M phng HYSYS qu trnh lm kh kh bng pp hp th MEG

1 | P a g e

1
LHDK52 Nhm 5
Li M u
Kh ng hnh v kh thin nhin khai thc t lng t thng bo ha hi
nc v hm lng hi nc ph thuc vo p sut, nhit , v thnh phn ha hc
ca kh. Mi mt gi tr nhit v p sut tng ng vi hm lng nc cc i
c th nht nh. Hm lng m tng ng vi hi nc bo ha ti a c gi l
m cn bng.
Hm lng hi nc trong kh ng hnh v kh thin nhin cn phi bit v
hi nc c th b ngng t trong cc h thng cng ngh x l sau ny, hnh thnh
cc hydrat ( cc tinh th cht rn ) d ng cc chim cc khong khng trong cc
ng dn hay cc thit b, ph v iu kin lm vic bnh thng i vi cc dy
chuyn khai thc, vn chuyn v ch bin kh. Ngoi ra s c mt ca hi nc v
cc hp cht cha lu hunh ( H
2
S v cc cht khc ) s l tin thc y n mn
kim loi, lm gim tui th v thi gian s dng ca cc thit b, cng trnh.
Trc nhng nguy c v tc hi to ln ca hi nc c mt trong kh thin
nhin v kh ng hnh trong cc quy trnh cng ngh th vic lm kh kh sao cho
t yu cu v tiu chun k thut l mt nhim v bt buc m bo kh nng
hot ng n nh v hiu qu ca cc dy chuyn cng ngh ch bin cc sn phn
kh sau ny. Kh c sy kh vi mc ch tch hi nc v to ra cho kh c nhit
im sng theo nc thp hn vi nhit cc tiu m ti kh c vn
chuyn hay ch bin.
Do vy, mc ch ca n ny l thit k mt s cng ngh lm kh kh
bng phng php Hp th dng MonoEtylenGlycol (MEG) bng phn mm m
phng Hysys.
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
2 | P a g e

2
LHDK52 Nhm 5
Chng I - Tng quan v qu trnh cng ngh sy kh kh

I. C s l thuyt
Hydrat l nhng hp cht c th tn ti mt cch bn vng di dng tinh th.
Thc cht l nhng dung dch rn, trong cc phn t nc dung mi nh cc lin
kt hydro to thnh khung hydrat. Trong cc khoang ca khung ny cc phn t
kh c kh nng to hydrat nh metan, etan, propan, isobutan, nit, H
2
S, CO
2
, argon
s chim ch. Cc hydrocacbon vi phn t ca n c th xm nhp vo khung
cng vi cc phn t kh c kch thc nh hn, dn ti thay i p sut cn bng
trn cc hydrat. Mc chim ch trong khung ca cc phn t kh to hydrat i
vi thnh phn kh cho ch yu ph thuc vo p sut v nhit ca h. Cc
tinh th hydrat hnh thnh trn b mt phn chia pha ca h kh-nc. Nc t do
cn li sau khi hnh thnh cc hydrat ch tip tc chuyn thnh trng thi hydrat
khi c s khuy trn cc pha v khi c nhng iu kin nhit ng thch hp. Khi
khng c s khuy trn th qu trnh khuch tn ca kh qua lp mng cng ca cc
hydrat rt kh khan v s pht trin lin tc ca cc hydrat s khng xy ra.
iu kin hnh thnh cc hydrat ngoi ra cn ph thuc vo hm lng ca
mui c trong nc, hm lng ca chng tng s dn n gim nhit bt u
to thnh hydrat. Nhit ny cng ph thuc vo thnh phn kh, v d nhit
bt u to thnh hydrat ca metan khi c mt propan, CO
2
, H
2
S s thp hn so vi
khi vng mt cc cht ny. Hnh dng ca hydrat rt a dng, n c xc nh bi
thnh phn kh v cc iu kin nhit ng hc. Thng thng v hnh dng chng
ging nh nc hay tuyt m nn.
Nhm ngn nga s hnh thnh cc hydrat ngi ta s dng rng ri phng
php c ch tc l phng php a vo dng kh cc cht khc nhau gi l cc
cht c ch lm h nhit to thnh hydrat nh methanol, glycol v phng
php lm kh (tch nc) kh da trn c s tch hi nc ra khi kh bng cc cht
hp th lng hoc rn.
- Phng php c ch: thc cht l cho cht c ch vo dng kh m, cht c ch
s tan trong nc t do, kt qu l lm gim p sut hi nc v h nhit to
thnh hydrat. Hin nay cc cht c ch ngn nga s to thnh hydrat thng dng
nht l:
o S dng cht c ch l methanol, cn c khu vc kh hydrat v khu vc
kh axit.
o S dng cht c ch glycol
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
3 | P a g e

3
LHDK52 Nhm 5
Trong thc t thng s dng cc loi glycol: EG, DEG,TEG vi nng
khong 60 - 80 % khi lng. Vic la chn mt loi glycol s dng t
hiu qu cao chomt qu trnh x l kh no ph thuc vo :
T ng c v nht ca dung dch glycol ;
h T to hydrate i vi nng glycol cho ;
kh nng ha tan ca glycol trong HC ngng t ;
thnh phn kh.
h T im sng ca kh ph thuc vo loi cht c ch,nng ca n v
T kh tip xc vi cht c ch .
Nhng u im m cc glycol c c
Glycol Metanol
Khng gy c vi ngi v mi
trng.
Gy c hi vi ngi v mi trng.
C p sut hi bo ha rt thp v c
kh nng thu hi rt cao bng phng
php vt l n gin l c c cc dung
dch nc cha glycol.
p sut hi bo ha cao do vy kh
tch ra khi dng kh, vic ti sinh n
rt phc tp nn vic tiu hao cht c
ch l ln.
Nhit si cao nn kh b bay hi.
Trnh mt mat khi thit b.
Nhit si thp nn kh nng tht
thot l rt cao.
Khng gy n mn cho thit b. Mt s phn xng i khi cn thit k
thm cc thit b loi axit c th sinh
ra.

- Phng php hp ph: cc phng php hp ph cho php t im sng theo
m trong khong 100200
o
C v sy su kh n im sng -85 -100
o
C. Cc
cht hp ph c th chia thnh : Boxit l khong thin nhin cha ch yu l oxit
nhm ; oxit nhm hot ha l Boxit lm sch ; cc loi Gel l nhng hp cht
cu to t oxit silic v alumogel ; cc ry phn t l cc zeolite. Cc cht hp ph
c b mt ring rt ln ( 500-800 m
2
/g ) v b mt ny c to thnh t cc mao
qun hay mng tinh th. Cc qu trnh hp ph c th thc hin gin on trong
cc thit b vi tng thp hp ph c nh hoc lin tc vi cc thit b cha cc
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
4 | P a g e

4
LHDK52 Nhm 5
lp hp ph chuyn ng. Tuy nhin cc qu trnh lin tc rt t kh c s dng
do cc thit b cng ngh rt phc tp.

- Phng php thm thu kh: Cho n nay, qu trnh dehydrat ha bng thm thu
kh hu nh khng cn c s dng trong cng nghip x l kh na do nhng
yu cu k thut qu cao ca qu trnh. dshydrat ha kh bng thm thu phi
la chn nhng hp cht cao phn t thch hp c ij rt ln, khong 200.000 (vi
loi mng mng ng th v khng h c khuyt tt) v khong 300 500 (vi
loi chm si rng). Hn na, phi chp nhn mt lng C
1
thm thu qua mng
lc mng lc c chn c b mt ring khng qu ln.

- Phng php hp th: phng php hp th c s dng rng ri sy kh
kh ti cc cng trnh ng dn kh cng nh trong cc nh my ch bin kh. Cht
hp th sy kh l nhng dung dch nc m c ca mono- , di- v
trietylenglycol. S sy kh kh bng cc cht hp th ny da trn s khc bit v
p sut ring phn ca hi nc trong khng kh v trong cht hp th. Gi tr
im sng ca kh c m bo bng dung dch Glycol.
So snh u nhc im ca cc dung mi hp th nc:
u im Nhc im
MEG
t tan trong kh ngng t. Dung
dch m c khng b ng c.
nht thp tng kh nng tip
xc vi hn hp kh. C kh nng
ngn nga to hidrat cao hn DEG
v TEG
p sut hi bo ha cao
hn DEG v TEG. Nhng
ha tan trong HC cao
hn DEG v TEG
DEG
ht m cao, kh bn khi c mt
cc hp cht lu hunh, O
2
v
CO
2
nhit thng. Dung dch
m c khng b ng c.
nhit cao c chn lc cao
Tiu hao do tht thot cao
hn TEG. Khi ti sinh kh
thu c DEG nng
>95%. im sng thp
hn so vi TEG. Gi thnh
cao
TEG
ht m cao. To im sng
cho kh sy cao (27.8 47.3
o
C)
bn cao khi c mt cc hp cht
lu hunh, O
2
v CO
2
nhit
i hi chi ph u t cao.
Dung dch TEG c kh
nng to mng khi c mt
cc HC nh. ha tan
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
5 | P a g e

5
LHDK52 Nhm 5
u im Nhc im
bnh thng. Khi ti sinh d thu
c nng cao >99%. Dung
dch khng b ng c. bay
hi TEG thp hn DEG
ca cc HC nh trong TEG
cao hn DEG
Metanol
Gi thnh r. c s dng ch
yu trong cc h thng vn
chuyn. iu kin thng dung
dch m c khng b ng c.
C nht thp nht nn kh nng
tip xc vi hn hp kh l cao
hn cc glicol
C p sut ring phn cao
ln kh tch ra khi kh khi
ti sinh. Tiu hao ln

c tnh vt l ca cc Glycol v Metanol (dng lm kh kh)
C TNH VT
L
MEG DEG TEG TREG METANOL
Cng thc
H
3
C-
CH
2
-
CH
2
-OH
HO-
(CH
2
-
CH
2
-
O)
2
-H
HO-
(CH
2
-
CH
2
-
O)
3
-H
HO-
(CH
2
-
CH
2
-
O)
4
-H
CH
3
OH

KLPT 62.1 106.1 150.2 194.2 32.04
im si p
sut 760mmHg,
(
o
C)
197.3 224.8 285.5 314 64.5
p sut hi
25
o
C, (mmHg)
0.12 <0.01 <0.01 <0.01 120
Khi lng ring
25
o
C, (g/ml)
1.110 1.113 1.119 1.120 0.790
Khi lng ring
25
o
C,
(pound/usgall)
9.26 9.29 9.34 9.34 6.59
im ng c,
(
o
C)
-13.3 -8.3 -7.2 -5.6 -97.8
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
6 | P a g e

6
LHDK52 Nhm 5
C TNH VT
L
MEG DEG TEG TREG METANOL

nht
ng
lc
(cP)

25
o
C

16.5
28.2 37.3 44.6 0.52

60
o
C

4.68
6.99 8.77 10.2 -
Sc cng b mt
25
o
C (dyn/cm)
47 44 45 45 22.5
Ch s khc x
25
o
C
1.430 1.446 1.457 1.457 20.328
Nhit dung ring
25
o
C (kj/kg.
o
C)
0.75 0.71 0.69 0.67 0.78
im chp chy
cc kn (
o
C)(flash
point)
115.6 123.9 1.769 204.4 12.0
im chp chy
cc h (
o
C) (fire
point)
118.3 143.3 165.6 190.6 -
Nhit

phn
hy
o
F 329 328 404 460 -
o
C 165 206.7 206.7 237.8 -










M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
7 | P a g e

7
LHDK52 Nhm 5
II. S nguyn tc cng ngh sy kh kh bng phng php hp th
dng Glycol [1]

Thit b Dng vt cht
1. Thp hp th I. Kh nguyn liu m
2, 4. T.B Trao i nhit II. Kh lm kh
3. TB thi kh tch HC ha tan III. Dng glycol giu
5. Thp ti sinh IV. Dng kh thi ra
6. TB gia nhit V. Dng glycol b sung nu cn
7. TB lm ngui VI. Dng glycol ti sinh (glycol ngho)
8. Bn cha VII. Dng hi nc (cha 1 t glycol)
9. Bm
iu kin hot ng
- Thp hp th (1):
+ Nhit thp (15 38
o
C)
+ p sut cao (60 85 bar)
- Thp ti sinh (5):
+ Nhit cao: T
nh
(115
o
C) T
y
T
p.hy glycol

+ p sut thp (1 1.2 bar)


M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
8 | P a g e

8
LHDK52 Nhm 5
Chng II - Tnh ton cc thng s c bn ca thp lm
kh kh bng phng php hp th dng
MonoEtylenGlycol
I. D liu ban u :[3]
- Thnh phn kh :
Cu t C
1
C
2
C
3
n-C
4
i-C
4
n-C
5
n-C
6
N
2
He
%V 82.0 4.7 3.8 2.5 2.8 1.5 1.2 1.0 0.5
- Nhit kh nguyn liu : 50
o
C
- Lu lng kh nguyn liu : 5.10
6
m
3
/ngy m
- p sut kh nguyn liu : 68 Bar
- p sut kh kh : 66 Bar
- im sng kh kh : 10
o
C
- Cht hp th MEG (Mono Etylen Glycol)
- Lu lng ring cht hp th 30 Kg/Kg H
2
O

II. Yu cu tnh :
- Nng ti thiu ca Glycol
- Lng dung dch tun hon/h (kg/h, kmol/h)
- S a l thuyt ca thp
- ng knh thp
- Chiu cao thp

III. Cc bc tnh ton [1]
Bc 1 : C th ha cc s liu ban u
Lu lng kh nguyn liu 5.10
6
m
3
/ngy m = 208333,33 m
3
/h
p sut kh nguyn liu 68 Bar = 6,8 MPa
p sut kh kh 66 Bar = 6,6 Mpa
Khi lng phn t trung bnh ca kh nguyn liu
H = Hi Ci

Trong : M
i
khi lng phn t ca cu t i
C
i
phn trm cu t i
o M = 21,68 vc
o T trng kh (coi t trng bng khi lng ring)
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
9 | P a g e

9
LHDK52 Nhm 5
J =
H P
RI
=
21,68 68
8,S14 (27S + Su)
= u,SS

Bc 2 : Xc nh nng Glycol ti sinh ti thiu
Da vo nhit tip xc (c nhn bng nhit ca kh cn sy kh) v
im sng ca kh sy kh xc nh nng ca Glycol ti sinh ti thiu
min

cn thu c im sng cho trc ca kh thng qua s hnh II.5 (trang 96
[1]), gin ny phn nh cc gi tr cn bng, m trong iu kin thc t khng t
c, nn xc nh nng Glycol theo th ny ta phi nhn im sng ca
kh thp hn gi tr cho 5-8
o
C.
Ta chn nhit im sng thp hn gi tr cho 8
o
C, tc nhit im
sng l 2
o
C. Da vo th hnh II.5 suy ra :
Nng Glycol ti sinh ti thiu
min
= 96%

Bc 3 : Xc nh hm m ca kh cn sy kh
Da vo th hnh II.1 (trang 90 [1]) xc nh hm m ca kh cn sy kh

1
v ca kh sy kh
2
(Do t trng ca kh l 0,55 nh hn 0,6 nn ta khng cn
h s hiu chnh hm m)
Vi kh nguyn liu iu kin T = 50
o
C ; 6,8 Mpa

1
= 1,65 g/m
3
= 0,00165 kg/m
3

Vi kh kh p sut 6,6 MPa v c nhit im sng l 10
o
C

2
= 0,19 g/m
3
= 0,00019 kg/m
3


Bc 4 : Tnh lu lng cht hp th ti sinh
L
1
= V*(
1
-
2
)*l (kg/h)
Trong : V l th tch kh nguyn liu (m
3
/h)
l l lu lng ring cht hp th (kg/kg H
2
O)

1
,
2
l hm m ca kh cn sy kh v kh sy kh (kg/ m
3
)
o L
1
= 208333,33*(0,00165 0,00019 )*30 = 9125 (kg/h)

Bc 5 : Tnh nng Glycol bo ha xc nh theo phng trnh cn bng vt
cht da trn m trong pha lng v kh

2
=
L
1

1
L
1
+(
1

2
)v

Ta chn nng ban u ca dung dch Glycol l
1
= 99% ln hn nng ti thiu
ca Glycol l
min
= 96%
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
10 | P a g e

10
LHDK52 Nhm 5
T suy ra :

2
=
L
1

1
L
1
+ (
1

2
)v
=
912S 99
912S + (u,uu16S u,uuu19) 2u8SSS,SS
= 9S,8%

Bc 6 : Tnh lng dung dich Glycol bo ha sau khi hp th
I
2
= L
1
+ (
1

2
)v
I
2
= 912S + (u,uu16S u,uuu19) 2u8SSS,SS = 9429,2 kgh

Bc 7 : Tnh hng s cn bng theo phng trnh
K =

2
{(1
1
)N
0
+18
1
]
748,44N
0
(1
1
)

Trong M
0
l khi lng phn t ca cht hp th M
MEG
= 62 vc
K =
u,19{(1 u,99)62 +18 u,99]
748,44 62(1 u,99)
= 7,SS. 1u
-3


Bc 8 : Xc nh yu t hp th A theo cng thc
A =
L
i
Kv
i

Trong :
L

l lu lng lng dung mi vo thp tnh ra Kmol/h

V

lu lng kh cn lm kh tnh ra Kmol/h

- Xc nh L

t L
1
: theo tnh ton trn ta c L
1
= 9125 kg/h. Khi lng phn
t trung bnh ca dung mi hp th c tnh theo cng thc
N
tb
=
9962+181
100
= 61,S6
o L
i
=
L
1
M
tb
=
9125
61,56
= 148,2S kmolh
- Xc nh V

t V : theo trn ta c V = 208333,33 m

3
/h.
o v
i
=
V
23,6
=
208333,33
23,6
= 8827,7 kmol/h
Vy :
A =
148,2S
7,SS. 1u
-3
8827,7
= 2,224

Bc 9 : H s tch m thc t ca qu trnh hp th

tt
=

1

2

1
=
1,6S u,19
1,6S
= u,88S
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
11 | P a g e

11
LHDK52 Nhm 5
Bc 10 : H s tch l thuyt khi tnh ton c ch n lng nc trong
glycol ti sinh

It
=

tt

n+1

n+1
K X
0

Trong : X
0
l nng phn mol ca nc trong cht hp ph ti sinh
X
0
=
1
1
18
1
1
18
+

1
62
=
1 u,99
18
1 u,99
18
+
u,99
62
= u,uSS6
Y
n+1
l phn mol nc trong kh cn sy kh
Ta c :
1
= 1,65 g/m
3
= 0,092 mol/m
3

Mt khc 1m
3
kh nguyn liu c s mol l : n = 1*0,55*10
3
/21,68 = 25,369 mol
o Y
n+1
= 0,092/25,369 = 3,626.10
-3

o
It
=
0,8853,62610
-3
3,62610
-3
-7,5510
-3
0,0336
= u,9S

Bc 11 : Tnh s a l thuyt
Ta c :
It
=
A
n+1
-A
A
n+1
-1

o (n+1)lg A = lg
q
lt
-A
q
lt
-1

o n = 3,05

Bc 12 : Tnh s a thc t
Theo kinh nghim thc t th hiu sut lm vic ca a l t 0,25-0,4
Ta chn hiu sut lm vic ca a l : = 0,35
n
tt
=
n
It

=
S,uS
u,SS
= 8,7
Vy s a thc t ca thp hp th l 9 a
Bc13 : Tnh ng knh thp hp th
= u,u114
_
u,1I
. P
( m )
Trong : Q l lu lng kh nguyn liu m
3
/s
T l nhit kh nguyn liu K
P p sut kh Mpa
vn tc tuyn tnh ca dng kh trong thp (0,05-0,15 m/s)
Chn = 0,13 m/s
M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
12 | P a g e

12
LHDK52 Nhm 5
o = u,u114_
0,11
m.P
= u,u114
_
0,1[
208333,33
3600
323
0,136,8
= u,S24 m
Bc 14 : Tnh chiu cao thp hp th
H = N
tt
*d + h
Trong : d l khong cch gia 2 a 0,5-0,6 m
h l chiu cao vm nh v y thp 1-1,2 m
Chn d = 0,6 m v h = 1,2 m
o H = 9*0,6 + 1,2 = 6,6 m
Vy chiu cao thp l 6,6 m



M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
13 | P a g e

13
LHDK52 Nhm 5
Chng III - M phng qu trnh cng ngh lm kh kh
bng MEG bng phn mm Hysys
I. Thng s u vo ca dng, thit b :[3]
- Thnh phn kh :
Cu t C
1
C
2
C
3
n-C
4
i-C
4
n-C
5
n-C
6
N
2
He
%V 82.0 4.7 3.8 2.5 2.8 1.5 1.2 1.0 0.5
- Nhit kh nguyn liu : 50
o
C
- Lu lng kh nguyn liu : 5.10
6
m
3
/ngy m
- p sut kh nguyn liu : 68 Bar
- p sut kh kh : 66 Bar
- im sng kh kh : 10
o
C
- Cht hp th MEG ( Mono Etylen Glycol )
- Lu lng ring cht hp th 30 Kg/Kg H
2
O
iu kin hot ng
- Thp hp th:
+ Nhit thp (15 38
o
C)
+ p sut cao (60 85 bar)
- Thp ti sinh:
+ Nhit cao: T
nh
(115
o
C) T
y
T
p.hy glycol

+ p sut thp (1 1.2 bar)

II. S PFD sau khi rt gn:


M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
14 | P a g e

14
LHDK52 Nhm 5
III. Tin hnh m phng:
1. nh ngha c s m phng:
S dng h nhit ng Peng-Robinson vi cc cu t nh sau: C
1
, C
2
, C
3
, n-C
4
,
i-C
4
, n-C
5
, n-C
6
, N
2
, He, EGlycol, H
2
O.
2. Nhp cc dng nguyn liu:
Do kh ng hnh v kh thin nhin khai thc t lng t thng bo ha hi
nc v hm lng hi nc ph thuc vo p sut, nhit , v thnh phn ha
hc ca kh. Mi mt gi tr nhit v p sut tng ng vi hm lng nc
cc i c th nht nh nn:
- S dng th II.1 (trang 90-[1]) nh trong bc 3, ta xc nh c hm
lng nc trong kh nguyn liu l 0,00165 (kg/m
3
), suy ra lu lng nc
trong kh nguyn liu l: 0,00165*208333.33/18 = 19,09 (kmol/h).
- Ta s nhp 2 dng kh u vo gm kh nguyn liu (cha tnh lng nc) v
hm m ca n, sau cho qua my trn c dng kh nguyn liu thc:
a. Dng khi nguyen lieu
Name khi nguyen lieu
Worksheet / Condition
Temperature 50
o
C
Pressure 6800 kPa
Molar Flow 8828 kgmole/h
Worksheet /
Composition
Mole Fractions
C
1
0.820
C
2
0.047
C
3
0.038
n-C
4
0.025
i-C
4
0.028
n-C
5
0.015
n-C
6
0.012
N
2
0.010
He 0.005
EGlycol 0.000
H
2
O 0.000


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b. Dng ham am
Name ham am
Worksheet / Condition
Temperature 50
o
C
Molar Flow 19.09 kgmole/h
Worksheet /
Composition
Mole Fractions
C
1
0.000
C
2
0.000
C
3
0.000
n-C
4
0.000
i-C
4
0.000
n-C
5
0.000
n-C
6
0.000
N
2
0.000
He 0.000
EGlycol 0.000
H
2
O 1.000

3. Nhp cc thit b:
a. Mixer
Nhp mt thit b trn vi cc thng s sau:
Name Mix-100
Design / Connection
Inlets
khi nguyen lieu
ham am
Outlets khi nglieu sau tron
Design / Parameter
Automatic Pressure Assignment Equalize All
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b. Cooler
Qua th nghim m phng cng vi iu kin vn hnh thp hp th t 15
38
o
C, ta nhp mt thit b lm lnh m bo dng kh nguyn liu nhit
lm vic ca thp.
Name lam lanh1
Design / Connection
Inlet khi nglieu sau tron
Outlet khi vao tach nc tu do
Energy Q1
Design / Parameter
Delta P 0 kPa
Worksheet / Condition
Temperature (khi vao tach nc tu do) 30
o
C

c. Separator
Nhp bnh tch tch nc t do trong dng kh nguyn liu, m bo cho
dng kh nguyn liu vo thp hp th khng c ln pha lng.
Name tach nc tu do
Design / Connection
Inlets khi vao tach nc tu do
Vapour Outlets khi di hap thu
Liquid Outlets nc tu do

d. Absorber Column
Name thap hap thu
Design / Connection
No. of Stage 9
Top stage inlet Glycol ngheo
Bottom stage inlet khi di hap thu
Ovhd Vapour outlet Khi kho
Bottom liquid oulet Glycol giau1
Pressure
Top 6600 kPa
Bottom 6800
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LHDK52 Nhm 5
Rating / Tray Sections
Diameter 0.5 m

e. Valve
Nhp mt van gim p gim p sut ca dng glycol giau1 xung p
sut ph hp vi iu kin ca thp ti sinh (t 1 1,2 bar).
Name VLV-100
Design / Connection
Inlet Glycol giau1
Outlet Glycol P thap
Worksheet / Condition
Pressure (Glycol P thap) 110 kPa


f. Heat Exchanger
Nhp 1 thit b trao i nhit un nng s b dng Glycol P thap bng
dng nng ra khi y thp ti sinh.
Name Trao doi nhiet1
Design / Connection
Tube Side Inlet Glycol ngheo1
Tube Side Outlet Glycol ngheo2
Shell Side Inlet Glycol P thap
Shell Side Outlet Glycol giau2
Design / Parameter
Heat Ex. Mode Weighted
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LHDK52 Nhm 5
Worksheet / Condition
Pressure (Glycol ngheo2) 40 kPa
Temperature (Glycol giau2) 115
o
C

g. Seperator
Nhp thm mt thit b tch ui kh HC ha tan trong ging glycol giu
ra khi thp hp th.
Name Thap tach HC
Design / Connection
Inlets Glycol giau2
Vapour Outlets HC thoi ra
Liquid Outlets Glycol giau3
Worksheet / Condition
Pressure (Glycol giau3) 110 kPa

h. Distillation Column
Nhp 1 thp chng ct thc hin vic ti sinh glycol giu vi iu kin
vn hnh cho trn.
Name Thap tai sinh
Design / Connection
No. of Stages 9
Inlet Streams Glycol giau3
Reb. Ener. Stream Reb Q
Bott. Liquid Outlet Glycol ngheo1
Condender Full Rflx
Ovhd Vapour Outlet Hoi nuoc
Cond. Ener. Stream Cond Q
Optional Side Draws Sp suon thap ts
Draw Stage 3
Pressure
Cond. Pressure 70 kPa
Cond. Pressure Drop 15 kPa
Reb. Pressure 100 kPa
Temperature
Reb. Tem. Estimate 160
o
C
Refulx Ratio 1.5
Vapour Rate 0.3 kgmole/h
Design / Specs
Sp suon thap ts (Spec. Value) 45 kgmole/h
Parameters / Profiles
Temp. 7_MainTS 160
o
C
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LHDK52 Nhm 5
8_MainTS 160
o
C
9_MainTS 160
o
C



i. Mixer
Nhp mt thit b trn th 2 m bo lu lng v nng ca dng
glycol ngho ti sinh s dng c cho thp hp th.
Name Mix-101
Design / Connection
Inlets
Glycol bo sung
Glycol ngheo2
Outlets Glycol ngheo P thap
Design / Parameter
Automatic Pressure Assignment Equalize All
Worksheet / Condition
Temperature (glycol bo sung) 20
o
C
Pressure (glycol ngheo2) 40 kPa

j. Pump
Nhp mt bm tng p sut ca dng glycol ti sinh ti p sut lm vic
ca thp hp th.
Name P-100
Design / Connection
Inlet Glycol ngheo P thap
Outlet Glycol ngheo P cao
Energy Pump Q
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LHDK52 Nhm 5
Worksheet / Condition
Pressure (Glycol ngheo P cap) 6670 kPa

k. Cooler
Nhp mt thit b lm lnh th 2 lm lnh dng glycol ngho ti sinh ti
nhit lm vic thp hp th.
Name lam lanh2
Design / Connection
Inlet Glycol ngheo P cao
Outlets Glycol ngheo
Energy Q2
Design / Parameter
Delta P 70 kPa
Worksheet / Condition
Temperature (glycol ngheo) 25
o
C
Pressure (glycol ngheo) 6600 kPa
Molar Flow (glycol ngheo) 148.2 kgmole/h
Worksheet / Composition / glycol
ngheo
Mole Fractions
C
1
0.000
C
2
0.000
C
3
0.000
n-C
4
0.000
i-C
4
0.000
n-C
5
0.000
n-C
6
0.000
N
2
0.000
He 0.000
EGlycol 0.990
H
2
O 0.010







M phng HYSYS qu trnh lm kh kh bng pp hp th MEG
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IV. Kt qu v phn tch

Da vo bng Datasheet ca dng kh lm kh ta thy rng lng hm lng
nc trong kh nguyn liu sau khi qua x l gim hn, phn trm th tch ca
nc trong kh lm kh l 0% v coi nh mc ch ca qu trnh thc hin
c.
Tuy nhin, qu trnh m phng thit k vn cn nhiu vn cn c khc
phc nh: vic ti u cc thit b cha thc hin c, qu trnh tnh ton bng tay
v m phng cn nhiu im cha so snh c,.

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LHDK52 Nhm 5
Ph lc (nh km)
1. S PFD c show table:

2. Workbook
3. Case Studies
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LHDK52 Nhm 5
Ti liu tham kho
[1]. MA. Berlin, VG. Gortrencop, HP. Volcop. Ngi dch Hong Minh Nam,
Nguyn Vn Phc, Nguyn nh Soa, Phan Minh Tn. Hiu nh Nguyn nh
Soa. Cng ngh ch bin kh thin nhin v kh du m, HKT-TPHCM.
[2]. Nguyn Th Minh Hin (2004), Cng ngh ch bin kh t nhin v kh ng
hnh, NXB KHKT, H Ni.
[3]. S liu t thy gio, TS. Nguyn Danh Nhi, H M a Cht.
[4]. Process Modeling using HYSYS.
[5]. Ngun Internet.

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Mc lc
Li M u ........................................................................................................................... 1
Chng I - Tng quan v qu trnh cng ngh sy kh kh ................................................... 2
I. C s l thuyt ............................................................................................................ 2
II. S nguyn tc cng ngh sy kh kh bng phng php hp th dng Glycol [1] . 7
Chng II - Tnh ton cc thng s c bn ca thp lm kh kh bng phng php hp th
dng MonoEtylenGlycol ........................................................................................................ 8
I. D liu ban u :[3]..................................................................................................... 8
II. Yu cu tnh : .......................................................................................................... 8
III. Cc bc tnh ton [1].............................................................................................. 8
Chng III - M phng qu trnh cng ngh lm kh kh bng MEG bng phn mm Hysys
........................................................................................................................................... 13
I. Thng s u vo ca dng, thit b :[3] ..................................................................... 13
II. S PFD sau khi rt gn: ................................................................................ 13
III. Tin hnh m phng: ............................................................................................. 14
IV. Kt qu v phn tch .............................................................................................. 21
Ph lc (nh km) .............................................................................................................. 22
Ti liu tham kho ............................................................................................................... 23
Mc lc ............................................................................................................................... 24