Ph o 12

AMIN- AMINOAXIT- PEPTIT-PROTEIN

Cu 1. Cho 1,52 g hhn hp 2 amin n chc no (c trn vi s mol bng nhau ) tc dng va vi 200ml dung dch HCl , thu c 2,98gam mui . Kt qu no sau y khng chnh xc A. Nng mol ca dung dch HCl bng 0,2M B. S mol mi cht l 0,02 mol C. Tn gi ca 2 amin l metyl amin v etyl amin D. Cng thc phn t ca 2 amin l CH5N v C2H7N Cu 2. un nng 26,2 g axit - aminocaproic thu c m g policaproamit (nilon_6). Bit hiu sut phn ng 80%. Gi tr m l: A. 22,6 g B. 18,08 g C. 16,95 g D. 20,96 g Cu 3. X l mt Hexapeptit cu to t mt Aminoacid H2N-CnH2n-COOH(Y) . Y c tng % khi lng Oxi v Nito l 61,33%. Thy phn ht m(g) X trong mi trng acid thu c 30,3(g) petapeptit, 19,8(g) ieptit v 37,5(g) Y. Gi tr ca m l? A. 69 gam. B. 84 gam. C. 100 gam. D.78 gam. Cu 4. Cho mt hn hp A cha NH3, C6H5NH2 V C6H50H. A c trung ho bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br 2 to kt ta. Lng cc cht NH 3, C6H5NH2 v C6H5OH ln lt bng: NH3 C6H5NH2 C6H50H A. 0,010 mol 0,005 mol 0,020 mol B. 0,005 mol 0,005 mol 0,020 mol C. 0,005 mol 0,020 mol 0,005 mol D. 0,010 mol 0,005mol 0,020 mol Cu 5. Thy phn hon ton 1 mol Pentapeptit(X) thu c 3 mol Gli; 1 mol Ala; 1 mol Phe. Khi thy phn khng hon ton (X) thu c hn hp gm Ala-Gly ; Gly-Ala v khng thy to ra Phe-Gly. Xc nh CTCT ca Petapeptit? A. Gly-Ala-Gly-Phe-Gly B. Gly-Gly-Ala-Phe-Gly C. Gly-Gly-Ala-Gly-Phe D. Gly-Ala-Gly-Gly-Phe Cu 6. Thy phn 14(g) mt Polipeptit(X) vi hiu sut t 80%,thi thu c 14,04(g) mt - aminoacid (Y). Xc nh Cng thc cu to ca Y? A. H2N(CH2)2COOH. B. H2NCH(CH3)COOH. C. H2NCH2COOH D. H2NCH(C2H5)COOH Cu 7. Hp cht hu c mch h X cha cc nguyn t C, H, N trong c 23,72% lng N. X tc dng vi HCl theo t l mol 1 : 1. Cu tr li no sau y l sai A. X l hp cht amin. B. Cu to ca X l amin n chc, no. C. Nu cng thc X l CxHyNz th z = 1 D. Nu cng thc X l CxHyNz th mi lin h 2x - y = 45. Cu 8. Xc nh Phn t khi gn ng ca mt Polipeptit cha 0,32% S tromh phn t. Gi s trong phn t ch c 2 nguyn t S? A. 20.000(vC) B.10.000(vC). C. 15.000(vC). D. 45.000(vC). Cu 9. X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH ; 1 nhm NH2. Trong A %N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit ; 25,6 gam ipeptit v 92,56 gam A. Gi tr ca m l : A. 149 gam. B. 161 gam. C. 143,45 gam. D. 159 gam. Cu 10. Cho 17,7g mot ankylamin tac dung vi dd FeCl3 d thu c 10,7g ket tua. CTPT cua ankylamin la A. C2H7N. B. C3H9N. C. C4H11N. D. CH5N. Cu 11. Cong thc nao sau ay cua pentapeptit (A) thoa ieu kien sau: + Thuy phan hoan toan 1 mol A th thu c cac - amino axit la: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin. + Thuy phan khong hoan toan A, ngoai thu c cac amino axit th con thu c 2 i peptit: Ala-Gly ; Gly- Ala va 1 tripeptit Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. B. Gly-Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly. Cu 12. Sp xp tnh baz tng theo cc dy sau A. C6H5NH2 , (C6H5 )2NH , CH3NH2, C2H5NH2 , (C2H5)2NH B. (CH3)2NH , C6H5NH2 , C2H5NH2 , (C2H5)2NH , (C6H5 )2NH C. (C6H5 )2NH , C6H5NH2 , CH3NH2 , C2H5NH2 , (C2H5)2NH D. C2H5NH2 , CH3NH2 , C6H5NH2 , (CH3)2NH , (C6H5 )2NH , (C2H5)2NH Cu 13. X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2,

Ph o 12

trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2 ? A. 2,8 mol. B. 2,025 mol. C. 3,375 mol. D. 1,875 mol. Cu 14. t chy hon ton 8,7 gam amin axit A (axit n chc ) th thu c 0,3 mol CO 2 , 0,25mol H2O v 1,12lt (ktc) mt kh tr. T A c th iu ch c bao nhiu polime A. 1 B. 2 C. 3 D. 4 Cu 15. : X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. m c gi tr l : A.. 68,1 gam. B. 64,86 gam. C. 77,04 gam. D. 65,13 gam. Cu 16. Pht biu no sau y l ng : A. dung dch anilin lm qu tm ho xanh B. glyxin khng lm qu tm chuyn mu C. cc amin u tc dung c vi dung dch HCl to ra mui amoni D. tnh baz ca NH3 yu hn anilin Cu 17. Mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). Phn t khi gn ng ca hemoglobin trn l : A. 12000. B. 14000. C. 15000. D. 18000. Cu 18. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H2SO4 long, lng mui thu c bng A. 28,4 gam B. 19,1 gam C. 14,2 gam D. 7,1 gam Cu 19. un nng alanin thu c mt s peptit trong c peptit A c phn trm khi lng nit l 18,54%. Khi lng phn t ca A l : A. 231. B. 160. C 373. D. 302. Cu 20. Hn hp X gm 2 amin n chc no , l ng ng k tip nhau. Cho mt lng hn hp X phn ng va vi 100ml dung dch H2SO4 1M thu c 17,4gam hn hp 2 mui . Khi lng ca 2 amin l A. 7,2 gam C2H5NH2 , 6,5 gam C3H7NH2 B. 4,5 gam C2H5NH2 , 3,8 gam C3H7NH2 C. 3,1 gam CH3NH2 , 4,5 gam C2H5NH2 D. 4,5 gam C2H5NH2 , 7,8 gam C3H5NH2 Cu 21. Khi thy phn hon ton 55,95 gam mt peptit X thu c 66,75 gam alanin (amino axit duy nht). X l A. tripeptit. B. tetrapeptit. C. pentapeptit. D. ipeptit. Cu 22. Xt cc dy chuyn ho : HCl Glyxin N aH A + X C HCl Glyxin + B N aH Y . X v Y: C A. u l ClH3NCH2COONa. B. ln lt l ClH3NCH2COOH v ClH3NCH2COONa. C. ln lt l ClH3NCH2COONa v H2NCH2COONa. D. ln lt l ClH3NCH2COOH v H2NCH2COONa Cu 23. Khi thy phn hon ton 65 gam mt peptit X thu c 22,25 gam alanin v 56,25 gam glyxin. X l : A. tripeptthu c. B. tetrapeptit. C. pentapeptit. D. ipeptit. Cu 24. t chy hon ton hn hp 2 amin no n chc ng ng lin tip, ta thu c t l th tch VCO2: VH2O ( cng k)= 8: 17. Cng thc ca 2 amin l: Chn mt cu tr li A. C2H5NH2 , C3H7NH2 B. C4H9NH2 , C5H11NH2 C. C3H7NH2 , C4H9NH2 D. CH3NH2 , C2H5NH2 Cu 25. Thu phn hon ton 500 gam mt oligopeptit X (cha t 2 n 10 gc -amino axit) thu c 178 gam amino axit Y v 412 gam amino axit Z. Bit phn t khi ca Y l 89. Phn t khi ca Z l : A. 103. B. 75. C. 117. D. 147. Cu 26. Amino axit X c 1 nhm NH2 v 1 nhm COOH bit 1 lng X tc dng va ht 200 ml dung dch NaOH 0,1 M thu c dung dch Y, cho dung dch HCl d vo dung dch Y sau lm kh thu c 2,51 gam cht Z. Cng thc ph hp ca X l A. CH3CH(NH2)COOH B. NH2CH2COOH C. NH2(CH2)4COOH D.CH3CH2CH(NH2)COOH Cu 27. Tripeptit X c cng thc sau : H2NCH2CONHCH(CH3)CONHCH(CH3)COOH Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH 1M. Khi lng cht rn thu c khi c cn dung dch sau phn ng l : A. 28,6 gam. B. 22,2 gam. C. 35,9 gam. D. 31,9 gam. Cu 28. Protein A c khi lng phn t l 50000 vC. Thu phn 100 gam A thu c 33,998 gam alanin. S mt xch alanin trong phn t A l : A. 191. B. 38,2. C. 2.3.1023 D. 561,8. Cu 29. Thy phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100000 vC th s mt xch alanin c trong X l : A. 453. B. 382. C. 328. D 479. Cu 30. t chy hon ton 7,7 gam cht hu c Z (c cng thc phn t trng vi cng thc n gin nht) bng oxi, thu c 6,3 gam H2O, 4,48 lt CO2, 1,12 lt N2 (cc kh o ktc). Cho Z phn ng vi dung dch NaOH un nng, c kh Z1. Kh Z1 lm xanh giy qu tm m v khi t chy Z 1 thu c sn phm lm c nc vi trong. Cng thc cu to ca Z l cng thc no sau y:

Ph o 12

A. HCOOH3NCH3 B. CH3COONH4 C. CH3CH2COONH4 D. CH3COOH3NCH3 Cu 31. Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin ; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly ; Gly-Ala v tripeptit GlyGly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l : A. Gly, Val. B. Ala, Val. C. Gly, Gly. D. Ala, Gly. Cu 32. Thu phn khng hon ton tetrapeptit (X), ngoi cc a-amino axit cn thu c cc ipetit: GlyAla ; Phe-Val ; Ala-Phe. Cu to no sau y l ng ca X ? A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly. C. Gly-Ala-Val-Phe. D. Gly-Ala-Phe-Val. Cu 33. Cho cac nhan nh sau ay: (1). Co the tao c 2 ipeptit t hai aminoaxit la Alanin va Glyxin. (2). Khac vi axit axetic, axit amino axetic co the tham gia phan ng vi axit HCl hoac phan ng trung ngng. (3). Giong vi axit axetic, aminoaxit co the tdung vi bazo tao muoi va nc. (4). Axit axetic va amino axetic co the ieu che t muoi Natri tng ng cua chung bang 1 phan ng hoa hoc. Co bao nhieu nhan nh ung. A. 1 B.2 C.3 D.4 Cu 34. Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. ht X c cng thc l A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. Cau 35. Cho cac nhan nh sau: (1). Alanin lam quy tm hoa xanh. (2). Axit Glutamic lam quy tm hoa o. (3). Lysin lam quy tm hoa xanh. (4). Axit - amino caporic la nguyen lieu e san xuat nilon 6. So nhan nh ung la: A. 1 B. 2 C.3 D.4 Cu 36. Cng thc no sau y ca pentapeptit (A) tha iu kin sau ? Thy phn hon ton 1 mol A th thu c cc - amino axit l : 3 mol glyxin, 1 mol alanin, 1 mol valin. Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 ipeptit : Ala-Gly ; Gly-Ala v 1 tripeptit Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. B. Gly- Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly. Cu 37. metyl amin( CH3-NH2) c th tc dng vi dd cc cht : A. HCl, NaOH, H2SO4. B. HNO3, H3PO4, NaCl. C. H2SO4, CuSO4, Na2CO3 D. HCl, HNO3, CuSO4. Cu 38. Thu phn hp cht : H2NCH2CONHCH(CH3)CONHCH(CH(CH3)2)CONHCH2CONHCH2COOH s thu c bao nhiu loi amino axit no sau y ? A. 3. B. 4. C. 5. D. 2. Cu 39. Nhn nh no sau y khng ng? A. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc. B. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. C. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. D. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH Cu 40. Thu phn hp cht : s thu c bao nhiu loi amino axit no sau y ? H2NCH(CH3)CONHCH(CH(CH3)2)CONHCH(C2H5)CONHCH2CONHCH(C4H9)COOH. A. 2. B. 3. C. 4. D. 5. Cu 41. Pht biu no di y khng ng A. Propan-2-amin (isopropyl amin) l mt amin bc hai B. Tn gi thng dng ca benzen amin (phenyl amin) l anilin C. C bn ng phn cu to amin c cng cng thc phn t C3H9N D. Dy ng ng amin no , n chc , mch h c cng thc CnH2n+3N Cu 42. Cho 3 cht X,Y,Z vo 3 ng nghim cha sn Cu(OH)2 trong NaOH lc u v quan st th thy: Cht X thy xut hin mu tm, cht Y th Cu(OH)2 tan v c mu xanh nht, cht Z th Cu(OH)2 tan v c mu xanh thm. X, Y, Z ln lt l : A. H tinh bt, HCOOH, mantoz. B. Protein, CH3CHO, saccaroz. C. Anbumin, C2H5COOH, glyxin. D. Lng trng trng, CH3COOH, glucoz. Cu 43. Thuc th c dng phn bit Gly-Ala-Gly v Gly-Ala l : A. dd HCl. B. Cu(OH)2/OHC. dd NaCl. D. dd NaOH. Cu 44. Alanin co the phan ng c vi bao nhieu chat trong cac chat cho sau ay: Ba(OH)2 ; CH3OH ; H2N-CH2-COOH; HCl, Cu, CH3NH2, C2H5OH, Na2SO4, H2SO4.

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A. 4 B.5 C.6 D.7 Cu 45. t chy hon ton m gam mt amin X bng 1 lng k.kh va thu c 17,6g CO 2, 12,6g H2O v 69,44 lit N2 (ktc). Gi thit k.kh ch gm N2 v O2, trong O2 chim 20% th tch k.kh. CTPT ca X l A. C4H11N B. C2H7N C. C3H9N D. CH5N Cu 46. chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi A. dd KOH v dd HCl. B. dd NaOH v dd NH3. C. dd HCl v dd Na2SO4 . D. dd KOH v CuO. Cu 47. Phn tch 6 g 1 CHC A thu c 8,8g CO 2; 7,2g H2O v 2,24 lit N2 (ktc). Bit 0,1 mol A p/ va vi 0,2 mol HCl. X/ CTPT ca A. A.C2H3N B. C2H8N2 C. C2H6N2 D. C2H7N Cu 48. X l mt amino axit khi cho 0,01 mol X t/d vi HCl th dng ht 80 ml dd HCl 0,125 M v thu c 1,835 g mui khan. Cn khi cho 0,01 mol X t/d vi dd NaOH th cn 25 gam dd NaOH 3,2%. CTCT ca X l: A. C7H12-(NH2)2-COOH B. C3H6-(NH2)2-COOH C. NH2-C3H5-(COOH)2 D. (NH2)2-C3H5-COOH Cu 49. C 4 ng nghim: 1) Benzen + phenol; 2) anilin + dd H2SO4d; 3) anilin + dd NaOH; 4) anilin + nc. Hy cho bit trong ng nghim no c s tch lp A. 1,2,3 B. 4 C. 3,4 D. 1,3,4. Cu 50. Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 3. B. 2. C. 1. D. 4. Cu 51. Cho cc cu sau: S nhn xt ng l: (1). Peptit l h/cht c h/thnh t 2 n 50 gc - amino axit. (2). Tt c cc peptit u p/ mu biure. (3). T 3 - amino axit ch c th to ra 3 tripeptit khc nhau. (4). Khi un nng dung dch peptit vi dung dch kim, sn phm s c phn ng mu biure. A. 1 B. 2 C. 3 D. 4 Cu 52. S ng phn amin ng vi CTPT C4H11N v s ng phn amin bc 1, bc 2, bc 3 ln lt l: A. 7, 3, 3, 1 B. 8, 4, 3, 1 C. 7, 3, 3, 1 D. 6, 3, 2, 1 Cu 53. Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3 B. 1 C. 2 D. 4 Cu 54. Cc cht no sau y va t/d vi HCl va t/d vi NaOH : (I) metyl axetat ; (II) Amoni axetat ; (III) metyl amino axetat ; (IV) etyl amoni nitrat ; (V) axit glutamic ; (VI) axit gluconic ;(VII) natri axetat A. I,II,III,IV,V,VII B. I, III, IV, V C. I,II,III, V, VII D. II, III, V, VII Cu 55. phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l A. dung dch NaOH. B. dung dch HCl. C. natri kim loi. D. qu tm. Cu 56. Mt - amino axit X ch cha 1 nhm -NH2 v 1 nhm COOH. Cho 10,68 gam X t/d vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. Glixin Cu 57. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 18,12 gam X tc dng vi KOH d thu c 22,68 gam mui. Cng thc cu to ca X l: A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH Cu 58. Trong cc tn gi di y, tn no khng ph hp vi cht CH3-CH(CH3)-CH(NH2)-COOH? A. Axit 3-metyl-2-aminobutanoic. B. Valin. C. Axit 2-amino-3-metylbutanoic. D. Axit -aminoisovaleric Cu 59. C bao nhiu amino axit c cng cng thc phn t C3H7O2N? A. 3 cht. B. 4 cht. C. 2 cht. D. 1 cht. Cu 60. Khi thy phn 500g protein A thu c 170g alanin. Nu phn t khi ca A l 50.000, th s mt xch alanin trong phn t A l: A. 189 B. 190 C. 191 D. 192 P N : 1 2 C B 11 12 C C 21 22 C D 31 32 A D 41 42 A D 51 52 A B

3 D 13 B 23 B 33 D 43 B 53 C

4 B 14 D 24 D 34 C 44 D 54 C

5 C 15 A 25 A 35 C 45 B 55 D

6 B 16 B 26 A 36 C 46 A 56 D

7 D 17 B 27 C 37 D 47 B 57 B

8 A 18 C 28 A 38 A 48 C 58 A

9 C 19 D 29 B 39 D 49 D 59 C

10 B 20 C 30 A 40 D 50 B 60 C