B HA HC HU C LUYN THI HSGQG

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B KIM TRA HA HC 12
KIM TRA S 1

K THI HC SINH GII QUC GIA LP 12 THPT

MN THI: HA HC

HA HC HU C
Thi gian lm bi: 180 pht (Khng k thi gian pht )
H v tn th sinh:........................................................................................................
S bo danh:.................................................................................................................
( thi gm c 2 trang)
Cu 1: (3.0 im)
Di y l chui chuyn ha c lin quan n mt s cht hu c
Sn,HCl
HCl
A
B
C
KMnO 4
NaOH,H2 O
D
E
F
o

NaNO 2 ,HCl
NaOH,t
G
H
I
Cc cht A, E v I l nhng ng phn, cng nh B v C. Cc cht C, F v G l nhng mui. Cht F cha
15,85% Natri theo khi lng. C th to c cht E bng cch oxi ha mt s ankaloid t nhin
1. Vit tn v cng thc cu to ca cc cht A, B, C, D, E, F, G, H ,I
2. Cht E c to ra t ankaloid no
3. Nhng phn ng chuyn ha no c xc tc bi cc dn xut ca E. Gii thch ngn gn
4. Vit cng thc cu to ca cc cht thu c khi B tc dng ln lt vi axit HNO2 v vi cht H
Cu 2: (2.0 im)
Mt axit cacboxylic A c cng thc nguyn l C5H8O2. Hp cht ny tn ti 2 dng ng phn lp th l
A1 v A2. gii thch cu trc ca hai ng phn trn, ngi ta x l A vi ozon. Sau phn ng thu c
axetanehit v axit 2-oxipropanoic. Khi hiro ha A1 v A2 bng hiro (trn thanh tip xc Platin) s sinh ra
hn hp raxemic ca axit cacboxylic B.
1. Vit CTCT cc ng phn hnh hc ca A1 v A2, gi tn
2. Vit cng thc chiu Fischer cc ng phn ca B v gi tn theo danh php Cahn-Jugold-Prelog v cho
bit hng quay (+ hoc ) ca cc ng phn
3. Vit phng trnh phn ng ca A1 v A2 vi Brom (dng cng thc hnh chiu Sge-bock). M t c
ch ca phn ng v cho bit trong cc sn phm , sn phm no c ng phn lp th i quang
Cu 3: (1.5 im)
1. Hy ch ra c ch phn ng v sn phm cui ca phn ng cng Brom (1 : 1) vi nhng cht sau:
a. Axit maleic (1)
b. Axit fumaric (2)
c. But-2-in (3)

H 3C C C CH3
(1)
(2)
(3)
2. Hy gi tn sn phm cui ca 3 phn ng trn theo danh php IUPAC, R/S, E/Z
Cu 4: (1.5 im)
Qu trnh tng hp aminoaxit nh sau:
NH3
H 2O
H2O / H +
H2 O / H +
CN / H +
CH 3CHO
A
[B]
C
D
E ( aminoaxit)
1. Vit cng thc cu to ca cc sn phm t A E
2. Vit cng thc chiu Fischer v gi tn aminoaxit E
Cu 5: (2.0 im)
Mt dn xut ca cc azoankan c dng lm cht khi mo cho phn ng trng hp v chng l ngun
cung cp cc gc t do. 1,1-ixiano-1,1-imetylazometan (X) c tng hp nh sau:
N 2 H4
Cl2 +H 2 O
Y
axeton
A
B
X . Bit cht A c mt nhm OH, cht B khng cha oxi
1. Nu r vai tr ca Cl2 + H2O
2. Vit cng thc cu to ca Y v gi tn. Xc nh CTCT ca A v B
3. Vit phng trnh phn ng phn hy (dng CTCT) ca X nu to ra 2 gc t do v cho thot ra kh X
(bit X c t khi hi vi oxi l 0,875).
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Cu 6: (1.0 im)
Xc nh cc cht A, B, C, D trong 2 s sau v vit cng thc cu to ca chng
1.C2 H5ONa
NaOH / H 2O,
HCl,
A(C7 H10 O4 )
B
C(C4 H6 O2 )
(a) C 2 H5 OCO CH2 COOC2 H5
2.Epoxit
3
2
2
2
2
2
4
A
B
C
D
(b) Anilin
2.H3PO2
1. Trong s (a), cho bit A c my ng phn
2. Trong s (b), gi tn C, D theo danh php IUPAC
Cu 7: (2.5 im)
Xiprofloxaxin (G) l mt thuc khng khun mi c ph rng. Tin trnh tng hp n l:

(CH CO) O

Cl

NaOH,H O

1.HNO /H SO

AlCl3
(C2 H5 O)3 CH
NaH

C8 H5Cl2 FO( A)
C11 H9 Cl2 FO3 (B)
(C)
CH 3COCl
(C2 H5 )2 CO3
C2 H5 ONa

xiclopropyla min
(E)C15 H13 ClFNO3
(C) ( D)C15 H14 Cl2 FNO3

(F )C13 H9 ClFNO3
(G )
(E)
1. Xc nh CTCT cc cht A, B, D, E, F
2. Ti sao phi dng NaH bin i A thnh B nhng li dng C2H5ONa chuyn B thnh C
3. Qu trnh bin i C thnh D l mt giai on hay hai giai on. Gii thch ngn gn
Cu 8: (1.5 im)
Qun ty c th l (i) rt tt k c khi b ma v khng li vt st l nh kh nng bo v ca hp cht
hu c X. Ngi ta c th tng hp X theo s sau:
mui Na ca este malonic
Cl2 / P
C2 H 5OH / H +
Br2 / CCl4
CH3COOH
A
B C(C11 H18 O6 )
D
Na / C 2 H 5OH
C
E ; E + D
F (C22 H34 O12 )
1. Xc nh cc cht t A F
2. Ti sao X li gi c np l (i) trn qun
Cu 9: (2.0 im)
1. Somatostatin l tetraecapeptit. Trt t cc aminoaxit c xc nh bi s kt hp gia thoi bin
Edman v thc nghim thy phn enzim. Da trn cc d kin sau y hy a ra cu trc bc I ca
Somatostatin:
- Thoi bin Edman cho PTH-Ala
- Thy phn chn lc c cc peptit sau: Phe-Trp, Thr-Ser-Cys, Lys-Thr-Phe, Thr-Phe-Thr-Ser-Cys,
Asn-Phe-Phe-Trp-Lys, Ala-Gly-Cys-Lys-Asn-Phe
- Somotostatin c cu ni isunfua
2. Tng hp Prolin t axit aipic
Cu 10: (3.0 im)
1. Arabinopyranoz (D-anopentoz c cu hnh 2S, 3R, 4R) c chuyn ha nh sau:

Ara (C5H10O5)

CH3OH/H

HIO4

1. LiAlH4
2. H2O
Br2/H2O

D
E

H2O/H

H2O/H

HOCH2-CHO + HOCH2-CH2OH
CHO-COOH + HOCH2-COOH

V cu trc ca B, C, D v E
2. Thy phn isaccarit c tnh kh turanoz ngi ta thu c D-glucoz v D-fructoz vi s mol bng
nhau v bng s mol turanoz dng. Metyl ha turanoz vi metyl iodua c mt bc oxit ri thy
phn k tip to thnh 2,3,4,6-tetra-O-metyl-D-fructoz. xut cu to c th c ca turanoz m
khng cn xc nh ha hc lp th ti cc v tr anome
3. T pentoz hy vit s chuyn ha thnh axit aipic (qua giai on to thnh fufural)
- - - - - - - - - - - - - Ht - - - - - - - - - - - - -

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B KIM TRA HA HC 12

K THI HC SINH GII QUC GIA LP 12 THPT

KIM TRA S 2
MN THI: HA HC
HA HC HU C
Thi gian lm bi: 180 pht (Khng k thi gian pht )
H v tn th sinh:........................................................................................................
S bo danh:.................................................................................................................
( thi gm c 2 trang)
Cu 1: C mt dy hp cht vng 6 cnh: Axit Benzoic (A), xiclohexanol (B), phenol (C), p-nitrophenol
(D), p-metylphenol (E), m-nitrophenol (F), m-bromphenol (G)
a. Sp xp dy cht trn theo trnh t tng dn tnh axit
*
I
b. Tnh pKa (F). Bit pKa (C) l 9,95 ; ca dy phenol l 2,1 ; NO2 = 2,80; m NO2 = 0, 71; NO2 = 0, 63.
Cu 2: Vit cng thc cc dng h bin ca cc hp cht sau:
a. Nitrobenzen
b. Ure (NH2CONH2)

c.
d. Guaniin (NH2C(NH)NH2)
Cu 3: Hy biu din hai cu dng gh ca (-)-mentol. Cho bit cu dng no bn nht

Cu 4: T benzen v cc hp cht hu c c s C 3, vit s tng hp cis-1-phenylhex-2-en

Cu 5: A, B l hai hirocacbon c tch t du m c cc tnh cht vt l v d kin phn tch nh sau:
ts (oC)
tnc (oC)
%C
%H
A
68,6
-141
85,63
14,34
B
67,9
-133
85,63
14,34
A cng nh B lm mt mu nhanh chng dung dch KMnO4 v nc brom, khi ozon phn cho sn phm
ging nhau. Xc nh cu trc ca A, B
Cu 6: Hon thnh s phn ng sau, xc nh cc hp cht t A n I:
PCl5
1.LiNH 2
H2
CH3 MgI
Ac2 O
1.Mg,ete khan
to
X
A
B
C
D
E
F
I(C19 H38 O2 )
2. CH 2 =C(CH3 ) CHO
2.C6 H13Br
Pd / C
ete khan
Cho bit: A c 1H etilenic, B c 5H etilenic, D c 1H etilenic, X l:

Cu 7: Hon thnh s phn ng sau:

HC CNa

1.NaNH 2
2.Na / NH3( l )

HC CNa

1.CH3MgBr
CH 3CH 2 CH 2 I
A B C
D
E(C11 H18 )
F
3.H 2O
2.CO2
NaNH 2
Br (CH 2 ) 4 Cl

NaI
S 2
N

F G (C12 H 20 O2 )
H 2 (1mol)
Pd / CaCO3

Cu 8: T benzen v hp cht c 4C, vit s iu ch

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Cu 9: Hon thnh dy chuyn ha sau:

2HCl + Zn (CN ) 2
H2
+X

A
B
C
AlCl3

F
epoxit
HCl
CH 3 NHCH3
D
E
Cho bit trong s trn X l:

Cu 10: 3-iot-2,2-imetylbutan khi phn ng vi AgNO3 trong etanol s cho 3 sn phm. Vit cng thc cu
to ca 3 sn phm y v cho bit sn phm no chim t l ln nht.
Cu 11: m-Flo-isopropylbenzen (I) c tng hp theo 8 bc i t benzen (A)
+ Me2 CHBr / AlCl3
+ Br2 / Fe
HNO3
HNO2
H2 O
6[H ]
to
Mg
A
B

C
D
E
F
G
H
I
HBF4
Xc nh CTCT cc cht.
Cu 12: Pheromol (H) c Bestmann iu ch nm 1982 nh sau:
Me(CH 2 )8 Br
2H 2
1.EtMgBr
1.EtMgBr
brom ha
HC CLi
A
B
C
D
E ( C16 H 29 Br )
2.HC C CH 2 OTs
2.Epoxit
Pd,Lindlar
CBr4 +PPh3

Ph 3P
NaI
1.OH
E
F
G
H
axeton
2.CH 2 =CH CHO

Xc nh cng thc cu to cc cht t A n G. Bit H l:

- - - - - - - - - - - - - Ht - - - - - - - - - - - - -

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B KIM TRA HA HC 12

K THI HC SINH GII QUC GIA LP 12 THPT

KIM TRA S 3
MN THI: HA HC
HA HC HU C
Thi gian lm bi: 180 pht (Khng k thi gian pht )
H v tn th sinh:........................................................................................................
S bo danh:.................................................................................................................
( thi gm c 2 trang)
Cu 1: Khi cho cis v trans-3,3-imetyl-2-bromxiclohexanol phn ng nhanh vi baz mnh s thu c 2
sn phm ring bit. Sn phm to thnh t cis-bromancol c vn hp th 1710 cm -1, cn sn phm kia
khng c vn hp th ny v cng khng c vn hp th 3350 cm -1. Xc nh cng thc cu to ca cc
sn phm trn
Cu 2: T 1,1-iphenylaxeton v imetylbenzen-1,2-icacboxylat, hy iu ch iphenaion

Cu 3: Hp cht A phn ng vi PCl3 cho ra B, kh ha B bng H2/Pd nhn c benzanehit. Mt khc

cho B tc dng vi NH3 c C, x l C vi Br2 trong mi trng kim c D. T B c th nhn c E
bng cch cho phn ng vi benzen xc tc AlCl3. E chuyn thnh F khi x l vi hiroxylamin, trong mi
trng axit F chuyn thnh G. Vit cng thc cu trc cc hp cht t A n G
Cu 4: T xiclohexa-1,3-ion v cc hp cht 4C, hy tng hp:

Cu 5: Hy thc hin dy chuyn ha sau:

H3O +
AlH3
CH 2 N 2
CrO3
EtONa
MeONa
X
B
C
D, trans
E
Y
o A
+1,2
Zn / Ag
H 2SO 4
HC C CH Br,70 C
Hg 2 +
to
2

Trong : X, Y ln lt l:

(X)
(Y)
Cu 6: Vit cng thc cu trc ca cc sn phm trung gian v dng mi tn ch r s tng tc ca nhn
vi trung tm phn ng:
OEt
ph vng
HOEt
OEt
khp vng
OEt
OEt
H+
X
A
B
C
D
E
F
G
Y
Trong X, Y ln lt l:

(X)
(Y)
Cu 7: Tin hnh ngng t gia benzanehit v etyl metyl xeton ln lt trong mi trng axit v mi
trng baz ngi ta thu c 2 sn phm khc nhau. Vit CTCT cc sn phm to thnh, gii thch
Cu 8: Gi tn cc sn phm to thnh khi cho ln lt axit cis-crotonic, axit trans-crotonic tc dng vi
OsO4/H2O2
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Cu 9: Thc hin dy chuyn ha sau:

H 2SO4
PhCHO
1.BuLi
Ni,Raney
H +,t o
HS (CH 2 )3 SH
A
B
C
D
E
2.Etyl trans But 2 enoat
H2
H 2O
H+
Trong E l:

Cu 10: Metylaxetimiua (A) thy phn trong mi trng NaOH ban u cho axetamit v metanol. Trong
dung dch axit, A thy phn (ban u) cho metyl axetat v ion amoni
a. Dng mi tn ch r c ch hnh thnh axetamit
OH
CH3 C(= NH) OCH3
CH3 CONH2 +CH3 OH
H2O
b. Dng mi tn ch r c ch hnh thnh metyl axetat
H+
CH3 C(= NH) OCH3
CH3 COOCH3 +NH4+
H2O
(H+ d)
c. Hy gii thch ti sao hai phn ng cho 2 sn phm khc nhau
Cu 11: Hp cht A, (S)-C8H17N quang hot, tan trong HCl, phn ng vi NaNO2/HCl khng tch kh, Cho
kt ta vi PhSO2Cl/NaOH. Metyl ha trit v tch loi Hopman cho anken, mt trong s l B
(C10H21N) . Tip tc cho thoi phn hopman nhn c hn hp Octa-1,4-ien v octa-1,5-ien. Hy xc
nh CTCT ca A v B
Cu 12: T catechol, metylamin v ClCH2COCl, hy vit s iu ch arenalin C9H13NO3

Cu 13: LSD l cht gy o gic mnh, c cng thc:

V Novocain l 2-(N,N-ietylamino)etyl-4-aminobenzoat
a. Vit CTCT ca Novocain
b. Vit CTCT sn phm sinh ra khi cho mi cht trn tc dng vi dung dch HCl theo t l mol 1:1
c. Vit CTCT tng sn phm sinh ra khi un nng cc cht trn vi dung dch HCl v vi dung dch
NaOH
- - - - - - - - - - - - - Ht - - - - - - - - - - - - -

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B KIM TRA HA HC 12

K THI HC SINH GII QUC GIA LP 12 THPT

KIM TRA S 4
MN THI: HA HC
HA HC HU C
Thi gian lm bi: 180 pht (Khng k thi gian pht )
H v tn th sinh:........................................................................................................
S bo danh:.................................................................................................................
( thi gm c 2 trang)
Cu 1: Tripeptit Eixenin cha mt nhm cacboxyl t do, khng phn ng vi initroflobenzen ; khi thy
phn hon ton cho 2 mol axit Lglutamic, 1 mol Lalanin v 1 mol NH3. Cn khi phn ng vi hirazin
khan th cho Lalanin nhng khng cho axit glutamic. Hy vit CTCT ca Eixenin
Cu 2: T alanin, glixerin v nitrobenzen. Hy vit s tng hp Quinolin
Cu 3: Hp cht A (C5H10O4) quang hot, tc dng vi anhirit axetic cho iaxetat nhng khng cho phn
ng trng bc. Khi cho A tc dng vi axit long s nhn c metanol v B (C4H8O4). Kh ha B nhn
c C (C4H10O4) khng quang hot. Khi oxi ha B trong iu kin m du s nhn c axit D (C4H8O5).
X l amit ca D bng dung dch HClO long s nhn c D-glixeranehit C3H6O3. Xc nh CTCT v cu
trc lp th ca A, B, C v D
Cu 4: Hy chuyn ha D-Glucoz thnh L-Guloz
Cu 5: Khi thy phn Phlorizin C21H24O10 c mt elmusin th c D-glucoz v hp cht A. X l
Phlorizin vi CH3I d/K2CO3 v sau thy phn bng axit th c hp cht B. Xc nh CTCT ca
Phlorizin. Bit rng:

Vi R = H Hp cht A ; R = CH3 Hp cht B

Cu 6: Gentibioz l ng kh v c kh nng to osazon, chu i quay v b thy phn bng dung dch
nc axit hoc bng elmusin cho D-glucoz. Metyl ha ri thy phn s cho sn phm l
2,3,4,6tetra-O-metyl-D-glucoz. Vit CTCT v gi tn Gentibioz C12H22O11
Cu 7: Hp cht thin nhin Y (C7H14O6) khng c tnh kh v khng i tnh quang hot. Y b thy phn
bi dung dch HCl/H2O thnh K l mt ng kh. Khi b oxi ha bi axit nitric long, K chuyn thnh axit
khng quang hot L (C6H10O8). S thoi phn Ruff dn ti mt ng kh M ; cht ny b oxi ha bi axit
nitric long thnh axit quang hot N (C5H8O7)
a. Xc nh cu trc ca Y, K, L, M, N
b. C tn ti s khng khng nh no v mt cu trc khng
Cu 8: Hp cht A C4H8O3 quang hot, tan tt trong nc to thnh dung dch phn ng axit vi giy qu.
un mnh dung dch, A chuyn thnh cht B C4H6O2 khng quang hot tan va phi trong nc v cng cho
phn ng axit vi giy qu. B phn ng vi KMnO4 mnh lin hn A. Oxi ha A bng dung dch H2CrO4
long s thnh cht lng bay hi C C3H6O. C khng phn ng vi KMnO4 nhng cho phn ng vi I2 trong
dung dch kim. Vit CTCT cc cht v phng trnh phn ng xy ra. Cc d kin trn iu kin
xc nh cu trc ca A cha, gii thch.
Cu 9: Xibeton c cng thc C17H30O b oxi ha nh nhnh cho 2 axit l: axit octanioic v axit nonanioic.
Hy gi tn Xibeton theo danh php IUPAC v chuyn hn hp ng phn ca n thnh cis-xibeton.
Cu 10: Hp cht X C6H9OBr phn ng vi metanol trong mi trng axit sinh ra Y C8H15O2Br. Cho Y
phn ng vi Mg trong ete khan, sau cho phn ng tip vi anehit formic c cht E. Thy phn E
trong mi trng axit c F, ehirat ha F thu c 2-vinylxiclopentanon
a. Xc nh CTCT ca X
b. Nu mun iu ch F t X c nht thit phi qua cc giai on nh trn khng, v sao.
Cu 11: Axit Mevalonic hay axit 3,5-ihiroxi-3-metylpentanoic gi vai tr quan trng trong qu trnh sinh
tng hp tecpenoic v steroit
a. un axit R-Mevalonic vi dung dch axit v c thu c sn phm A C6H10O3. Vit phng trnh phn
ng bng cch dng CTCT. Cho bit cu hnh ca A
b. Khi kh nhm cacbonyl ca A thu c cht B C6H12O3, B d b chuyn ha nh xc tc axit to thnh
C C6H12O3. Vit cng thc ca B, C c ghi k hiu cu hnh. Trnh by c ch phn ng chuyn ha B
thnh C
Cu 12: Higrin X C8H15ON l mt ankaloit c tm thy trong cy cca.
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a. Xc nh CTCT ca X bit rng: X khng tc dng vi benzensunfoclorua, khng tan trong kim nhng
tan trong dung dch HCl. X tc dng vi phenylhirazin v cho phn ng ioofom. Nu oxi ha X bng
dung dch CrO3 s to thnh axit higrinic C6H11O2N
b. C th tng hp axit higrinic C6H11O2N bng chui cc phn ng sau:
CH3 NH 2
[CH(COOEt) 2 ]- Na +
Br2
Ba (OH) 2 dd
ddHCl
BrCH 2CH 2 CH 2 Br
A
B

C(C11 H19 O4 )

E
to
o

t
E
axit higrinic + CO 2 +H 2 O
- - - - - - - - - - - - - Ht - - - - - - - - - - - - -

B KIM TRA HA HC 12

K THI HC SINH GII QUC GIA LP 12 THPT

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MN THI: HA HC

KIM TRA S 5

HA HC HU C
Thi gian lm bi: 90 pht (Khng k thi gian pht )
H v tn th sinh:........................................................................................................
S bo danh:.................................................................................................................
( thi gm c 1 trang)
Cu 1: Axit Abxixic thuc loi sesquitacpenoit c nhiu trong gii thc vt c tc dng iu chnh gic ng
ng ca cy ci v cho php cy tn ti trong mi trng bt li. C nhiu phng php tng hp axit
Abxixic. y dn ra phng php i t axeton:
H+
NaNH 2
- 2H 2 O
etylenglicol

D(C11 H18 O2 )
3CH 3COCH3
A
B(C19 H13 O)

C
(C
H
O
)

11 18 2
p- CH C H SO H
3 6

KMnO 4
OH-

KMnO4
OH-

CH3SO2 Cl
piridin

D [E](C11H 20 O4 ) F (C11 H18 O4 )

G (C11 H15 O3 )
Tip theo s ni mch to thnh axit nh sau:
H 2O
CrSO 4
LDA
G
Metyl-3-metylpent-2Z-en-4-inoat
H (Li + C-7 H 7 O2 )
I (C18 H22 O5 Li)
K

L
DMF
+

NH 4
1.CH3ONa,H 2O
L
M

axit Abxixic
H 2O
2.H+

a. Vit CTCT cc cht t A n M bit rng hn hp metansunfonyl clorua/ piriin dng tch nc
ancol bc ba. LDA l: Liti iisopropyl amiua
b. Axit Abxixic c tnh quang hot hay khng, n c cu hnh nh th no
Cu 2: tch ring xiclohexanon ra khi mt hn hp gm xiclohexanon (t os = 156oC) v xiclohexanol (tos
= 160oC) ngi ta tin hnh nh sau: Lc hn hp vi dung dch NaHSO 3 bo ha trong nc. Sau mt thi
gian thm imetylete v trn u. Tch ly ring phn ete v phn H2O. Thm dung dch NaOH hoc dung
dch H2SO4 long vo phn dung dch nc. Sau li chit bng ete nh trn. Phn dch ete ln ny em
lm khan, chng ct loi b ete thu c xiclohexanon
1. Gii thch ngn gn qu trnh trn. Cho bit dng cht g lm khan
2. Vit cc phng trnh xy ra v gii thch tc dng ca axit v kim
Cu 3: Fomanehit phn ng vi NH3 to ra hexametylentetramin (Urotropin) C6H14N4 v nc. Cht ny
c cu to ging nh adamantan nhng ti cc u mt ca cc vng u do N chim gi. l nhng cht
bn c im nng chy cao. Cho hexametylenetramin tc dng vi HNO 3 trong CH3COOH khan to ra
hexogen (cht ny rt ph bin dng lm cht n trong th gii chin th II) ng thi gii phng 3 mol
HCHO v 1 mol NH3. Vit cc phng trnh phn ng
Cu 4: Vitamin C (axit L-ascobic) c cu trc nh sau:

a. Hy gii thch tnh axit ca axit L-ascobic (pKa = 4,21)

b. iu ch L-ascobic t D-glucoz
Cu 5: T pentoz, hy vit s chuyn ha thnh axit aipic qua giai on to thnh fufuran
Cu 6: Salixin C13H18O7 b thy phn bi elmusin cho D-glucoz v Saligenin C7H8O2. Salixin khng kh
thuc th Tolen. Oxi ha Salixin bng HNO3 thu c mt hp cht hu c X m khi thy phn th cho DGlucoz v anehit Salixylic. Metyl ha Salixin thu c pentametylsalixin, thy phn hp cht ny cho ta
2,3,4,6-tetra-O-metyl-D-Glucoz. Xc nh CTCT ca Salixin
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