A gm CuSO4 0,01M v
Ag2SO4 0,001M. Sau khi phn ng xong thu c dung dch B v cht rn C. Tnh % khi lng mi
kim loi?
A. 19,75% v 80,25%
B. 19,57% v 80,43%
C. 57,19% v 42,81%
D. p n
khc.
Cu 67: Cho 3,76g hn hp kim loai Al va Ni ti l mol (3:5) vao 0,2 lit dd co AgNO3 va Cu(NO3)2. Sau
khi phan ng xong thu c 8,21g hn hp X gm 3 kim loai . Cho X vao dd HCl d thi co 0,672 lit H2
thoat ra (ktc). Tinh nng mol mui nitrat ban u
Cu 68: Cho 8,3g hn hp X gm Al, Fe (nAl = nFe) vo 100ml dung dch Y gm Cu(NO3)2 v AgNO3,
sau khi phn ng kt thc thu c cht rn A gm 3 kim loi. Ho tan A vo dung dch HCl d thy
c 1,12 l kh thot ra (ktc) v cn li 28g cht rn khng tan B. Nng CM ca Cu(NO3)2 v AgNO3
trong dung dch Y l:
A. 2M v 1M
B. 1M v 2M
C. 0,2M v 0,1M
D. 0,2M v 0,3M
Cu 69: Cho hn hp X gm 3,6g Mg v 5,6g Fe vo 1 lt dd Y cha AgNO3 0,1M v Cu(NO3)2 0,15M.
sau phn ng thu c cht rn C v dd D. Thm NaOH d vo dd D c kt ta, em nung kt ta
ny ngoi khng kh c cht rn E. Tnh khi lng C v E.(s: mc=23,2g; mE=10g)
Cu 20: Chia 23,8 gam hn hp X gm Al v Zn thnh 2 phn bng nhau. Phn 1 cho tc dng ht vi
dung dch HCl, thu c 8,96 lt kh H2 (ktc). Phn 2 cho tc dng vi 300 ml dung dch Y cha Cu(NO3)2
1M v AgNO3 1M n khi phn ng hon ton th thu c cht rn Z. S lng kim loi trong Z l
A. 4.

B. 3.

C. 2.

D. 1.

Cu 70: Cho m gam bt Fe vo dung dch cha 0,16 mol Cu(NO3)2 v 0,4 mol HCl, lc cho cc phn
ng xy ra hon ton. Sau phn ng thu c hn hp kim loi c khi lng bng 0,8m gam v V(l)
kh duy nht khng mu ho nu ngoi khng kh. Gi tr ca m v V l:
A. 17,36g v 2,24 l B. 35,6g v 2,24 l
C. 11,2g v 4,48 l
D. 36,5g v 4,48 l
Dng 4: Kh oxit kim loi bng CO, H2
Cu 71: Nung nng 38,3 gam hn hp PbO v CuO vi mt lng CO va , lng kh sinh ra dn vo
dd nc vi trong d thu c 30g kt ta. Khi lng ca PbO trong hn hp l
A. 24g.
B. 26g
C. 22,3g
D. 15,3g
Cu 72: Kh 32g Fe2O3 bng CO d, dn sn phm kh sinh ra vo bnh nc vi trong d thu c a
gam kt ta. Gi tr ca a l?
A. 60g
B. 55g.
C. 65g
D. 45g
Cu 73: Cho 32g oxit st tc dng hon ton vi kh cacbon monooxit th c 22,4g st. CTPT ca oxit
st l?
A. FeO.
B. Fe2O3.
C. Fe3O4.
D. Fe3O2.
Cu 74: Kh mt oxit st bng CO nhit cao, phn ng xong ngi ta thu c 0,84g Fe v 448ml
CO2 (o ktc). Cng thc phn t oxit st l cng thc no sau y:
A. FeO
B. Fe2O3.
C. Fe3O4.
D. Fe4O3
Cu 75: Thi t t V lt hn hp kh gm CO v H2 i qua ng ng hn hp gm CuO, Al2O3, Fe3O4 .
Sau phn ng thu c hn hp kh v hi c khi lng ln hn khi lng hn hp CO v H2 ban
u l 0,32g. V (ktc) c gi tr l? A. 0,224 lt.
B. 0,336lt.
C. 0,448 lt
D. 0,672 lt.
Cu 76: Thi mt lung khi CO d qua ng x ng hn hp Fe3O4 v CuO nung nng n kh phn ng
hon ton, ta thu c 2,32g hn hp kim loi. Kh thot ra c dn vo bnh ng nc vi trong d
c 5 g kt ta trng. Khi lng hn hp hai oxit ban u l?
A. 3,12g
B. 3,22g
C. 4g
D. 4,2g
Cu 77: Dn mt lung kh CO i qua ng s c cha m g hn hp rn X gm CuO v Fe2O3 un nng.
Sau mt thi gian ng s cn li n g hn hp rn Y. Kh thot ra c hp th bng dung dch Ca(OH)2
d thu c p g kt ta. Lp biu thc lin h gia m, n, p:
A. m = n 0,16p
B. m = n + 0,16p
C. n = m + 0,16p
D. n = m 0,32p

Cu 5: Ly x gam X gm Fe2O3, Fe3O4, FeO cho vo mt ng s, nung nng ri cho 1 lung kh CO i

qua, ton b kh CO2 sinh ra c hp th ht vo dung dch Ba(OH)2 d, thu c y gam kt ta. Cht rn
cn li trong ng s c khi lng 19,200 gam gm Fe, FeO v Fe3O4, Fe2O3. Gi tr ca x v y tng ng l
A. 20,880 v 20,685.
C. 18,826 v 1,970.

B. 20,880 v 1,970.
D. 18,826 v 20,685.

Cu 6: Dn lung kh CO qua m gam Fe 3O4 nung nng, thu c cht rn X gm FeO v Fe. ho tan
ht X, cn 300ml dung dch HCl 2M. Gi tr ca m l
A. 46,4.

B. 23,2.

C. 34,8.

D. 69,6.

Cu 7: Nung nng 58,2 gam hn hp X gm CuO, Fe2O3 v Al2O3, ri dn kh CO d i qua n khi phn
ng hon ton, thu c 45,4 gam cht rn Y. Cho Y tc dng ht vi dung dch HNO3, thu c sn phm
kh duy nht l V lt kh N2O (ktc). Gi tr ca V l:
C. 4,48.

A. 2,24.

B. 8,96.

D. 17,92.

Cu 8: Cho hn hp A gm 0,1 mol Fe v 0,2 mol Fe 2O3 vo trong mt bnh kn dung tch khng i
11,2 lt cha CO (ktc). Nung nng bnh 1 thi gian, sau lm lnh ti 0oC. Hn hp kh trong bnh lc
ny c t khi so vi H2 l 15,6. S gam cht rn cn li trong bnh sau khi nung l
A. 20,4.

B. 35,5.

C. 28,0.

D. 36,0.

Cu 10: Hn hp X gm CuO v MO theo t l mol tng ng l 1: 2 (M l kim loi ha tr khng i). Cho
1 lung H2 d i qua 2,4 gam X nung nng, thu c hn hp cht rn Y. ho tan ht Y cn 40 ml dung
dch HNO3 2,5M v thu c sn phm kh l kh NO duy nht. Hiu sut cc phn ng t 100%. Kim loi
M l
A. Ca.

B. Mg.

C. Zn.

D. Pb.

Cu 11: ho tan hon ton hn hp X gm Fe2O3, Fe3O4, FeO, cn dng 400 ml dung dch H2SO4 1M.
Nu kh hon ton lng hn hp X trn (nung nng), cn V lt hn hp kh gm CO v H2. Gi tr ca V l
A. 2,24.

B. 4,48.

C. 8,96.

D. 17,92.

Cu 13: Kh hon ton mt oxit ca kim loi M cn dng 1,344 lt H2(ktc). Ton b lng kim loi M sinh ra
cho tc dng vi dung dch HCl d thu c 1,008 lt H2 (ktc). Cng thc oxit l
A. Fe3O4.

B. Fe2O3.

C. FeO.

D. ZnO

Cu 14: Kh hon ton 32,20 gam hn hp gm CuO, Fe 2O3 v ZnO bng CO nhit cao thu c
25,00 gam hn hp X gm 3 kim loi. Cho X tc dng va vi dung dch HNO3 th thu c dung dch
cha m gam mui (khng cha NH4NO3). Gi tr ca m l
A. 52,90.

B. 38,95.

C. 42,42.

D. 80.80.