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HIROCACBON KHNG NO
CHUYN 3 :
HIROCACBON KHNG NO
BI TP V ANKEN
Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l
A. isohexan.
B. 3-metylpent-3-en.
C. 3-metylpent-2-en. D. 2-etylbut-2-en.
Cch c tn anken SGK 11 nc 156 Tn v tr Tn nhnh tn mch chnh s v tr - en
nh s th t gn ni i nht.
5
4
3
2
1
CH3 CH2 C(CH3) = CH CH3.
=> 3 metylpentan 2 en Ni i 2 , mch nhnh 3 ; mch chnh 5C pentan
Cu 2: S ng phn ca C4H8 l
A. 7.
B. 4.
C. 6.
D. 5.
Ch ng phn hnh hc Xem li file vit p + cng thc + Cch xc nh p hnh hc Chuyn 1
C4H8 c k = 1 => 1 pi hoc 1 vng => ng phn dng anken hoc xicloankan
Xt p anken Ch p hnh hc
CH2 = CH CH2 CH3 ko c phh =>1 ;
CH3 CH = CH CH3 c p hh =>2
CH2 =C(CH3) CH3 ko phh =>1
Xicloankan : Vng 3 cnh CH3 Tam gic CH3 => 1
Vng 4 cnh => 1 => Tng cng c 6 => C
Mnh vit tt 3 cnh v 4 cnh hiu l tam gic v hnh vung
Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
C5H10 c k =1 + mch h => anken ; ng phn cu to => Khng tnh ng phn hnh hc. Xem file xc nh
ng phn i thi hay b la
CH2 = CH CH2 CH2 CH3 ; CH3 CH =CH CH2 CH3 ; CH2=CH CH(CH3) CH3
CH2 =C(CH3) CH2 CH3 CH3 C(CH3)=CH CH3
=> Tng c 5 => B
Cu 4: Hp cht C5H10 c bao nhiu ng phn anken ?
A. 4.
B. 5.
C. 6.
D. 7.
ng phn anken => tnh c ng phn hnh hc.
Cu 3 c cht CH3 CH=CH-CH2-CH3 c p hnh hc => 6
Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
ng phn cu to => Khng tnh hnh hc
C5H10 c k =1 => 1 pi Anken hoc 1 vng Xicloankan
Anken => bi 3 => c 5 p cu to
Xicloankan :
CH3
CH3
CH3
CH3
C2H5
=> 5 p xicloankan
CH3
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-1-
CHUYN 3 :
HIROCACBON KHNG NO
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-2-
CHUYN 3 :
HIROCACBON KHNG NO
CH3CH2CH=CHCH2CH3 c p hh => 1
CH3C(CH3)=CHCH2CH3 khng c v R1 v R2 l CH3
CH3CH2C(CH3)=C(C2H5)CH(CH3)2 c R1 # R2 hay C2H5 # CH3 ; R3#R4 hay C2H5 # C3H7 => 1
CH3CH=CHCH3 c => 1
=> Tng c 4 cht.
Cu 14: p dng quy tc Maccopnhicop vo trng hp no sau y ?
A. Phn ng cng ca Br2 vi anken i xng.
C. Phn ng cng ca HX vo anken i xng.
B. Phn ng trng hp ca anken.
D. Phn ng cng ca HX vo anken bt i xng.
SGK 11nc 162 => D To ra 2 sn phm ; chnh v ph
C sai v anken i xng nh CH2 = CH2 ch to ra 1 sn phm hoc CH3 CH=CH CH3 i xng nhau qua lin
kt i
Cu 15: Khi cho but-1-en tc dng vi dung dch HBr, theo qui tc Maccopnhicop sn phm no sau y l sn phm
chnh ?
A. CH3-CH2-CHBr-CH2Br.
C. CH3-CH2-CHBr-CH3.
B. CH2Br-CH2-CH2-CH2Br .
D. CH3-CH2-CH2-CH2Br.
SGK 11nc 162 => sn phm chnh Halogen vo C t H cn H vo C nhiu H
Hoc halogen vo C bc cao nht v H vo C cn li
Bc
2
3 1
1
But 1 en : CH2 = CH CH2 CH3 + HBr => CH3 CHBr CH2 CH3 => C
Cu 16: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
P to anken + HCl to ra 1 sn phm duy nht => Anken i xng
CH3 CH =CH CH3 => c p hnh hc => 2 => D
Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi
phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l:
A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en.
D. 2-metylpropen, cis -but-2-en v xiclobutan.
Cu 18: Cho hn hp tt c cc ng phn mch h ca C4H8 tc dng vi H2O (H+,to) thu c ti a bao nhiu sn
phm cng ?
A. 2.
B. 4.
C. 6.
D. 5
P vi H2O => OH vo C bc cao v H vo C cn li C=C
AD Cu 2 => CH2 = CH CH2 CH3
=> sp OH-CH2 CH2 CH2 CH3 hoc CH3 CH(OH)-CH2 CH3
CH3 CH = CH CH3 => sp : CH3 CH(OH) CH2 CH3
CH2 =C(CH3) CH3 => sp : CH3 (OH)C(CH3) CH3 hoc OH CH2 CH(CH3) CH3
Gp 3 trng hp => c 4 sn phm TH1 v TH2 cng CH3 CH(OH) CH2 CH3
=> B
Cu 19: C bao nhiu anken th kh (kt) m khi cho mi anken tc dng vi dung dch HCl ch cho mt sn
phm hu c duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
SGK 11 nc 159 => Anken th kh t C2 ti C4
Vi C2H4 => to ra 1 cht anken i xng
C3H6 => C = C C => to ra 2 sn phm anken bt i xng
C4H6 => C - C = C C => mi ng phn hnh hc to ra 1 sn phm => 2 cht
tng l 3 : C2H4 ; cis C4H6 ; trans C4H6 => C mnh Khng dm khng nh cis v trans
Cu ny khng chc p n.
Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. 2-metylpropen v but-1-en (hoc buten-1).
B. propen v but-2-en (hoc buten-2).
C. eten v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
2anken to thnh 2 ancol => mi anken to thnh 1 ancol => anken i xng.
A,D loi v cha but 1 en : C = C C C to ra 2 ancol => cht cn li = 1 => 3 ancol
B loi v Propen to ra 2 ancol + but - 2 en to ra 1 ancol (i xng )
C. Eten v but 2 en u mch i xng => mi cht to ra 1 ancol duy nht => C
Cu 21: Anken thch hp iu ch ancol sau y (CH3 CH2)3C-OH l
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-3-
CHUYN 3 :
HIROCACBON KHNG NO
A. 3-etylpent-2-en.
B. 3-etylpent-3-en.
C. 3-etylpent-1-en.D. 3,3- imetylpent-1-en.
(CH3 CH2)3C-OH ; CH3 CH2 (CH3CH2)C(OH) CH2 CH3
1
2
3 4
5
=> anken iu ch : CH3 CH2 = (CH3CH2)C CH2 CH3
Ni i v tr 2 ; etyl v tr 3 ; mch chnh c 5 C => pent => A .3 etylpent 2 en =>A
Xem li cch vit danh php anken
Cu 22: Hirat ha hn hp X gm 2 anken thu c ch thu c 2 ancol. X gm
A. CH2=CH2 v CH2=CHCH3.
B. CH2=CH2 v CH3CH=CHCH3.
C. B hoc D.
D. CH3CH=CHCH3 v CH2=CHCH2CH3.
Cu ny t B hoc D => Chn B hoc D cng c m B chc chn ng ri Bi 20
C bao qut => Cu ny p n khng hp l
D khng tha mn
Sa p n . C . B v D
B ng
Cu 23: S cp ng phn cu to anken th kh (kt) tho mn iu kin: Khi hirat ho to thnh hn hp gm ba
ancol l
A. 6.
B. 3.
C. 5.
D. 4.
Anken th kh => C2 ti C4 SGK 11 nc 159
Hidrat ha l p anken + H2O => Ru SGK 11 nc 161
Cu 24: S cp ng phn anken th kh (kt) tho mn iu kin: Khi hirat ho to thnh hn hp gm ba ancol
l:
A. 6.
B. 7.
C. 5.
D. 8.
Cu 25: Hp cht X c CTPT C3H6, X tc dng vi dung dch HBr thu c mt sn phm hu c duy nht. Vy X
l:
A. propen.
B. propan.
C. isopropen.
D. xicloropan.
C3H6 => k = 1 => 1pi hoc 1 vng => loi B . Khng c p n C . i vi Cht c 3C khng c iso.
=> A v D . M A to ra 2 sn phm => D ng Hoc thy ngay p SGK bi xicloankan
Cu 26: Hai cht X, Y c CTPT C3H6 v C4H8 v u tc dng c vi nc brom. X, Y l
A. Hai anken hoc xicloankan vng 3 cnh.
C. Hai anken hoc xicloankan vng 4 cnh.
B. Hai anken hoc hai ankan.
D. Hai anken ng ng ca nhau.
Anken lun p vi dd Br2. Xicloankan c vng 3 cnh lun p vi dd Br2 => A
B sai v ankan ; C sai v vng 4 cnh ko p vi dd Br2 ; D thiu trng hp Xicloankan
Cu 27: C hai ng nghim, mi ng cha 1 ml dung dch brom trong nc c mu vng nht. Thm vo ng th nht
1 ml hexan v ng th hai 1 ml hex-1-en. Lc u c hai ng nghim, sau yn hai ng nghim trong vi pht.
Hin tng quan st c l:
A. C s tch lp cc cht lng c hai ng nghim.
B. Mu vng nht vn khng i ng nghim th nht
C. ng nghim th hai c hai lp cht lng u khng mu.
D. A, B, C u ng.
Cu 28: Trng hp eten, sn phm thu c c cu to l:
A. (-CH2=CH2-)n .
B. (-CH2-CH2-)n .
C. (-CH=CH-)n. D. (-CH3-CH3-)n .
Eten : C2H4 => trng hp => (-CH2-CH2-)n => B P SGK 11 nc 162
Cu 29: Oxi ho etilen bng dung dch KMnO4 thu c sn phm l:
A. MnO2, C2H4(OH)2, KOH.
C. K2CO3, H2O, MnO2.
B. C2H5OH, MnO2, KOH.
D. C2H4(OH)2, K2CO3, MnO2.
P SGK 11 nc 162 :
3C2H4 + 2KMnO4 + 4H2O => 3C2H4(OH)2 etylenglicol + 2MnO2 + 2KOH => A
Cu 30: X la h n h p g m 2 hirocacbon. t cha y X c nCO2 = nH2O. X co th g m
A. 1xicloankan + anken.B. 1ankan + 1ankin.
C. 2 anken.
D. A hoc B hoc C.
X c th : A ng v c 2 cht u c k = 1 ;
B c th : v nu nankan = nankin
C ng v k = 1
=> D
Nu phn vn B cha bit th ta thy A v C ng => D ng
Cu 31: iu ch etilen trong phng th nghim t C 2H5OH, (H2SO4 c, 170oC) thng ln cc oxit nh SO2, CO2.
Cht dng lm sch etilen l:
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CHUYN 3 :
HIROCACBON KHNG NO
A. dd brom d.
B. dd NaOH d.
C. dd Na2CO3 d.D. dd KMnO4 long d.
Lm sch etilen tc l lm mt i SO2 v CO2 trong kh etilen.
Xt A dd Br2 d => Etilen v SO2 u lm mt mu => khng th loi c
B ng v ch c SO2 v CO2 p => cn li etilen => B
SO2 + NaOH d => Na2SO3 + H2O ; CO2 + NaOH d => Na2CO3 + H2O
C sai v khng cht no p
D sai v Etilen v SO2 u p.
Cu 32: Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ?
A. 3-Metylbut-1-en.
B. 2-Metylbut-1en.
C. 3-Metylbut-2-en.
D. 2-Metylbut-2-en.
ehidrat ha tc l p tch nhm H2O t ancol to thnh anken SGK 11 nc 227
Quy tc Zaixep OH tch cng vi H bc cao bn cnh sn phm chnh
Sn phm ph ngc li cng H bc thp bn cnh
I
II
2 metylbutan 2 ol : CH3 (CH3)C (OH) CH2 CH3 => tch cng H bc II
1
2
3
4
=> CH3 C(CH3)=CH CH3 => 2 metylbut 2 en => D
Cu 33: Khi tch nc t ru (ancol) 3-metylbutanol-1 (hay 3-metylbutan-1-ol), sn phm chnh
thu c l:
A. 2-metylbuten-3 (hay 2-metylbut-3-en).
B. 3-metylbuten-2 (hay 3-metylbut-2-en).
C. 3-metylbuten-1 (hay 3-metylbut-1-en).
D. 2-metylbuten-2 (hay 2-metylbut-2-en).
1
2
3
4
AD 32 : 3-metylbutan-1-ol : OH CH2 CH2 CH(CH3) CH3
1
2
3
4
=> CH2=CH2 CH(CH3) CH3 => 3 metyl but 1 en => C
Cu 34: Hp cht 2-metylbut-2-en l sn phm chnh ca phn ng tch t cht no ?
A. 2-brom-2-metylbutan.B. 2-metylbutan -2- ol. C. 3-metylbutan-2- ol.D. Tt c u ng.
2 metylbut 2 en : CH3 - C(CH3) = CH CH3
A. 2-brom-2-metylbutan P tch HX SGK 11 nc 214
Quy tc Zai Xp ; Nguyn t halogen X u tin tch cng vi H C bc cao bn cnh
Bc: I
II
CH3 (Br)C(CH3) CH2 CH3 => tch cng C bc II => CH3 C(CH3) = CH CH3
Tha mn P vi kim KOH c xc tc C2H5OH , nhit
B. 2-metylbutan -2- ol. AD bi 32
I
II
CH3 (OH)C(CH3) CH2 CH3 => Tch cng C bc 2
CH3 C(CH3)=CH CH3 Tha mn
A, B ng => D
I
III
Xt C. 3 metylbutan 2 ol ; CH3 CH(OH) CH(CH3) CH3 => tch cng C bc 3
=> CH3 CH=C(CH3) CH3 Tha mn Ngc li
Cu 35: Khi lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu sut phn ng t
40% l:
A. 56 gam.
B. 84 gam.
C. 196 gam.
D. 350 gam.
Phn ng tch H2O SGK 11 nc 227
Ru etylic C2H5OH => C2H5OH => C2H4 etilen + H2O
5 mol
=> 5 mol
=> mC2H4 theo PT = 140g .
CT tnh H% ;
H% p = mPT . 100% / mTT ; H%Sp = mTT.100% / mPT
mPT l m phng trnh Tnh theo PT ; mTT l m thc t thu c hoc ban u
sp l sn phm ; p l phn ng
C th thay khi lng bng th tch hay s mol - mPT v mTT ca cng mt cht
C2H4 l sn phm => H%sp = mTT.100% / mPT 40% = mTT.100% / 140
mTT = 140.40/100 = 56g => A mC2H4 thc t thu c
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-5-
CHUYN 3 :
HIROCACBON KHNG NO
Cu 36: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau phn ng khi lng bnh
brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l:
A. 0,05 v 0,1.
B. 0,1 v 0,05.
C. 0,12 v 0,03. D. 0,03 v 0,12.
C lin kt pi => c phn ng cng Br2 => EtilenC2H4 p vi Br2 cn etanC2H6 khng p.
SGK 11 nc 160 ; anken p cng Br2
Tng qut : X + kBr2 => XBr2k X l cht hu c mch h c k 1 k = 0 l ankan ko c p cng
P cng xut pht t lin kt pi
Tng qut vi k = 1 => CnH2nOz ; k =2 => CnH2n-2Oz k=1 c gc hidrocacbon ging Anken; k = 2 c gc
hidrocabon ging Ankin
VD: C2H4 + Br2 => C2H4Br2 V C2H4 c k = pi
C3H6O2 + Br2 => C3H6O2Br2 v C3H6O2 c k = 1
C5H8 + 2Br2 => C5H8Br4 V c k =2
Cng Br2 nh cng X2 , H2 ; X l halogen
m bnh tng = mAnken cho vo V anken b hp th - BT khi lng
=> mC2H4 = 2,8 g => nC2H4 = 0,1 mol => nC2H6Etan = nhh nC2H4 = 0,15 0,1 = 0,05 => A
Cu 37: 2,8 gam anken A lam mt mau va u dung dich cha 8 gam Br2. Hirat hoa A chi thu c mt ancol duy
nht. A co tn la:
A. etilen.
B. but - 2-en.
C. hex- 2-en.
D. 2,3-dimetylbut-2-en.
Hidrat ha A p anken + H2O => ancol => thu c 1 sn phm => Mch i xng
Cc p n A,B,D i xng
A. CH2 = CH2 ; B . CH3 CH=CH-CH3 ; C. CH3-CH=CH-CH2-CH3 Ko i xng
D. CH3 C(CH3) =C(CH3)-CH3
A , B , C , D u l anken ui en => nAnken = nBr2 = 0,05 mol
=> M anken = 2,8 / 0,05 = 56 = 14n n = 4 CnH2n => C4H8 => B Ch c B c 4C
Cu 38: 0,05 mol hirocacbon X lam mt mau va u dung dich cha 8 gam brom cho ra san phm co ham lng
brom at 69,56%. Cng thc phn t cua X la:
A. C3H6.
B. C4H8.
C. C5H10.
D. C5H8.
Ta c nX = nBr2 = 1 =k => Hidrocabon c CT : CnH2n Bi 36
P : CnH2n + Br2 => CnH2nBr2
%Br = 160.100% / (14n+160) = 69,56% n = 5 Cch bm nh chuyn 1 ; ly 160.100%/69,56 - 160 sau ly
kt qu chia 14 => n = 5 => C5H10 =>C
Cu 39: Dn t t 8,4 gam hn hp X gm but-1-en v but-2-en li chm qua bnh ng dung dch Br 2, khi kt thc
phn ng thy c m gam brom phn ng. m c gi tr l:
A. 12 gam.
B. 24 gam.
C. 36 gam.
D. 48 gam.
But 1 en ; But 2 en l ng phn ca C4H8
=> n hn hp = 8,4 / 56 = 0,15 mol = nBr2 V k =1 :anken => mBr2 p = 24g => B
Cu 40: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng
bnh tng thm 7,7 gam. Thnh phn phn % v th tch ca hai anken l:
A. 25% v 75%.
B. 33,33% v 66,67%. C. 40% v 60%.
D. 35% v 65%.
Anken p vi Br2 => m bnh tng = mAnken p = 7,7 g V anken p vi dd Br2
mhh 7,7
=
= 51,33 = 14n <=> n = 3,67 => n=3 v n = 4 2 anken kt tip
Gi CT ca hn hp : CnH2n => M =
nhh 0,15
nhau
Xem li cch xc nh % th tch nhanh Bi 47 chuyn 2 hoc trong file pp gii nhanh ha hu c
%C4H8 = 67% Hay 66,67 mnh lm trn % C ln = s sau du ,
=> % C3H6 = 100 % - %S ln = 33,33 % => B
Cu 41: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho hn hp X i qua bnh
ng nc brom d, khi lng bnh tng ln 9,8 gam. % th tch ca mt trong 2 anken l:
A. 50%.
B. 40%.
C. 70%.
D. 80%.
Tng t Bi 40 => n = 3,5 => %C4H8 = 50% => %C3H6 = 50% => A
Cu 42: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng
bnh tng thm 7,7 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6. B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. C5H10 v C6H12.
Tng t bi 40 => n = 3,67 => n = 3 (C3H6) v n = 4 (C4H8) => B v lin tip
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-6-
CHUYN 3 :
HIROCACBON KHNG NO
Cu 43: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho X qua nc Br 2 d
thy khi lng bnh Br2 tng 15,4 gam. Xc nh CTPT v s mol mi anken trong hn hp X.
A. 0,2 mol C2H4 v 0,3 mol C3H6.
B. 0,2 mol C3H6 v 0,2 mol C4H8.
C. 0,4 mol C2H4 v 0,1 mol C3H6.
D. 0,3 mol C2H4 v 0,2 mol C3H6.
Tng t bi 40 => n = 2,2 => n = 2C2H4 v n =3 C3H6 2 anken lin tip
Xem li bi 47 chuyn 2 . Tm t l s mol 2 cht lin tip t n
0,2nC2H4 = 0,8nC3H6 nC2H4 = 4nC3H6 => chn nC3H6 = x mol => nC2H4 = 4xmol
M nC2H4 + nC3H6 = 0,5 mol => x = 0,1 => nC2H4 = 0,4 ; nC3H6 = 0,1 => C
Cu 44: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th kh (
ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom tng ln 2,8 gam; th tch kh cn li
ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v khi lng ca hn hp X l:
A. C4H10, C3H6 ; 5,8 gam.
B. C3H8, C2H4 ; 5,8 gam.
C. C4H10, C3H6 ; 12,8 gam.
D. C3H8, C2H4 ; 11,6 gam.
Ch c anken p vi Br2 => Th tch cn li = 2/3 th tch hh ban u = V ankan
V ankan = 2.6,72/3 = 4,48 lt => nankan = 0,2 mol => nAnken = nhhX nAnkan = 0,3 0,2 = 0,1 mol
m bnh tng = mAnken = 2,8 g => Manken = 28 =14n => n =2 => C2H4 B
A l C3H8 V A c C ln hn B 1 C v A c dng CnH2n+2
M hn hp X = mC3H8 + mC2H4 = 0,2.44 + 0,1.28 = 11,6 g => D
Cu 45: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh ktc. Cho hn hp
X i qua nc Br2 d th th tch kh Y cn li bng na th tch X, cn khi lng Y bng 15/29 khi lng X. CTPT
A, B v thnh phn % theo th tch ca hn hp X l
A. 40% C2H6 v 60% C2H4.
B. 50% C3H8v 50% C3H6
C. 50% C4H10 v 50% C4H8.
D. 50% C2H6 v 50% C2H4
Bi 44 => Th tch Y = V ankan = VX /2 => Vankan = V anken = VX / 2 => %theo th tch = 50%
Loi A.
A v B cng s C => A c CT : CnH2n+2Ankan => CnH2n l CT Banken
Chn nAnkan = 1 mol => nAnken = 1mol
mY
mAnkan
15
14n+2
15
=
=
=
n = 2 => C2H6 vaf C2H4
=>
mhhX mAnkan+mAnken 29
14n+2 + 14n 29
Mo p n A v D cng cng thc ; p n B,C,D cng % V
=> Ly C t A hoc D ; Ly % t B,C,D => Cch ny dng cho bn khng lm c khi i thi
Cu 46 : Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung dch brom d thy c 1 cht kh bay ra,
t chy hon ton kh ny thu c 5,544 gam CO2. Thnh phn % v th tch metan v olefin trong hn hp X l:
A. 26,13% v 73,87%.
B. 36,5% v 63,5%.
C. 20% v 80%.
D. 73,9% v 26,1%.
Metan CH4 v Olefinanken CnH2n 1 cht kh l CH4 V anken b Br2 d hp th
nCH4 = nCO2 to ra = 0,126 mol Bt nguyn t C
VCH4 = 2,8224 => %CH4 = 2,6133 .100% / 10,8 = 26,13% => % Anken = 73,87% => A
Cu 47: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phn ng thy khi lng bnh brom tng 22,4
gam. Bit X c ng phn hnh hc. CTCT ca X l:
A. CH2=CHCH2CH3.
B. CH3CH=CHCH3.
C. CH3CH=CHCH2CH3.
D. (CH3)2C=CH2.
X c ng phn hnh hc => Loi A v D Xem li k ng phn hnh hc
Tng t bi 40 => n = 4 => C4H8 => B v C c 5C
Cu 48: a. Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha
74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l:
A. but-1-en.
B. but-2-en.
C. Propilen.
D. Xiclopropan.
p n => u c th p cng Br2 v u c 1 pi hoc 1 vng => Cng thc : CnH2n
PT : CnH2n + Br2 => CnH2nBr2 => %Br = 160.100% / (14n + 160) = 74,08 n= 4 => Loi C,D
X p vi HBr thu c 2 sn phm => X l anken khng i xng => A :CH2=CH-CH2-CH3
b. Hirocacbon X cng HCl theo ti l mol 1:1 tao san phm co ham lng clo la 55,04%. X co cng thc phn t
l:
A. C4H8.
B. C2H4.
C. C5H10.
D. C3H6.
p n => X c CT : CnH2n
P : CnH2n + HCl => CnH2n+1Cl
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-7-
CHUYN 3 :
HIROCACBON KHNG NO
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-8-
CHUYN 3 :
HIROCACBON KHNG NO
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-9-
CHUYN 3 :
HIROCACBON KHNG NO
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- 10 -
CHUYN 3 :
HIROCACBON KHNG NO
=> D tha mn
Cu 68: Hn hp X gm propen v B l ng ng theo t l th tch 1:1. t 1 th tch hn hp X cn 3,75 th tch
oxi (cng k). Vy B l:
A. eten.
B. propan.
C. buten.
D. penten.
T l th tch = t l s mol => nPropen = nB
p n => A,C,D u l anken ui en => Xt Trng hp B l anken nu khng ng => B ng v A,C,D sai
B c CT : CnH2n ;
T l th V = t l s mol => Chn nX = 1 mol => nO2 = 3,75 mol ; nC3H6 = nB = 0,5 mol T l 1 : 1
Ta lun c nO2 = (x + y/4).nCxHy => 3,75 = (3+6/4).nC3H6 + (n+2n/4).nCnH2n
3,75 = 2,25 + (3n/2) . 0,5 n = 2 => C2H4 => eten => A
Cu 69: em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu c CO2 v nc
c khi lng hn km nhau 6,76 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. C5H10 v C6H12.
Ta lun c nCO2 = n .nAnken ; nH2O = n . nAnken C n H2 n + O2 => n CO2 + n H2O Hoc bo ton nguyn
t
=> mCO2 mH2O = 44. n .0,1 18. n .0,1 = 6,76 => n = 2,6 => n = 2 v n =3 Lin tip =>A
Cu 70: X, Y, Z la 3 hirocacbon k tip trong day ng ng, trong o MZ = 2MX. t chay hoan toan 0,1 mol Y ri
hp thu toan b san phm chay vao 2 lit dung dich Ba(OH)2 0,1M c mt lng kt tua la:
A. 19,7 gam.
B. 39,4 gam.
C. 59,1 gam.
D. 9,85 gam.
Ta thy X,Y,Z => C2H4 ; C3H6 v C4H8 xem li cc bi trn
0,1 mol YC3H6 => 0,3 mol CO2 BTNT C
ADCT : nCO32- BaCO3= nOH- Bazo - nCO2 = 2nBa(OH)2 nCO2 = 2.0,2 0,3 = 0,1
Xem phn chuyn 1 C CT cu 65
m kt ta = 19,7 g =>A
Cu 71: Chia hn hp gm C3H6, C2H4, C2H2 thnh hai phn u nhau.
Phn 1: t chy hon ton thu c 2,24 lt CO2 (ktc).
Phn 2: Hiro ho ri t chy ht th th tch CO2 thu c (ktc) l bao nhiu ?
A. 1,12 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 3,36 lt.
Phn 1 => nC(trong hn hp) = nCO2 thu c
Phn 2=> nC (trong hn hp) = nCO2 thu c => nCO2 phn 1 = nCO2 phn 2 => V1 = V2 = 2,24 lt =>B
Khi hidro ha ch lm thay i H P cng H2 => khng lam thay i C => BT nguyn t C khng i.
Cu 72: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c
24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh H2 l:
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1
T l th tch = t l s mol => 20 ml hn hp X => 24 ml CO2 20 mol X => 24 mol CO2
nCO = 2nCH4 Gi x,y l mol C3H6 v CH4 => nCO = 2y => n hn hp = nC3H6 + nCH4 + nCO
= x + y + 2y = x + 3y = 20
BTNT C => 3nC3H6 + nCH4 + nCO = nCO2 3x + y + 2y = 24 Gii h => x = 2 ;y = 6
nC3H6 = 2 ; nCH4 = 6 ; nCO = 12 => m hn hp = mC3H6 + mCH4 + mCO = 2.42 + 6.16 + 12.26 = 516
M hn hp = m hn hp / n hn hp = 516 / 20 = 25,8 => T khi vi H2 = 25,8/2 = 12,9 =>A
Cu 73: t chy hon ton 0,1 mol anken X thu c CO 2 v hi nc. Hp th hon ton sn phm bng 100 gam
dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH ch cn 5%. Cng thc phn t ng
ca X l:
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Anken => CT : CnH2n => nCO2 = 0,1.n mol
CO2 p vi NaOH sau p thy d NaOH => CO2 ht ; NaOH d ( bi)
P : CO2 + 2NaOH => Na2CO3 + H2O => nNaOH p = 2nCO2 = 0,2n => mNaOH p = 8n (g)
m NaOH d = mNaOH ban u - mNaOH p = 100.21,62/100% - 8n = 21,62 8n
Ta c m dd sau p => mH2O + mCO2 + mddNaOH = 1,8 n + 4,4n + 100 (V cho ton b sn phm vo)
C% NaOH sau p = mNaOH d / mdd sau p
5% = (21,62-8n).100%/(4,4n + 1,8n +100) n = 2 => C2H4 (Chc chn n = 2 v 21,62 8n >0 => n < 2,7
n = 2 (Hoc c th th p n => A
Dng ny c CT : C% = (mNaOH ban u 8 n ) / (6,2 n + mddNaOH)
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- 11 -
CHUYN 3 :
HIROCACBON KHNG NO
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- 12 -
CHUYN 3 :
HIROCACBON KHNG NO
gam kt ta l:
A. 20.
B. 40.
C. 30.
D. 10.
X,Y , Z k tip nhau + MZ = 2MX => X,Y,Z c cng thc : CnH2n v n = 2;3;4 Duy nht
=> Z l C4H8 ; its 0,1 mol C4H8 => 0,4 mol CO2 BTNT C => nCaCO3 kt ta = nCO2 = 0,4 mol
=> m = 40 g => B
Cu 82: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng
khi lng ca CO2 v H2O thu c l:
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Propan C3H8 propen C3H6 ; Propin C3H4 => Nhn thy cng s C => CT : C3Hy
Ta c MY = 21,2.2 = 12.3 + y y = 6,4
PT : C3H6,4 + O2 => 3CO2 + 3,2H2O => nCO2 = 0,3 mol ; nH2O = 0,32 mol
=> Tng khi lng = mCO2 + mH2O = 0,3.44 + 0,32.18 = 18,96g
Cu 83: X la hn hp C4H8 va O2 (ti l mol tng ng 1:10). t chay hoan toan X c hn hp Y. Dn Y qua binh
H2SO4 c d c hn Z. Ti khi ca Z so vi hiro la
A.18.
B. 19.
C. 20.
D. 21.
Ngc li bi 74 : T l 1 : 10 => chn nC4H8 = 1 mol => nO2 = 10 mol
nO2 p = (4 + 8/4) . nC4H8 = 6 mol => nO2 d = 4 mol
nCO2 to thnh = 4nC4H8 = 4mol => M sau khi hp th = (mCO2 + mO2 d) / (nCO2 + nO2 d) = 38
T khi vi H2 = 19 => B
Cu 84: Hn hp X gm 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc t chy hon ton
hn hp X dng ht 24,64 lt O2 (ktc). Cng thc phn t ca 2 anken l:
A. C2H4 v C3H6. B. C2H4 v C4H8.
C. C3H6 v C4H8.
D. A v B u ng.
Anken p vi Br2 => nhn hp Anken = nBr2 = 0,3 mol k=1 Xem li CT: nBr2 = k.nX vi k = s pi
Gi cng thc trung ca hn hp 2 anken l C n H2 n
nO2 = ( n + 2n /4) . nC n H2 n nO2 = (x +y).nCxHy 1,1 = 3 n .0,3/ 2 n = 2,44 => A v B ng
n nm gia 2 s C ca 2 cht => D
Cu 85: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO2 nh nhau v t l s mol
nc v CO2 i vi s mol ca K, L, M tng ng l 0,5 ; 1 ; 1,5. CTPT ca K, L, M (vit theo th t tng ng) l:
A. C2H4, C2H6, C3H4.
B. C3H8, C3H4, C2H4.
C. C3H4, C3H6, C3H8. D. C2H2, C2H4, C2H6.
Xem li bi 99 chuyn 2
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- 13 -
CHUYN 3 :
HIROCACBON KHNG NO
A. propen, but-1-en.
B. penta-1,4-dien, but-1-en.
C. propen, but-2-en.
D. but-2-en, penta-1,3- ien.
But 1 en CH2=CH-CH2-CH3 ko c p hnh hc => Loi A v B
Propen khng c ng phn hnh hc : CH2 = CH CH3 ko c => Loi C => D
But 2n : CH3 CH=CH CH3 ; Penta 1,3 ien : CH2 = CH CH = CH CH3 p hnh hc lin kt pi th 2
=> D
Cu 4: Cng thc phn t ca buta-1,3-ien (ivinyl) v isopren (2-metylbuta-1,3-ien) ln lt l
A. C4H6 v C5H10.B. C4H4 v C5H8.
C. C4H6 v C5H8.
D. C4H8 v C5H10.
Thy c 2 cht u c ui ien => k = 2 2 lin kt pi => CnH2n 2 => C tha mn
Buta 1,3 ien : CH2 = CH CH = CH2 ; 2 metylbuta 1,3 ien => C4H6
CH2 = C(CH3) CH = CH2 => C5H8
Cu 5: Hp cht no trong s cc cht sau c 9 lin kt xch ma v 2 lin kt ?
A. Buta-1,3-ien. B. Penta-1,3- ien.
C. Stiren.
D. Vinyl axetilen.
Xem li cu 7 phn anken => Cng thc tnh lin kt xch ma ;
2 lin kt pi => CT : CnH2n-2 Xem li phn tm CT 2 cch chuyn 1
Lin kt xch ma = s C + s H 1 = 9 s C + s H = 8 = n + 2n 2 = 10 n = 4 => C4H6 => A
D c 3 lin kt pi :CH2=CH-C=*CH Ch =* l ni 3
Vinyl : CH2=CH
Cu 6: Hp cht no trong s cc cht sau c 7 lin kt xch ma v 3 lin kt ?
A. Buta-1,3-ien. B. Tuloen.
C. Stiren.
D. Vinyl axetilen.
Tng t bi 5: 3 lin kt pi => CT : CnH2n 4 ;
=> S lin kt xch ma = n + 2n 4 - 1 = 7 n = 4 => D:C4H4
Cu 7: Cho phn ng gia buta-1,3-ien v HBr -80oC (t l mol 1:1), sn phm chnh ca phn ng l
A. CH3CHBrCH=CH2. B. CH3CH=CHCH2Br. C. CH2BrCH2CH=CH2.D. CH3CH=CBrCH3.
nhit -80 oC => Br C bc cao ; v sn phm cng v tr 1,2 SGK 11nc 167
1(I) 2(III)
CH2=CH CH=CH2 + HBr => CH3-CHBr CH=CH2 => A
1 2 3 4
Ch cch cng : R C = CR CR = C R => cng vo v tr 1,2 hoc 1 ,4
v cht phi c dng nh zy R c th l H hoc hidrocabon ; halogen
VD: CH3 C=C(CH3) C(C2H5)=C-C3H7 ; CH2=CH CH =CH2 ; .
Mnh hiu l cng vo v tr 1,2 ni i 1 hoc 1,4 ni i 1 v ni i 4 a lin kt i vo trong
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- 14 -
CHUYN 3 :
HIROCACBON KHNG NO
CH2 =C(CH3)-CH=CH2 => 1 ni i => 2 sn phm chnh v ph => 2 ni i c 4 sn phm Cng theo quy tc
macopnhicop SGK 11nc 161
Cng vo v tr 1,2 ging 2 trng hp trn=> khng
Cng vo v tr 1,4 c 2 sn phm ; BrCH2-C(CH3)=CH-CH3 ng phn hnh hc
; CH3 C(CH3)=CH-CH2Br => 3
=> Tng = 4 + 3 = 7 =>C
Cu 12: Cht no sau y khng phi l sn phm cng gia dung dch brom v isopren (theo t l mol 1:1) ?
A. CH2BrC(CH3)BrCH=CH2.
B. CH2BrC(CH3)=CHCH2Br.
C. CH2BrCH=CHCH2CH2Br.
D. CH2=C(CH3)CHBrCH2Br.
Iso pren c nhnh => C khng tha mn
Cu 13: Ankaien A + brom (dd) CH3C(CH3)BrCH=CHCH2Br. Vy A l
A. 2-metylpenta-1,3-ien.
B. 2-metylpenta-2,4-ien.
C. 4-metylpenta-1,3-ien.
D. 2-metylbuta-1,3-ien.
Sn phm CH3 CBr(CH3)CH = CH CH2Br sn phm cng v tr 1,4V ni i gia
5
4
3
2
1
cht A ; CH3 C(CH3)=CH CH=CH2 => 4 metylpenta 1,3 ien
cch gi tn s ch v tr mch nhnh mch chnh s ch v tr ien
Vi cch nh s C gn lin kt i nht ien ch c 2 lin kt i tr ln
Cu 14: Ankaien B + Cl2 CH2ClC(CH3)=CH-CH2Cl-CH3. Vy A l
A. 2-metylpenta-1,3-ien.
B. 4-metylpenta-2,4-ien.
C. 2-metylpenta-1,4-ien.
D. 4-metylpenta-2,3-ien.
1
2
3
4 5
Ging 13 cng vo 1,4 => CH3 =C(CH3)-CH=CH-CH3 => 2 metyl penta 1,3 ien => A
Cu 15: Cho 1 Ankaien A + brom(dd) 1,4-ibrom-2-metylbut-2-en. Vy A l
A. 2-metylbuta-1,3-ien.
C. 3-metylbuta-1,3-ien.
B. 2-metylpenta-1,3-ien.
D. 3-metylpenta-1,3-ien.
1
2
3
4
1,4 ibrom 2 metylbut 2 en => CH2Br C(CH3)=CH CH2Br cng vo v tr 1,4
1
2
3 4
=> A : CH2 = C(CH3)-C=CH2 => 2 metylbuta 1,3 ien => A
Cu 16: Trng hp ivinyl to ra cao su Buna c cu to l ?
A. (-C2H-CH-CH-CH2-)n.
B. (-CH2-CH=CH-CH2-)n.
C. (-CH2-CH-CH=CH2-)n.
D. (-CH2-CH2-CH2-CH2-)n.
ivinyl hay 2vinyl Vinyl : CH2 =CH- => ivinyl : CH2=CH-CH=CH2
trng hp => (-CH2-CH=CH-CH2-)n => B
Trng hp l tch ht ni i thnh ni n ri ni vo nhau
VD: CH2 = CH2 => tch ni i : -CH2 - CH2 => -CH2 CH2CH2=CH-CH = CH2 ; tch ; CH2=CH => -CH2-CH Tch CH = CH2 => - CH CH2 - => ni vi nhau => -CH2 CH = CH CH2 Cu 17: ng trng hp ivinyl v stiren thu c cao su buna-S c cng thc cu to l
A. (-CH2-CH=CH-CH2-CH(C6H5)-CH2-)n.
B. (-C2H-CH-CH-CH2-CH(C6H5)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(C6H5)-CH2-)n.
D. (-CH2-CH2-CH2-CH2- CH(C6H5)-CH2-)n .
Stiren SGK 11 nc 194 C6H5-CH=CH2 ; ivinyl : CH2=CH-CH=CH2
P SGK 11 nc 195
P ng trng hp Tch ht cc lin kt i ban u ri ni vi nhau => A
Cu 18: ng trng hp ivinyl v acrylonitrin (vinyl xianua) thu c cao su buna-N c cng thc cu to l
A. (-C2H-CH-CH-CH2-CH(CN)-CH2-)n.
B. (-CH2-CH2-CH2-CH2- CH(CN)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(CN)-CH2-)n.
D. (-CH2-CH=CH-CH2-CH(CN)-CH2-)n .
ivinyl : CH2=CH2-CH=CH2 ;
Vinyl xiannua : CN - CH=CH2 => ng trng hp => (-CH2-CH2=CH-CH2-CH(CN)-CH2-)n => D
Cu 19: Trng hp isopren to ra cao su isopren c cu to l
A. (-C2H-C(CH3)-CH-CH2-)n .
C. (-CH2-C(CH3)-CH=CH2-)n .
B. (-CH2-C(CH3)=CH-CH2-)n.
D. (-CH2-CH(CH3)-CH2-CH2-)n .
SGK 11nc 198 =>B
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- 15 -
CHUYN 3 :
HIROCACBON KHNG NO
CH3
A. 4-metylpent-2-in.
B. 2-metylpent-3-in.
C. 4-metylpent-3-in.
D. 2-metylpent-4-in.
S ch v tr Tn nhnh / tn mch chnh/ - s ch v tr in
Mch chnh l mch c lk i, di nht v c nhiu nhnh nht.nh s C mch chnh bt u t pha gn lk i
hn.S ch v tr lk i ghi ngay trc ui in)
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- 16 -
CHUYN 3 :
HIROCACBON KHNG NO
(RH c th to kt ta vi dd AgNO3/NH3 l ankin loi C4H10 (ankan) v C4H8 (anken hoc xicloankan) ,ch
c th l C4H6 v C3H4)
Cu 33: Hn hp A gm hiro v cc hirocacbon no, cha no. Cho A vo bnh c niken xc tc, un nng bnh mt
thi gian ta thu c hn hp B. Pht biu no sau y sai ?
A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v s mol nc khi t
chy hon ton hn hp B.
B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon ton hn hp B.
C. S mol A - S mol B = S mol H2 tham gia phn ng.
D. Khi lng phn t trung bnh ca hn hp A bng khi lng phn t trung bnh ca hn hp B.
A ng v bo ton nguyn t C v H trc v sau p . Ta c hn hp A p to thnh hn hp B
=> Tng s H , C trong hn hp A = Tng s H,C trong hn hp B V hn hp A ch c H v C , nh H2 l H ,
hidrocacbon no , ko n cng cha H v C
B ng . nu ta gi CT tng qut ca hn hp A l CxHy V thnh phn ch cha C , H => hn hp B cng l CxHy
Bo ton nguyn t trc v sau p => u t chy cng mt lng O2.
C ng.
Cu 34: Cht no trong 4 cht di y c th tham gia c 4 phn ng: Phn ng chy trong oxi, phn ng cng brom,
phn ng cng hiro (xc tc Ni, to), phn ng th vi dd AgNO3 /NH3
A. etan.
B. etilen.
C. axetilen.
D. xiclopropan.
(mi cht hu c u tham gia p chy trong O2.ankan khng tham gia p cng Br loi A.etilen v xiclopropan
khng tham gia p th vi AgNO3//NH3 loi B,D.ch c axetilen c th tham gia c 4 p :C)
Cu 35: Cu no sau y sai ?
A. Ankin c s ng phn t hn anken tng ng.
B. Ankin tng t anken u c ng phn hnh hc.
C. Hai ankin u dy khng c ng phn.
D. Butin c 2 ng phn v tr nhm chc.
(ankin khng c ng phn hnh hc v k c lk i khng phi lk ba)
Cu 36: Cho cc phn ng sau:
(1) C H4 + C2l
a skt
1:1
(2) C2H4 + H2
(3) 2 CHCH
(4) 3 CHCH
(5) C2H2 + Ag2O
(6) Propin + H2O
S phn ng l phn ng oxi ho kh l:
A. 2.
B. 3.
C. 4.
D. 5.
(1) CH4 + Cl2 CH3Cl + HCl
(2) C2H4 + H2 C2H6
(3) 2 CHCH CH2=CH-CCH
(4) 3 CHCH C6H6
(5) C2H2 + Ag2O AgCCAg+H2O
(6) Propin + H2O C2H5CHO
Xem p no c s thay i s OXH l p OXH-K => 1 , 2 ,3 , 6 => C : 4
Cch xc nh s oxi ha C trong cht hu c.
(Cc s oxi ha ca cc cht O , H , N , halogen th vn vy)
+ Trong hp cht hu c th tch ring tng nhm Cn ra tnh
VD : CH3 CH2 CH(CH3) CH3 => CH3 | CH2 | CH | CH3 | CH3 => -3|-2|-1|-3|-3
+ Nu nhm chc khng cha C (halogen , -OH , -O-,NH2) thnh tnh s Oxihoa C gn c nhm chc.
VD: CH3 CH(Br)-CH3 => CH3 | CHBr | CH3 => -3 | 0 | -3
CH3 CH2 CH2OH => CH3 | CH2 | CH2OH => -3 | -2 | -1
CH3 O CH2 CH3 => CH3 O| O CH2 | CH3 => -2 | -1 | -3
+ Nu nhm chc c C th tnh ring.
VD : CH3 CHO => CH3 | CHO => -3 | +1
CH3 COOH => CH3 | COOH => -3 | +3
P 1 thy Cl2 => HCL Cl0 + e => Cl-1 ; C-4 -2e => C-2 CH3CL
P 2 thy H2 => C2H6 => H0 - e => H+1 ; C-2 + e=> C-3
P 3 thy 2CHCH => CH2=CH-CCH : C-1 + e => C-2 ; C-1 - e => C0
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- 17 -
CHUYN 3 :
HIROCACBON KHNG NO
P 6 thy propin CH3-CCH => -3 | 0 | -1 => C2H5CHO => CH3 CH2 CHO => -3 | -2 | +1 ;
C0 + 2e => C-2 ; C-1 - 2e => C+1
=> 4 p. => C
Cu 37: Cho dy chuyn ho sau: CH4 A B C Cao su buna. Cng thc phn t ca B l
A. C4H6.
B. C2H5OH.
C. C4H4.
D. C4H10.
Caosu buna => (-CH=CH CH=CH-)n => C l C4H6 => Loi A
Thm mt st p
Al2 O3
2C2 H5 OH
Na, t
C4H10
CH 2=CH-CH=CH 2 +2H2
B
HCl
D
N + H2 D E (spc)
Xc nh N, B, D, E bit rng D l mt hidrocacbon mch h, D ch c 1 ng phn.
A. N : C2H2 ; B : Pd ; D : C2H4 ; E : CH3CH2Cl.
B. N : C4H6 ; B : Pd ; D : C4H8 ; E : CH2ClCH2CH2CH3.
C. N : C3H4 ; B : Pd ; D : C3H6 ; E : CH3CHClCH3.
D. N : C3H4 ; B : Pd ; D : C3H6 ; E : CHCH2CH2Cl.
bi => D ch c 1 ng phn => Loi B v D: C4H8 to ra do p E p => CH2=CH-CH2 CH2 ; CH3 CH =
CH CH3 ng phn hnh hc)
E l sn phm chnh .=> Loi D v p CH2 = CH CH3 (C3H6) + HCL => spc CH3 CHCL CH3 , sn phm ph
l CH2CL CH2 CH3.
Loi A v E l sn phm chnh nu D l C2H4 s to ra mt sn phm. P C2H4 + HCL => C2H5CL
=> C ng
Cu 39: Cht no sau y khng iu ch trc tip c axetilen ?
A. Ag2C2.
B. CH4.
C. Al4C3.
D. CaC2.
Ag2C2 + 2HCl C2H2 + 2AgCl
2CH4 C2H2 + 3 H2 k 1500 oC, lm lnh nhanh
CaC2 + 2H2O Ca(OH)2 + C2H2
Al4C3 +12H2O 4Al(OH)3 + 3CH4 2CH4 C2H2 + 3 H2
=> C
Cu 40: lm sch etilen c ln axetilen ta cho hn hp i qua dd no sau y ?
A. dd brom d.
B. dd KMnO4 d.
C. dd AgNO3 /NH3 d. D. cc cch trn u ng.
(anken,ankin tham gia p cng halogen(Br), p OXH (KMnO4):lm mt mu thuc tm loi A,B,D.Ankin c th t/d
vi dd AgNO3/NH3 d cn an ken th khng :C)
Cu 41: nhn bit cc bnh ring bit ng cc kh khng mu sau y: SO2, C2H2, NH3 ta c th dng ho cht
no sau y ?
A. Dung dch AgNO3/NH3.B. Dung dch Ca(OH)2 C. Qu tm m. D. Dung dch NaOH
KOH
Cu 42: X l mt hirocacbon kh ( ktc), mch h. Hiro ho hon ton X thu c hirocacbon no Y c khi
lng phn t gp 1,074 ln khi lng phn t X. Cng thc phn t X l
A. C2H2.
B. C3H4.
C. C4H6.
D. C3H6.
p n => A,B,C u l c dng CnH2n-2
Xt A,B,C nu sai th => D ng
PT : CnH2n-2 + 2nH2 => CnH2n+2 Hidro ha l p cng H2 vo lin kt pi + Thu c hidrocabon no
Chn 1 mol CnH2n-2 => to thnh 1 mol CnH2n+2
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- 18 -
CHUYN 3 :
HIROCACBON KHNG NO
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- 19 -
CHUYN 3 :
HIROCACBON KHNG NO
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- 20 -
CHUYN 3 :
HIROCACBON KHNG NO
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- 21 -
CHUYN 3 :
HIROCACBON KHNG NO
nC2H2 = 3,36 / 22,4 = 0,15 mol Kh = nCaC2 => mPT CaC2 = 0,15.64 = 9,6 g
=> m thc t = mPT .100% / 80% = 9,6.100% / 80 = 12 g =>D
Cu 62: C 20 gam mt mu CaC2 (c ln tp cht tr) tc dng vi nc thu c 7,4 lt kh axetilen (20 oC,
740mmHg). Cho rng phn ng xy ra hon ton. tinh khit ca mu CaC2 l
A. 64%.
B. 96%.
C. 84%.
D. 48%.
Ta c 1atm = 760 mmHg => 740 mm Hg =0,9736 atm
nC2H2 = P.V/T.0,082 = 0,9736.7,4 / ((20 + 273).0,082) n = 0,3 mol = nCaC2 PT bi 61
mPT CaC2 = 0,3.64 = 19,2 g => tinh khit = mPT / mBan u = 19,2 .100%/ 20 = 96%
Cu 63: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng
brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch
AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l
A. 40%.
B. 20%.
C. 25%.
D. 50%.
Gi x , y , z ln lt l s mol CH4 , C2H4 , C2H2
=> 16x + 28y + 26z = 8,6
(I)
P vi Br2 d => nC2H4 + 2nC2H2 = nBr2 y + 2z = 0,3mol (II)
Vi 13,44 lt (ktc) => n hn hp = nCH4 + C2H4 + nC2H2 = 0,6
n C2H2 = nKet tua AgCCAg = 0,15 mol
=> nC2H2 / n hn hp = z / (x + y + z) = 1 /4 x + y 3z = 0 (III) Phi chia tm ra t l v 13,44 lt khng phi
ca 8,6 g
Gii h I , II , III => x = 0,2 ; y = z = 0,1 => %VCH4 = nCH4 / n hn hp = x .100%/ (x + y + z) = 0,2 / 0,4 = 50%
Cu 64: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi
lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,1 mol C3H6 v 0,2 mol C3H4.
C. 0,2 mol C2H4 v 0,1 mol C2H2.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Cch 1 : th p n => D tha mn
Cch 2 :
Ta c M = m / n = 12,4 / 0,3 = 41,33 = 12x + y => x = 3 => y = 5,33 => loi A v B v c 3 C
=> Th 1 trong 2 p n B v D . Xt B sai => D ng
Cu 65: Trong mt binh kin cha hirocacbon A th khi (kt) va O2 (d). Bt tia la in t chay ht A a hn
hp v iu kin ban u trong o % th tich cua CO 2 va hi nc ln lt la 30% va 20%. Cng thc phn t cua A
va % th tich ca hirocacbon A trong hn hp la
A. C3H4 va 10%.
B. C3H4 va 90%.
C. C3H8 va 20%.
D. C4H6 va 30%.
Tao c %CO2 = 30% ; %H2O = 20% => Cn li 50% ca O2 v O2 d
T l % theo th tch = t l s mol => chn nCO2 = 3 mol => nH2O = 2 mol => nO2 d = 5 mol
T l nCO2 / nH2O = 3 /2 => chn nCO2 = 3 ; nH2O = 2 => n = nCO2 / (nCO2 nH2O) = 3 => C3H4 V nCO2 >
nH2O => CnH2n-2
nC3H4 = nCO2 / 2 = 1 mol ; BTNT oxi : 2nO2 = 2nCO2 + nH2O = 2.3 + 2 nO2 p = 4 mol
mol hn hp ban u = nC3H4 + nO2 p + nO2 d = 1 + 4 + 5 = 10 mol
=> %VC3H4 A hn hp = nC3H4 / n hn hp = 1 / 10 = 10% => A
Cu 66: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc
th tch kh v hi o trong cng iu kin nhit v p sut). Cng thc phn t ca X l
A. C2H4.
B. CH4.
C. C2H6.
D. C3H8.
Cch 1 th p n
T l th tch = t l s mol
1 mol hn hp C2H2 v X => 2 mol CO2 + 2molH2O
p n => B,C,D u c dng CnH2n+2 => Xt X l CnH2n+2
Gi x , y ln lt l nC2H2 v CnH2n+2
x+y=1;
(1)
2x + ny = nCO2 = 2 BTNT C
(2)
2x + y(2n+2) = 2nH2O = 4 BTNT H
2(x+y) + 2ny = 4
(3)
Th 1 vo 3 ta c ny = 1 => th vo 2 => x = 0,5 th vo 1 => y = 0,5
x = y = 0,5 th vo 2 => n = 2 => C2H6 => C
Cu 67: Hn hp X c t khi so vi H 2 l 21 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng
khi lng ca CO2 v H2O thu c l
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- 22 -
CHUYN 3 :
HIROCACBON KHNG NO
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Tng t 1 bi lm ri => Propan C3H8 Propen C3H6 Propin C3H4 => u c 3C
=> Gi CT chung : C3Hy Ta c M = 21.2 = 42 = 12.3 + y => y = 6
=> CT : C3H6 +O2 => 3CO2 + 3H2O
0,1mol
0,3mol 0,3mol => m = 0,3.44 + 0,3.18 = 18,6 g => A
Cu 68: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn
V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu
trnh l 50%)
A. 224,0.
B. 448,0.
C. 286,7.
D. 358,4.
PVC : C2H3Cl ; BT NT C => nCH4 = 2nC2H3Cl = 2. 4 = 8 mol
=> n kh thin nhin = nCH4 . 100% / 80% = 10 mol => V = 224 lt => B
Cu 69: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp
kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc)
c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,20 gam.
B. 1,04 gam.
C. 1,64 gam.
D. 1,32 gam.
Bo ton khi lng => m trc = m sau mC2H2 + mH2 = m bnh tng + mZ V m hn hp ban u = m hn hp
Y v m hn hp Y = m anken, ankin nu c cho vo dd Br2 + m hn hp Z bay ra
0,06.26 + 2. 0,04 = m bnh tng + 32.0,5.0,02 m bnh tng = 1,32 g => D
Cu 70: t chy hon ton m gam hirocacbon th kh, mch h, nng hn khng kh thu c 7,04 gam CO2. Sc
m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca
m l
A. 2 gam.
B. 4 gam.
C. 10 gam
D. 2,08 gam
nCO2 = 0,16 = x .nCxHy BT NT C
Gi k l s lin kt pi trong hidrocacbon => k .nCxHy = nBr2 nCxHy = 0,16 / k th vo trn ta c
0,16 = x. 0,16 / k x = k
CT tng qut : CnH2n + 2 2k Ta c n = k => CnH2
Ta c hidrocacbon nng hn khng kh => 12n + 2 > 29 => n > 2,25
Ta c m = (12n+2).0,16/n
V th kh => C2 C4 => s C = 2 4
Ta c n > 2,25 => n = 3 v n = 4
Xt n = 3 => C3H2 Khng th vit c => Loi hoc vi k = 3 => n 4
=> n = 4 => m = (12.4+2).0,16 / 4 = 2 g => A
Cu 71: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04 gam CO2. Sc m gam hirocacbon
ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn ng. Gi tr ca m l
A. 2 gam.
B. 4 gam.
C. 2,08 gam.
D. A hoc C.
Ging bi 71 ch khng c nng hn khng kh
Ta vn c m = (12n+2).0,16/n
Xt n = 2 => m = 2,08 ; xt n = 4 => m = 2 g => D
V C bin thin t 2 => 4 v n = 3 khng c => ch c n =2 v n = 4
Cu 72: Dn V lt ( ktc) hh X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn
Y vo lng d AgNO3 trong dd NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam
brom v cn li kh Z. t chy hon ton kh Z c 2,24 lt kh CO2 (ktc) v 4,5 gam H2O. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Y vn cn C2H2 d v Y p vi AgNO3 / NH3 => AgCCAg => nC2H2 d = nAgCCAg = 0,05 mol ;
Kh i ra khi bnh p vi Br2 => C2H4 To thnh => nC2H4 = nBr2 = 0,1 mol
t kh Z => t C2H6Ankan + H2 dNu c => nC2H6 = nCO2 / 2 = 0,05 molBTNT C
nH2O to thnh t C2H6 => 6nC2H6 = 2nH2O BTNT H => nH2O = 0,15 mol
nH2 d = nH2O to thnh nH2O to thnh t C2H6 = 0,25 0,15 = 0,1 nH2 = nH2O BTNT H2
Ta c cht ban u : C2H2 ; H2 => Cht sau p hn hp Y gm 0,05 mol C2H2 d ; 0,1 mol C2H4 ; 0,05 mol C2H6
v 0,1 mol H2 d
BTNT C => 2nC2H2 = 2nC2H2 d + 2nC2H4 + 2nC2H6 nC2H2 = nC2H2 d + nC2H4 + nC2H6
= 0,05 + 0,1 + 0,05 = 0,2 mol
BTNT H => 2nC2H2 + 2nH2 = 2nC2H2 d + 4nC2H4 + 6nC2H6 + 2nH2 d
2. 0,2 + 2nH2 = 2.0,05 + 4.0,1 + 6.0,05 + 2.0,1 nH2 = 0,3 mol => n hn hp X = nC2H2 + nH2 = 0,2 + 0,3 =
0,5 mol => V = 11,2 lt
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- 23 -
CHUYN 3 :
HIROCACBON KHNG NO
Cu 73: Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br 2 0,5M.
Sau khi p hon ton, s mol Br2 gim i mt na v m bnh tng thm 6,7 gam. CTPT ca 2 hirocacbon l
A. C3H4 v C4H8. B. C2H2 v C3H8.
C. C2H2 v C4H8.
D. C2H2 v C4H6.
T p n => hidrocabon => 1 ankin v 1 anken
Mol Br2 gim 1 na => P 1 na ; m bnh tng = m hn hp V c 2 cht u p
Gi x , y l s mol Ankin v anken => n hn hp = x + y = 0,2 mol
nBr2 p = 2x + y = 0,35 1 na x = 0,15 ; y = 0,05 => Th p n : MA . 0,15 + MB .0,05 = 6,7
=> C tha mn c MA = MC2H2 = 26 ; MB = MC4H8 = 56
Gi CT ankin : CnH2n-2 ; CT anken : CmH2m
m hn hp = (14n 2) . 0,15 + 14m.0,05 = 6,7 3n + m = 10 => n < 10/3 => n = 2 v n = 3
Xt n = 2 => m = 4 => C tha mn
Xt n = 3 => m = 1 Khng c CH2 => Loi
C
Cu 74: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dd brom (d). Sau khi phn ng hon ton,
c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO 2 (ktc).
CTPT ca hai hirocacbon l
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
p n => 1 ankan Hoc da vo 1,12 lt kh khng p => V ankan = 1,12 => nCnH2n+2 = 0,05 mol
V cht cn li = 1,68 1,12 = 0,56 mol => n cht = 0,025 = nBr2 4 g Br2 p => Cht l anken :CnH2n
nAnkan = 0,05 ; nAnken = 0,025 ; Gi CT an kan : CnH2n+2 ; anken : CmH2m
t to ra CO2 => BTNT C => n.nCnH2n+2 + m.nCmH2m = nCO2 n.0,05 + m.0,025 = 0,125
2n + m = 5 n < 5/2 => n = 1 v n = 2
Xt n = 1 => m = 3 =>C tha mn
Xt n = 2 => m = 1 Loi v khng c cht CH2 => Loi
=> C
Cu 75: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2 bng s mol H2O.
Thnh phn % v s mol ca X v Y trong hn hp M ln lt l
A. 35% v 65%.
B. 75% v 25%.
C. 20% v 80%.
D. 50% v 50%.
Gi X : CnH2n+2 ; Y : CmH2n-2 ; gi x , y l s mol X v Y
BTNT C => x.n + y.m = nCO2
BTNT H => (2n+2).x + (2n-2)y = 2nH2O (n+1)x + (n-1)y = nH2O
Ta c nCO2 = nH2O x.n + y.m = (n + 1)x + (n-1)y x y = 0 x= y => % mi cht = 50%
Cu 76: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c
24,0 ml CO2 (cc kh o cng iu kin to, p). T khi ca X so vi kh hiro l
A. 25,8.
B. 12,9.
C. 22,2.
D. 11,1.
T l th tch = t l s mol => 20mol hn hp X => 24 mol CO2
Gi x , y ln lt l s mol C3H6 , CH4 => nCO = 2y VCO gp 2 ln VCH4
n hn hp = nC3H6 + nCH4 + nCO = x + y + 2y = x + 3y = 20
BTNT C => 3nC3H6 + nCH4 + nCO = nCO2 3x + y + 2y = 24 3x+ 3y = 24
Gii h => x = 2 ; y = 6 => m hn hp = 2.42 + 6.16 + 12.28 = 516 g => M hh X = 516/20 = 25,8
T khi vi H2 = 12,9
Nu khng lm c c th m thy A v B gp i nhau ; C v D gp i nhau
B v D kh nng ng cao hn hay cho la khng tnh t khi
Tng kh nng ng.
Cu 77: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H 2 c hn hp
Y. Khi cho Y qua Pt nung nng th thu c kh Z c t khi i vi CO 2 bng 1 (phn ng cng H2 hon ton). Bit
rng VX = 6,72 lt v VH = 4,48 lt. CTPT v s mol A, B trong hn hp X l (Cc th tch kh o kc)
A. 0,1 mol C2H6 v 0,2 mol C2H2.
B. 0,1 mol C3H8 v 0,2 mol C3H4.
C. 0,2 mol C2H6 v 0,1 mol C2H2.
D. 0,2 mol C3H8 v 0,1 mol C3H4.
2
Cu 78: Mt hn hp X gm C2H2, C3H6, CH4. t chy hon ton 11t hn hp X thu c 12,6 gam H2O. Nu cho
11,2 lt hn hp X (ktc) qua dung dch brom d thy c 100 gam brom phn ng. Thnh phn % th tch ca X ln
lt l
A. 50%; 25% ; 25%.
B. 25% ; 25; 50%.
C.16% ; 32; 52%.
D. 33,33%; 33,33; 33,33%.
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- 24 -
CHUYN 3 :
HIROCACBON KHNG NO
Cu 79: Dn 4,032 lt (ktc) hn hp kh A gm C2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dc AgNO3 trong
NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2 gam kt ta. Khi lng bnh 2 tng thm 1,68
gam. Th tch (ktc) hn hp A ln lt l:
A. 0,672 lt; 1,344 lt; 2,016 lt.
B. 0,672 lt; 0,672 lt; 2,688 lt.
C. 2,016; 0,896 lt; 1,12 lt.
D. 1,344 lt; 2,016 lt; 0,672 lt.
Cu 80: X, Y, Z l 3 hirocacbon th kh trong iu kin thng, khi phn hu mi cht X, Y, Z u to ra C v H 2,
th tch H2 lun gp 3 ln th tch hirocacbon b phn hu v X, Y, Z khng phi l dng phn. CTPT ca 3 cht l
A. C2H6 ,C3H6 C4H6.
B. C2H2 ,C3H4 C4H6.
C. CH4 ,C2H4 C3H4.
D. CH4 ,C2H6 C3H8.
Cu 81: Hn hp X gm 0,1 mol C2H2; 0,15 mol C2H4 ; 0,2 mol C2H6 v 0,3 mol H2. un nng X vi bt Ni xc tc 1
thi gian c hn hp Y. t chy hon ton hn hp Y c s gam CO2 v H2O ln lt l
A. 39,6 v 23,4. B. 3,96 v 3,35.
C. 39,6 v 46,8. D. 39,6 v 11,6.
Cu 82: Hn hp ban u gm 1 ankin, 1 anken, 1 ankan v H 2 vi p sut 4 atm. un nng bnh vi Ni xc tc
thc hin phn ng cng sau a bnh v nhit ban u c hn hp Y, p sut hn hp Y l 3 atm. T khi
hn hp X v Y so vi H2 ln lt l 24 v x. Gi tr ca x l
A. 18.
B. 34.
C. 24.
D. 32.
Cu 83: Hn hp A gm H2, C3H8, C3H4. Cho t t 12 lt A qua bt Ni xc tc. Sau phn ng c 6 lt kh duy nht
(cc kh o cng iu kin). T khi hi ca A so vi H2 l
A. 11.
B. 22.
C. 26.
D. 13.
Cu 84: un nng hn hp X gm 0,1 mol C3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc c hn hp Y. Dn
ton b Y qua bnh ng dung dch KMnO 4 d, thy thot ra 6,72 l hn hp kh Z (ktc) c t khi so vi H 2 l 12.
Bnh ng dung dch KMnO4 tng s gam l:
A. 17,2.
B. 9,6.
C. 7,2.
D. 3,1.
Cu 85: t chy m gam hn hp C2H6, C3H4, C3H8, C4H10 c 35,2 gam CO2 v 21,6 gam H2O. Gi tr ca m l
A. 14,4.
B. 10,8.
C. 12.
D. 56,8.
Cu 86: t chy 1 hirocacbon A c 22,4 lt kh CO2 (ktc) v 27 gam H2O. Th tch O2 (ktc) (l) tham gia phn
ng l:
A. 24,8.
B. 45,3.
C. 39,2.
D. 51,2.
Cu 87: Mt hn hp X gm 1 ankin v H 2 c V = 8,96 lt (kc) v mX = 4,6 gam. Cho hn hp X i qua Ni nung
nng, phn ng hon ton cho ra hn hp kh Y, c t khi
ankin l
A. 0,16 mol; 3,6 gam; C2H2.
B. 0,2 mol; 4 gam; C3H4.
C. 0,2 mol; 4 gam; C2H2.
D. 0,3 mol; 2 gam; C3H4.
Cu 88: t chy mt hirocacbon M thu c s mol nc bng s mol CO 2 v s mol CO2 nh hn hoc bng 5
ln s mol M. Xc nh CTPT v CTCT ca M bit rng M cho kt ta vi dung dch AgNO3/NH3.
A. C4H6 v CH3CH2C CH.
B. C4H6 v CH2=C=CHCH3.
C. C3H4 v CH3C CH.
D. C4H6 v CH3C CCH3.
CHUYN 3 :
HIROCACBON KHNG NO
BI TP V ANKEN
1C
11C
21A
31B
41A
51D
61C
71B
81B
2C
12B
22C
32D
42B
52A
62B
72A
82B
3B
13A
23C
33C
43C
53A
63D
73A
83B
http://aotrangtb.com
4C
14D
24B
34D
44D
54C
64A
74B
84D
5D
15C
25D
35A
45D
55A
65C
75C
85D
6D
16A
26A
36A
46A
56D
66C
76C
- 25 -
7C
17A
27D
37B
47B
57C
67D
77A
8C
18B
28B
38C
48AB
58C
68A
78C
9D
19C
29A
39B
49A
59A
69A
79A
10D
20C
30D
40B
50D
60A
70A
80D
CHUYN 3 :
HIROCACBON KHNG NO
2B
12C
22C
32B
42C
52C
62B
72A
82D
3D
13C
23D
33D
43D
53D
63D
73C
83A
4C
14A
24C
34C
44A
54A
64D
74C
84D
5A
15A
25C
35B
45D
55A
65B
75D
85C
6D
16B
26B
36C
46C
56C
66C
76B
86C
7A
17A
27B
37C
47B
57D
67A
77D
87B
8B
18D
28B
38C
48D
58A
68B
78A
88A
9C
19B
29A
39C
49C
59A
69D
79A
http://aotrangtb.com
- 26 -
10A
20D
30B
40C
50D
60C
70A
80A