TON V P C TRNG CA AMIN

A. TM TT L THUYT:
* CTTQ: - Amin: CxHyNt (vi y 2x + 2 + t v t cng l hay cng chn) - Amin n chc: CxHyN (vi y 2x + 2) - Amin no, n chc, mch h: CnH2n+3N ( n 1, nguyn) - Amin, no, n chc, mch h bc I: CnH2n+1NH2 ( n 1, nguyn) - Amin thm, n chc, cha 1 nhn benzen, gc hidrocacbon lin kt vi nhn l gc no: CnH2n-7NH2. ( n 6, nguyn) * Tnh cht ha hc ca amin: l tnh baz. .. R NH2 + H+ R NH3+. - Tc dng vi axit: Vd: CH3-NH2 + HCl metyl amin C6H5-NH2 + H2SO4 phetyl amin - Tc dng vi dd mui: Vd: C2H5NH2 + FeCl3 + H2O etyl amin Nu l amin thm ( nh anilin: C6H5 NH2 ) cn cho p th hin nhn thm: NH2 + Br2 Anilin Hay : C6H5-NH2 + Br2

B. BI TON VN DNG:
DNG 1: Xc nh CTPT ca amin (da vo p chy) to * PTHH: CxHyNt + (x+y/4) O2 x CO2 + y/2 H2O + t/2 N2 to 2CnH2n+3N + [ (6n+3)/2 ]O2 2n CO2 + (2n+3) H2O + N2

BT1: t chy hon ton amin X mch h, n chc X, thu c 0,312 mol CO2; 0,546 mol H2O v 0,078 mol N2. CTPT ca X l: A. CH5N. B .C2H5N. C. C2H7N. D. C3H7N. BT2: t chy hon ton amin X thu c 9,72g H2O v 15,84g CO2 v V lt N2 (ktc). Bit X thuc dy ng ng ca metyl amin.. Gi tr V v CTPT ca X l: A. 1,344 lt vCH5N. B . 1,344 ltC3H9N. C. 0,672 lt v C3H9N. D. 0,672 lt C3H9N BT3: t chy hon ton mt amin thm n chc X thu c 30,8g CO2 v 8,1g H2O. Bit M < 120 vC, th CTPT v s ng phn amin thm, n chc c th c ca X l:

A. C8H11N (7 ng phn). B. C8H11N (9 ng phn). C. C7H9N (4 ng phn). D. C8H11N (5 ng phn). BT4: t chy hon ton hn hp hai amin no, n chc, bc nht, l ng ng lin tip thu c 2,24 lit kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca hai amin l: A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2. C. C3H7NH2 v C4H9NH2 D.C4H9NH2 v C5H11NH2 BT5: t chy hon ton hn hp 2 amin no, n chc, ng ng lin tip thu c t l nCO2 : nH 2O =5:8. Thnh phn % s mol v CTPT ca 2 min trong hn hp ban u l: A. C2H7N (50%) v C3H9N (50%).B. CH5N (60%) v C2H7N (40%). C. CH5N (40%) v C2H7N (60%). D. C3H9N (50%) v C4H11N (50%). BT6: t chy hon ton 13,52g hn hp 2 min no, n chc, ng ng k tip X, Y. Sn phm chy cho li chm qua dd nc vi trong d, thu c 65g kt ta. CTPT X, Y (vi MX > MY) l: A. C4H11N v C3H9N. B. CH5N v C2H7N. C. C3H9N v C2H7N. D. C2H7N v C3H9N. BT7: t chy hon ton m gam amin n chc X thu c 9,9g H2O v 10,08 lt hn hp kh CO2 v N2 (ktc) c t khi so vi khng kh l 1,456. a. Gi tr ca m l: A. 6,57g. B. 7,3g. C. 8,03g. D. 10,95g. b. CTPT ca X l: A. C2H7N. B. C3H9N. C. C4H11N. D. C7H9N. DNG 2: Xc nh CTPT ca amin (da vo tnh baz)

BT1: Amin bc nht n chc X tc dng va vi lng HCl c trong 120ml dung dch HCl 0,1M thu c 0,81 gam mui X l: A. Metyl amin B. Etyl amin C. Propyl amin D. Benzyl amin BT2: trung ha 11,8 g mt amin n chc bc I cn dng 200ml dd HCl 1M. Amin ny c CT l: A . CH3NH2 B . C2H5NH2 C . C3H7NH2 D . C4H9NH2 BT3(H 2007): trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N. BT4: Cho 0,45g amin n chc tc dng va vi dung dch HCl . Sau phn ng , c cn dung dch ta thu c 0,815g mui khan . Amin trn l : A. metylamin B. etylamin C.dimetylamin D.B, C u ng. BT5: Cho 2,6 gam hn hp 2 amin no n chc l ng ng k tip nhau tc dng vi dd HCl long d. Sau phn ng c cn dd thu c 4,425 gam mui. CTPT ca 2 amin l: A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D. C4H9NH2 v C5H11NH2 BT6: Cho 17,7g mot ankylamin tac dung vi dung dch FeCl3 d thu c 10,7g ket tua. Vy, CTPT ca ankylamin la: A. C2H7N B. C3H9N C. C4H11N D. CH5N BT7: Cho 24,9 gam hn hp X gm 2 amin no n chc mch h ng ng k tip tc dng vi dung dch FeCl3 d thu c 21,4 gam kt ta. Cng thc v % khi lng ca 2 amin l : A. C2H7N( 27,11%) v C3H9N (72,89%) B. C2H7N( 36,14%) v C3H9N (63,86%) C. CH5N( 31,12%) v C2H7N (68,88%) D. Kt qu khc.

TON V P C TRNG CA AMINO AXIT

A. TM TT L THUYT:
1/ Khi nim: Amino axit l hp cht hu c tp chc (cha NH2 v COOH) * CTCT: R(NH2)x(COOH)y - Nu x =y Mi trng trung tnh. - Nu x < y Mi trng axit. - Nu x >y Mi trng baz. 2/ Tnh cht ha hc c trng ca amino axit: - Tnh lng tnh: trong , tnh axit l do nhm COOH v tnh baz l do c nhm NH2. VD: NH2 CH2 COOH + HCl NH2 CH2 COOH + NaOH Lu : ngoi amino axit, mui amoni ca axit hu c (RCOONH4) cng c tnh lng tnh. - P este ha: H+ VD: NH2 CH2 COOH + CH3OH
to

- Phn ng trng ngng ( hay ngng t): , xt , p VD: NH2 CH2 COOH t
o

B. BI TON VN DNG:
DNG 1: Xc nh CTPT ca amino axit da vo p chy y z to CxHyOzNt + ( x + )O2 x CO2 + y/2 H2O + t/2 N2 4 2 Lp t l x,y,z,t CTPT x : y : z : t = nC : nH : nO : nN (1) m m m m x:y:z:t= C : H : O : N (2) 12 1 16 14 %C % H %O % N : : : x:y:z:t= (3) 12 1 16 14 BT1: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. C3H7NO2 B. C4H9NO2. C. C2H5NO2 D. C5H11NO2 BT2: t chy ht a mol mt amino axit X n chc bng oxi va ri ngng t ht hi nc c 2,5a mol hh CO2 v N2. CTPT ca X: A. C5H11NO2 B. C3H7N2O4 C. C3H7NO2 D. C2H5NO2 BT3: t chy hon ton 5,15g mt cht X th cn va 5,88 lt oxi thu c 4,05g H 2O v 5,04 lt hn hp gm CO2 v N2. Bit X l mt aminoaxit c mt nhmNH2 trong phn t.Cng thc phn t ca X l (kh o ktc): A. C3H7O2N. B. C4H9O2N. C. C2H5O2N. D. C5H9O2N. BT4: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. DNG CTCT ca A l: 2: Xc nh CTPT ca amino axit da vo tnh cht lng tnh - CH(CH3)- COOCH3 A. NH2 - CH2 -COOCH3 B. NH2 :* R(NH2)x(COOH)y +3xHCl :2)-COOCHx(COOH)y. (1) R(NH3Cl) 3 C.CH - CH(NH D.NH2-CH(NH2) - COOCH3 n) BT5:. (H KA 2007 HCl t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 s nhm Khi trong phn t amino dch NaOH thu c sn phm c mui H NT o x = ( cc kh (1) ktc) v 3,15 gam H20.NH2X tc dng vi dung axit X. 2 nX CH2-COONa. CTCT thu gn ca + yNaOH : R(NH ) (COONa) + yH O (2) X l * R(NH2)x(COOH)y 2 x y 2 A.H2NCH2CH2COOH B. H2NCH2COOCH3 C.H2NCH2CCOOC3H7 D. H2NCH2COOC2H5 nNaOH s nhm COOH trong phn t amino axit X. T (1) y = nX * Tm cu to gc R ri suy ra CTPT amino axit X.

BT1: Cho 0,1 mol amino axit X tc dng va vi 0,1 mol HCl. Ton b sn phm thu c tc dng va vi 0,3 mol NaOH. X l amino axit c A. 1 nhm -NH2 v 1 nhm COOH B. 2 nhm NH2 v 1 nhm COOH C. 1 nhm NH2 v 3 nhm COOH D. 1 nhm NH2 v 2 nhm COOH BT2: Cho 0,01mol amino axit X phn ng va vi 0,02mol HCl hoc 0,01mol NaOH. Cng thc cu to ca X l: A. H2NRCOOH B. H2NR(COOH)2 C. (H2N)2RCOOH D. (H2N)2R(COOH)2 BT3: X l - aminoaxit no ch cha mt nhm -NH2 v mt nhm -COOH. Cho 23,4 gam X tc dng vi dd HCl d thu c 30,7g mui ca X. CTCT thu gn ca X c th l: A. CH3CH(NH2)COOH B. H2NCH2COOH. C. H2NCH2CH2COOH D. CH3CH(CH3)CH(NH2)COOH BT4: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l: A. H2NC4H8COOH. B. H2NC3H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. BT5 : X l este ca mt -aminoaxit vi ancol metylic. Ho hi 25,75g X th thu c th tch hi bng th tch ca 8g kh O2 cng iu kin. Cng thc cu to ca X l A. H2N-CH2-CH2-COO-CH3 B. CH3-CH(NH2)-COO-CH3 C. H2N-CH2-COO-CH3 D. CH3-CH2-CH(NH2)-COO-CH3 BT6: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C 3H7O2N p vi 100ml NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7gam cht rn. Cng thc cu to thu gn ca X l: A. H2NCH2COOCH3 B. HCOOH3NCH=CH2 C. H2NCH2CH2COOH D. CH2=CHCOONH4 BT7: Cho 0,02 mol cht X (X l mt -aminoaxit) phn ng va ht vi 160ml dd HCl 0,125M th to ra 3,67g mui. Mt khc, 4,41g X khi tc dng vi mt lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l : A. HOOC-CH(NH2)-CH(NH2)-COOH. B.HOOC-CH2-CH2-CH(NH2)-COOH. C. CH3-CH2-CH(NH2)-COOH. D. CH3-CH2-CH2-CH(NH2)-COOH BT8: un nng 100ml dung dch mt aminoaxit 0,2 M tc dng va vi 80ml dung dch NaOH 0,25M. Sau phn ng ngi ta c cn dung dch thu c 2,5 g mui khan. Mt khc, ly 100g dung dch aminoaxit trn c nng 20,6 % phn ng va vi 400ml dung dch HCl 0,5 M. Cng thc phn t ca aminoaxit l: A. H2NCH2COOH B.CH3CH(NH2)COOH. C. CH3CH2CH(NH2)COOH D. CH3COONH4. BT9 (H KA 2007) - aminoaxit X cha mt nhm NH2 . Cho 10,3 gam X tc dng vi axit ( HCl) ( d ), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A.H2NCH2COOH B. CH3CH2CH(NH2 )COOH C.H2NCH2CH2COOH D. CH3CH2 (NH2)COOH BT10: (H KA 2009). Cho 1 mol amino axit X phn ng hon ton vi dd HCl (d), thu c m1 gam mui Y. Cng mol amino axit X phn ng vi dd NaOH d, thu c m2 gam mui Z. Bit m2 m1 = 7,5. CTPT ca X l: A. C4H10O2N2 B. C4H8O4N2 C. C5H9O4N D. C5H11O2N

PHIU KIM TRA S 01

Cu 1: C hai amin bc mt: X (ng ng ca anilin) v Y (ng ng ca metylamin). t chy hon ton 3,21g amin X sinh ra kh CO2 v hi nc v 336 cm3 kh nit (ktc). Khi t chy hon ton amin Y cho nCO2: nH2O = 2:3 Cng thc phn t ca amin l: A.CH3C6H4NH2, CH3CH2CH2NH2 B.C2H5C6H4NH2 , CH3CH2CH2NH2 C.CH3C6H4NH2 , CH3(CH2)4 NH2 D. A v B ng. Cu 2: t chy hon ton mt amin thm X thu c 3,08g CO2v 0,9g H2Ov 336ml N2(o ktc). trung ho 0,1 mol X cn dng 600ml HCl 0,5M. Cng thc phn t ca X l cng thc no sau y: A.C7H11N B.C7H8NH2 C.C7H11N3 D.C8H9NH2 Cu 3: t chy hon ton 6,2g mt amin no n chc cn dng 10,08 lt kh oxi (ktc). Cng thc phn t ca amin l: A.C2H5NH2 B.C3H7NH2 C.CH3NH2 D.C4H9NH2. Cu 4: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6g CO2v 12,6g H2O v 69,44 lt nit. Gi thit khng kh ch gm nit v xi, trong oxi chim 20% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: A.C2H5NH2 B.C3H7NH2 C.CH3NH2 D.C4H9NH2. Cu 5: Cho 20 gam hn hp 3 amin no, n chc, ng ng k tip, tc dng vi dung dch va , sau c cn thu c 31,68 hn hp mui. Nu 3 amin trn trn theo th t khi lng mol tng dn vi s mol c t l 1: 10: 5 th amin c khi lng phn t nh nht c cng thc phn t l: ACH3NH2 B.C2H5NH2 C.C3H7NH2 D.C4H11NH2. Cu 6: Cng thc phn t ca amin cha 23,73% khi lng nit? A.C2H5NH2 B.C6H5NH2 C.(CH3)2NH D.(CH3)3N. Cu 7: Cho 9,85 gam hn hp 2 amin, n chc, bc 1 tc dng va vi dung dch HCl thu c 18,975 gam mui. Khi lng HCl phi dng l A.9,521 B.9,125 C.9,215 D.9,512. Cu 8: X l hp cht hu c mch h, cha cc nguyn t C, H, N, trong N chim 31,11%% v khi lng. X tc dng vi dung dch HCl theo t l 1:1. X c s ng phn l: A.2 B.3 C.4 D.5. -amino axit mch khng nhnh. Cho 0,015 mol X tc dng va vi dung dch HCl to ra Cu 9: X l mt 2,5125 gam mui. Cng lng X trn khi tc dng vi dung dch NaOH ly d thy to thnh 2,295 gam mui. Cng thc ca X l A. H2N(CH2)5COOH B. H2N(CH2)3CH(NH2)COOH. C. H2N(CH2)6COOH D. H2N(CH2)4CH(NH2)COOH. Cu 10: Trung ha 1 mol -amino axit X cn 1 mol HCl to ra mui Y c hm lng clo l 28,286% v khi lng. Cng thc cu to ca X l. A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH. C. H2N-CH2-CH2-COOH D. H2N-CH2-CH(NH2)-COOH. Cu 11: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l : A. axit glutamic B. valin C. glixin D. Alanin Cu 12: X l mt aminoaxit t nhin, 0,01 mol X tc dng va vi 0,01 mol HCl to mui Y. Lng Y sinh ra tc dng va vi 0,02 mol NaOH to 1,11 gam mui hu c Z. X l: A. axit aminoaxetic B. axit -aminopropionic C. axit aminopropionic D. axit aminoglutaric. Cu 13: Cho 0,01 mol mt aminoaxit A (mt amino axit thit yu, mch khng nhnh, c cha nhm amin cui mch) tc dng va vi 100 ml dung dch HCl 0,2M, thu c dung dch B. Dung dch ny tc dng va ht vi 100 ml dung dch NaOH 0,3M, thu c 2,85 gam mui. A l A. H2(CH2)3CH(NH2)COOH B. H2N(CH2)4CH(NH2)COOH C. (H2N)2CH(CH2)3COOH D. (H2N)2CH(CH2)4COOH

Cu 14: Hp cht X cha 2 loi nhm chc amino v cacboxyl. Cho 100ml dd X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dd th thu c 5,31g mui khan. Bit X c mch cacbon khng phn nhnh v c mt nhm amino v tr . Cng thc cu to ca X l: A. CH3-CH(NH2)-COOH. C. CH3-CH(NH2)-(COOH)2. B. HOOC-CH2-CH(NH2)-COOH. D. H2N-CH2-COOH. Cu 15: Cho 0,1 mol hp cht X tc dng va vi 80 ml dung dch HCl 1,25M, sau c cn dung dch thu c 18,75 gam mui. Mt khc, cho 0,1 mol X tc dng vi NaOH va ri c cn th c 17,3 gam mui. Bit X l mt - aminoaxit v c kh nng phn ng vi Br2/Fe cho hp cht C8H9O2NBr. Cng thc cu to ca X l. A. C6H5CH(NH2)COOH. B. H2NCH2C6H4COOH. C. H2NC6H4CH2COOH. D. H2NC6H4COOH. Cu 16: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 17: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D.H2N-CH2-CH2-OOC2H5. Cu 18: Cho 0,01 mol amino axit A tc dng va 80 ml dung dch HCl 0,125 M.C cn dung dch thu c 1,835 gam mui . Khi lng ca A l : A. 9,7. B. 1,47 C. 1,2 D. 1,5 Cu 19 (C KHI A -2007): Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O =16; Na = 23) A. CH2=CHCOONH4. B. H2NCOO-CH2CH3. C. H2NCH2COO-CH3. D. H2NC2H4COOH. Cu 20 (H KHI A -2007): Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO 2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. Cu 21 (H KHI A -2007): Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. Cu 21 (H KHI B -2008): Mui C6H5N2+Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5 oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,2 mol. B. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,3 mol. D. 0,1 mol v 0,1 mol Cu 22 (H KHI A -2009): Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6.

PHIU KIM TRA S 02

Cu 1: Cho m g anilin tc dng vi dd HCl c d, c cn dung dch sau p thu c 15,54 g mui khan. Hiu sut p t 80% . m c gi tr l : A.13,95g B.8,928g C.11,16g D.12,5g. Cu 2: Cho 20 g hh 3 amin: metyl amin , etyl amin, anlyl amin tc dng va vi V ml dd HCl 1M . Sau p c cn dd thu c 31,68 g mui khan. Gi tr ca V l: A.120ml B.160ml C.240ml D.320 ml Cu 3: Cho 11,8 g hn hp X gm 3 amin : n-propyl amin, etylmetylamin, trimetyl amin. Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l : A. 100ml B. 150 ml C. 200 ml D. Kt qu khc. Cu 4: t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 (l) CO2 (ktc) v 7,2 g H2O. Gi tr ca a l : A. 0 ,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol. Cu 5: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v 14,4 g H2O. CTPT ca hai amin l : A. CH3NH2 v C2H7N B. C3H9N v C4H11N C. C2H7N v C3H9N D. C4H11N v C5H13 N. Cu 6: Ba cht A, B, (CxHyNz) c thnh phn % theo khi lng N trong A, C ln lt l 45,16%; 15,05% ;A , B tc dng vi axit cho mui amoni R NH3Cl CT ca A, B ln lt l: A.CH3NH2 , C4H9NH2 B.CH3NH2, C6H5NH2 C.CH3NH2 , C6H5NH2 D.CH3NH2 , C2H5NH2 Cu 7: Dung dch X gm HCl v H2SO4 c pH = 2. trung ho hon ton 0,59gam hn hp hai amin no n chc, bc 1 ( c s nguyn t C nh hn hoc bng 4 th phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin l A. CH3NH2 v C4H9NH2. B. C3H7NH2 v C4H9NH2. C. C2H5NH2 v C4H9NH2. D. A v C. Cu 8: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc Cu 9: Cho 22,15 g mui gm CH2NH2COONa v CH2NH2CH2COONa tc dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch th lng cht rn thu c l : A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc Cu 10: Cho 13,35 g hn hp X gm CH2NH2CH2COOH v CH3CHNH2COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l A. 100 ml B. 150 ml C. 200 ml D. 250 ml Cu 11: Cho 20,15 g hn hp X gm (CH 2NH2COOH v CH3CHNH2COOH) tc dng vi 450 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 200 ml dung dch NaOH 3,5M. Phn trm khi lng ca mi cht trong X l: A. 55,83 % v 44,17 % B. 53,58 % v 46,42 % C. 58,53 % v 41,47 % D. 52,59 % v 47,41% Cu 12: cho 100 ml dd aminoaxit A 0,2M tc dng va vi 80 ml dd NaOH 0,25M. mt khc 100 ml dd A trn tc dng vag vi 80 ml dd HCl 0,5M. Bit d A/H2 = 52 . CTPT ca A l A. (H2N)2C2H3COOH B. H2NC2H3(COOH)2 C. (H2N)2C2H2(COOH)2 D. H2NC3H5(COOH)2 Cu 13: Cho X l mt aminoaxit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dd HCl 0,125M v thu c 1,835 gam mui khan. Cn cho 0,01 mol X tc dng vi dd NaOH th cn dng 25 gam dd NaOH 3,2%. CTCT ca X l A. H2NC3H6COOH B. H2NC2H4COOH C. H2NC3H5(COOH)2 D. (H2N)2C3H4(COOH)2

Cu 14: Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng ng. Bit mi cht u cha mt nhm - NH2 v mt nhm - COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2 aminoaxit l. : A. H2NCH2COOH, H2NCH(CH3)COOH. B. H2NCH(CH3)COOH, H2N(CH2)3COOH. C. H2NCH2COOH, H2NCH2CH2COOH. D. H2NCH(CH3)COOH, C2H5CH(NH2)COOH. Cu 15: Hp cht hu c X l este c to bi axit glutamic v mt ancol bc nht. phn ng va ht 37,8 gam X cn 400ml dung dch NaOH 1M. Cng thc cu to thu gn ca X A. C3H5(NH2)(COOH)(COOCH2-CH2-CH3 B. C3H5(NH2)(COOCH2-CH2-CH3)2 C. C2H3(NH2)(COOCH2CH3)2 D.C2H3(NH2)(COOH)(COOCH2-CH2-CH2-CH3) Cu 16: A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c l 19,346%. Cng thc ca A l : A. HOOCCH2CH2CH(NH2)COOH B. HOOCCH2CH2 CH2CH(NH2)COOH. C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH Cu 17 (H- KHI A 2010) Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,50. B. 0,65. C. 0,70. D. 0,55. Cu 18 (H- KHI A 2010) Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5. Cu 19(H KHI A -2011): Thnh phn % khi lng ca nit trong hp cht hu c C xHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 2. B. 3. C. 4. D. 1. Cu 20(H KHI B -2011): Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45.