BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

CHNG 3: AMIN, AMINO AXIT V PROTEIN A. BI TP L THUYT TRC NGHIM 1. Khng nh no sau y lun ng? A. Tnh baz ca amin tng dn theo th t : bc I < bc II < bc III. B. Tnh baz ca anilin l do nhm NH2 nh hng ln gc C6H5. C. V c tnh baz nn anilin lm i mu cht ch th mu. D. Do nh hng ca nhm C6H5 lm gim mt e trn nit nn anilin c tnh baz yu. 2. Bc ca amin phu thuc vao A. Bc ca nguyn t cacbon mang nhom -NH2. B. Ha tr ca nit . C. S nguyn t H trong NH3 a c thay bng gc hidro cacbon. D. S nhm NH2 . 3. Nhn nh no sau y khng ng v anilin? A. Tnh baz ca anilin yu hn NH3 do gcC6H5 hut e nn lm gim mt e trn nguyn t nit. B. Nh c tnh baz, anilin tc dng c vi dung dich Brom. C. Anilin khng tc dng c vi dung dich NaOH. D. Anilin t tan trong nc v rt c. 4. S ng phn amin bc II ca C4H11N l A. 1 B. 2 C. 3 D. 4 5. Vi cc cht amoniac (1), metylamin (2), etylamin (3), anilin (4). Tnh baz tng dn theo trnh t A. (4) < (1) <(2) < (3) B. (4) < (1) < (3) < (2) C. (3) < (2) < (1) <(4) D. (3) < (2) < (4) < (1) 6. Cho vi git anilin vo nc, sau thm dung dich HCl (d) vo, ri li nh tip dung dch NaOH vo, s xy ra hin tng: A. Lc u dung dich b vn c, sau trong sut v cui cng b vn c li. B. Lc u dung dich trong sut, sau b vn c v cui cng tr li trong sut. C. Dung dch trong sut. D. Dung dch b vn c hon ton. 7. phn bit anilin v etylamin ng trong 2 lo ring bit, ta dng thuc th no su y? A. Dung dch Br2 B. Dung dich HCl C. Dung dich NaOH D. Dung dich AgNO3 8. Vi s phn ng bn di th cht B l cht no?
HNO3,(1 mol) Fe, HCl (d) NaOH C6H6------------------->A--------------->B ------------->C H2SO4, a c

A. Nitro benzen B. anilin C. Natri phenolat D. Mt loi mui clorua 9. Theo s phn ng sau: t0 HNO 3, H 2 SO 4 t0 Fe , HCl , du CH4 A B C D. A, B, C, D ln lt l C 1:1 A. C2H2, C6H6, C6H5NO2, C6H5NH2 B. C2H2, C6H6, C6H5NO2, C6H5NH3Cl C. C2H4, C6H6, C6H5NH2, C6H5NH3Cl D. C6H6, C6H5NO2, C6H5NH2, C6H5NH3Cl 10. phn bit phenol, anilin, benzen bng phng phap hoa hoc, ta cn dung cac hoa cht la: A. Dung dich Brm, Na B. Qui tim C. Kim loai Na D. Qui tim, Na. 11. C 3 cht hu c : H2N-CH2-COOH; CH3-CH2-COOH v CH3-CH2-CH2-NH2. nhn ra dung dch ca cc hp cht trn, ngi ta ch cn th vi mt cht no trong cc cht sau y? A. NaOH B. HCl C. CH3OH/HCl D. Qu tm 12. chng minh glyxin C2H5O2N l mt amino axit, ch cn cho phn ng vi A. HCl B. NaOH C. CH3OH/HCl D. Hai phn ng A v B 13. Cho cc cht sau y: 1. H2N-CH2-CH2-COOH 2. CH2 = CH-COOH 3. CH2O v C6H5OH 4. HO-CH2-COOH Cc trng hp no c kh nng tham gia phn ng trng ngng ? A. 1,2,3 B.1,2,4 C. 1,3,4 D. 2,3,4 14. iu khng nh no sau y khng ng? A. Khi lng phn t ca mt amino axit (gm mt chc NH2 v mt chc COOH) lun l s l B. Hp cht amino axit phi c tnh lng tnh C. Dung dch amino axit khng lm giy qu tm i mu 1

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

D. Thu phn protit bng axit hoc kim s cho mt hn hp cc amino axit 15. Cho dung dch cha cc cht sau: C6H5 NH2 (X1); CH3NH2 (X2); H2N - CH2 - COOH (X3); HOOC - CH2- CH2- CH(NH2)- COOH (X4); H2N - (CH2)4- CH(NH2)- COOH (X5) C. X2 ; X5. D. X3 ; X4 ; X5. 16. Khi thy phn H2N-CH2-CO-NH-CH-CO-NH-CH2-COOH s to ra CH3 A. H2N-CH2-COOH ; CH3-CH-COOH v H2N-CH2-CH2-COOH NH2 B. H2N-CH2-COOH v CH3-CH-COOH NH2 C. CH3-CH-COOH D. CH3-CH2-CH-COOH NH2 NH2 17. Mt hp cht hu c X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dung dch NaOH v HCl. Cht hu c X c cng thc cu to l A. H2N-CH=CH-COOH B. CH2=CH-COONH4 C. H2N-CH2-CH2-COOH D. A v B ng 18. Trong cc cht sau, cht no lm qu tm chuyn sang mu hng? A. H2N-CH2-COOH B. H2N-CH2-CH2-CH(NH2)-COOH C. CH3-CH2-NH2 D. HOOC-CH2-CH2-CH(NH2)-COOH 19. Hp cht no sau y khng phi l amino axit ? A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH C. CH3-CH2-CO-NH2 D. HOOC-CH2-CH(NH2)-COOH 20. Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. 21. Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. 22. Tn gi ca amino axit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC.(CH2)2-CH(NH2)-COOH (axit glutaric) 23. Khng nh no sau y khng ng v tnh cht vt l ca amino axit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan trong nc. D. Tt c u c nhit nng chy cao. 24. Cho glixin (X) phn ng vi cc cht i y, trng hp no PTHH c vit khng ng? A. X + HCl ClH3NCH2COOH B. X + NaOH H2NCH2COONa C. X + CH3OH + HCl ClH3NCH2COOCH3 + H2O D. X + HNO2 OHCH2COOH + N2 + H2O 25. Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Glixinalaninglyxin B. Glixylalanylglyxin C. Alaningyxylalanin D. Alanylglyxylglyxyl 26. Pht biu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protit gm cc mch di polipeptit to nn. C. Protit rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh. 2 Nhng dung dch lm giy qu tm ho xanh l A. X1 ; X2 ; X5. B. X2 ; X3 ; X4.

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

27. Trong cc cht sau Cu, HCl, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. C. Cu, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. 28. - amino axit l amino axit m nhm amino gn cacbon v tr th my? A. 1 B. 2 C. 3 D. 4 29. Cho cc cht H2N-CH2-COOH (X); H3C-NH-CH2-CH3 (Y); CH3-CH2-COOH (Z); C6H5-CH(NH2)COOH (T); HOOC.CH2-CH(NH2)-COOH (G); H2N-CH2-CH2-CH2-CH(NH2)-COOH (P). Amino axit l A. X, Z, T, P B. X, Y, Z, T C. X, Z, G, P D. X, Y, G, P. 30. Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)-COOH 31. Cho dd qu tm vo 2 dd sau: (X) H2N-CH2-COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng i mu, Y ha . D. X, Y lm qu ha 32. Khi un nng, cc phn t -alanin (axit -aminopropionic ) c th tc dng vi nhau to ra cc [-NH-CH- CO-]n [-CH2-CH- CO-]n [ -CH2-CH- CH2-]n sn phm no di y: COOH NH2 CH3 A. [-NH-CH2- CO-]n B. C. D. 33. Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl 34. Mt amino axit c mt nhm -NH2 v mt nhm -COOH v c cng thc phn t l C4H9O2N. Amino axit ny c bao nhiu cng thc cu to ca cc ng phn? A. 3 B. 4 C. 5 D. 6 35. Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -amino axit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l ipeptit, 3 nhm -CO-NH- c gi l tripeptit C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc amino axit c sp xp theo mt th t xc nh. 36. Alanin khng tc dng vi A. CaCO3 B. C2H5OH C. H2SO4 long D. NaCl 37. C s phn ng sau C3H7O2N + NaOH CH3-OH + (X) Cng thc cu to ca (X) l A. H2N-CH2-COOCH3 B. CH3- CH2-COONa C. H2N-CH2-COONa D. H2N-CH2-CH2-COOH 38. Hp cht no khng lng tnh? A. Amoni axetat B. Alanin C. Etyl amin D. Amino axetat metyl 39. Cho s d phn ng sau:
axit

Amino axit (Y) + CH3OH

o

C3H7O2N + H2O

Amino axit (Y) l

t A. H2N-CH2-CH2-COOH B. H2N-CH2-COOCH3 C. CH3-CH(NH2)-COOH C. H2N-CH2-COOH 40. Cho cc cht: (1)amoniac. (2)metylamin. (3)anilin. (4)dimetylamin. Tnh baz tng dn theo th t no sau y? A. (1) < (3) < (2) < (4). B. (3) < (1) < (2) < (4). C. (1) < (2) < (3) < (4). D. (3) < (1) < (4) < (2) 3

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

41. Cho cc cht: C6H5NH2, C6H5OH, CH3NH2, CH3COOH. Cht no lm i mu qu tm sang mu xanh? A. CH3NH2 B. C6H5NH2, CH3NH2 C. C6H5OH, CH3NH2 D. C6H5OH, CH3COOH 42. Cht no l amin? (1) CH3-NH2; (2) CH3-NH-CH2-CH3; (3) CH3-NH-CO-CH3; (4) NH2-(CH3)2-NH2;
(5) (CH3)2NC6H5; (6) NH2-CO-NH2; (7) CH3-CO-NH2; (8) CH3-C6H4-NH2

A. 1, 2, 5 B. 1, 5, 8 C. 1, 2, 4, 5, 8 D. 3, 6, 7 43. Pht biu nao sau y sai? A. Cc amin u c tnh baz. B. Tnh baz ca cc amin u mnh hn NH3. C. Anilin c tnh baz rt yu. D. Amin co tinh baz do N co cp electron t do. 44. Hp cht C4H11N c bao nhiu ng phn amin? A. 6 B. 7 C. 8 D. 9 45. Amin c tnh baz do: A. Amin tan nhiu trong nc B. C nguyn t N trong nhm chc C. Nguyn t N cn cp e t do c th nhn proton D. Phn t amin c lin kt hiro vi H2O 46. Cc amino axit no c th phn ng vi tt c cc cht trong nhm no sau y? A. Dng dd NaOH, dd HCl, C2H5COOH, C2H5OH B. Dng dd NaOH, ddBrom, dd HCl, CH3OH C. Dng dd Ca(OH)2 , dd thuc tm, dd H2SO4, C2H5OH D. Dng dd H2SO4, dd HNO3, CH3OC2H5, dd thuc tm 47. Mt hp cht hu c X c cng thc C3H9O2N. Cho X phn ng dung dch NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm t. Cho Y tc dng vi NaOH rn, un nng c CH4 . X c cng thc cu to no sau y? A. C2H5-COO-NH4 B. CH3-COO-NH4 C. CH3-COO-H3NCH3 D. B v C ng 48. Polipeptit (-NH-CH2-CO-)n l sn phm ca phn ng trng ngng A. axit glutamic B. axit amino axetic C. axit -amino propionic D. alanin 49. Mt trong nhng im khc nhau gia protein vi gluxit v lipit l A. protein lun c khi lng phn t ln B. protein lun c nhm chc OH trong phn t. C. protein lun c nguyn t N trong phn t D. protein lun l cht hu c no. 50. Pht biu no sau y khng ng? A. Thy phn protein bng axit hoc kim khi nung nng s cho mt hn hp cc amino axit. B. Phn t khi ca mt amino axit (gm mt chC.NH2 v mt chc COOH) lun l s l C. Cc amino axit u tan tt trong nc D. Dung dch amino axit khng lm giy qu i mu. 51. nhn bit bn dung dch khng nhn gm: albumin, CH3COOH, NaOH, glixerol ngi ta dng A. qu tm B. phenolphtalein C. HNO3 c D. CuSO4. 52. nhn bit cc dung dch: glixin, h tinh bt, lng trng trng ngi ta dng A. Cu(OH)2/OH v un nng B. dd AgNO3/NH3 C. dd HNO3 c D. dd iot 53. nhn bit cc cht: glixerol, glucoz, anilin, albumin ngi ta tin hnh theo trnh t sau: A. Dng dd AgNO3/NH3, dng dd CuSO4, dng dd NaOH B. Dng dd CuSO4, dng dd H2SO4, dng dd iot C. Dng Cu(OH)2 lc v un nh, dng nc brom. D. Dng dd HNO3, dng dd NaOH, dng dd H2SO4. 54. Cho cc cht sau: CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3). Dy cht c xp theo chiu tng dn tnh baz l A. (1) < (2) < (3) B. (2) < (3) < (1) C. (3) < (2) < (1) D. (3) < (1) < (2) 55. Thuc th duy nht nhn bit cc cht lng anilin, stiren, benzen l A. dung dch HCl B. dung dch brom C. dung dch NaOH D. dung dch H2SO4. 56. Tnh baz ca etylamin mnh hn amoniac c gii thch l do: A. Nguyn t N cn i e cha lin kt B. Nguyn t N c m in ln hn C. Ch cha 1 nguyn t D. nh hng y e ca nhm C2H5. 57. Cht hu c no sau y l cht lng iu kin thng? A. CH3Cl B. CH3OH C. CH3OCH3 D. CH3NH2. 4

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

58. nhn bit hai kh CH3NH2 v NH3, ngi ta dng cch no sau y? A. Mi ca kh B. Qu tm m C. t ri cho sn phm qua dung dch Ca(OH)2. D. Th bng HCl c 59. nhn bit dung dch cc cht C6H5NH2, CH3CH(NH2)COOH, (CH3)2NH v Anbumin. Ta c th tin hnh theo trnh t no sau y: A. Dng qu tm, dng Cu(OH)2, dng H2SO4 c B. Dng phenolphtalein, dng CuSO4, dng HNO3 c C. Dng nc Brom, dng H2SO4 c, dng qu tm D. Dng nc Brom, dng HNO3 c, dng qu tm 60. Hy sp xp cc cht sau theo th t tng dn tnh baz: (1) C6H5NH2; (2) C2H5NH2; (3) (C2H5)2NH2; (4)NaOH; (5) NH3. Trng hp no sau y ng? A. (1)<(5)<(2)<(3)<(4) B. (1)<(2)<(5)<(3)<(4) C. (1)<(5)<(3)<(2)<(4) D. (2)<(1)<(3)<(5)<(4) 61. C cc cht: metanol, glixerol, dd glucoz, dd anilin. nhn cc cht trn bit ngi ta thc hin: A. Dng dd AgNO3/NH3, dng Cu(OH)2, dng nc brom B. Dng dd AgNO3/NH3, dng nc brom C. Dng Na kim loi, dng dd AgNO3/NH3 D. Dng Na kim loi, dng nc brom 62. Anilin v phenol u c phn ng vi A. dd NaOH B. dd HCl C. dd NaCl D. nc Br2. 63. Hp cht no sau y khng phi l amino axit? A. CH3CONH2 B. HOOC CH(NH2)CH2COOH C. CH3CH(NH2)COOH D. CH3CH(NH2)CH(NH2)COOH 64. C 3 ng nghim khng nhn cha 3 dung dch sau: NH2 (CH2)2CH(NH2)COOH ; NH2CH2COOH ; HOOCCH2CH2CH2CH(NH2)COOH. C th nhn ra c 3 dung dch bng: A. Giy qu B. Dung dch NaOH C. Dung dch HCl D. Dung dch Br2 65. Axit aminoaxetic khng tc dng vi A. CaCO3 B. H2SO4 long C. CH3OH D. KCl 66. Thc hin phn ng trng ngng 2 amino axit glixin v alanin thu c ti a bao nhiu ipeptit A. 1 B. 2 C. 3 D. 4 67. Khi thy phn tripeptit H2N CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc amino axit A. H2NCH2COOH v CH3CH(NH2)COOH B. H2NCH2CH(CH3)COOH v H2NCH2COOH C. H2NCH(CH3)COOH v H2NCH(NH2)COOH D. CH3CH(NH2)CH2COOH v H2NCH2COOH 68. Cho cc cht sau: etilen glicol (A), hexa metylen diamin (B), axit -amino caproic (C), axit acrylic (D), axit aipic (E). Cht c kh nng tham gia phn ng trng ngng l A. A, B B. A, C, E C. D, E D. A, B, C, E. 69. Cho C4H11O2N + NaOH A + CH3NH2 + H2O CTCT ca C4H11O2N l A. C2H5COOCH2 NH2 B. C2H5COONH3CH3 B. CH3COOCH2CH2NH2 D. C2H5COOCH2CH2NH2 70. Phenol v anilin u lm mt mu nc brom cn toluen th khng, iu ny chng t A. nhm OH v NH2 y e mnh hn nhm CH3 B. nhm OH v NH2 y e yu hn nhm CH3. C. kh nng y e ca nhm OH>-CH3>-NH2 D. nhm CH3 ht e mnh hn nhm OH v NH2. 71. ra sch chai l ng anilin, nn dng cch no sau y? A. Ra bng x phng B. Ra bng nc C. Ra bng dd NaOH sau ra li bng nc D. Ra bng dd HCl sau ra li bng nc 72. tch phenol ra khi hn hp lng gm: phenol, benzen v anilin. Ngi ta c th lm theo cch: A. Ha tan hn hp vo dd HCl d, sau chit tch ly phn tan ri cho phn ng vi NaOH d, tip tc chit tch ly phn phenol khng tan. 5

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

B. Ha tan hn hp vo dd NaOH d, sau chit tch ly phn mui tan ri cho phn ng vi CO2 d, tip tc chit tch phenol khng tan. C. Ha tan hn hp vo nc d, sau chit tch ly phenol D. Ha tan hn hp vo xng, chit ly phenol 73. Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: A. C6H12 (xiclohexan), C6H5-CH3 B. C2H2, C6H5-NO2. C. CH4, C6H5-NO2 D. C2H2, C6H5-CH3. 74. Cc cht no sau y l amino axit? a) glixin, b)glixerol, c) etylenglicol, d) alanin, e) anilin, f) amoni axetat, g) axit glutamic, h) axit lactic, i) glicocol, j) etylamino axetat, k) axit -aminocaproic. A. a, d, f, g, i, k B. g, h, k C. a, c, e, j, k D. a, d, g, i, k 75. Dung dch lm qu tm ha l A. axit glutamic B. axit -amino propionic C. axit 2,3-iamino butiric D. axit phenic 76. Dung dch khng lm i mu qu tm l A. axit 2-amino pentanioic B. axit -amino aipic C. axit lactic D. axit -amino isovaleric. 77. Cht lng tnh l: a). metyl axetat, b) amoni axetat, c) glixin, d) metyl amoni fomiat, e) metyl amoni nitrat, f) axit glutamic, g) natri axetat. A. c,f B. b,d,e,f C. b,c,d,f D. a,b,c,d,f,g. 78. Alanin c th phn ng vi cc cht trong dy cht A. Ba(OH)2, CH3OH, CH2NH2-COOH B. HCl, Cu, CH3NH2 C. C2H5OH, FeCl2, Na2SO4 D. H2SO4, CH3-CH=O, H2O. 79. Cc amino axit c th phn ng tt c cc cht trong dy A. dd NaOH, dd HCl, C2H5COOH, C2H5OH B. dd NaOH, dd brom, dd HCl, CH3OH C. dd Ca(OH)2, dd thuc tm, dd H2SO4, C2H5OH D. dd H2SO4, dd HNO3, CH3OCH3, dd thuc tm 80. Dung dch metylamin khng tc dng vi cht no sau y? A. HNO2. B. Dung dch HCl. C. Dung dch FeCl3. D. Dung dch Br2. 81. Dung dch cht no sau y khng lm chuyn mu qu tm? A. CH3 - CHOH - COOH. B. H2N(CH2)2CH(NH2)COOH. C. H2N - CH2 - COOH. D. C6H5NH3Cl. 82. Trong cc cht sau, dung dch cht no khng lm chuyn mu qu tm? A. HOOC.CH2-CH2CH(NH2)COOH B. H2N-CH2-COOH C. H2N-CH2CH2CH2CH2-CH(NH2)-COOH D. CH3-CHOH-COOH 83. Hp cht khng lm i mu giy qu m l A. CH3NH2. B. H2NCH2COOH. C. C6H5ONa. D. H2N - CH2 - CH(NH2)COOH. 84. Anilin v phenol u c phn ng vi: A. Dung dch NaOH. B. Dung dch NaCl. C. Dung dch Br2. D. Dung dch HCl. 85. un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l A. H2N-CH2-COOH, H2N-CH(CH3)-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. D. H2N-CH2-COOH, H2N-CH2-CH2-COOH. 86. Tng s ng phn amin ca cht c cng thc phn t C3H9N l A. 5 B. 1 C. 4 D. 3 87. Dng nc Br2 khng phn bit c 2 cht trong cp no sau y? A. Anilin v stiren. B. Anilin v amoniac. C. Anilin v alylamin (CH2 = CH - CH2 - NH2). D. Anilin v phenol. 88. Nhn nh no sau y khng ng? A. Metyl amin c tnh baz mnh hn anilin. B. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk. C. Tnh baz ca cc amin u mnh hn NH3. 6

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

D. Cc amin u c kh nng nhn proton. 89. Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l A. Tinh bt. B. Xenluloz. C. Saccaroz. D. Protit. 90. Phn ng no di y khng th hin tnh baz ca amin? A. C6H5NH2 + HCl C6H5NH3Cl .
3+ + O B. Fe +3RNH 2 + 3H 2 Fe(OH) 3 + 3RNH 3 .

C. RNH 2 +HNO2 ROH + N 2 + H 2O .

+ D. RNH2 +H 2O RNH 3 +OH . CH3I HNO2 CuO 91. Cho s phn ng: NH3 X Y Z . (1 :1) t0

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l A. CH3OH, HCHO. B. CH3OH, HCOOH. C. C2H5OH, HCHO. D. C2H5OH, CH3CHO. 92. B thuc th no sau y c th phn bit c cc dung dch mt nhn sau: C2H5NH2, C6H5NH2, glucoz, glixerol? A. Qi tm, dung dch Br2. B. C A, B, C u ng. C. Phenolphtalein, Cu(OH)2. D. AgNO3/NH3, dung dch Br2, qi tm. 93. Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau: CH3NH2, H2NCH2COOH, CH3COONH4, anbumin. A. Qi tm, dung dch HNO3 c, dung dch NaOH. B. Dung dch AgNO3/NH3, dung dch Br2, dung dch HNO3 c. C. Cu(OH)2, qy tm, ung dch Br2. D. Dung dch Br2, dung dch HNO3 c, dung dch I2. 94. Cho dy chuyn ho sau: + NaOH + HCl + HCl + NaOH Glyxin Z X ; Glyxin T Y . X v Y ln lt l A. ClH3NCH2COOH v ClH3NCH2COONa. B. ClH3NCH2COOH v H2NCH2COONa. C. ClH3NCH2COONa v H2NCH2COONa. D. u l ClH3NCH2COONa. 95. Nhn nh no sau y cha chnh xc? A. Tc phn ng nh xc tc enzim rt chm, mi enzim ch xc tc cho mt s chuyn ho. B. Peptit l nhng hp cht c hnh thnh bng cch ngng t hai hay nhiu phn t -amino axit. C. Enzim l nhng cht hu ht c bn cht protein, c kh nng xc tc cho cc qu trnh ho hc, c bit trong c th sinh vt. D. Protein l nhng polipeptit cao phn t c vai tr l nn tng v cu trc v chc nng ca mi s sng. 96. Nhn nh no sau y khng ng? A. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH. B. Amino axit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. C. Amino axit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. D. Cc amino axit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc. 97. Thy phn hon ton polipeptit sau thu c bao nhiu amino axit?
H2N - CH2- CO - NH - CH - CO - NH - CH - CO - NH - CH2- COOH CH2COOH CH2- C6H5

A. 3. B. 4. C. 5. D. 2. 98. Khi lm th nghim xong vi anilin, trc khi trng li bng nc, nn ra ng nghim bng dung dch A. dd HCl B. dd NH3 C. dd Ca(OH)2 D. dd NaCl 99. S ipeptit to thnh t glyxin v alanin l 7

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

A. 1. B. 2. C. 4. D. 3. 100. Pht biu khng ng l A. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. B. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. C. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO2 li thu c axit axetic. D. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. 101. Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2-CH3 102. Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 103. Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin 104. Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 105. Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl 3+ C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3+ D. CH3NH2 + HNO2 CH3OH + N2 + H2O 106. Dung dch no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 107. X l cht hu c c cng thc phn t C5H11O2N. un X vi dung dch NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c Y. Cho hi Y qua CuO, t0 c cht Z c kh nng trng gng. Cng thc cu to ca X l A. H2NCH2CH2COOC2H5. B. CH3(CH2)4NO2. C. H2NCH2COOCH2CH2CH3. D. H2NCH2COOCH(CH3)2. 108. Nhn nh no sau y khng ng? A. Anilin c tnh baz nn lm mt mu nc brom. B. Anilin khng lm i mu qu tm. C. Trong phn t anilin c nh hng qua li gia nhm amino v gc phenyl. D. Amin c tnh baz v trn nguyn t N c i electron t do nn c kh nng nhn proton. 109. Dy gm cc cht u lm giy qi tm m chuyn sang mu xanh l A. Anilin, metylamin, amoniac. B. Anilin, amoniac, natri hiroxit. C. Metylamin, amoniac, natri axetat. D. Amoniclorua, metylamin, natri hiroxit. 110. Cho cc cht sau: C6H5NH2 (1); C2H5NH2 (2); (C2H5)2NH2 (3); NaOH (4); NH3 (5) Trt t tng dn tnh baz (t tri qua phi) l A. (1), (2), (5), (3), (4). B. (1), (5), (3), (2), (4). C. (1), (5), (2), (3), (4). D. (2), (1), (3), (5), (4). 111. Khi thy phn hon ton mt polipeptit ta thu c cc amino axit X, Y, Z, E, F. Cn khi thu phn tng phn th thu c cc i- v tripeptit XE, ZY, EZ, YF, EZY. Trnh t cc amino axit trong polipeptit trn l A. X - Z - Y - F - E. B. X - E - Z - Y - F. C. X - Z - Y - E - F. D. X - E - Y - Z - F. 112. Axit glutamic (HOOC[CH2]2CH(NH2)COOH) l cht c tnh A. trung tnh. B. axit. C. baz. D. lng tnh. 113. Trong phn t hp cht hu c no sau y c lin kt peptit? A. Xenluloz. B. alanin. C. Protein. D. Glucoz. 114. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri qua phi l 8

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

A. C6H5NH2, NH3, CH3NH2. B. NH3, CH3NH2, C6H5NH2. C. CH3NH2, C6H5NH2, NH3. D. CH3NH2, NH3, C6H5NH2. 115. chng minh glyxin C2H5O2N l mt amino axit, ch cn cho phn ng vi A. NaOH v HCl. B. HCl. C. NaOH. D. CH3OH/HCl. 116. Sn phm cui cng ca qu trnh thu phn cc protein n gin nh xc tc thch hp l. A. amino axit. B. amino axit. C. Axit cacboxylic. D. Este. 117. Cho cc loi hp cht: amino axit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca amino axit (T). Dy gm cc hp cht u tc dng c vi dung dch NaOH v u tc dng vi dung dch HCl l A. X, Y, T. B. X, Y, Z, T. C. X, Y, Z. D. Y, Z, T. H2NCH2COOH + HCl Cl 3N + 2COOH . H CH 118. Cho cc phn ng:
H2NCH2COOH + NaOH H2NCH2COONa +H2O . Hai phn ng trn chng t axit aminoaxetic

A. ch c tnh baz. B. ch c tnh axit. C. va c tnh oxi ho, va c tnh kh. D. c tnh lng tnh. 119. Cho dung dch NaOH vo dung dch metyl amoni propionat. Phn ng no sau y tng ng vi th nghim ny? A. CH3-CH2-COONH4 + NaOH CH3-CH2-COONa + NH3 + H2O B. CH3-CH2-COO-NH3CH3 + NaOH CH3-CH2-COONa + CH3NH2.+ H2O C. CH3-COO-CH3NH2 + NaOH CH3COONa + CH3NH2. D. CH3-CH2-COO-NH3-C2H5 + NaOH CH3-CH2-COONa + C2H5NH2+ H2O 120. T hai amino axit l alanin v glixin c th to thnh bao nhiu ipeptit? A. 2 B. 3 C. 4 D. 1 B. BI TP TON TRC NGHIM 1. Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi dung dch HCl. Khi lng mui thu c l A. 7,65 gam B. 8,10 gam C. 8,15 gam D. 0,85 gam 2. t chy hon ton 6,2 gam mt amin no n chc th phi dng 10,08 lt O2(ktc). Cng thc ca amin l A. C2H5NH2 B. CH3NH2 C. C3H7NH2 D. C4H9NH2. 3. Cho 0,01 mol amino axit X phn ng ht vi 40ml dd HCl 0,25M to thnh 1,115 gam mui khan. X c cng thc cu to l A. H2N-CH2-COOH B. H2N-(CH2)2-COOH C. CH3COONH4 D. H2N-(CH2)3-COOH 4. Thc hin phn ng este ha gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. Cng thc cu to ca X l A. H2N-CH2-COOH B. H2N-CH2-CH2-COOH C. CH3-CH(NH2)-COOH D. H2N-CH2-CH2-CH2-COOH 5. Khi t chy hon ton mt amin no, n chc X thu c 13,2 gam kh CO2 ,kh N2 v 8,1 gam H2O. Cng thc phn t ca X l A. C3H7N B. C2H7N C. C3H9N D. C4H9N 6. Cho 9,3 gam anilin tac dung vi dung dch brom, thu c m gam chat ket tua mau trang. Khoi lng ket tua la A. 93 gam B. 33 gam C. 330 gam D. 39 gam 7. 1 mol amino axit A tc dng va vi 1mol HCl 0,5 mol amino axit A tc dng va vi 1mol NaOH. A c cng thc phn t A. C5H9NO4 B. C4H7N2O4 C. C8H5NO2 D. C7H6N2O4 8. 0,01 mol amino axit A tc dng va vi 50 ml dung dch HCl 0,2M. C cn dung dch sau phn ng c 1,835g mui. A c phn t khi l A. 89 vC B. 103 vC C. 117 vC D. 147 vC

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

9. A l hp cht hu c cha C, H, O, N. t chy A c hn hp CO2, hi nc, N2 c t khi so vi hidro l 13,75. Bit th tch CO2 = th tch hi nc v s mol O2 dng bng na tng s mol CO2, H2O to ra. A l A. C2H5NO2 B. C2H7NO2 C. C4H7NO2 D. C4H9NO 10. Cho 23,9g hn hp gm axit aminoaxetic v axit -aminopropionic vo 0,6 lt dung dch NaOH 0,5M. Phn trm v s mol ca 2 axit ln lt l A. 40,5% v 59,5% B. 20,3% v 79,7% C. 24,5% v 75,5% C. 33,3% v 66,7% 11. Khi lng anilin thu c khi kh 246g nitrobenzen ( hiu sut H=80%) l A. 186g B. 148,8g C. 232,5g D. 260,3g 12. t chy 2 amin no n chc ng ng lin tip nhau thu c 2,24 lit CO 2 (kc) v 3,6g nc. Hai amin c CTPT l A. CH5N v C2H7N B. C3H9N v C4H11N C. C2H7N v C3H9N D. C4H11N v C5H13N 13. Hm lng nit trong amin n chc A l 19,17%. A c CTPT A. CH5N B. C2H7N C. C3H7N D C4H11N 14. Cho 1,87 g hn hp anilin v phenol tc dng va vi 20g dung dich Brom 48%. Khi lng kt ta thu c l A. 6,61g B. 11,745 g C. 3,305 g D. 1,75g 15. Mt hn hp gm ancol etylic, phenol, anilin co khi lng 23,3 gam. Nu cho hn hp tac dung vi Na d, thy thoat ra 2,24 lit khi (kc). Cung lng hn hp o, nu cho tac dung vi dung dich NaOH thy cn va ung 100 ml dung dich NaOH 1M. Khi lng mi cht trong hn hp ln lt la A. 4,6g; 9,4g va 9,3g B. 9,4g; 4,6 g va 9,3g C. 6,2g; 9,1g va 8 g D. 9,3g; 4,6g va 9,4g. 16. 0,1 mol amino axit A phn ng va vi 100ml dung dch HCl 2M. Mt khc 18g A cng phn ng va vi 200ml dung dch HCl trn. A c khi lng mol phn t l A. 120 B. 90 C. 60 D. 80 17. A l mt amino axit c khi lng phn t l 147. Bit 1 mol A tc dng va vi 1 mol HCl; 0,5 mol tc dng va vi 1mol NaOH. Cng thc phn t ca A l A. C5H9NO4 B. C4H7N2O4 C. C5H25NO3 D. C8H5NO2

C.BI TP TON T LUYN Cu 1. Hy cho bit kt lun no sau y ng nht? A. Nguyn nhn gy ra tnh cht baz ca amin l do phn t c cha N c m in ln. B. Do amin c to lin kt hiro vi nc v vi cc axit. C. Do amin c nguyn t Nit lin kt vi cc gc hirocacbon. D. Do nguyn t Nit trong amin cn cp electron cha lin kt linh ng c th to lin kt cho nhn vi H+. Cu 2. Cht no sau y khng c kt ta trng khi cho dung dch Br2 vo dung dch cht ? A. phenyl amoni clorua B. phenol B. anilin D. p-Metylanilin. Cu 3. Khi cho dung dch NaOH vo dung dch phenyl amoni clorua, hy cho bit hin tng no s xy ra? A. thu c dung dch ng nht B. thu c kt ta trng C. ban u thu c dung dch ng nht sau tch thnh 2 lp. D. tch lun thnh 2 lp. Cu 4. Cht X c cha vng benzen v c cng thc phn t l C 7H9N. Khi cho X tc dng vi brom (dd) thu c kt ta Y c cng thc phn t khi l C7H6NBr3. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4

10

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

Cu 5. Hp cht X c vng benzen v c CTPT l CxHyN. Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH2Cl. Trong cc phn t X, % khi lng ca N l 11,57%; Hy cho bit X c bao nhiu cng thc cu to? A. 3 B. 4 C. 5 D. 6 Cu 6. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100 ml B. 50 ml C. 200 ml D. 320 ml Cu 7. Cht X c cng thc phn t l C7H9N. Khi cho X tc dng vi dung dch Br2 thu c kt ta trng. Hy cho bit X c bao nhiu cng thc cu to ? A. 2 B. 3 C. 4 D. 5 Cu 8. tch ring tng cht t hh benzen, anilin v phenol ta ch cn dng cc ho cht (dng c, iu kin th nghim y ) l: A. dung dch NaOH, dung dch HCl v kh CO2 B. dung dch NaOH, dung dch NaCl v kh CO2 . C. dung dch NaOH, dung dch Br2 v kh CO2 . D. dung dch HCl, dung dch Br2 v kh CO2 . Cu 9. Cho cht X c cng thc phn t l C3H7O2N. un nng X vi NaOH thu c mui cacboxylat, H2O v cht hu c Y. Hy cho bit X c bao nhiu cng thc cu to tha mn. A. 2 B. 3 C. 4 D. 5 Cu 10. C cc dung dch : natriphenolat, anilin, phenol, phenyl amoni clorua. Ha cht no c th s dng nhn bit cc dung dch (Nu gi thit rng chng c t trong cc bnh mt nhn). Cc dng c v thit b c . A. dd NaOH, dd Br2, qu tm B. qu tm, dung dch HCl v dung dch NaOH C. qu tm, dung dch HCl v dung dch Br2. D. phenolphtalein, dung dch HCl v dung dch NaOH. Cu 11. Mt l ha cht m c nghi l phenyl amoni clorua. Ha cht no c th s dng kim tra l ha cht . A. dd NaOH , dd HCl B. dd NaOH, dd AgNO3 C. dd NaOH, dd NH3 D. dd AgNO3, dd HCl Cu 12. Dng tn ti ch yu ca glyxin l dng no sau y: A. H2N-CH2-COOH B. H3N+-CH2-COO -, C. H3N+-CH2-COOH. D. H2N-CH2-COO-. Cu 13. Trng hp no sau y lm hng qu tm tm H2O: A. CH3-CH(NH2)-COOH B. H2N-CH2-COONa C. H2N-CH2-CH(NH2)-COOH. D.ClH3N-CH2-CH2-COOH Cu 14. Cho cc cht sau: Glyxin (I); axit glutamic (II) ; HOOC-CH2-CH2-CH(NH3Cl)-COOH (III) ; H2N-CH2-CH(NH2)-COOH (IV) Sp xp cc cht trn theo th t tng dn v pH (gi s chng c cng nng mol/l). A. (I) < (II) < (III) < (IV) B. (III) < (I) < (II) < (IV) C. (III) < (II) < (I) < (IV) D. (III)<(IV) < (I) <(II) Cu 15. Cho dung dch phenolphtalein vo cc dung dch sau: H2N-CH2-CH(NH2)-COOH (1); H2NCH2-COONa (2); ClH3N-CH2COOH (3) ; HOOC-CH2-CH2-CH(NH2)-COOH (4) ; NaOOC-CH2-CH2-CH(NH2)-COONa (5). Hy cho bit dung dch no chuyn sang mu hng? A. (1) (2) (4) (5) B. (1) (2) (5) C. (1) (3) (5) D. (2) (3) (4) (5) Cu 16. Cht X c cng thc phn t C8H15O4N. T X, thc hin bin ha sau: C8H15O4N + dung dch NaOH d ,t0 Natri glutamat + CH4O + C2H6O Hy cho bit, X c th c bao nhiu cng thc cu to? A. 1 B. 2 C. 3 D. 4 + NaOH ,t + HCl du ,t Cu 17. Cho s sau: C4H9O2N C3H6O2NNa X. Hy cho bit X c cng thc phn t l g?
0 0

11

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CHNG 3: AMIN, AMINO AXIT V PROTEIN

A. C3H7O2N B. C3H7O2NaCl C. C3H8O2NCl D. C3H9O2NCl. Cu 18. Cho axit glutamic tc dng vi hn hp ru etylic v metylic trong mi trng HCl khan, hy cho bit c th thu c bao nhiu loi este? A. 5 B. 6 C. 7 D. 8 Cu 19. Cht no sau y c nhit nng chy cao nht? A. CH3CH2CH(NH2)-COOH B. CH3CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. CH3COOCH2CH2NH2 Cu 20. Mt hn hp gm alanin v glixin. Hy cho bit t hn hp d c th to nn bao nhiu loi ipeptit mch h. A. 1 B. 2 C. 3 D. 4 Cu 21. Trong mi trng HCl khan, khi thc hin P este ha gia glyxin vi ru metylic, sn phm hu c cui cng thu c l: A. H2N-CH2-COOCH3 B. ClH3N-CH2-COOCH3 C. ClH3N-CH2COOH D. ClH3NCH(CH3)COOCH3 Cu 22. Hy cho bit, trong cc dng tn ti sau, dng tn ti no l ch yu ca axit glutamic trong dung dch ca n ? A. HOOC-CH2-CH2-CH(NH+3)-COOB. - OOC-CH2-CH2-CH(NH+3)-COOH C. HOOC-CH2-CH2-CH(NH+3)-COOH D. - OOC-CH2-CH2-CH(NH2)-COO Cu 23. Cho s sau: NaOH, t0 dd X -NH3, -H2O X1 C H OH/ H2SO4 H2SO4 X 2 5 0 -Na2SO4 2 c, t 2O -H CH3-CH-COOC2H5 NH3HSO4

Hy cho bit cht X l A. CH3-CH(NH2)-COONH4 B. CH3-CH(NH3Cl)-COOH C. CH3-CH(NH2)-COONH2 D. H2N-CH2-COONH4 Cu 24. Hy cho bit dng qu tm c th phn bit c dy cc dung dch no sau y ? A. glyxin ; H2N-CH2COOCH3 ; H2N-CH2COONa. B. glyxin ; H2N-CH2COONa ; H2N-CH2-CH2COONa. C. glyxin ; H2N-CH2-COONa ; axit glutamic. D. ClH3N-CH2COOH, axit glutamic, glyxin. Cu 25. Cht X c cng thc phn t l C3H9O2N. un nng X trong NaOH thu c mui cacboxylat Y, H2O v cht hu c Z. T khi ca Z i vi H2 > 15. Hy cho bit c bao nhiu cht hu c X tha mn. A. 1 B. 2 C. 3 D. 4 Cu 26. Cht X c cng thc phn t l C4H9O2N. X tc dng vi NaOH v HCl. un nng X trong NaOH thu c mui X1 c cng thc l C3H3O2Na. Hy cho bit tn gi ca X. A. metyl amoni axetat B. metyl amoni acrylat C. amoni metacrrylat D. mety amoni propionat. Cu 27. Cht X c CTPT l C4H9O2N. Khi cho X tc dng vi NaOH un nng thu c mui X1 c cng thc l C2H4O2NNa. Hy cho bit cng thc cu to ca X. A. H2N-CH2-COOCH3 B. H2N-CH2-CH2-COOCH3 C. H2N-CH2-COOCH2-CH3 D. CH3-CH(NH2)-COOCH3 Cu 28. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH 2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N-CH2-COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 29. Este X c iu ch t aminoaxit X1 v ru etylic. X khng tc dng vi Na. t chy hon ton 2,03 gam cht X thu c 3,96 gam CO2; 1,53gam nc v 112 ml N2 (ktc). a/ X c cng thc phn t trng vi cng thc n gin nht. Cng thc phn t ca X l: A. C5H11O2N B. C7H13O2N C. C9H17O4N D. C10H17O4N 12

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

b/ un nng 0,1 mol X vi 200 ml NaOH 1,5M; sau khi phn ng hon ton, em c cn cn thn dung dch sau phn ng, thu c cht rn G c khi lng l: A. 19,1 gam B. 23,1 gam C. 27,7 gam D. 32,3 gam. c/ Cho ton b cht rn G vo dd HCl d, sau em c cn cn thn dung dch sau phn ng thu c cht rn E c khi lng l: A. 54,25 gam B. 48,4 gam C. 42,55 gam D. 35,9 gam Cu 30. X l cht hu c c dng: ROOC-(CH2)n-CH(NH2)-COOR. un nng 0,1 mol X trong 200 ml dung dch NaOH 1,5M, sau khi phn ng xy ra hon ton, c cn cn thn dung dch sau phn ng thu c 9,2 gam ru v dung dch Y. a/ Cng thc ca ru l : A. CH3OH B. C2H5OH C. CH3CH2CH2OH D. CH2=CH-CH2OH b/ C cn dung dch Y thu c cht rn Z c khi lng l 23,1 gam. Xc nh n. A. n = 0 B. n = 1 C. n = 2 D. n = 3 c/ Cho ton b cht rn Z vo dung dch HCl d, sau em c cn cn thn thu c bao nhiu gam cht rn khan. A. 35,9 gam B. 30,05 gam C. 24,2 gam D. 18,35 gam. Cu 31. Cht no sau y lm i mu qu tm: H2N-CH2-CH(NH2)-COOH (I) ; HOOC-CH(NH2)CH2-COOH (II) ; H2N-CH2-COOH (III) ; CH3CH(NH2)COOH (IV); ClH3N-CH2COOH (V); ClH3N-CH2-COOCH3 (VI) v H2N-CH2COONa (VII). A. (I) (II) (V) (VI) v (VII) B. (I) (II) (III) (IV) v (VII) C. (I) (II) v (VII) D. (I) v (II) Cu 32. Cho 0,1 mol -amino axit X tc dng va vi 0,1 mol HCl. Trong mt th nghim khc, cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn thu c 37,65 gam mui khan. Vy X l: A. glixin B. alanin C. glutamic D. amino butiric. Cu 33. Thc hin phn ng este ha gia alanin vi ru metylic trong mi trng HCl khan, thu c cht hu c X. Dung dch cht X c mi trng axit. Vy X l: A. H2NCH(CH3)-COOCH3 B. ClH3N-CH(CH3)-COOCH3 C. H2NCH2COOCH3 D. ClH3NCH2COOCH3 Cu 34. Cho 0,1 mol -amino axit X (X c mch cacbon khng phn nhnh) tc dng va vi 0,2 mol NaOH thu c 17,7 gam mui. Mt khc, 2,66 gam X tc dng vi HCl (va ) cho 3,39 gam mui Y. a/ Vy X l: A. HOOC-CH(NH2)-COOH B. HOOC-CH2-CH(NH2)-COOH C. HOOC-(CH2)2-CH(NH2)-COOH D. HOOC-(CH2)3-CH(NH2)COOH b/ Nu cho 3,39 gam mui Y tc dng vi 200 ml dung dch NaOH (ly d) , sau phn ng hon ton, c cn cn thn dung dch thu c 5,91 gam cht rn khan. Xc nh nng mol/l ca dung dch NaOH? A. 0,3M B. 0,35M C. 0,4M D. 0,45M Cu 35. Cho aminoaxit X (cha 1 nhm amino v 1 nhm cacboxyl). Cho m gam X tc dng va vi NaOH, thu c 8,88 gam mui Y. Mt khc, cho m gam X tc dng vi dung dch HCl d, c cn cn thn dung dch thu c 10,04 gam hn hp mui Z. a/ Xc nh m. A. 7,12 gam B. 7,18 gam C. 8,04 gam D. 8,16 gam b/ Xc nh s cng thc cu to c th c ca X. A. 1 B. 2 C. 3 D. 4 Cu 36. Cho cc cht v ion no sau: H3N+-CH2COOH; H2N-CH2-CH(NH2)-COONa; HOOC-CH2-CH2CH(NH2)-COOH; 13

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

H2N-CH2COOH; CH2=CH-COONH3CH3; CH3-CH(NH2)-COOH. Hy cho bit c bao nhiu cht hoc ion c tnh cht lng tnh. A. 1 B. 2 C. 3 D. 4 Cu 37. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht. A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Hy cho bit c bao nhiu cht c kh nng i mu qu tm? A. 1 B. 2 C. 3 D. 4 Cu 38. Hp cht X, Y l ng phn ca nhau c cng thc phn t l C4H11O2N. Khi cho 0,15 mol hn hp G gm X, Y tc dng vi dung dch NaOH va th thu c 13,7 gam hn hp mui natri ca 2 axit cacboxylic n chc v hn hp hi gm 2 amin l ng ng k tip nhau. a/ Cng thc cu to ca X, Y l: A.CH3COOH3NCH2CH3vHCOOH3NCH2CH2CH3 B.CH3COOH2N(CH3)2vHCOOH2N(CH3)CH2CH3 C. CH3COOH3NCH2CH3 v CH3CH2COOH3NCH3 D.CH3COOH2N(CH3)2 v HCOOHN(CH3)3 b/ Hp th hon ton lng amin thu c bi dung dch HCl, sao em c cn cn thn dung dch sau phn ng thu c cht rn c khi lng l: A. 10,675 gam B. 10,825 gam C. 11,19 gam D. 12,125 gam c/ chng minh tnh lng tnh ca X hoc Y cn cho X hoc Y tc dng vi cht no sau y? A. dung dch NaOH v dung dch NH4Cl B. dung dch HCl v dung dch NH3 C. dung dch HCl v dung dch NaOH D. dung dch NH4Cl v dung dch NH3 Cu 39. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH 2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N CH2 COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 40. Cho X l mt aminoaxit. Khi cho 0,01mol X tc dng vi HCl th dng ht 80ml dd HCl 0,125M v thu c 1,835g mui khan. Cn khi cho 0,01mol X tc dng vi dung dch NaOH th cn dng 25gam dd NaOH 3,2%. Cng thc cu to ca X l: A. C3H6(NH2)-COOH B. C2H4(NH2)COOH C. H2N-C3H5(COOH)2 D. (H2N)2C3H5 COOH Cu 41. t chy hon ton 6,52 gam cht X (cha C, H, O, N) thu c 10,56 gam CO 2, 4,68 gam H2O v 0,448 lt N2 (ktc). a/ Xc nh CTPT ca X, bit n trng vi cng thc n gin. A. C6H7O2N B. C6H7O4N C. C6H13O2N D. C6H13O4N o b/ T X, ngi ta thc hin dy bin ha sau: X + NaOH d, t X1 + CH4O + C2H6O Bit rng X1 c nhm NH2 v tr - v X1 c mch cacbon khng phn nhnh. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 c/ Hy cho bit 0,1 mol X1 tc dng ti a bao nhiu mol HCl. A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol. Cu 42. X l -aminoaxit c mch cacbon no khng phn nhnh cha 2 nhm amino 2 cacbon khng cnh nhau v 1 nhm cacboxyl. a/ Cng thc chung ca dy ng ng cha X l: A. CnH2n(NH2)2COOH (n 2) B. CnH2n-1(NH2)2COOH (n 2) C. CnH2n-1(NH2)2COOH (n 3) D.CnH2n(NH2)2COOH(n 3) b/ Cho 1,18 gam X vo dung dch HCl d, c cn cn thn dung dch sau phn ng thu c 1,91 gam cht rn E. Mt khc, cho 1,18 gam cht rn E vo 200 ml dung dch KOH (d) , un nng cc phn ng xy ra hon ton. C cn cn thn dung dch sau phn ng thu c 3,8 gam cht rn khan. Xc nh nng mol/l ca dung dch KOH. A. 0,2M B. 0,25M C. 0,3M D. 0,35M 14

BI TP TRC NGHIM HA HU C

CHNG 3: AMIN, AMINO AXIT V PROTEIN

Cu 43. E, F l ng phn ca nhau v c cng thc phn t l C4H9O2N. Khi cho E, F cng tc dng vi dung dch NaOH un nng th t E thu c mui E1 c cng thc phn t C4H8O2NNa cn F thu c mui F1 c cng thc phn t l C3H6O2NNa. C E1 v F1 u c nhm NH2. a/ Xc nh s lng ng phn ca E v ca F. A. E-3 ; F -2 B. E -4 ; F -3 C. E - 5 ; F -2 D. E - 5 ; F -3 b/ S sp xp no sau y ng vi chiu tng dn v pH ca 2 dung dch E, F nu chng c cng nng mol/l ? A. E > F B. E < F C. E = F D. khng xc nh. Cu 44. X l amino axit no ch cha mt nhm -COOH v mt nhm -NH2 v tr -. Cho X tc dng va vi 16,6 ml dung dch HCl 20% ( d = 1,1 g/ml) thu c dung dch G. Cho dung dch G tc dng hon ton v va vi V ml dung dch NaOH 0,5M thu c dung dch F. a/ Xc nh V. A. 200 ml B. 300 ml C. 400 ml D. 250 ml b/ C cn cn thn dung dch F thu c 15,55 gam mui khan. Cng thc ca X l: A. H2N-CH2-COOH B. H2N-CH(CH3)-COOH C. CH3CH2CH(NH2)COOH D.(CH3)2C(NH2)-COOH Cu 45. Cht hu c X cng thc phn t l C3H9O2N. un nng cc cht vi NaOH u thu c mui cacboxylat v amin. Hy cho bit c bao nhiu cng thc cu to ph hp vi X. A. 1 B. 2 C. 3 D. 4 Cu 46. Cht no sau y l cht rn : A. C3H5(OH)3 ; B. CH2Cl-CHCl-CH2Cl C. H2N-CH2-COOH ; D. C 6 H6 Cu 47. Cho 0,1 mol X tc dng va vi 0,1 mol axit H2SO4; 0,1 mol X tc dng va vi 0,1 mol NaOH. Hy cho bit cng thc chung no ng vi axit X. A. R(NH2)COOH B. R(NH2)2COOH C. R(NH2)(COOH)2 D. R(NH2)2(COOH)2 Cu 48. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) X4 (C2H6O5N2) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht. A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Nhng cht no lm qu tm i sang mu ? A. cht Cu 49. Thc hin phn ng ca glixin vi CH3OH trong mi trng HCl khan, ngi ta thu c cht X c cng thc l: ClH3N-CH2-COOCH3. Hy cho bit c th ch ha X vi cht no sau y c th thu c cht Y c cng thc H2N-CH2COOCH3 vi hiu sut cao nht: A. NaOH B. AgNO3 C. NH3 D. Ba(OH)2

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