Trng THPT chuyn Nguyn nh Chiu

Gv: Nguyn Hoi Hn

BI TP CHNG 6: NHM HALOGEN. A. T LUN. DNG 1: CHUI PHN NG

1. Hon thnh chui phn ng: a. MnO2 Cl2 FeCl3 Fe(OH)3 FeCl3 AgCl Cl2. b. KMnO4 Cl2 HCl CuCl2 BaCl2 BaSO4. c. NaCl HCl Cl2 FeCl3 NaCl NaOH NaCl Cl2 CaCl2 AgCl Ag. d. NaCl HCl KCl Cl2 NaCl H2 HCl Cl2 CuCl2 AgCl. 2. Xc nh A,B,C, D,E,F,G: HCl + MnO2 (A) + (B) rn + (C) lng. (A) + Fe FeCl3. s (A) + (C) a (D) + (E) (D) + Ca(OH)2 (G) + (C). (F) + (E) t (C) (F) + (A) t (D). 3. B tc v cn bng cc pt theo s : a. HCl + ? Cl2 + ? + ? b. ? + ? CuCl2 + ? c. HCl + ? CO2 + ? + ? d. HCl + ? AgCl + ? HCl + ? + ? e. KCl + ? f. Cl2 + ? HClO + ? g. Cl2 + ? NaClO + ? + ? h. Cl2 + ? CaOCl2 + ? i. CaOCl2 + ? HClO + ? k. NaClO + NaHCO3 + ? 4. Vit cc phng trnh biu din dy bin ha sau (ghi r iu kin). a. MnO2 Cl2 nc javen NaHCO3. KCl AgCl Cl2 KClO3. CaOCl2 CaCO3 CO2 HClO NaClO. Br2 I2 AgI. b. Cl2 FeCl3 NaCl Cl2 Br2 HBrO NaBrO. c. H2 HCl Cl2 FeCl2 Fe(NO3)2 Fe(OH)2 FeSO4 FeCl2 AgCl. DNG 2: NHN BIT cc dung dch mt nhn bng phng php ha hc. a. NaOH, HCl, NaCl, NaNO3. b. KCl, KNO3, HCl, HNO3. c. KCl, K2SO4, KNO3. d. HCl, H2SO4, HNO3. e. Ba(OH)2, H2SO4, Na2SO4 , KCl, HNO3. f. CaCl2, Ca(OH)2, NaOH, Ca(NO3)2. g. Ba(OH)2, HCl, NaCl, Na2SO4, KOH. h. NaF, NaBr, NaI. i. Na2CO3, NaCl, NaOH, K2SO4, NaBr. DNG 3: VIT PHNG TRNH IU CH 1. Vit cc phng trnh iu ch nc giaven khi ch c: Na, Mangandioxit, hidroclorua. 2. T clo v cc iu kin cn thit vit cc phng trnh iu ch: a. Nc giaven. c. Kali clorat. b. Clorua vi. d. axit hypoclor. 3. Nu tnh cht ha hc c trng ca axit clohidric.Vit 2 phng trnh chng minh mi tnh cht . 4. Nu tnh cht ha hc c trng ca clo. Vit phng trnh chng minh? 5. Vit 2 phng trnh chng minh clo th hin tnh oxi ha v 1 phng trnh chng minh clo va th hin tnh oxi ha va th hin tnh kh. 6. Vit cc phng trnh phn ng ca clo tc dng vi: Ca, K, Fe, FeCl2, ddNaOH, H2O.Gi tn sn phm. 7. Cho cc cht : KCl, CaCl2, MnO2, H2SO4c. Nu tt c cc phng php iu ch kh hidroclorua. 8. Vit cc phn ng xy ra gia cc cht(nu c): a. St tc dng vi clo. b. St tc dng vi axit clohidric. c. ng tc dng vi axit clohidric. d. ng oxit tc dng vi axit clohidric. e. St (II) hydroxyt tc dng vi axit clohidric. f. St (III) hydroxyt tc dng vi axit clohidric. g. Canxi cacbonat vi axit clohidric. h. Clo vi kali hydroxyt c(100oC). Trong cc phn ng trn, phn ng no l phn ng oxi ha kh, xc nh vai tr mi cht.
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Trng THPT chuyn Nguyn nh Chiu Gv: Nguyn Hoi Hn 9. Cp cht no sau y khng cng tn ti trong dung dch? Vit cc phng trnh phn ng xy ra? a. NaCl + ZnBr2. e. KCl + AgNO3. b. KCl + I2. f. NaI + HBr. c. NaOH + KBr. g. Cl2 + KBr d. Cl2+ KBr. h. CuCl2 + MgI2. DNG 4: BI TP NH TNH Vn 1: Kim loi hoc oxit kim loi vo dd HCl 1. Cho 26,1g MnO2 tc dng ht vi 400ml dung dch axit clohidric m c. a. Tnh th tch kh thot ra ktc. b. Tnh nng mol HCl. c. Lng kh clo thu c c tc dng ht vi 1,12g st khng? 2. Cho 30g hn hp gm Cu v Zn tc dng ht vi 200g dung dch HCl thu c 5600ml kh (ktc). a. Tnh khi lng mi kim loi. b. Tnh thnh phn % khi lng mi kim loi theo khi lng. c. Tnh nng % HCl. 3. Cho 15g hn hp gm Fe,Ag tc dng ht vi dung dch HCl 15,6% thu c 3360ml kh thu c (ktc). a. Tnh khi lng mi kim loi trong hn hp. b. Tnh thnh phn % khi lng mi kim loi. c. Tnh khi lng dung dch HCl phn ng. 4. Cho 1,4g st tc dng vi 840ml kh clo (ktc). a. Tnh khi lng cc cht thu c sau phn ng. b. Tnh th tch dung dch HCl 0,5M tc dng ht vi cc cht thu c trong phn ng trn. 5. Cho 29,8g hn hp gm Fe,Zn tc dng ht vi 600ml dung dch HCl thu dc 11,2 lt kh (ktc). a. Tnh thnh phn % theo khi lng mi kim loi. b. Tnh nng mol HCl. 6. Cho clo tc dng vi va vi Fe ri ha tan lng mui sinh ra vo nc c 100g dung dch mui c nng 16,25%. a. Tnh khi lng mui trong dung dch. b. Tnh khi lng st v clo (ktc) dung. 7. Ha tan 10,55g hn hp gm Zn v ZnO vo mt lng va dung dch HCl 10% th thu c 2,24 lt kh (ktc). a. Tnh khi lng mi cht trong hn hp u. b. Tnh khi lng dung dch HCl dng. 8. Cho 10g hn hp Al, Mg, Cu tc dng vi dung dch HCl d th thu c 7,84 lt H2(ktc). Tnh thnh phn % khi lng mi kim loi. 9. ha tan hon ton 14,9g hn hp Fe, Zn ngi ta cn va ng 250 ml dung dch HCl 2M. a. Tnh % khi lng tng kim loi trong hn hp. b. Tnh th tch kh sinh ra (ktc). 10. Ha tan 7,8g hn hp Al,Mg bng dung dch HCl d. Sau phn ng khi lng dung dch axit tng thm 7g. Xc nh khi lng mi kim loi trong hn hp ban u. 11. Cho Cho 78,3g MnO2 tc dng va vi dung dch HCl 20%. a. Tnh khi lng dung dch HCl phn ng v th tch kh sinh ra. b. Tnh nng dung dch mui thu c. c. Kh sinh ra cho tc dng vi 250ml dung dch NaOH nhit thng. Tnh nng mol ca NaOH phn ng v ca dung dch thu c. 12. Cho 500ml dung dch AgNO3 0,5M tc dng vi 200g dung dch HCl 5,475%.(D = 0,5g/ml). a. Tnh khi lng cc cht thu c sau phn ng. b. Tnh nng mol cc cht thu c sau phn ng.

B. TRC NGHIM:
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Trng THPT chuyn Nguyn nh Chiu

Gv: Nguyn Hoi Hn

1. Cu hnh e lp ngoi cng ca cc nguyn t cc nguyn t halogen l: A. ns2np4. B. ns2p5. C. ns2np3. D. ns2np6. 2. trng thi c bn cc nguyn t halogen c my e c thn? A. 1 B. 5. C. 3. D. 7. 3. Lin kt trong cc phn t n cht halogen l g? A. cng ha tr khng cc. B. cng ha tr c cc. C. lin kt ion. D. lin kt cho nhn. 4. Cht no c tnh kh mnh nht? A. HI. B. HF. C. HBr. D. HCl. 5. Trong phn ng clo vi nc, clo l cht: A. oxi ha. B. kh. C. va oxi ha, va kh. D. khng oxi ha, kh 6. Thuc th ca axit clohidric v mui clorua l: A. ddAgNO3. B. dd Na2CO3. C. ddNaOH. D. phenolphthalein. 7. Hp cht no c tnh oxi ha mnh nht? A. HClO. B. HClO2. C. HClO3. D. HClO4. 8. Trng thi ng ca brom l: A. rn B. lng. C. kh. D. tt c sai. 9. Cho dy axit: HF, HCl,HBr,HI. Theo chiu t tri sang phi tnh cht axit bin i nh sau: A. gim. B. tng. C. va tng, va gim. D. Khng tng, khng gim. 10. Hy la chn phng php iu ch kh hidroclorua trong phng th nghim: A. Thy phn AlCl3. B. Tng hp t H2 v Cl2. C. clo tc dng vi H2O. D. NaCl tinh th v H2SO4c. 11.Axit khng th ng trong bnh thy tinh l: A. HNO3 B. HF. C. H2SO4. D. HCl. 12. Dung dch AgNO3khng phn ng vi dung dch no sau y? A. NaCl. B. NaBr. C. NaI. D. NaF. 13. Cho phn ng: SO2 + Cl2 + 2H2O 2HCl + H2SO4. Clo l cht: A oxi ha. B. kh. C. va oxi ha, va kh. D. Khng oxi ha kh 14. c im no khng phi l c im chung ca cc halogen? A. u l cht kh iu kin thng. B. u c tnh oxi ha mnh. C. Tc dng vi hu ht cc kim loi v phi kim. D. Kh nng tc dng vi nc gim dn t F2 n I2. 15. Trong phng th nghim clo c iu ch t ha cht no sau y? A. KClO3 B. NaCl. C. MnO2. D. HClO. 16. Theo chiu tng in tch ht nhn th kh nng oxi ha ca cc halogen n cht: a. tng dn. B. gim dn. C. khng thay i. D. va tng, va gim. 17. Cc halogen c tnh cht ha hc gn ging nhau v c cng: A. cu hnh e lp ngoi cng. B. tnh oxi ha mnh. C. s e c thn. D. s lp e. 18. Khi m vi nc my, nu ch mt cht s pht hin mi l. l do nc my cn lu gi vt tch ca thuc st trng. chnh l clo v ngi ta gii thch kh nng dit khunl do: A. clo c nn c tnh st trng. B. clo c tnh oxi ha mnh. C. clo tc dn vi nc to ra HClO cht ny c tnh oxi ha mnh. D. mt nguyn nhn khc. 19. Axit clohidric c th tham gia phn ng oxi ha kh vi vai tr: A. cht kh. B. cht oxi ha. C. mi trng.D. tt c u ng. 3

Trng THPT chuyn Nguyn nh Chiu Gv: Nguyn Hoi Hn 20.Trong cc kim loi sau y, kim loi no khi t dng vi clo v axit clohidric cho cng mt loi mui? A. Zn. B. Fe. C. Cu. D. Ag 21. Cht no sau y c ng dng dung trng phim nh? A. NaBr. B. AgCl. C. AgBr. D. HBr. 22. Thuc th phn bit dung dch KI l. A. Qu tm. B. Clo v h tinh bt C. h tinh bt. D. dd AgNO3. 23. Dy cc cht no sau y u tc dng vi axit clohidric? A. Fe2O3, KMnO4, Cu, Fe, AgNO3. B. Fe2O3, KMnO4Fe, CuO, AgNO3. C. Fe, CuO, H2SO4, Ag, Mg(OH)2. D. KMnO4, Cu, Fe, H2SO4, Mg(OH)2. 24. Clorua vi l: A. Mui to bi kim loi lin kt vi mt gc axit. B. Mui to bi kim loi lin kt vi hai gc axit. C. Mui to bi hai kim loi lin kt vi mt gc axit. D. Clorua vi khng phi l mui. 25. Cho phn ng: Cl2+ 2 NaBr 2 NaCl + Br2. nguyn t clo: A. ch b oxi ha. B. ch b kh. C. va b oxi, va b kh. D. Khng b oxi ha, khng b kh. 26. Ti sao ngi ta iu ch c nc clo m khng iu ch c nc flo. A.V flo khng tc dng vi nc. B. V flo c th tan trong nc. C. V flo c th bc chy khi tc dng vi nc. D. V mt l do khc. 27. Cht no sau y c ta tt nht? A. AgI. B. AgCl. C. AgBr. D. AgF. 28. Thuc th nh ra iot l: A. h tinh bt. B. nc brom. C. phenolphthalein. D. Qu tm. 29 Phn ng no chng t HCl l cht kh? A. HCl + NaOH NaCl + H2O. B. 2HCl + Mg MgCl2+ H2 . C. MnO2+ 4 HCl MnCl2+ Cl2 + 2H2O. D. NH3+ HCl NH4Cl.