2011 - Ly Thuyet &amp Bai Tap Ve Cacbonhidrat

TT LUYN THI & BI DNG KIN THC NGY MI 18A/88 INH VN T - TP.
HI DNG
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CHUYN

L THUYT BI TP
CACBONHIRAT

Hi Dng, thng 11 nm 2011
TI LIU LUYN THI & BI DNG KIN THC NM 2011
MT S CU HI V DNG TON THNG GP CA CHNG

DNG 1: PHN NG PHN NG OXI HA KHNG HON TON

- Cc cht tham gia phn ng: Glucozo; fructozo v mantozo
- Phn ng xy ra nh vi andehit n chc
+ Oxi ha bng AgNO
3
/NH
3
(phn ng trng gng)
| |
3 2 4 3 2
2 ( ) 2 3 R CHO Ag NH OH RCOONH Ag NH H O + + + +
Vy ta c: 2.
Ag R CHO
n n

=
+ Oxi ha bng Cu(OH)
2
/OH
-
, t
0
(c kt ta gch ca Cu
2
O)
2 2 2
2 ( ) 3 R CHO Cu OH NaOH RCOONa Cu O H O + + + +
Vy ta c:
2
Cu O R CHO
n n

=
A Khi lm bi tp ta cn ch v cch lm theo s ha bi ton nh sau:
3
2
2
AgNO
R CHO Ag
+

2
2 ( )
2
Cu OH
R CHO Cu O
A Glucozo, mantozo lm mt mu dung dch Br
2
, KMnO
4
cn fructozo th khng c phn ng ny

BI TP MINH HA

Cu 1: Cho 50ml dung dch glucozo cha r nng tc dng vi mt lng d AgNO
3
trong dung dch NH
3

thu c 2,16 gam kt ta Ag. Nng mol ca dung dch gulozo.
A. 0,20M B. 0,10M C. 0,01M D. 0,02M
Cu 2: Ha tan 70,2 gam hn hp X gm glucozo v saccaozo vo nc thu c dung dch Y. Cho dung dch
Y tc dng vi dung dch AgNO
3
/NH
3
(ly d), un nng th thu c 43,2 gam. Thnh phn % khi lng ca
cacbohidrat c trong hn hp X.
A. 51,282% B. 48,718% C. 74,359% D. 97,436%
Cu 3: Chia 200 gam dung dch hn hp gm glucozo v fructozo thnh 2 phn bng nhau:
- Phn 1: Cho tc dng vi lng d dung dch AgNO
3
/NH
3
thu c 86,40 gam Ag.
- Phn 2: Mt mu va ht dung dch cha 35,2 gam Br
2
.
Nng % ca fructozo trong dung dch ban u l:
A. 32,4% B. 39,6% C. 16,2% D. 45,0%
Cu 4: Thu phn hon ton 62,5 gam dung dch saccaroz 17,1% trong mi trng axit (va ) c dung
dch X. Cho dung dch AgNO
3
/NH
3
vo X v un nh c m gam Ag. Gi tr ca m l.
A. 13,5. B. 7,5. C. 10,8. D. 6,75.
Cu 5: Thy phn hon ton 31,25 gam dung dch saccaroz 13,68% trong mi trng axit (va ) thu c dung
dch D. Cho lng d dung dch AgNO
3
/NH
3
vo dung dch D v un nh, sau khi phn ng kt thc, khi lng Ag
thu c l:
A. 2,565 gam B. 5,13 gam

C. 2,70 gam D. 5,40 gam

Cu 6: Thc hin phn ng trng gng vi dung dch X cha m gam hn hp glucoz v saccaroz thu c 0,02
mol Ag. Nu un nng dung dch X trong H
2
SO
4
long, trung ha dung dch thu c ri thc hin phn ng trang
gng th thu c 0,06 mol Ag. Gi tr ca m l:
A. 8,44 gam B. 10,24 gam

C. 5,22 gam D. 3,60 gam

TT LUYN THI & BI DNG KIN THC NGY MI 18A/88 INH VN T - TP. HI DNG
Cu 7: Ha tan hon ton 140,4 gam hn hp X gm glucozo, fructozo v saccarozo vo nc ri chia thnh
hai phn bng nhau:
- Phn 1: Cho tc dng vi dung dch AgNO
3
/NH
3
d, un nng thu c 43,2 gam Ag
- Phn 2: Lm mt mu va dung dch cha 16 gam Brom
Thnh phn % khi lng fructozo v saccarozo c trong hn hp X ln lt l:
A. 74,36% v 25,64% B. 48,72% v 25,64% C. 25,64% v 74,36% D. 12,82% v 74,36%
Cu 8: Cho m gam hn hp gm glucozo v fructozo tc dng vi lng d dung dch AgNO
3
/NH
3
to ra 43,2
gam Ag. Cng m gam hn hp ny tc dng va ht vi 8 gam brom. S mol ca glucoz v fructozo trong hn
hp ln lt l:
A. 0,05 mol v 0,15 mol B. 0,1 mol v 0,15 mol C. 0,2 mol v 0,2 mol D. 0,05 mol v 0,35 mol
Cu 9: Ngi ta thng dung glucozo trng rut phch. Trung bnh cn phi dung 0,75 gam glucozo cho 1
chic rut phch, bit hiu sut ca ton qu trnh l 80%. Lng bc c trong 1 chic rut phc l:
A. 0,36 gam B. 0,45 gam C. 0,72 gam D. 0,90 gam

DNG 02: PHN NG THY PHN TNG HP CC CHT KHC

Phng php:
Cacbonhidrat c chia thnh 3 loi
+ Monosaccarit: glucozo v fructozo khng b thy phn
+ isaccarit: Saccarozo (C
12
H
22
O
11
) thy phn cho 2 mono saccarit (glucozo v fructozo)
12 22 11 2 6 12 6 6 12 6
H
C H O H O C H O C H O
+
+ +
+ Polisaccarit: Tinh bt v xenlulozo (C
6
H
10
O
5
)
n
thy phn cho n mono saccarit (glucozo)
( )
6 10 5 2 6 12 6
H
n
C H O nH O nC H O
+
+
+ Sn xut ru etylic C
2
H
5
OH
(C
6
H
10
O
5
)
n
nC
6
H
12
O
6
2nCO
2
+ 2nC
2
H
5
OH
+ iu ch xenluloz trinitrat [C
6
H
7
O
2
(ONO
2
)
3
]
n

[C
6
H
7
O
2
(OH)
3
]
n
+ 3nHNO
3
[C
6
H
7
O
2
(ONO
2
)
3
]
n
+ 3nH
2
O

* Lu :
- tin cho vic tnh ton v n gin ha bi ton th ta nn: s dng s thay cho phng trnh phn ng
v chn h s polime n = 1
- Vi bi ton c lin quan ti hiu sut ca phn ng th
1) A
H
B ( H

l hiu sut phn ng)
n
A
= n
B
.
100
H
; n
B
= n
A
.
100
H

2) A
1
H
B
2
H
C ( H
1
, H
2
l hiu sut phn ng ca cc gia on 1, 2)
n
A
= n
c
.
1 2
100 100
.
H H
; n
c
= n
A
.
1 2
.
100 100
H H
.

BI TP
Cu 1: Thy phn 243 gam tinh bt vi hiu sut ca phn ng l 75%, khi lng glucozo thu c l:
A. 202,5 gam B. 270 gam C. 405 gam D. 360 gam
Cu 2: Thy phn hon ton 3,42 gam saccarozo trong mi trng axit, thu c dung dch X. Cho ton b
dung dch X phn ng ht vi lng d dung dch AgNO
3
/NH
3
, un nng, thu c m gam Ag. Gi tr ca M l
Cu 3: Thc hin phn ng trng bc vi dung dch X cha m gam hn hp gm glucozo v saccarozo thu
c 0,02 mol Ag. Nu un nng X trong dung dch H
2
SO
4
long ti khi phn ng xy ra hon ton, trung ha
dung dch X ri mi trng bc th thu c 0,06 mol Ag. Gi tr ca m l:
Cu 4: Thy phn 34,2 gam dung dch saccarozo 30% trong mi trng axit v c long un nng c dung
dch X (H = 100%). Trung ha dung dch X ri cho tc dng vi dung dch AgNO
3
/NH
3
d, un nng thu c
m gam Ag. Gi tr ca m l:
Cu 5: Ha tan hon ton 70,2 gam hn hp X gm glucozo v saccarozo vo nc ri cho tc dng vi dung
dch AgNO
3
/NH
3
d, un nng phn ng xy ra hon ton. Sau phn ng thu c 43,2 gam Ag. Tnh %
khi lng ca saccarozo c trong hn hp X:
A. 48,7% B. 51,3% C. 74,4% D. 25,6%
Cu 6: Chia mt hn hp gm tinh bt v glucozo thnh hai phn bng nhau
+ Phn 1: Ha tan trong nc ri cho phn ng hon ton vi AgNO
3
/NH
3
d th thu c 2,16 gam Ag
+ Phn 2: un nng vi H
2
SO
4
long d, sau trung ha bng NaOH ri cho tc dng tip vi AgNO
3
/NH
3

d th thu c 6,48 gam Ag.
Khi lng tinh bt c trong hn hp ban u l:
Cu 7: Cho m gam hn hp gm tinh bt v glucozo tc dng vi lng d dung dch AgNO
3
/NH
3
, un nng
thu c 21,6 gam Ag. Mt khc, un nng m gam X vi HCl long d, phn ng xy ra hon ton, thu
c ung ch Y. Dung dch Y lm mt mu va ht dung dch cha 32 gam Br
2
. Gi tr m l:
Cu 8: Cho 9,0 kg gam glucozo cha 15% tp cht tr, ln men thnh ru etylic. Trong qu trnh ch bin,
ru b hao ht 10%. Hi khi lng ru etylic thu c sau phn ng.
A. 4,60 kg B. 3,519 kg 3,910 kg D. 4,140 kg
Cu 9: Trong mt nh my ru, ngi ta s dng nguyn liu l mn ca cha 50% xunlulozo sn sut
ru etylic, vi hiu sut ca ton b qu trnh phn ng l 80%. sn sut c 1,0 tn ancol etylic th lng
mn ca cn dng l:
A. 1,76 tn B. 2,20 tn C. 3,52 tn D. 4,40 tn
Cu 10: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO
2
sinh ra c
hp th hon ton vo dung dch Ca(OH)
2
thu c 550 gam kt ta v dung dch X. un nng dung dch n
khi phn ng xy ra hon ton th thu c 100 gam kt ta. Gi tr ca m l
A. 550 gam B. 810 gam C. 650 gam D. 750 gam
Cu 11: Th tch dung dch HNO
3
67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to
thnh 89,1 kg xenluloz trinitrat l (bit lng HNO
3
b hao ht l 20 %)
A. 81 lt. B. 55 lt. C. 49 lt. D. 70 lt.
Cu 12: T 48,6 kg xenluloz iu ch c bao nhiu kg t xenluloz axetat, bit thnh phn ca t axetat
gm xenluloz iaxetat v xenluloz triaxetat vi t l mol 2:1. Hiu sut ca phn ng l 90%.
A. 73,98 gam B. 78 gam C. 70,2 gam D. 210,6 gam
Cu 13: Cho 10 kg glucoz cha 10 % tp cht ln men thnh ru etylic. Trong qu trnh ch bin, ru b
hao ht 5 %. Hi khi lng ru etylic thu c bng bao nhiu?
A. 4,65kg B. 4,37kg C. 6,84kg D. 5,56kg
Cu 14: Cho glucoz ln men thnh ru etylic. Ton b kh cacbonic sinh ra trong qu trnh ny c hp th
ht vo dung dch Ca(OH)
2
d, to ra 40 g kt ta. Bit hiu sut ln men t 75 % khi lng glucoz cn
dng l:
A. 2,4g B. 24g C. 48g D. 50g
Cu 15: Bng phng php ln men ancol t glucoz ta thu c 0,1 lt ancol etylic (khi lng ring 0,8g/ml).
Bit hiu sut ln men 80%. Khi lng glucoz dng l:
A. 185,60 g. B. 190,50 g. C. 195,65 g D. 198,50 g.
Cu 16: Th tch dung dch HNO
3
67,5 % (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1
kg xenluloz trinitrat l (bit lng HNO
3
b hao ht l 20 %).
A. 70 lt. B. 49 lt. C. 81 lt. D. 55 lt.
Cu 17: Xenluloz trinitrat l cht d chy v n mnh c iu ch t xenluloz v HNO
3
. Mun iu ch
29,7 kg cht (hiu sut 90%) th th tch HNO
3
96% (D = 1,52 g/ml) cn dng l.
A. 1,439 lt. B. 14,39 lt. C. 15 lt. D. 24,39 lt.
DNG 03: S PHN NG CHUYN HA GIA CC CHT

Cu 1. Cho s sau: +

2 2 2
0
+H O +C H
H ,t
men gim men ru
Xenluloz X Y Z T . Cng thc ca T l:
A. CH
2
= CHCOOC
2
H
5
. B. CH
3
COOCH=CH
2
. C. CH
2
= CHCOOCH
3
. D. CH
3
COOC
2
H
5
.
Cu 2. Cho s chuyn ho: Glucoz X Y CH
3
COOH. Hai cht X, Y ln lt l
A. CH
3
CHO v CH
3
CH
2
OH B. CH
3
CH
2
OH v CH
3
CHO
C. CH
3
CH(OH)COOH v CH
3
CHO D. CH
3
CH
2
OH v CH
2
=CH
2

Cu 3. Mt cacbohirat (Z) c cc phn ng din ra theo s chuyn ha:
Z
2
Cu(OH) /NaOH
dd xanh lam
0
t
kt ta gch.
Vy Z khng th l:
A. Glucoz. B. Saccaroz. C. Fructoz. D. Tt c u sai.
Cu 4. Cho bin ha sau: Xenluloz A B C Caosubuna. A, B, C ln lt l:
A. CH
3
COOH, C
2
H
5
OH, CH
3
CHO. B. C
6
H
12
O
6
(glucoz), C
2
H
5
OH, CH
2
=CHCH=CH
2
.
C. C
6
H
12
O
6
(glucoz), CH
3
COOH, HCOOH. D. CH
3
CHO, CH
3
COOH, C
2
H
5
OH.
Cu 5. Cho s chuyn ha sau: Tinh bt X Y axit axetic. X v Y ln lt l
A. ancol etylic, anehit axetic. B. glucoz, ancol etylic.
C. glucoz, etyl axetat. D. glucoz, anehit axetic.
Cu 6. Cho cc chuyn ha sau:
0
,
2 2
3 3 2 4 3
2 3

gluconat+2Ag+2NH
xt H
t
X H O Y Y H Sobitol
Y AgNO NH H O Amoni NO Y
+
+ +
+ + +
/
2 cht dip lc
xt
a s
E Z
Z H O E Z
+
+ +

X, Y v Z ln lt l:
A. Tinh bt, glucozo v kh cacbonic B. Xenlulozo, glucozo, kh cacbon oxit
C. Xenlulozo, fructozo v kh cacbonic D. Tinh bt, glucozo v ancol etylic
Cu 7. Xt cc phn ng theo s bin ho
CO
2
tinh bt
etanol glucozo
(1)
(2) (3)
(4)
(5)

Tm pht biu cha ng
A. p (1) quang hp nh cht dip lc B. p (3) Thu phn tinh bt nh xc tc H
2
SO
4
long
C. p (5) ln men ru D. p (4) t chy glucoz ( phng php duy nht )
Cu 8. Cho s chuyn ho sau, trong Z l buta - 1,3 - ien, E l sn phm chnh:

o o
3 2 4
CH COOH/ H SO , t HBr(1:1) NaOH, t
Tinh bt X Y Z E F G
.
Cng thc cu to ng ca G l.
A. CH
3
COOCH
2
CH = CHCH
3
. B. CH
3
COOCH(CH
3
)CH = CH
2
.
C. CH
3
COOCH
2
CH
2
CH = CH
2
. D. A

hoc C.
Cu 9. Cho s sau:
+

2 2 2
0
+H O +C H
H ,t
men gim men ru
Xenluloz X Y Z T .
Cng thc ca T l.
A. CH
2
= CHCOOC
2
H
5
. B. CH
3
COOCH=CH
2
. C. CH
2
= CHCOOCH
3
. D. CH
3
COOC
2
H
5
.
Cu 10. Cho dy chuyn ho sau:
+

o
3
o
H O t
450
+ ZnO,MgO , p, xt enzim
xenluloz X Y Z T.
T l cht no trong cc cht sau:
A. Axit axetic. B. Cao su buna. C. Buta - 1,3 - ien. D. Polietilen.
Cu 11. Cho s chuyn ho sau (cc cht phn ng l hp cht hu c, mi mi tn l 1 phn ng):
E
Q
CO
2
C H OH
X
Y
Z
2 5 .
E, Q, X, Y, Z ln lt l.
A. C
12
H
22
O
11
, C
6
H
12
O
6
, CH
3
COOH, CH
3
COOC
2
H
5
, CH
3
COONa.
B. (C
6
H
10
O
5
)
n
, C
6
H
12
O
6
, CH
3
CHO
,
CH
3
COONH
4
, CH
3
COOH.
C. (C
6
H
10
O
5
)
n
, C
6
H
12
O
6
, CH
3
CHO
,
CH
3
COONa, CH
3
COOH.
D. (C
6
H
10
O
5
)
n
, C
6
H
12
O
6
, CH
3
CHO, CH
3
COOH, CH
3
COOC
2
H
5
.
Cu 12. Cho s :
(1) (2) (3) (4)

2 6 10 5 n 6 12 6 2 5 3
CO (C H O ) C H O C H OH CH COOH .
Tn gi ca phn ng no sau y l khng ng:
A. (3): Phn ng ln men ancol. B. (4): Phn ng ln men gim.
C. (2): Phn ng thy phn. D. (1): Phn ng cng hp.
Cu 13. Cho dy phn ng ho hc sau:
(1) (2) (3) (4)

2 6 10 5 n 12 22 11 6 12 6 2 5
CO (C H O ) C H O C H O C H OH .
Cc giai on c th thc hin nh xc tc axit l.
A. (2), (3), (4). B. (1), (2), (3). C. (2), (3). D. (1), (2), (4).
Cu 14. Cho s phn ng: Thuc sng khng khi X Y Sobiton. X , Y ln lt l
A. xenluloz, glucoz B. tinh bt, etanol C. mantoz, etanol D. saccaroz, etanol
Cu 15. Cho s chuyn ha sau : Tinh bt A
1
A
2
A
3
A
4
CH
3
COOC
2
H
5
. A
1
, A
2
, A
3
, A
4
c
CTCT thu gn ln lut l
A. C
6
H
12
O
6
, C
2
H
5
OH, CH
3
CHO, CH
3
COOH. B. C
12
H
22
O
11
, C
2
H
5
OH, CH
3
CHO, CH
3
COOH.
C.glicozen, C
6
H
12
O
6
, CH
3
CHO , CH
3
COOH. D. C
12
H
22
O
11
, C
2
H
5
OH , CH
3
CHO, CH
3
COOH.
Cu 16. Cho dy chuyn ha : Xenlulozo A B C polibutadien. A, B, C l nhng cht no sau y ?
A. CH
3
COOH, C
2
H
5
OH, CH
3
CHO. B. glucozo, C
2
H
5
OH, but-1,3-dien.
C. glucozo, CH
3
COOH, HCOOH. D.CH
3
CHO, CH
3
COOH, C
2
H
5
OH
Cu 17. Cho s chuyn ha sau : CO
2
XY Z T PE. Cc cht X, Y, Z l
A. tinh bt, xenlulozo, ancol etylic, etilen. B. tinh bt, glucozo, ancol etylic, etilen.
C. tinh bt, saccarozo, andehit, etilen. D. tinh bt, glucozo, andhit, etilen.
Cu 18. B sung iu kin cho chui phn ng sau:
(C
6
H
5
O
5
)n
(1)
C
6
H
12
O
6

(2)
C
2
H
5
OH
(3)
C
2
H
4

(4)
C
2
H
5
Cl
(5)
C
2
H
4

(6)
( CH
2
-CH
2
)
n

A. (1) H
2
O, (2) ln men, (3) H
2
SO
4
c, (4) HCl, (5) KOH, (6) trng ngng.
B. (1) H
2
O, (2) ln men, (3) H
2
SO
4
c, (4) Cl
2
, (5) KOH, (6) trng ngng.
C. (1) H
2
O, (2) ln men, (3) H
2
SO
4
c, (4) HCl, (5) H
2
O, (6) trng ngng.
D. (1) H
2
O, (2) ln men, (3) H
2
SO
4
c, (4) NaCl, (5) KOH, (6) trng ngng.
DNG 04: NHN BIT PHN BIT CC CHT

Cu 1. C 4 dung dch mt nhn: Glucoz, glixerol, fomanehit, etanol. Thuc th nhn bit c 4 dung
dch trn l:
A. Dung dch
AgNO
3
/NH
3

B. Nc Brom C. Cu(OH)
2
/OH
-
,t
o
D. Na kim loi
Cu 2. phn bit glucoz, saccaroz, tinh bt v xenluloz, c th dng cht no trong cc thuc th sau:
1) Nc 2) Dung dch AgNO
3
/NH
3
3) Dung dch I
2 4) Giy qu.

A. 1, 3, 4 B. 1, 2, 3 C. 2, 3, 4 D. 1, 2, 4
Cu 3. phn bit 3 cht lng l etanol, glixerol, dung dch glucoz cn dng.
A. CuO (t
o
). B. Kim loi natri. C. Cu(OH)
2
;
t
o
. D. H
2
SO
4 c
(170
o
C).
Cu 4. C ba dung dch mt nhn: h tinh bt, saccaroz, glucoz. Thuc th phn bit chng l:
A. I
2
. B. Vi sa. C. dd AgNO
3
/NH
3
. D. Cu(OH)
2
, t
o

Cu 5. C cc thuc th: H
2
O (1); dd I
2
(2); Cu(OH)
2
(3); AgNO
3
/NH
3
(4); Qu tm (5). nhn bit 4 cht rn
mu trng l glucoz, saccaroz, tinh bt, xenluloz c th dng nhng thuc th no sau y?
A. (1), (2), (5). B. (1), (4), (5). C. (1), (2), (4). D. (1), (3), (5).
Cu 6. phn bit glucoz, saccaroz, tinh bt, xenluloz c th dung cht no trong cc thuc th sau:
1. Nc 2. Dung dch AgNO
3
/NH
3
3. Dung dch I
2
4. Giy qu
A. 2, 3. B. 1, 2, 3. C. 3, 4. D. 1, 2.
Cu 7. nhn bit 3 cht bt mu trng: Tinh bt, xenluloz, saccarozo, ta c th tin hnh theo trnh t no
sau y:
A. Ha tan vo nc, dng vi git dd H
2
SO
4
, un nng, dng dung dch AgNO
3
, NH
3

B. Ha tan vo nc, dng it
C. Dng vi git H
2
SO
4
un nng, dng dd AgNO
3
trong NH
3

D. Dng it, dng dd AgNO
3
trong NH
3

Cu 8. phn bit tinh bt v xenluloz, ngi ta dng phn ng:
A. Trng gng B. Phn ng mu vi it C. Thu phn D. C A, B, C u sai

DNG 05: TNH CHT HA HC CA CC CHT

Cu 1. Dung dch saccaroz khng phn ng vi:
A. Cu(OH)
2
. B. Dd AgNO
3
/NH
3
. C. Vi sa Ca(OH)
2
. D. H
2
O (H
+
, t
0
).
Cu 2. Fructoz khng phn ng vi cht no sau y?
A. Dung dch Br
2
. B. dd AgNO
3
/NH
3
. C. H
2
(Ni, t
0
). D. Cu(OH)
2
.
Cu 3. Glucoz khng c tnh cht no di y?
A. Ln men to ancol etylic. B. Tham gia phn ng thy phn.
C. Tnh cht ca ancol a chc. D. Tnh cht ca nhm anehit.
Cu 4. Dy gm cc cht u tc dng c vi Cu(OH)
2
l.
A. Fructoz, xenluloz, saccaroz, ancol etylic. B. Glucoz, glixerol, natri axetat, tinh bt.
C. Glucoz, glixerol, mantoz, axit axetic. D. Glucoz, glixerol, anehit fomic, natri axetat.
Cu 5. Phn ng no sau y chuyn glucoz v fructoz thnh mt sn phm duy nht?
A. Phn ng vi Cu(OH)
2
, un nng. B. Phn ng vi dung dch Br
2
.
C. Phn ng vi H
2
(Ni, t
0
). D. Phn ng vi dung dch AgNO
3
/NH
3
.
Cu 6. Phn ng ca glucoz vi cht no sau y khng chng minh c glucoz cha nhm anehit?
A. Cu(OH)
2
/OH
-
. B. dd AgNO
3
/NH
3
. C. H
2
(Ni, t
o
). D. Cu(OH)
2
, t
o

Cu 7. Dy gm cc dung dch u tc dng vi Cu(OH)
2
l:
A. glucoz, glixerol, ancol etylic. B. glucoz, andehit fomic, natri axetat.
C. glucoz, glixerol, axit axetic. D. glucoz, glixerol, natri axetat.
Cu 8. Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng
A. ha tan Cu(OH)
2
. B. trng ngng. C. trng gng. D. thy phn.
Cu 9. Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, fructoz. S cht trong dy tham gia phn
ng trng gng l.
A. 3. B. 4. C. 2. D. 5.
Cu 10. Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi
Cu(OH)
2
l.
A. 3. B. 1. C. 4. D. 2.
Cu 11. Cho cc dung dch sau: saccaroz, glucoz, anehit axetic, glixerol, ancol etylic, axetilen, fructoz. S
lng dung dch c th tham gia phn ng trng gng l.
A. 3. B. 4. C. 5. D. 2.
Cu 12. Dy cc cht no sau y u c phn ng thu phn trong mi trng axit?
A. Tinh bt, xenluloz, glucoz. B. Tinh bt, xenluloz, fructoz.
C. Tinh bt, xenluloz, saccaroz. D. Tinh bt, saccaroz, fructoz
Cu 13. Cht khng c kh nng phn ng vi dung dch AgNO
3
/NH
3
(un nng) gii phng Ag l:
A. axit axetic B. axit fomic C. glucoz D. fomanehit
Cu 14. Cho cht X vo dung dch AgNO
3
trong NH
3
un nng, khng thy xy ra phn ng trng gng. Cht
X c th l cht no trong cc cht di y?
A. glucoz B. fructoz C. axetanehit D. saccaroz
Cu 15. Cht khng tham gia phn ng thy phn l:
A. saccaroz B. xenluloz C. fructoz D. tinh bt
Cu 16. Cht lng ha tan c xenluloz l:
A. benzen B. ete C. etanol D. nc Svayde
Cu 17. Saccaroz, tinh bt v xenluloz u c tham gia vo:
A. phn ng trng bc B. phn ng vi Cu(OH)
2
C. phn ng thy phn D. phn ng i mu iot
Cu 18. Cho cc dung dch sau: CH
3
COOH, C
2
H
4
(OH)
2
, C
3
H
5
(OH)
3
, glucoz, saccaroz, C
2
H
5
OH. S lng
dung dch c th ho tan c Cu(OH)
2
l:
A. 3 B. 4 C. 5 D. 6
Cu 19. Saccaroz c th tc dng c vi cht no sau y?
(1) H
2
/Ni, t
0
(2) Cu(OH)
2
(3) [Ag(NH
3
)
2
]OH (4) CH
3
COOH (H
2
SO
4
c).
Hy chn p n ng trong cc p n sau:
A. (1), (2). B. (2), (4). C. (2), (3). D. (1), (4).
Cu 20. Nhm m tt c cc cht u tc dng c vi H
2
O (xc tc; iu kin thch hp):
A. C
2
H
6
, CH
3
COOCH
3
, tinh bt. B. Saccaroz, CH
3
COOCH
3
, benzen.
C. C
2
H
4
, CH
4
, C
2
H
2
. D. Tinh bt, C
2
H
4
, C
2
H
2
.
Cu 21. Cho cc hp cht hu c sau: glucoz, saccaroz, etanal, tinh bt, glyxerol. C bao nhiu cht khng
tham gia phn ng trng gng?
A. 1 cht B. 2 cht C. 3 cht D. 4 cht

2011 - Ly Thuyet &amp Bai Tap Ve Cacbonhidrat

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2011 - Ly Thuyet &amp Bai Tap Ve Cacbonhidrat

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TT LUYN THI & BI DNG KIN THC NGY MI 18A/88 INH VN T - TP.

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