HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

CHNG III: AMIN-AMINOAXIT-PROTEIN I. Amin 1. Khi nim

Tn gc -chc Tn Thay th Metyl amin metanamin Etyl amin etanamin propyl amin propan-1-amin isopropyl amin propan-2-amin etyl metyl amin N-metyletanamin phenyl amin bezenamin Hexametylen Hexan-1,6 iamin iamin 3. S ng phn amin C3H9N: 4 p (2 bc 1; 1 bc 2, 1 bc 3) C4H11N: 8 p (4 bc 1; 3 bc 2, 1 bc 3 (6 p mch C khng nhnh) C5H13N: 17 p (8 bc 1; 6 bc 2, 3 bc 3) C6H15N: 7 ng phn amin bc 3 C7H9N: 5 ng phn cha vng benzen (4 bc 1, 1 bc 2) 4.So snh tnh baz: * Cng nhiu nhm y e (CH3-, C2H5 -,.) tnh baz cng mnh * Cng nhiu nhm ht e (C6H5 -,.) tnh baz cng yu Tnh baz MOH > Amin bo (b2>b1>b3) > ddNH3 > Amin thm Tnh baz C6H5 CH2 NH2 > CH3 C6H4 NH2 > C6H5NH2 5.Nhit si ca amin < ancol < axit cacboxylic 6.Tnh cht ho hc metylamin (CH3NH2) Anilin etylamin (C2H5NH2),... C6H5NH2 qu tm ho khng i mu axit p to mui p to mui dung dch brom khng phn ng p to kt ta trng dd NaOH khng phn ng khng phn ng + HCl RNH Cl RNH 7.

2. Danh php (sgk) Hp cht CH3NH2 CH3CH2NH2 CH3CH2CH2NH2 CH3CH(CH3)NH2 CH3NHC2H5 C6H5NH2 H2N[CH2]6NH2

-nH NH3 Amin + nR

ba amin =n c
Tn Thng

anilin

Phenol C6H5OH khng i mu khng phn ng p to kt ta trng p to mui + nc

+ MOH 3 RNH2 RNH3NO3 RNH 2 + COOH R RNH2 RCOONH3R

2 3 + HNO

(M l Na, K,..)

mamin + maxit = mmui 8. t chy amin no n chc CnH2n + 3 N + (

2n+3 1 6n+3 )O2 nCO2 + H2O + N2 4 2 2

t chy amin n chc CxHy N + ( x+

y )O2 4

xCO2 +

y HO+ 2
2

1 N2 2

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HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

9. Mui ca amin vi axit cacboxylic (RCOONH3R) v mui amoni ca axit cacboxylic no n chc (RCOONH4) l ng phn ca nhau v u l nhng hp cht lng tnh * C2H7O2N

CH3COONH4 + NaOH CH3COONa+NH3 +H2O HCOONH 3CH3 HCOONa+CH 3NH 2 +H 2O

II. Aminoaxit: 1. Khi nim: Aminoaxit tp chc

m nho cacboxyl (-COOH) m nho amino (-NH2 )

quytm khog om n i au quytmhoa ng ho quytm hoa xanh

R -(COOH)a

a=b : a>b : a<b :

(NH2 )b

2. Tnh cht vt l: iu kin thng, aminoaxit l cht rn kt tinh, d tan trong nc, c nhit nng chy cao 3. Tnh cht ho hc a) Aminoaxit c tnh lng tnh

tnh baz: Tadu g vaxit (g iog am c n i n in) *co i a + kimloa m nh 2 * co tnh axit: baz, oxitbaz, m + uoi cu axit ye hn (CO 3 a u ,..) +ancol este
(H2N)b-R-(COOH)a + bHCl (ClH3N)b-R-(COOH)a

S nhm NH2 =

so HCl mol so aminoaxit mol so MOH mol so aminoaxit mol

maminoaxit + maxit = mmui

(H2N)b-R-(COOH)a+ aMOH (H2N)b-R-(COOM)a+aH2O S nhm COOH = maminoaxit + mMOH = mmui + mH2O poliamit

b) Phn ng trng ngng: Cc

c) t chy aminoaxit A(c 1 nhm COOH) y y t CxHyO2Nt + ( x+ -1)O2 xCO2 + H2O + N2 4 2 2 Lu Ch c -aminoaxit tn ti trong t nhin

trug ngng n , -aminoaxit

II. BI TP:
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

Cu 1:

NaOH H l Cho dy chuyn ha: Glyxin + X + C Y ; +HCl + NaOH Glyxin Z T. Y v T ln lt l: A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa

Cu 2:

Cho bit s amin bc III ca C4H11N: A. 1 B. 2 C. 3 D.4 Cu 3: C7H9N c bao nhiu ng phn thm? A. 3 B. 4 C. 5 D. 6 Cu 4: C3H9N co bao nhiu ng phn amin? A. 2 B. 3 C. 4 D. 5 Cu 5: Cho CTCT: CH3NHC2H5 goi tn theo danh phap thay th? A. Etyl metyl amin B. N- Metyl etan amin C. N- etyl metan amin D. N, N- i metyl amin Cu 6: Phn ng no sau y ca anilin khng xy ra : A. C6H5NH2 + H2SO4 B. C6H5NH3Cl + NaOH (dd) C. C6H5NH2 + Br2(dd) D. C6H5NH2 + NaOH. Cu 7: Phng trnh chy ca amin CnH2n+3N, c 1 mol amin trn cn dng lng xy l: A. (6n+3)/4 B. (2n+3)/2 C. (6n+3)/2 D. (2n+3)/4. Cu 8: Khi cho etylamin vo dung dch FeCl3 ,hin tng no xy ra c: A. kh bay ra B. kt ta mu nu C. kh mi khai bay ra D.Khng hin tng g. Cu 9: Sp xp nao sau y la ung? A. C6H5NH2> C2H5NH2 B. CH3NH2> NH3> C2H5NH2 C. C2H5NH2> CH3NH2> C6H5NH2 D. C6H5NH2>CH3NH2> NH3 Cu 10: Cng thc chung ca amin no n chc, mch h l: A. CnH2n+1N B. CnH2n+1NH2 C. CnH2n+3N D. CxHyN Cu 11: Cht tham gia phn ng trng ngng l A. C2H5OH. B. CH2 = CHCOOH. C. H2NCH2COOH. D. CH3COOH. Cu 12: nhn bit 3 cht hu c H2NCH2COOH, HOOCCH(NH2)COOH, H2NCH(NH2)COOH, ta ch cn th vi mt trong cc cht no sau y: A. NaOH B. HCl C. Qy tm D. CH3OH/HCl Cu 13: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, . Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 4. B. 6. C. 5. D. 3.

Cu 14:

Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. Cu 15: Thc hin phn ng trng ngng 2 aminoaxit : Glixin v Alanin s ipeptt thu c ti a l: A.1 B.2 C.3 D.4

Cu 16:

Khi thy phn tripeptit H2N CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc aminoaxit B. H2NCH2CH(CH3)COOH v H2NCH2COOH D. CH3CH(NH2)CH2COOH v H2NCH2COOH

A. H2NCH2COOH v CH3CH(NH2)COOH C. H2NCH(CH3)COOH v H2NCH(NH2)COOH

Cu 17: Cu 18:

chng minh tnh lng tnh ca NH2-CH2-COOH (X) , ta cho X tc dng vi A. HCl, NaOH. B. Na2CO3, HCl. C. HNO3, CH3COOH. D. NaOH, NH3. Mt amino axit c cng thc phn t l C4H9NO2. S ng phn amino axit l
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

A. 3

B. 4

C. 5

D. 6

Cu 19:

Thu phn khng hon ton tetra peptit (X), ngoi cc - amino axit cn thu c cc ipetit: Gly-Ala; Phe-Val; Ala-Phe. Cu to ng ca X l A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly. C. Gly-Ala-Val-Phe D. Gly-Ala-Phe Val. Cu 20: Peptit c cng thc cu to nh sau: H2N-CH-CO-NH-CH2-CO-NH-CH-COOH CH3 CH(CH3)2. Tn gi ng ca peptit trn l: A. Ala-Ala-Val. B. Ala-Gly-Val. C. Gly Ala Gly. D. Gly-Val-Ala.

Cu 21:

C th nhn bit l dngdung dch CH3NH2 bng cch no trong cc cch sau y? A. Nhn bit bng mi B. Thm vi git dung dch H2SO4 C. Thm vi git dung dch Na2CO3 D. HCl m c

Cu 22:

C 4 dd long khng mu ng trong bn ng nghim ring bit, khng dn nhn: Anbumin, Glixerol, CH3COOH, NaOH. Chn mt trong cc thuc th sau phn bit 4 cht trn: A. Qu tm B. Phenolphtalein. C. HNO3 c. D. CuSO4. Cu 23: Cho 9,85 gam hn hp 2 amin n chc, bc mt tc dng va vi dung dch HCl thu c 18,975 g mui. Khi lng ca HCl phi dng l: A. 9,521g B. 9,125g C. 9,215g D. 9,512g Cu 24: t chy mt amin no n chc X thu c CO2 v H2O vi t l mol 2:3. X l: A. Etyl amin B. Etyl metyl amin C. Trietyl amin D. B v C u ng Cu 25: Mt amin no n chc X c thnh phn % v N l 23,73% theo khi lng. X l: A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C3H5NH2 Cu 26: trung ho 3,1g mt amin n chc cn 100ml dung dch HCl 1M. Amin l A. CH5N B. C3H9N C. C2H7N D. C3H7N Cu 27: Cho 7,6 g hh hai amin n chc, bc mt k tip nhau, tac dung va u vi 200ml dd HCl 1M. CTCT cua hai amin trn la A. CH3NH2, CH3NHCH3, B. CH3NH2, C2H5NH2 C. C2H5NH2,C3H7NH2 D. p n khac Cu 28: Cho 0,1 mol X (-amino axit dng H2NRCOOH) phn ng ht vi HCl to 11,15 gam mui. X l: A. Glyxin B. Alanin C. Phenylalanin D. Valin

Cu 29:

Cho -amino axit mch thng X c cng thc H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. X l: A. Axit 2-aminopropanioic B. Axit 2-aminobutanioic C. Axit 2-aminopentanioic D. Axit 2-aminohexanioic t chy hon ton amol mt aminoaxit X c 2a mol CO2 v 2,5a mol nc. X c CTPT l: A. C2H5NO4 B. C2H5N2O2 C. C2H5NO2 D. C4H10N2O2

Cu 30: Cu 31:

0,1 mol aminoaxit X phn ng va vi 100ml dung dch HCl 2M. Mt khc18g X cng phn ng va vi 200ml dung dch HCl trn. X c khi lng phn t l A. 120 B. 90 C. 60 D. 80 Cu 32: Th tch nc brom 3% (D= 1,3g/ml) cn dng iu ch 4,4g tribromanilin l A. 164,1ml. B. 49,23ml. C 146,1ml. D. 16,41ml.

Cu 33:

Khi trng ngng 13,1g axit -aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c m gam polime v 1,44g nc. Gi tr m l A. 10,41g. B. 9,04g. C. 11,66g. D. 9,328g.

Cu 34:

Cho cc dung dch : (1) H2NCH2COOH ; (2) ClH3N-CH2COOH ; (3) H2NCH2COONa ; (4) H2N[CH2]2CH(NH2)COOH ; (5) HOOC[CH2]2CH(NH2)COOH
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

S dung dch lm qu tm ha l: A. (3) B. (2) C. (1), (4) D. (2), (5) Cu 35: Sp xp cc hp cht sau theo th t gim dn tnh baz: (1) C6H5NH2 ; (2) C2H5NH2 ; (3) (C6H5)2NH ; (4) (C2H5)2NH ; (5) NaOH ; (6) NH3 A. (5) > (4) > (2) > (6) > (1) > (3) B. (5) > (4) > (2) > (1) > (3) > (6) C. (1) > (3) > (5) > (4) > (2) > (6) D. (6) > (4) > (3) > (5) > (1) > (2) Cu 36: Hp cht no sau y thuc loi ipeptit ? A. H2N-CH2CONH-CH2CONH-CH2COOH. B. H2N-CH2CONH-CH(CH3)-COOH. C. H2N-CH2CH2CONH-CH2CH2COOH. D. H2N-CH2CH2CONH-CH2COOH. Cu 37: Tripeptit l hp cht A. m mi phn t c 3 lin kt peptit. B. c 3 gc aminoaxit ging nhau. C. c 3 gc aminoaxit khc nhau. D. c 3 gc aminoaxit. Cu 38: Thuc th no di y nhn bit cc dung dch: Lng trng trng, glucoz, glixerol v h tinh bt? A. Cu(OH)2/OH- un nng. B. Dung dch AgNO3/NH3. C. Dung dch HNO3 c. D. Dung dch Iot. Cu 39: Tnh baz ca cc cht tng dn theo th t: A. NH3 < CH3CH2NH2 < CH3NHCH3< C6H5NH2 B. NH3 < C6H5NH2 < CH3NHCH3 < CH3CH2NH2 C. C6H5NH2 < NH3 < CH3NHCH3 < CH3CH2NH2 D. C6H5NH2 < NH3 < CH3CH2NH2 < CH3NHCH3 Cu 40: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoniclorua), H2NCH2CH2CH(NH2)COOH, ClH3N-CH2-COOH, HOOCCH2-CH2-CH(NH2)-COOH, H2N-CH2COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3.

Cu 41:

ng vi cng thc C4H11N c s ng phn amin bc 2 l: A. 3. B. 4. C. 5. D. 6. Cu 42: Nhn bit ba dung dch cha ba cht glixin, metylamin, axit axtic ngi ta dng: A . Qu tm B . Dung dch NaOH C . Dung dch HCl D . Tt c u ng. Cu 43: iu khng nh no sau y khng ng: A . Cc aminoaxit u tan c trong nc. B . Phn t lng ca mt aminoaxit cha mt nhm NH2 v mt nhm COOH lun l s l. C . Thy phn protein trong mi trng axit thu c hn hp cc aminoaxit. D . Cc dung dch cha cc amino axit u lm i mu qu tm. Cu 44: Goi tn CTCT: CH3CH2CH(NH2)COOH theo danh phap thay th A. Axit 2-amino butanoic B. Axit 2- amino propionic B. Axit 3-amino butiric D. Axit 2- amino butiric Cu 45: ng vi CTPT C4H9NO2 co bao nhiu amino axit la ng phn cua nhau? A. 3 B. 4 C. 5 D. 6 Cu 46: Cng thc nao sau y ung vi tn goi: Axit 2-amino propanonic A. H2NCH2COOH B. HOOCCH2CH2NH2 C. CH2-CH(NH2)COOH D. CH3CH(NH2)COOH Cu 47: Axit amino axetic tac dung c bao nhiu cht cho di y: (iu kin co u) NaOH, Na, CH3CHO, CH3OH, H2SO4 A. 2 B. 3 C. 4 D. 5 Cu 48: t chy hon ton hn hp 2 amin no, n chc, mch h ng ng lin tip, ta thu c t l th tch VCO2 VH 2O = 5 ( cng iu kin). Cng thc ca 2 amin l 8 B. C3H7NH2 , C4H9NH2 D. C4H9NH2 , C5H11NH2
Trang 5

A. CH3NH2 , C2H5NH2 C. C2H5NH2 , C3H7NH2

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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

Cu 49: Cu 50: Cu 51:

Cho 9,3 gam ankyl amin tc dng vi dd FeCl3 d thu c 10,7 gam kt ta. ankyl amin l A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2

Cho lng d anilin phn ng vi dd cha 0,05 mol H2SO4 long, lng mui thu c bng: A. 28,4 gam B. 8,8 gam C. 19,1 gam D. 14,2 gam X l mt -aminoaxit mch thng ch cha mt nhm NH2 v mt nhm -COOH. Cho 10,3 gam X tc dng vi dd HCl d thu c 13,95 gam mui clorua ca X. CTCT thu gn ca X l: A. CH3CH(NH2)COOH B. H2NCH2COOH C. H2NCH2CH2COOH D. CH3CH2CH(NH2)COOH

Cu 52:

Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c l (Cho H = 1, C = 12, O = 16, Na = 23) A. 11,05 gam. B. 9,8 gam. C. 7,5 gam. D. 9,7 gam. Cu 53: t chy ht amol 1 aminoaxit X bng Oxi va ri ngng t hi nc c 2,5a mol hn hp CO2 v N2. Cng thc phn t ca X l: A. C2H5NO2 B. C3H7NO2 C. C3H7N2O4 D. C5H11NO2 Cu 54: 0,01mol aminoaxit X tc dng va vi 50ml dd HCl 0,2M. C cn dd sau phn ng c 1,835g mui khan. Khi lng phn t ca X l : A. 89 B. 103 C. 117 D. 147 Cu 55: Este X c iu ch t -amino axit v ancol metylic. T khi hi ca X so vi hidro bng 44,5. Cng thc cu to ca X l: A. CH3CH(NH2)COOCH3. B. H2N-CH2CH2-COOH C. H2NCH2COOCH3. D. H2NCH2CH(NH2)COOCH3. Cu 56: Khi lng anilin cn dng tc dng vi nc brom thu c 6,6g kt ta trng l A. 1,86g. B. 18,6g. C. 8,61g. D. 6,81g.

Cu 57:

Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Cu 58: S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l A. 2. B. 3. C. 5. D. 4. Cu 59: T glyxin (Gly) v alanin (Ala) c th to ra my ipeptit? A. 1 B. 2 C. 3 D. 4 Cu 60: Glixin khng tc dng vi A. H2SO4 long. B. CaCO3. C. C2H5OH. D. NaCl.

CHNG 4: POLIME - VT LIU POLIME 1. Phn loi polime: - polime tng hp: + polime trng hp (c iu ch bng phn ng trng hp):polietilen (PE), polivinylclorua (PVC), poli striren, caosu buna (poli butaien), poli (metyl metacrylat) (thu tinh hu c), + polime trng ngng (c iu ch bng phn ng trng ngng): nilon -6, nilon-6,6 (poli(hexemetylen iamin)), nilon-7, poli (etylen terephtalat), poli (phenol-fomanehit) (PPF), poli(ure-fomanehit) - polime thin nhin: tinh bt, xenluloz, cao su thin nhin,. - polime bn tng hp: t visco, t axetat, 2. Cu to mch polime: c 3 kiu cu to mch polime - Mch khng nhnh: PE, PVC,. - Mch c nhnh: amilopectin, glicogen, - Mch khng gian: caosu lu ho, nha bekelit,
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

6. Phn ng trng hp Khi nim * Trng hp l qu trnh kt hp nhiu phn t nh (monome) ging nhau hay tng t nhau thnh phn t ln (polime)

7.Phn ng trng ngng Trng ngng l qu trnh kt hp nhiu phn t nh (monome) thnh phn t ln (polime) ng thi gii phng nhng phn t nh khc (th d H2O) phi c t nht 2 nhm chc c kh nng phn ng

iu kin cn v cu to monome

Trong phn t phi c lin kt bi hoc vng km bn c th m ra

MT S POLIME THNG GP TRONG: I. Cht do: 1. PE: poli etylen

nCH2=CH2
xt, t0, p

CH2-CH2 n

2. PVC: poli (vinyl clorua) nCH2=CH

xt, t0, p

CH2-CH Cl nCH2=CH

Cl 3. PVA: poli (vinylaxetat)

xt, t0, p

CH2-CH CH3COO CH3

CH3COO 4. PMM: poli (metylmetacrylat) n CH2= C-COOCH3 CH3 metyl metacrylat 5. PP: poli propilen nCH2=CH CH3 6. PS: poli stiren
nCH2=CH
xt, t0, p t , p, xt
0

CH2-C COOCH3

Poli(metyl metacrylat)
xt, t0, p

CH2-CH CH3
CH2-CH

7. PPF: (nha novalac, nha crezol, nha crezit hay bakelit) II. T: 1. T nilon-6, nilon-7 2. T nilon-6,6

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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

nH2N-[CH2]6-NH2 + n HOOC-[CH2]4-COOH

t0

( NH-[CH2]6-NHCO-[CH2]4-CO ) n

+ 2nH2O

Poli(hexametylen-aipamit) (nilon-6,6) 3. T lapsan (axit terephtalic v etylenglicol) o nHOOC-C 6H 4 COOH +nHOCH 2-CH 2OH t Axit terephtalic Etylen glicol ( CO-C6 H4 CO-O-C2 H 4 O ) +2n H2 O n poli(etylen terephtalat) 4. T olon (nitron): acrilonitrin (vinyl xianua)

V du nCH2=CHCN : Acrilonitrin 5. T capron

nH2N[CH2]5COOH
axit -aminocaproic
xt, t0, p

t0, p, xt

CH2-CH CN Poliacrionitrin

policaproamit (nilon-6)

HN-[CH2]5-CO n + nH2O

n CH2

CH2 - CH - C =O 2 v n c ( NH-[CH ] -CO ) t | 2 5 n to CH2 - CH2 - NH

Caprolactam 6. T enang (axit - aminoetanoic)

nH2N[CH2]6COOH

capron
xt, t0, p

HN-[CH2]6-CO n + nH2O

III. Cao su: 1. Cao su buna nCH2=CH-CH=CH2 2. Cao su buna-S

nCH2=CH-CH=CH2 + n CH=CH2
t0, p, xt

Na

CH2-CH=CH-CH2 n
CH2-CH=CH-CH2-CH-CH2 n

cao su buna-S

3. Cao su buna-N
nCH2=CH-CH=CH2 + n CH=CH CN
t0, p, xt 2

CH2-CH=CH-CH2-CH-CH2 n CN cao su buna-N

4. Cao su isopren n CH2= C-CH= 2 CH CH3 isopren

t0, xt, p

CH2-C= CH-CH2 CH3 cau su isopren

II. BI TP:

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HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

Cu 61:

Cht khng c kh nng tham gia phn ng trng hp l A. stiren. B. isopren. C. propen. D. toluen. Cu 62: Cht c kh nng tham gia phn ng trng hp l A. propan. B. propen. C. etan. D. toluen. Cu 63: Qu trnh nhiu phn t nh (monome) kt hp vi nhau thnh phn t ln (polime) ng thi gii phng nhng phn t nh khc c gi l phn ng A. trao i. B. nhit phn. C. trng hp. D. trng ngng. Cu 64: Monome c dng iu ch polietilen l A. CH2=CH-CH3. B. CH2=CH2. C. CHCH. D. CH2=CH-CH=CH2. Cu 65: Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. B. CH2=CH-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, CH3-CH=CH2. Cu 66: Nha rezol (PPF) c tng hp bng phng php un nng phenol vi A. HCHO trong mi trng baz. B. CH3CHO trong mi trng axit. C. HCHO trong mi trng axit. D. HCOOH trong mi trng axit. Cu 67: Poli(vinyl axetat) l polime c iu ch bng phn ng trng hp A. C2H5COO-CH=CH2. B. CH2=CH-COO-C2H5. C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3. Cu 68: Poli(vinylclorua) c iu ch bng phn ng trng hp: A. CH3-CH2Cl B. CH2=CHCl. C. CHCCl. D. CH2Cl-CH2Cl Cu 69: Nilon6,6 l mt loi A. t axetat. B. t poliamit. C. polieste. D. t visco. Cu 70: Polime dng iu ch thu tinh hu c (plexiglas) l A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2. Cu 71: T c sn xut t xenluloz l A. t tm. B. t capron. C. t nilon-6,6. D. t visco. Cu 72: Cho cc polime: polietilen, xenluloz, polipeptit, tinh bt, nilon-6, nilon-6,6, polibutaien. Dy gm cc polime tng hp l A. polietilen, xenluloz, nilon-6, nilon-6,6 B. polietilen, polibutaien, nilon-6, nilon-6,6 C. polietilen, tinh bt, nilon-6, nilon-6,6 D. polietilen, xenluloz, nilon-6,6 Cu 73: Monome c dng iu ch polipropilen (PP) l A. CH2=CH-CH3. B. CH2=CH2. C. CHCH. D. CH2=CH-CH=CH2. Cu 74: T lapsan thuc loai A. t poliamit. B. t visco. C. t polieste. D. t axetat. Cu 75: T nilon - 6,6 c iu ch bng phn ng trng ngng A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. D. H2N-(CH2)5-COOH. 450 C ,p Cu 76: Cho s chuyn ho: Glucoz menru X ZnO , Y xt,t Cao su Buna. Hai cht X, Y ln lt l A. CH3CH2OH v CH3CHO. B. CH3CH2OH v CH2=CH2. C. CH2CH2OH v CH3-CH=CH-CH3. D. CH3CH2OH v CH2=CH-CH=CH2. Cu 77: Teflon l tn ca mt polime c dng lm A. cht do. B. t tng hp. C. cao su tng hp. D. keo dn. Cu 78: Polime c cu trc mng khng gian (mng li) l A. PVC. B. nha bakelit. C. PE. D. amilopectin. Cu 79: Poli(ure-fomanehit) c cng thc cu to l
0 0

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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

A.

HN-CO-NH-CH2 n

B.

CH2-CH CN OH

C.

NH-[CH2]6-NH-CO-[CH2]4-CO n

D.

CH2

Cu 80:

Chn pht biu khng ng: polime ... A. u c phn t khi ln, do nhiu mt xch lin kt vi nhau. B. c th c iu ch t phn ng trng hp hay trng ngng. C. c chia thnh nhiu loi: thin nhin, tng hp, nhn to. D. u kh bn vi nhit hoc dung dch axit hay baz. Cu 81: Polime no sau y l polime thin nhin? A. cao su buna B. cao su isopren C. amiloz D. nilon-6,6 Cu 82: Polime c cu trc mch khng phn nhnh l A. Nha bakelit. B. Amilopectin ca tinh bt. C. Poli (vinyl clorua). D. Cao su lu ha. Cu 83: Cu to ca monome tham gia c phn ng trng ngng l B. trong phn t phi c lin kt cha no hoc vng khng bn. B. tha iu kin v nhit , p sut, xc tc thch hp. C. c t nht 2 nhm chc c kh nng tham gia phn ng. D. cc nhm chc trong phn t u c cha lin kt i. Cu 84: Cht c th tham gia phn ng trng ngng l A. H2N CH2 COOH. B. C2H5 OH, C6H5 OH. C. CH3 COOH, HOOC COOH. D. CH2=CH COOH. Cu 85: Nha novolac (PPF) c tng hp bng phng php un nng phenol vi A. HCHO trong mi trng baz. B. CH3CHO trong mi trng baz. C. HCHO trong mi trng axit. D. HCOOH trong mi trng axit. Cu 86: Cao su buna S c to thnh bng phn ng A. trng hp B. trng ngng C. cng hp D. ng trng hp Cu 87: T 4 tn C2H4 c cha 30% tp cht c th iu ch bao nhiu tn PE ? (Bit hiu sut phn ng l 90%) A. 2,55 B. 2,8 C. 2,52 D.3,6 Cu 88: Phn t khi trung bnh ca PVC l 750000. H s polime ho ca PVC l A. 12.000 B. 15.000 C. 24.000 D. 25.000 Cu 89: Phn t khi trung bnh ca polietilen l 420000. H s polime ho ca PE l A. 12.000 B. 13.000 C. 15.000 D. 17.000 Cu 90: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 113 v 152. B. 121 v 114. C. 121 v 152. D. 113 v 114. Cu 91: Trong cc phn ng gia cc cp cht sau, phn ng no lm gim mch polime A. poli(vinyl clorua) + Cl2 t0 B. cao su thin nhin + HCl t0 OH ,t 0 ,t C. poli(vinyl axetat) + H2O D. amiloz + H2O H +0 Cu 92: Dy gm tt c cc cht u l cht do l A. Polietilen; t tm, nha rezol. B. Polietilen; cao su thin nhin, PVA. C. Polietilen; t st t; PVC. D. Polietilen; polistiren; bakelit Cu 93: Nha rezit (nha bakelit) c iu ch bng cch o A. un nng nha rezol 150 C to mng khng gian. o B. un nng nha novolac 150 C to mng khng gian. o C. un nng nha novolac vi lu hunh 150 C to mng khng gian. o D. un nng nha rezol vi lu hunh 150 C to mng khng gian.
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

Cu 94:

T gm 2 loi l A. t ha hc v t tng hp. B. t thin nhin v t nhn to. C. t ha hc v t thin nhin. D. t tng hp v t nhn to. Cu 95: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enan. Nhng t thuc loi t nhn to l A. T tm v t enan. B. T visco v t nilon-6,6. C. T nilon-6,6 v t capron. D. T visco v t axetat. Cu 96: Theo ngun gc, loi t cng loi vi len l A. bng B. capron C. visco D. xenluloz axetat. Cu 97: Loi t thng dng dt vi may qun o m hoc bn thnh si len an o rt l A. t capron B. t nilon -6,6 C. t capron D. t nitron. Cu 98: Khi t chy mt polime Y thu c kh CO2 v hi nc theo t l s mol tng ng l 1 :1. Vy Y l A. poli(vinyl clorua). B. polistiren. C. polipropilen. D. xenluloz. Cu 99: Polime di y c cng cu trc mch polime vi nha bakelit l A. Amiloz B. Glicogen C. Cao su lu ha D. Xenluloz. Cu 100: Cho cc polime: PE, PVC, polibutaien, poliisopren, nha rezit, amiloz, amilopectin, xenluloz, cao su lu ho. Dy gm tt c cc polime c cu trc mch khng phn nhnh l A. PE, polibutaien, poliisopren, amiloz, xenluloz, cao su lu ho B. PE, PVC, polibutaien, nha rezit, poliisopren, xenluloz. C. PE, PVC, polibutaien, poliisopren, amiloz, xenluloz. D. PE, PVC, polibutaien, poliisopren, amiloz, amilopectin, xenluloz. Cu 101: Pht biu sai l A. Bn cht cu to ho hc ca t tm v len l protit; ca si bng l xenluloz. B. Bn cht cu to ho hc ca t nilon l poliamit C. Qun o nilon, len, t tm khng nn git vi x phng c kim cao D. T nilon, t tm, len rt bn vng vi nhit. Cu 102: Pht biu khng ng l A. Tinh bt v xenluloz u l polisaccarit (C6H10O5)n nhng xenluloz c th ko si, cn tinh bt th khng. B. Len, t tm, t nilon km bn vi nhit v khng b thu phn trong mi trng axit hoc kim. C. Phn bit t nhn to v t t nhin bng cch t, t t nhin cho mi kht. D. a s cc polime u khng bay hi do khi lng phn t ln v lc lin kt phn t ln. Cu 103: Poli (metyl metacrylat) v t nilon-6 c to thnh t cc monome tng ng l A. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. C. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. D. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. Cu 104: Mt on mch PVC c khong 1000 mt xch. Hy xc nh khi lng ca on mch . A. 62500 vC B. 625000 vC C. 125000 vC D. 250000vC. Cu 105: Bn cht ca s lu ho cao su l A. to cu ni isunfua gip cao su c cu to mng khng gian. B. to loi cao su nh hn. C. gim gi thnh cao su. D. lm cao su d n khun. Cu 106: Cho cc polime : polietilen, xenluloz, amiloz, amilopectin, poli(vnylclorua), t nilon-6,6; poli(vinyl axetat). Cc polime thin nhin l A. xenluloz, amilopectin, poli(vinyl clorua), poli(vinyl axetat) B. amilopectin, PVC, t nilon - 6,6; poli(vinyl axetat) C. amilopectin, poli(vinyl clorua), poli(vinyl axetat) D. xenluloz, amiloz, amilopectin
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 HA HC 12: AMIN AMINO AXIT PROTEIN - POLIME

Trng ngng axit aminocaproic thu c m kg polime v 12,6 kg H2O vi hiu sut phn ng 90%. Gi tr ca m l A. 71,19. B. 79,1. C. 91,7. D. 90,4. Cu 108:T 100ml dd ancol etylic 33,34% (D = 0,69g/ml) c th iu ch c bao nhiu g PE (hiu sut 100%) A. 23 B. 14 C. 18 D. Kt qu khc Cu 109: H s trng hp ca loi polietilen c khi lng phn t l 4984 vC v ca polisaccarit (C6H10O5)n c khi lng phn t 162000 vC ln lt l: A. 178 v 1000 B. 187 v 100 C. 278 v 1000 D. 178 v 2000 Cu 110: iu ch cao su buna ngi ta c th thc hin theo cc s bin ha sau: C2H5OH 5%0 buta-1,3-ien 8%0 cao su buna Tnh khi lng ancol etylic cn ly c th iu ch c 54 gam cao su buna theo s trn? A. 92 gam B. 184 gam C. 115 gam D. 230 gam.

Cu 107:

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