ANKAN 11.

Tien hanh clo hoa 3-metylpentan t le 1:1 thu c bao nhieu dan xuat monoclo la ong phan cua nhau? A. 4 B. 5 C. 2 D. 3 13. Hidrocacbon X co CTPT C5H12 khi tac dung vi Clo tao c 3 dan xuat monoclo ong phan cua nhau. X la: A. iso-pentan B. n-pentan C. neo-pentan D. 2-metyl butan 14. Ankan X co cong thc phan t C5H12, khi tac dung vi clo tao c 4 dan xuat monoclo. Ten cua X la: A. pentan B. iso-pentan C. neo-pentan D.2,2- dimetylpropan 15. Brom hoa ankan ch tao mot dan xuat monobrom Y duy nhat. dY/ khng kh = 5,207. Ankan X co ten la: A. n- pentan B. iso-butan C. iso-pentan D. neo-pentan 16. Phan tch 3 g ankan cho 2,4g cacbon . CTPT cua A la g ? A. CH4 B.C2H6 C. C3H8 D. ket qua khac 17. Mot ankan tao c dan xuat monoclo, trong o ham lng clo bang 55,04%. Ankan co CTPT la: A. CH4 B. C2H6 C.C3H8 D. C4H10 18. Khi phan huy hoan toan hidrocacbon X trong ieu kien khong co khong kh, thu c san pham co the tch tang gap 3 lan the tch hidrocacbon X ( cung ieu kien ) . Cong thc phan t cua X la : A. C2H6 B. C4H10 C. C5H12 D. C6H14 19. ot chay hoan toan 0,15 mol hon hp 2 ankan thu c 9,45g H2O. Cho san pham chay qua bnh ng Ca(OH)2 d th khoi lng ket tua thu c la bao nhieu ? A.37,5g B. 52,5g C. 15g D.42,5g 1. Co bao nhieu ankan ong phan cau tao co cong thc phan t C5H12? A. 3 ong phan B. 4 ong phan C. 5 ong phan D. 6 ong phan 6. Phan tram khoi lng cacbon trong phan t ankan Y bang 83,33% . Cong thc phan t cua Y la A. C2H6 B. C3H8 C. C4H10 D. C5H12 Cau 2: Trong cac hp chat sau, chat nao khong phai la hp chat hu c? A.(NH4)2CO3 C6H5NH2 B.CH3COONa C. CH3Cl D.

Cau 3 : Cho cc cht: CaC2, CO2, HCHO, Al4C3, CH3COOH, C2H5OH, NaCN, C2H2O4, CaCO3.
1

S cht hu c A. 3 A. CO2, CaCO3 CO, CaC2.

B. 4 B. CH3Cl, C6H5Br

C. 5

D. 6 C. NaHCO3, NaCN D.

Cau 4: Cap hp chat nao sau ay la hp chat hu c?

Cau 24: Trong cc cng thc sau cng thc no l cng thc n gin: A. C2H5; C3H6; CH4O. C2H4O; C2H6O. C. C2H5; C3H6; CH4O; C2H4O; C2H6O; C3H8O3 C2H4O; C3H6 Cau 25: Trong cc cng thc cho di y, cng thc no l cng thc phn t? A. C5H10; C4H8O2. C. CH4O; C2H6O. C4H8O2; C5H10O. Cau 26: Mun bit cht hu c X l cht g phi da vo loi cng thc no sau y: A. Cng thc n gin B. Cng thc phn t thc tng qut. Cau 28: Cho cac chat: (1) CH4, (2) C2H2, (3) C5H12, (4) C4H10, (5) C3H6, (6) C7H12, (7) C6H14. Chat nao la ong ang cua nhau? A.1, 2, 3, 4, 5, 6, 7 5, 7 (1) CH3CH2CH2CH2CH2CH3 (3) CH3CH2CH(CH3)CH2CH3 A. 1, 2, 3 B. 1, 2 C. 1, 4 B. 1, 3, 4, 7 C. 2, 5, 7, 6, 7 D. 1, 3, C. Cng thc cu to D. Cng B. C2H6O; C4H8O2; C5H10. D. CH 4O; C5H10; C2H6O; D. CH 4O; B. CH 4O;

Cau 31: Nhng chat nao sau ay la ong phan cau tao cua nhau? (2) CH3CH2CH2CH(CH3)2 (4) CH3CH2CH2CH2CH3. D. 1, 2, 3, 4

Cau 32: Trong cac phan ng sau, phan ng nao khong phai la phan ng the? (1) C2H6 + Cl2 (3) C6H6 + Cl2
s a
o

C2H5Cl + HCl

(2) C6H6 + 3Cl2

2 4 0

s a

C6H6Cl6

, p , xt t

,t C6H5Cl + HCl (4) C2H5OH H SO dac C2H4 + H2O

A. 4

B. 2, 4

C. 2

D. 1, 2, 4

Cau 34: Day chat nao sau ay thuoc day ong ang co cong thc chung la CnH2n+2. A.CH4, C2H2, C3H8, C4H10, C6H12 C.C4H10, C5H12, C6H12. B. CH4, C3H8, C4H10, C5H12 D. C2H6, C3H6, C4H8, C5H12.

Cau 35: Trong cac cap chat sau,cap chat nao la ong ang cua nhau? A.C2H6, CH4, C4H10 C.CH3OCH3, CH3CHO Cau 36: ng vi cng thc phn t C4H8 c tt c: A. 3 ng phn. B. 4 ng phn. C. 6 ng phn. D. 5 ng phn. Cau 37: Hirocacbon X c cng thc phn t l C4H10. Vy X l: A- Hirocacbon no, khng vng 3 ng phn. B- Hirocacbon no, khng vng 2 ng phn. C- Hirocacbon khng no, 2 ng phn. D- Hirocacbon no, c vng 2 ng phn 5. Phn ng c trng ca hidrocacbon no A. Phn ng tch B. Phn ng th C. Phn ng cng D. C A, B v C. CH3 CH3-CH - CH2 - C- CH2-CH3 CH2CH3 A. 2,4 ietyl-4-metylhexan dimetylheptan C. 5-etyl-3,5-imetylheptan pentan CH2 CH3 B. 3- etyl-3,5D. 2,2,3- trietylB. C2H5OH, CH3CH2CH2OH D. Cap A va cap B.

6. Cho Ten goi hp chat X co cong thc cau tao :

11. Khi cho butan tac dung vi brom thu c san pham monobrom nao sau ay la san pham chnh? A. CH3CH2CH2CH2Br C.CH3CH2CH2CHBr2 B. CH3CH2CHBrCH3 D. CH3CH2CBr2CH3.

14. Ankan Y td vi Brom tao ra 2 dan xuat monobrom co ty khoi hi so vi H2 bang 61,5. Ten cua Y la: A. butan B. propan C. isobutan D. 2-metylbutan 16. Ankan Z co cong thc phan t la C5H12. Tien hanh p/ dehidro hoa Z thu c mot hon hp gom 3 anken la ong phan cua nhau trong o co hai chat la ong phan hnh hoc. Cong thc cau tao cua Z la?

A. CH3CH2CH2CH2CH3 CH3CH2CH(CH3 )2 C. C(CH 3)4 cau tao nao phu hp

B. D. Khong co

20. Khi nhiet phan mot ankan X trong ieu kien khong co khong kh thu c kh H2 va muoi than, thay the tch kh thu c gap 5 lan the tch ankan X( o cung ieu kien ve nhiet o ap suat ). CTPT cua X la : A. CH4 B. C2H6 C. C3H8 D. C4H10 21. ot chay ht 2,24 lt ankan X (ktc), dan ton b san pham chay vao dd nc voi trong d thay co 40g. CTPT X A. C2H6 B. C4H10 C. C3H6 D. C3H8 22. ot chay hoan toan 0,15 mol hon hp 2 ankan thu c 9,45g H2O. Cho san pham chay qua bnh ng Ca(OH)2 d th khoi lng ket tua thu c la bao nhieu ? A.37,5g B. 52,5g C. 15g D.42,5g Cu 2: Sn phm chnh ca phn ng brom ho 2- metylbutan theo t l s mol 1:1 l: A. 1- clo- 2- metylbutan B. 2- clo- 3- metylbutan C. 1- clo- 3- metylbutan D. 2- clo- 2- metylbutan Cu 3: Dy no sau y gm cc cht l ng ng ca metan A. C2H4, C3H7Cl, C2H6O B. C4H10, C5H12, C6H14 C. C4H10, C5H12, C5H12O D. C2H2, C3H 4, C4H 6 Cu 5: Khi nhit phn CH3COONa vi vi ti xt thi thu c sn phm kh: A. N2, CH4 B. CH4, H2 C. CH4, CO2 D. CH4 Cu 10: CTPT ng vi tn gi 4-etyl-2,3,3-trimetylheptan l: A.C12H26 B. C10H22 C. C11H24 D. C12H24 Cu 8. Khi cho 2-metylpentan tc dng vi brom thu c sn phm chnh l dn xut monobrom no sau y? A.2-brom-2-metylpentan. B. 3-brom-metylpentan. C.1-brom-2-metylpentan D. 4-brom-2-metylpentan Cu 2. C bao nhiu ng phn hnh hc, mch h c cng thc phn t C3H5Br? A. 2 B.4 C.5 D.6 Cu 3 .Cht hu c c cng thc cu to sau c tn gi l g? CH3 - CH(CH3)-CHBr-CH2-CCl(CH3)-CH3 A. 2-clo-4-brom-2,5-imetylhexan B. 4-brom-2-clo-2,5-imetylhexan C. 3-brom-2-clo-2,5-imetylhexan D. 4 brom-2-clo-2,5-trimetylhexan Cu 3. Tn gi: 2 clo 3 metylbutan ng vi cng thc cu to no sau y?

CH3

CH CH2 CH3 Cl
CH3 CH CH CH3 Cl

A.

CH3 CH2 CH CH2 Cl CH3 B.

CH3 CH3 H2C C CH2 CH3 Cl
4

CH3
C.

D.

Cu 62: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th Tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l: A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 12: Cho 4 cht: metan, etan, propan v n-butan. S lng cht to c mt sn phm th monoclo duy nht l: A. 1. B. 2. C. 3. D. 4. Cu 14: Khi t chy hon ton 7,84 lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 16,8 lt kh CO2 (ktc) v x gam H2O. Gi tr ca x l A. 6,3. B. 13,5. C. 18,0. D. 19,8. Cu 15: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c 7,84 lt kh CO2 (ktc) v 9,0 gam H2O. Cng thc phn t ca 2 ankan l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Cu 16: khi clo ha mt ankan c cng thc phn t C6H14, ngi ta ch thu c 2 sn phm th monoclo. Danh php IUPAC ca ankan l A. 2,2-imetylbutan. B. 2-metylpentan. C. n-hexan.D. 2,3imetylbutan. Cu 17: Khi clo ha hn hp 2 ankan, ngi ta ch thu c 3 sn phm th monoclo. Tn gi ca 2 ankan l A. etan v propan. B. propan v isobutan. C. iso-butan v n-pentan.D. neo-pentan v etan. Cu 18: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng ng k tip thu c 96,8 gam CO2 v 57,6 gam H2O. Cng thc phn t ca A v B l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Cu 19: Hn hp kh X gm 2 hirocacbon A v B l ng ng k tip. t chy X vi 64 gam O2 (d) ri dn sn phm thu c qua bnh ng Ca(OH)2 d thu c 100 gam kt ta. Kh ra khi bnh c th tch 11,2 lt 0OC v 0,4 atm. Cng thc phn t ca A v B l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Dng cho cu 20, 21: Nung m gam hn hp X gm 3 mui kali ca 3 axit no n chc vi NaOH d thu c cht rn D v hn hp Y gm 3 ankan. T khi ca Y so vi H2 l 11,5. Cho D tc dng vi H2SO4 d thu c 17,92 lt CO2 (ktc). Cu 20: Gi tr ca m lA. 42,0.B. 84,8. C. 42,4. D. 84,0. Cu 21: Tn gi ca 1 trong 3 ankan thu c lA. metan. B. etan. C. propan. D. butan. Cu 27: t chy hon ton V lt hn hp A (ktc) gm CH4, C2H6 v C3H8 thu c 6,72 lt kh CO2 (ktc) v 7,2 gam H2O. Gi tr ca V lA. 5,60. B. 3,36. C. 4,48. D. 2,24. Cu 30 (A-2007): Khi brom ho mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi so vi hiro l 75,5. Tn ca ankan l A. 3,3-imetylhexan. B. isopentan. C. 2,2,3-trimetylpentan. D. 2,2imetylpropan. Cu 4: t chy ht 0,224 lt (ktc) mt hirocacbon no mch h, sn phm sau khi t chy cho qua 1 lt nc vi 0,143% (D = 1 g/l) thu c 0,1g kt ta.Cng thc phn t hirocacbon l: A. C4H10 B. C3H8 C. C5H12 D. C2H6 E. Kt qu khc.

ANKE
5

*170/ Hn hp X gm propen l ng ng theo t l th tch 1:1.t 1 th tch hn hp X cn 3,75 th tch oxi(cng k). Vy B l: a.eten b.propan c.buten d.penten 171/ t hon ton 0,2 mol hn hp CH4;C4H10;C2H4 thu c 0,28 mol CO2 v 8,28 ml H2O. S mol ankan v anken trong hn hp ln lt l: a.0,02 v 0,18 b.0,16 v 0,04 c.0,18 v 0,02 d.0,04 v 0,16 172/ Cho hn hp X gm 2 olefin qua bnh ng dd brom,khi phn ng xong c 16 g brom tham gia phn ng .Tng s mol ca 2 anken l: a.0,01 b.0,5 c.0,05 d.0,1 173/ Mt hn hp kh A gm 1 ankan,1 anken c cng s cacbon v ng mol .Cho a g h hp A phn ng va vi 120 g dd Br 2 20% trong CCl4 .t a g hn hp trn thu c 20,16 lt CO 2 (ktc).Cng thc phn t ca ankan , anken ln lt l :a.C3H8 v C3H6 b.C3H8 v C3H6 c. C2H6 v C2H4 d. C4H10 v C4H8 174/ m gam hn hp gm C3H6 ; C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO2 (ktc).Nu Hiro ho hon ton m g hn hp trn ,ri t chy ht hn hp thu c V(ml) CO 2 (ktc).Gi tr ca V? a. 22,4 b.22400 c.44,80 d.33600 175/ t chy hon ton m g etanol thu 3,36 lt CO2 (ktc).Nu un m g etanol vi H2SO4 c ;180o C ri t chy ht sn phm thu c a g H2O.Gi tr ca a l: a.2,7 g b.7,2 g c.1,8 g d.5,4 g Cu 266. Hin nay PVC c iu ch theo s sau: C2H4 CH2Cl CH2Cl C2H3Cl PVC. Nu hiu sut t 80% th lng C2H4 cn dng sn xut 5000kg PVC l: a.28kg b.1792kg c.2800kg d.179,2kg 5. Anken CH3CH=CHCH2CH3 co ten la A. metylbut-2-en B. pent-3-en C. pent-2-en D. but-2en 3. Co bao nhieu ong phan cong thc cau tao cua nhau co cung cong thc phan t C4H8? ( khong ke p hnh hoc)A. 6 5 B. 3 C. 4 D.

4. ng vi cong thc phan t C4H8 co bao nhieu ong phan cau tao eu tac dung c vi hidro? A. 2 B. 3 C. 5 D. 6 5. ng vi cong thc phan t C4H8 co bao nhieu ong phan cua olefin? A. 4 B. 3 C. 5 D. 6 6. Co bao nhieu chat ong phan cau tao co cung cong thc phan t C4H8 tac dung vi Brom ( dung dch)? A. 5 chat B. 6 chat C. 4 chat D. 3 chat 8. Trong Phong th nghiem co the ieu che mot lng nho kh etilen theo cach nao sau ay? A. e hidro hoa etan H2SO4, 170OC. B. un soi hon hp gom etanol vi axit
6

C. Crackinh butan. xuc tac la Pd/PbCO3.

D. Cho axetilen tac dung vi hidro co

9. e tach rieng metan khoi hon hp vi etilen va kh SO 2 co the dan hon hp vao: A. dd Natrihidroxit D. dd HCl B. dd axit H2SO4 C. dd nc brom
CH2 C CH2 CH2 CH2Cl

10. Cho bit tn ca hp cht sau theo IUPAC : A. 1-Clo-4-Etylpent-4-en C. 2-etyl-5-Clopent-1-en

CH2

CH3

B. 1-clo-4-metylenhexan D. 5- Clo-2-etylpent-1-en

11. Trong so cac anken C5H10 ong phan cau tao cua nhau, bao nhieu chat co cau tao hnh hoc ? A. 1 B. 2 C. 3 D. 4 13. Co bao nhieu anken ong phan cau tao cua nhau khi cong hidro eu tao thanh 2- metylbutan? A. 1 B. 2 C. 3 D. 4 B. CH2 = D. CH2 = 15. Cho bit sn phm chnh ca phn ng sau: CH2 = CHCH2CH3 + HCl ?. A. CH3 CHClCH2CH3. CHCH2CH2Cl. C. CH2 ClCH2CH2CH3. CHCHClCH3.

16. Hidrocacbon A va B thuoc cung mot day ong ang. Biet M A = 2MB. A va B thuoc day ong ang nao? A. Anken hoac xicloankan B. Aren C. Co the thuoc bat ky day nao. D. Anken 17. Cho 2,24 lt anken X (ktc) tac dung vi dd brom thu c san pham co khoi lng ln hn khoi lng anken la A. 0,8 g B. 10,0g C. 12,0 g D. 16,0g 18. Anken X tac dung vi nc (xuc tac axit) to ra hon hp 2 ancol ong phan cua nhau. d/N2 = 2,00. Ten ca X la A. iso-penten B. but-1en C. but-2-en D. pent-1en 19. Anken Y tac dung vi dd brom tao thanh dan suat ibrom trong o % khoi lng C bang 17,82 %. CTPT Y la A. C3H6 B.C4H8 C. C4H10 D. C5H10 20. ot chay hoan toan 1,12 lt mot anken X (ktc) thu c 5,60 lt kh CO2 (ktc). CTPT X la: A. C3H6 B.C4H8 C. C4H10 D. C5H10 21. ot chay hoan toan mot the tch hon hp gom anken X va hidrocacbon Y thu c 5,56 lt kh CO2 ( ktc) va 5,40 g nc. Y thuoc loai hirocacbon co cong thc phan t dang.
7

A.CnH2n Cu 11: Hp cht :

B.CnH2n-2
CH2 CH CH CH3 CH3

C. CnH2n+2 c tn gi l:

D. CnH2n-4

A. 3-metylbut-1-en B. 2-metylbut-1-en C. 2-metylbut-3-en D. 3metylpent-1-en Cu 12. t chy hon ton (m) gam hh X gm metan , propen v butan thu c 4,4 gam CO2 v 2,52 gam H2O . Gi tr ca m l : A . 1,48 g B . 2,48 g C . 14,8 gam D . 24,7 gam 67. Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ? A. 3-Metylbut-1-en B. 2-Metylbut-1en C. 3-Metylbut-2-en D. 2-Metylbut-2en 73. Anken thch hp iu ch ancol sau y (CH3CH2)3C-OH l: A. 3-etylpent-2-en B. 3-etylpent-3-en C. 3-etylpent-1-en D. 3,3- imetylpent-1-en Cu 21:. Nhng hp cht no sau y c th c ng phn hnh hc (cis-trans) CH3CH = CH2 (I) ; CH3CH = CHCl (II) ; CH3CH = C(CH3)2 (III)
H3C C2H5 C C CH3 C2H5

H3C C2H5 C C

Cl H

(V) A. (I), (IV), (V) B. (II), (IV), (V) C. (III), (IV) D. (II), III, (IV), (V) Cu 23. Oxi ho etilen bng dd KMnO4 thu c sn phm l : A. MnO2, C2H4(OH)2, KOH B. K2CO3, H2O, MnO2 C. C2H5OH, MnO2, KOH D. MnO2, C2H4(OH)2, K2CO3 Cu 6: Hn hp X gm 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc t chy hon ton hn hp X dng khng ht 24,64 lt O2 (kc).Cng thc phn t ca 2 anken l : A. C2H4 v C3H6 B. C2H4 v C4H8 C. C3H6 v C4H8 D. A v B u ng Cu 18: Hp cht 2- metylbut - 2- en l sn phm chnh ca phn ng tch t cht no trong cc cht sau : A. 2-brom-2-metylbutan B. 2-metylbutan -2- ol C. 3-metylbutan-2- ol D. Tt c u ng Cu 7: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). 16. (KB 2008) Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc). A. CH4 v C2H4 B. CH4 v C3H4 C. CH4 v C3H6 D. C2H6 v C3H6 Thi du 3:t chay hoan toan hn hp gm 1 ankan va 1 anken. Cho san phm chay ln lt i qua binh 1 ng P2O5 d va binh 2 ng KOH rn, d thy binh 1 tng 4,14g, binh 2 tng 6,16g. S mol ankan co trong hn hp la: A. 0,06 B. 0,09 C. 0,03 D. 0,045 Thi du 5: t chay hoan toan 0,1 mol hn hp gm CH4, C4H10 va C2H4 thu c 0,14 mol CO2 va 0,23 mol H2O. S mol ankan va anken co trong hn hp ln lt la:
8

(IV)

A. 0,09 va 0,01

B. 0,01 va 0,09

C. 0,08 va 0,02

D. 0,02 va 0,08

Thi du : Mt hm hp khi gm 1 ankan va 1 anken co cung s nguyn t C trong phn t va co cung s mol. Ly m gam hn hp nay thi lam mt mau va u 80g dung dich 20% Br2 trong dung mi CCl4. t chay hoan toan m gam hn hp o thu c 0,6 mol CO2. Ankan va anken o co cng thc phn t la: A. C2H6, C2H4 C5H10 B. C3H8, C3H6 C. C4H10, C4H8 D. C5H12,

Vi du 3: Cho 14g hn hp 2 anken la ng ng lin tip i qua dung dich nc Br2 thy lam mt mau va u dd cha 64g Br2.Cng thc phn t cua cac anken la: A. C2H4, C3H6 B. C3H8, C4H10 C. C4H10, C5H12 B. 2:1 C. 2:3 D. C5H10, C6H12 D. 1:1 Ty l s mol 2 anken trong hn hp la: A. 1:2

Thi du 4: Cho 10,2g hn hp khi A gm CH4 va anken ng ng lin tip i qua dd nc brom d, thy khi lng binh tng 7g, ng thi th tich hn hp giam i mt na. Cng thc phn t cac anken la: A. C2H4, C3H6 B. C3H6, C4H10 C. C4H8, C5H10 D. C5H10, C6H12 2. Phn trm th tich cac anken la A. 15%, 35% B. 20%, 30% C. 25%, 25% D. 40%. 10% Bi 3. t chy hon ton 0,1 mol anken X thu c CO2 v hi nc. Hp th hon ton sn phm bng 100 gam dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH ch cn 5%. La chn cng thc phn t ng ca X.A. C2H4 B. C3H6 C. C4H8 D. C5H10. Bi 4. em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu c CO2 v nc c khi lng hn km nhau 6,76 gam. Vy 2 cng thc phn t ca 2 anken l: A. C2H4 v C3H6 B. C3H6 v C4H8 C. C4H8 v C5H10 D. C5H10 v C6H12. Bi 5. (KB-08)- Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin. Bi 6. (C-07)- Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k) A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH. C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH. 9. Mt hn hp gm 1 ankan v 1 anken. Dn hn hp qua 100 gam dung dch brom 16% thy dung dch brom mt mu v khi lng bnh tng 2,8 gam, sau phn ng thy thot ra 3,36 lit mt kh (ktc). t chy hon ton hn hp kh bay ra thu c 8,8 gam CO2 v 5,4 gam nc. Vy cng thc ca anken v ankan ln lt l: A. CH4 v C2H4 B. C2H6 v C2H4 C. C2H6 v C3H6 D. CH4 v C3H6 C-08)-Cu 28: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut).
9

T khi ca X so vi kh hiro l: A. 12,9. B. 25,8. C. 22,2. D. 11,1. Cu 1:Anken l hiro cacbon c : a.cng thc chung CnH2n b.mt lin kt pi. c.mt lin kt i,mch h. d.mt lin kt ba,mch h Cu 2: Nhm vinyl c cng thc l: a.CH2= CH b.CH2= CH2 c.CH2= CHd.CH2= CH-CH2Cu 3: Nhm anlyl c cng thc l: a.CH2= CHCH2 b.CH3CH2= CH2 c.CH2= CH-CH2. d.CH2= CH-CH2Cu 4 : S ng phn cu to ng vi cng thc C5H10 l : a.05 b.06 c.09 d.10. Cu 5: Xiclobutan v cc buten l cc ng phn: a.mch cacbon b.v tr lin kt i. c.cis-trans. d.nhm chc. Cu 6: but-1-en v cc but-2-en l cc ng phn: a.mch cacbon b.v tr lin kt i. c.cis-trans. d.nhm chc. Cu7 : Cc anken cn c gi l: a.olefin b.parafin c.vadlin d.iolefin. Cu8: phn bit propen vi propan ,ta dng : a.dung dch brom c.dung dch brom trong CCl4 b.dung dch thuc tm d.c a,b,c. Cu9: Cht tc dng vi HCl (hoc HBr,HI,H2SO4) to ra 2 sn phm l: a.etilen b.but-2-en c.isobutilen d.propen. Cu10 : Hn hp kh propen v buten tc dng vi HCl to ra 4 sn phm ,cng thc cu to ca buten l: a.CH2= CH-CH2-CH3 b.CH3-CH=CH-CH3 c.CH=CH- CH3 d.CH2 = C- CH3 | CH3 CH3 Cu37: but-1-en tc dng vi HBr to ra sn phm chnh l: a.1-clobuten b.1-clobuten c.1-clobutan d.2-clobutan Cu38: Theo qui tc Mac-cop-nhi-cop ,trong phn ng cng axit hoc nc vo ni i ca anken th phn mang in dng cng vo : a.cacbon bc cao hn c.cacbon mang ni i ,bc thp hn b.cacbon bc thp hn d.cacbon mang ni i ,c t H hn Cu39: Sn phm trng hp etilen l : a.poli(etilen) b.polietilen c.poliepilen d.polipropilen Cu40: Sn phm trng hp propen l : a.-[CH2-CH(CH3)]nc.-(CH2-CH(CH3))nb.-n(CH2-CH(CH3))d..-n[CH2-CH(CH3)]Cu41: Khi t chy anken ta thu c : a.s mol CO2 s mol nc. c.s mol CO2> s mol nc b.s mol CO2 <s mol nc d.s mol CO2 = s mol nc Cu42: Khi t chy hirocacbon A ta thu c s mol CO2 = s mol nc,A l : a.anken hoc xicloankan c.monoxicloankan b.xicloankan hoc ankan d.anken hoc monoxicloankan Cu43: Sn phm phn ng oxiho etilen bng dung dch thuc tm l : a.HOCH2-CH2OH. b.KOOCH2-COOK. c.HOCH2-CHO. d.HOOCH2-COOH. Cu44: Sn phm phn ng oxiho propilen bng dung dch thuc tm l : a.propan-1,1-iol b.propan-1,2-iol c.propan-1,3-iol d.propan-1,3-ial
10

Cu 45: Trong phn ng oxiho anken CnH2nbng dung dch thuc tm c tng h s cc cht lc cn bng l : a.15 b.16 c.17 d.18 Cu46:Trong phn ng oxiho anken CnH2nbng dung dch thuc tm , h s KMnO4 lc cn bng l : a.2 b.3 c.4 d.5 Cu47: HOCH2-CH2OH c tn gi l: a.etanol b.glixerol c.eteniol d.etilenglicol. Cu48:Trong phn ng oxiho anken CH2=CH CH2OH bng dung dch thuc tm , h s KMnO4 lc cn bng l : a.2 b.3 c.4 d.5 Cu49: phn bit dung dch propen,propan ta c th dng dung dch : a.Brom/nc b.Brom/CCl4 c.thuc tm d.a,b,c u ng. Cu50:Trong phng th nghim ,etilen c iu ch bng cch : a.tch hiro t ankan c.tch nc t ancol b.crckinh ankan d.a,b,c u ng. Cu51:Trong cng nghip ,etilen c iu ch bng cch ; a.tch hiro t ankan c.tch nc t ancol b.crckinh ankan d.a,b u ng. Cu52: T etilen c th iu ch c cht no ? a.etilenglicol b.etilenoxit c.anehit axetic d.c a,b,c

11

Cu53:3 anken k tip A,B,C ,c tng khi lng phn t bng 126vc.A,B,C ln lt l: a.C4H8 ,C3H6 ,C2H4 b.C2H4,C3H6 ,C4H8 . c.C2H4,C3H8 ,C4H8 . d.C2H4,C3H6 ,C4H6, Cu54:C4H7Cl mch h ,c s ng phn l: a.8 b.9 c.10 d.11 Cu55:C4H7Cl mch h ,c s ng phn cu to l: a.8 b.9 c.10 d.11 Cu56:Hn hp gm propen v B(C4H8) tc dng vi nc c axit lm xc tc,un nng to ra hn hp c cha ancol bc 3.B l : a.but-1-en b.but-2-en c.-butilen. d.i-butilen Cu57:Hn hp gm propen v B(C4H8) tc dng vi HBr,un nng to ra hn hp c 3 sn phm .Vy B l : a.but-1-en b.but-2-en c.-butilen. d.i-butilen Cu58: lm sch metan c ln etilen ta cho hn hp qua : a.kh hiroc Ni ,t0. c.dung dchAgNO3/NH3. b.dung dch Brom. d.kh hiroclo rua. Cu59: lm sch etilen c ln metan ta cho hn hp tc dng ln lt vi: a.Zn ,Brom b.Ag[NH3]OH,HCl c.HCl ,Ag[NH3]OH d.Brom , Zn . Cu60: Kh nc t but-2-ol ta thu c sn phm chnh l: a.but-1-en b.but-2-en c.iso-butilen d.-butilen. Cu61:Cng nc vo iso-butilen ta c sn phm gm: a.1 ancol bc 3 duy nht. c.1anccol bc1,1anccol bc3 b.1anccol bc1,1anccol bc2 d.1anccol bc2,1anccol bc3 Cu62: hiro ha i-pentan ta c bao nhiu anken c cu to khc nhau? a.1 b.2 c.3 d.4 Cu63: Dn 2mol mt olefin A qua dung dch brom d ,khi lng bnh sau phn ng tng 5,6 gam.Vy cng thc phn t ca A l: Cu64: 5,6gam mt olefin A phn ng va vi 16gam brom. A tc dng vi HBr to ra 1 sn Cu65:Mt olefin X tc dng vi HBr cho hp cht Y .X tc dng vi HCl cho cht Z . Bit %C trong Z > %C trong Y l 16,85%.X l: a.C3H6 b.C5H10 c.C4H8 d.C6H12 Cu 66:t chy hon ton 1lt kh hirocacbon X cn 4,5lt oxi,sinh ra 3 lt CO2(cng iu kin)Xc th lm mt mu dung dch KMnO4 .Vy X l: a.propan. b.propen. c.propin. d.propa-ien. Cu67:Mt hn hp ankenA v H2 c d= 0,689 cho qua niken ,un nng A b hiro ha hon ton th t khi hn hp mi l 1,034.Cng thc phn t A l: a.C3H6 b.C5H10 c.C4H8 d.C6H12 Cu68:Phn tch 0,5gam cht hu c Acha C,F ta c 0,78gam Floruacanxi. 1.Cng thc nguyn ca hp cht A l: a.(CF2)n b.(C2F)n c.(CF3)n d.(C2F3)n 2.Bit phn t lng ca A :90<MA<110.Cng thc phn t ca A l: a.C2F3 b.C2F4 c.C2F6 d.C2F2 3.Tn gi ca A l: a.teflon c.cacbon tetra flo d.cacbon b. florua cacbon tetraforua
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a. (-CF2-CF -]n Cu69:Sn 2phm trng hp ca C2F4 l: n b.[-CF2-CF2-) c.(-CF2-CF2-)n d.[-CF2-CF2-]n Cu 70:Trong 1 bnh kn ,t 1hn hp gm 1th tch anken,1lng oxi c th tch gp 2ln th tch oxi cn dng.Sau khi cho hi nc ngng t,a v k ban u,th tch gim 25% so vi hn hp u.Cu to olefin l: a..CH2 = CH-CH2CH3 c.CH2 = CH-CH3 b.CH3CH2 = CH-CH2CH3 d.c a v b u ng Cu71:Trn 30ml hn hp gm anken X v CO2 vi 40Cm3 oxi (d) ,t chy hon ton hn hp thu c 70Cm3 hn hp kh v hi.Nu dn hn hp qua CaCl2 cn li 50Cm3 ,cho qua dung dch Ca(OH)2 d cn li 10 Cm3.Cng thc phn t ca X l : a.C4H2 b.C3H6 c.C4H8 d.C2H4 Cu72:Ly 0,2 mol mt anken X cho vo 50gam brom,sau phn ng khi lng hn hp thu c bng 64gam.1.Anken X l: a.C2H4 b.C3H6 c.C4H8 d.C5H10. Cu73:Anken X l cht hu c duy nht sinh ra khi kh nc ca ancol Y.Vy ancol Y l: a.pen-1-ol. b.pen-2-ol. c.pen-2 on. d.pen-1-on. Cu74:A v B l 2anken th kh c trn theo t l th tch 1:1 th 8,4g hh cng va 32g brom..Nu A v B c trn theo t l 1:1 v khi lng th 5,6g hh cng va 0,3g hiro.Cng thc phn t ca A,B ln lt l: a..C2H4,.C4H8 b.C2H4,.C3H6 c.C3H6,.C4H8 d.C4H8 ,C5H10. Cu75:Cht no c ng phn cis-trans? a.2-brom-3-Clo but-2-en. c.but-1-en b.1,3-ibromprop-1-en. d.pen-1-en Cu76:3 hiro cacbon A,B,C , l ng ng k tip nhau trong dy ng ng.Phn t lng ca C gp i phn t lng ca A.Vy A,B,C thuc dy ng ng : a.ankan b.anken c.ankin d.xicloankan Cu77: 3 hiro cacbon X,Y,Z , l ng ng k tip nhau trong dy ng ng.Phn t lng ca X bng mt na phn t lng ca Z.Vy X,Y,Z c cng thc phn t ln lt l : a.C2H4,C3H6 , C4H8 b.CH4,C2H6,C3H8 c.C2H2 ,C3H4 ,C4H6 d.C3H6,C4H8 ,C5H10 Cu78:Khi t chy 1 th tch hirocacbon X mch h cn 6 th tch oxi , to ra 4 th tch kh CO2 ,X cng HCl to ra 1 sn phm duy nht.Vy X l: a.propen b.but-1-en c.but-2-en d.i-butylen Cu79:Khi t chy 1 th tch hirocacbon X mch h cn 6 th tch oxi , to ra 4 th tch kh CO2 ,X cng HCl to ra 2 sn phm .Vy X l: a.but-1-en b.i-butylen c.propen d.a,b u ng Cu80:Thc hin phn ng Crackinh hon ton 6,6gam propan thu c hn hp A gm 2 hirocacbon.Cho A qua bnh cha 125ml dung dch brom c nng x mol /lt ,dung dch brom b mt mu.Kh thot ra khi bnh brom c t khi i vi metan bng 1,1875.Gi tr ca x l: a.0,08M b.0,8M c.0,8% d.0,18M Cu81:Hn hp X gm 1 ankan A v 1 anken B (u th kh).S nguyn t Cacbon trong B nhiu hn trong A. TN1: t 0,1mol hn hp gm amol A v bmol B thu c khi lng CO2 ln hn khi lng ca nc l 7,6gam. TN2: t 0,1mol hn hp gm bmol A v amol B thu c khi lng CO2 ln hn khi lng ca nc l 6,2gam.Cng thc phn t ca A,B ln lt l: a.C2H4,C4H8 b.C2H4,C3H6 c.C2H4 ,C5H10 d.C3H6,C4H8 . 0 Cu82:Mt hn hp X gm 2 olefin ng ng k tip c th tch 1,792lt (0 C,2,5atm) sc qua dd KMnO4(d),khi lng bnh tng 70gam.Cng thc phn t ca 2olefin l:
13

a.C5H10,C6H12 b.C2H4,C3H6 c.C4H8,C5H10 d.C3H6,C4H8 . Cu83:Trn 400 ml hn hp gm hirocacbon X v N2 vi 900Cm3 oxi (d) ,t chy hon ton hn hp thu c 1300Cm3 hn hp kh v hi.Nu dn hn hp qua CaCl2 cn li 900Cm3 ,cho qua dung dch Ca(OH)2 d cn li 500 Cm3.Cng thc phn t ca X l : a.C2H2 b.C3H6 c.C2H6 d.C2H4 Cu84: t chy hon ton agam hn hp eten,propen,but-1-en thu c 1,2mol CO2 v 1,2mol nc.Gi tr ca a l: a.18,8g b.18,6g c.16,8g d.16,4g Cu85:t chy hon ton agam hn hp eten,propen,but-2-en cn dng va b lt oxi ktc thu c 2,4mol CO2 v 2,4 mol nc.Gi tr ca b l: a.92,4l b.94,2l c.29,4l d.24,9l Cu86:t chy hon ton 2,24l etilen ktc ,ri hp th ton b sn phm vo dd cha 11,1g Ca(OH)2 ,sau khi kt thc phn ng ,khi lng dung dch tng hay gim bao nhiu gam? a.tng 2,4gam b.tng 4,2gam c.gim 2,4gam d.gim 4,2gam Cu87:t chy hon ton 2,24l etilen ktc ,ri hp th ton b sn phm vo dd cha 11,1g Ca(OH)2 ,sau khi kt thc phn ng ,khi lng bnh tng hay gim bao nhiu gam? a.tng 2,8gam b.tng 4,2gam c.gim 2,4gam d.gim 4,2gam Cu88:Mot hirocacbon A co t khoi hi oi vi hiro bang 14 .Cong thc phan t cua A la: a.C2H4 b. CH4 c. C4H4 d. C3H4 Cu 89: Mot hirocacbon A co t khoi hi oi vi Nit bang 1,5 .A cong nc tao 2 ancol.Ten goi cua cua A la: a.xichclo b.propan d. propin propan c. propen Cau 90: Mot hirocacbon A co t khoi hi oi vi Nit bang 1,5 .T A co the ieu che hp chat ial .Ten goi cua cua A la: a.xichclo b.propan d. propin propan c. propen Cau 100: Mot hirocacbon X co t khoi hi oi vi etilen bang 2 .Xcong HCl tao 1 san pham duy nhat.X la: a.but-1-en b.but-3-en c.but-2-en d. i-butilen. Cau 101: Mot hirocacbon Y co t khoi hi oi vi etilen bang 2 .Y cong HCl tao 2 san pham. Yla: a. but-1-en hoac but-2-en c.but-2-en hoac i-butilen b. i-butilen. hoac but-3-en d. but-1-en hoac i-butilen Cau 102: Mot hirocacbon Y co t khoi hi oi vi khong kh bang 2 , 4137.Y co 2 ong phan lap theYla: a. pent-1-en c. 2-metylbutd. 2-metylbutb. pent-2-en 1-en 2-en Cau 103: Mot hirocacbon Z co t khoi hi oi vi khong kh bang 2 , 4137.Z cong nc tao ra hon hp trong o co 1 ancol bac 3.Vay Z la: a. pent-1-en c. 2-metylbutd. 2-metylbutb. pent-2-en 1-en 2-en Cau 104: Mot hirocacbon Y co so cacbon trong phan t 2 va khi ot chay hoantoan thu c so mol CO2 bang so mol nc.Vay Y thuoc day ong ang:
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a. ankan b. anken c.ankin d.xicloankan Cl 2 nhietphn Cau 105:A B C PVC.Vay A,B,C lan lt la: a. etilen ;1,2-icloetan ; vinyl clorua .b. etilen ; 1,1-icloetan ; vinyl clorua . c. axetilen ;1,1-icloetan ; vinyl clorua .d. axetilen ;1,2-icloetan ; vinyl clorua xt ,t 0 Cau 107:A(C,H,O) B anehytaxetic. Vay A,B,C la: a. metanol , eten , metan. c etanol , eten , metan. b.axit axetic , metanol , eten d. etanol , metanol , eten NaOH KMnO 4 Cau 108:A(cha C,H,O,Na) B etilen glicol. A,B lan lt la: CaO ,t 0 a.Natriaxetat , etanol. b. Natripropenat . c. Natriphenolat, etilen d. Natripropenat, etanol
.Cau 109:Crackinh butan thu c hon hp trong o co cha2 hirocacbon A,B (t khoi so vi hiro bang 1,5.) Vay A,B lan lt la:

a.C2H4, C3H6.

c. CH4 , C3H6. d. C2H6 , C3H6. Cau 110:A(C,H,O) B C etan 1,2-iol. A,B,C lan lt la: a.etanol , etilen , 1,2-ibrom etan. b.metanol , etilen , 1,2ibrom etan. c.etanol , etilen , 1,2-ibrom eten. d.etanol , etilen , 1,1 -ibrom etan.
H 2 SO 4 t0 Br 2 NaOH t0

b. C3H6 , C2H4.

Cau 111:ot chay hoan toan 0,1 mol anken A .Dan toan bo san pham qua bnh ng nc voi trong co d thu c 40gam ket tua.A tac dung vi HCl tao ra 1 san pham duy nhat.Vay A la:

a.but-1- en c. -butilen b. but-2- en d. i-butilen Cau 112: ot chay hoan toan 7gam anken A .Dan toan bo san pham qua bnh ng nc voi trong co d thu c 70gam ket tua.Vay A la: a.C4H8 c. C7H14 b.C6H12 d. khong xac nh. Cau 113:ot chay hoan toan mot lng hirocacbon A roi dan toan bo san pham i qua bnh ng nc voi trongCo d., khoi lng bnh tang 18,6gam va co 30gam ket tua.The tch oxi(ktc) tham gia phan ng la: a.1,12l b.2,24l c.5,4l d. 10,08l Cau 114: ot chay hoan toan mot lng hirocacbon A thu c CO2 va nc co t le ve khoi lng la: 22:9 . Neu ot chay hoan toan 0,1mol A roi dan toan bo hon hp qua bnh ng nc voi trong co d thu c 40gam ket tua.Cong thc phan t cua A la: a.C4H8 b.C5H10 c.C6H12 d.C7H14. Cau 115: e phan biet but-1- en va butan ta co the dung 1 loai thuoc th la :
a.dung dch brom. b.dung dch qu tm. c.dung dch AgNO3/NH3. d.dung dch brom hoac qu tm

Cau 116: Hirocacbon A co cong thc phan t C5H10 ,tac dung c vi nc tao ra hon hp trong o co 1 ancol bac 3.Ten cua A la: a. pent-1-en c. 2-metylbutd. 2-metylbutb. pent-2-en 1-en 2-en Cau 117: A,B la hai hirocacbon kh ieu kien thng :A co cong thc C2xHy ,B : CxH2x= .T khhoi cua A oi vi khong kh bang 2 ,cua B oi vi a bang 0,482.Cong thc phan t cua A lan lt bang : a.C4H10 va C2H4 b. C3H6 va C5H10 c. C4H8 va C3H6 d. C4H8 va C2H4 .
15

a.500,00 Cau 118: Mot oan polietilen co phan t kho M = 140000 vc.He so b.5000,0 c.50000 d.50,00 trung hp la: A tac dung vi oxi tao ra san pham gom a mol CO2 b mol H2O.Quan Cau 119: Mot anken he cua a va b la: a.a=2b b.a<b c.a>b d.a=b

16

Cu 129:ivinyl tc dng cng HBr theo t l mol 1:1, -80OC to ra sn phm chnh l: a.3-brm-but-1-en b.3-brm-but-2-en c.1-brm-but-2-en d..2-brm-but-3-en O Cu 130:ivinyl tc dng cng HBr theo t l mol 1:1, 40 C to ra sn phm chnh l: a.3-brm-but-1-en b..3-brm-but-2-en c.1-brm-but-2-en d..2-brm-but-3-en Cu 131: Sn phn trng hp A Caosubu Na.Vy A l: a.2-mtyl-butaien-1,3 b.1,3-butaien c.butaien-1,3 d.buta-1,3-ien Cu 132: Sn phn trng hp B Caosu isopren.Vy B l: a.isopren b. 2-mtyl-1,3-butaien c.2-mtyl-butaien-1,3 d.2-mtylpenta-1,3-ien Cu 133:Sn phm trng hp ca ivinyl c tn gi l: a.poly(butaien) b.polybutaien c.poly(isopren) d.polyisopren Cu 134:Sn phm trng hp ca isopren c tn gi l: a.poly(butaien) b.polybutaien c.poly(isopren) d.polyisopren Cu 135: Sn phm trng hp ca: CH2=C(CH3)-CCl=CH2 c tn gi l: a.Cao subuNa b.Cao isopren c.Cao subuNa-S d.Cao cloropren Cu 136: hir ho hidrcacbon no A thu c ivinyl.Vy A l: a.n-butan b.iso butan c.but-1-en d.but-2-en Cu 137: hir ho hidrcacbon no A thu c isopren.Vy A l: a.n-pentan b.iso pentan c.pen-1-en d.pen-2-en xt cu 138: Cht hu c X cha C,H,O ivinyl + ? + ? Vy X l: t0 a.etanal b.etanol c.metanol d.metanal Cu 139: S ng phn mch h ng vi cng thc C4H6 c l:a.3 b.4 c5 d.6 Cu 140: ien C4H6 c s ng phn cu to cng chc l:a.3 b.4 c5 d.6 Cu 141: ng vi cng thc C5H8 c s ng phn mch h l:a.4 b.6 c.8 d.9 Cu 142: ng vi cng thc ien C5H8 c s ng phn mch h l:a.5 b.6 c.7 d.8 Cu 143:ng vi cng thc ien ,mch thng C5H8 c s ng phn mch h l: a.4 b.6 c.7 d.8 Cu 144:ivinyl tc dng cng Br2 theo t l mol 1:1, -80OC to ra sn phm chnh l: a.3,4-ibrm-but-1-en b.3,4-ibrm-but-2-en c.1,4-ibrm-but-2-en d.1,4-ibrm-but-1-en Cu 145:ivinyl tc dng cng Br2 theo t l mol 1:1, 40OC to ra sn phm chnh l: a.3,4-ibrm-but-1-en b.3,4-ibrm-but-2-en c.1,4-ibrm-but-2-en d.1,4-ibrm-but-1-en Cu 146: nhn bit butan v buta-1.3-ien ta c th dng thuc th: a.dd brm b.dd thuc tm c.kh H2 d.dd brom hoc thuc tm Cu 147: nhn bit but-1-en v buta-1.3-ien ta c th dng thuc th: a.dd brm v phng php nh tnh b.dd brm v phng php nh lng c.kh H2 v phng php nh tnh d.dd thuc tm v phng php nh tnh Cu 148: Cho s phn ng etilen A(C,H,O) B Cao su buNa. Vy A ; B ln lt l: a.buta-1,3-ien ; etanol b.etanol ; buta-1,3-ien c.etanol ; buta-1,2-ien d.etanal ; buta-1,3-ien Cu 149: Cho s phn ng 3-metyl-but-1-en A B Cao su isopren. A , B ln lt l: a. isopren ; isopentan b.isopentan ; isopren . c.isopenten ; isopren d.isobutan ; but-1,3-ien Cu 150:Cho s phn ng axetilen AB Cao su buNa. Vy A , B ln lt l: a.buta-1,3-ien ; etanol b.etanol ; buta-1,3-ien c.vinyl axetilen ,buta-1,3-ien, d. buta-1,3-ien,vinyl axetilen Cu 151:Mt hn hpA gm 0,3mol hiro v 0,2mol etilen .Cho hhA qua bt Ni nung nng c hn hp kh B.Hn hp B phn ng va vi 1,6gam brom.Hiu sut phn ng hiroha l:a.95% b.59% c.95,5% d.50% Cu 152:Hai anken kh iu kin thng cng nc cho hn hp gm 2 ancol.Vy 2 anken l: a.etilen v propen. b.etilen v pent-1-en. c.etilen v but-1-en. d.etilen v but-2-en
17

Cu 153: Bit khi lng ring ancol etilic bng 0,8g/ml ,hiu sut phn ng t 60%.T 240lt ancol 96 0 iu ch c mt lng buta-1,3-ien l: a.64913,4gam. b.69413,4gam. c.64931,4gam. d.64193,4gam. Cu 154: Cho 1 mol isopren tc dng vi 2mol brom.Sau phn thu dc: a.1dn xut brom. b.2dn xut brom. c.3 dn xut brom. d.4dn xut brom. Cu 155: Cho 1 mol ivinyl tc dng vi 2mol brom.Sau phn thu dc: a.1dn xut brom. b.2dn xut brom. c.3 dn xut brom. d.4dn xut brom. Cu 156:A(C4H6O2) .T A bng 3 phn ng lin tip iu ch c cao su buna.A c th l hp cht :a.iol hoc ion b.ial hoc ion c.iol hoc ial d.iol ,ial hoc ion Cu 157:t chy hon ton hiro cacbon kh X thu c sn phm cha 76,52 % CO2 v khi lng.Cng thc phn t ca X l:a.C2H6 b.C3H6 c.C4H6 d.C4H8 Cu 158: 4,48 l(ktc)mt hirocacbon A th kh trong iu kin thng tc dng va vi 100ml ddbrom 1M thu c sn phm ch,562 % Br v khi lng.Cng thc phn t ca A l: a.C2H6 b.C3H6 c.C4H6 d.C4H8 Cu 159:t chy hon ton m gam hn hp gm buta-1,3-ien v isopren thu c 0,9 mol CO2 v 12,6g nc.Gi tr cu m bng:a.12,1g b.12,2g c.12,3g d.12,4g Cu 160:t chy hon ton agam hn hp gm buta-1,3-ien v isopren thu c 20,16l CO2 ktcv 12,6g nc.Th tch oxi cn dng tc l:a.28lit. b.29l c.18lit d.27lit Cu 161:X,Y,Z l 3 ng ng k tp.Phn t khi ca Z gp 3ln X.X lm mt mu dd brom .X,Y,Z thuc dy ng ng :a.anken b.ankain c.xicloankan d.ankaien. Cu 162:khi t chy hon ton hn hp X gm 1anken v 1ankan thu c 8,28gam nc v 12,32gam CO2 .S mol ankan trong hn hp l:a.0,06 b.0,09. c.0,12 d.0,18 163/ t 0,05 mol cht A(C,H) thu c 0,2 mol H2O.Bit A trng hp cho B c tnh n hi.Vy A l: a.buta-1,3-ien b.2-metylbuta-1,3-ien c.2-metylbuta-1,2-ien d.2-metylbuta-1,3-ien 164/Mt Hircacbon A cha 14,29% H v khi lng.A cng dd brm to dn xut cha 85,11% brm v khi lng.Cng thc cu to ca B l: a.CH3CHBr2 b.CHBr2- CHBr2 c.CH2Br- CH2Br d. CH3CHBr-CH2Br 165/ tch etan,eten ra khi hn hp ca chng ta ln lt thc hin phn ng: a.Tc dng vi Zn,t0,dd Br2 b.Cng H2,un vi H2SO4 c 0 c. Tc dng vi dd Br2,Zn,t d. Tc dng vi dd thuc tm, H2SO4 c,t0 166/ Ankaien A + Brom(dd) CH3C(CH3)Br-CH=CH-CH2Br . Vy A l: a.2-metylpenta-1,3-ien. b. 2-metylpenta-2,4-ien. c. 4-metylpenta-1,3-ien. d. 2-metylbuta-1,3-ien. 167/ Ankaien B + Cht v c CH2Cl-C(CH3)=CH-CH2Cl-CH3 . Vy A l: a. 2-metylpenta-1,3-ien. b. 4-metylpenta-2,4-ien. c. 2-metylpenta-1,4-ien. d. 4-metylpenta-2,3-ien. 168/ Cho 1 Ankaien A + Brom(dd) 1,4-ibrm,2-metylbut-2-en. Vy A, l: a. 2-metylbuta-1,3-ien. b. 3-metylbuta-1,3-ien. c. 2-metylpenta-1,3-ien. d. 3-metylpenta-1,3-ien. 170/ Hn hp X gm propen l ng ng theo t l th tch 1:1.t 1 th tch hn hp X cn 3,75 th tch oxi(cng k).Vy B l:a.eten b.propan c.buten d.penten 171/ t hon ton 0,2 mol hn hp CH4;C4H10;C2H4 thu c 0,28 mol CO2 v 8,28 ml H2O.S mol ankan v anken trong hn hp ln lt l: a.0,02 v 0,18 b.0,16 v 0,04 c.0,18 v 0,02 d.0,04 v 0,16 172/ Cho hn hp X gm 2 olefin qua bnh ng dd brom,khi phn ng xong c 16 g brom tham gia phn ng .Tng s mol ca 2 anken l:a.0,01 b.0,5 c.0,05 d.0,1 173/ Mt hn hp kh A gm 1 ankan,1 anken c cng s cacbon v ng mol .Cho a g h hp A phn ng va vi 120 g dd Br2 20% trong CCl4 .t a g hn hp trn thu c 20,16 lt CO 2 (ktc).Cng thc phn t ca ankan , anken ln lt l :a.C3H8 v C3H6 b.C3H8 v C3H6 c. C2H6 v C2H4 d. C4H10 v C4H8 174/ m gam hn hp gm C3H6 ; C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO2 (ktc).Nu Hiro ho hon ton m g hn hp trn ,ri t chy ht hn hp thu c V(ml) CO2 (ktc).Gi tr ca V?
18

a. 22,4 b.22400 c.44,80 d.33600 175/ t chy hon ton m g etanol thu 3,36 lt CO2 (ktc).Nu un m g etanol vi H2SO4 c ;180o C ri t chy ht sn phm thu c a g H2O.Gi tr ca a l: a.2,7 g b.7,2 g c.1,8 g d.5,4 g Cu 176/ Ankin l hirocacbon: a.c dng CnH2n-2,mch h b. c dng CnH2n+1,mch h c.Mch h ; 1 lin kt ba trong phn t d.(a);(c) u ng. Cu 177/ Dy ng ng ca axetilen c cng thc chung l a. CnH2n+2 (n>=2) b. CnH2n-2 (n>=1) c. CnH2n-2 (n>=3) d. CnH2n-2 (n>=2) Cu 178/ A,B,C l 3 ankin k tip nhau trong dy ng ng c tng khi lng 162 vC.Cng thc A,B,C ln lt l: a.C2H2;C3H4;C4H6 b.C3H4;C4H6;C5H8 c.C4H6;C3H4;C5H8 d.C4H6;C5H8;C6H10 179/ A,B l 2 ankin ng ng th kh ,trong iu kin thng T khi hi ca B so vi Abng 1,35.Vy A,B l: a.etin;propin b.etin;butin c.propin;butin d.propin;pentin 180/ Ankin A c cha 11,11% H v khi lng .Vy A l: a.C2H2 b.C3H4 c.C4H6 d.C5H8 181/ Ankin B c cha 90% Cv khi lng,mch thng,c phn ng vi AgNO3/ddNH.Vy B l: a.axetilen b.propin c.but-1-in d.but-2-in 182/ Cc ankin c ng phn v tr khi s cacbon trong phn t ln hn hoc bng : a.2 b.3 c.4 d.5 183/ C5H8 c s ng phn cu to ca ankin l:a.2 b.3 c.4 d.5 184/ Theo IUPAC CH3-C C-CH3-CH3 ; c tn gi l: a.etylmetylaxetilen b.pent-3-in c.pent-2-in d.pent-1-in C-CH2-CH(CH3)-CH3 ; c tn gi l: 185/ Theo IUPAC CH a.isobutylaxetilen b.2-metylpent-2-in c.4-metylpent-1-in d.4-metylpent-1,2-in 186/ Theo IUPAC CH3-C C-CH(CH3)-CH(CH3)-CH3 ; c tn gi l: a.4-imetylhex-1-in b. 4,5-imetylhex-1-in c. 4,5-imetylhex-2-in d. 2,3-imetylhex-4-in 187/ Theo IUPAC CH3-CH(C2H5)-C C-CH(CH3)-CH2- CH2-CH3 ; c tn gi l: a.3,6-imetylnon-4-inb.2-etyl,5-metyloct-3-in c.7-etyl,6-metyloct-5-in d.5-metyl,2-etyloct-3-in 188/ Ankin CH C-CH(C2H5)-CH(CH3)-CH3 c tn gi l: a.3-etyl,2-metylpent-4-in b.2-metyl,3-etylpent-4-in c.4-metyl,3-etylpent-1-in d.3-etyl,4-metylpent-1-in 189/ Cu to c th c ca ankin C4H6 l:a.1 b.2 c.3 d.4 190/ Trong phn t axetilen lin kt ba gia 2 Cacbon gm: a.1 lin kt pi v 2 lin kt xich-ma b.2 lin kt pi v 1 lin kt xich-ma c. 3 lin kt pi d.3 lin kt xich-ma 192/ di ca lin kt ba,lin kt i,lin kt n gia 2 nguyn t C tng theo th t: a.ba,n,i b.n,ba,i c. i,n,ba d. ba,i,n 193/ bn ca lin kt ba,lin kt i,lin kt n tng theo th t: a.ba,n,i b.n,i,ba c. i,n,ba d. ba,i,n 194/ Cc ankin bt u c ng phn mch C khi s C trong phn t: a. 2 b. 3 c. 4 d. 5 195/ Mt trong nhng loi ng phn nhm chc ca ankin l: a.ankan b.anken c.ankaien d.aren 196/ chuyn ho ankin thnh anken ta thc hin phn ng cng H2 trong iu kin c xc tc: a.Ni/ to b.Mn/ to c.Pd/ PbCO3 d.Pb/PdCO3 197/ chuyn ho ankin thnh ankan ta thc hin phn ng cng H2 trong iu kin c xc tc: a.Ni/ to b.Mn/ to c.Pd/ PbCO3 d.Pb/PdCO3 198/ phn bit etan,eten,etin ta dng 1 thuc th duy nht l: a.dd Brom b.dd AgNO3/NH3 c.dd HCl d.dd Ca(OH)2 199/ Phn ng ankin + dd Brom xy ra 2 giai on,mun phn ng dng li giai on 1,ta phi tin hnh phn ng nhit : a.thp b.trung bnh c.cao d.rt cao
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200/ Dietylaxetilen tc dng vi nc Brom nhit thp to ra sn phm: a.3,3,4,4-tetrabromhexan b.3,4-ibromhex-3-en c.3,4-ibromhex-2-en d. 3,3,4,4-tetrabromheptan 201/ Cho but-2-in tc dng vi nc brom d ta thu c sn phm l: a.2,3-ibrombut-2-in b.2,3-ibrombut-2-in c.1,2,3,4-tetrabrombutan d.2,2,3,3-tetrabrombutan 202/ Cho axetilen tc dng vi HCl trong iu kin c xc tc HgCl2 150-200oC,ta thu c sn phm cng l: a.vinylclorua b.etylclorua c.1,2-icloetan d.1,1-icloetan 203/ Cho axetilen tc dng vi HCl trong iu kin khng c xc tc,ta thu c sn phm cng l: a.vinylclorua b.etylclorua c.1,2-icloetan d.1,1-icloetan 204/ Phn ng cng nc vo propin trong iu kin c xc tc HgSO4/H2SO4 80oC to ra sn phm: a.CH3CH2CHO b.CH3COCH3 c.CH3-C(OH)=CH2 d.CH3-CH=CH2-OH 205/ Cho axetilen tc dng vi H2O A.Vy cu to ca A : a.CH3CHO b.CH2=CH-OH c.CH3CH2OH d.CH3COOH C-CH3 cng nc (HgSO4/H2SO4 /80 oC) to ra sn phm: 206/ CH3-C a. CH3-CH=C(OH)-CH3 b. CH3CH2CH2CHO c.CH3-CO-CH2CH3 d. CH2=CH-CH2-CH2-OH 207/ Cho A tc dng vi nc CH3CH2 CH2CHO.Vy A l: a.but-1-in b. but-2-in c. but-1-en d. but-2-en 208/ Trong iu kin thch hp v xc tc v nhit ,axetilen tham gia phn ng nh hp to ra: a.buta-1,3-ien b.buta-1,3-in c.Vinylaxetilen d.xiclobuten 209/ Trong iu kin thch hp (C;600oC),axetilen tham gia phn ng tam hp to thnh phn t: a.stiren b.benzen c.toluen d.hexen 210/ Propin tham gia phn ng tam hp to ra sn phm: a.1,2,3-trimetylbenzen b. 2,4,6-trimetylbenzen c. 1,3,5-trimetylbenzen d.etyl,metylbenzen 211/ Trong iu kin thch hp pent-2-in tam hp thnh sn phm: a.1,2,3-trietyl-4,5,6-trimetylbenzen b. 1,2,4-trietyl-3,5,6-trimetylbenzen c. 1,3,5-trietyl-2,4,6-trimetylbenzen d. 4,5,6-trimetyl-1,2,3-trietyl-benzen 212/ Axetilen + CH3COOH (xt) A.Vy A l: a.etylaxetat b.vinylaxetat c.etilenglicol d.metylacrylat o 213/ Etin + C2H5OH (xt ,t ) B.Vy B l: a.etylvinylete b. etylvinyleste c. vinyletylete d. vinyletyleste 214/ Axetilen + A vinylaxetat.Vy A l: a.ancoletylic b.anehytaxetic c.axit axetic d.ancolvinylic 215/ Axetilen + B etylvinylete.Vy B l: a. anehytaxetic b. axit axetic c. ancolvinylic d. ancoletylic 216/ Cho cc cht (1)but-1-in (2)but-2-in (3)propin (4)buta-1,3-in.Cc cht c phn ng vi dd AgNO3/NH3 to kt ta vng nht l: a.(1),(3),(4) b. (2),(3),(4) c. (1),(2),(3) d. (1),(2),(4) 217/ HC CH + [Ag(NH3)2](OH)2 A + B + H2O .Vy A,B ln lt l: a. HC CAg ; NH3 b. AgC CAg ; NH3 c. AgC CAg ; NH4NO3 d. HC CAg ; NH4NO3 CH + [Ag(NH3)2](OH)2 A .Ct to ca A l: 218/ CH3-C a. AgCH2-C CH b. AgCH2-C CAg c. CH3-C CAg d. CH3-CAg CAg 219/ Cho A(C4H6)c phn ng vi AgNO3/NH3 to kt ta vng nht .A l: a.But-2-in b. But-1-in c. But-2-en d. But-1-in CH + AgNO3 + NH3 + H2O A + B. A ,B ln lt l: 220/ R-C a. R-C CAg b. R-C CAg ; NH4NO3 c. Ag ; NH4NO3 d. R-CAg=CAg ; NH4NO3 221/ 1 cht hu c A + [Ag(NH3)2](OH)2 to ra kt ta vy A l: a.anehyt b.axit cacboxylic c.ank-1-in d. anehyt hoc ank-1-in 222/ 1 Cht hu c B + AgNO3 + NH3 + H2O vng nht.Vy B thuc loi hp cht: a. anehyt b.HCOOR c.ankin d.ank-1-in 223/ Mt hn hp X gm 1 g propin v 2,7 g ankin B(C 4H6) tc dng vi dd AgNO3/NH3 d to 3,675 g kt ta.Vy B l:a.but-1-in b.but-2-in c.ivinyl d. but-1-in hoc but-2-in 224/ A(C4H6) + dd AgNO3/NH3 to kt ta. A l:
20

a. ivinyl b. but-1-in c. but-2-in d. but-1-en 225/ t chy hon ton 1 ankin ta c : a. S mol CO2 < H2O b. S mol CO2 > H2O c.nCO2 = nH2O + 1 d. nCO2 = nH2O - 1 226/ t chy hon ton 0,2 mol ankin A 0,4 mol H2O.Hiro ho hon ton 0,2 mol ankin A ri t ht sn phm to thnh thu c a mol H2O.Gi tr ca A l: a.0,8 b.0,6 c.1,25 d.2,5 227/ t chy V(l) (ktc) mt ankin A 21,6 g H2O.Nu cho ton b sn phm chy hp th hon ton vo bnh ng dd nc vi trong ly d ,th khi lng bnh tng 100,8 g .V c gi tr l: a.6,72l b.4,48l c.3,36l d.13,44l 228/ t chy V(l) (ktc) mt ankin th kh thu c CO 2 v H2O c tng khi lng bng 50,4 g.Nu cho sn phm chy qua bnh ng nc vi trong d th thu c 90 g kt ta.V c gi tr l: a.6,72l b.4,48l c.3,36l d.13,44l 229/ t chy a mol ankin b mol CO2 v c mol H2O.Quan h gia a,b,c l: a.b>c v a= b-c b. b<c v a= b-c c. b>c v a= b+c d. b>c v a= c-b 230/ t chy hon ton 0,2 mol hn hp 2 hirocacbon c M hn km nhau 28 vC ta thu c 17,92 lt CO2 (ktc) v 14,4 g H2O.Cng thc phn t ca 2 HC l: a.C3H6 v C5H10 b. C3H8 v C5H12 c. C2H4 v C4H8 d. C4H8 v C6H12 231/ t chy hon ton 0,2 mol hn hp 2 hirocacbon A,B c M hn km nhau 14 vC thu c 15,68 lit CO2 (ktc)v 12,6 g H2O.CTPT ca A v B l: a.C3H6 v C4H8 b. C2H4 v C3H6 c. C4H8 v C5H10 d. C5H10 v C6H12 232/ t chy hon ton 4 g ankin A 6,72 l CO2 (ktc) v 3,6 ml H2O(lng).Cng thc phn t A l: a.C2H2 b. C3H4 c. C4H6 d. C5H8 233/ Ankin B (mch thng)c t khi i vi H2 l 17,khng phn ng vi dd AgNO3/NH3 .Vy B l: a.but-1-in b.but-2-in c.butin-1 d.1-butin 234/ t chy ht 5,4 g Hirocacbon X(CnH2n-2) thu c 0,4 mol CO2 v 0,3 mol H2O.X tc dng vi dd AgNO3/NH3 to kt ta vng nht.Vy X l: a.But-1-in b.but-2-in c.buta-1,2-ien d. buta-1,3-ien 235/ Cho 1,3 g ankin A cht kh k thng tc dng vi dd AgNO3/NH3 to 12 g kt ta vng nht.Vy CTPT ca A l: a.C2H2 b.C3H6 c.C3H4 d.C4H8 236/ / Cho 2 g ankin B cht kh k thng tc dng vi dd AgNO3/NH3 to 7,35 g kt ta vng nht.Vy CTPT ca B l:a.C2H2 b.C3H6 c.C3H4 d.C4H8 237/ Cho s : Kh thin nhin A + HCl B P.V.C Vy A,B ln lt l: a.axetilen;vinylclorua b. vinylclorua; axetilen c. axetilen;1,1-icloetan d. axetilen;1,2-icloetan 238/ Cho s : vi ABCDP.V.C A,B,C,D ln lt l: a.Canxioxit;etin;t n;vinylaxetat b. t n;Canxioxit;etin; vinylaxetat c. Canxicacbua;etin;t n;vinylaxetat d. Canxioxit t; n;etin; vinylaxetat 239/ Cho s : CH4 ABDCaosu BuNa A,B,D ln lt l: a.axetilen;vinylaxetilen;buta-1,3-ien b. axetilen;vinylaxetilen;butaien-1,3 c. vinylaxetilen;axetilen; buta-1,3-ien d. axetilen;but-2-en;buta-1,3-ien 240/ Cho s : C2H2 ABCH3COOH A,B ln lt l: a.etilen;etanal b.etanal;etanol c.etilen;etanol d.a,b,c u ng 241/ Cho s : CaC2 ABCH3CHO A,B ln lt l: a. C2H2;CH2=CH2 b. C2H2;CH2=CHCl c. C2H2;CH3-CHCl2 d.a,b,c u ng 242/ Cho axetilen + HCN sn phm A.Vy A c cu to l: a.CH3CH2CN b.HC C-CN c.CH2=CH-CN d.CN- C C-CN 243/ Cho s propin A + dd KMnO4 B . A,B ln lt l: a.propen;propan-1,2-iol b.propen; propan-1,3-iol c. propan-1,3-iol; propen d. propan-1,2-iol; propen 244/ phn bit propan;propen;propin ta dng 1 thuc th l: a. dd AgNO3/NH3 b. dd Brom c. dd NaOH d. dd HCl 245/ tch C2H2;C2H6 ra khi hn hp ca chng ta ln lt thc hin phn ng vi cc cht : a. dd AgNO3/NH3; dd HCl b. dd HCl ;dd AgNO3/NH3 c.dd Br2 ;Zn d. Zn ;dd Br2
21

246/ Ankin A c cng thc (C4H7)n .Cng thc phn t ca A l: a.C12H21 b.C5H8 c.C8H10 d.C8H14 247/ Axetilen c iu ch bng cch: a.nhit phn kh metan b.cho t n hp nc c. hiroho etilen d. a,b,c u ng. 248/ Phn ng no ca axetilen c dng trong hn ct kim loi? a.cng nc b.t chy trong oxi khng kh. c.cng H2 d. t chy trong oxi nguyn cht. 249/ Hm lng axetilen trong khng kh c th gy chy n l: a.1,5% b.2,5% c.3.5% d.4,5% 250/ Cch n gin c th phn bit etan,etilen,etin bng 1 thuc th l: a.Br2 b.Cl2 c.H2 d. AgNO3/NH3 251/ ng vi cng thc C6H10 c bao nhiu cu to ankin? a.5 b.6 c.7 d.8 252/ phn bit but-2-in v buta-1,3-ien ta dng 1 thuc th l: a.Br2 b.Cl2 c.H2 d. AgNO3/NH3 253/ Ngn la n x oxi-axetilen dng trong hn v ct kim loi c th t ti nhit : a.1000oC b. 2000oC c. 3000oC d. 4000oC 254/ t chy hon ton 2 ankin k tip nhau trong dy ng ng ri dn sn phm qua dd Ca(OH)2 d thu c 50 g kt ta .Cng thc phn t ca 2 ankin l: a.C2H2 v C3H4 b. C3H4 v C4H6 c. C4H6 v C5H8 d. C5H8 v C6H10 255/ Cho 13,2 g hn hp 2 ankin A v B k tip nhau trong dy ng ng;M A <MB phn ng ti a vi dd cha 0,8 mol Br2 .Cng thc phn t ca A;B ln lt l: a. C3H4 v C4H6 b. C2H2 v C3H4 c. C4H6 v C5H8 d. C5H8 v C6H10 256/ A l 1 ankin ng trc B trong dy ng ng .Hn hp kh gm 2 g A v 5,4 g B c th tch 3,36 lt(ktc).Cng thc phn t ca A;B ln lt l: a.C2H2 v C3H4 b. C3H4 v C4H6 c. C4H6 v C5H8 d. C5H8 v C6H10 257/ 1.6 g hn hp propin v ankin B(C4H6) tc dng vi dd AgNO3/NH3 (d)to 3,675 g kt ta vng nht.Vy CTPT ca B l:a.but-1-in b.but-2-in c.butin-1 d.butin-2 ddKMnO 4 D.1 mol D chy cho 207 g cht rn .vy D l: 258/ Cho s C3H4 C(dn xut benzen)
COOH

COOH

COOK

COOK

COOK COOK COOK COOH a. COOH b. COOH c. KOOC d. COOH 259/ Ankin A p vi dd KMnO4 /KOH theo phng trnh: A + KMnO4 + KOH CH3COOK + K2CO3 + MnO2 + H2O Vy A l: a.axetilen b.propin c.but-1-in d.but-2-in 260/ Cho 1 lng ankin lng k thng vo bnh ng dd AgNO3/NH3 d sau phn ng khi lng bnh tng thm 20,5 g v c 47,25 g kt ta .Cng thc phn t ca ankin l: a.C3H4 b.C4H6 c.C5H8 d.C6H10 261/ P.V.C c iu ch theo s C 2H2 C2H3Cl P.V.C iu ch 31,25 kg P.V.C(hiu sut chung ca qu trnh iu ch t 80%)th lng C2H2 cn dng l:a.13kg b.26kg c.16,52 kg d.16,25kg 262/ P.V.C iu ch theo s : C2H2 C2H3Cl P.V.C Hiu sut chung ca qu trnh iu ch t 80%)th lng P.V.C thu c l:a.10kg b.12,5kg c.15,625kg d.31,5kg 263/ 1 g ankin A c s C>= 3tc dng vi dd AgNO3/NH3 d thu c 3,675 g kt ta .Cng thc phn t ca ankin l:a.C3H4 b.C4H6 c.C5H8 d.C6H10 AgNO 3/ NH 3 HCl 264/ A(C3H4) B D B;D ln lt l: CAg;AgCl a. CH3-C b. AgCH2-C CAg;AgCl c. CH3-C CAg;Ag d. AgCl; AgCH2-C CAg Cu 265. Hin nay PVC c iu ch theo s sau: C2H4 CH2Cl CH2Cl V.C PVC. Nu hiu sut t 80% th lng PVC thu c t 280kg etilen l: a.50kg b.500kg c.55kg d.781,25kg Cu 266. Hin nay PVC c iu ch theo s sau: C2H4 CH2Cl CH2Cl C2H3Cl PVC. Nu hiu sut t 80% th lng C2H4 cn dng sn xut 5000kg PVC l: a.28kg b.1792kg c.2800kg d.179,2kg

22

Cu 267. Trn 300ml hn hp hidrocacbon (X) vi 500ml oxi (d) ri t chy thu c 750ml hn hp kh v hi. Lm lnh hn hp cn li 650ml, tip tc cho qua dung dch KOH d cn li 450ml. Cng thc phn t ca X l: a.C2H2 b.C2H4 c.C2H6 d.C3H6 Cu 268. t 0,2mol A(CxHy) bng mt lng oxi va thu c 17,92 lt hn hp kh 273 0C; 3 atm. T khi hi ca hn hp i vi H2 bng
53 . Cng thc phn t ca A l: 3

a.C2H2 b.C4H4 c.C6H6 d.C8H8 Cu 269. A(C4H2) c cha 1 lin kt n C C , tc dng vi dung dch AgNO3/NH3 to kt ta. Cho 2,3kg A tc dng vi dd AgNO3/NH3 d to ra m(g) kt ta. Gi tr ca m l: a.11000 b.12000 c.13000 d.13050 Cu 270. A (c cha C, H) phn ng c vi dd AgNO3/NH3 d to ra m(g) kt ta. Vy A l hp cht: a.Ankin b.Ank 1 in c.C 1 lin kt -C C- u mch d.C 2 lin kt -C C- u mch Cu 271. t chy hon ton 100ml A(CxHy) trong mt lng oxi va thu c 500ml hn hp kh v hi. Lm lnh hi cn li 300ml (cc th tch kh cng iu kin). Cng thc phn t ca A l: a.C3H4 b.C3H6 c.C2H2 d.C4H2 Cu 272. t chy hon ton 1 cht hu c A ch thu c sn phm gm CO2 v H2O. T khi hi ca A i vi CH4 l 1,625. Cng thc phn t ca A l: a.C2H4 b.C2H6 c.C2H2 d.C4H2 Cu 273. Anken A (C4H8), c ng phn cis trans. Vy A l: a.But 1 en b.But 2 en c.2 metyl prop 1 en d.2 buten Cu 274: Anken (X) (C5H10), c ng phn lp th. Vy A l: a.but 1 en b.2 metyl pro 1 en c.but 2 en d.3 metyl but 1 en Cu 275: A (C, H, O, Na) + NaOH Etylen + Vy A l: a.Natri axetat b.Natri propionat c.Natri metacrylat d.Natri acrlyat Cu 276. S ng phn cu to tha mn iu kin: c mt ni ba, cng thc phn t l C 6H10, mch di nht c cha 5 cacbon l: a.3 b.6 c.4 d.5 Cu 277. S ng phn cu to tha mn iu kin: c mt ni ba, cng thc phn t l C6H10, mch di nht c cha ot61i a 5 cacbon l: a.2 b.3 c.4 d.5 Cu 278. S ng phn cu to tha mn iu kin: c mt ni ba, cng thc phn t l C 6H10, mch di nht c cha 4 cacbon l: a.1 b.2 c.3 d.4 Cu 279. Dy cc cht u c phn ng vi axetilen ( iu kin thch hp) l: a.H2O, AgNO3/NH3, Br2, C2H2, H2 b.H2O, NaOH, Br2, C2H2 c.H2O, Br2, H2, CaO, KMnO4 d.Br2, H2, HCl, CH3COOH, NaOH Cu 280. 0,1mol A(CxHy), cht kh iu kin thng, chy hon ton to 0,3 mol H 2O, phn ng vi Br2 theo t l 1 : 2. A l: a.C2H6 b.C3H6 c.C4H6 d.Butin Cu 281. A(CxHy). 2,7g A c th tch bng th tch ca 0,8g CH4 250C, 740mmHg. A l: a.C2H2 b.C2H6 c.C3H6 d.C4H6 Cu 282. A (C2H4) + Cl2 sp B (c ng phn cis trans). Vy B l: a.CHCl2 CHCl2 b.CH2Cl CH2Cl c.CH3CHCl2 d.CHCl = CHCl Cu 283. Cng thc tng qut ca mi hidrocacbon l CnH2n+2-2k. Gi tr ca hng s k cho bit: a.S lin kt pi b.S vong no c.S lin kt i d.S lin kt pi + vng no Cu 284. Cng thc tng qut ca hidrocacbon mch h l CnH2n+2-2a. Gi tr ca a cho bit: a.S vng no b.S lin kt pi c.S lin kt i d.S lin kt pi hoc lin kt i. Cu 285. Cho cng thc CnH2n+2-2k. ng vi ankin th gi tr ca n v k phi tha mn: a. n 1, k 2 b. n 1, k 1 c.. n 2, k 2 d. n 2, k 3 Cu 286. A c dng CnH2n+2-2k. A l anken th gi tr ca n v k phi tha mn: a. n 2, k 2 b. n 2, k 1 c. n 2, k 0 d. n 1, k 2 Cu 287. Cho a(g) CaC2 + H2O (d) V(lit) kh v dung dch A. trung ha dung dch A cn va dung dch cha 0,2 mol HCl 1. Gi tr ca V (ktc) l: a.1,12 (l) b.2,24 (l) c.3,36 (l) d.4,48 (l) 2. Gi tr ca a bng: a.6,4g b.10g c.12,8g d.18,2g 3. Khi lng nc tham gia phn ng l: a.6,4g b.4,6g c.3,6g d.6,3g
23

HCl Cl 2 288/ CH3-C CH A B (A;B l sn phm chnh).Vy A;B l: a.CH3-CCl=CH2 ;CH3-CH2-CH2-Cl b. CH3-CH=CHCl ;CH3-CHCl-CH2-Cl c. CH3-CCl2-CH2Cl ;CH3-CHCl=CH2 d. CH3-CHCl-CHCl2 ;CH3-CH=CH-Cl C ,600 C 289/ Cho 20 g CaC2 + H2O(d) Kh A 4,68 g benzenBit hiu sut phn ng to benzen l 60%. tinh khit t n l: a.90% b.92% c.94% d.96% o 290/ Oxi ho cht hu c A bi CuO,t C,(khng c khng kh)cho sn phm qua dd Ca(OH)2 d.Sau phn ng bnh tng 8,4 g v c 15 g kt ta .Khi lng CuO gim 6,4 g.Cng thc nguyn ca A l: a.(CH)n b.(C3H4)n c.(C4H7)n d.(C5H8)n 291/ t chy 2 ankin A,B k tip thu c V hi H2Ogp 0,6 ln th tch CO2 cng k.Cng thc A,B ln lt l: a.C2H2 v C3H4 b. C3H4 v C4H6 c. C4H6 v C5H8 d.C4H6 v C3H4 292/ Cho h hp gm 2 ankin C2H2 a mol v C3H4 b mol.Tnh gi tr s C trung bnh ca 2 ankin trn: a.2,5 b.2a+3b c.(2a+3b)/5 d.(2a+3b)/(a+b) 293/ Cho 2 HC CxHy(amol) v CnHm (b mol).S H trung bnh ca 2 HC trn l: a.(y+m)/2 b.ay+bm c.(ay+bm)/(x+n) d.(ay+bm)/(a+b) o 294/ 50 g t n cng nc 18,5 lt C2H2 (20 C;740mmHg).Hiu sut 100%(c tp cht).% tp cht c trong t n l: a.92% b.29% c.8% d.95% 295/ Cho 2 g ankin A phn ng va vi dd Br2 10% to hp cht no.CTPT ca A l: a.C2H2 b.C2H6 c.C4H6 d.C5H8 296/ Phn tch 0,02 mol A (cha C v Ag)ta c 17,6 g CO2 v 5,74 g AgCl.Cng thc phn t ca A l: a.C2Ag2 b.C3H3Ag c. C3H4Ag d. C3H2Ag2 297/ Cho 2 ankin A;B c MA < MB.T khi hi ca B i vi A l 1,35.Vy A,B ln lt l: a.axetilen;propin b.propin;axetilen c.butin;propin d.propin;butin 298/ Cho 4,1 g 1 ankin A (lng ,k thng)tc dng vi dd AgNO3/NH3 d ,sau phn ng thu c cht hu c nng hn ankin p l 5,35 g.Cng thc phn t ca ankin l: a.C4H6 b.C5H8 c.C6H10 d.C7H12 299/ Trong phn t benzen,cc nguyn t C u trng thi lai ho : a.sp b.sp2 c.sp3 d.sp2d 300Trong vng benzen mi nguyn t C dng 1 obitan p cha tham gia lai ho to ra : a.2 lin kt pi ring l b.2 lin kt pi ring l c.1 h lin kt pi chung cho 6 C d.1 h lin kt xigma chung cho 6 C 301/ Trong phn t benzen: a.6 nguyn t H v 6 C u nm trn 1 mt phng. b.6 nguyn t H nm trn cng 1 mt phng khc vi mp ca 6 C c.Ch c 6 C nm trong cng 1 mt phng. d. Ch c 6 H mm trong cng 1 mt phng. 302/ Cho cc CT :
o H

(1) (2) (3) Cu to no l ca benzen: a.(1) v (2) b.(1) v (3) c.(2) v (3) d.(1) ; (2) v (3) 303/ Dy ng ng ca benzen c cng thc chung l: a.CnH2n+6 ; n>=6 b. CnH2n-6 ; n>=3 c. CnH2n-6 ; n=<6 d. CnH2n-6 ; n>=6 304/ Cho cc cht C6H5CH3 (1) p-CH3C6H4C2H5 (2) C6H5C2H3 (3) o-CH3C6H4CH3 (4) Dy gm cc cht l ng ng ca benzen l: a.(1);(2) v (3) b.(2);(3) v (4) c.(1);(3) v (4) d.(1);(2) v (4)
CH3

305/ Cho cu to sau:C tn gi g sau y: a.o-xilen b.m-xilen c.p-xilen 306/ CH3C6H2C2H5 c tn gi l:

24

CH3

d.1,5-imetylbenzen

a.etyl,metylbenzen b. metyl,etylbenzen c.p-etyl,metylbenzen d.p-metyl,etylbenzen 307/ (CH3)2CHC6H5 c tn gi l: a.propylbenzen b.n-propylbenzen c.i-propylbenzen d.imetylbenzen 308/ Ankylbenzen l HC c cha : a.vng benzen b.gc ankyl v vng benzen c.gc ankyl v 1 benzen d.gc ankyl v 1 vng benzen 309/ iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen: a. v tr 1,2 gi l ortho b.1,4-para c.1,3-meta d.1,5-ortho 310/ t chy 16,2 g 1 cht hu c (A) thu c 1,2 mol CO2 ; 0,9 mol H2O. 150 < MA < 170.Cng thc phn t ca A l: a.C8H10 b.C9H12 c.C10H14 d.C12H18 311/Mt ankylbenzen A (C12H18)cu to c tnh i xng cao.A l: a.1,3,5-tri etylbenzen b. 1,2,4-tri etylbenzen c. 1,2,3-tri metylbenzen d. 1,2,3,4,5,6-hexaetylbenzen 312/ t chy hon ton m (g) A (CxHy) m g H2O 150 < MA < 170. Cng thc phn t ca A l: a.C4H6 b.C8H12 c.C16H24 d.C12H18 313/ t chy hon ton a (g) hp cht hu c A ch thu c CO2 v H2O.Trong khi lng H2O bng a g.Cng thc nguyn ca A l: a.(CH)n b.(C2H3)n c.(C3H4)n d.(C4H7)n 313. C7H8 c s ng phn thm l: a.1 b.2 c.3 d.4 314. A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A l: a.C3H4 b.C6H8 c.C9H12 d.C12H16 315. ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen? a.6 b.7 c.8 d.9 Cu 316. Mt ankylbenzen A c cng thc C9H12, cu to c tnh i xng cao. Vy A l: a.1, 2, 3 trimetyl benzen b.n propyl benzen c.i- propyl benzen d.1, 3, 5 trimetyl benzen Cu 317. A l dn xut benzen c cng thc nguyn (CH)n. 1 mol A cng ti a 4 mol H2 hoc 1 mol Br2(dd). Vy A l:a.etyl benzen b.metyl benzen c.vinyl benzen d.ankyl benzen Cu 318. Cc cht benzen, toluen, etyl benzen c nhit nng chy: a.bng nhau b.C6H6 < C6H5CH3 < C6H5C2H5 c.C6H6 > C6H5CH3 > C6H5C2H5 d.C6H6 < C6H5CH3 = C6H5C2H5 Cu 319. Tnh cht no sau y khng phi ca ankyl benzen a.Khng mu sc b.Khng mi v c.Khng tan trong nc d.Tan nhiu trong cc dung mi hu c Cu 320. Hot tnh sinh hc ca benzen, toluen l: a.Gy hi cho sc khe b.Khng gy hi cho sc khe c.Gy nh hng tt cho sc khe d.Ty thuc vo nhit c th gy hi hoc khng gy hi Cu 321. Tnh cht no khng phi ca benzen? a.Tc dng vi dung dch Br2 (Fe) b.Tc dng vi HNO3 /H2SO4() c.Tc dng vi dung dch KMnO4 d.Tc dng vi Cl2 (as) Cu 322. Tnh cht no khng phi ca toluen? a.Tc dng vi dung dch Br2 (Fe) b.Tc dng vi Cl2 (as) 0 c.Tc dng vi dung dch KMnO4, t d.Tc dng vi dung dch Br2 Cu 323. So vi benzen, toluen + ddHNO3/H2SO4 (): a.D hn, to ra o nitro toluen v p nitro toluen b.Kh hn, to ra o nitro toluen v p nitro toluen c.D hn, to ra o nitro toluen v m nitro toluen d.D hn, to ra m nitro toluen v p nitro toluen Cu 324. Toluen + Cl2 (as) xy ra phn ng: a.Cng vo vng benzen b.Th vo vng benzen, d dng hn c.Th nhnh, kh khn hn CH4 d.Th nhnh, d dng hn CH4 Cu 325. Tin hnh th nghim cho nitro benzen tc dng vi HNO3/H2SO4 (), nng ta thy: a.Khng c phn ng xy ra b.Phn ng d hn benzen, u tin v tr meta c.Phn ng kh hn benzen, u tin v tr meta d.Phn ng kh hn benzen, u tin v tr ortho Cu 326. Dy cc nhm th lm cho phn ng th vo vng benzen d dng hn v u tin v tr o- v pl: a.CnH2n+1, -OH, -NH2, b.OCH3, -NH2, -NO2 c.CH3, -NH2, -COOH d.NO2, -COOH, -SO3H
25

Cu 327. Dy gm cc nhm th lm cho phn ng th vo vng benzen d dng hn v u tin v tr ml: a.-CnH2n+1, -OH, -NH2 b.OCH3, -NH2, -NO2 c.CH3, -NH2, -COOH d.NO2, -COOH, -SO3H Cu 328. i-propyl benzen cn gi l: a.Toluen b.Stiren c.Cumen d.Xilen Cu 329. Phn ng no sau y khng xy ra: a.Benzen + Cl2 (as) b.Benzen + H2 (Ni, t0) c.Benzen + Br2 (dd) d.Benzen + HNO3 /H2SO4() Cu 330. Cho benzen + Cl2 (as) ta thu c dn xut clo A. Vy A l: a.C6H5Cl b.p-C6H4Cl2 c.C6H6Cl6 d.m-C6H4Cl2 Ni ,t Cu 331. A + 4 H2 etyl xiclo hexan. Cu to ca A l: a.C6H5CH2CH3 b.C6H5CH3 c.C6H5CH2CH=CH2 d.C6H5CH=CH2 Ni ,t Cu 332. B + 3H2 etyl benzen. B l: a. etyl benzen b. metyl benzen c. vinyl benzen d. ankyl benzen Cu 333. phn bit benzen, toluen, stiren ta ch dng 1 thuc th duy nht l: a.Brom (dd) b.Br2 (Fe) c.KMnO4 (dd) d.Br2 (dd) hoc KMnO4(dd) Cu 334. t chy hon ton 10,8g mt ankyl benzen A thu c 39,6g CO2. Cng thc phn t ca A l: a.C6H6 b.C8H8 c.C8H10 d.C9H12 Cu 335. t chy 10,8g A (CxHy) 10,8g H2O. A c cha 1 vng benzen. Cng thc phn t ca A l: a.C3H4 b.C6H8 c.C9H12 d.C12H16 Cu 336. Tnh cht no khng phi ca benzen? a.D th b.Kh cng c.Bn vi cht oxi ha d.Km bn vi cc cht oxi ha xt ,t Cu 337. A toluen + 4H2. Vy A l: a.metyl xiclo hexan b.metyl xiclo hexen c.n-hexan d.n-heptan Cu 338. Benzen + X etyl benzen. Vy X l a.axetilen b.etilen c.etyl clorua d.etan xt ,t Cu 339. C6H6 + Y etyl benzen + 4 HCl. Vy Y l: a.CH2ClCH2Cl b.CH2=CHCl c.CH3CH2Cl d.CH2=CH-CH2Cl Cu 340. ng dng no benzen khng c: a.Lm dung mi b.Tng hp monome c.Lm nhin liu d.Dng trc tip lm dc phm Cu 341. Thuc n TNT c iu ch trc tip t a.benzen b.metyl benzen c.vinyl benzen d.p-xilen Cu 342/ Cht no sau y c th cha vng benzen: a.C10H16 b. C9H14BrCl c. C8H6Cl2* d. C7H12 Cu 343/ Cu to ca 4-cloetylbenzen l:
o o o o
C2H5
C2H5

C2H5
C2H5 Cl

Cl a. b. c. d. Cu 344/ ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen? a.2 b.3 c.4 d.5 Cu 345/ Cht no sau y khng th cha vng benzen a.C8H10 b. C6H8 c. C8H10 d. C9H12 Cu 346/ Phn ng chng minh tnh cht no;khng no ca benzen ln lt l: a.th,cng b.cng,nitro ho c.chy,cng d.cng,brom ho Cu 347/ phn bit c cc cht Hex-1-in,Toluen,Benzen ta dng 1 thuc th duy nht l: a. dd AgNO3/NH3 b.dd Brom c.dd KMnO4 d.dd HCl Cu 348/ D phn bit d dng Hex-1-in,Hex-1-en,benzen ta ch dng 1 thuc th duy nht l: a. dd Brom b. dd AgNO3/NH3 c.dd [Ag(NH3)2]OH d.dd HCl Cu 349/ Phn ng no sau y khng dng iu ch Benzen: a.tam hp axetilen b.kh H2 ca xiclohexan c.kh H2,ng vng n-hexan d.tam hp etilen Cu 350/ Phn ng Benzen tc dng vi clo to C6H6Cl6 xy ra trong iu kin: a. c bt Fe xc tc b.c nh snh khuych tn c.c dung mi nc d.c dung mi CCl4 Cu 351/ Phn ng no khng iu ch c Toluen? AlCl ;t a.C6H6 + CH3Cl b. kh H2,ng vng benzen
Cl
Cl

26

c.kh H2 metylxiclohexan d.tam hp propin Cu 352/ Gc C6H5-CH2- c tn gi l: a.Phenyl b.Vinyl c.anlyl d.benzyl Cu 353/ Cho benzen vo 1 l ng Cl2 d ri a ra asng .Sau khi phn ng xy ra hon ton thu c 5,82 kg benzen.Tn ca sn phm v khi lng benzen tham gia phn ng l: a.clobenzen;1,56kg b.hexacloxiclohexan;1,65kg c.hexacloran;1,56kg d.hexaclobenzen;6,15kg Cu 354/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H 2O v V (l) CO2 (ktc).Gi tr ca V l: a.15,654 b.15,465 c.15,546 d.15,456 Cu 355/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H2O v CO2.Dn ton b lng CO2 vo 100ml dd NaOH 1M thu c m g mui.Gi tr ca m v thnh phn ca mui: a.64,78 g (2 mui) b.64,78g (Na2CO3) c.31,92g(NaHCO3) d.10,6g (Na2CO3) Cu 356/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c H2O v 30,36 g CO2 .Cng thc phn t ca A v B ln lt l: a.C8H10 ; C9H14 b. C8H10 ; C9H12 c. C8H12 ; C9H14 d. C8H14 ; C9H16 Cu 357/ t chy hon ton 12 g cht hu c A , ng ng ca benzen thu c 20,16 lt CO2 (ktc) Cng thc phn t ca A l: a. C9H12 b. C8H10 c. C7H8 d. C10H14 Cu 358/ t chy hon ton m g A ng ng ca benzen thu c 20,16 lt CO 2 (ktc) v 10,8 ml H2O (lng).Cng thc ca A l: a. C7H8 b. C8H10 c. C9H12 d. C10H14 Cu 359/ t chy hon ton 0,1 mol CxHy thu c 20,16 lt CO2 (ktc) v 10,8 g H2O (lng).Cng thc ca CxHy l: a. C7H8 b. C8H10 c. C10H14 d. C9H12 Cu 360/ Cho cc cht (1)benzen ; (2) toluen; (3)xiclohexan;(4)hex-5-trien; (5)xilen;(6) Cumen Dy gm cc HC thm l: a.(1);(2);(3);(4) b. (1);(2);(5;(6) c. (2);(3);(5) ;(6) d. (1);(5);(6);(4) as Cu 361/ 1 mol Toluen + 1 mol Cl2 A . A l: a.C6H5CH2Cl b. p-ClC6H4CH3 c. o-ClC6H4CH3 d.B v C u ng H SO d B + H2O. B l: Cu 362/ 1 mol nitrobenzen + 1 mol HNO3 t a.m-initrobenzen b. o-initrobenzen c. p-initrobenzen d.B v C u ng. Cu 363/ A(CxHy) l cht lng iu kin thng c dA/kk l 2,7. A chy mCO2 : mH2O = 4,9 : 1.Cng thc phn t ca A l:a. C7H8 b. C6H6 c. C10H14 d. C9H12 Cu 364/ Stiren khng phn ng c vi nhng cht no sau y: a.dd Br2 b.khh H2 ,Ni,to c.dd KMnO4 d.dd NaOH Cu 365/ Hiro ho etylbenzen ta c stiren;trng hp stiren ta c polistiren vi hiu sut chung 80%.Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l: a.13,52 tn b.10,6 tn c.13,25 tn d.8,48 tn Cu 366/ t chy hon ton hi A(CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi.Cng thc phn t ca A l: a. C7H8 b. C8H10 c. C10H14 d. C9H12 Cu 367/ t chy hon ton 1,3 g A(CxHy) 0,9 g H2O .Cng thc nguyn ca A l: a.(CH)n b.(C2H3)n c.(C3H4)n d.(C4H7)n Cu 368/ A t 1 hp cht vng c to thnh t s trng hp axetilen,dA/kk l 3,59.C.thc phn t A l: a. C8H8 b. C6H6 c. C10H14 d. C4H4 Cu 369/ A c cng thc phn t l C8H8 ,tc dng vi dd KMnO4 nhit thng to ra ancol 2 chc.1 mol A tc dng ti a vi: a.4 mol H2; 1 mol brom b. 3 mol H2; 1 mol brom c.3 mol H2; 3 mol brom d. 4 mol H2; 4 mol brom Cu 370/ 5,2 g stiren b trng hp 1 phn tc dng va vi dd cha 0,0125 mol brom.Lng stiren cha b trng hp l: a.25% b.50% c.52% d.75% Cu 371/ 1 ankylbenzen A(C9H12),tc dng vi HNO3 c (c xt H2SO4 ) theo t l mol 1:1 to ra 1 dn xut mononitro duy nht . Vy A l: a. n-propylbenzen b.p-etyl,metylbenzen c.i-propylbenzen d.1,3,5trimetylbenzen* trung / hop Cu 372/ Cho phn ng A 1,3,5-trimetylbenzen .A l:
2 o 4

27

a.axetilen b.metyl axetilen c.etyl axetilen d.imetyl axetilen Cu 373/ Cho A(CxHy) l 1 cht kh kthng .t chy hon ton 1 lng cht A thu c 1 sn phm cha 76,52% CO2 v khi lng.Cng thc phn t ca A l: a. C2H6 b. C3H6 c. C4H6 d. C6H6 Cu 373/ A l 1 HC mch h , cht kh iu kin thng .4,48 lt kh A ktc tc dng va vi 0,4 mol Brom to ra sn phm B cha 85,562% brom v khi lng. Cng thc phn t ca A l: a. C2H6 b. C3H6 c. C4H6 d. C6H6 Cu 374/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi stiren ,gi tr ca n v a ln lt l: a. 8 v 5 b.5 v 8 c.8 v 4d .4 v 8 Cu 375/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi naptalen ,gi tr ca n v a ln lt l: a.10 v 5 b.10 v 6 c.10 v 7 d.10 v 8 Cu 376/ Benzen A o-brom-nitrobenzen.Cng thc ca A l: a.nitrobenzen b.brombenzen c.aminobenzen d.o-ibrombenzen Cu 377/ C2H2 A B m-brombenzen .A v B ln lt l: a.benzen ; nitrobenzen b.benzen,brombenzen c. nitrobenzen ; benzen d. nitrobenzen; brombenzen Cu 378/ Phn ng ng trng hp gia stiren v buta-1,3-ien to ra sn phm l: a.cao su buna b.cao su buna-N c.cao su buna-S d.cao su isopren Cu 379/ Hn hp gm C2H2 v HCl c t l mol tng ng 1:1,5 i vi 1 hn hp ,trong iu kin thch hp ,hiu sut 100%;sau phn ng to ra cht g? a.1mol C2H3Cl ; 0,5 mol HCl b. 1mol C2H3Cl ; 0,5 mol C2H4Cl2 c. 0,5mol C2H3Cl ; 0,5 mol C2H4Cl2 d. 0,5mol C2H3Cl ; 1 mol C2H4Cl2 Cu 380/ Hn hp C6H6 v Cl2 c t l mol 1:1,5.Trong iu kin c xc tc bt Fe,to ,hiu sut 100%.Sau phn ng thu c cht g ? bao nhiu mol? a.1 mol C6H5Cl ; 1 mol HCl ; 1 mol C 6H4Cl2 b. 1,5 mol C 6H5Cl ; 1,5 mol HCl ; 0,5mol C6H4Cl2 c. 1 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2 d. 0,5 mol C6H5Cl ; 1,5 mol HCl ; 1 mol C6H4Cl2 Cu 381/ Cho m g HC (A) chy thu c 0,396 g CO2 v 0,108 g H2O.Trng hp 3 phn t A thu c cht B l ng ng ca benzen.A v B thuc dy no sau? a.A,B u l ankin b.A,B u l ankylbenben c.A:ankylbenzen;B:ankin d. A:ankin ; B:ankylbenzen* Cu 382/ Cho a g cht A(CxHy) chy thu c 13,2 g CO2 v 3,6 g H2O.Tam hp A thu c B,mt ng ng ca ankin benzen.Cng thc phn t ca A v B ln lt l: a.C3H6 v C9H8 b. C2H2 v C6H6 c. C3H4 v C9H12 d. C9H12 v C3H4 Cu 383/ 1 mol HC A(C6H6) tc dng vi dd AgNO3/NH3 theo t l mol nA : nAgNO3 = 1:2.Vy A l: a.benzen b.hexaien c.hexaiin d.xiclohexin Cu 384/ Mt cht hu c A c mC:mH:mCl = 1,2 : 0.1 : 3,55.Phn t c vng 6 cnh.Vy A l: a.hexacolran b.hexacloxiclohexan c.hexaclobenzen d.a,b,c u ng Cu 385/ t 0,13 g mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 g H2O.d A/B l 3; d B/C2H4 l 0,5.Cng thc ca A v B ln lt l: a.C2H2 v C6H6 b. C6H6 v C2H2 c. C2H2 v C4H4 d. C6H6 v C8H8 Cu 386/ 1,3 g cht hu c A chy hon ton thu c 4,4 g CO2 v 0,9 g H2O.T khi hi ca A i vi oxi(d) tho mn iu kin 3<d<3,5.Cng thc phn t ca A l: a.C2H2 b.C8H8 c.C4H4 d.C6H6 Cu 387/ Cho 120 t n khng nguyn cht tc dng hon ton vi H2O thu c kh A.Chuyn kh A thnh benzen vi hiu sut 60%,thu c 26 ml benzen(d=0,9 g/ml)% khi lng tp cht trong t n l: Cu 1. Cho cc hp cht c cng thc phn t l C2H2On. Vi n nhn cc gi tr no th cc hp cht l hp cht no a chc? A. 2 v 3 B. 1 v 2 C. 2 v 4 D. 1 v 3 Cu 2. Khi tch nc t mt cht X c cng thc phn t C5H10O thu c isopren l sn phm duy nht. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 4 C. 1 D. 3 Cu 3. Dy cc cht tc dng vi fomanehit l: A. Mg, NaOH; Ag2O/ NH3 (hoc AgNO3/NH3) B. phenol, Ag2O/ NH3 (hoc AgNO3/NH3) ; kh C. axit axetic, Cu(OH)2/NaOH v ru etylic D. Na, NaOH v Ag2O/ NH3 (hoc AgNO3/NH3)
28

Cu 4. Este X c cng thc phn t l C4H8O2. un nng X vi KOH thu c mui c phn t khi nh hn phn t khi ca X. Vy X c th l: A. metyl propionat B. n-propyl fomiat C. etyl axetat D. iso-propyl axetat Cu 5. C cc cht sau: ru etylic, axit axetic, phenol, anilin, NaOH v dd Br2. S cp cht tc dng c vi nhau l: A. 4 B. 7 C. 5 D. 6 Cu 6. Hirat ha anken X thu c ru Y duy nht. Oxi ha ru Y bng O2 (xt Cu,t0) thu c cht hu c Z. Z c phn t khi gp 1,2857 ln phn t khi ca X. Hy cho bit c bao nhiu anken c th l X? A. 1 B. 3 C. 2 D. 4 Cu 7. Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l: A. CH3COO-CH=CH2 B. HCOO-C(CH3)=CH2 C. CH2=CH-COO-CH3 D. HCOO-CH=CH-CH3 Cu 8. Dy gm cc cht tc dng vi ru etylic l: A. Na, NaOH v HBr B. HBr, CuO v Na C. CuO, KOH, HBr D. CH3COOH, Na v NaOH Cu 9. Trong cc phn ng sau, c bao nhiu phn ng khng xy ra? (1) CO2 + H2O + C6H5ONa (2) C6H5OH + NaOH (3) CH3COOH + Cu(OH)2 (4) C3H5(OH)3 + Cu(OH)2 (5) C6H5NH3Cl + AgNO3 (6) CO2 + H2O + CH3COONa (7) CH3COOH + C6H5OH (8) C6H5OH + HCHO A. 2 B. 1 C. 4 D. 3 Cu 10. Cht X c cng thc phn t l C5H8O2. un nng X vi NaOH thu c mui Y v cht hu c Z. Z tc dng vi Br2 (dd) thu c cht hu c G. un nng G trong NaOH thu c mt hp cht a chc. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 5 C. 3 D. 4 Cu 11. Thuc th phn bit cc dung dch axit acrylic, ru etylic, axit axetic, natri axetat v natri phenolat ng trong cc l mt nhn l: A. qu tm, dd Br2 B. qu tm, dd NaOH C. qu tm, Cu(OH)2 D. qu tm, dd Na2CO3 Cu 12. Dy gm cc cht c th s dng iu ch trc tip axit axetic l: A. glucoz, anehit axetic v etyl axetat B. ru etylic, anehit axetic, etylen C. anehit axetic, natri axetat v ru etylic D. n-butan, ru etylic, axetilen Cu 13. C th s dng dung dch Br2 phn bit dy cc ha cht no sau y? A. natri phenolat, phenol, ru etylic B. toluen, benzen, anilin C. benzen, anilin, phenol D. stiren, phenol, benzen Cu 14. Dy cht no sau y xut hin kt ta trng khi cho tc dng vi dung dch Br2? A. p-crezol, anilin v natri phenolat B. axit picric, aniin v p-crezol. C. axit phenic, toluen, anilin D. phenyl amoni clorua, benzen v p-crezol Cu 15. Cho cc cht mch h c cng thc phn t l C4H8O2 tc dng vi Cu(OH)2 (nhit thng) v NaHCO3 th c bao nhiu phn ng xy ra? A. 3 B. 5 C. 4 D. 2 Cu 16. chng minh nh hng qua li gia nhm -OH v vng benzen trong phenol, cn cho phenol tc dng vi cht no sau y? A. dd Br2 v qu tm B. Na v dd Br2 C. dd NaOH, dd Br2 D. dd HCl v dd NaOH Cu 17. X phng ha este X trong NaOH thu c mui ca axit l ng ng ca axit fomic v ru Y. hirat ha ru Y thu c 3 anken. Vy cng thc phn t tng qut ca X l: A. CnH2nO2 (n 6) B. CnH2n-2O2 (n 8) C. CnH2nO2 (n 4) D. CnH2nO2 (n 5) C6H6 Y anilin. Vi X, Y ln lt l: Cu 18. Cho s sau: X A. CH4, C6H5NO2 B. xiclohexan, C6H5CH3 C. C2H2, C6H5CH3 D. C2H2, C6H5NO2 Cu 19. Dy cc cht no sau y i mu qu tm sang xanh? A. natri axetat, imetyl amin, NaOH B. phenol, natri axetat v phenyl amoni clorua C. glixerin, natri metylat, anilin D. metyl amin, natri phenolat, ru eylic
29

Cu 20. Cho s chuyn ho: Glucoz X Y Z CH3COOH. Hai cht X, Y ln lt l: A. CH3CHO v CH3CH2OH B. CH3CH2OH v CH3COONa C. CH3CH2OH v CH3CHO D. CH3CH2OH v CH3CH2Cl Cu 21. Cht X c cng thc phn t l C7H8O. X tc dng vi NaOH. Khi cho tc dng vi brom thu c kt ta Y c phn t khi l 266. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 4 C. 3 D. 1 Cu 22. Cho 7,6 gam hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng tc dng vi dung dch HCl d thu c 14,9 gam hn hp mui. Xc nh % khi lng ca amin nh trong hn hp? A. 37,85 B. 56,45 C. 40,79% D. 28,66 Cu 23. Dy gm cc cht u tc dng vi Ag2O (hoc AgNO3) trong dung dch NH3 l: A. anehit axetic, axetilen, butin-2 B. anehit fomic, axetilen, etilen C. axit fomic, vinylaxetilen, propin D. anehit axetic, butin-1, etilen Cu 24. Khi thc hin phn ng tch nc i vi ru X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 4,48 lt CO2 (ktc) v 4,5 gam nc.C bao nhiu cng thc cu to ph hp vi X? A. 3 B. 2 C. 4 D. 5 polime Y polime Z. Bit rng X, Y, Z u cha cc nguyn t C, Cu 25. Cho s bin ha sau:X H,O. Hy cho bit X c th l cht no sau y? A. vinyl axetat B. metyl metacrylat C. metyl acrylat D. axit acrylic Cu 26. Cho vinyl axetat tc dng vi Br2 thu c cht hu c Y. un nng Y trong dung dch NaOH long (va ) thu c dung dch cha 2 mui v cht hu c Y1. Hy cho bit Y1 l cht no sau y? A. HO-CH2-CH=O B. CH3CH=O C. CH3CH2OH D. O=CH-CH=O Cu 27. Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l: A. CH3COOH B. HCC-COOH C. CH3-CH2-COOH D. CH2=CH-COOH Cu 28. Dy gm cc cht c th iu ch trc tip t ru etylic l: A. anehit axetic, etilen v glucoz B. cao su buna, axit axetic v etyl axetat C. butaien-1,3; axit axetic v etyl nitrat D. anehit axetic, axit axetic v polietilen Cu 29. Cho m gam hn hp X gm etyl axetat, metyl axetat v etyl propionat tc dng va vi 100 ml dung dch NaOH 1,2M. Mt khc, t chy hon ton m gam hn hp X sau cho sn phm chy vo dung dch nc vi trong d thu c 30 gam kt ta. Vy gi tr ca m l: A. 7,4 gam B. 9,25gam C. 8,04 gam D. 10,2 Cu 30. Cht X mch h c cng thc phn t l C4H6O2. X khng tc dng vi NaHCO3.Hiro ha X thu c cht hu c Y. Y tc dng vi Cu(OH)2 nhit thng. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 4 C. 5 D. 3 Cu 31. C bao nhiu este no n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 40%? A. 4 B. 2 C. 3 D. 1 Cu 32. Hiro ha hon ton anehit X thu c ru Y. t chy hon ton Y thu c CO2 v H2O theo t l nCO2 : nH2O = 2: 3 v s mol O2 t chy gp 2,5 ln s mol X t chy. Khi cho 0,1 mol X tc dng vi Ag2O d (hoc AgNO3 ) trong dung dch NH3 thu c ti a bao nhiu gam Ag? A. 32,4 gam B. 43,2 gam C. 21,6 gam D. 10,8 gam Cu 33. S sp xp no sau y ng vi chiu tng dn tnh axit ca cc axit c cng thc phn t sau: C2H4O2 (X); C3H6O2 (Y); C3H4O2 (Z) v C2H2O4 (G)? A. Y < X < G < Z B. X < Y < Z < G C. X < G < Y < Z D. Y < X < Z < G Cu 34. Dy no bao gm cc cht c sp xp theo chiu tng dn nhit si ca cc cht? A. axit axetic, metyl fomiat, natri fomiat B. etyl amin, ru etylic, axit axetic C. ru etylic, axit fomic, anehit axetic D. imetyl amin, imetyl ete, ru etylic Cu 35. Amin X n chc c cha vng benzen. X tc dng vi HCl thu c mui Y c cng thc dng RNH2Cl. Khi cho Y tc dng vi AgNO3 thu c kt ta c khi lng ng bng khi lng Y phn ng. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 4 C. 3 D. 1
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Cu 36. un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l: A. 55,55% B. 62,5% C. 41,67% D. 75% Cu 37. Cho 2,9 gam mt anehit phn ng hon ton vi lng d Ag2O (hoc AgNO3) trong dung dch NH3 thu c 10,8 gam Ag. Cng thc cu to thu gn ca anehit l: A. O=HC-CH=O B. CH3CH2CH=O C. CH2=CH-CH=O D. HCH=O Cu 38. Thc hin phn ng este ha gia 7,5 gam mt axit n chc v 5,75 gam mt ru n chc thu c 8,8 gam este. Bit hiu sut phn ng este ha t 80%. Bit rng ban u s mol ru bng s mol axit. Vy este thu c l: A. metyl axetat B. metyl fomiat C. etyl propionat D. etyl axetat Cu 39. Mt hn hp gm 2 phenol n chc hn km nhau mt nguyn t cacbon trong phn t. Cho 0,1 mol hn hp tc dng vi brom (dd) thy c 0,3 mol Br2 phn ng v thu c 33,94 gam kt ta. Bit rng mch nhnh ca vng benzen no. Vy 2 cht trong hn hp X l : A. phenol v m-crezol B. phenol v p-crezol C. phenol v o-crezol D. mcrezol v m-etylphenol Cu 40. X l este to t axit n chc v ru a chc. X khng tc dng vi Na. t chy hon 8,72 gam este X thu c 15,84 gam CO2 v 5,04 gam H2O. Vy cng thc phn t ca X l: A. C6H8O6 B. C9H14O6 C. C6H10O4 D. C4H6O4 Cu 41. hirat ha 2 ru ch thu oc 1 anken. Hai ru l: A. n-butylic v iso-butylic B. sec-butylic v iso-butylic C. sec-butylic v n-butylic D. iso-butylic v tert-butylic Cu 42. Cho 6,96 gam anehit X n chc, mch h phn ng vi lng d Ag2O trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 1,792 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l: A. CH2=CH-CH=O B. CH3CH2CH=O C. HCH=O D. CH3CH=O Cu 43. Thc hin phn ng oxi ha m gam ru etylic nguyn cht thnh axit axetic (hiu sut phn ng t 75%) thu c hn hp Y. Cho Y tc dng vi Na d thu c 3,92 lt H2 (ktc). Xc nh m A. 16,1 gam B. 6,9 gam C. 8,05 gam D. 9,2 gam Cu 44. Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l: A. H-CH=O B. CH3-CH(OH)-CH=O C. O=CH-CH=O D. CH3-CH=O Cu 45. Este X c cha vng benzen v c cng thc phn t l C8H8O2. un nng 0,1mol X trong 200 ml dung dch NaOH 1M, sau phn ng hon ton c cn dung dch sau phn ng th thu c 19,8 gam hn hp cht rn gm 2 mui khan. Hy cho bit c bao nhiu este tha mn iu kin ? A. 3 B. 2 C. 4 D. 5 Cu 46. t chy hon ton a mol axit X thu c a mol H2O. trung ha dung dch cha a mol X cn 500 ml dung dch NaOH nng 2a M. Vy axit X c th l: A. HOOC-CC-COOH B. CH2=CH-COOH C. HCOOH D. HOOC-COOH Cu 47. Cho hn hp X gm hai cht hu c n chc c cng cng thc phn t C2H4O2 tc dng va vi dung dch NaOH v un nng. C cn cn thn dung dch sau phn ng thu c 15,35gam cht rn v b gam ru. Cho ru tc dng vi CuO chuyn ha ht thnh anehit. Ly lng anehit thu c cho tc dng vi Ag2O d trong NH3 thu c 32,4 gam Ag. Vy khi lng hn hp X ban u l: A. 11,5 gam B. 16,0 gam C. 12,0 gam D. 9,0 gam Cu 48. Hp cht X c phn t khi l 60. Cho 6,0 gam X tc dng vi Na thu c 1,12 lt H2 (ktc). Hy cho bit X c bao nhiu cng thc cu to? A. 4 B. 5 C. 3 D. 2 Cu 49. t chy hon ton a mol axit X thu c a mol H2O. trung ha dung dch cha a mol X cn 500 ml dung dch NaOH nng 2a M. Vy axit X c th l: A. CH2=CH-COOH B. HOOC-COOH C. HCOOH D. HOOC-CC-COOH Cu 50. Cho 11,4 gam ru X tc dng va vi 6,9 gam Na. Oxi ha X thu c anehit Y (ch cha mt loi nhm chc). Cho 0,1 mol Y tc dng vi Ag2O d trong NH3 thu c 43,2 gam Ag. Cng thc
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cu to thu gn ca Y l: A. CH3-CH2-CH=O B. HCH=O C. O=CH-CH2-CH=O D. O=CHCH=O 1. Co bao nhieu ankan ong phan cau tao co cong thc phan t C5H12? A. 3 ong phan B. 4 ong phan C. 5 ong phan D. 6 ong phan 2. Theo chieu tang so nguyen t cacbon trong phan t , phan tram khoi lng cacbon trong phan t anken A. Tang dan B. giam dan C. khong oi D. bien oi khong theo quy luat 3. Theo chieu tang so nguyen t cacbon trong phan t, phan tram khoi lng cacbon trong phan t ankin.A. Tang dan B. Giam dan C. Khong oi D. Bien oi khong theo quy luat 4. ng vi cong thc phan t C4H8 co bao nhieu ong phan cau tao eu tac dung c vi hidro?A. 2 B. 3 C. 5 D. 6 5. Anken CH3CH=CHCH2CH3 co ten la A. metylbut-2-en B. pent-3-en C. pent-2-en D. but-2-en 6. Phan tram khoi lng cacbon trong phan t ankan Y bang 83,33% . Cong thc phan t cua Y la : A. C2H6 B. C3H8 C. C4H10 D. C5H12 7. Phn ng c trng ca hidrocacbon no A. Phn ng tch B. Phn ng th C. Phn ng cng D. C A, B v C. 8. Cong thc n gian nhat cua hidrocacbon M la CxH2x+1. M thuoc day ong ang nao? A. ankan B. khong u d kien e xac nh C. ankan hoac xicloankan D. xicloankan 9. Bng phn ng no chng t bezen c tnh cht ca hirocacbon no? A.Phn ng vi dung dch nc brom. B.Phn ng th vi brom hi C.phn ng nitro ha D.c B v C 10. Phn ng no sau y chng t bezen c tnh cht ca hirocacbon khng no ? A.Phn ng vi hiro B.Phn ng vi dung dch nc brom C.Phn ng vi clo c chiu sng D. c A v C 11. Tien hanh clo hoa 3-metylpentan t le 1:1 thu c bao nhieu dan xuat monoclo la ong phan cua nhau? A. 4 B. 5 C. 2 D. 3 12. Khi cho butan tac dung vi brom thu c san pham monobrom nao sau ay la san pham chnh? A. CH3CH2CH2CH2Br B. CH3CH2CHBrCH3 C.CH3CH2CH2CHBr2 D. CH3CH2CBr2CH3. 13. Hidrocacbon X co CTPT C5H12 khi tac dung vi Clo tao c 3 dan xuat monoclo ong phan cua nhau. X la: A. iso-pentan B. n-pentan C. neo-pentan D. 2-metyl butan 14. Ankan X co cong thc phan t C5H12, khi tac dung vi clo tao c 4 dan xuat monoclo. Ten cua X la A. pentan B. iso-pentan C. neopentan D.2,2- dimetylpropan
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15. Brom hoa ankan ch tao mot dan xuat monobrom Y duy nhat. dY/ khng kh = 5,207. Ankan X co ten la: A. n- pentan B. iso-butan C. isopentan D. neo-pentan 16. Phan tch 3 g ankan cho 2,4g cacbon . CTPT cua A la g ? A. CH4 B.C2H6 C. C3H8 D. ket qua khac 17. Mot ankan tao c dan xuat monoclo, trong o ham lng clo bang 55,04%. Ankan co CTPT la A. CH4 B. C2H6 C.C3H8 D. C4H10 18. Khi phan huy hoan toan hidrocacbon X trong ieu kien khong co khong kh, thu c san pham co the tch tang gap 3 lan the tch hidrocacbon X ( cung ieu kien ) . Cong thc phan t cua X la : A. C2H6 B. C4H10 C. C5H12 D. C6H14 19. ot chay hoan toan 0,15 mol hon hp 2 ankan thu c 9,45g H2O. Cho san pham chay qua bnh ng Ca(OH)2 d th khoi lng ket tua thu c la bao nhieu ? A.37,5g B. 52,5g C. 15g D.42,5g 20. Trong Phong th nghiem co the ieu che mot lng nho kh etilen theo cach nao sau ay? A. e hidro hoa etan B. un soi hon hp gom etanol vi axit O H2SO4, 170 C. C. Crackinh butan. D. Cho axetilen tac dung vi hidro co xuc tac la Pd/PbCO3. 21. e tach rieng metan khoi hon hp vi etilen va kh SO2 co the dan hon hp vao: A. dd Natrihidroxit B. dd axit H2SO4 C. dd nc brom D. dd HCl 12. Co bao nhieu anken ong phan cau tao cua nhau khi cong hidro eu tao thanh 2- metylbutan? A. 1 B. 2 C. 3 D. 4 23. Cho bit sn phm chnh ca phn ng sau: CH2 = CHCH2CH3 + HCl ?. A. CH3 CHClCH2CH3. B. CH2 = CHCH2CH2Cl. C. CH2 ClCH2CH2CH3. D. CH2 = CHCHClCH3. 24. Hidrocacbon A va B thuoc cung mot day ong ang. Biet MA = 2MB. A va B thuoc day ong ang nao? A. Anken hoac xicloankan B. Aren C. Co the thuoc bat ky day nao. D. Anken 25. ot chay hoan toan 1,12 lt mot anken X (ktc) thu c 5,60 lt kh CO 2 (ktc). CTPT X la: A. C3H6 B.C4H8 C. C4H10 D. C5H10 26. ot chay hoan toan mot the tch hon hp gom anken X va hidrocacbon Y thu c 5,56 lt kh CO2 ( ktc) va 5,40 g nc. Y thuoc loai hirocacbon co cong thc phan t dang. A.CnH2n B.CnH2n-2 C. CnH2n+2 D. CnH2n-4 27. Co bao nhieu ong phan cua ankin nhau khi cong hidro d, xuc tac niken, to tao thanh 3-metylhexan? A. 2 B. 3 C. 4 D. 5
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28. Ankaien la ong phan cau tao cua: A. ankan B. anken C. ankin D. xicloankan 29. Co bao nhieu hirocacbon mach h khi cong hiro tao thanh butan?A. 2 B. 3 C.5 D. 6 30. S ankin ng vi cng thc phn t C6H10 tc dng vi dung dch AgNO3/NH3 l:A. 1.B. 2 C. 3. D. 4 31. Trong phan t ankin X, hidro chiem 11,765% khoi lng . Cong thc phan t cua X la : A. C2H2 B. C3H4 C. C4H6 D. C5H8 32. ot chay hoan toan 1,3g ankin X thu c 2,24 lt kh CO 2 (ktc) . Cong thc phan t cua X la : A. C2H2 B. C3H4 C.C4H6 D. C5H8 33. ot chay hoan toan 5,4g ankaien X thu c 8,96 lt kh CO2 ( ktc) . Cong thc phan t cua X la A. C4H4 B. C4H8 C.C4H6 D. C4H10 34. Cho 2,24 lt hon hp kh X ( ktc) gom axetilen va etilen suc cham qua dung dch AgNO3 trong NH3 (lay d ) thay co 6g ket tua. Phan tram the tch cua kh etilen trong hon hp bang A. 75% B. 40% C.50% D. 25% 35. ot chay hoan toan hon hp kh gom ankin X va hidrocacbon Y mach h co cung so nguyen t C, thu c san pham chay co the tch hi nc bang the tch kh CO2 (cac the tch o cung ieu kien). Y thuoc loai A.ankin B. anken C. xicloankan D. ankan 36. ot chay 1 so mol nh nhau cua 3 hidrocacbon A, B, C thu c lng CO 2 nh nhau, con t le so mol CO2 va H2O oi vi A, B, C lan lt la 0,5: 1:1,5. CTPT cua A, B, C A. CH4, C2H6, C3H8 B. C2H4, C3H6, C4H8 C. C2H2, C2H4, C2H6 D. C2H6, C 2 H 4 , C 2 H2 37. Tnh thm ca benzen c th hin iu no ? A. D tham gia phn ng th B.Kh tham gia phn ng cng C.Bn vng vi cht oxi ha. D.Tt c cc l do trn 38. Trong cc cht sau y, cht no l ng ng ca benzen: 1, Toluen 2, etylbezen 3, pxylen 4, Stiren A. 1 B. 1, 2, 3, 4 C. 1, 2,3 D. 1, 2 39. iu no sau y sai khi ni v toluen ? A.L 1 hirocacbon thm B.C mi thm nh C.L ng phn ca benzen D.Tan nhiu trong dung mi hu c 40.ng vi cng thc phn t C8H10 c bao nhiu ng phn hirocacbon thm?A. 2 B. 3 C. 4 D. 5 41. Co bao nhiu ng phn la dn xut cua benzen ng vi cng thc phn t C9H10 :A. 4 B. 5 C. 6 D. 7 42. Phn ng ca benzen vi cht no sau y gi l phn ng nitro ha ? A. HNO3 /H2SO4 B. HNO2 /H2SO4 C. HNO3 long /H2SO4 D. HNO3 43. Sn phm chnh khi oxi ha ankylbenzen bng dung dch KMnO4 l: A. C6H5COOH B. C6H5CH2COOH C. C6H5CH2CH2COOH D. CO2
34

44. Cac chat nao cho sau co the tham gia p/ the vi Cl2 (as) ? A.etin,butan,isopentan B.propan,toluen, xiclopentan C.xiclopropan,stiren,isobutan D.metan,benzen, xiclohexan 45. Khi trong phn t benzen c sn cc nhm th nh: -NH2, -OH, ankyl, cc nhm halogen th cc nhm th tip theo s nh hng u tin vo cc v tr no so vi nhm th th 1 : A. Octo v mta B. mta v para C. ch duy nht para D. octo v para 46. T benzen e thu c m-bromnitrobenzen phai tien hanh lan lt cac p/ vi nhng tac nhan nao sau? A. HNO3 loang, Br2 ( xt: Fe, t0) B. Br2 ( xt: Fe, t0) , HNO3 (xt: H2SO4,t0) C. HNO3(xt: H2SO4,t0) , Br2 ( xt: Fe, t0) D. HNO3(xt: H2SO4,t0) , Br2 ( As) 47. Sn phm dinitrobezen no (nu sau y) c u tin to ra khi cho nitrobebzen tc dng vi hn hp gm HNO3 c v H2SO4 c? A.o dinitrobezen B.m dinitrobezen C.p dinitrobezen D.c A v C 48. Sn phm iclobezen no ( nu sau y) c u tin to ra khi cho clobebzen tc dng vi clo c bt Fe un nng lm xc tc?A.o iclobezen B.m iclobezen C.p icloobezen D.c A v C 49. Hin tng g xy ra khi cho bromlng vo ng nghim cha benzen, lc ri yn ? A.dd brom b mt mu. B.C kh thot ra C.Xut hin kt ta D.dd brom khng b mt mu 50. Hin tng g xy ra khi un nng toluen vi dung dch thuc tm ? A.Dung dch KMnO4 b mt mu B. C kt ta trng C. C si bt kh D.Khng c hin tng g 51. Chat nao sau ay lam mat mau nc brom? A. stiren, butadien-1,3, isopentin, etylen B. isopropylbenzen, pentin-2, propylen C. xiclopropan, benzen, isobutylen, propin D. toluen, axetylen, butin1, propen 52. Thnh phn chnh ca kh thin nhin l:A. H2 B. CH4 C. C2H4 D. CO 53.Thnh phn ch yu ca kh l cc :A. H2 v CO B. H2 v CH4 C. H2 v CO2 D. H2 v C 2 H6 54.Dng nc brom lm thuc th c th phn bit c cp cht no sau y ? A. Metan v etan B.Toluen v stiren C. Etilen v propilen D. Etilen v stiren 55. Hirocacbon thm X c phn trm khi lng H xp x 7,7%. X tc dng c vi dung dch brom. Cng thc no sau y l cng thc phn t ca C? A. C7H8 B. C8H10 C. C6H6 D. C8H8 56. Mt hirocacbon thm A c thnh phn %C trong phn t l: 90,57%. CTPT ca A l: A. C6H6 B. C8H10 C. C7H8 D. C9H12 57. Khi phn tch thnh phn nguyn t ca hirocacbon Y cho kt qu %H=9,44 %, %C=90,56 %. Y ch tc dng vi brom theo t l 1:1 un nng c bt Fe xc tc. Y c cng thc phn t l: A. C8H10. B. C9H12. C. C8H8. D. Kt qu khc. 58. t 0,78g cht hu c X hoc Y u thu c 1,344 lt CO2 (ktc) v 0,54g H2O; dX/Y =3. X v Y c cng thc phn t ln lt l: A. C6H12 v C2H6. B. C6H12 v C2H4 C. C6H6 v C2H2 D. Kt qu khc.
35

59. t chy hirocacbon X ngi ta thu c CO2 v H2O theo t l mCO2 : mH2O = 22: 4,5. Bit X khng lm mt mu dung dch brom. X l hirocacbon no trong s cc hirocacbon sau y: A. CH3-CH3 B. CH CH. C. CH2=CH2. D. Benzen 60. Cho 100ml benzen (D=0,879g/ml) tc dng vi brom lng (D=3,1g/ml) v bt st iu ch brombenzen. Th tch brom cn dng l: A. 59,68ml. B. 68,168ml. C. 58,164ml. D. 34,184ml. 61. Cho clo tc dng vi 78g benzen (bt st lm xc tc) thu c 78g clobenzen. Hiu sut ca phn ng l: A. 71%. B. 65%. C. 69,33%. D. 75,33%. 62. Sn phm chnh thu c khi cho 2-clo but-2-en tc dng vi HBr c tn thay th l: A.1-brom-3-clobutan B. 2-brom-3-clobutan C. 2-brom-2-clobutan D. 2-clo-3brombutan 63.Cho ancol (CH3)2C(OH)CH2CH3, bc ca ancol l : A. 1 B. 2 C. 3 D. 4 0 64. Khi oxi ho mt ancol X bng CuO (t ) ta thu c mt Xeton tng ng. Vy A l ancol bc A. I B. II C. III D. I hoc II 65. Cht hu c C5H12O c s ng phn nh sau A. 3 ete , 3 ancol B. 3 ete , 6 ancol C. 6 ete , 8 ancol D. 4 ete , 8 ancol 66. S ng phn ca C4H10O tc dng vi CuO un nng to Xeton l: A. 2 B. 3 C. 4 D. 1 67. Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ? A. 3-Metylbut-1-en B. 2-Metylbut-1en C. 3-Metylbut-2-en D. 2-Metylbut-2-en 68.Cht no sau y c nhit si cao nht ? A. CH3 - CH2 - OH B. CH3 - CH2 - CH2 - OH C. CH3 - CH2 - Cl D. CH3 - O-CH3 69. Ancol no sau y khi tch nc thu c sn phm chnh l but-2-en? A. butan-3-ol B. butan-1-ol C. butan-2-ol D. C A, v C 0 70. un hh 3 ancol n chc vi H2SO4 c 140 C th s ete thu c l A. 4 B. 6 C. 8 D. 3 71. un nng hn hp gm 20 ancol n chc vi H2SO4 m c 1400C th thu c ti a bao nhiu ete. A. 245 B. 250 C. 210 D. 220 72. Danh php thay th ca cht c cng thc cu to : CH3CH(OH)CH(CH3)CH3 l: A. 2-Metyl butan-3 -ol B. 1,1-imeyl propan-2-ol C. 3-Metyl butan-2-ol D. 1,2-imeyl propan-1-ol 73. Anken thch hp iu ch ancol sau y (CH3CH2)3C-OH l: A. 3-etylpent-2-en B. 3-etylpent-3-en C. 3-etylpent-1-en D. 3,3- imetylpent-1-en 74. Trong mi cp ancol sau y cp ancol no c tng s ng phn cu to l ln nht: A. CH3OH v C5H11OH B. C2H5OH v C4H9OH C. C3H7OH v C4H9OH D. C2H5OH v C3H7OH 75. Co 3 ancol a chc: (1) CH2OH-CHOH-CH2OH; (2) CH2OH-CH2OH; (3) CH3-CHOH-CH2OH. Cht nao co th phan ng c vi ca Na, HBr, Cu(OH)2:A. (1), (2), (3) C. (1), (2) C. (1), (3) D. (2), (3) 76. Cho cc cht sau y:CH2OHCH2OH (I); HOCH2CH2CH2OH(II); HOCH2CH(OH)CH3(III); CH3COOH (IV); CH3CH(OH)COOH(V); C6H5OH(VI). Nhng cht ha tan c Cu(OH)2 nhit phng l: A. II, III, IV, V B. I, II, III, IV C. I, III, IV, V. D. I, II, IV, V, VI
36

77. Mt ancol co cng thc n gin nht la C3H8O. Vy cng thc phn t cua ancol trn la: A. C3H8O2 B. C6H16O2 C. C3H8O D. C6H14O2 78. Cho 4,6 gam ancol etylic phn ng va vi Na, sau phn ng thu c V lt kh H2 ( ktc). Gi tr V l A. 2,24 lt. B. 3,36 lt. C. 1,12 lt. D. 4,48 lt. 79. Cho 36 gam mt ancol no n chc tc dng ht vi Na d thu c 6,72 lt H2 (ktc). CT ca ancol l A. CH3OH B. C2H5OH. C. C3H7OH D. C4H9OH. 80. un nng 10ml ancol etylic 92O vi H2SO4 m c 170OC (hiu sut phn ng 60%) thu c bao nhiu lt kh etilen (ktc) ? Bit khi lng ring etanol l 0,8 g/cm3 A. 2 lt B. 2,15 lt C. 2,46 lt D. 3,56 lt 81. t chy cht hu c mnh h X thu c 1,008(l) CO2 (ktc) v 1,08 gam nc .Vy X l: A. C3H8O B. C4H8O C. C2H6O D. C4H10O 82. Thc hin phn ng tch nc 4,6 gam 1 ancol no n chc mch h thu c 2,24 lt kh (ktc). Xc nh cng thc phn t ca ancol v gi tn thay th? A. C2H5OH,ancol etylic B. C3H7OH,propan-1-ol C. C2H5OH,etanol D. C A,C ng 83. un nng ancol no, n chc X vi hn hp HBr v H2SO4 c thu c cht hu c Y ( cha C, H, Br ) trong Br chim 73,4% v khi lng. Cng thc ca X l: A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH 84. Cho 11g hn hp gm 2 ancol n chc tc dng ht vi natri, thu c 3,36 lt H2 (kc) .Phn t khi trung bnh ca 2 ancol bng bao nhiu? A. 40,8 B. 71,3 C. 36,7 D. 30,6 85. Cho 1,06g hh 2 ancol n chc l ng ng lin tip td ht vi Na thu c 224ml H2 (ktc). CTPT 2 ancol l A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C.C3H5OH v C4H7OH D. C4H9OH v C5H10OH 86. Cho 15,6 gam hn hp 2 ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Vy 2 ancol l: A. C3H5OH v C4H7OH B. C2H5OH v C3H7OH C. C3H7OH v C4H9OH D. CH3OH v C2H5OH 87. Cho 7,6 gam mt ancol c cng thc phn t dng C nH2n(OH)2 tc dng vi lng d Na, thu c 2,24 lt H2 ( ktc). Vy cng thc ca ancol trn l: A.C2H4(OH)2 B. C3H6(OH)2 C. C4H8(OH)2 D. C5H8(OH)2 88. un nong mot hh gom 2 ancol no n chc vi H 2SO4 ac 1400C thu c 21,6g nc va 72g hh 3 ete, biet 3 ete thu c co so mol bang nhau va phan ng xay ra hoan toan. Hai ancol co CTPT la: A.CH3OH va C2H5OH B. C2H5OH va C3H7OH C. CH3OH va C3H7OH D. Tat ca eu sai 89. un 1,66 gam hh 2 ancol vi H2SO4 c thu c 2 anken ng ng k tip nhau (gia thit hiu sut at 100%). Nu t hh 2 anken o cn 2,688 lit O2 (ktc). Bit ete tao ra r 2 ancol trn co mach nhanh. CTCT cua 2 ancol la: A. C2H5OH va CH3 -CH2 -CH2 OH B. C2H5OH va (CH3)2 CH OH C. (CH3)2CH-OH va (CH3)3 C -OH D. (CH 3)2CHOH va CH3 CH2-CH2 -CH2 -OH 90.S hp cht thm c cng thc phn t C7H8O tc dng c vi Na lA. 1 B. 2 C. 3 D. 4 91. C7H8O c s ng phn tc dng NaOH l:A. 2 B. 3 C. 4 D. 5 92. ng vi cng thc C8H100 co bao nhiu ng phn tac dung c vi Na v NaOH ? A. 5 B. 8 C. 7 D. 9
37

93. Cho cac cht sau: (1) phenol ; (2) ancol etylic ; (3) ancol allylic ln lt tac dung vi: Na, NaOH, Na2CO3, nc brom. Vy tng s phng trinh xay ra se la:A. 4 B. 5 C. 6 D. 7 94.Hp cht X tc dng vi Na nhng khng phn ng vi NaOH. Cht X l : A. B. C. D. 95. Nha phenolfomandehit c iu ch bng cch un nng phenol (d) vi dung dch: A. HCHO trong mi trng axit B. CH3CHO trong mi trng axit C. HCOOH trong mi trng axit D. CH3COOH trong mi trng axit 96. Mot dung dch X cha 5,4 gam chat ong ang cua phenol n chc. Cho dung dch X phan ng vi nc brom d thu c 17,25 gam hp chat cha ba nguyen t brom trong phan t, gia s phan ng xay ra hoan toan. Cong thc phan t chat ong ang cua phenol la: A. C7H7OH B. C8H9OH C. C9H11OH D. C10H13OH 97. Chia a gam ancol etylic thanh 2 phn u nhau.Phn 1: mang t chay hoan toan 2,24 lit CO2 (ktc) Phn 2: mang tach nc hoan toan thanh etylen, t chay hoan toan lng etylen m gam H2O. m co gia tri la: A. 1,6g B. 1,8g C. 1,4g D. 1,5g 98. un 132,8 hn hp gm 3 ru n chc vi H2SO4 c, 1400C hn hp cac ete co s mol bng nhau va co khi lng la 111,2g. S mol ete la: A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol 99. Cho 10g hn hp 2 ru no n chc k tip nhau trong day ng ng tac dung va u vi Na kim loai tao ra 14,4g cht rn va V lit khi H2 (ktc). V co gia tri la: A. 1,12 lit B. 2,24 lit C. 3,36 lit D. 4,48 lit 100. Tach nc hoan toan t hn hp Y gm 2 ru A, B ta c hn hp X gm cac olefin. Nu t chay hoan toan Y thi thu c 0,66g CO2. Vy khi t chay hoan toan X thi tng khi lng CO2 va H2O la: A. 0,903g B. 0,39g Cau 1: Hoa hoc hu c la nganh hoa hoc: A. Chuyen nghien cu cac hp chat cua cacbon cac hp chat cua hidro. B.Chuyen nghien cu

C. Chuyen nghien cu cac hp chat cua cacbon tr CO, CO2, muoi cacbonat, xianua, cacbua D. Chuyen nghien cu cac hp chat cua cacbon, hidro, oxi. Cau 2: Trong cac hp chat sau, chat nao khong phai la hp chat hu c? A.(NH4)2CO3 B.CH3COONa C. CH3Cl D. C6H5NH2 Cau 3 : Cho cc cht: CaC2, CO2, HCHO, Al4C3, CH3COOH, C2H5OH, NaCN, C2H2O4, CaCO3. S cht hu c l: A. 3 B. 4 C. 5 D. 6 Cau 4: Cap hp chat nao sau ay la hp chat hu c? A. CO2, CaCO3 B. CH3Cl, C6H5Br C. NaHCO3, NaCN D. CO, CaC2. Cau 24: Trong cc cng thc sau cng thc no l cng thc n gin: C2H4; C2H5; C3H6; C4H8; CH4O; C2H4O; C2H6O; C3H8O3;
38

A. C2H5; C3H6; CH4O. C2H6O. C. C2H5; C3H6; CH4O; C2H4O; C2H6O; C3H8O3

B. CH 4O; C2H4O;

D. CH4O; C2H4O; C3H6

Cau 25: Trong cc cng thc cho di y, cng thc no l cng thc phn t? CH4O; C5H10; C5H11; C2H6O; C4H8O2; C5H10O.A. C5H10; C4H8O2. B. C2H6O; C4H8O2; C5H10. C. CH 4O; C2H6O. C4H8O2; C5H10O. Cau 26: Mun bit cht hu c X l cht g phi da vo loi cng thc no sau y: A. Cng thc n gin tng qut. Cau 28: Cho cac chat: (1) CH4, (2) C2H2, (3) C5H12, (4) C4H10, (5) C3H6, (6) C7H12, (7) C6H14. Chat nao la ong ang cua nhau?A.1, 2, 3, 4, 5, 6, 7 B. 1, 3, 4, 7 C. 2, 5, 7, 6, 7 D. 1, 3, 5, 7 Cau 31: Nhng chat nao sau ay la ong phan cau tao cua nhau? (1) CH3CH2CH2CH2CH2CH3 CH3CH2CH2CH(CH3)2 (3) CH3CH2CH(CH3)CH2CH3 CH3CH2CH2CH2CH3. A. 1, 2, 3 B. 1, 2 C. 1, 4 D. 1, 2, 3, 4 (2) (4) B. Cng thc phn t C. Cng thc cu to D. Cng thc D. CH 4O; C5H10; C2H6O;

Cau 32: Trong cac phan ng sau, phan ng nao khong phai la phan ng the? (1) C2H6 + Cl2 (3) C6H6 + Cl2 A. 4
s a
o

C2H5Cl + HCl C6H5Cl + HCl B. 2, 4 C. 2

(2) C6H6 + 3Cl2

2 4

s a
0

C6H6Cl6

, p , xt t

,t (4) C2H5OH H SO dac C2H4 + H2O

D. 1, 2, 4

Cau 34: Day chat nao sau ay thuoc day ong ang co cong thc chung la CnH2n+2. A.CH4, C2H2, C3H8, C4H10, C6H12 C5H12 C.C4H10, C5H12, C6H12. C5H12. A.C2H6, CH4, C4H10 C.CH3OCH3, CH3CHO Cau 36: ng vi cng thc phn t C4H8 c tt c: A. 3 ng phn. B. 4 ng phn. C. 6 ng phn.
39

B. CH 4, C3H8, C4H10, D. C2H6, C3H6, C4H8,

Cau 35: Trong cac cap chat sau,cap chat nao la ong ang cua nhau? B. C2H5OH, CH3CH2CH2OH D. Cap A va cap B. D. 5 ng phn.

Cau 37: Hirocacbon X c cng thc phn t l C4H10. Vy X l: A- Hirocacbon no, khng vng 3 ng phn. B- Hirocacbon no, khng vng 2 ng phn. C- Hirocacbon khng no, 2 ng phn. D- Hirocacbon no, c vng 2 ng phn. Cau 38: Mt hp cht hu c X c CTPT l C4H8O. Xc nh s ng phn mch h (khng vng) ca X? A. 8 B. 5 C. 4 D. 7 B- hp cht no, 5 ng phn . D- hp cht no, 4 ng phn Cau 39: Hp cht X c cng thc phn t l C3H6Cl2. Vy X l: A-hp cht no, 6 ng phn . C- hp cht khng no, 4 ng phn.

2. Phan tram khoi lng cacbon trong phan t ankan Y bang 83,33% . Cong thc phan t cua Y la : A. C2H6 B. C3H8 C. C4H10 D. C5H12 3. Theo chieu tang so nguyen t cacbon trong phan t , phan tram khoi lng cacbon trong phan t ankan A. Khong oi vong va mach h B. Giam dan C. tang dan D. Mach

4. Theo chieu tang so nguyen t C trong phan t, phan tram khoi lng C trong phan t xicloankan. A. tang dan khong theo quy luat B. giam dan C. khong oi D. bien oi

5. Phn ng c trng ca hidrocacbon no A. Phn ng tchB. Phn ng th C. 6. Cho Ten goi hp chat X co cong thc cau tao : CH3-CH - CH2 - C- CH2-CH3 CH2CH3 A. 2,4 ietyl-4-metylhexan dimetylheptan C. 5-etyl-3,5-imetylheptan pentan CH2 CH3 B. 3- etyl-3,5D. 2,2,3- trietylCH3 C. Phn ng cng D. C A, B v

10. Tien hanh clo hoa 3-metylpentan t le 1:1, co the thu c bao nhieu dan xuat monoclo la ong phan cua nhau? A. 4 B. 5 C. 2 D. 3 11. Khi cho butan tac dung vi brom thu c san pham monobrom nao sau ay la san pham chnh? A. CH3CH2CH2CH2Br CH3CH2CBr2CH3. B. CH3CH2CHBrCH3 C.CH3CH2CH2CHBr2 D.

12. Hidrocacbon X co CTPT C5H12 khi tac dung vi Clo tao c 3 dan xuat monoclo ong phan cua nhau. X la: A. iso-pentan butan B. n-pentan
40

C. neo-pentan

D.

2-metyl

13. Ankan X co cong thc phan t C5H12, khi tac dung vi clo tao c 4 dan xuat monoclo. Ten cua X la A. pentan dimetylpropan B. iso-pentan C. neo-pentan D.2,2-

14. Ankan Y td vi Brom tao ra 2 dan xuat monobrom co ty khoi hi so vi H2 bang 61,5. Ten cua Y la: A. butan B. propan C. isobutan D. 2-metylbutan 15. Brom hoa ankan ch tao mot dan xuat monobrom Y duy nhat. dY/ khng kh = 5,207. Ankan X co ten la: A. n- pentan B. iso-butan C. iso-pentan D. neo-pentan 16. Ankan Z co cong thc phan t la C5H12. Tien hanh p/ dehidro hoa Z thu c mot hon hp gom 3 anken la ong phan cua nhau trong o co hai chat la ong phan hnh hoc. Cong thc cau tao cua Z la? A. CH3CH2CH2CH2CH3 B. CH3CH2CH(CH3 )2 Khong co cau tao nao phu hp C. C(CH3)4 B.C2H6 D.

17. Phan tch 3 g ankan cho 2,4g cacbon . CTPT cua A la g ? A. CH4 C. C3H8 D. ket qua khac

18. Mot ankan tao c dan xuat monoclo, trong o ham lng clo bang 55,04%. Ankan co CTPT la A. CH4 B. C2H6 C.C3H8 D. C4H10 19. Khi phan huy hoan toan hidrocacbon X trong ieu kien khong co khong kh, thu c san pham co the tch tang gap 3 lan the tch hidrocacbon X ( cung ieu kien ) . Cong thc phan t cua X la : A. C2H6 B. C4H10 C. C5H12 D. C6H14 20. Khi nhiet phan mot ankan X trong ieu kien khong co khong kh thu c kh H2 va muoi than, thay the tch kh thu c gap 5 lan the tch ankan X( o cung ieu kien ve nhiet o ap suat ). CTPT cua X la : A. CH4 B. C2H6 C. C3H8 D. C4H10 21. ot chay ht 2,24 lt ankan X (ktc), dan ton b san pham chay vao dd nc voi trong d thay co 40g. CTPT X A. C2H6 B. C4H10 C. C3H6 D. C3H8 22. ot chay hoan toan 0,15 mol hon hp 2 ankan thu c 9,45g H2O. Cho san pham chay qua bnh ng Ca(OH)2 d th khoi lng ket tua thu c la bao nhieu ? A.37,5g B. 52,5g C. 15g D.42,5g 23. Xicloankan ( ch co mot vong) A co t khoi so vi nit bang 3. A tac dung vi clo co chieu sang ch cho mot dan xuat monoclo duy nhat, xac nh cong thc cau tao cua A?
CH3

CH3

CH3

A.

B.

C.

H3C

D.

H3C

CH3

1. Theo chieu tang so nguyen t cacbon trong phan t , phan tram khoi lng cacbon trong phan t anken A. Tang dan khong theo quy luat B. giam dan C. khong oi
41

D. bien oi

2. Theo chieu tang so nguyen t cacbon trong phan t, phan tram khoi lng cacbon trong phan t ankin. A. Tang dan khong theo quy luat B. Giam dan C. Khong oi D. Bien oi

3. Co bao nhieu ong phan cong thc cau tao cua nhau co cung cong thc phan t C4H8? ( khong ke p hnh hoc)A. 6 B. 3 C. 4 D. 5 4. ng vi cong thc phan t C4H8 co bao nhieu ong phan cau tao eu tac dung c vi hidro? A. 2 B. 3 C. 5 D. 6 5. ng vi cong thc phan t C4H8 co bao nhieu ong phan cua olefin? A. 4 B. 3 C. 5 D. 6 6. Co bao nhieu chat ong phan cau tao co cung cong thc phan t C4H8 tac dung vi Brom( dung dch)? A. 5 chat B. 6 chat C. 4 chat B. pent-3-en D. 3 chat C. pent-2-en D. but7. Anken CH3CH=CHCH2CH3 co ten la A. metylbut-2-en 2-en 8. Trong Phong th nghiem co the ieu che mot lng nho kh etilen theo cach nao sau ay? A. e hidro hoa etan axit H2SO4, 170OC. C. Crackinh butan. tac la Pd/PbCO3. B. un soi hon hp gom etanol vi D. Cho axetilen tac dung vi hidro co xuc

9. e tach rieng metan khoi hon hp vi etilen va kh SO2 co the dan hon hp vao: A. dd Natrihidroxit HCl
CH2 C CH2 CH2 CH2Cl

B. dd axit H2SO4

C. dd nc brom

D.

dd

10. Cho bit tn ca hp cht sau theo IUPAC : A. 1-Clo-4-Etylpent-4-en 5- Clo-2-etylpent-1-en B. 1-clo-4-metylenhexan

CH2

CH3

C. 2-etyl-5-Clopent-1-en

D.

11. Trong so cac anken C5H10 ong phan cau tao cua nhau, bao nhieu chat co cau tao hnh hoc ? A. 1 B. 2 C. 3 D. 4 CH3CH = CH2 (I);
C l C C H

12.Nhng hp cht no sau y c th c ng phn hnh hc (cis-trans) : CH3CH = CHCl (II) ;

H3C

CH3CH = C(CH3)2 (III), A. (I), (IV), (V)

C2H5

CH3 C2H5

H3C

(IV) ;

C2H5

(V)

B. (II), (IV), (V)

42

C. (III), (IV)

D. (II), III, (IV), (V)

13. Co bao nhieu anken ong phan cau tao cua nhau khi cong hidro eu tao thanh 2- metylbutan? A. 1 A. CH3 CHClCH2CH3. CHCHClCH3. B. 2 C. 3 D. 4 CH2 = CHCH2CH3 + HCl ?. CH2 = 15. Cho bit sn phm chnh ca phn ng sau:

B. CH2 = CHCH2CH2Cl. C. CH2 ClCH2CH2CH3. D.

16. Hidrocacbon A va B thuoc cung mot day ong ang. Biet MA = 2MB. A va B thuoc day ong ang nao? A. Anken hoac xicloankan B. Aren C. Co the thuoc bat ky day nao. D. Anken 17. Cho 2,24 lt anken X (ktc) tac dung vi dd brom thu c san pham co khoi lng ln hn khoi lng anken la A. 0,8 g B. 10,0g C. 12,0 g D. 16,0g 18. Anken X tac dung vi nc (xuc tac axit) to ra hon hp 2 ancol ong phan cua nhau. d/N2 = 2,00. Ten ca X la A. iso-penten B. but-1-en C. but-2-en D. pent-1en 19. Anken Y tac dung vi dd brom tao thanh dan suat ibrom trong o % khoi lng C bang 17,82 %. CTPT Y la A. C3H6 B.C4H8 C. C4H10 D. C5H10 20. ot chay hoan toan 1,12 lt mot anken X (ktc) thu c 5,60 lt kh CO 2 (ktc). CTPT X la: A. C3H6 B.C4H8 C. C4H10 D. C5H10 21. ot chay hoan toan mot the tch hon hp gom anken X va hidrocacbon Y thu c 5,56 lt kh CO2 ( ktc) va 5,40 g nc. Y thuoc loai hirocacbon co cong thc phan t dang. A.CnH2n B.CnH2n-2 C. CnH2n+2 D. CnH2n-4 C. 4 22. Co bao nhieu ankin ng vi cong thc phan t C5H8? A. 2 B. 3 D. 5

23. Co bao nhieu ong phan cua ankin nhau khi cong hidro d, xuc tac niken, to tao thanh 3-metyl hexan? A. 2 B. 3 C. 4 D. 5 24. Co bao nhieu chat mach h ong phan cau tao (gom ankin va ankaien lien hp) co cung CTPT C5H8 ? A. 5 chat B. 6 chat C. 4 chat D. 3 chat B. anken C. ankin 25. Ankaien la ong phan cau tao cua: A. ankan D. xicloankan

26. Cho cong thc cau tao: CH2=CH-CH=CH-CH3. Ten goi nao sau ay la phu hp vi CTCT o? A. pentadien B. penta-1,3-dien C. penta-2,4-dien D. isopren 27. Co bao nhieu hirocacbon mach h khi cong hiro tao thanh butan?A. 2 B. 3 C.5 D. 6 28. Tecpen l tn gi nhm hircacbon khng no thng c cng thc chung l . A. (C4H8)n , n > 2 (C5H8)n, n > 2 B. (C5H10)n, n > 2
43

C. (C4H6)n , n > 2

D.

29. Cho s o p/: X, Y, Z thch hp?

metan X Y Z

CaosuBuNa. B.

Cho biet cac chat X: metylclorua , Y:

A. X : etylen , Y : buten-1, Z: buta-1,3 -dien etylen , Z : butadien-1,3 C. X : etin , Y : vinylaxetylen , Z : buta-1,3-ien etan, Z: buten-2

D. X : metylenclorua , Y :

30. S ankin ng vi cng thc phn t C6H10 tc dng vi dung dch AgNO3/NH3 l:A. 1.B. 2 C. 3. D. 4 31. Trong phan t ankin X, hidro chiem 11,765% khoi lng . Cong thc phan t cua X la : A. C2H2 B. C3H4 C. C4H6 D. C5H8 32. ot chay hoan toan 1,3g ankin X thu c 2,24 lt kh CO 2 (ktc) . Cong thc phan t cua X la : A. C2H2 B. C3H4 C.C4H6 D. C5H8 33. ot chay hoan toan 5,4g ankaien X thu c 8,96 lt kh CO2 ( ktc) . Cong thc phan t cua X la A. C4H4 B. C4H8 C.C4H6 D. C4H10 34. Cho 2,24 lt hon hp kh X ( ktc) gom axetilen va etilen suc cham qua dung dch AgNO3 trong NH3 (lay d ) thay co 6g ket tua. % the tch cua kh etilen trong hon hp bang A. 75% B. 40% C.50% D. 25% 35. ot chay hoan toan hon hp kh gom ankin X va hidrocacbon Y mach h co cung so nguyen t C, thu c san pham chay co the tch hi nc bang the tch kh CO2 (cac the tch o cung ieu kien). Y thuoc loai A.ankin B. anken C. xicloankan D. ankan 36. Khi propin tac dung vi brom trong dung dch tao thanh chat X trong o % khoi lng C bang 18% . CTPT X la : A. C3H4Br4 B. C3H4Br2 C.C3H3Br D. C3H4Br 37. ot chay 1 so mol nh nhau cua 3 hidrocacbon A, B, C thu c lng CO 2 nh nhau, con t le so mol CO2 va H2O oi vi A, B, C lan lt la 0,5: 1:1,5. CTPT cua A, B, C A. CH4, C2H6, C3H8 C2H 4, C2H 2 B. C2H4, C3H6, C4H8 C. C2H2, C2H4, C2H6 :A. 3 B.4 C. 5 D. C2H6,

5. S ng phn thm ca cht c CTPT C8H10 D.6 A. 4 B. 5 C. 6

6. Co bao nhiu ng phn la dn xut cua benzen ng vi cng thc phn t C9H10 D. 7 CH3

7. Danh php IUPAC ankyl benzen c CTCT sau l: C 2 H5 A. 1etyl 3metylbenzen B.5etyl1metylbenzen benzen
44

C.2etyl4metylbenzen

D.4metyl2etyl

8. Hirocacbon thm A c cng thc phn t l C8H10. Bit khi nitro ha A ch thu c mt dn xut mononitro. A l:A. o-xilen. B. p-xilen. C. m-xilen D. etylbenzen 9. Chat nao sau ay co the tham gia phan ng trung hp? A. but-2-in, xiclohexan, propen, naftalen C. stiren, but-2- en, axetilen, propin A. etin, butan, isopentan C. xiclopropan, stiren, isobutan A. ankan B. anken B. isopren, benzen, etin, vinylaxetilen D. but-1-en, toluen, eten, butadien-1,3 B. propan, toluen, xiclopentan D. metan, benzen, xiclohexan . X thuc dy ng ng no sau y: D. aren C. ankin

10. Cac chat nao cho sau co the tham gia p/ the vi Cl2 (as) ?

11. Cng thc tng qut ca hirocacbon X c dng :

12. Khi trong phn t benzen c sn cc nhm th nh: -NH2, -OH, ankyl, cc nhm halogen th cc nhm th tip theo s nh hng u tin vo cc v tr no so vi nhm th th 1 : A. Octo v mta 5. A. a) 1,2,3. b) 4,5,6. B. mta v para 2. . b) Cc cht c nh hng th m- l: B. a) 1,2,4,6. b) 3,5. C. a) 1,3,5. b) 2,4,6. D. a) 3,4,5,6. b) 1,2. 6. C. ch duy nht para D. octo v para . 3. 4. 13. Cho cc hp cht thm sau: 1. a) Cc cht c nh hng th o- v p- l:

14. T benzen e thu c p-bromnitrobenzen phai tien hanh lan lt cac p/ vi nhng tac nhan nao sau? A. Br2 ( xt: Fe, t0) , HNO3(xt: H2SO4,t0) B. Br2 ( xt: Fe, t0) , HNO3 loang C. Br2 ( As), HNO3(xt: H2SO4,t0) Br2 ( xt: Fe, t0) D. HNO3(xt: H2SO4,t0) ,

15. T benzen e thu c m-bromnitrobenzen phai tien hanh lan lt cac p/ vi nhng tac nhan nao sau? A. HNO3 loang, Br2 ( xt: Fe, t0) B. Br2 ( xt: Fe, t0) , HNO3(xt: H2SO4,t0) C. HNO3(xt: H2SO4,t0) , Br2 ( xt: Fe, t0) Br2 ( As) 16. Chat nao sau ay lam mat mau nc brom? A. stiren, butadien-1,3, isopentin, etylen pentin-2, propylen C. xiclopropan, benzen, isobutylen, propin 1, propen A. C6H6 A. C. 19. Cho s phn ng:
45

D. HNO3(xt: H2SO4,t0) ,

B.

isopropylbenzen,

D. toluen, axetylen, butin-

17. Cho dy bin ha sau : C2H5OH A B C. Hy tm C trong cc trng hp sau: B.C2H6 C.C2H2 B. D. . . X, Y tng ng vi nhm cht no sau y? D. C3H8 18. iu ch (meta)bromonitrobenzen s no sau y l ng nht:

A.

B.

C. D. Cu 1: CH3 CH2 CH(CH3)2- CH(CH3)- CH3 ng vi tn gi no sau y? A. 2, 3- imetylpentan B. 3, 4- imetylpentan C. isopropylpentan D. 2- metyl- 3- etylpentan Cu 2: Sn phm chnh ca phn ng brom ho 2- metylbutan theo t l s mol 1:1 l: A. 1- clo- 2- metylbutan B. 2- clo- 3- metylbutan C. 1- clo- 3- metylbutan D. 2- clo- 2- metylbutan Cu 3: Dy no sau y gm cc cht l ng ng ca metan A. C2H4, C3H7Cl, C2H6O B. C4H10, C5H12, C6H14 C. C4H10, C5H12, C5H12O D. C2H2, C3H4, C4H 6 Cu 4: S ng phn ng vi CTPT C5H12 l: A. 2 B. 3 C. 4 D. 5 Cu 5: Khi nhit phn CH3COONa vi vi ti xt thi thu c sn phm kh: A. N2, CH4 B. CH4, H2 C. CH4, CO2 D. CH4 Cu 9: Khi cho metylxiclopentan tc dng vi clo trong iu kin chiu sng thu c my dn xut monoclo ( ch xt ng phn cu to)?A. 1. B. 2. C. 3. D. 4. Cu 10: CTPT ng vi tn gi 4-etyl-2,3,3-trimetylheptan l: A.C12H26 B. C10H22 C. C11H24 D. C12H24
CH2 CH CH CH3

Cu 11: Hp cht :

CH3

c tn gi l:

A. 3-metylbut-1-en B. 2-metylbut-1-en C. 2-metylbut-3-en D. 3metylpent-1-en Cu 12. t chy hon ton (m) gam hh X gm metan , propen v butan thu c 4,4 gam CO2 v 2,52 gam H2O . Gi tr ca m l : A . 1,48 g B . 2,48 g C . 14,8 gam D . 24,7 gam Cu 13: Mt cht c CTCT: CH3- CH- C(CH3) = C-CH3 c tn l: A/ 2- metylpent-1- in B/ 4- metylpent-2- in C/ 2- metylbut-2- in D/ 4metylpent-2- en Cu 14: Ankin c cc ng phn: A. v tr lin kt ba mch C. B. v tr lin kt ba, mch C, p hnh hc C. v tr lin kt ba, p hnh hc. D. c A, C Cu 15: Cho propin tc dng vi H2 c d(xt Ni, t0 ) thu c sn phm c cng thc l: A. CH2 = CH2. B. CH3 CH2 -CH3 C. CH3 - CH3 D. CH2 = CH- CH3 0 Cu 16: Cho But-1-in tc dng vi H2 c d c xt Pd/ PbCO3; t thu c sp l: A. CH3-CH2-CH = CH2. B. CH3-CH2-CH2-CH3 C. CH3-CH CH3 D. CH3CH =CH2 Cu 17: Sc kh propin vo dd AgNO3/ NH3 thu c kt ta c cng thc: A. CH3 -C CAg B. Ag-CH2-C CAg C. Ag3-C-C CAg D.CH CH Cu 18: Cht no sau y tc dngc vi dd AgNO3/ NH3 A. CH3- C CH3 B.CH3- C C-C2H5 C. CH C-CH3 D.CH2=CH-CH3 Cu 19: lm sch kh axetilen c ln CO2 , ta cho hn hp qua: A. dd KMnO4 B. dd KOH C. ddd HCl D. dd Br2 0 Cu 20: Cho isopren P vi H2 c xt Ni, t thu c sn phm: A. isopentan B. isobutan C. pentan D. butan Cu 21:. Nhng hp cht no sau y c th c ng phn hnh hc (cis-trans) CH3CH = CH2 (I) ; CH3CH = CHCl (II) ; CH3CH = C(CH3)2 (III)
46

H3C C2H5 C C

CH3 C2H5

H3C C2H5 C C

Cl H

(IV) (V) A. (I), (IV), (V) B. (II), (IV), (V) C. (III), (IV) D. (II), III, (IV), (V) Cu 22. Cho bit sn phm chnh ca phn ng sau : CH2=CHCH2CH3 + HCl A. CH3CHClCH2CH3 B. CH2=CHCH2CH2Cl C. CH2ClCH2CH2 D. CH2=CHCHClCH3 Cu 23. Oxi ho etilen bng dd KMnO4 thu c sn phm l : A. MnO2, C2H4(OH)2, KOH B. K2CO3, H2O, MnO2 C. C2H5OH, MnO2, KOH D. MnO2, C2H4(OH)2, K2CO3 Cu 24. Trong phng th nghim etilen c iu ch t nhng phng php no sau y: A. Tch H2 t etilen. B. Crackinh propan. C. un nng etanol vi H2SO4 c D. Hp H2 vo a Cu 25: Cho cc cht sau: (1) ddBr2; (2) Br2 khan (Fe); (3) HNO3 c / H2SO4 c; (4) H2/ Ni, to; (5) O2 1) Toluen phn ng c vi nhng cht no? A. 2, 3, 4, 5 B. 2, 3, 4 C. 1, 2, 5 D. 1, 4, 5 2) Stiren phn ng c vi nhng cht no? A. 1, 2, 3, 4, 5. B. 1, 2,4 C. 3, 5 D. 1, 4, 5 Cu 26: Cho toluen tc dng vi Br2 (as) thu c sn phm l: A. o- Br- C6H4- CH3 B. p-Br- C6H4- CH3 C. m- Br- C6H4- CH3 D. C6H5- CH2Br Cu 27: Phn bit toluen, benzen, stiren c th dng ho cht: A. ddBr2 B. ddKMnO4 C. H2 D. ddAgNO3/NH3 Cu 28: Cho stiren tc dng vi H2 d thu c sn phm l: A. etylbenzen B. metylbenzen C. etylxiclohexan D. metylxiclohexan Cu 29: Phn biy etylbenzen v stiren c th dng ho cht no: A. H2 B. dd KMnO4 C. ddBr2 D. Br2 khan/ Fe Cu 30: Cng thc tng qut ca anken l A. CnH2n+2 (n 1) B. CnH2n -6( n 6) C. CnH2n (n 2) D. CnH2n-2 (n 2) Cu 32. Dy gm cc cht u phn ng c vi dung dch Br2 l A. Etilen; vinyl clorua; toluen; xiclo propan. B. 3-clo propen -1; 2-brom butan; benzen; etilen. C. Axetilen; 1,2-ibrom etan; stiren; vinylaxetilen; buten -1. D. Propen; xiclopropan; pentin -2; stiren. Cu 33. Sp xp cc cht sau: butan, metanol, etanol, nc theo th t nhit si tng dn l: A. metanol < etanol < nc< butan. B. butan< metanol < etanol < nc. C. butan< etanol < metanol < nc. D. butan< nc < metanol < etanol. Cu 34. S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l: A. 1. B. 2. C. 3. D. 4. Cu 35. Khi un nng etyl clorua trong dung dch cha KOH v C2H5OH, thu c: A. etan. B. etilen. C. axetilen D. etanol. Cu 36. Cht no khng phi l dn xut ca hydrocacbon ? A. ClBrCH-CF3. B. C6H6Cl6. C. Cl2CH-CF2-O-CH3. D. CH2=CH-CH2Br. Cu 37. Cht (CH3)3COH c tn l g trong cc tn sau? A. 1,1- imetyletanol. B. isobutan-2-ol. C. 2-metylpropan-2-ol. D. 1,1- imetyletan-1-ol. Cu 38. S ng phn cu to c cng thc phn t C4H9Cl l: A. 2. B. 1. C. 4. D. 3. Cu 39. Trong dung dch ca etanol trong nc c my loi lin kt hiro? A. 2. B. 3. C. 1.D. 4 Cu 40. Ancol isobutylic c cng thc cu to nh th no ? A. (CH3)2CHCH2OH. B. CH3CH2CH(OH)CH3. C. (CH3)2CHCH2CH2OH. D. (CH3)3COH.
47

Cu 41. Kt lun no sau y l ng? A.Ancol etylic v phenol u tc dng vi Na v vi dung dch NaOH. B.Phenol tc dng vi Na v vi dung dch Na2CO3 . C.Ancol etylic tc dng c vi Na nhng khng tc dng c vi CuO nung nng. B. Phenol tc dng c vi Na v vi axit HBr. Cu 42. Khi cho phenol vo dung dch NaOH thy phenol tan. Sc kh CO2 vo dung dch li thy phenol tch ra. iu chng t A. phenol l axit yu, yu hn c axit cacbonic. B. phenol l cht c tnh baz mnh. C. phenol l axit mnh. D. phenol c tnh lng tnh. Cu 43. C bao nhiu ancol c cng thc C3H8O2 tc dng vi Cu(OH)2?A. 1. B. 2. C. 3. D. 4. Cu 44. So snh tan trong nc v nhit si ca cc cht: propan-1-ol (1), etanol (2), butan-1-ol (3), dimetyl ete (4): A. 4<2<1<3 B. 4<1<2<3 C.4<2<3<1 D. 4<3<1<2 Cu 45. Mt ancol no Y c CTTN (C2H5O)n . CTPT ca Y l: A. C4H10O . B. C4H10O2 . C. C6H15O3 . D.C6H14O5 . Cu 46. Co 3 ancol a chc: (1) CH2OH-CHOH-CH2OH; (2) CH2OH-CH2OH; (3) CH3-CHOH-CH2OH. Cht nao co th phan ng c vi ca Na, HBr, Cu(OH)2: A. (1), (2), (3) B. (1), (2) C. (1), (3) D. (2), (3) Cu 47. Khi un nng ancol etylic vi axit sunfuric c nhit khong 1400C, thu c sn phm chnh l : A. Etyl hirosunfat. B. Etilen. C. ietyl ete. D. ietyl sunfat. Cu 48. Dy gm cc cht u phn ng vi phenol l: A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, kim loi Na , dung dch NaOH. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, qu tm, dung dch NaOH. Cu 49. ti to phenol t dung dch natri phenolat ta khng th dng cht no ? A. CO2 B. CH3COOH C. HCl D. C2H5OH Cu 50. Phn ng no sau y khng xy ra : a) C2H5OH + CH3OH b) C2H5OH + Na t c) C2H5OH + CuO d) C2H5OH + NaOH Cu 1: Cho cc cht sau CH3CHO (X) ; C6H5OH (Y); C6H5CH2OH(Z); (CH3)2CHCHO (T) CH3C6H4OH (E) ; Nhng cp cht ng ng ca nhau l :A. C 5 u l ng ng ca nhau B. (X) v (Z) ; (Y) v (E) C. (X) v (Y) ; (Y) v (T) D. (X) v (T) ; (Y) v (E) Cu 2: Ankan X c phn trm khi lng cacbon bng 83,33%.Cng thc phn t v s ng phn c th c ca X l :A. C5H12 ; 3 ng phn B. C3H8 ; 1 ng phn C. C4H10 ; 2 ng phn D. C5H12 ; 2 ng phn Cu 3: Hn hp X gm mt ankan E v mt anehit n no F chng c cng khi lng phn t . T l s nguyn t hiro trong phn t ca E v F l 5 :3 . Vy cng thc phn t ca E v F ln lt l : A. C3H8 v C3H8O B. C4H10 v C3H6O C. C5H12 v C4H8O D. C3H8 v C2H4O Cu 4: C2H4 v C2H2 phn ng c vi tt c cc cht trong dy no sau y ? A. CO2; H2 (Ni, t0);dd KMnO4 B. dd Br2 ; dd HCl ;dd KMnO4 ; H2 (Ni, t0) C. H2 (Ni, t0); NaOH; dd HCl D. dd Br2 ; dd HCl ; dd AgNO3/NH3 d Cu 5: Cho benzen v clo vo bnh thy tinh ri em phi nng s thy xut hin khi trng , l : A. C6H6Cl6 B. C6H5Cl C. C6H6 D. C2H5Cl Cu 6: Hn hp X gm 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc t chy hon ton hn hp X dng khng ht 24,64 lt O2 (kc).Cng thc phn t ca 2 anken l : A. C2H4 v C3H6 B. C2H4 v C4H8 C. C3H6 v C4H8 D. A v B u ng Cu 7: Dn hn hp kh A gm propan v xiclopropan i vo dung dch brom s quan st c hin tng no :
48

A. Mu dung dch khng i. B. Mu dung dch mt hn v khng cn kh thot ra. C. Mu dung dch nht dn v c kh thot ra. D. Mu dung dch nht dn v c khng c kh thot ra. Cu 8: Hn hp Y gm mt ankanol Z cha 60% cacbon v mt ankin T c s nguyn t hiro bng vi s nguyn t hiro c trong Z. Vy cng thc phn t ca Z v T ln lt l : A. C3H8O v C5H8 B. C4H10O v C6H10 C. C2H6O v C4H6 D. C4H8O v C5H8 Cu 9: T ancol etylic v iu kin cn thit c c th to ra etyl clorua; ietyl ete ; 1,2- ibrom etan; etylen glycol ; anehit axetic vi s phng trnh phn ng t nht l :A. 4 B. 7 C. 6 D. 5 Cu 10: Trong cc pht biu sau : a) ng vi cng thc phn t C3H8O c 3 ng phn cu to . b) Benzyl clorua l dn xut halogen bc 2. c) Tt c cc ancol a chc u tc dng vi Cu(OH)2 . d) Oxi ha ancol bc 2 to xeton. e) Ankin v anken ch c ng phn v tr lin kt bi. f) Anehit va c tnh kh, va c tnh oxi ha Nhng pht biu sai l :A. a ;d ; f B. b ; c ; e C. a ; b; c ; d D. a ; b ; c Cu 11: Dng dung dch AgNO3/NH3 lm thuc th c th phn bit c dy cc cht no sau y A. Metan, benzen v axetilen B. Toluen , axeton v axetilen C. Metan , axetilen , anehit axetic D. Axetilen , , etanol v benzen Cu 12: Dn hn hp X gm etilen v axetilen qua dung dch brom d khi lng bnh brom tng 1,34g. Cn khi cho tc dng ht vi dung dch AgNO3/NH3 thu c 7,2g kt ta. Thnh phn phn trm th tch ca etilen v axetilen ln lt l :A. 50% ; 50% B. 35,5% ; 64,5% C. 40% ; 60% D. 25% ; 75% Cu 13: Cho 17g hn hp hai ancol n chc no tc dng va vi Na thy thot ra 4,48 lt H 2(ktc). Hn hp cc cht cha Na c to ra c khi lng l bao nhiu? A. 28,3g B. 19g C. 14,7g D. 25,8g Cu 14: Khi t chy hp cht hu c X bng oxi khng kh thu c hn hp kh v hi gm CO2 , H2O, N2 . iu chng t phn t cht X A. chc chn phi c cc nguyn t C, H,c th c cc nguyn t O, N B. chc chn phi c cc nguyn t C, H, N C. chc chn phi c cc nguyn t C, O, H, N D. ch c cc nguyn t C, H Cu 15: S ng phn cu to ca C5H12O khi oxi ha to anehit c nhnh l : A. 5 B. 2 C. 3 D. 4 Cu 16: Trong phn t buta - 1,3 - ien, cc nguyn t lin kt vi nhau bng : A. By lin kt v mt lin kt B. Chn lin kt v mt lin kt . C. Mi lin kt . D. Chn lin kt v hai lin kt Cu 17: t chy hon ton hn hp gm hai ancol no n chc hn km nhau 2 nguyn t C thu c CO2 v H2O theo t l mol nCO :n H O = 2 : 3 . Cng thc phn t v phn trm th tch mi ancol trong hn hp l : A. CH3OH (30%); C3H7OH (70%) B. C2H5OH (50%); C4H10OH (50%) C. CH3OH (50%); C3H7OH (50%) D. C3H7OH (35%); C5H11OH (65%) Cu 18: Hp cht 2- metylbut - 2- en l sn phm chnh ca phn ng tch t cht no trong cc cht sau : A. 2-brom-2-metylbutan B. 2-metylbutan -2- ol C. 3-metylbutan-2- ol D. Tt c u ng Cu 19: t chy hon ton mt hirocacbon kh cn s mol oxi phn ng gp i s mol nc to ra. Bit X khng tc dng vi AgNO3/NH3, vy cu to ca X l : A. CH % C CH3 B. CH2 = C = CH2 C. CH3 C% C CH3 D. CH2 = CH CH = CH2 Cu 20: Cho ln lt cc cht : C2H4 ,C2H5Cl ,C2H5OH , C6H5OH v C6H5CH2Br vo dd NaOH un nng. S phn ng xy ra l : A. 3 B. 1 C. 2 D. 4
2 2

49

Cu 21: Hy chn pht biu sai : A. Phenol cho kt ta trng vi dung dch vi dung dch nc Br2.. B. Phenol l cht c mt hay nhiu nhm - OH lin kt trc tip vi nguyn t cacbon ca vng benzen C. Phenol l mt axit yu, khng lm i mu qu tm . D. Phenol l cht trong phn t c nhm - OH v nhn benzen Cu 22: Bc ca dn xut halogen c xc nh da vo : A. s nguyn t hiro b thay th . B. s nguyn t cacbon lin kt vi halogen. C. bc ca nguyn t cacbon lin kt vi nguyn t halogen. D. s nguyn t halogen th vo hirocacbon . Cu 23: Etan c th tham gia nhng phn ng ha hc no sau y:Tc dng vi clo c nh sng (1); Phn ng cng (2) ; Phn ng chy (3) ; Phn ng tch H2 (4) ; Phn ng cracking (5) A. (2) , (3) , (5) B. (1) , (3), (4) C. (1) ,(2), (3) , (5) D. (1), (2) , (4) Cu 24: Cc cng thc chung CnH2n+2 (n 1) ; CnH2n+1OH (n 1); CnH2n-2 (n 2); CnH2n+1CHO (n 0) ln lt ca cc dy ng ng sau : A. Ankan ; ancol n chc ; ankin ; anehit no . B. Ankan ; ancol no n chc ; ankin ; anehit no n chc. C. Ankan ; ancol a chc ; ankin ; anehit n chc. D. Anken ; ancol no ; ankaien ; anehit no n chc. + Cu 25: Trong s sau : CaC2 +X C2H2 +Y ( Pd / PbCO ) C2H4 + Z ( PdCl ) CH3CHO Z CH3COONH4. ,CuCl Cc cht X, Y, Z ln lt l : A. H2O , H2 , O2 , [Ag(NH3)2]OH B. H2 , KOH , HCl , [Ag(NH3)2]OH C. Br2 , KOH , CO2, [Ag(NH3)2]OH D. Br2 , NaOH , NaCl , NH3 Cu 26: Thc hin phn ng th brm theo t l 1 : 1 vo trong nhng cht sau( c y xc tc v iu kin cn thit ) : C6H5CH3 (1) ; C6H5COOH ( 2) ; C6H5SO3H ( 3) ; C6H5NH2 ( 4).Nhng cht cho sn phm th octho hoc para l :A. (1) v (3) B. ( 3) C. (1) v (4) D. (1) Cu 27: Cho cc cht sau: axetlen, buta-1, 3 - ien, toluen, phenol , etan, etanal .Cht no lm mt mu dung dch Br2:A. axetilen, buta-1, 3 - ien, etan B. buta-1, 3 - ien, , phenol C. etan, etanal , buta-1, 3 - ien , toluen, etan D. axetlen, buta-1,3 - ien , phenol , etanal . Cu 28: Cho 0,87g mt anehit n chc no cho tc dng ht vi dung dch AgNO 3/NH3 thu c 3,24g Ag. Cng thc cu to ca anehit l: A. CH3CH2CHO B. HCHO C. CH3CH2CH2CHO D. CH3CHO Cu 29: Cho Na tc dng hon ton vi 20,5g hn hp hai ancol no n chc k tip trong dy ng ng sinh ra 4,48 lt kh H2(ktc). Cng thc phn t ca hai ancol l: A. C4H9OH v C5H11OH B. C2H5OH v C3H7OH C. CH3OH v C2H5OH D. C3H7OH v C4H9OH. Cu 31: Nhng phn ng no sau y chng t phenol c lc axit mnh hn etanol nhng yu hn axit cacbonic: 2C6H5OH + 2Na g 2C6H5ONa + H2 (1) C6H5OH + NaOH g C6H5ONa + H2O (2) C6H5OH + 3Br2 g C6H2Br3OH + 3HBr (3) C6H5ONa + CO2 + H2O g C6H5OH + NaHCO3 (4) A. (2) v (4) B. (1) v (4) C. (3) v (4) D. (2) v (3) Cu 32: Cho m gam hn hp gm etanol v phenol tc dng ht vi Na thu c 2,24 lt H 2 ( kc).Cng m gam hn hp tc dng va vi 25 ml dung dch NaOH 2M. Gi tr m l : A. 13,5g B. 10,5g C. 12,6 g D. 11,6g Cu 6: Khi cho mt t git dung dch phenolphtalein vo mt dung dch cha C 2H5ONa th dung dch c mu: A. . B. Vng. C. Hng. D. Khng i mu. E. Xanh. Cu 7: Khi cho mt t giy qu vo C2H5OH nguyn cht th giy qu chuyn sang mu: A. . B. Vng. C. Hng D. Khng i mu. E. Xanh. Cu 8: thu c ancol etylic nguyn cht t dung dch ancol, ta dng ha cht sau: A. Cho H2SO4 m c vo ancol. D. C A,B,C u ng.
3 2 2

50

B. Cho P2O5 vo ancol. E. C A,B,C u sai. C. Cho CuSO4 khan vo ancol. Cu 9: Khi cho C2H5ONa vo nc th n b : A. Thy phn. B. To ra dung dch C2H5ONa. C. Nhit phn. D. Tt c u sai. E. Phn hy. Cu 10: Trong s cc cht sau: Na, Ca, CaO, CuO, CH3COOH, HCl. Cht tc dng c vi ancol etylic l: A. Na, CuO. B. CuO, CH3COOH, HCl, Na, Ca. C. Ca, CH3COOH. D. Tt c cc cht trn. E. CuO, CH3COOH, HCl Cu 11: phn bit c ancol isopropylic v n- propylic ta lm: A. Oxi ha ri cho tc dng dung dch AgNO3/NH3 . B. Tch nc ri cho tc dng dung dch Br2 C. Cho tc dng Na. D. C 3 u ng. E. C 3 u sai. Cu 12: phn bit c ancol anlylic v ancol n-propylic ta tin hnh: A. Oxi ha ri cho tc dng dung dch AgNO3/NH3. B. Tc dng dung dch Br2. C. Dng dung dch KMnO4. D. C B,C u sai. E. C B,C u ng. Cu 13: phn bit metanol v propanol-1 ta tin hnh nh sau: A. Dng phng php nh lng. B.C A,E u ng. C. Khng th phn bit c. D. C A,E u sai. E. Tch nc ri cho sn phm tc dng dung dch Br2. Cu 14: Cho s chuyn ha: C2H5OH A Cao su buna. iu kin chuyn ha ancol etylic thnh A l: A. Al2O3 + ZnO v 450oC. D. H2SO4 c, 170oC. B. Fe xt, 70oC. E. CuO v un nng. C. As, nhit thng. Dng cc thng tin sau cho cc cu hi 15v 16 X2 C3H8(A) (CH3)2CHX(B) C3H7OH(C). Cu 15: thu c B vi hiu sut cao nn dng X2 l: A. Cl2. B. Br2.C. F2. D. I2. E. H2. Cu 16: Vi X l Clo, chiu tng dn nhit si ca A,B,C l: A. A < B < C. B. B < A < C. C. B < C < A. D. C < A < B. E. A < C < B. *Cu 18: Ancol n chc A c cng thc phn t C4H10O. Khi b oxi ha to ra xeton. Khi tch nc to ra anken mch thng. A. CH3CH2CH2CH2OH. B. (CH3)3CHOH.C. (CH3)2CH-CH2OH. C. CH3CH2-CH(OH)CH3. D. (CH3)3COH. Cu 19: Dy ng dng ca ancol etylic c cng thc tng qut l: A. CnH2n+2OH(n 1). B. CnH2n-1OH(n 1). C. CnH2n+1OH(n 1) D.Tt c u sai.C. C nH2n-2O(n 1). Cu 20: Ancol (CH3)2CHOH c tn l: A. Ancol isopropylic. B. C A v C u ng. C. Ancol etylic. D. C A v C u sai.C. Propanol- 2. Cu 21: Tn quc t ca C. 2- Metyl propanol-1.
CH3 CH CH3 CH2 OH

l: A. 2- Etyl propanol. B. 2- Etyl propanol-1. C. 2- Metyl propanol. D. Tt c u sai. Cu 23: Cng thc cu to ng ca ancol tert - butylic l: A. (CH3)3COH. B.(CH3)3CCH2OH. C. (CH3)2CHCH2OH. D. CH3CH2CH2CH2OH. E.CH3CHCH2CH3. OH Cu 25: S ng phn v ancol (mch h) ng vi cng thc phn t C4H8O l:A. 2. B. 3. C. 5.E. 6. Cu 26: ng vi cng thc phn t C3H6O s c bao nhiu ng phn v ancol (mch h). A. 1. B. 2. C. 3. D. 4. E. 5.
51

4.D.

Cu 29: Ancol sec - butylic l ancol bc: A. 1.B. 2. C. 3. D. 4. E. 0. Cu 30: Cho cc cht: C2H5OH(I); C2H5Cl(II); C2H5Br(III); C2H5F(IV); C3H8(V). Chiu tng dn nhit si ca cc cht: A. (V) < (IV) < (II) < (III) < (I). D. (IV) < (II) < (III) < (I) < (V). B. (V) < (II) < (IV) < (III) < (I). E. (IV) < (III) < (II) < (V) < (I).C. (III) < (II) < (IV) < (I) < (V). Cu 32: Cho s chuyn ha H2SO4, c H2O/H2SO4 CH3CH2CH2OH A B (spc) Tn gi ca B l: A. Propanol -2. B. C A,B u ng.C. Ancol iso-propylic. D. C A,B u sai. C. Ancol etylic. Cu 33: Buten-1 phn ng vi HCl thu c hp cht cha Clo. un nng hp cht ny vi dung dch NaOH c thu c ancol. un nng ancol va sinh ra vi H 2SO4 c nhit trn 170C cho ta mt anken. Cng thc cu to ca anken l:A. CH3CH=CHCH3. B. CH2=CHCH2CH2CH3 C. CH2=CHCH2CH3. D.Ktqukhc. C. (CH3)2C=CH2. Cu 34: Cho s chuyn ha: HCl NaOH H2SO4c Br2 H2O/ NaOH Buten-1 A B C D E Cng thc cu to E phi l: A. CH3CH2CH(OH)CH3. B.CH3CH2CHCH3. OH C. CH2-CHCH2CH3. OH OH D. CH3CHCHCH3. OH OH Cu 35: Cho s chuyn ha: HCl iso-Butilen

E. Kt qu khc.

ddNaOH A B C

Na

Cng thc cu to C phi l: A. (CH3)3C-ONa. D. CH3CH2CH(ONa) CH3. B. (CH3)2CHCH2ONa. E. Kt qu khc. C. CH3CH2CH2CH2ONa. Cu 36: Mt hn hp cha ng thi 2 ancol nguyn cht CH3OH v C2H5OH. Hi trong hn hp tn ti bao nhiu kiu lin kt hiro gia cc phn t?A. 1. B. 2. C. 3. D. 4. E. 5. Cu 38: Hy xc nh v tr sai trong tng hp: H2O HCl H2O C2H2 CH2= CH-Cl CH2= CH-OH polivinylic CaC2 (1) (2) (3) (4) A. (1) v (3). B. (3) v (4). C. (2) v (4). D. (2) v (3). E. (1) v (4). Cu 39: Cho s tng hp cao su Buna: 1500C, lm lnh nhanh(1) NH4Cl; CuCl(2) H2,Ni(3) CH C-CH=CH2 CH2=CH-CH=CH2 CH4 C2H2 o Na,t ,p(4) Caosu Buna .Hy xc nh v tr sai: A. (1) v (3). B. (3). C. (2) v (4). D. (2). E. (1) v (4). Cu 40: Khi tin hnh tch nc ancol etylic, c mt H2SO4 ta thu c: A. Etilen. D. C A,B,C B. ietyl ete. E. A v B. C. H2O. Cu 41: C th iu ch trc tip ancol etylic t:
52

A. C2H2. B. C2H4. C. CH3CHO. D. C B,C,D. E . C2H5Cl. Cu 42: C th iu ch ancol metylic t: A. HCHO. B. C A,B,C. C. CH3COOCH3. D. A v B. E . CH4. Cu 43: S oxi ha trung bnh ca C trong phn t CH3CH2OH l: A. 1. B. 2. C. -2. D. 3 E. -3. Cu 44: Bc ca ancol chnh l: A. S oxi ha ca nguyn t C m nhm -OH nh vo.B. Bc ca nguyn t C m nhm -OH nh vo. C. Bng s nhm -OH. D. A v B. E. A v C. Cu 45: Ancol no sau y khng tn ti? A. CH2=CH-OH. B. A v B.M C. CH3CH(OH)2. D. C A,B,C. C. CH2=CH-CH2OH. Cu 46: Ancol sau y khng bn: CH3-C(OH)=CH-CH3. N s chuyn ha thnh: A. Axit. B. A hoc B. C. Anehit. D. A hoc C. C. Xeton. Cu 47: Nguyn tc chuyn ancol n-propylic thnh ancol isopropylic l: A. Tch nc, ri li hp nc B. A v B. C. Oxi ha, ri li kh. D. A v C. C. Kh, ri li oxi ha. * Cu hi v bi tp nh lng: Cu 48: Cho 11g hn hp gm hai ancol no n chc k tip nhau trong dy ng ng tc dng ht vi Na thu c 3,36lit H2(o kc). Cng thc phn t ca 2 ancol trn l: C. C3H7OH v C2H5OH. A.CH3OH v C2H5OH B. C3H5OH v C2H5OH. C. CH3OH v C2H3OH D. Tt c u sai. Cu 49: Cho 16,6g hn hp gm ancol etylic v ancol n-propylic phn ng ht vi Na(ly d), thu c 3,36lit kh H2(kc). Thnh phn phn trm v khi lng tng ng ca hai ancol l: A. 72,3%v 27,7%. B. 50% v 50%. C. 46,3% v 53,7%. D. 27,7% v 72,3%. C. 40% v 60%. Cu 50: un nng mt hn hp gm 2 ancol no n chc vi H 2SO4c 140C thu c 21,6g H2O v 72g hn hp 3 ete(cho bit 3 ete thu c c s mol bng nhau). Cng thc cu to ca hai ancol phi l: A.CH3OH v C2H5OH. D. (CH3)2CHOH v C2H5OH. B. CH3OH v CH3CH2CH2OH. E. C2H5OH v CH3CH2CH2OH. C. (CH3)2CHOH v CH3CH2CH2OH. Dng cc thng tin sau cho cc cu hi 51 v 52. un nng 57,5g C2H5OH vi H2SO4c 170C. Hn hp cc sn phm dng hi c dn ln lt qua cc bnh cha dung dch H2SO4c; dung dch NaOH c v cui cng l dung dch Brom(d) trong CCl4. Sau khi kt thc th nghim, bnh cha Br2 nng thm 21g. Cu 51: Hiu sut ca phn ng tch nc t ancol l: A. 67,3%. B. 60%. C. 45,5%. D. 70%. E. 50%. Cu 52: Vai tr ca cc bnh cha dung dch H2SO4c v dung dch NaOH c ln lt l: A. H2SO4c gi nc, NaOH gi CO2. B. H2SO4c gi SO2, H2O; NaOH gi CO2. C. H2SO4c gi nc, NaOH gi CO2, SO2. D. H2SO4c gi nc, NaOH gi CO2. E. H2SO4c gi CO2, SO2; NaOH gi nc. Cu 53: Lng glucz cha trong nc qu nho sau khi ln men cho ta 100lit ancol vang 10 l bao nhiu. Cho bit hiu sut ca qu trnh l 95% v khi lng ring ca ancol nguyn cht l 0,8g/ml. A. 16475,97g. B. 14568,77g. C. 165974,86g. D. 15189,76g. E. 17896,98g. Dng cc thng tin sau cho cc cu hi 54 v 55. t chy 23g mt cht hu c A thu c 44g CO2 v 27g H2O. A c kh nng tc dng vi Na gii phng kh H2.Cu 54: Cng thc n gin nht ca A l: A. C2H2O. B. C3H6O. C. C2H4O. D. C2H6O. C. CH3O. Cu 55: Cng thc phn t A l: A. CH3OH. B. C3H6O. C. C2H4O2. D. C2H6O. E. C3H6O2. Dng cc thng tin sau cho cc cu hi 56; 57;58 v 59. Mt hn hp X gm 3 ancol n chc thuc cng mt dy ng ng. t chy mg hn hp X thu c 4,4g CO2 v 2,7g H2O.Cu 56: Cng thc tng qut ca 3 ancol phi l: A. CnH2n+2O(n 1). B. C A,C u ng .C. CnH2n-1OH(n 1). D. C A,C u sai. C. CnH2n+1OH(n 1). Cu 57: Khi lng ca hn hp 3 ancol l: A. 4,6g. B. 2,7g. C . 9,2g. D. 4,9g. C. 2,3g.
53

Cu 58: Th tch kh H2(kc) thu c khi cho 4,6g hn hp X tc dng Na d: A. 5,6lit. B. 3,36lit. C.0,112lit. D. 1,12lit. E. 2,24lit. Cu 59: Khi un hn hp X vi H2SO4c ta ch thu c anken c s nguyn t cacbon nh hn hoc bng 3. Cng thc cu to ca 3 ancol l: A.CH3OH; CH3CH2OH; (CH3)2CHOH. B. CH3CH2OH; (CH3)2CHOH; CH3CH2CH2OH. C. CH3CH2CH2OH; CH2=CH-CH2OH; (CH3)2CHOH. D. CH3OH; CH3CH2OH; CH3CH2CH2OH. E. Tt c u sai. Cu 60: 140g mt hn hp X gm CH3CH2OH v C6H6. Ly 1/10 hn hp cho tc dng Na d thu c 1,12lit H2(kc). % ca ancol trong hn hp l: A. 56,55%. B. 33,15% C. 21,31%. D. 32,85%. E. 42,83%. Dng cc thng tin sau cho cc cu hi 61 v 62. Mt hn hp X gm hai ancol CH3OH v C2H5OH c s mol theo t l 2:3. Khi cho hn hp tc dng vi Na d thu c 5,6lit H2(kc). Cu 61: S mol ca CH3OH v C2H5OH ln lt l: A. 0,15mol v 0,225mol B. 0,8mol v 1,2mol.C . 0,2mol v 0,3mol. E. Kt qu khc. C. 0,4mol v 0,6mol. Cu 62: Ly lng hn hp X trn em kh nc nhit thch hp phn ng ch cho ete, phn ng xy ra hon ton. Bit rng c hai ete c s mol bng nhau. % mi ete khng i xng theo s mol l: A. 40% B. 70%. C. 20%. D. 80%. E. 50%. Dng cc thng tin sau cho cc cu hi 63 v 64 Mt hn hp X gm hai ancol n chc A,B khi b kh nc(phn ng hon ton v ch cho anken) to ra hn hp hai kh c t khi hi i vi CH4 bng 2,333. Cho MB= MA+ 28. Cu 63: Cng thc phn t ca A, B ln lt l: A. C2H5OH v C4H9OH D. CH3OH v C3H5OH. B. C3H7OH v C5H11OH E. C2H5OH v C4H7OH. C. CH3OH v C3H7OH. Cu 64: Thnh phn phn trm ca hai ancol tng ng l: A. 66,7% v 33,3% B. 30% v 70%. C. 50% v 50%. D. Kt qu khc. E. 46% v 54%. Dng cc thng tin sau cho cc cu hi 65 v 66 t chy hon ton mt lng ancol n chc A th thu c 13,2g CO2 v 8,1g nc. Cu 65: A l ancolA. n chc, no. D. C B,C u ng. B. n chc, khng no E. n chc, khng no c hai ni i. C. n chc, khng no c mt ni i. Cu 66: Tn gi ca A l: A. Ancol etylic D. C A,B u ng. B. Etanol. E. C A,B u sai. C. Ancol metylic. Cu 67: Khi lng ete to thnh t 25g CH3OH nu phn ng ehidrat ha xy ra vi hiu sut l 80%: A. 12,2g. B. 7,2g. C. 9,7g D. 5.7g. E. 14,4g. Cu 68: Ngi ta iu ch c 6g ete t 18,4g etanol. Hiu sut sn phm trong phn ng ehidrat ha l: A. 50,5%. B. 40,5%.C. 45,9%. D. Kt qu khc. E. 40,6%. Cu 69: Mt cht hu c c th tham gia phn ng este ha, khng th hin r tnh axit. Bit rng khi chy to nn 2,64gCO2 v 1,44g nc. Cng thc c th c ca hp cht l: A. (CH3)2CHO B. C A,B. C. CH3CH2CH2OH. D. C A,B,C. C. C2H5OH. Cu 70: Khi ehidrat ha ancol no n chc ri ch ha sn phm vi lng d HBr, thu c 65,4g bromua vi hiu sut 75% l thuyt. Cng mt lng ancol khi tc dng vi Na gii phng 8,96lit kh ( iu kin tiu chun). Ancol l : A. CH3OH B. (CH3)2CHOH C. CH3CH2CH2OH. D. C4H9OH . C2H5OH. Cu 71: Khi oxi ha hon ton ancol n chc, thu c axit. trung ha 10g axit , cn 27ml dung dch KOH 20%(khi lng ring l 1,18g/ml). Cng thc cu to ca n l: A. CH3CH2CH(OH)CH3 B. C A,B,C .C. (CH3)2CHCH2OH. D. B v C. C. CH3CH2CH2CH2OH. Cu 72: Mt ancol no n chc bc mt tc dng vi Na gii phng 6,72lit kh (kc). Khi ehidrat ha cng mt khi lng ancol , thu c 33,6g mt olefin. Cng thc phn t ca ancol l: A. CH3CH2CH(OH)CH B. C A,B,C. C. (CH3)2CHCH2OH. D. B v C. C. CH3CH2CH2CH2OH.
54

Cu 73: Khi ehidrat ha gia cc phn t 30g ancol n chc cha bit thnh phn, thu c 3,6g nc vi hiu sut phn ng l 80% l thuyt. Trong phn t ancol trn c hai nhm metylen. Cng thc cu to ca ancol l: A. CH3CH2CH2OH B. (CH3)2CHOH. C. CH3CH2CH2CH2OH D. A v D. C. CH3CH2CH(OH)CH3. Dng cc thng tin sau cho cc cu hi 74 v 75: Mt lng ancol n chc cha bit thnh phn, khi ch ha vi Na, gii phng 2,24lit kh(kc). Cht hu c c to nn khi tc dng vi lng d ankylbromua to nn 20,4g hp cht i xng cha oxi. Cu 74: Khi lng ancol ly l: A. 11g. B. 12g. C. 13g. D. 14g. E. 15g. Cu 75: Cng thc cu to ca ancol l: A. CH3CH2CH2OH B. (CH3)2CHCH2OH.C. CH3CH2CH2CH2OH. D. A v D. E. CH3CH2CH(OH)CH3. Cu 76: Mt ancol no n chc khi chy to nn mt th tch kh CO2 gp 8 ln th tch H2 thot ra khi cng mt lng ancol tc dng vi lng d Na. Bit trong phn t ancol c 3 nhm metyl. Cng thc cu to ca ancol l: A. (CH3)3COH B. (CH3)2CHOH. . CH3CH2CH2CH2OH. D. Kt qu khc. E. CH3CH2CH(OH)CH3. Cu 77: Cho mt lng d Na vo 16,6g hn hp ca ancol etylic v propylic. Trn H2 sinh ra vi 4,48lit argon(kc), thu c hn hp c t khi so vi khng kh l 0,818. Thnh phn phn trm ca ancol etylic trong hn hp u l: A. 92,3% B. 64,9%. C. 27,7%. D Kt qu khc.E. 45,5%. Cu 78: Cho 1,85g mt ancol no n chc X tc dng vi Na d thu c 308ml kh H2(1atm v 27,3oC). Cng thc phn t ca X l: A. C2H5OH. B. C5H11OH. C. C3H7OH. D. Kt qu khc.E. C4H9OH. Cu2: Tn gi ca
OH

CH3

l:

A. p-crezol B. C A,B u ng. C. 4-metylphenol D. C A,B u sai. E. 3-metylphenol Dng cc thng tin sau cho cc cu hi 5 v 6. Trong mt hn hp gm phenol v xiclohexanol vi s mol bng nhau Cu 5: Trong hn hp trn tn ti bao nhiu kiu lin kt hiro. A. 4. B. 3. C. 2. D. 1. E. 5. Cu 6: Trong s cc loi lin kt hiro th kiu chim u th(bn vng nht) l: A. O ca ancol v H ca phenol. D. Ancol - ancol. B. O ca phenol v H ca ancol. E. Tt c u sai. C. Phenol - phenol. Cu 7: Cho cc cht: CH3OH(I), C2H5OH(II), C6H5OH(III),o-O2NC6H4OH(IV). Chiu tng dn linh ng ca nguyn t H l: A. (II)<(I)<(IV)<(III) B. (I)<(I)<(IV)<(III).C. (III)<(II)<(I)<(IV).D. (I)<(II)<(III)<(IV). E. (II)<(I)<(III)<(IV). Cu 8: Phn ng ha hc chng minh nguyn t H trong nhm -OH ca phenol linh ng hn H trong nhm -OH ca ancol etylic: A. Tc dng NaOH. B. C A,B u ng. C. Tc dng Na D. C A,B,C u ng. E. Tc dng vi axit( phn ng este ha). Cu 9: Cho s chuyn ha: H2SO4bc khi NaOH nng chy, d HCl Benzen A B C Tn gi ca C: A. Phenylclorua. B. Benzylclorua. C. Phenol. D. Tt c u sai. E. Natriphenolat. Cu 10: Cho s : Cl2,Fe Dung dch NaOH c d dung dch HCl A B C Phenol
55

Cng thc ca A l: A. C2H2. B. C6H5CH2CH3 .C. C6H6. D. C6H5Cl. E. C6H5CH3. Cu 11: ng vi cng thc phn t C7H8O s c bao nhiu ng phn phenol ? A. 2.B. 3. C. 4. D. 5. E. 1. Cu 12: C hai ng nghim ng hai cht: Phenol lng v ancol n-butylic. phn bit hai cht ta dng: A. Na. B. C B,C u ng.C. Dung dch Br2. D. C A,B,C u ng. E. HNO3/H2SO4 Cu 14: Khi cho phenyl clorua tc dng vi NaOH m c ta thu c: A. C6H5ONa. B. A hoc B. C. C6H5OH. D. C A,B,C. E. C6H5Na. Cu 15: Hy chn cm t ng nht in vo ch trng:Phenol l hp cht hu c m phn t ca chng c nhm -OH ...... vi nguyn t C ca vng benzen. A. Lin kt B. Ni vi. C. Lin kt trc tip. D. Tt c u sai. E. Tham gia lin kt. Cu 16: Trong s cc tnh cht vt l sau, tnh cht no l tnh cht ca phenol: A. t tan trong nc lnh B. A, B, C u ng.C. Rt c. D. C A,B,C u sai. C. Tinh th khng mu. Cu 17: T phenol ngi ta c th iu ch cc cht sau: A. 2,4-D. B. Phenolfomandehit. C. 2,4,5-T. D. Tt c cc cht trn. E. Axit picric Cu 18: Trong s cc cht sau: Dung dch Br2, Na, NaOH, HCl, CH3COOH. Phenol phn ng c vi cht no? A. Br2, Na, NaOH. B. Dung dch Br2, Na, CH3COOH. C. NaOH, HCl, CH3COOH. D. Tt c cc cht trn. E. Dung dch Br2, Na. Cu 20: Dng ha cht no sau y phn bit phenol v ancol etylic? A. Na B. C 3 cu trn.C. Dung dch Br2. D. B v C. C. HNO3 /H2SO4. Cu 21: Dng ha cht no sau y phn bit phenol v ancol benzylic? A. Na B. C 3 cu trn C. Dung dch Br2. D. B v C. C. HNO3/H2SO4. Cu 22: Dng ha cht no sau y chng minh s c mt phenol trong hn hp gm: Phenol, ancol benzylic v etanol? A. Na B. A v C. C. Dung dch Br2. D. C v B. E. HNO3/H2SO4. Cu 23: Trong s cc ha cht sau, ha cht no dng phn bit ancol allylic v phenol? A. NaOH B. B v C. C. Dung dch Br2. D. A v B. E. HNO3/H2SO4. Cu 24: Trong s cc tnh cht sau, tnh cht no khng phi l ca phenol? A. C tnh axit yu B. To kt ta trng vi HNO3/H2SO4c. C. Rt c. D.C v D. C. Tc dng vi ancol etylic to este. Cu 25: T phenol ngi ta c th iu ch: A. Aspirin. B. Phenolphtalein. C. Metylsalixilat. D. C 4 cu trn. E. Phenolfomandehit. Cu 26: c im ca lin kt gia O v H trong nhm -OH ca phn t phenol l: A. B phn cc mnh B. Lin kt ion.C. B phn cc mnh v pha Oxi.D. Tt c u sai. C. Khng phn cc. Cu 27: Hp cht A c cng thc phn t C7H8O, bit rng A c kh nng tc dng vi NaOH v vi Na gii phng kh H2 . Cng thc cu to ca A l: A. C6H5OCH3. B. p-HOC6H4CH3. C. o-HOC6H4CH3. D. B,C, v D. E. m-HOC6H4CH3. Cu 28: Hp cht B c cng thc phn t C7H8O, bit rng B khng c kh nng tc dng vi Na gii phng kh H2 cng nh tc dng vi NaOH. Cng thc cu to ca B l: A. C6H5OCH3. B. p-HOC6H4CH3. C. o-HOC6H4CH3. D. B,C, v D. E. m-HOC6H4CH3. * Cu hi v bi tp nh lng: Cu 29: Mt dung dch cha 6,1g cht ng ng ca phenol n chc. Cho dung dch trn tc dng vi nc Br2 (d) thu c 17,95g hp cht cha 3 nguyn t Br trong phn t. Cng thc phn t cht ng ng ca phenol l: A. C2H5C6H4OH. B. C2H5CH3C6H3OH. C. (CH3)2C6H3OH. D. A hoc B. E. (C2H5)2C6H3OH. Cu 30: Mt hn hp gm CH3OH; C2H5OH; phenol c khi lng 28,9g. Chia hn hp thnh hai phn bng nhau lm hai th nghim. Phn mt phn ng hon ton vi Na ta thu c 2,806lit H 2 27C, 750mmHg. Phn hai phn ng va ht vi 100ml dung dch NaOH 1M. Phn trm theo khi lng phenol l: A. 36,87%. B. 65,05%.C. 76,89%. D. 32,65%. E. 12,34%.
56

Dng cc thng tin sau cho cc cu hi 31v 32 Mt hn hp X gm benzen; phenol; v etanol. Ly 142,2g hn hp v chia lm hai phn bng nhau.1/2 hn hp va trung ha 20g NaOH. 1/2 hn hp cn li tc dng Na d thu c 6,72lit H2(kc). Cu 31: Khi lng ca phenol trong hn hp X bng: A. 7,05g. B. 4,7g. C. 18,8g. D. 9,4g. E. 14,1g. Cu 32: tch phenol ra khi hn hp ta lm: A. Cho hn hp tc dng NaOH. Sau chng ct, ly phn cn li cho tc dng CO2 d thu ly phenol. B. Cho hn hp tc dng Na. Sau chng ct, ly phn cn li cho tc dng CO2 d thu ly phenol. C. Khng th tch ly phenol. D. C A,B u ng. E. C A,B u sai. Cu 33: t chy 5,8g cht A ta thu c 2,56g Na2CO3; 2,26g H2O; v 12,1gCO2. Bit rng 1 phn t A ch cha 1 nguyn t O. Cng thc phn t ca A l : A. CH3COONa. B. C3H7ONa. C. C6H5CH2ONa. D. C6H5ONa. E. C2H5ONa. Cu 34: Khi nitro ha 10g phenol bng HNO350% thu c 17g hp cht nitro trong phn khi lng ca N l 17%. Hiu sut phn ng nitro ha l: A. 40 %. B. 50%. C. 60%. D. 70%. E. 55%. Cu 2: Cng thc cu to ca anehit acrylic l: A. CH3CH2CHO. B. (CH3)2CHCHO. C. CH3CHO . D. Tt c u sai. C. CH2 = CH - CHO. Cu 3: Cho hp cht A:
CHO CH3

Tn gi ca A l:A. 2- Metylxiclopentan -1- cacbanehit. D. C A, B u ng. B. 2-Metylxiclopentan. E. C A, B, C u sai. C. 2- Metylxiclohexanal. Cu4:Cho hpcht B: (CH3)2CHCHO. Tn gi quc t ca B l: A. 2- Metylpropanal. B. C A, B u ng. C. Isobutanal. D. C A, B u sai E. Isopropanal. Cu 5: Cho cc cht: HCHO(I); CH3CHO(II); C2H5Cl (III) ; CH3OH (IV) Chiu gim dn nhit si ca cc cht:A. (IV) > (III) > (II) > ( I). B. (IV) > (II) > (I) > (III). C. (IV) > (II) > (III) > (I). D. (II) > (IV) > (III) > (I). E. (IV) > (I) > (III) > (II). Cu 6: Cho cc cht: Axeton, anehit axetic, ancol isopropylic. nhn bit anehit axetic ta dng ha cht: A. AgNO3/NH3. B. C A, B, C u ng. C. [Ag(NH3)2]OH. D. C A, B, C u sai E. Cu(OH)2/NaOH. Cu 7: Focmon l dung dch anehit focmic trong nc c nng : A. 2-5%. B. 50-70%. C. 10-20%. D. 75-80%. E. Khong 40%. Dng cc thng tin sau cho cc cu hi 8 v 9. Cho s chuyn ha : Vi ti, xt Cl2,as dung dch NaOH CuO,to AgNO3/NH3 CH3COONa A B C D E Cu 8: Cng thc cu to ca A l: A. CH3ONa. B. C2H2. C. CH4. D. CH3CH2OH. E. C2H4. Cu 9: Cng thc cu to ca E phi l: A. HCHO. B. HCOONH4. C. C2H5OH. D. CH3COOH. E. HCOOH. Cu 10: Trong phn ng trng ngng gia phenol v anehit fomic, xc tc c dng l: A. Dung dch axit. B. C A v B u sai. C. Dung dch baz. D. Cht xc tc khc. E. C A v B u ng. Dng cc thng tin sau cho cc cu hi 11 v 12. Cho s chuyn ha: Cl2, as dung dch NaOH CuO,tO phenol,xt A B C D nha phenolfomaehit. Cu 11: Cng thc ca A l: A. C2H2. B. C6H6. C. C2H6. D CH3Cl. E. CH4. Cu 12: Cng thc cu to ng ca C l: A. CH3-OH. B. CH3Cl. C. H-CHO. D. CH3CH2OH. E. CH3CHO. Cu 13: T C2H2 iu ch HCHO cn t nht bao nhiu phn ng: A. 6. B. 2. C. 3. D. 4. E. 5. Cu 14: Sp xp nhit si ca cc cht sau theo th t tng dn: C2H6(I); CH3Cl(II); CH3OH(III); CH3CHO(IV). A. (I) < (II) < (IV) < (III). D. (I) < (IV) < (II) < (III).
57

B. (I) < (III) < (II) < (IV). E. (I) < (II) < (IV) < (III). C. (I) < (IV) < (II) < (III). Cu 15: Khi t chy mt anehit no, n chc, mch h thu c: A. S mol nc bng s mol CO2. B. S mol nc ln hn s mol CO2. C. S mol nc b hn s mol CO2.D. S mol nc bng 2 ln s mol CO2. E. Tt c u sai. Cu 16: C th dng thuc th no phn bit ng thi 3 cht lng sau: Metanol; pentin-1; etanal. A. Dung dch Br2. B. AgNO3/NH3.C. Na. D. Ha cht khc. E. Cu(OH)2/NaOH. Cu 17: iu ch CH3CHO t Al4C3 cn t nht bao nhiu phng trnh phn ng: A. 2. B. 3.C. 4.D. 5.E. 6. Cu 18: CH3CHO c th iu ch trc tip t: A. CH4. B. C B,C u ng. C. C2H2. D. C A ,B u ng. E. C2H4. Cu 19: Axetanehit c th c tng hp trc tip t: A. Vinylaxetat. B. C ba u ng. C. C2H4. D. C A,B,C u sai. E. C2H2. Cu 20: Cc anehit th hin tnh kh trong phn ng vi cht: A. H2/Ni, to. B. O2. C. AgNO3/NH3. D. C B, C, D u ng. E. Cu(OH)2/NaOH. Cu 21: Cc anehit th hin tnh oxi ha trong phn ng vi cht: A. H2/Ni, to. B. O2. C. AgNO3/NH3. D. C B, C, D u ng. E. Cu(OH)2/NaOH. Cu 22: Khi oxi ha ancol no sau y th thu c anehit: A. (CH3)2CHOH. B. C 3 u ng. C. (CH3)3COH. D. C A,B,C u sai. E. CH3CH(OH)C2H5. Cu 23: ng vi cng thc phn t C3H6O s c bao nhiu ng phn v anehit? A. 1. B. 2. C. 3. D. 4. E. 5. Cu 24: ng vi cng thc phn t C4H8O s c bao nhiu ng phn v anehit?A. 1. B. 2.C. 3.D. 4. E. 5. Cu 25: ng vi cng thc phn t C5H10O s c bao nhiu ng phn v anehit?A. 1. B. 2.C. 3.D. 4. E. 5. Cu 26: Hp cht no sau y khng cha nhm -CHO? A. HCOOCH3. B. HCHO.C. CH3CHO. D. C A,C. E. CH3COOH. Cu 27: Trong s cc cht sau cht no khng tc dng c vi AgNO3/NH3? A. HCHO. B. CH3CHO. C. C2H2. D. Tt c u sai. E. HCOOCH3. Cu 28: Trong s cc cht sau, cht no dng lm nguyn liu u iu ch nha phenolfomandehit? A. HCHO. B. CH3CHO. C. C2H2. D. C A v C. E. C6H5OH. Cu 29: Trong s cc cht sau, cht no dng ngm xc ng vt? A. Dung dch HCHO.B.Dung dch CH3CHO.C. Dung dch CH3COOH. D. C A v C.E. Dung dch CH3OH. Cu 30: Trong s cc tnh cht sau, tnh cht no khng phi l tnh cht ca anehit axetic? A. Tc dng NaOH. B. Trng ngng to polime. C. Tc dng AgNO3/NH3. D.C A v D. E. Tc dng Cu(OH)2NaOH. Cu 31: Trong s cc tnh cht sau, tnh cht no khng phi l tnh cht ca anehit acrylic? A. Tc dng vi dung dch Br2. B. Tc dng vi ancol metylic. C. Tc dng vi Na. D. Trng hp. E. Tc dng vi O2,to. Cu 32: Pht biu no sau y l khng chnh xc? A. Anehit va c tnh oxi ha va c tnh kh.B. Anehit ch c tnh oxi ha.C. Anehit ch c tnh kh. D. So vi ancol tng ng th anehit c nhit si cao hn. E. C B,C,D. Cu 33: Ha cht no sau y dng phn bit anehit fomic v phenol? A. Na. B. C A,B,C. C. AgNO3/NH3. D.E. A v B. E. Cu(OH)2/NaOH Cu 34: Ha cht no sau y dng phn bit anehit fomic v anehit axetic? A. AgNO3/NH3. B. Tt c u sai. C. Na. C. A v B. E. H2. Cu 35: Ha cht no sau y dng phn bit anehit fomic v phenol? A. Dung dch Br2. B. A v B C. Na. D. C A,B,C. E. HNO3/H2SO4c. Cu 36: Ha cht no sau y dng phn bit HCHO v CH2=CHCHO? A. Dung dch Br2. B. C A,C. C. Qu tm. D. Khng phn bit c. E. Kali. Cu 37: Ha cht no sau y dng phn bit anehit fomic v ancol metylic? A. Na. B. C A v B. C. AgNO3/NH3. D. C A,B,C. E. Cu(OH)2/NaOH.
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Cu 38: Ha cht no sau y dng chng minh s c mt ca anehit axetic trong hn hp: Anehit axetic, ancol etylic v nc? A. Na. B. Na2CO3 C. AgNO3/NH3. D. C A,B. E. Qu tm. Cu 39: Ha cht no sau y dng chng minh s c mt ca anehit acrylic trong hn hp: Anehit acrylic, ancol etylic? A. Dung dch Br2. B. Na2CO3. C. AgNO3/NH3. D. C A,B. E. Qu tm. Cu 40: Mt hp cht A c cng thc C3H6O, bit rng A khng phn ng vi Na, nhng c tham gia phn ng trng gng. Cng thc cu to ng ca A phi l: A. CH3COCH3. B. C3H5OH. C. CH3CH2CHO. D. Tt c u sai.E. CH2=CH-CH2OH. Cu 41: Hp cht X c cng thc phn t C4H8O, X tc dng vi dung dch AgNO3/NH3 th to ra kt ta Ag. Cng thc cu to c th c ca A l: A. (CH3)2CHCHO. B. C A v B.C. CH3CH2CH2CHO. D. C A,B,C. E. CH2=CHCH2CHO. Cu 42: Khi cho hp cht Y c cng thc phn t l C3H8O tc dng vi O2, un nng c xc tc CuO th thu c sn phm Z. Z c kh nng tham gia phn ng trng gng. Cng thc cu to ng ca X phi l: A. CH3CH2CH2OH. B. CH3CH2OCH3.C. CH3CH(OH)CH3. D . Tt c u sai.E. CH3OCH2CH3. Cu 43: Cho CH3OH phn ng vi CuO nng , ly d, thu c anehit fomic. Cho hn hp rn cn li sau phn ng tc dng ht vi HNO3 ta thu c 0,734lit NO2 ( 27oC, v 765 mmHg). Khi lng anehit sinh ra l: A. 0,45g. B. 0,225g. C. 0,9g. D. Kt qu khc. E. 0,18g. Dng cc thng tin sau cho cc cu hi 44 v 45. Cho 0,87g mt anehit no, n chc phn ng hon ton vi Ag2O/NH3 thu c 3,24g Ag. Cu 44: Cng thc cu to ca anehit l: A. CH3CHO. B. CH3CH2CH2CHO. C. HCHO. D. (CH3)2CHCHO. E. C2H5CHO. Cu 45: Cho 11,6 g anehit trn phn ng vi H2/Ni (h=100%). Th tch H2 cn phn ng iu kin chun l: A. 2,24 lit. B. 3,36 lit. C. 4,48 lit. D. Kt qu khc.E. 1,12 lit. Cu 46: Khi cho 0,75g anehit fomic phn ng hon ton vi dung dch AgNO3/NH3 d th khi lng Ag gii phng l: A. 10,8. B. 21,6g. C. 2,7g. D. Kt qu khc. E. 5,4g. Cu 47: Cho 13,89ml dung dch anehit focmic 25%(d=1,08g/ml) phn ng vi Cu(OH)2/NaOH d. Sau phn ng thu c 17,28g kt ta gch. Hiu sut ca phn ng l: A. 93,75%. B. 45,78%. C. 64,03%. D. 28,7%. E. 48,00%. Cu 48: Oxi ha 8g ancol metylic bng CuO ri cho anehit tan vo 10g nc. Nu hiu sut phn ng l 80% th nng anehit trong dung dch l: A. 67%. B. 44,4%. C. 37,5%. D. 45.9%. E. 76,6%. Cu 49: iu ch anehit fomic t CH2(COONa)2 cn t nht bao phng trnh phn ng: A. 1. B. 2. C. 3. D. 4. E. 5. Cu 50: Trong mt bnh kn dung tch 9lit cha hn hp kh HCHO v H 2. Khi nhit ca bnh l 27oC th p sut trong bnh l 2,05atm. Nung nng bnh c xc tc Ni cho phn ng xy ra hon ton. Sau a v nhit ban u th p sut trong bnh lc ny l 1,64atm. T l % khi lng ca anehit focmic l: A. 20%. B. 30%. C. 40%. D. 60%. E. 80%. Cu 51: Trong cng nghip ngi ta iu ch anehit focmic bng cch oxi ha ancol metylic bng oxi khng kh c xc tc ng kim loi 500-700oC. thu c 6,11m3 HCHO( 25oC,1atm) cn dng bao nhiu lit CH3OH (bit d=0,792g/ml v hiu sut ca phn ng oxi ha l 80%) A. 10,1lit. B. 12,63lit. C. 11,84lit. D. Kt qu khc. E. 13,47lit. Cu 52: Anehit fomic c th c tng hp trc tip bng cch oxi ha CH4 bng O2 c xc tc V2O5 20oC. Tnh khi lng HCHO thu c nu ban u dng 4,48m 3 CH4( kc). Hiu sut ca phn ng l 75%. A. 3kg. B. 5,4kg. C. 4,5kg. D. 7.9kg. E. 4,8kg. Cu 53: Mt anehit axetic k thut c em thc hin phn ng trng gng. Nu dng 1,6g anehit axetic k thut trn ngi ta thu c lng bc kim loi kt ta ti a l 6,48g. Hm lng tp cht trong anehit k thut trn l: A. 12,5%. B. 25,5%. C. 21,5%. D. 43,6%. E. 17,5%. Cu 54: Axetanehit l hp cht trung gian c s dng tng hp axit axetic lm nguyn liu tng hp este. Nu ngi ta dng 2,56kg Axetanehit k thut(14% tp cht) th thu c bao nhiu kg dung dch CH3COOH 80%. Nu hiu sut phn ng l 100%. A. 5,9kg. B. 3,75kg. C. 4,6kg. D. 3kg. E. 3,25kg.
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Cu 55: Cho 1,02g hn hp hai anehit A v B k tip nhau trong dy ng ng ca anehit no, n chc phn ng vi dung dch AgNO3/NH3 un nng thu c 4,32gAg. Cng thc ca A,B l: A. HCHO v CH3CHO. D. C2H3CHO v C3H5CHO. B. CH3CHO v C2H5CHO. E. CH3CHO v C2H3CHO. C. C2H5CHO v C3H5CHO. Cu 56: Cho 0,92g hn hp gm axetilen v anehit axetic phn ng hon ton vi dung dch AgNO3/NH3 d th thu c 5,64g hn hp rn. Thnh phn phn trm v khi lng ca axetilen trong hn hp l: A. 28,26%.* B. 32,98%. C. 35,54%. D. 43,90%. E. 23,45%. Dng cc thng tin sau cho cc cu hi 57,58 v 59. Oxi ha mg ancol n chc bc mt A bng CuO nhit cao th thu c anehit B. Hn hp kh v hi thu c sau phn ng c chia lm ba phn bng nhau.Phn 1 cho tc dng vi Na d th thu c 5,6lit kh H2(kc).Phn 2 cho tc dng dung dch AgNO3/NH3 d th thu c 64,8gAg.Phn 3 em t chy hon ton bng O2 c 33,6lit(kc) v 27gH2O.Cu 57: Hiu sut phn ng oxi ha ancol thnh anehit l: A. 60%. B. 67%. C. 34%. D. Kt qu khc. E. 65%. Cu 58: Cng thc cu to ca A l: A. C2H5OH. B. CH2=CH-CH2OH. C. CH3OH. D. CH2=CH- CH2CH2OH. E. C3H7OH. Cu 59: Gi tr ca m l: A. 87g. B. 29g. C. 58g. D. 34g. E. 45g. Cu 60: Khi thm mt lng d dung dch AgNO3/NH3 vo 1,46g hn hp CH3CHO v C2H5CHO, thu c 6,48g kt ta. Thnh phn phn trm theo khi lng ca CH3CHO trong hn hp l: A. 60,3%. B. 34,6%. C. 39,7%. D. Kt qu khc. E. 45,5%. Cu 61: hiro ha c xc tc 17,8g hn hp anehit fomic v anehit axetic n cc ancol tng ng, cn n 11,2lit H2(kc). Khi lng anehit fomic trong hn hp l: A. 50,6%. B. 24,9%. C. 49,4%. D. Kt qu khc. E. 34,7%. Cu 62: Mt hn hp fomandehit v H2 c t khi so vi H2 l 4,5 sau khi i qua cht xc tc Ni, t khi ca hn hp lm lnh n 0oC so vi H2 l 3. Hiu sut ca sn phm phn ng l: A. 20%. B. 40%. C. 30%. D. Kt qu khc. E. 60%. Cu 63: un nng 6,36g anehit cha bit vi hn hp thu c khi cho 22,4g CuSO4 tc dng vi kim. Lc kt ta c to nn v gi 150oC cho n khi c khi lng khng i th thu c 10,24g cht rn. Cng thc cu to c th c ca anehit l: A. HCHO. B. CH2=CHCHO C. C6H5CHO. D. C2H5CHO. E. CH3CHO. Cu 64: Khi oxi ha mt mol cht hu c cha bit bng dung dch KMnO 4, thu c 46g K2CO3, 66,7gKHCO3, 116gMnO2 v nc.Cht hu c l: A. HCHO. B. C2H5CHO. C. CH3CHO. D. C6H5CHO. E. CH2=CHCHO. Cu 65: Cht A tham gia phn ng trng gng. Cht A b oxi ha thnh cht B. Cht B phn ng vi CH3OH khi c mt H2SO4c to nn cht C c mi d chu. Cht C chy to nn kh CO2 c th tch ln gp 1,5 ln th tch thu c khi t chy cht B. Cng thc ca A l: A. CH3CHO. B. C2H5CHO. C. HCHO. D. C3H7CHO. E. CH2=CHCHO. Cu 2: Cng thc chung ca cc axit cacboxylic n chc, no, mch h l: A. CnH2nO2(n 0). B. CnH2n+1-2kCOOH(n 0).C. CnH2n+1COOH(n 0).B. Tt c u sai. D. (CH2O)n. Cu 3: Axit cacboxylic n chc, no A c t khi hi so vi xy l 2,75. Vy cng thc phn t ca A l: A. C2H4O2. B. C4H6O2. C. C3H6O2. D. C5H10O2. E. C4H8O2. Cu 4: Tn quc t ca axit cacboxylic c cng thc cu to
CH3 CH CH3 CH CH3 COOH

l: A. Axit 2-metyl - 3 - etylbutanoic. D. Axit isohexanoic. B. Axit 3-etyl - 2 - metylbutanoic. E. Axit - i -2,3 - metylpentaoic. C. Axit 2,3 - imetylpentanoic. Cu 5: mnh ca cc axit: HCOOH(I), CH3COOH(II), CH3CH2COOH(III), (CH3)2CHCOOH(IV) theo th t tng dn l:
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A. I < II < III < IV. B. IV < III < II < I. C. II < IV < III < I. D. Tt c u sai. E. IV < II < III < I. Cu 6: phn bit HCOOH v CH3COOH ngi ta dng: A. Dung dch NaOH. B. C A,,C u sai. C. Na. D. C A,B,C u ng. E. AgNO3/NH3. Cu 7: phn bit HCOOH v CH2 = CH-COOH ngi ta dng: A. Dung dch Brom. D. C A,B,C u sai. B. AgNO3/NH3.E. C A,B,C u ng. C. Cu(OH)2/NaOH. Cu 8: Tn gi ca axit CH2 = C(CH3)COOH l: A. Axit 2-metylpropenoic. B. A, B,C u ng. C. Axit 2-metyl-2- propenoic. D. C A,B,C u sai. E. Axit metacrylic. Cu 9: Tn gi ca axit (CH3)2CHCOOH l: A. Axit 2-metylpropanoic. B. C A, B, C u ng. C. Axit isobutyric. D. C A, B u ng.E. Axit butyric. Cu 10: phn bit CH3COOH v C2H5OH ngi ta dng: A. Na. D. Dung dch Brom. B. NaOH. E. Tt c u sai. C. Dung dch H2SO4. Cu 11: Cho cc cht: C2H5Cl (a), CH3CHO (b), CH3COOH (c), CH3CH2OH (d). Nhit si ca cc cht gim dn nh sau: A. (d) > (b) > (c) > (a). B. (c) > (a) > (b) > (d). C. (a) > (c) > (b) > (d). D. (c) > (b) > (a) > (d). E. (c) > (d) > (b) > (a). Cu 12: Cho cc cht ClCH2COOH (a), BrCH2COOH (b), ICH2COOH (c), FCH2COOH (d). Chiu tng dn tnh axit ca cc cht trn l:A. (a) < (b) < (c) < (d). D. (c) < (a) < (b) < (d) B. (b) < (a) < (c) < (d). E. (c) < (b) < (a) < (d). C. (a) < (b) < (d) < (c). Cu 13: Chn pht biu sai: A. HCOOH l axit mnh nht trong dy ng ng ca n.B. HCOOH c tham gia phn ng trng gng. C. HCOOH khng phn ng c vi Cu(OH)2/NaOH. D. HCOOH c tnh axit yu hn HCl. E. HCOOH c tnh axit mnh hn axit H2CO3. Cu 14 : Cho cc cht : C6H5COOH (a), p-H2NC6H4COOH (b), p-O2NC6H4COOH (c). Chiu tng dn tnh axit ca dy trn l : A. (a) < (b) < (c). D. (c) < (a) < (b) .B. (a) < (c) < (b). E. (b) < (a) < (c). C. (b) < (c) < (a). Cu 15: Chn cu tr li sai cho cu hi: Axit axetic c th iu ch trc tip t cht no? A. CH3CHO. D. CH3CCl3. B. C2H5OH. E . CH 3OCH3. C. nButan. Cu 16 : Chn cu tr li ng nht cho cu hi : V sao axit axetic c nhit si cao hn hn anehit axetic? A. Gia cc phn t axit c lin kt hidro mnh. B. Phn t lng ca axit ln hn. C. Phn t axit axetic phn cc hn. D. Anehit axetic khng c tnh axit. E. Axit axetic tan nhiu trong nc. Cu 17: Chn cu tr li ng nht cho cu hi: V sao tan ca cc axit cacboxylic no, n chc, mch h trong nc gim dn khi tng s nguyn t cacbon trong mch? A. Khi lng phn t tng. B . Tnh axit gim. C. Kch thc gc hidrocacbon tng, tnh k nc tng. D. phn cc ca phn t gim. E. Lc lin kt hiro gim. Cu 18: Gim n l dung dch c nng 2 - 5% ca: A. Axit fomic. D. Axit propionic. B. Axit axetic. E. Axit butyric. C. Axit acrylic. Cu 19: Phn ng este ha c c im l: A. Xy ra chm. D. Ch xy ra i vi axit hu c. B. Thun nghch. E. C A, B, C u ng. C. Xy ra khng hon ton. Cu 21: Trong phn ng: CH3 - CH2 - CH2 - COOH + Cl2 A S X(spc) + HCl Cng thc cu to ca X l: A. CH2Cl - CH2 - CH2 - COOH. D. CH3 - CHCl - CHCl - COOH. B. CH3 - CHCl - CH2 - COOH. E. Cng thc khc. C. CH3 - CH2 - CHCl - COOH. Cu 22: Trong phn ng: CH3COOH + CH CH A.
to

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Cng thc ca A l: A. CH3OCOCH=CH2. D. CH3CH=CHCOOH.B. CH3COOCH=CH2.E. Tt c u sai.C. CH2=CHCH2COOH. Cu 23: Trong phn ng: CH2= CH COOH + HBr X (spc) Th cng thc ca X l: A. CH2CHBrCOOH. D. CH2BrCH2COOHB. CH2BrCHCOOH.E. CH3CH2(OH)COBr. C. CH3CHBrCOOH. Cu 24: Khi oxi ha C6H5CH2CH2CH2CH3 bng KMnO4/H2SO4 c ngi ta thu c cc sn phm l: A. C6H5CH2COOH v CH3COOH. B. C6H5CH2CH2COOH v HCOOH. C. C6H5COOH v CH3CH2COOH. D. C6H5CH2CH2CH2COOH. E. C6H5CH2CH2COOH v CH3COOH. Cu 25: S ng phn axit ca C4H6O2 l: A. 2.B. 3. C. 4. D. 5. E. 6. Cu 26: Khi t chy axit cacboxylic n chc, no, mch h th thu c: A. Khi lng CO2 bng khi lng nc.B. S mol nc bng s mol CO2.C. S mol nc ln hn s mol CO2. D. S mol nc b hn s mol CO2. E. S mol nc bng hai ln s mol CO2. Cu 27: Mt axit cacboxylic n chc c cng thc n gin nht l C 2H3O. Cng thc cu to c th c l: A. CH2=CH-CH2COOH. D. C A,B,C u ng. B. CH2=C(CH3)COOH. E. C A,B,C u sai. C. CH3CH=CHCOOH. Cu 28: tng hiu sut ca phn ng este ha ngi ta cn: A. Tng nng ca axit. D. Tt c u ng. B. Tng nng ca ancol. E. Tt c u sai. C. Dng H2SO4 c ht nc. Cu 29: Trong cc ng phn axit cacboxylic khng no, mch h c cng thc phn t l C 4H6O2. Axit c ng phn cis- trans l: A. CH2=CH-CH2COOH. D. Tt c u c ng phn cis- trans. B. CH3CH=CHCOOH. E. Khng cht no c ng phn cis- trans. C. CH2=C(CH3)COOH. Cu 30: Pht biu no sau y l sai: A. Axit acrylic mnh nht trong dy ng ng ca n. B. Axit acrylic mnh hn axit benzoic.* C. Axit acrylic mnh hn axit propionic. D. Axit acrylic c th lm mt mu dung dch Br2. E. A v B. Cu 31: Trong s chuyn ha sau: Cl2, AS H2O/NaOH CuO, to AgNO3/NH3 C2H6 A B C D Th C l: A. CH3COOH. D. CH3COONH4. B. CH3CH2OH. E. C2H5Cl. C. CH3CHO.* Dng cc thng tin sau cho cc cu hi 32, 33 v 34. Cl2, as H2O/NaOH O2, xt Na2CO3 NaOH/CaO Cho s : A B C D F CH4 Cu 32: F l cht no trong s cc cht sau y: A. CH3CH2CH2COONa. D. HCOONa.B. CH3CH2COONa. E. CH2(COONa)2. C. CH3COONa. Cu 33: Cng thc cu to ca D l: A. CH3CH2OH. D. CH3COOCH3. B. CH3CHO. E. HCOOCH3. C. CH3COOH. Cu 34: Tn gi ca A l: A. Axetilen. D. Metan. B. Etilen. E. Propan. C. Etan.* Dng cc thng tin sau cho cc cu hi 35 v 36. Cho s : Cl2, 500oC NaOH CuO,to AgNO3/NH3 G A B D E Bit G l amoniacrylat. Cu 35: Cng thc cu to ca D l: A. CH2=CH-CHO. D. CH3CH(OH)COOH. B. CH2(OH)CH2COOH. E.CH3CH2CH2OH.C.CH2=CHCH2OH. Cu 36: Cng thc cu to ca A l: A. CH3CH=CH2 D. CH2=CH2B. CH3CH=CHCH3. E. Tt c u sai. C. CH2=C=CH2
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Cu 37: S c mt ca nhm nh chc -COOH trn nhn benzen gy nn hin tng no sau y ca axit benzoic. A. Lm gim mt electron trong nhn benzen. B. Phn hot ha phn t i vi phn ng th Br2. C. ng hng cc nhm th vo v tr octo v para.D. Cc hin tng A,B E. Cc hin tng A,B,C. Cu 38: Xt cc phn ng sau: (1). CH3COOH + Na (2). CH3COOH + NaCl (3). C6H5OH + NaHCO3 (4). C17H35COONa + Ca(HCO3)2 Phn ng no trong cc phn ng trn khng xy ra: A. 1. D. 4. B. 2. E. C B,C. C. 3. Cu 39: Cho axit
Cl CH3CH2 C Cl CH CH3 COOH

Axit trn c tn l:A. 3,3- iclo-2- metylpentanoic. B. Axit 3,3- iclo-2- metylpentanoic. C. 2-Metyl-3,3-iclopetanoic. D. Axit 3,3- iclo-3-etyl-2- metylpropanoic. E. Tt c u sai. Cu 40: Tn quc t ca (CH3)2CHCOOH l: A. Axit iso-butiric. D. Axit isopropylcacboxylicB. Axit 2-metylpropanoic. E. Tt c u ng. C. Axit propan-2-cacboxylic. Cu 41: Hy cho bit tn sn phm E trong s tng hp sau: H2SO4c, 170oC B B + NaOH C + NaCl CH3CH2OH A + H2O. A + Cl2 D + Cu + H2O C + CuO [O] D E A. Axit oxalic. D. Axit axetic. B. Anehit oxalic. E. Axit acrylic. Dng cc thng tin sau cho cc cu hi 42 v 43. Cho s : NaOH A B G Cao su Buna C. Axit fomic

C D poli(metylacrylat). Cu 42: Cng thc cu to ca D l: A. CH3CH2COOH. D. CH3OH. B. CH2=C(CH3)COOH. E. C2H5OH. C. CH2=CHCOOH. Cu 43: Tn gi ca A l: A. Vinyl propionat. D. Etyl acrylat. B. Metyl metacrylat. E. Tt c u sai. C. Vinyl acrylat. Cu 44: Cho cc cht sau: C6H5COOH(a); o-O2NC6H4COOH(b); m-O2NC6H4COOH(c); pO2NC6H4COOH(d). Chiu tng dn tnh axit ca cc cht trn l: A. b < a < d < c. D. c < a < b < d. B. b < c < a < d. E. b < a < c < d. C. a < b < c < d. Cu 45: Cho cc cht sau: C6H5COOH(a); o-HOOCC6H4COOH(b); m-HOOCC6H4COOH(c); pHOOCC6H4COOH(d). Chiu tng dn tnh axit ca cc cht trn l: A. b < a < d < c. D. c < a < b < d. B. b < c < a < d. E. a < c < d < b. C. a < b < c < d. Cu 46: Cho axit HOOC-CH2CH2CH2CH2CH2-COOH Tn gi ca axit trn l: A. Axit aipic. D. C ba u ng. B. Axit 1,4-butanicacboxylic. E. C A,B,C u sai.C. Axit 1,6hexaioic. Cu 47: iu ch trc tip HCOOH ngi ta c th i t: A. HCHO. D. C A v B. B. HCOONa. E. C A,B,C. C. CH3OH. Cu 48: iu ch trc tip CH3COOH ngi ta c th i t: A. CH3CHO. D. CH3COONa. B. CH3COOC2H5. E. C 4 cu trn. C. C2H5OH. Cu 49: phn bit CH3COOH v CH2=CH-COOH ta dng ha cht:
63

A. NaOH. D. Dung dch KMnO4 .B. Na. E. C v D. C. Dung dch Br2. Cu 50: phn bit HCOOH v CH3COOH ta dng ha cht: A. AgNO3/NH3. D. C A v B. B. NaOH. E. A,B v C. C. Na2CO3. Cu 51: phn bit ancol anlylic v axit acrylic ngi ta dng ha cht: A. Na. D. C A,B,C. B. NaOH c pha phenolphtalein. E. B v C. C. CaCO3. Cu 52: chng minh s c mt ca axit axetic trong hn hp gm axit axetic, ancol etylic v anehit axetic, ta dng ha cht: A. Qu tm. D. AgNO3/NH3. B. Na. E. p n A v C. C. NaOH v phenolphtalein. Cu 54: Cho 180g axit axetic tc dng vi lng d ancol etylic c mt axit sunfuric c lm xc tc. trng thi cn bng, nu hiu sut phn ng l 66% th khi lng este thu c l: A. 246g. D. 768g. B. 264g. E. Tt c u sai. C. 276g. Cu 55: trung ha 8,8g mt axit cacboxylic A thuc dy ng ng ca axit axetic cn 100ml dung dch NaOH 1M. Cng thc cu to c th c ca A l: A. CH3CH2CH2COOH. D. CH3COOH. B. CH3CH2CH2CH2COOH. E. HCOOH. C. CH3CH2COOH. Cu 56: Tnh kh ca axit focmic c th hin trong phn ng: A. Vi kim loi. D. Tt c u ng. B. CuO. E. Tt c u sai. C. Cu(OH)2/NaOH. Cu 57: trung ha ht 1,96g hn hp ca axit focmic v axit axetic th cn dng 70ml dung dch NaOH 0,5M. Thnh phn phn trm v khi lng ca axit axetic trong hn hp l: A. 80,48%. B. 78,52%. C. 74,27%. D. 65,75% E. 76,53%. Cu 58: trung ha ht 60g gim n th cn 50ml NaOH 1M. Nng phn trm ca axit axetic trong gim n l: A. 3%. B. 4%.C. 5%.D. 6%. E. 7%. Cu 59: Khi lng axit axetic trong gim n thu c l bao nhiu khi ln men 0,5lit ancol etylic 6o. Bit khi lng ring ca ancol etylic l 0,8g/ml. A. 31,3g. B. 34,5g.C. 37,7g. D. 39,8g. E. 34,9g. Cu 60: Cho 10,9g hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thu c 1,68lit kh(kc). Khi lng axit acrylic trong hn hp l: A. 7,2g. B. 7,4g. C. 6,7g. D. 14,4g.E. 9,8g. Cu 61: t chy mt axit cacboxylic n chc A. Trong phn t oxi chim 53,33% v khi lng. Cng thc cu to ca A l: A. HCOOH. D. CH C-COOH. B. CH3COOH. C. CH2=CH-COOH.E. CH3CH2COOH. Cu 62: Trung ha 1,72g mt axit n chc R th cn 40g dung dch NaOH 2%. Cng thc cu to ca R l: A. CH2=C(CH3)COOH. D. CH3CH2COOH.B. CH2=CH-COOH. E. CH3COOH.C. CH CCH2COOH. Cu 63: t chy mt axit cacboxylic n chc X th thu c 3,3g CO2 v 0,9g nc. Cng thc cu to ca X l: A. HCOOH. D. CH3CH2COOH B. CH2=CH-COOH E. CH3COOH.C. CH CCH2COOH Cu 64: Khi trung ha 25ml dung dch mt axit cacboxylic n chc A th cn 200ml dung dch NaOH 0,25M. C cn th thu c 4,1g cht rn. Cng thc cu to ca A l: A. HCOOH. D. CH3CH2COOH. B. CH2=CH-COOH. E. CH3COOH.C. CH CCH2COOH. Cu 65: 3,52g este ca axit cacboxylic n chc no v ancol n chc tc dng va vi 40ml dung dch NaOH 1M, to ra mui A v ancol B. t chy hon ton 0,6g ancol B cho 1,32g CO2 v 0,72g H2O. T khi hi cu ancol B so vi H2 bng 30. Oxi ha ancol B cho anehit. Cng thc cu to ca este l: A. CH3CH2COOCH3. D. HCOOCH(CH3)2. B. CH3COOCH2CH3. E. Tt c u sai.C. HCOOCH2CH2CH3. Cu 66: Hp cht c cng thc CxHyOz c khi lng phn t l 60vC. Trong cc cht trn c cht A tc dng c vi Na2CO3 sinh ra CO2. Cht B tc dng c vi Na v c phn ng trng gng. Cht C tc dng c vi NaOH nhng khng tc dng c Na. Cng thc cu to c th c ln lt ca A,B,C l: A. C3H7COOH; HOCH2CH2CHO; CH3COOCH3.B. HCOOH; (CH3)2CHOH; CH3CH2OCH3. C. C2H5COOH; HOCH2CH2CHO; C2H5COOCH3. D. CH3COOH; HOCH2CHO; HCOOCH3. E. CH3COOH; HCOOCH3 ; HOCH2CHO . Cu 67: trung ha 2,49g hn hp axit focmic v axit acrylic th cn dng 400ml dung dch NaOH 0,1M. Nu cho ton b lng hn hp axit trn phn ng vi kim loi Mg d th th tch kh H2 thu c iu
64

kin chun l bao nhiu? A. 0,112lit. D. 0,448lit. B. 0,224lit. E. 0,56lit. C. 0,336lit. Cu 68: 2,76g hn hp axit axetic v axit acrylic va lm mt mu hon ton 50g dung dch Br2 9,6%. trung ha ht 1,38g hn hp hai axit trn th cn bao nhiu ml dung dch NaOH 0,25M ? A. 40ml. D. 80ml. B. 50ml. E. 100ml. C. 60ml. Cu 69: t chy 4,09g hn hp A gm hai axit cacboxylic l ng ng k tip trong dy ng ng ca axit axetic ngi ta thu c 3,472lit kh CO2 (kc). Cng thc cu to ca cc axit trong hn hp phi l: A. HCOOH v CH3COOH. D. C2H5COOH v CH3CH2CH2COOH. B. CH3COOH v C2H5COOH. E. C C v D u ng. C. C2H5COOH v (CH3)2CHCOOH. Cu 70: t chy hon ton 1,52g hn hp axit focmic v axit axetic ngi ta thu c 0,896lit CO2 (kc). Nu ly lng hn hp axit trn ri thc hin phn ng trng bc th khi lng bc thu c l bao nhiu? A. 3,72g. D. 4,65g. B. 4,05g. E. 3,98g. C. 4,32g. -5 Cu 71: Axit axetic c hng s phn li Ka=1,8.10 . Nu in li =1,2% th nng dung dch l: A. 0,0653M. D. 0,1425M. B. 0,0845M E. Kt qu khc. C. 0,1235M. -3,75 Cu 72: Axit focmic c Ka= 10 . Nu nng dung dch l 0,5M th in ly l: A. 0,23%. D. 2,5%. B. 0,85%. E. Kt qu khc. C. 1,9%. -5 Cu 73: Hng s in ly ca axit acrylic l Ka= 5,5.10 . Dung dch acrylic c nng 1,25M th s c pH l: A. 1,2. D. 4,2. B. 2,2. E. Kt qu khc. C. 3,2. Cu 74: Dung dch axit focmic c pH= 2,15. Nng ca dung dch s l bao nhiu nu Ka=1,8.10-4 A. 0,13M. D. 0,33M. B. 0,22M. E. Kt qu khc. C. 0,28M. Cu 75: Dung dch axit axetic 0,022M c pH= 3,2. Hng s in li s l: A. 1,8.10-4. D. 4,6.10-6. B. 1,8.10-5. E. Kt qu khc. C. 1,35.10-5. Cu 76: trung ha hn hp ca phenol v axit axetic cn dng 23,4ml dung dch KOH 20%(khi lng ring l 1,2g/ml). Hn hp ban u khi tc dng vi nc brom to nn 16,55g kt ta. Khi lng ca axit trong hn hp l:A. 2g D. 5g. B. 3g. E. Kt qu khc. C. 4g. Cu 77: Trung ha 50g dung dch CH3COOH bng dung dch NaHCO3. Cho kh sinh ra i qua nc vi trong, thu c 7,5g kt ta. Nng axit trong dung dch l: A. 9%. D. 27% . B. 12%. E. Kt qu khc. C. 18%. Cu 78: Dung dch ca hn hp axit focmic v axit axetic phn ng ht vi 0,77g Magie. Khi cho sn phm t chy cng mt lng hn hp i qua ng ng ng sunfat khan, khi lng ng gim bt 1,8g. T l s mol ca HCOOHv CH3COOH tng ng l: A. 7:9. D. 7:10. B. 4:5. E. Kt qu khc. C. 5:7. Cu 79: Khi oxi ha 400g dung dch nc ca axit focmic bng dung dch AgNO3/NH3, thu c 8,64g kt ta. Nng ca axit trong hn hp u l: A. 0,92%. D. 0,24%. B. 0,46%. E. Kt qu khc. C. 0,67%.. Cu 2: Tn quc t ca
CH3 CH CH3 CH2 OH

l: A. 2- Etylpropanol. C. 2- Metylpropanol-1. E. Tt c u sai.B. 2- Metylpropanol. D. 2Etylpropanol-1. Cu 3: Cng thc cu to ng ca ancol tert-butylic l: A. (CH3)3COH. D. (CH3)2CHCH2OH.B. (CH3)2CHCH2OH. E. CH3CH2CH2CH2OH C. CH3CHCH2CH3 Cu 4: ng vi cng thc phn t C3H6O s c bao nhiu ng phn mch h v ancolA. 1. B. 2.C. 3.D. 4.E. 5. Cu 5: Ancol sec-butylic l ancol bc:A. 1. B. 2. C. 3. D. 4. E. 0. Cu 6: Cho cc cht: C2H5OH(I); C2H5Cl(II); C2H5Br(III); C2H5F(IV); C3H8(V). Chiu tng dn nhit si ca cc cht: A. (V) < (IV) < (II) < (III) < (I). B. (V) < (II) < (IV) < (III) < (I). C. (III) < (II) < (IV) < (I) < (V).
65

D. (IV) < (II) < (III) < (I) < (V). E. (IV) < (III) < (II) < (V) < (I). Cu 7: Buten-1 phn ng vi HCl thu c hp cht cha clo. un nng hp cht ny vi dung dch NaOH c thu c ancol. un nng ancol va sinh ra vi H 2SO4 c nhit trn 170C cho ta mt anken. Cng thc cu to ca anken l:A. CH3CH=CHCH3. D. CH2=CHCH2CH2CH3. B. CH2=CHCH2CH3. E. Kt qu khc. C. (CH3)2C=CH2. Cu 8: Mt hn hp cha ng thi 2 ancol CH3OH v C2H5OH. Hi trong hn hp tn ti bao nhiu kiu lin kt hiro gia cc phn t? A. 1. B. 2. C. 3. D. 4. E. 5. Cu 9: Cho 11g hn hp gm hai ancol no n chc k tip nhau trong dy ng ng tc dng ht vi Na thu c 3,36lit H2(o kc). Cng thc phn t ca 2 ancol trn l: A.CH3OH v C2H5OH.D. C3H5OH v C2H5OH.B. CH3OH v C2H3OH.E. Tt c u sai.C. C3H7OH v C2H5OH. Cu 10: Cho 16,6g hn hp gm ancol etylic v ancol n-propylic phn ng ht vi Na(ly d), thu c 3,36lit kh H2(kc). Thnh phn phn trm tng ng ca hai ancol l: A. 72,3%v 27,7%. D. 50% v 50%. B. 46,3% v 53,7%. E. 27,7% v 72,3%. C. 40% v 60%. Cu 11: ng vi cng thc phn t C7H8O s c bao nhiu ng phn phenol ?.A. 2. B. 3. C. 4. D. 5.E. 1.. Cu 13: Phn ng ha hc chng minh nguyn t H trong nhm -OH ca phenol linh ng hn H trong nhm -OH ca ancol etylic:A. Tc dng NaOH.D. C A,B u ng.B. Tc dng Na. E. C A,B,C u ng.C. Tc dng vi axit( phn ng este ha). Cu 14: C hai ng nghim ng hai cht: Phenol lng v ancol n-butylic. phn bit hai cht ta dng: A. Na. D. C B,C u ng.B. Dung dch Br2. E. C A,B,C u ng. C. Dung dch HNO3/H2SO4. Cu 15: Mt hn hp gm CH3OH; C2H5OH; Phenol c khi lng 28,9g. Chia hn hp thnh hai phn bng nhau lm hai th nghim. Phn mt phn ng hon ton vi Na ta thu c 2,806lit H 2 27C, 750mmHg. Phn hai phn ng va ht vi 100ml dung dch NaOH 1M. Phn trm theo khi lng phenol l: A. 36,87%. D. 65,05%. B. 76,89%. E. 32,65%. C. 12,34%. Cu 17: T phenol ngi ta c th iu ch: A. Aspirin. D. Phenolphtalein. B. Metyl salixilat. E. C 4 cu trn. C. Phenolfomandehit. Cu 18: c im ca lin kt gia O v H trong nhm -OH ca phn t phenol l: A. B phn cc mnh.D. Lin kt ion.B. B phn cc mnh v pha Oxi. E. Tt c u sai.C. Khng phn cc. Cu 19: Hp cht A c cng thc phn t C7H8O, bit rng A c kh nng tc dng vi NaOH v Na gii phng kh H2. Cng thc cu to ca A l: A. C6H5OCH3. D. p-HOC6H4CH3 .B. o-HOC6H4CH3. E. B,C, v D. C. m-HOC6H4CH3. Cu 20: t chy 5,8g cht A ta thu c 2,56g Na2CO3; 2,26g H2O; v 12,1gCO2. Bit rng 1 phn t A ch cha 1 nguyn t O. Cng thc phn t ca A l : A. CH3COONa. D. C3H7ONa. B. C6H5CH2ONa. E. C6H5ONa. C. C2H5ONa. Cu 3: Trong s cc cht sau: Na, Ca, CaO, CuO, CH3COOH, HCl. Cht tc dng c vi ancol etylic l:A. Na, CuO.D. CuO, CH3COOH, HCl, Na, Ca. B. Ca, CH3COOH. E. Tt c cc cht trn .C. CuO, CH3COOH, HCl Cu 4: phn bit c ancol allylic v ancol n-propylic ta tin hnh: A. Oxi ha ri cho tc dng dung dch AgNO3/NH3.B. Tc dng dung dch Br2.C. Dng dung dch KMnO4. D. C B,C u sai. E. C B,C u ng. Cu 5: Cho s chuyn ha: C2H5OH A Cao su Buna. iu kin chuyn ha ancol etylic thnh A l: A. Al2O3 + ZnO v 450oC. D. H2SO4 c, 170oC.B. Fe xt, 70oC. E. CuO v un nng. C. As, nhit thng. Dng cc thng tin sau cho cc cu hi 6v 7 X2 C3H8(A) (CH3)2CHX(B) C3H7OH(C).
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Cu 6: thu c B vi hiu sut cao nn dng X2 l: A. Cl2. B. Br2.C. F2. D. I2. E. H2. Cu 7: Vi X l clo, chiu tng dn nhit si ca A,B,C l: A. A < B < C. D. B < A < C. B. B < C < A. E. C < A < B. C. A < C < B. Cu 8: Ancol n chc A c cng thc phn t C4H10O. Khi b oxi ha to ra xeton. Khi tch nc to ra anken mch thng. A. CH3CH2CH2CH2OH.D. (CH3)3CHOH.B. (CH3)2CH-CH2OH. E. CH3CH2-CH(OH)CH3.C. (CH3)3COH. Dng cc thng tin sau cho cc cu hi 9 v 10. Mt hn hp X gm hai ancol CH3OH v C2H5OH c s mol theo t l 2:3. Khi cho hn hp tc dng vi Na d thu c 5,6lit H2(kc).Cu 9: S mol ca CH3OH v C2H5OH ln lt l: A. 0,15mol v 0,225mol.D. 0,8mol v 1,2mol.B. 0,2mol v 0,3mol. E. Kt qu khc. C. 0,4mol v 0,6mol. Cu 10: Ly lng hn hp X trn em kh nc nhit thch hp phn ng ch cho ete, phn ng xy ra hon ton. Bit rng c hai ete c s mol bng nhau. % ca ete khng i xng theo s mol l: A. 40%. B. 20%. C. 50%. D. 70%. E. 80%. Cu 11: Tn gi ca
OH

CH3

l:

A. p-crezol. D. C A,B u ng. *B. 4-metylphenol E. C A,B u sai.C. 3-metylphenol Dng cc thng tin sau cho cc cu hi 12v 13.Trong mt hn hp gm phenol v xiclohexanol vi s mol bng nhauCu 12: Trong hn hp trn tn ti bao nhiu kiu lin kt hiro. A. 4. B. 3. C. 2. D. 1. E. 5. Cu 13: Trong s cc loi lin kt hiro th kiu chim u th l: A. O ca ancol v H ca phenol. D. Ancol - ancol. B. O ca phenol v H ca ancol. E. Tt c u sai. C. Phenol - phenol. Cu 14: Cho s chuyn ha: H2SO4bc khi NaOH nng chy HCl Benzen A B C Tn gi ca C: A. Phenylclorua. C. Natriphenolat. E. Tt c u sai. B. Phenol. D. Benzylclorua. Cu 16: Trong s cc tnh cht vt l sau, tnh cht no l tnh cht ca phenol: A. t tan trong nc lnh.D. Tt c u ng.B. Rt c. E. C A,B,C u sai. C. Tinh th khng mu. Cu 17: Dng ha cht no sau y phn bit phenol v ancol benzylic? A. Na. D. C 3 cu trn.B. Dung dch Br2 E. B v C. C. HNO3/H2SO4. Dng cc thng tin sau cho cc cu hi 18v 19 Mt hn hp X gm benzen; phenol; v etanol. Ly 142,2g hn hp v chia lm hai phn bng nhau. 1/2 hn hp va trung ha 20g NaOH. 1/2 hn hp cn li tc dng Na d thu c 6,72lit H2(kc). Cu 18: Khi lng ca phenol trong hn hp X bng:A. 7,05g. B. 4,7g. C. 18,8g. D. 9,4g. E. 14,1g. Cu 19: tch phenol ra khi hn hp ta lm: A. Cho hn hp tc dng NaOH. Sau chng ct, ly phn cn li cho tc dng CO2 d thu ly phenol. B. Cho hn hp tc dng Na. Sau chng ct, ly phn cn li cho tc dng CO2 d thu ly phenol. C. Khng th tch ly phenol. D. C A,B u ng. E. C A,B u sai. Cu 20: Mt dung dch cha 6,1g cht l ng ng ca phenol n chc. Cho dung dch trn tc dng vi nc Br2 (d) thu c 17,95g hp cht cha 3 nguyn t Br trong phn t. Cng thc phn t cht ng ng ca phenol l:
67

A. C2H5C6H4OH. D. C2H5CH3C6H3OH. B. (CH3)2C6H3OH. E. A hoc B. C. (C2H5)2C6H3OH. Cu 1: Cng thc cu to ca anehit acrylic l: A. CH3CH2CHO. D. (CH3)2CHCHO. B . CH3CHO. E. Tt c u sai. C. CH2 = CH - CHO. Cu 3: Cho cc cht: HCHO(I); CH3CHO(II); C2H5Cl (III) ; CH3OH (IV) Chiu gim dn nhit si ca cc cht: A. (IV) > (III) > (II) > ( I). D. (IV) > (II) > (I) > (III). B. (IV) > (II) > (III) > (I). E. (II) > (IV) > (III) > (I). C. (IV) > (I) > (III) > (II). Cu 4: Cho cc cht: Axeton, anehit axetic, ancol isopropylic. nhn bit anehit axetic ta dng ha cht: A. AgNO3/NH3. D. A v C ng. B. Na. E. C A, B, C u ng. C. Cu(OH)2/NaOH. Dng cc thng tin sau cho cc cu hi 5 v 6. Cho 0,87g mt anehit no, n chc phn ng hon ton vi Ag2O/NH3 thu c 3,24g Ag. Cu 5: Cng thc cu to ca anehit l: A. CH3CHO. D. CH3CH2CH2CHO. B. HCHO. E. (CH3)2CHCHO. C. C2H5CHO. Cu 6: Cho 11,6 g anehit trn phn ng vi H 2/Ni (h=100%). Th tch H2 cn phn ng iu kin chun l: A. 2,24 lit. D. 3,36 lit. B. 4,48 lit. E. Kt qu khc. C. 1,12 lit. Cu 7: Focmon l dung dch anehit fomic trong nc c nng : A. 2-5%. D. 50-70%. B. 10-20%. E. 75-80%. C. Khong 40%. Cu 8: Khi cho 0,75g anehit fomic phn ng hon ton vi dung dch AgNO 3/NH3 d th khi lng Ag gii phng l: A. 10,8. D. 21,6g. B. 2,7g. E. Kt qu khc. C. 5,4g. Cu 9: Trong phn ng trng ngng gia phenol v anehit fomic, xc tc c dng l: A. Dung dch axit. D. C A v B u ng. B. Dung dch kim. E. C A, B, C u sai.C. o Ni, t . Cu 10: T C2H2 iu ch HCHO cn t nht bao nhiu phn ng: A. 1. B. 2. C. 3. D. 4. E. 5. Cu 1: Cng thc chung ca cc axit cacboxylic n chc no l: A. CnH2nO2(n 1). D. CnH2n+1-2kCOOH(n 0). B. CnH2n+1COOH(n 0). E. Tt c u sai.C. (CH2O)n(n 1). Cu 2: Axit cacboxylic n chc, no A c t khi hi so vi xy l 2,75. Vy cng thc phn t ca A l: A. C2H4O2. D. C4H6O2.B. C3H6O2. E. C5H10O2. C. C4H8O2. Cu 3: mnh ca cc axit: HCOOH(I), CH3COOH(II), CH3CH2COOH(III), (CH3)2CHCOOH(IV) theo th t tng dn l: A. I < II < III < IV. D. IV < III < II < I. B. II < IV < III < I. E. II < III < I < IV. C. IV < II < III < I. Cu 4: phn bit HCOOH v CH3COOH ngi ta dng: A. Dung dch NaOH. D. A,B,C u sai. B. Na. E. A,B,C u ng. C. AgNO3/NH3. Cu 5: Chn pht biu sai: A. HCOOH l axit mnh nht trong dy ng ng ca n.B. HCOOH c tham gia phn ng trng gng. C. HCOOH khng phn ng c vi Cu(OH)2/NaOH. D. HCOOH c tnh axit yu hn HCl. E. HCOOH c tnh axit mnh hn axit cacbonic. Cu 6: Chn cu tr li sai cho cu hi: Axit axetic c th iu ch trc tip t cht no? A. CH3CHO. D. CH3CCl3. B. C2H5OH. E. CH3OCH3. C. n-Butan. Cu 7: tng hiu sut ca phn ng este ha ngi ta cn: A. Tng nng ca axit. D. Tt c u ng. B. Tng nng ca ancol. E. C A,B,C u sai. C. Dng H2SO4 c ht nc. Cu 8: trung ha 8,8g mt axit cacboxylic A thuc dy ng ng ca axit axetic cn 100ml dung dch NaOH 1M. Cng thc cu to c th c ca A l: A. CH3CH2CH2COOH. D. CH3COOH. B. CH3CH2CH2CH2COOH. E. HCOOH. C. CH3CH2COOH. Cu 9: trung ha ht 60g gim n th cn 50ml NaOH 1M. Nng phn trm ca axit axetic trong gim n l: A. 3%. B. 4%. C. 5%. D. 6%. E. 7%.
68

Cu 10: Trong cc ng phn axit cacboxylic khng no c mch h c cng thc phn t l C4H6O2. Axit c ng phn cis- trans l: A. CH2=CH-CH2COOH. D. Tt c u c ng phn hnh hc. B. CH3CH=CHCOOH. E. Tt c u khng c ng phn hnh hc. C. CH2=C(CH3)COOH. Cu 1Hp cht hu c A c CTPT l C4H9Cl c s ng phn l: A. 3 B. 4 C. 5 D. 6 Cu 2Cht X c cng thc cu to: CH3-CH(CH3)- CHBr-CH3. X c tn gi l: A. 2-brom-3-metylbutan B. 2- metyl -3- brombutan C. 2-metyl-3-brombutan D. 2-brom- iso-pentan Cu 3Tn gi: 2 clo 3 metylbutan ng vi cng thc cu to no sau y?

CH3

CH

CH2
CH3 CH Cl

A.

CH3 Cl
CH3 CH CH3

CH3 CH2 CH CH2 Cl CH3 B. CH CH3

H2C
D.
3

C Cl

CH2 CH3

C.

Cu 4 Sp xp theo chiu tng dn nhit si:

Cl F
Br

; D. B < C < D < A

(A) (B) (C) (D) A. A < B < C < D B. A < D < C < B C. B < A < C < D Cu6.Tm sn phm chnh trong phn ng sau y: KOH, ancol CH3 CH3 C CH2 CH3 to Br A. CH2

CH3 C CH2 CH3

CH3 CH3 CH3 C CH2 CH3 OH C. D. CH3 CH CH CH2 Cu 7. T propan c th to c bao nhiu dn xut iclo? A. 2 B. 4 C. 5 D. 6 Cu 8. Khi cho 2-metylpentan tc dng vi brom thu c sn phm chnh l dn xut monobrom no sau y? A.2-brom-2-metylpentan. B. 3-brom-metylpentan. C.1-brom-2-metylpentan D. 4-brom-2metylpentan Cu 9.un si hn hp gm C2H5Br v KOH d trong C2H5OH, sau khi p xy ra hon ton, dn kh sinh ra qua dung dch brom d, thy c 8 gam Br2 tham gia phn ng . Khi lng C2H5Br tham gia phn ng l A. 1,4 gam B. 2,725 gam C. 5,45 gam D. 10,9 gam Cu 10t chy hon ton mt lng cht hu c cha C, H, Cl sinh ra 0,22 gam CO 2 v 0,09 gam H2O. Khi phn tch nh lng clo ca cng mt lng cht bng dung dch AgNO3, ngi ta thu c 1,435 g AgCl. CTPT ca hp cht trn l: A. CH2Cl2 B. CH3Cl C. C2H4Cl4 D. C2H4Cl2 Cu 1 C bao nhin dn xut clo bc I l ng phn ca nhau c cng thc phn t C5H11Cl? A. 3 B. 4 C.5 D.6 Cu 2. C bao nhiu ng phn hnh hc, mch h c cng thc phn t C3H5Br? A. 2 B.4 C.5 D.6
69

B. CH3

CH3 C CH CH3

Cu 3 .Cht hu c c cng thc cu to sau c tn gi l g? CH3 - CH(CH3)-CHBr-CH2-CCl(CH3)-CH3 A. 2-clo-4-brom-2,5-imetylhexan B. 4-brom-2-clo-2,5-imetylhexan C. 3-brom-2-clo-2,5-imetylhexan D. 4 brom-2-clo-2,5-trimetylhexan Cu 4. Cng thc cu to ca hp cht c tn gi: 2-metyl -3,3-iclo- 4-hexin -1 en l Cu 5. Sp xp theo chiu gim dn nhit si:

CH3

CH3 Cl , (A) (B) (C) A. A < B < C < D B. D < A < B < C

H C Br CH3 CH3 ,

H C Cl CH3 , CH3 CH2 Cl

(D) C. A < D < C < B D. B < A < C < D D. NaOH

Cu 6.Nhn bit: hexylbromua, brombenzen, 1 brom but 2 en bng: A. NaOH (nhit thng), AgNO3 B. NaOH, AgNO3, Br2 C. NaOH (un si), AgNO3 Cu 7.Cht no sau y khi thu phn trong NaOH thu c anehit ? A. vinyl clorua B. etyl clorua C. benzyl clorua D. 1,2-icloetan CH3-CH-CH=CH2

CH3 Cu 8H?p ch?t: L s?n ph?m chnh (theo quy t?c Zai- xep) c?a ph?n ?ng lo?i HCl h?p ch? t no sau dy? A. 1- clo- 2- metyl butan. B. 2- metyl- 3- clo butan. C. 1- clo- 3- metyl butan. D. 2- clo-3metyl butan. Cu 9.Khi cho toluen tc dng vi clo (trong iu kin thch hp) thu c cht no sau y khng phi l sn phm chnh?A. 2-clo toluen. B. 3-clo toluen. C. 4-clo toluen. D. benzyl clorua. Cu 10.Phn bit C2H5Cl, CH2=CHCH2Cl, C6H5Cl bng: A. NaOH, nhit thng B. NaOH, un nng C. NaOH, AgNO3 D. H2O (un si), AgNO3 Cu 11Cho s phn ng sau CH4 A B PVC. Cng thc ca A, B l A. C2H2, CH2=CHCl B. C2H4, CH2=CHCl C. C3H4, CH3CH=CHCl D. C2H6, CH2=CHCl Cu 12 .Cho 5 gam hn hp CH2=CHCH2Cl, C6H5CH2Cl tc dng vi dung dch NaOH d thu c 5,85 gam mui. Xc nh khi lng ru thu c: A. 3,15 gam B. 4,15 gam C. 2,15 gam D. 3,1 gam Cu 13. un nng 3,57 gam hn hp A gm propyl clorua v phenyl clorua vi dung dch NaOH long, va , sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 2,87 gam kt ta. Khi lng phenyl clorua c trong hn hp l: A. 1 gam B. 1,57 gam C. 2 gam D. 2,57 gam Cu 14. un nng 27,4 gam CH3CHBrCH2CH3 vi KOH d trong C2H5OH, sau khi phn ng xy ra hon ton, thu c hn hp kh X gm 2 olefin trong sn phm chnh chim 80%, sn phm ph chim 20%. t chy hon ton X thu c bao nhiu lt CO2? A. 4,48 lt B. 8,96 lt C. 11,2 lt D. 17,92 lt. Cu 15. Quy trnh sn xut PVC theo s sau:

CH2=CH2

+ Cl2

ClCH2CH2Cl

xt,t0

CH2=CHCl

xt,t0

PVC

Tnh th tch etilen v kh clo (ktc) sn xut 1 tn PVC theo s trn, gi s H = 100%. A. 358400 lit, 358400 lit. B. 179200 lit, 358400 litC. 358400 lit, 179200 lit D. 179200 lit, 358400 lit Cu 1Hp cht hu c A c CTPT l C4H9Cl c s ng phn l:A. 3 B. 4 C. 5 D. 6 Cu 2. Cht X c cng thc cu to: CH3-CH(CH3)- CHBr-CH3. X c tn gi l: A. 2-brom-3-metylbutan B. 2- metyl -3- brombutan C. 2-metyl-3-brombutan D. 2-brom- isopentan Cu 3. Tn gi: 2 clo 3 metylbutan ng vi cng thc cu to no sau y?

CH3

CH CH2 CH3 Cl

A.

CH3 CH2 CH CH2 Cl CH3 B.

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CH3 CH3 CH3 H2C C CH2 CH3 CH3 CH CH CH3 Cl Cl C. D. Cu 5 . Cho cc cht sau: phenyl clorua, benzyl clorua, ru benzylic. Nhng cht no c kh nng phn ng vi dung dch NaOH un nng. A. phenyl clorua B. benzyl clorua C. benzylic D. c 3 cht d. Cu6. Tm sn phm chnh trong phn ng sau y: CH3 KOH, ancol CH3 C CH2 CH3 to Br CH3 CH3 A. CH2 C CH2 CH3 B. CH3 C CH CH3 CH3 CH3 CH3 C CH2 CH3 OH C. D. CH3 CH CH CH2 Cu 7. T propan c th to c bao nhiu dn xut iclo? A. 2 B. 4 C. 5 D. 6 Cu 8. Khi cho 2-metylpentan tc dng vi brom thu c sn phm chnh l dn xut monobrom no sau y? A. 2-brom-2-metylpentan. B. 3-brom-metylpentan. C.1-brom-2-metylpentan D. 4-brom-2metylpentan Cu 9. un si hn hp gm C2H5Br v KOH d trong C2H5OH, sau khi p xy ra hon ton, dn kh sinh ra qua dung dch brom d, thy c 8 gam Br2 tham gia phn ng . Khi lng C2H5Br tham gia phn ng l A. 1,4 gam B. 2,725 gam C. 5,45 gam D. 10,9 gam Cu 10. t chy hon ton mt lng cht hu c cha C, H, Cl sinh ra 0,22 gam CO 2 v 0,09 gam H2O. Khi phn tch nh lng clo ca cng mt lng cht bng dung dch AgNO3, ngi ta thu c 1,435 g AgCl. CTPT ca hp cht trn l: A. CH2Cl2 B. CH3Cl C. C2H4Cl4 D. C2H4Cl2 Cu 11 . C bao nhin dn xut clo bc I l ng phn ca nhau c cng thc phn t C5H11Cl? A. 3 B. 4 C.5 D.6 Cu 12. C bao nhiu ng phn hnh hc, mch h c cng thc phn t C3H5Br?A.2 B.4 C.5 D.6 Cu 24. un nng 27,4 gam CH3CHBrCH2CH3 vi KOH d trong C2H5OH, sau khi phn ng xy ra hon ton, thu c hn hp kh X gm 2 olefin trong sn phm chnh chim 80%, sn phm ph chim 20%. t chy hon ton X thu c bao nhiu lt CO2? A. 4,48 lt B. 8,96 lt C. 11,2 lt D. 17,92 lt. TUYN TP HA HU C 11 TRONG CC THI I HC CAO NG
Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. Cu 2: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23) A. C3H5OH v C4H7OH. B. C2H5OH v C3H7OH. C. C3H7OH v C4H9OH. D. CH3OH v C2H5OH. Cu 3: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5) A. 3. B. 6. C. 4. D. 5. Cu 4: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40)
71

A. 20. B. 40. C. 30. D. 10. Cu 5: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H6. B. C3H4. C. C2H4. D. C4H8. Cu 6: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. CH3CHO. B. HCHO. C. CH3CH2CHO. D. CH2 = CHCHO. Cu 7: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 8: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. HCHO. B. CH3CHO. C. OHC-CHO. D. CH3CH(OH)CHO. Cu 9: Cho s
+ axit HCl + NaOH c (d) + Cl2 (t l mol C6H6 (benzen) X Y Z 1:1) to cao, p cao

Hai cht hu cFe, to ln lt l: Y, Z A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu 10: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l (cho H = 1, C = 12, O = 16, Ca = 40) A. 550. B. 810. C. 650. D. 750. Cu 11: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16) A. 10,12. B. 6,48. C. 8,10. D. 16,20. Cu 12: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l D. HOOC-COOH. A. HOOC-CH2-CH2-COOH. B. C2H5-COOH. C. CH3-COOH. Cu 13: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) A. y = 100x. B. y = 2x. C. y = x - 2. D. y = x + 2. Cu 14: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. (CH3)3COH. B. CH3OCH2CH2CH3. C. CH3CH(OH)CH2CH3. D. CH3CH(CH3)CH2OH. Cu 15: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen. Cu 16: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A. C3H8. B. C3H6. C. C4H8. D. C3H4. Cu 17: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 18: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l (cho H = 1, C = 12, O = 16, Na = 23) A. C2H5COOH. B. CH3COOH. C. C3H7COOH. D. HCOOH. Cu 19: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu
72

c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 8,96. B. 11,2. C. 6,72. D. 4,48. Cu 20: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O = 16) A. HOCH2C6H4COOH. B. C2H5C6H4OH. C. HOC6H4CH2OH. D. C6H4(OH)2. Cu 21: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. no, hai chc. B. no, n chc. C. khng no c hai ni i, n chc. D. khng no c mt ni i, n chc. Cu 22: Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. B. CH2=CH-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, CH3-CH=CH2. D. CH2=CH-CH=CH2, lu hunh. Cu 23: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 2. B. 4. C. 3. D. 1. Cu 24: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 2. B. 3. C. 1. D. 4. Cu 25: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l (cho C = 12, O = 16) A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C3H7OH. Cu 26: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C4H8O2. B. C3H6O2. C. CH2O2. D. C2H4 O2. Cu 27: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 4. B. 5. C. 3. D. 2. Cu 28: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l (cho H = 1, C =12, O = 16) A. 0,92. B. 0,32. C. 0,64. D. 0,46. Cu 29: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn A. giy qu tm. B. nc brom. C. dung dch NaOH. D. dung dch phenolphtalein. Cu 30: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 3,3-imetylhecxan. B. isopentan. C. 2,2,3-trimetylpentan. D. 2,2-imetylpropan. Cu 31: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l (cho H = 1, C = 12, O = 16) A. C2H3CHO. B. CH3CHO. C. HCHO. D. C2H5CHO. Cu 32: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l (cho H = 1, C = 12, N = 14, O = 16) A. 60%. B. 50%. C. 80%. D. 70%. Cu 33: Dy gm cc cht u phn ng vi phenol l: A. dung dch NaCl, dung dch NaOH, kim loi Na.B. nc brom, axit axetic, dung dch NaOH. C. nc brom, anhirit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH. Cu 34: Cho s phn ng: NH3
+ CH3I + HONO

(t l mol 1:1)

X Y Z to

+ CuO

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, CH3CHO. B. CH3OH, HCOOH. C. C2H5OH, HCHO. D. CH3OH, HCHO
73

Cu 35: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l (Cho H = 1; C = 12; O = 16) A. 70,0 lt. B. 78,4 lt. C. 84,0 lt. D. 56,0 lt. Cu 36: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 3. C. 2. D. 1. Cu 37: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH2=CH2. B. CH3CHO v CH3CH2OH. C. CH3CH2OH v CH3CHO. D. CH3CH(OH)COOH v CH3CHO. Cu 38: t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O3. B. C3H4O. C. C3H8O2. D. C3H8O. Cu 39: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40) A. CH2=CH-COOH. B. CH3COOH. C. HC C-COOH. D. CH3-CH2-COOH. Cu 40: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng (Cho H = 1; C = 12; O = 16; Br = 80; Ag = 108) A. 11,2. B. 13,44. C. 5,60. D. 8,96 Cu 41: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. HOC6H4CH2OH. C. CH3C6H3(OH)2. D. CH3OC6H4OH. Cu 42: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16; Ag = 108) A. HCHO. B. CH2=CH-CHO. C. OHC-CHO. D. CH3CHO. Cu 43: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5)A. 2-metylpropan. B. 2,3-imetylbutan.C. butan. D. 3-metylpentan. Cu 44: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k) D. C4H9OH v A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH.C. C2H5OH v C4H9OH. C5H11OH. Cu 45: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16) A. 55%. B. 50%. C. 62,5%. D. 75%. Cu 46: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16) A. 2. B. 3. C. 4. D. 5. Cu 47: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T. Cu 48: Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O = 16) A. 5. B. 4. C. 3. D. 2.
74

Cu 49: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 7,4. C. 9,2. D. 8,8. Cu 50: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 5. B. 3. C. 2. D. 4. Cu 51: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc.B. khng no (cha mt ni i C=C), n chc. C. no, hai chc. D. no, n chc. Cu 52: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 6,84 gam. B. 4,90 gam. C. 6,80 gam. D. 8,64 gam. Cu 53: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. HCHO. C. C2H5CHO. D. C4H9CHO. Cu 54: S ng phn este ng vi cng thc phn t C4H8O2 l A. 6. B. 4. C. 5. D. 2. Cu 55: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l: A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. C2H6, C2H5OH, CH3CHO, CH3COOH. C. C2H6, CH3CHO, C2H5OH, CH3COOH. D. CH3COOH, C2H6, CH3CHO, C2H5OH. Cu 56: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 18,60 gam. B. 18,96 gam. C. 20,40 gam. D. 16,80 gam. Cu 57: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l: A. 0,60. B. 0,55. C. 0,45. D. 0,40. Cu 58: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l A. 2-metylbuten-3 (hay 2-metylbut-3-en). B. 3-metylbuten-2 (hay 3-metylbut-2-en). C. 3-metylbuten-1 (hay 3-metylbut-1-en). D. 2-metylbuten-2 (hay 2-metylbut-2-en). Cu 59: Hp cht trong phn t c lin kt ion l A. HCl. B. NH3. C. H2O. D. NH4Cl. Cu 60: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 224,0. B. 448,0. C. 286,7. D. 358,4. Cu 61: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l: A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam. Cu 62: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l:A. C6H14. B. C3H8. C. C4H10. D. C5H12. Cu 63: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc lA. 4.B. 1. C. 2. D. 3. Cu 64: S ng phn xeton ng vi cng thc phn t C5H10O l :A. 5. B. 4. C. 3. D. 6. Cu 65: Cho s chuyn ho sau:
75

+ Br2 (1:1mol),Fe,t + NaOH (d ),t ,p + HCl(d ) Toluen X Y Z

Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol. Cu 66: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l D. C3H7OH v A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH.C. C3H5OH v C4H7OH. C4H9OH. Cu 67: Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 1. B. 3. C. 4. D. 2. Cu 68: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. Cu 69: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 70: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. Cu 71: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. Cu 72: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C6H8O6. B. C3H4O3. C. C12H16O12. D. C9H12O9. Cu 73: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH. Cu 74: Cho cc phn ng: t HBr + C2H5OH C2H4 + Br2 askt (1:1mol) C2H4 + HBr C2H6 + Br2 S phn ng to ra C2H5Br l : A. 4. B. 3. C. 2. D. 1. Cu 75: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. C. nc Br2. D. H2 (Ni, nung nng). Cu 76: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 4. C. 2. D. 5. Cu 77: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. Cu 78: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H6. B. C2H4. C. CH4. D. C3H8. Cu 79: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin. Cu 80: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z
0

76

u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. Cu 81: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng caA. ankan. B. ankin. C. ankaien. D. anken. Cu 82: Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4 c, 140oC) th s ete thu c ti a l A. 4.B. 2. C. 1. D. 3. Cu 83: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l A. 6,0 gam. B. 4,4 gam. C. 8,8 gam. D. 5,2 gam. Cu 84: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 85: Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l: A. (2), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (1), (3), (4). Cu 86: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 12,9. B. 25,8. C. 22,2. D. 11,1. Cu 87: t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O2, C3H8O2. B. C2H6O, CH4O. C. C3H6O, C4H8O. D. C2H6O, C3H8O. Cu 88: t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. HCHO. B. CH3CHO. C. (CHO)2. D. C2H5CHO. Cu 89: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. Cu 90: t chy hon ton mt ru (ancol) a chc, mch h X, thu c H2O v CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l A. C2H6O2. B. C2H6O. C. C3H8O2. D. C4H10O2. Cu 91: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 75% v 25%. B. 20% v 80%. C. 35% v 65%. D. 50% v 50%. Cu 92: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. etan. C. 2,2-imetylpropan. D. 2-Metylpropan. Cu 93: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l A. CH3-CHOH-CH3. B. CH3-CH2-CHOH-CH3.C. CH3-CO-CH3. D. CH3-CH2-CH2-OH. 1. (C - 2007) Khi cho ankan X (83,72% khi lng cacbon trong phn t) tc dng vi clo theo t l mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l A. butan B. 2- metylpropan C. 2,3-imetylbutan D. 3-metylpentan. 1.(C 2007) Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C 7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H 2 thu c bng s mol X
77

tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. HOC6H4CH2OH. C. CH3C6H3(OH)2. D. CH3OC6H4OH. 3. (KA 2007) Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C4H8. B. C3H6. C. C3H4. D. C2H4. 4. (KA 2007) Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. eten v but-2-en (hoc buten-2). B. 2-metylpropen v but-1-en (hoc buten-1). C. propen v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). 5. (KA 2007) Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. CH3CHO. B. OHC-CHO. C. HCHO. D. CH3CH(OH)CHO. 6.(KA 2007) Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C3H4 v C4H8. B. C2H2 v C3H8. C. C2H2 v C4H8. D. C2H2 v C4H6. 7.( KB-2007) Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 2,2,3-trimetylpentan. B. 2,2-imetylpropan. C. 3,3-imetylhecxan. D. isopentan. 8.(KB2007)S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi ddNaOH l A. 2. B. 3. C. 1. D. 4. 9. (CD 2008) t chy hon ton mt hirocacbon X thu c 0,11 mol CO 2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. etan C. 2,2-imetylpropan. D. 2Metylpropan. 10.(KA 2008) un nng hn hp kh gm 0,06 mol C 2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,04 gam. B. 1,32 gam. C. 1,64 gam. D. 1,20 gam. 11.(KA 2008) un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H 2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc. 12. (KB 2008) Cho s chuyn ho sau : + Br (1:1mol),Fe,t + NaOH (d ),t ,p + HCl(d ) Toluen X Y Z Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm : A. m-metylphenol v o-metylphenol B. benzyl bromua v o-bromtoluen C. o-bromtoluen v p-bromtoluen D. o-metylphenol v p-metylphenol 13. (KB 2008) Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan B. ankaien C. anken D. ankin 14. (KB 2008) Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3 B. 4 C. 2 D. 5 15. (KB 2008) t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H6 B. C2H4 C. CH4 D. C3H8
2 0 0

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16. (KB 2008) Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc). A. CH4 v C2H4 B. CH4 v C3H4 C. CH4 v C3H6 D. C2H6 v C3H6 Cu 1: Pht biu no sau y khng chnh xc? A. Tnh cht ca cc cht ph thuc vo thnh phn phn t v cu to ha hc. B. Cc cht c cng khi lng phn t l ng phn ca nhau. C. Cc cht l ng phn ca nhau th c cng cng thc phn t. D. S xen ph trc to thnh lin kt , s xen ph bn to thnh lin kt . Cu 2: Tng s lin kt v vng ng vi cng thc C5H12O2 lA. 0. B. 1. C. 2. D. 3. Cu 3: Cng thc tng qut ca anehit n chc mch h c 1 lin kt i trong gc hirocacbon l A. CnH2n+1CHO. B. CnH2nCHO. C. CnH2n-1CHO. D. CnH2n-3CHO. Cu 4: Trong hp cht CxHyOz th y lun lun chn v y 2x+2 l do A. a 0 (a l tng s lin kt v vng trong phn t) B. z 0 (mi nguyn t oxi to c 2 lin kt). C. mi nguyn t cacbon ch to c 4 lin kt. D. cacbon v oxi u c ha tr l nhng s chn. Cu 5: Aminoaxit no, cha mt nhm amino v hai nhm cacboxyl c cng thc tng qut l A. H2N-CnH2n+1(COOH)2. B. H2N-CnH2n-1(COOH)2 .C. H2N-CnH2n(COOH)2. D. H2NCnH2n-3(COOH)2. Cu 6: Anehit mch h c cng thc tng qut CnH2n-2O thuc loi A. anehit n chc no. B. anehit n chc cha mt lin kt i trong gc hirocacbon. C. anehit n chc cha hai lin kt trong gc hirocacbon. D. anehit n chc cha ba lin kt trong gc hirocacbon. Cu 7: Cho cng thc cu to sau: CH3-CH(OH)-CH=C(Cl)-CHO. S oxi ha ca cc nguyn t cacbon tnh t phi sang tri c gi tr ln lt l A. +1; +1; -1; 0; -3. B. +1; -1; -1; 0; -3. C. +1; +1; 0; -1; +3. D. +1; -1; 0; -1; +3. Cu 8: Cng thc tng qut ca dn xut iclo mch h c cha mt lin kt ba trong phn t l A. CnH2n-2Cl2. B. CnH C. CnH2nCl2. D. CnH2n-6Cl2. 2n-4Cl2. Cu 9: S lng ng phn mch h ng vi cng thc phn t C3H6O lA. 2. B. 3. C. 4. D. 5. Cu 10: S lng ng phn ng vi cng thc phn t C4H10O lA. 4. B. 5. C. 6. D. 7. Cu 11: t chy hon ton 0,1 mol mt ancol mch h ba ln cha mt lin kt ba trong gc hirocacbon thu c 0,6 mol CO2. Cng thc phn t ca ancol l A. C6H14O3. B. C6H12O3. C. C6H10O3. D. C6H8O3. A. 1-brom-3,5-trimetyl hexa-1,4-ien. B. 3,3,5-trimetyl hexa-1,4-ien-1-brom. C. 3,3,5-trimetyl hexa-1,4-ien-1-brom. D. 1-brom-3,3,5-trimetyl hexa-1,4-ien.

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C 1 : H p ch t CH3 u 2

C CH CH3

CH3 C CH CH3

CH

Br c d n p p IUPAC l a h h

C 1 : H p ch X c cng thc c to CH3 u 3 t u

CH3 C= CH C CH3. Da php IUPAC ca X l nh CH3 CH3

A. 2,2,4- trimetylpent-3-en. B. 2,4-trimetylpent-2-en C. 2,4,4-trimetylpent-2-en. D. 2,4-trimetylpent-3-en. Cu 14: Cc cht hu c n chc Z1, Z2, Z3 c CTPT tng ng l CH2O, CH2O2, C2H4O2. Chng thuc cc dy ng ng khc nhau. Cng thc cu to ca Z3 l A. CH3COOCH3. B. HO-CH2-CHO. C. CH3COOH. D. CH3-O-CHO. Cu 15: Cng thc tng qut ca dn xut ibrom khng no mch h cha a lin kt l A. CnH2n+2-2aBr2. B. CnH2n-2aBr2. C. CnH2n-2-2aBr2. D. CnH2n+2+2aBr2. Cu 16: Cng thc tng qut ca ru n chc mch h c 2 ni i trong gc hirocacbon l A. CnH2n-4O. B. CnH2n-2O. C. CnH2nO. D. CnH2n+2O. Cu 17: Tng s lin kt v vng ng vi cng thc C5H9O2Cl lA. 0. B. 1. C. 2. D. 3. Cu 18 (B-07): Cho tt c cc ng phn n chc mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi Na, NaOH , NaHCO3. S phn ng xy ra lA. 4. B. 5. C. 3. D. 2.
C 1 : H p ch t CH2 u 9 CH CH3 C CH2 CH3 CH OH CH3 c d n p p IUPAC l a h h

A. 1,3,3-trimetyl pent-4-en-1-ol. B. 3,3,5-trimetyl pent-1-en-5-ol. C. 4,4-imetyl hex-5-en-2-ol. D. 3,3-imetyl hex-1-en-5-ol. Cu 20: Cho cc cht cha vng benzen: C6H5-OH (X); C6H5-CH2-OH (Y); CH3-C6H4-OH (Z); C6H5-CH2-CH2-OH (T). Cc cht ng ng ca nhau l: A. X, Y, T. B. X, Z, T. C. X, Z. D. Y, Z. Cu 21: X l dn xut ca benzen c cng thc phn t C8H10O tho mn iu kin: X khng tc dng vi NaOH; khi tch nc t X thu c Y, trng hp Y thu c polime. S lng ng phn tho mn vi cc tnh cht trn lA. 1. B. 2. C. 3. D. 4. Cu 22: Hp cht hu c mch h c cng thc phn t C3H6O2 c th thuc loi cht sau: A. ru hai ln c mt lin kt i trong gc hirocacbon. B. anehit hoc xeton no hai ln. C. axit hoc este no n chc. D. hp cht no cha mt chc anehit v mt chc xeton. Cu 23: Hp cht hu c c cng thc tng qut CnH2n+2O2 thuc loi A. ru hoc ete no mch h hai ln. B. anehit hoc xeton no mch h 2 ln. C. axit hoc este no n chc mch h. D. hiroxicacbonyl no mch h. Cu 24: Anehit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon lA. 0.B. 1. C. 2. D. 3. Cu 25: Axit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon lA. 0. B. 1. C. 2. D. 3. Cu 26: Tng s lin kt v vng trong phn t axit benzoic l A. 3. B. 4. C. 5. D. 6.
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Cu 27: Hp cht hu c no sau y khng c ng phn cis trans? A. 1,2-icloeten. B. 2-metyl pent-2-en. C. but-2-en. D. pent-2-en. Cu 28: Ru no mch h c cng thc tng qut chnh xc nht l A. R(OH)m. B. CnH2n+2Om. C. CnH2n+1OH. D. CnH2n+2-m(OH)m. Cu 29: S lng ng phn mch h ng vi cng thc phn t C2H4O2 lA. 2. B. 3. C. 4. D. 5. Cu 30: Cng thc phn t tng qut ca axit hai chc mch h cha mt lin kt i trong gc hirocacbon l A. CnH2n-4O4. B. CnH2n-2O4. C. CnH2n-6O4. D. CnH2nO4. Cu 31: Hp cht C4H10O c s lng ng phn lA. 4. B. 7. C. 8. D. 10. Cu 1: Mt hp cht hu c gm C, H, O; trong cacbon chim 61,22% v khi lng. Cng thc phn t cahp cht c th l;A. C4H10O. B. C3H6O2. C. C2H2O3. D. C5H6O2. Cu 2: t chy hon ton mt hp cht hu c n chc X thu c sn phm chy ch gm CO2 v H2O vi t l khi lng tng ng l 44 : 27. Cng thc phn t ca X l A. C2H6. B. C2H6O. C. C2H6O2. D. C2H4O. Cu 3 (B-2007): Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X, sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C4H8O2. B. C3H6O2. C. CH2O2. D. C2H4O2. Cu 4: t chy hon ton 0,12 mol cht hu c A mch h cn dng 10,08 lt O2 (ktc). Dn ton b sn phm chy (gm CO2, H2O v N2) qua bnh ng dung dch Ba(OH)2 d, thy khi lng bnh tng 23,4g v c 70,92g kt ta. Kh thot ra khi bnh c th tch 1,344 lt (ktc). Cng thc phn t ca A l A. C2H5O2N. B. C3H5O2N. C. C3H7O2N. D. C2H7O2N. Cu 5: t chy hon ton 0,2 mol mt axit cacboxylic no 2 ln thu c 1,2 mol CO2. Cng thc phn t ca axit lA. C6H14O4. B. C6H12O4. C. C6H10O4. D. C6H8O4. Cu 6: t chy hon ton 0,1 mol mui natri ca mt axit cacboxylic, thu c Na2CO3, hi nc v 3,36 lt kh CO2 (ktc). Cng thc cu to thu gn ca mui l A. C2H5COONa. B. HCOONa. C. CH3COONa. D. CH2(COONa)2. Cu 7: Cho 25,4 gam este X bay hi trong mt bnh kn dung tch 6 lt 136,5oC. Khi X bay hi ht th p sut trong bnh l 425,6 mmHg. Cng thc phn t ca X l A. C12H14O6. B. C15H18O6. C. C13H16O6. D. C16H22O6. Cu 8: Mt hp cht hu c Y khi t chy thu c CO2 v H2O c s mol bng nhau; ng thi lng oxi cn dng bng 4 ln s mol ca Y. Cng thc phn t ca Y l A. C2H6O. B. C4H8O. C. C3H6O. D. C3H6O2. Cu 9: t chy hon ton 5,8 gam mt hp cht hu c n chc X cn 8,96 lt kh O2 (ktc), thu c CO2 v H2O c s mol bng nhau. Cng thc n gin nht ca X l A. C2H4O. B. C3H6O. C. C4H8O. D. C5H10O. Cu 10: t chy hon ton hn hp 2 ru (ancol) n chc, thuc cng dy ng ng c s mol bng nhau, thu c CO2 v H2O vi t l mol tng ng l 2 : 3. Cng thc phn t ca 2 ru (ancol) l
81

B. C2H6O v C3H8O. C. CH4O v C2H6O. D. C2H6O v C4H10O. Cu 11: t chy hon ton mt axit a chc A, thu c 1,344 lt kh CO2 (ktc) v 0,9 gam H2O. Cng thc n gin ca A l:A. C2H3O2. B. C4H7O2. C. C3H 5O 2. D. CH2O. Cu 12: Hn hp A gm 2 ru (ancol) n chc X v Y, trong s mol ca X bng 5/3 ln s mol ca Y. t chy hon ton 0,04 mol A thu c 1,98 gam H2O v 1,568 lt kh CO2 (ktc). Cng thc phn t ca X v Y ln lt lA. C2H6O v C3H8O. B. CH4O v C3H6O. C. CH4O v C3H4O. D. CH4O v C3H8O. Cu 13: t chy hon ton 4,3gam mt cht hu c n chc A cha C, H, O ri dn sn phm chy qua bnh 1 cha P2O5 d v bnh 2 cha NaOH d. Sau th nghim bnh 1 tng 2,7g; bnh 2 thu c 21,2g mui. Cng thc phn t ca A l:A. C2H3O. B. C4H6O. C. C3H6O2. D. C4H6O2. Cu 14: t chy hon ton 1,18 gam cht B (CxHyN) bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH)2 d, thu c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. Bit khng kh cha 20% oxi v 80% nit v th tch. Cng thc phn t ca B l A. C2H7N. B. C3H9N. C. C4H11N. D. C4H9N. Cu 15: Trong mt bnh kn dung tch khng i cha hn hp hi cht A (CxHyO) vi O2 va t chy hp cht A 136,5oC v 1 atm. Sau khi t chy, a bnh v nhit ban u, th p sut trong bnh l 1,2 atm. Mt khc, khi t chy 0,03 mol A lng CO2 sinh ra c cho vo 400 ml dd Ba(OH)2 0,15M thy c hin tng ho tan kt ta, nhng nu cho vo 800 ml dd Ba(OH)2 ni trn th thy Ba(OH)2 d. Cng thc phn t ca A l A. C2H4O. B. C3H6O. C. C4H8O. D. C3H6O2. Cu 16: Hp cht hu c Y c t khi hi so vi H2 l 37. Y tc dng c vi Na, NaOH v tham gia phn ng trng gng. Cng thc phn t ca Y lA. C4H10O. B. C3H 6O 2. C. C2H2O3. D. C4H8O. Cu 17: Hn hp A gm mt s hirocacbon l ng ng k tip. Tng khi lng phn t ca cc hirocacbon trong A l 252, trong khi lng phn t ca hirocacbon nng nht bng 2 ln khi lng phn t ca hirocacbon nh nht. Cng thc phn t ca hirocacbon nh nht v s lng hirocacbon trong A l A. C3H6 v 4. B. C2H4 v 5. D. C3H8 v 4. D. C2H6 v 5. Cu 18: Trn mt hirocacbon X vi lng O2 va c hn hp A 0oC v p sut P1. t chy ht X, tng th tch cc sn phm thu c 218,4oC v p sut P1 gp 2 ln th tch hn hp A 0oC, p sut P1. A. C4H10. B. C2H6. C. C3H6. D. C3H8. Cu 19: t chy hon ton 1,605 gam hp cht hu c A thu c 4,62 gam CO2; 1,215 gam H2O v 168ml N2 (ktc). T khi hi ca A so vi khng kh khng vt qu 4. Cng thc phn t ca A l A. C7H9N. B. C6H7N. C. C5H5N. D. C6H9N. Cu 20: t chy hon ton 5,8 gam cht A thu c 2,65 gam Na2CO3; 2,26 gam H2O v 12,1 gam CO2. Cng thc phn t ca A l: A. C6H5O2Na.B. C6H5ONa. C. C7H7O2Na. D. C7H7ONa. Cu 21: t chy hon ton 1,88g A (cha C, H, O ) cn 1,904 lt kh O2 (ktc), thu c CO2 v H2O vi t l mol tng ng l 4:3. Cng thc phn t ca A l: A. C4H 6O 2. B. C8H12O4. C. C4H6O3. D. C8H12O5. Cu 22: t chy hon ton mt lng cht X (cha C, H, O) cn 0,6 mol O2 to ra 0,6 mol CO2 v 0,6 mol H2O. Cng thc phn t ca X lA. C6H12O6. B. C12H22O11. C. C2H4O2. D. CH2O.
82

A. CH4O v C3H8O.

Cu 23: t chy hon ton mt lng cht Y (cha C, H, O) cn 0,3 mol O2 to ra 0,2 mol CO2 v 0,3 mol H2O. Cng thc phn t ca Y lA. C2H6O. B. C2H6O2. C. CH4O. D. C3H6O. Cu 24: t chy hon ton mt lng cht hu c cha C, H, Cl thu c 2,2 gam CO2; 0,9 gam H2O. Khi xc nh clo trong lng cht bng dung dch AgNO3 th thu c 14,35 gam AgCl. Cng thc phn t ca hp cht l:A. C2H4Cl2. B. C3H6Cl2. C. CH2Cl2. D. CHCl3. Cu 25: t chy hon ton 0,1 mol cht X cn 6,16 lt kh O2 (ktc), thu c13,44 lt (ktc) hn hp CO2, N2 v hi nc. Sau khi ngng t ht hi nc, cn li 5,6 lt kh (ktc) c t khi so vi hiro l 20,4. Cng thc phn t ca X l:A. C2H7O2N. B. C3H7O2N. C. C3H9O2N. D. C4H9N. Cu 26: t chy hon ton 10,4 gam hp cht hu c Y (cha C, H, O) ri cho ton b sn phm chy ln lt qua bnh 1 dng H2SO4 c, bnh 2 ng nc vi trong d. Sau th nghim, ngi ta thy khi lng bnh 1 tng 3,6 gam v bnh 2 thu c 30 gam kt ta. Cng thc phn t ca X l A. C3H6O2. B. C4H6O2. C. C4H6O4. D. C3H4O4. Cu 1: Khi t chy ankan thu c H2O v CO2 vi t l tng ng bin i nh sau: A. tng t 2 n + . B. gim t 2 n 1. C. tng t 1 n 2. D. gim t 1 n 0. Cu 2: t chy hon ton hn hp 2 hirocacbon thu c s mol CO2 nh hn s mol H2O. Hn hp A. gm 2 ankan. B. gm 2 anken. C. cha t nht mt anken. D. cha t nht mt ankan. Cu 3: S lng ng phn ng vi cng thc phn t C5H12 lA. 2. B. 3. C. 4. D. 5. Cu 4: Khi cho isopentan tc dng vi Cl2 theo t l mol 1:1 th s lng sn phm th monoclo to thnh l A. 2. B. 3. C. 4. D. 5. Cu 5: khi cho 2-metylbutan tc dng vi Cl2 theo t l mol 1:1 th to ra sn phm chnh l A. 1-clo-2-metylbutan. B. 2-clo-2-metylbutan. C. 2-clo-3-metylbutan. D. 1-clo-3-metylbutan.
n h c u o CH3 C 6 C g t c t u : CH3 C CH2 CH3 CH CH3 c d n p p IUPAC l a h h CH3

B. 2,4-trimetylpetan.C. 2,4,4-trimetylpentan. D. 2-imetyl-4-metylpentan. Cu 7: Trong phng th nghim, ngi ta iu ch CH4 bng phn ng A. craking n-butan. B. cacbon tc dng vi hiro. C. nung natri axetat vi vi ti xt. D. in phn dung dch natri axetat. Cu 8: Khi clo ha C5H12 vi t l mol 1:1 thu c mt sn phm th monoclo duy nht. Danh php IUPAC ca ankan lA. 2,2-imetylpropan. B. 2metylbutan. C. n-pentan. D. 2-imetylpropan. Cu 9: Thnh phn chnh ca kh thin nhin lA. metan. B. etan.C. propan. D. n-butan. Cu 10: khi clo ha metan thu c mt sn phm th cha 89,12% clo v khi lng. Cng thc ca sn phm l A. CH3Cl. B. CH2Cl2. C. CHCl3. D. CCl4. Cu 11: Khi tin hnh craking 22,4 lt kh C4H10 (ktc) thu c hn hp A gm CH4, C2H6, C2H4, C3H6, C4H8, H2 v C4H10 d. t chy hon ton A thu c x gam CO2 v y gam H2O. Gi tr ca x v y tng ng l A. 176 v 180. B. 44 v 18. C. 44 v 72. D. 176 v 90.
83

A. 2,2,4-trimetylpentan.

Cu 12: Cho 4 cht: metan, etan, propan v n-butan. S lng cht to c mt sn phm th monoclo duy nht l A. 1. B. 2. C. 3. D. 4. Cu 13: Khi t chy hon ton V lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 44 gam CO2 v 28,8 gam H2O. Gi tr ca V l:A. 8,96. B. 11,20. C. 13,44. D. 15,68. Cu 14: Khi t chy hon ton 7,84 lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 16,8 lt kh CO2 (ktc) v x gam H2O. Gi tr ca x lA. 6,3. B. 13,5. C. 18,0. D. 19,8. Cu 15: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c 7,84 lt kh CO2 (ktc) v 9,0 gam H2O. Cng thc phn t ca 2 ankan l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Cu 16: khi clo ha mt ankan c cng thc phn t C6H14, ngi ta ch thu c 2 sn phm th monoclo. Danh php IUPAC ca ankan l A. 2,2-imetylbutan. B. 2-metylpentan. C. n-hexan. D. 2,3-imetylbutan. Cu 17: Khi clo ha hn hp 2 ankan, ngi ta ch thu c 3 sn phm th monoclo. Tn gi ca 2 ankan l A. etan v propan. B. propan v iso-butan. C. iso-butan v n-pentan. D. neo-pentan v etan. Cu 18: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng ng k tip thu c 96,8 gam CO2 v 57,6 gam H2O. Cng thc phn t ca A v B l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Cu 19: Hn hp kh X gm 2 hirocacbon A v B l ng ng k tip. t chy X vi 64 gam O2 (d) ri dn sn phm thu c qua bnh ng Ca(OH)2 d thu c 100 gam kt ta. Kh ra khi bnh c th tch 11,2 lt 0OC v 0,4 atm. Cng thc phn t ca A v B l A. CH4 v C2H6. B. C2H6 v C3H8. C. C3H8 v C4H10.D. C4H10 v C5H12. Dng cho cu 20, 21: Nung m gam hn hp X gm 3 mui kali ca 3 axit no n chc vi NaOH d thu c cht rn D v hn hp Y gm 3 ankan. T khi ca Y so vi H2 l 11,5. Cho D tc dng vi H2SO4 d thu c 17,92 lt CO2 (ktc). Cu 20: Gi tr ca m lA. 42,0. B. 84,8. C. 42,4. D. 84,0. Cu 21: Tn gi ca 1 trong 3 ankan thu c lA. metan. B. etan. C. propan. D. butan. Dng cho cu 22, 23: Hn hp A gm 1 ankan v 2,24 lt Cl2 (ktc). Chiu nh sng qua A thu c 4,26 gam hn hp X gm 2 dn xut (mono v i clo vi t l mol tng ng l 2: 3.) th lng v 3,36 lt hn hp kh Y (ktc).Cho Y tc dng vi NaOH va thu c dung dch c th tch 200ml v tng nng mol ca cc mui tan l0,6 M.Cu 22: Tn gi ca ankan l A. metan. B. etan. C. propan. D. nbutan. Cu 23: Phn trm th tch ca ankan trong hn hp A lA. 30%. B. 40%. C. 50%. D. 60%. Dng cho cu 24, 25: Craking n-butan thu c 35 mol hn hp A gm H2, CH4 ,C2H4 ,C2H6 ,C3H6 , C4H8 v mt phn butan cha b craking. Gi s ch c cc phn ng to ra cc sn phm trn. Cho A qua bnh nc brom d thy cn li 20 mol kh. Nu t chy hon ton A th thu c x mol CO2. Cu 24: Hiu sut phn ng to hn hp A lA. 57,14%. B. 75,00%.C. 42,86%. D. 25,00%. Cu 25: Gi tr ca x lA. 140. B. 70. C. 80. D. 40. Cu 26: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc) cha 12% C2H2 ;10% CH4 ;78%H2 (v th tch). Gi s ch xy ra 2 phn ng: 2CH4 C2H2 + 3H2 (1) v CH4 C + 2H2 (2). Gi tr ca V l A. 407,27. B. 448,00. C. 520,18. D. 472,64.
84

Cu 27: t chy hon ton V lt hn hp A (ktc) gm CH4, C2H6 v C3H8 thu c 6,72 lt kh CO2 (ktc) v 7,2 gam H2O. Gi tr ca V lA. 5,60. B. 3,36. C. 4,48. D. 2,24. Cu 28: t chy hon ton 6,72 lt hn hp A (ktc) gm CH4, C2H6, C3H8, C2H4 v C3H6, thu c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Tng th tch ca C2H4 v C3H6 (ktc) trong hn hp A l A. 5,60. B. 3,36. C. 4,48. D. 2,24. Cu 29: t chy hon ton hn hp A gm CH4, C2H2, C3H4, C4H6 thu c x mol CO2 v 18x gam H2O. Phn trm th tch ca CH4 trong A lA. 30%. B. 40%. C. 50%. D. 60%. Cu 30 (A-2007): Khi brom ho mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi so vi hiro l 75,5. Tn ca ankan l A. 3,3-imetylhexan. B. isopentan. C. 2,2,3-trimetylpentan. D. 2,2-imetylpropan. Cu 1: S ng phn cu to ng vi cng thc phn t C4H8 lA. 3. B. 4. C. 5. D. 6. Cu 2 (A-2007): Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 d, thu c s gam kt ta lA. 30. B. 10. C. 20. D. 40. Cu 3: Cho cc cht sau: CH3CH=CHCH3 (X); CH3C CCH3 (Y); CH3CH=CHCH2CH3 (Z); Cl2C=CHCH3 (T) v (CH3)2C=CHCH3 (U). Cc cht c ng phn cis trans l A. X, Y, Z. B. Y, T, U. C. X, Z. D. X, Y. Cu 4: Khi cho 2-metylbut-2-en tc dng vi dung dch HBr th thu c sn phm chnh l A. 3-brom-3-metylbutan. B. 2-brom-2-metylbutan. C. 2-brom-3-metylbutan. D. 3-brom-2-metylbutan. Cu 5: t chy hon ton hn hp A gm 1 ankan v 1 anken thu c x mol H2O v y mol CO2. Quan h gia x v y lA. x y. B. x y. C. x < y. D. x > y. Cu 6: Cho 1,12 gam mt anken tc dng va vi dung dch Br2 thu c 4,32 gam sn phm cng. Cng thc phn t ca anken lA. C3H6. B. C2H4. C. C4H8. D. C5H10. Cu 7: Nu t CnH2n + 2 2a (vi a 0) l cng thc phn t tng qut ca hirocacbon th gi tr ca a biu din A. tng s lin kt i. B. tng s lin kt i v lin kt ba. C. tng s lin kt pi ( ). D. tng s lin kt pi ( )v vng. Cu 8: Khi t chy hon ton hn hp gm 2 hirocacbon mch h thu c s mol CO2 v H2O bng nhau. Hn hp c th gm A. 2 anken (hoc 1 ankin v 1 ankaien). B. 2 ankin (hoc 1 ankan v 1 anken). C. 2 anken (hoc 1 ankin v 1 ankan). D. 2 ankin (hoc 1 ankan v 1 ankaien). Cu 9: t chy hon ton hn hp 2 anken thu c 11,2 lt kh CO2 (ktc). S lt O2 (ktc) tham gia phn ng chy lA. 11,2. B. 16,8. C. 22,4. D. 5,6. Cu 10: Khi cng HBr vo isopren vi t l mol 1: 1 th s lng sn phm cng to thnh l A. 2. B. 4. C. 6. D. 8.

85

Cu 11: Khi cho 0,2 mol mt ankin tc dng vi AgNO3 trong dung dch NH3 (d) thu c 29,4 gam kt ta. Cng thc phn t ca ankin l:A. C2H2. B. C3H4. C. C4H6. D. C5H8. Cu 12: Trong phng th nghim, etilen c iu ch t A. un nng ru etylic vi H2SO4 170OC. B. cho axetilen tc dng vi O H2 (Pd, t ). C. craking butan. D. cho etylclorua tc dng vi KOH trong ru. Cu 13: Cho 12,60 gam hn hp 2 anken l ng ng k tip tc dng va vi dung dch Br2 thu c 44,60 gam hn hp sn phm. Cng thc phn t ca 2 anken l A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. Cu 14: Chia 16,4 gam hn hp gm C2H4 v C3H4 thnh 2 phn bng nhau. Phn 1 tc dng va vi dung dch cha 56,0 gam Br2. Phn 2 cho tc dng ht vi H2 (Ni, tO), ri ly 2 ankan to thnh em t chy hon ton th thu c x gam CO2. Gi tr ca x l.A. 52,8. B. 58,2. C. 26,4. D. 29,1. Cu 15: Dn 4,48 lt hn hp gm C2H4 v C3H4 (ktc) qua bnh ng dung dch Br2 d thy khi lng bnh tng 6,2 gam. Phn trm th tch ca C3H4 trong hn hp lA. 75%. B. 25%. C. 50%. D. 20%. Cu 16: t chy hon ton hn hp 3 anken ri dn sn phm chy ln lt qua bnh 1 ng dung dch H2SO4 c v bnh 2 ng dung dch nc vi trong d, thy khi lng bnh 1 tng m gam v khi lng bnh 2 tng (m + 5,2)gam. Gi tr ca m lA. 1,8. B. 5,4. C. 3,6. D. 7,2. Cu 17: Dn hn hp gm 2 hirocacbon mch h c cng thc phn t C3H4 v C4H6 qua bnh ng dung dch Br2 d thy lng Br2 tham gia phn ng l 112,00 gam. Cng lng hn hp trn, nu dn qua dung dch AgNO3 trong NH3 (d) th thu c 22,05 gam kt ta. Cng thc cu to ca 2 hirocacbon tng ng l. A. CH3-C CH v CH3-CH2-C CH. B. CH2=C=CH2 v CH2=C=CH-CH3. C. CH2=C=CH2 v CH2=CH-CH=CH2. D. CH3-C CH v CH2=CH-CH=CH2. Cu 18: Hn hp kh A gm H2 v mt olefin c t l s mol l 1:1. Cho hn hp A qua ng ng Ni nung nng, thu c hn hp kh B c t khi so vi H2 l 23,2; hiu sut bng b%.Cng thc phn t ca olefin v gi tr ca b tng ng lA. C3H6; 80%. B. C4H8; 75%. C. C5H10; 44,8%. D. C6H12; 14,7%. Dng cho cu cu 19, 20: un nng hn hp X gm 0,04 mol C2H2 v 0,06 mol H2 vi bt Ni (xt) 1 thi gian c hn hp kh Y. Chia Y lm 2 phn bng nhau. Phn 1 cho li t t qua bnh nc brom d thy khi lng bnh tng m gam v cn li 448 ml hn hp kh Z (ktc) c t khi so vi hidro l 4,5. Phn 2 em trn vi 1,68 lt O2 (ktc) ri t chy hon ton thy lng O2 cn li l V lt (ktc). Cu 19: Gi tr ca m lA. 0,8. B. 0,6. C. 0,4. D. 0,2. Cu 20: Gi tr ca V lA. 0,448. B. 0,224. C. 1,456. D. 1,344. Cu 21: Trn mt hirocacbon kh (X) vi lng O2 va c hn hp A 0oC v p sut P1. t chy ht X, tng th tch cc sn phm thu c 218,4oC v p sut P1 gp 2 ln th tch hn hp A 0oC, p sut P1. Cng thc phn t ca X l:A. C2H6. B. C3H8. C. C2H4. D. C3H6. Cu 22: Cho kh C2H2 vo bnh kn c than hot tnh nung nng lm xc tc, gi s ch c mt phn ng to thnh benzen. Sau phn ng thu c hn hp kh, trong sn phm chim 50% th tch. Hiu sut phn ng l A. 25%. B. 50%. C. 75%. D. 90%. Cu 23: Trong mt bnh kn c cha C2H2 v CuCl, NH4Cl. Nung nng bnh mt thi gian thu c hn hp kh A cha 2 hirocacbon vi hiu sut phn ng l 60%. Cho A
86

hp th ht vo dung dch AgNO3 trong NH3 thu c 43,29 gam kt ta. S gam C2H2 ban u lA. 7,80. B. 5,20. C. 10,40. D. 15,60. Cu 24: t chy hon ton 0,2 mol hn hp 2 ankin l ng ng k tip thu c 9,0 gam nc. Cng thc phn t ca 2 ankin l:A. C2H2 v C3H4. B. C3H4 v C4H8. C. C4H6 v C5H10.D. C3H4 v C4H6. Cu 25: tch C2H2 ra khi hn hp gm C2H2 v C2H6, ngi ta c th s dng dung dch A. Br2. B. AgNO3 trong NH3. C. KMnO4. D. HgSO4, un nng. Cu 26: Khi cho C2H2 tc dng vi HCl thu c vinylclorua vi hiu sut 60%. Thc hin phn ng trng hp lng vinylclorua trn thu c 60,0 kg PVC vi hiu sut 80%. Khi lng C2H2 ban u l A. 52,0 kg. B. 59,8 kg. C. 65,0 kg. D. 62,4 kg. + Cu 27: Khi cho 2,4,4-trimetylpent-2-en tc dng vi H2O (H ), thu c sn phm chnh l A. 2,4,4-trimetylpentan-3-ol. B. 2,2,4-trimetylpetan-3-ol.C. 2,4,4-trimetylpentan-2-ol.D. 2,2,4trimetylpetan-4-ol. Cu 28 (A-2007): Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng xy ra hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l. A. C2H2 v C3H8. B. C3H4 v C4H8. C. C2H2 v C4H6. D. C2H2 v C4H8. Cu 29 (A-2007): Mt hirocacbon X cng hp vi HCl theo t l mol 1 : 1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l A. C3H4. B. C3H6. C. C2H4. D. C4H8. Cu 30 (A-2007): Hirat ho 2 anken ch to thnh 2 ancol (ru). Hai anken l A. propen v but-2-en (hoc buten-2). B. eten v but-1-en (hoc buten-1). C. 2-metylpropen v but-1-en (hoc buten-1). D. eten v but-2-en (hoc buten-2). Cu 31 (A-2007): Hn hp gm hirocacbon X v oxi c t l mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi so vi hiro bng19. Cng thc phn t ca X lA. C3H4. B. C3H8. C. C3H6. D. C4H8. Cu 1: Cng thc phn t tng qut ca ru 2 chc c 1 ni i trong gc hirocacbon l A. CnH2n + 2O2. B. CnH2n - 2O2. C. CnH2nO2. D. CnH2n 2aO2. Cu 2: Ru etylic c nhit si cao hn imetyl ete l do A. ru etylic c cha nhm OH. B. nhm -OH ca ru b phn cc. C. gia cc phn t ru c lin kt hiro. D. ru etylic tan v hn trong nc. Cu 3: Ru etylic tan v hn trong nc l do A. ru etylic c cha nhm OH. B. nhm -OH ca ru b phn cc. C. gia ru v nc to c lin kt hiro. D. nc l dung mi phn cc. Cu 4: Theo danh php IUPAC, hp cht (CH3)2C=CHCH2OH c tn gi l A. 3-metylbut-2 en-1-ol. B. 2- metylbut-2-en-4-ol.C. pent-2-en-1-ol. D. ancol isopent-2-en-1-ylic. Cu 5: Cht hu c X c cng thc phn t l C4H10O. S lng cc ng phn ca X c phn ng vi Na l A. 4. B.5. C. 6. D.7. Cu 6: Khi t chy hon ton 1 ancol thu c nCO < nH O . Ancol l A. ancol no, n chc. B. ancol no. C. ancol khng no, a chc. D. ancol khng no. Cu 7: Ch dng cc cht no di y phn bit 2 ancol ng phn c cng CTPT l C3H7OH?
2 2

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A. Na v H2SO4 c. B. Na v CuO. C. CuO v dung dch AgNO3/NH3. D. Na v dung dch AgNO3/NH3. Cu 8: Ch dng ho cht no sau y phn bit hai ng phn khc chc c CTPT l C3H8O? A. Al. B. Cu(OH)2. C. CuO. D. dd AgNO3/NH3. Cu 9: S lng ng phn ancol bc 2 c cng CTPT C5H12O lA. 2. B. 3. C. 4. D. 5. Cu 10: S lng ng phn c cng CTPT l C5H12O, khi oxi ho bng CuO (t0) to sn phm c phn ng trng gng lA. 2. B. 3. C. 4. D. 5. Cu 11: Cho 4 ancol sau: C2H5OH, C2H4(OH)2, C3H5(OH)3, HO-CH2-CH2-CH2-OH. Ancol khng ho tan c Cu(OH)2 l: A. C2H4(OH)2v HO- CH2- CH2- CH2-OH. B. C2H5OH v C2H4(OH)2. C. C2H5OH v HO- CH2- CH2- CH2-OH. D. Ch c C2H5OH. Cu 12: Cht hu c X mch h, c ng phn cis - trans c CTPT C 4H8O, X lm mt mu dung dch Br2 v tc dng vi Na gii phng kh H2. X c cu to l A. CH2 = CH- CH2- CH2OH. B. CH3- CH = CH- CH2OH. C. CH2 = C(CH3) - CH2OH. D. CH3 - CH2 - CH = CH OH. Cu 13: Ba ancol X, Y, Z u bn v khng phi l ng phn ca nhau. t chy hon ton mi cht u thu c CO2 v H2O vi t l s mol 3 : 4. CTPT ca ba ancol l A. C3H8O; C3H8O2; C3H8O3.B. C3H8O; C3H8O2; C3H8O4.C. C3H6O; C3H6O2; C3H6O3.D. C3H8O; C4H8O; C5H8O. Cu 14: Mt ancol no, a chc X c cng thc tng qut: CXHYOZ (y=2x+z). X c t khi hi so vi khng kh nh hn 3 v KHNG tc dng vi Cu(OH)2. Cng thc ca X l A. HO-CH2-CH2OH. B. CH2(OH)-CH(OH)-CH3.C. CH2(OH)-CH(OH)- CH2 OH D. HOCH2-CH2-CH2OH. Cu 15: Ancol no, a chc X c cng thc n gin nht l C2H5O. X c CTPT l A. C4H10O2. B. C6H15O3. C. C2H5O. D. C8H20O4. Cu 16: Khi un nng CH3CH2CH(OH)CH3 (butan-2-ol ) vi H2SO4 c, 1700C th thu c sn phm chnh l A. but-1-en. B. but-2-en. C. ietyl ete. D. butanal. Cu 17: Cho cc ancol sau: CH3-CH2-CH2-OH (1); (CH3)2CH-OH (2); CH3-CH(OH)-CH2-OH (3); CH3-CH(OH)-C(CH3)3 (4). Dy gm cc ancol khi tch nc ch cho mt olefin duy nht l A. (1), (2). B. (1), (2), (3). C. (1), (2), (4). D. (2), (3). Cu 18: Khi cho etanol i qua hn hp oxit ZnO v MgO 4500C th thu c sn phm chnh c cng thc l A. C2H5OC2H5. B. CH2=CH-CH=CH2. C. CH2=CH-CH2-CH3. D. CH2=CH2. Cu 19 (B-2007): X l ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H5(OH)3. B. C3H6(OH)2. C. C2H4(OH)2. D. C3H7OH. Cu 20 (A-2007): Cho 15,6 gam hn hp 2 ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH.C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 21: t chy hon ton m gam hn hp hai ancol n chc A v B thuc cng mt dy ng ng, ngi ta thu c 70,4 gam CO2 v 39,6 gam H2O.Gi tr ca m lA. 3,32. B. 33,2. C. 16,6. D. 24,9.
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Cu 22: t chy hon ton mt ancol n chc X thu c 4,4 gam CO2 v 3,6 gam H2O. Cng thc phn t ca X lA. CH3OH. B. C2H5OH. C. C3H5OH. D. C3H7OH. Cu 23: t chy hon ton 0,1 mol mt ancol no, mch h cn 5,6 lt kh O2 (ktc). Cng thc phn t ca ancol l A. CH4O. B. C2H6O. C. C2H 6O 2. D. C2H8O2. Cu 24: Cho 2,84 gam hn hp X gm hai ancol n chc, l ng ng k tip tc dng va vi Na to ra 4,6 gam cht rn v V lt H2(ktc). Gi tr ca V l: A. 2,240. B. 1,120. C. 1,792. D. 0,896. Cu 25: t chy mt ru a chc, thu c H2O v CO2 vi t l mol tng ng l 3:2. CTPT ca ru l A. C5H12O2. B. C4H10O2. C. C3H8O2. D. C2H6O2. Cu 26: Cho 10,6 gam hn hp X gm hai ru no n chc l ng ng lin tip tc dng vi Na d thu c 2,24 lt kh H2 (ktc). Cng thc ca 2 ru trong X l A. CH3OH v C2H5OH. B. C3H7OH v C2H5OH.C. C3H7OH v C4H9OH. D. C4H9OH v C5H11OH. Cu 27: Cho 9,2gam glixerin tc dng vi Na d thu c V lt kh H2 00C v 1,2 atm. Gi tr ca V l A. 2,798. B. 2,6. C. 2,898. D. 2,7. Cu 28: Cho ru X c CTCT thu gn l CH3-CH(CH3)-CH(OH)-CH2-CH3. Danh php IUPAC ca X l A. 2-metyl pentan-3-ol. B. 2-metyl pentanol-3. C. 4-metyl pentan-3-ol. D. 4-metyl pentanol-3. Cu 29: Tch nc mt hp cht X thu c but-1-en duy nht. Danh php quc t ca X l A. 2-metyl propan-1-ol. B. butan-1-ol. C. butan-2-ol. D. pentan-2-ol. Cu 30: Cho mt ru n chc X qua bnh ng Na d thu c kh Y v khi lng bnh tng 3,1 g. Ton b lng kh Y kh c (8/3) gam Fe2O3 nhit cao thu c Fe. Cng thc ca X l. A. CH3OH. B. C2H5OH. C. C3H5OH. D. C3H7OH. Cu 31: Cng thc tng qut ca ru no, 3 chc l A. CnH2n-3(OH)2. B. CnH2n+1(OH)3. C. CnH2n-1(OH)3. D. CnH2n+2(OH)3. Cu 1: un nng mt ancol no, n chc X vi H2SO4 c nhit thch hp thu c cht hu c Y. T khi hi ca Y so vi X l 0,7. CTPT ca X lA. C2H5OH. B. C3H7OH. C. C4H9OH. D. C5H11OH. Cu 2: Thc hin phn ng tch nc hn hp X gm ba ru vi H2SO4c 1700C, thu c sn phm ch gm hai anken v nc. Hn hp X gm A. ba ru no, n chc B. ba ru no, n chc trong c hai ru l ng phn. C. hai ru ng phn v mt ru l CH3OH. D. ba ru no a chc. Cu 3: Cho hn hp A gm hai ru no, n chc l ng ng lin tip tch H 2O (H2SO4 c, 1400C ) thu c ba ete. Trong c mt ete c khi lng phn t bng khi lng phn t ca mt trong hai ru. A gm A. CH3OH.v C2H5OH. B. C2H5OH v C3H7OH. C. C2H5OH v C4H9OH. D. C3H7OH v C4H9OH. Cu 4: un nng 15,2 gam hn hp 2 ru no n chc, l ng ng k tip vi H2SO4 c 140OC, thu c 12,5 gam hn hp 3 ete (h = 100%). Cng thc ca 2 ru l A. C3H7OH v C4H9OH. B. CH3OH v C2H5OH. C. C2H5OH v C3H7OH. D. CH3OH v C3H7OH.
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Cu 5: Thc hin phn ng tch nc mt ancol no n chc X vi H2SO4 c nhit thch hp, thu c cht hu c Y. T khi hi ca Y so vi X l 1,4375. Cng thc ca X l A. C2H5OH. B. C3H7OH. C. CH3OH. D. C4H9OH. Cu 6: Chia 27,6 gam hn hp 3 ancol n chc thnh 2 phn bng nhau. Phn 1 cho tc dng ht vi Na, thu c 3,36 lt kh H2 (ktc). Phn 2 tch nc thu c m gam hn hp 6 ete (h=100%). Gi tr ca m l A. 24,9. B. 11,1. C. 8,4. D. 22,2. Cu 7: Chia hn hp 2 ru no n chc thnh 2 phn bng nhau. t chy hon ton phn 1, thu c 2,24 lt kh CO2 (ktc). Phn 2 tch nc hon ton thu c 2 anken. S gam H2O to thnh khi t chy hon ton 2 anken trn l. A. 3,6. B. 2,4. C. 1,8. D. 1,2. Cu 8: t chy hon ton hn hp X gm 2 ancol (ru) n chc, thuc cng dy ng ng, thu c 13,2 gam CO2 v 8,28 gam H2O. Nu cho X tch nc to ete (h=100%) th khi lng 3 ete thu c l A. 42,81. B. 5,64. C. 4,20. D. 70,50. Cu 9: Cho 15,6 gam hn hp 2 ancol n chc qua bnh ng Na (d) thy khi lng bnh tng 15,2 gam. Cng lng hn hp trn, nu tch nc to ete (h = 100%) th s gam ete thu c l A. 12,0. B. 8,4. C. 10,2. D. 14,4. Cu 10: un nng mt ancol n chc X vi H2SO4 c nhit thch hp thu c cht hu c Y v nc. T khi hi ca Y so vi X l 1,609. Cng thc ca X l A. CH3OH. B. C3H7OH C. C3H5OH. D. C2H5OH. Cu 11: un nng 12,90 gam hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip trong H2SO4 c 140oC thu c 10,65 gam hn hp Y gm 3 ete (h = 100%). Tn gi ca 2 ru trong X l A. metanol v etanol. B. etanol v propan-2-ol.C. etanol v propan-1-ol. D. propan-1-ol v butan-1-ol. Cu 12: Cho 3-metylbutan-2-ol tch nc iu kin thch hp, ri ly anken thu c tc dng vi nc (xc tc axit) th thu c ancol (ru) X. Cc sn phm u l sn phm chnh. Tn gi ca X l A. 3-metylbutan-2-ol. B. 2-metylbutan-2-ol. C. 3-metylbutan-1-ol. D. 2metylbutan-3-ol. Cu 13: un nng hn hp X gm 6,4 gam CH3OH v 13,8 gam C2H5OH vi H2SO4 c 140oC, thu c m gam hn hp 3 ete. Bit hiu sut phn ng ca CH3OH v C2H5OH tng ng l 50% v 60%. Gi tr ca m l A. 9,44. B. 15,7. C. 8,96. D. 11,48. Cu 14: Cho hn hp X gm cc ru no n chc cha 1; 2 v 3 nguyn t cacbon tch nc th s lng ete ti a thu c lA. 3. B. 6. C. 10. D. 12. Cu 15: Cho m gam hn hp 2 ru no, n chc, bc 1, l ng ng k tip tc dng vi Na d thu c 1,68 lt kh 0oC; 2 atm. Mt khc cng un m gam hn hp trn 140oC vi H2SO4 c thu c 12,5 gam hn hp 3 ete (h=100%). Tn gi 2 ru trong X l A. metanol v etanol. B. etanol v propan-1-ol.C. propan-1-ol v butan-1-ol. D. pentan-1-ol v butan-1-ol. Cu 16: un nng 16,6 gam hn hp X gm 3 ru no n chc vi H2SO4 c 140oC thu c 13,9 gam hn hp 6 ete c s mol bng nhau. Mt khc, un nng X vi H2SO4 c 180oC thu c sn phm ch gm 2 olefin v nc. Cc phn ng xy ra hon ton. Tn gi ca 3 ru trong X l A. metanol, etanol v propan-1-ol. B. etanol, propan-2-ol v propan-1-ol.
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2-ol. Cu 17: Cho 0,4 mol hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip un nng vi H2SO4 c 140OC thu c 7,704 gam hn hp 3 ete. Tham gia phn ng ete ho c 50% lng ru c khi lng phn t nh v 40% lng ru c khi lng phn t ln. Tn gi ca 2 ru trong X l A. metanol v etanol. B. etanol v propan-1-ol.C. propan-1-ol v butan-1-ol. D. pentan-1-ol v butan-1-ol. Cu 18: t chy hon ton 20,64 gam hn hp X gm 3 ru n chc, thuc cng dy ng ng, thu c 42,24 gam CO2 v 24,28 gam H2O. Mt khc, un nng 20,64 gam hn hp X vi H2SO4 c 140oC (vi hiu sut phn ng ca mi ru l 50%), th thu c m gam hn hp 6 ete. Gi tr ca m l A. 17,04. B. 6,72. C. 8,52. D. 18,84. Cu 19: Cho 8,5 gam gam hn hp X gm 3 ru n chc tc dng ht vi Na, thu c 2,8 lt kh H2 (ktc). Mt khc, un nng 8,5 gam hn hp X vi H2SO4 c 140oC (vi hiu sut phn ng ca mi ru l 80%), th thu c m gam hn hp 6 ete. Gi tr ca m lA. 6,7. B. 5,0. C. 7,6. D. 8,0. Cu 20: t chy hon ton mt ancol n chc X thu c 4,4 gam CO2 v 3,6 gam H2O. Nu cho lng X trn tch nc to ete (h=100%) th s gam ete thu c l A. 3,2. B.1,4. C. 2,3. D. 4,1. Cu 21: Cho 15,6 gam hn hp X gm 2 ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Nu cho 15,6 gam X tch nc to ete (h = 100%) th s gam ete thu c lA. 10,20. B. 14,25. C. 12,90. D. 13,75. Cu 22 (A-07): Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh 3 anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. CH3CH(OH)CH2CH3. B. (CH3)3COH. C. CH3OCH2CH2CH3. D. CH3CH(CH3)CH2OH. H SO ,170 C H O, H SO l Cu 23: Cho dy chuyn ho sau: CH3CH2CH2OH X Y . Bit X, Y l cc sn phm chnh. Cng thc cu to ca X v Y ln lt l A. CH3-CH=CH2 v CH3-CH2-CH2OH. B. C3H7OC3H7 v CH3-CH2CH2OSO3H. C. CH3-CH=CH2 v CH3-CH2-CH2OSO3H. D. CH3-CH=CH2 v CH3CH(OH)CH3. Cu 24: un nng 2,3-imetylpentan-2-ol vi H2SO4 c, 1700C, thu c sn phm chnh l A. (CH3)2C=C(CH3)-CH2-CH3. B. CH3-CH=C(CH3)-CH(CH3)2. . C. CH3-CH2-CH(CH3)-C(CH3)=CH2. D. CH 2=CH-CH(CH3)CH(CH3)2. Cu 1: Cho C2H5OH qua bnh ng CuO, nung nng thu c hn hp hi X cha ti a A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. Cu 2: Oxi ho m gam hn hp X gm 2 ancol (ru) n chc, bc 1, l ng ng k tip, thu c hn hp Y gm anehit (h = 100%). Cho Y tc dng vi lng d Ag2O trong dung dch NH3, thu c 86,4 gam Ag. Mtkhc, nu cho m gam X tc dng ht vi Na th thu c 3,36 lt kh H2 (ktc). Cng thc ca 2 ru trong X l A. CH3OH v C3H7OH. B. CH3OH v C2H5OH. C. C2H5OH v C3H7OH. D. C3H5OH v C4H7OH.
2 4 0 2 2 4

C. propan-2-ol, butan-1-ol v propan-1-ol.

D. etanol, butan-1-ol v butan-

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Cu 3: Oxi ho 4,96 gam X l mt ancol (ru) n chc bc 1 (h=100%), ri ly anehit thu c cho tc dng ht vi lng d Ag2O trong dung dch NH3, thu c 66,96 gam Ag. Cng thc ca X l A. CH3OH. B. C2H5OH. C. C3H7OH. D. C3H5OH. Cu 4: Cho 12,4 gam hn hp X gm 2 ancol (ru) n chc, bc 1 l ng ng k tip qua H2SO4 c 140oC, thu c 9,7 gam hn hp 3 ete. Nu oxi ho X thnh anehit ri cho anehit thu c tc dng ht vi lng d Ag2O trong dung dch NH3 th thu c m gam Ag. Cc phn ng xy ra hon ton. Gi tr ca m l A. 64,8. B. 48,6. C. 86,4. D. 75,6. Cu 5: Oxi ho hn hp X gm C2H6O v C4H10O thu c hn hp Y gm 2 anehit. Cho Y tc dng vi dung dch AgNO3 trong NH3 (d) thu c m gam Ag. Cng lng X nh trn, nu cho tc dng vi Na d th thu c 1,12 lt kh H2(ktc). Gi tr ca m l.A. 5,4. B. 10,8. C. 21,6. D. 16,2. Cu 6: Oxi ho mt ancol X c cng thc phn t C4H10O bng CuO nung nng, thu c cht hu c Y khng tham gia phn ng trng gng. Tn gi ca X l A. butan-1-ol. B. butan-2-ol C. 2-metyl propan-1-ol. D. 2metyl propan-2-ol. Cu 7: Oxi ho 18,4 gam C2H5OH (h = 100%), thu c hn hp X gm anehit, axit v nc. Chia X thnh 2 phn bng nhau. Phn 1 cho tc dng vi lng d Ag2O trong dung dch NH3 th thu c 16,2 gam Ag. Phn 2 tc dng va vi V lt dung dch NaOH 0,5M. Gi tr ca V l A. 0,50. B. 0,65. C. 0,25. D. 0,45. c k on vn sau tr li cu 8 v 9: Oxi ho X l ru n chc, bc 1 c anehit Y. Hn hp kh v hi sau phn ng c chia thnh 3 phn bng nhau. Phn 1 cho tc dung vi Na d, thu c 5,6 lt kh H2 (ktc). Phn 2 cho tc dng vi Ag2O trong dung dch NH3 (d) thu c 64,8 gam Ag. Phn 3 t chy hon ton thu c 33,6 lt kh (ktc) CO2 v 27 gam H2O. Cu 8: Tn gi ca X lA. ru metylic. B. ru etylic. C. ru allylic. D. ru iso-butylic. Cu 9: Hiu sut qu trnh oxi ha X thnh Y lA. 40%. B. 50%. C. 60%. D. 70%. Cu 10: Oxi ho 12,8 gam CH3OH (c xt) thu c hn hp sn phm X. Chia X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Ag2O trong dung dch NH3 d thu c 64,8 gam Ag. Phn 2 phn ng va vi 30 ml dung dch KOH 2M. Hiu sut qu trnh oxi ho CH3OH lA. 60%. B. 70%. C. 80%. D. 90%. Cu 11: t chy hon ton 0,01 mol mt ancol (ru) no Y cn 0,025 mol O2. Nu oxi ho 0,02 mol Y thnh anehit (h=100%), ri cho ton b lng anehit thu c tc dng ht vi Ag2O trong dung dch NH3 th s gam Ag thu c lA. 4,32. B. 6,48. C. 8,64. D. 2,16. c k on vn sau tr li cu 12 v 13: Cho 18,8 gam hn hp A gm C2H5OH v mt ru ng ng X tc dng vi Na d thu c 5,6 lt kh H2 (ktc). Oxi ho 18,8 gam A bng CuO, nung nng thu c hn hp B gm 2 anehit (h = 100%). Cho B tc dng vi Ag2O trong dung dch NH3 (d) thu c m gam Ag. cu 12: Tn gi ca X l:A. propan-2-ol. B. metanol. C. propan-1ol. D. butan-1-ol. Cu 13: Gi tr ca m lA. 86,4. B. 172,8. C. 108,0. D. 64,8. Cu 14: Hn hp X gm 2 ru no n chc c s nguyn t cacbon chn. Oxi ho a gam X c 2 anehit tng ng. Cho 2 anehit tc dng vi Ag2O trong dung dch NH3 (d) thu 21,6 gam Ag. Nu t a gam X th thu c 14,08 gam CO2. Bit cc phn ng xy ra hon ton v 1 trong 3 ete l ng phn ca 1 trong 2 ru. Tn gi ca 2 ru trong X l
92

B. etanol v butan-2-ol. C. etanol v butan-1-ol. D. hexan-1-ol v butan-1-ol. Cu 15: t chy hon ton m gam mt ancol (ru) n chc X thu c 4,4 gam CO2 v 3,6 gam H2O. Oxi ho m gam X (c xc tc) thu c hn hp Y (h = 100%). Cho Y tc dng ht vi dung dch AgNO3 trong NH3 thu c 30,24 gam Ag. S mol anehit trong Y lA. 0,07. B. 0,04. C. 0,06. D. 0,05. Cu 16: phn bit ancol bc 3 vi ancol bc 1 v bc 2, ngi ta c th dng A. CuO (to) v dung dch Ag2O trong NH3. B. CuO (to)C. Cu(OH)2.D. dung dch H2SO4 c 170oC. Cu 17: Cho 15,6 gam hn hp X gm 2 ancol n chc, bc 1 qua ng cha 35,2 gam CuO (d), nung nng. Sau khi phn ng hon ton thu c 28,8 gam cht rn v hn hp hi Y c t khi so vi hiro l A. 27,5. B. 13,75. C. 55,0. D. 11,0. Cu 18: Chia hn hp A gm CH3OH v mt ru ng ng (X) thnh 3 phn bng nhau. Phn 1 cho tc dng vi Na d thu c 336 ml H2(ktc). Oxi ho phn 2 thnh anehit (h=100%), sau cho tc dng Ag2O trong NH3 d thu c 10,8 gam Ag. Phn 3 t chy hon ton thu c 2,64 gam CO2. Cng thc phn t ca X l A. C2H6O. B. C3H8O. C. C4H10O. D. C5H12O. Cu 19: Chia 30,4 gam hn hp X gm 2 ru n chc thnh 2 phn bng nhau. Cho phn 1 tc dng vi Na d thu c 3,36 lt H2 (ktc). Phn 2 cho tc dng hon ton vi CuO nhit cao thu c hn hp Y cha 2 anehit (h = 100%). Ton b lng Y phn ng ht vi Ag2O trong NH3 thu c 86,4 gam Ag. Tn gi 2 ru trong X l A. metanol v etanol. B. metanol v propan-1-ol.C. etanol v propan-1-ol. D. propan-1-ol v propan-2-ol. Cu 20: un nng m gam hn hp X gm CH3OH v C2H5OH vi H2SO4 c 140OC thu c 2,7 gam nc. Oxi ho m gam X thnh anehit, ri ly ton b lng anehit thu c cho tc dng vi dung dch AgNO3 trong NH3 (d) thy to thnh 86,4 gam Ag. Cc phn ng xy ra vi hiu sut 100%. Phn trm khi lng ca C2H5OH trong X lA. 25,8%. B. 37,1%. C. 74,2%. D. 62,9%. Cu 21: t chy hon ton hn hp 2 ru l ng ng k tip thu c 17,6 gam CO2 v 12,6 gam H2O. Cng lng hn hp , nu oxi ha thnh anehit (h = 100%), sau cho anehit trng gng th thu c m gam Ag. Gi tr ca m l: A. 64,8. B. 86,4. C. 108,0. D. 162,0. Cu 22(B-07): Cho m gam mt ancol (ru) no, n chc qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi so vi hiro l 15,5. Gi tr ca m lA. 0,92. B. 0,32. C. 0,64. D. 0,46. Cu 23: Cho m gam hn hp X gm C2H5OH v C2H4(OH)2 tc dng ht vi Na, thu c 4,48 lt kh H2 (ktc). Nu cho m gam X tc dng ht vi CuO, nung nng th khi lng Cu thu c l A. 6,4 gam. B. 16,0 gam. C. 8,0 gam. D. 12,8 gam. Cu 1: Chia hn hp 2 anehit no n chc thnh 2 phn bng nhau. t chy hon ton phn 1 thu c 0,54 gam H2O. Phn 2 cho tc dng vi H2 d (h = 100%) thu c hn hp 2 ru. t chy hon ton 2 ru thu c V lt kh CO2 (ktc). Gi tr ca V lA. 0,112. B. 2,24. C. 0,672. D. 1,344. Cu 2: Cho 10,2 gam hn hp X gm 2 anehit no (c s mol bng nhau) tc dng vi dung dch AgNO3 trong NH3 (d) thu c 64,8 gam Ag v mui ca 2 axit hu c. Mt khc, khi cho 12,75 gam X bay hi 136,5OC v 2 atm th th tch hi thu c l 4,2 lt. Cng thc ca 2 anehit l A. CH3-CHO v OHC-CHO. B. HCHO v OHCCH2-CHO.
93

A. metanol v etanol.

C. CH3-CHO v HCHO. D. OHC-CHO v C2H5CHO. Cu 3: C hai bnh mt nhn cha C2H2 v HCHO . Thuc th duy nht c th nhn c 2 bnh trn l A. dung dch AgNO3 trong NH3. B. dung dch NaOH. C. dung dch HCl. D. Cu(OH)2. Cu 4: S lng ng phn anhit ng vi cng thc phn t C5H10O lA. 3. B. 4. C. 5. D. 6. Cu 5: Anehit no X c cng thc n gin nht l C2H3O. CTPT ca X l A. C2H3O. B. C4H6O2. C. C6H9O3. D. C8H12O4. Cu 6: Oxi ho 2,2 gam mt anehit n chc X thu c 3 gam axit tng ng (h = 100%). CTCT ca X l A. CH3-CHO. B. CH3- CH2-CHO. C. (CH3)2CH-CHO. D. CH3CH2-CH2-CHO. Cu 7: Cho 1,02 gam hn hp gm hai anehit no, n chc, mch h (khc HCHO) k tip nhau trong dy ng ng phn ng vi dung dch AgNO3 trong NH3 d, thu c 4,32 gam Ag (h = 100%). Tn gi ca 2 anehit l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. Cu 8: Cho 2,3 gam hp cht hu c X (cha C, H, O) phn ng ht vi dung dch AgNO3 trong NH3 d, to ra 10,8 gam Ag. Tn gi ca X lA. anehit fomic. B. anehit axetic. C. axit fomic. D. anehit acrylic. Cu 9: t chy mt hn hp anehit l ng ng, thu c a mol CO2 v 18a gam H2O. Hai anehit thuc loi anehitA. no, n chc. B. vng no, n chc. C. no, hai chc. D. khng no c mt ni i, hai chc. Cu 10: Khi cho 0,1 mol X (c t khi hi s vi H2 ln hn 20) tc dng vi dung dch AgNO3 trong NH3 d, thu c 43,2g Ag. X thuc loi anehit: A. n chc. B. 2 chc. C. 3 chc. D. 4 chc. Cu 11: Hp cht hu c X un nh vi dung dch AgNO3 trong NH3 (1:2), thu c sn phm X. Cho X tc dng vi dung dch HCl hoc dung dch NaOH u thu c kh. Cng thc cu to ca X l A. HCOOH. B. HCHO. C. CH3COONa. D. CH3CHO. Cu 12: Cho 0,94 g hn hp hai anehit n chc, no, k tip nhau trong dy ng ng tc dng vi dung dch AgNO3 trong NH3 thu c 3,24 gam Ag. CTPT ca hai anehit l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. Cu 13: Trong cng nghip, ngi ta iu ch HCHO bng phng php A. oxi ho CH3OH (Cu, tO). B. nhit phn (HCOO)2Ca. C. kim ho CH2Cl2.D. kh HCOOH bng LiAlH4. Cu 14: Cng thc tng qut ca anehit no, hai chc mch h l A. CnH2n+2O2. B. CnH2nO2. C. CnH2n-2O2. D. CnH2n-4O2. Cu 15: Cho 7,2 gam mt anehit no, n chc X phn ng hon ton AgNO3 trong NH3 thu c 21,6 gam Ag. Nu cho A tc dng vi H2 (Ni, to), thu c ru n chc Y c mch nhnh. CTCT ca A l A. (CH3)2CH-CHO. B. (CH3)2CH-CH2-CHO. C. CH3-CH2-CH2-CHO. D. CH3CH(CH3)-CH2-CHO. Cu 16: X c CTCT l Cl-CH2-CH(CH3)-CH2-CHO. Danh php IUPAC ca X l A. 1-clo2-metyl butanal.B. 2-metylenclorua butanal. C. 4-clo3-metyl butanal. D. 3-metyl-4-clobutanal.

94

Cu 17: Cho hn hp X gm 2 anehit ng ng k tip tc dng ht vi H 2 (Ni, tO), thu c hn hp Y. t chy hon ton Y thu c 6,6 gam CO2 v 4,5 gam H2O. Cng thc phn t ca 2 anehit trong X l A. CH4O v C2H6O. B. CH2O v C2H4O. C. C3H6O v C4H8O. D. C3H8O v C4H10O. Cu 18: t chy hon ton 19,2 gam hn hp X gm 2 anehit ng ng k tip thu c 17,92 lt kh CO2 (ktc) v 14,4 gam H2O. Nu cho 9,6 gam X tc dng ht vi dung dch AgNO3 trong NH3 (d) th thu c m gam Ag. Gi tr ca m lA. 75,6. B. 151,2. C. 37,8. D. 21,6. Cu 19: Hn hp X gm 2 anehit no n chc, mch thng, l ng ng k tip. Khi cho 3,32 gam B tc dng vi dung dch AgNO 3 trong NH3 d thu c 10,8 gam Ag. Tn gica 2 anehit trong X l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. Cu 20: Chuyn ho hon ton 4,2 gam anehit X mch h bng phn ng trng gng vi dung dch AgNO3 trong NH3 d ri cho lng Ag thu c tc dng ht vi dung dch HNO3 to ra 3,792 lt NO2 27o C v 740mmHg. Tn gi ca X l anehitA. fomic. B. axetic. C. acrylic. D. oxalic. Cu 21: X l hn hp HCHO v CH3CHO. Khi oxi ho p gam X bng O2 thu c (p+1,6) gam Y gm 2 axit tng ng (h=100%). Cho p gam X tc dng vi dung dch AgNO3trong NH3 d thu c 25,92 gam Ag. Phn trm khi lng HCHO trong hn hp B lA. 14,56%. B. 85,44%.C. 73,17%. D. 26,83%. Cu 22: X l hn hp HCHO v CH3CHO. Khi oxi ho X bng O2 thu c hn hp Y gm 2 axit tng ng (h=100%). T khi hi ca Y so vi X l m. Khong gi tr ca m l A. 1,36 < m < 1,53. B. 1,36 < m < 1,67. C. 1,53 < m < 1,67. D. 1,67 < m < 2,33. Cu 23: Oxi ho 53,2 gam hn hp 1 ru n chc v 1 anehit n chc thu c 1 axit hu c duy nht (h=100%). Cho lng axit ny tc dng ht vi m gam dung dch NaOH 2% v Na2CO313,25% thu c dung dch ch cha mui ca axit hu c nng 21,87%. Tn gi ca anehit ban u l A. etanal. B. metanal. C. butanal. D. propanal. Cu 24: t chy hon ton hn hp 3 anehit no n chc thu c 4,48 lt kh CO2 (ktc). Cng lng hn hp , nu oxi ho thnh axit (h = 100%), ri ly axit to thnh em t chy hon ton th thu c m gam nc. Gi tr ca m lA. 1,8. B. 2,7. C. 3,6. D. 5,4. Cu 25: Cho hn hp X gm 2 anehit n chc tc dng vi H2 (Ni,to) thy tn V lt H2 (ktc) v thu c 2 ru no. Nu cho hn hp ru ny tc dng ht vi Na thu c 0,375V lt H2(ktc). Hn hp X gm A. 2 anehit no. B. 2 anehit khng no. C. 1 anehit no v 1 anehit khng no. D. 1 anehit khng no v 1 anehit thm. Cu 26 (A-07): Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X lA. HCHO. B. CH3CH(OH)CHO. C. OHC-CHO. D. CH3CHO. Cu 27 (A-07): Cho 6,6 gam mt anehit X n chc, mch h tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi HNO3 thot ra 2,24 lt kh NO duy nht (ktc). Cng thc cu to thu gn ca X l: A. CH3CHO.B. HCHO. C. CH2=CHCHO. D. CH3CH2CHO. Cu 28 (A-07): Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3 l
95

axetilen, etilen. C. anehit axetic, but-2-in, axetilen. D. axit fomic, vinylaxetilen, propin. Cu 29 (B-07): t chy hon ton a mol mt anehit X mch h to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. no, hai chc.B. no, n chc.C. khng no c hai ni i, n chc. D. khng no c mt ni i, n chc. Cu 30 (B-07): Khi oxi ho 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit lA. C2H3CHO. B. CH3CHO. C. HCHO. D. C2H5CHO. Cu 1: t chy hon ton 0,1 mol hn hp X gm 2 axit cacboxylic ng ng k tip thu c 6,16 gam CO2 v 2,52 gam H2O. Cng thc ca 2 axit l: A. CH3COOH v C2H5COOH. B. C2H3COOH v C3H5COOH. C. HCOOH v CH3COOH. D. C2H5COOH v C3H7COOH. Cu 2: Chia 0,6 mol hn hp 2 axit no thnh 2 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh CO2 (ktc). Phn 2 tc dng va vi 500 ml dung dch NaOH 1M. Cng thc cu to ca 2 axit ban u l A. CH3-COOH v CH2=CH-COOH. B. H-COOH v HOOC-COOH. C. CH3-COOH v HOOC-COOH. D. H-COOH v CH3-CH2-COOH. Cu 3: Cng thc chung ca axit cacboxylic no, n chc, mch h l A. CnH2nO2. B. CnH2n+2O2. C. CnH2n+1O2. D. CnH2n-1O2. Cu 4: Cng thc chung axit cacboxylic no, a chc, mch h l A. CnH2n-m(COOH)m. B. CnH2n+2-m(COOH)m.C. CnH2n+1(COOH)m D. CnH2n-1(COOH)m Cu 5: C4H8O2 c s ng phn axit lA. 1. B. 2. C. 3. D. 4. Cu 6: Trn 20 gam dung dch axit n chc X 23% vi 50 gam dung dch axit n chc Y 20,64% thu c dung dch D. trung ho D cn 200 ml dung dch NaOH 1,1M. Bit rng D tham gia phn ng trng gng. Cng thc ca X v Y tng ng l A. HCOOH v C2H3COOH. B. C3H7COOH v HCOOH. C. C3H5COOH v HCOOH. D. HCOOH v C3H5COOH. Cu 7: Axit icacboxylic mch thng c phn trm khi lng ca cc nguyn t tng ng l % C = 45,46%, %H = 6,06%, %O = 48,49%. Cng thc cu to ca axit l A. HOOC-COOH. B. HOOC-CH2-COOH.C. HOOC-CH2-CH2-COOH.D. HOOC-CH2CH2-CH2-COOH. Cu 8: Axit X mch thng, c cng thc thc nghim (C3H5O2)n. Cng thc cu to ca X l A. C2H4COOH. B. HOOC-(CH2)4-COOH. C. CH3CH2CH(COOH)CH2COOH. D. HOOCCH2CH(CH3)CH2COOH Cu 9: trung ho 8,8 gam mt axit cacboxylic mch thng thuc dy ng ng ca axit fomic cn 100ml dung dch NaOH 1M. Cng thc cu to ca axit l A. CH3COOH. B. CH3(CH2)2COOH. C. CH3(CH2)3COOH. D. CH3CH2COOH. Cu 10: X, Y l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp A gm 4,6 gam X v 6,0 gam Y tc dng ht vi Na thu c 2,24 lt kh H2 (ktc). Cng thc phn t ca X v Y ln lt l A. CH2O2 v C2H4O2. B. C2H4O2 v C3H6O2.C. C3H6O2 v C4H8O2. D. C4H8O2 v C5H10O2.
96

A. anehit axetic, but-1-in, etilen.

B.

anehit

fomic,

Cu 11: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. Cng thc phn t ca chng l A. C2H4O2 v C3H6O2. B. C3H6O2 v C4H8O2 C. CH2O2 v C2H4O2. D. C3H4O2 v C4H6O2. Cu 12: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. S mol ca mi axit ln lt l A. 0,05 v 0,05. B. 0,045 v 0,055. C. 0,04 v 0,06. D. 0,06 v 0,04. Cu 13: Cho 14,8 gam hn hp 2 axit hu c no, n chc tc dng vi lng va Na2CO3 to thnh 2,24 lt kh CO2 (ktc). Khi lng mi mui thu c lA. 23,2. B. 21,2. C. 20,2. D. 19,2. Cu 14: Mt hn hp hai axit hu c c phn ng trng gng. Axit c khi lng phn t ln khi tc dng vi Cl2 (as) thu c ba sn phm monoclo. Cng thc ca hai axit l A. CH3COOH v HCOOH. B. CH3COOH v HOOC-COOH C. HCOOH v CH3(CH2)2COOH. D. HCOOH v (CH3)2CHCOOH. Cu 15: Trung ho 9 gam mt axit n chc bng lng va NaOH thu c 12,3 gam mui. Cng thc cu to ca axit lA. HCOOH. B. CH2=CHCOOH. C. CH3COOH. D. CH3CH2COOH. Cu 16: Cng thc thc nghim ca mt axit no, a chc l (C3H4O3)n. Cng thc phn t ca axit l A. C6H8O6. B. C3H4O3. C. C9H12O8. D. C3H4O4. Cu 17: t chy hon ton mt axit hu c ta thu c: nCO2 = nH2O. Axit l A. axit hu c c hai chc, cha no. B. axit vng no.C. axit n chc, no. D. axit n chc, cha no. Cu 18: Trong cc ng phn axit C5H10O2. S lng ng phn khi tc dng vi Cl2 (as) ch cho mt sn phm th monoclo duy nht (theo t l 1:1) lA. 4. B. 2. C. 3. D. 1. Cu 19: t chy hon ton 1,44 gam mui ca axit hu c thm n chc ta thu c 0,53 gam Na2CO3 v 1,456 lt kh CO2 (ktc) v 0,45 gam H2O. CTCT ca mui axit thm l A. C6H5CH2COONa. B. C6H5COONa. C. C6H5CH2CH2COONa. D. C6H5CH(CH3)COONa. Cu 20: X l axit hu c tho mn iu kin: m gam X + NaHCO 3 x mol CO2 v m gam X + O2 x mol CO2. Axit X l A. CH3COOH. B. HOOC-COOH. C. CH3C6H3(COOH)2. D. CH3CH2COOH. Cu 21: Cho 5,76g axit hu c n chc X tc dng ht vi CaCO3 d, thu c 7,28g mui. Tn gi ca X l A. axit fomic B. axit axetic C. axit butyric. D. axit acrylic. Cu 22: trung ho a gam hn hp X gm 2 axit no, n chc, mch thng l ng ng k tip cn 100 ml dung dch NaOH 0,3M. Mt khc, t chy hon ton a gam X thu c b gam nc v (b+3,64) gam CO2. Cng thc phn t ca 2 axit l A. CH2O2 v C2H4O2. B. C2H4O2 v C3H6O2. C. C3H6O2 v C4H8O2. D. C4H8O2 v C5H10O2. Cu 23: Thc hin phn ng este ho m gam CH3COOH bng mt lng va C2H5OH (xc tc H2SO4 c, un nng) thu c 1,76 gam este (h=100%). Gi tr ca m lA. 2,1. B. 1,1. C. 1,2. D. 1,4. Cu 24: Hn hp X gm 1 axit no n chc v 2 axit khng no n chc c 1 lin kt i, l ng ng k tip nhau. Cho X tc dng va vi 100ml dung dch NaOH 2M, thu c 17,04 gam hn hp mui. Mt khc, t chy hon ton X thu c tng khi lng CO2 v H2O l 26,72 gam. Cng thc phn t ca 3 axit trong X l: A. CH2O2, C3H4O2 v C4H6O2. B. C2H4O2, C3H4O2 v C4H6O2.
97

C. CH2O2, C5H8O2 v C4H6O2. D. C2H4O2, C5H8O2 v C4H6O2 Cu 25: Cho hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip tc dng va vi dung dch NaHCO3 thu c 1,12 lt kh CO2 (ktc). Nu t chy hon ton X th thu c 3,136 lt CO2 (ktc). Cng thc cu to ca 2 axit trong X l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH. C. C2H3COOH v C3H5COOH. D. C2H5COOH v C3H7COOH. Cu 26 (A-07): t chy hon ton a mol mt axit hu c Y c 2a mol CO2. Mt khc, trung ho a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. CH3COOH. B. HOOC-COOH. C. HOOC-CH2-CH2-COOH. D. C2H5COOH. Cu 27 (B-07): trung ho 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y lA. CH3COOH. B. C2H5COOH. C. C3H7COOH. D. HCOOH. Cu 28 (B-07): t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 (ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V lA. 8,96. B. 11,2. C. 4,48. D. 6,72. c k on vn sau tr li cu 29 v 30: Hn hp X gm 1 axit no, mch thng, 2 ln axit (A) v 1 axit khng no c mt ni i trong gc hirocacbon, mch h, n chc (B), s nguyn t cacbon trong A gp i s nguyntcacbon trong B. t chy hon ton 5,08g X thu c 4,704 lt CO2(ktc).Trung ho 5,08g X cn 350ml dung dch NaOH 0,2M.Cu 29: Cng thc phn t ca A v B tng ng l A. C8H14O4 v C4H6O2. B. C6H12O4 v C3H4O2.C. C6H10O4 v C3H4O2. D. C4H6O4 v C2H 4O 2. Cu 30: S gam mui thu c sau phn ng trung ho lA. 5,78. B. 6,62. C. 7,48. D. 8,24. Cu 1: un nng hn hp gm 1 mol axit X c cng thc phn t C4H6O4 vi 1 mol CH3OH (xc tc H2SO4 c) thu c 2 este E v F (MF > ME). Bit rng mE = 1,81mF v ch c 72% lng ru b chuyn ho thnh este. S gam E v F tng ng lA. 47,52 v 26,28. B. 26,28 v 47,52. C. 45,72 v 28,26. D. 28,26 v 45,72. Cau 2: Trong phn ng este ho gia ru v axit hu c th cn bng s dch chuyn theo chiu to ra este khi A. gim nng ru hay axit. B. cho ru d hay axit d. C. tng nng cht xc tc. D. chng ct tch este ra. Dng cho cu 3 v 4: Hn hp M gm ru no X v axit n chc Y mch h c cng s nguyn t cacbon. t chy 0,4 mol M cn 30,24 lt O2 (ktc) thu c 52,8 gam CO2 v 19,8 gam H2O. Nu un nng 0,4 mol M vi H2SO4 c l xc tc, thu c m gam hn hp 2 este (h = 100%). Cu 3: Cng thc phn t ca X v Y tng ng l A. C3H8O3 v C3H4O2. B. C3H8O2 v C3H4O2.C. C2H6O2 v C2H4O2. D. C3H8O2 v C3H 6O 2. Cu 4: Gi tr ca m lA. 22,2. B. 24,6. C. 22,9. D. 24,9. Dng cho cu 5 v 6: Chia hn hp gm mt axit n chc vi mt ru n chc thnh 3 phn bng nhau. Phn 1 cho tc dng ht vi Na thu c 3,36 lt kh H2(ktc). Phn 2 t chy hon ton thu c 39,6 gam CO2. Phn 3 un nng vi H2SO4 c thu c 10,2 gam este E (h=100%). t chy ht lng este thu c 22 gam CO2 v 9 gam H2O. Cu 5: Cng thc phn t ca E lA. C3H6O2. B. C4H8O2. C. C5H8O2. D. C5H10O2. Cu 6: Nu bit s mol axit ln hn s mol ru th cng thc ca axit l A. HCOOH. B. CH3COOH. C. C2H5COOH. D. C3H7COOH.
98

Dng cho cu 7, 8 v 9: Thc hin phn ng este ha gia mt axit no X v mt ru no Y c este 0,1 mol E mch h. Cho 0,1 mol E phn ng hon ton vi dung dch NaOH to ra16,4g mui. t chy hon ton 0,1 mol ru Y cn 0,25 mol O2.Cu 7: Cng thc phn t ca Y l: A. C2H6O. B. C2H6O2.C. C3H8O. D. C3H8O3. Cu 8: Cng thc phn t ca E lA. C6H10O4. B. C5H8O4. C. C6H10O2. D. C5H 8O 2. Cu 9: Cho 90,0g X tc dng vi 62,0g Y c 87,6g E th hiu sut phn ng este ha l A. 80%. B. 70%. C. 60%. D. 50%. Cu 10: Cho 24,0 gam axit axetic tc dng vi 18,4 gam glixerin (H2SO4 c v un nng) thu c 21,8 gam glixerin triaxetat. Hiu sut ca phn ng l:A. 50%. B. 75%. C. 25%. D. 80%. Cu 11: t chy hon ton hn hp X gm 2 ru n chc, ng ng k tip thu c 14,08 gam CO2 v 9,36 gam H2O. Nu cho X tc dng ht vi axit axetic th s gam este thu c l A. 18,24. B. 22,40. C. 16,48. D. 14,28. Cu 12: t chy hon ton 19,68 gam hn hp Y gm 2 axit l ng ng k tip thu c 31,68 gam CO2 v 12,96 gam H2O. Nu cho Y tc dng vi ru etylic, vi hiu sut phn ng ca mi axit l 80% th s gam este thu c lA. 25,824. B. 22,464. C. 28,080. D. 32,280. Cu 13: Chia 26,96 gam hn hp X gm 3 axit n chc thnh 2 phn bng nhau. Phn 1 cho tc dng vi NaHCO3 d thu c 4,48 lt kh CO2 (ktc). Phn 2 cho tc dng ht vi etylen glicol ch thu c gam 3 este tp chc v nc. Gi tr ca m lA. 44,56. B. 35,76. C. 71,52. D. 22,28. Cu 14: Cho 5,76g axit hu c n chc X tc dng ht vi CaCO3 d, thu c 7,28g mui.Nu cho X tc dng vi 4,6 ru etylic vi hiu sut 80% th s gam este thu c l A. 6,40. B. 8,00. C. 7,28. D. 5,76. Cu 15: t chy hon ton m gam hn hp hai ancol n chc X v Y thuc cng mt dy ng ng, ngi ta thu c 70,4 gam CO2 v 37,8 gam H2O. Nu cho m gam hn hp trn tc dng vi 24,0 gam axit axetic (h = 50%) th s gam este thu c lA. 20,96. B. 26,20. C. 41,92. D. 52,40. Cu 16: t chy hon ton mt ru a chc, thu c H2O v CO2 vi t l mol tng ng l 3:2. Nu cho ru tc dng vi hn hp gm axit axetic v axit fomic th s lng este c th to thnh l A. 2. B. 3. C. 4. D. 5. Dng cho cu 17 v 18: un nng 25,8g hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip trong H2SO4 c 140oC thu c 21,3g hn hp Y gm 3 ete (h = 100%). Nu cho 25,8g X tc dng ht vi axit fomic th thu c m gam este. Cu 17: Tn gi ca 2 ru trong X l: A. metanol v etano B. etanol v propan-2-ol. C. etanol v propan-1-ol. D. propan-1-ol v butan-1-ol. Cu 18: Gi tr ca m lA. 19,9. B. 39,8. C. 38,8. D. 19,4. Cu 19: Cho 37,6 gam hn hp X gm C2H5OH v mt ru ng ng Y tc dng vi Na d thu c 11,2 lt kh H2 (ktc). Nu cho Y bng lng Y c trong X tc dng ht vi axit axetic th thu c s gam este l A. 44,4. B. 22,2. C. 35,2. D. 17,6. Cu 20: t chy hon ton hn hp 2 ru l ng ng k tip thu c 8,8 gam CO2 v 6,3 gam H2O. Cng lng hn hp trn, nu cho tc dng ht vi axit oxalic th thu c m gam hn hp 3 este khng cha nhm chc khc. Gi tr ca m lA. 19,10. B. 9,55. C. 12,10. D. 6,05.
99

Dng cho cu 21 v 22: Chia 0,9 mol hn hp 2 axit no thnh 3 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh CO2 (ktc). Phn 2 tc dng va vi 500 ml dung dch NaOH 1M. Phn 3 tc dng va vi ru etylic (xc tc H2SO4 c) thu c m gam hn hp 2 este khng cha nhm chc khc. Cu 21: Cng thc cu to ca 2 axit ban u l A. CH3-COOH v CH2=CH-COOH. B. H-COOH v HOOC-COOH. C. CH3-COOH v HOOC-COOH. D. H-COOH v CH3CH2-COOH. Cu 22: Gi tr ca m lA. 36,6. B. 22,2. C. 22,4. D. 36,8. Cu 23: Chia hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip thnh 3 phn bng nhau. Phn1 tc dng vi dung dch NaHCO3 d thu c 2,24 lt kh CO2 (ktc). Phn 2 t chy hon ton X thu c 6,272 lt CO2 (ktc). Phn 3 tc dng va vi etylen glycol thu c m gam hn hp 3 este khng cha nhm chc khc. Gi tr ca m lA. 9,82. B. 8,47. C. 8,42. D. 9,32. Cu 24: X, Y l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp A gm 5,52 gam X v 10,80 gam Y tc dng ht vi Na thu c 3,36 lt kh H2 (ktc). Nu cho A tc dng ht vi ru etylic th thu c m gam este. Gi tr ca m lA. 24,72. B. 22,74. C. 27,42. D. 22,47. Cu 25: S lng este thu c khi cho etylen glycol tc dng vi hn hp gm CH3COOH, HCOOH v CH2=CH-COOH lA. 6. B. 9. C. 12. D. 18. Cu 26 (A-07): Hn hp X gm HCOOH v CH3COOH (t l mol 1:1). Ly 5,3 gam X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c), thu c m gam hn hp este (hiu sut cc phn ng este ho u bng 80%). Gi tr ca m lA. 10,12. B. 16,20. C. 8,10. D. 6,48. Cu 27 (B-07): Cho glixerol (glixerin) phn ng vi hn hp axit bo C 17H35COOH v C15H31COOH, s loi trieste ti a c to ra l A. 6. B. 3. C. 4. D. 5. Cu 28: S lng este thu c khi cho etylenglycol tc dng vi hn hp gm 4 axit cacboxylic n chc l A. 8. B. 10. C. 14. D. 12. t chay hoan toan 0,15 mol hn hp 2 ankan thu c 9,45g H2O. Cho san phm chay vao dung dich Ca(OH)2 d thi khi lng kt tua thu c la:A. 37,5g B. 52,5g C. 15g D. 42,5g t chay hoan toan hn hp gm 1 ankan va 1 anken. Cho san phm chay ln lt i qua binh 1 ng P2O5 d va binh 2 ng KOH rn, d thy binh 1 tng 4,14g, binh 2 tng 6,16g. S mol ankan co trong hn hp la: A. 0,06 B. 0,09 C. 0,03 D. 0,045 t chay hoan toan 0,1 mol hn hp gm CH4, C4H10 va C2H4 thu c 0,14 mol CO2 va 0,23 mol H2O. S mol ankan va anken co trong hn hp ln lt la: A. 0,09 va 0,01 B. 0,01 va 0,09 C. 0,08 va 0,02 D. 0,02 va 0,08 Cho hn hp 2 anken i qua binh ng nc Br2 thy lam mt mau va u dung dich cha 8g Br2. Tng s mol 2 anken la: A. 0,1 B. 0,05 C. 0,025 D. 0,005 t chay hoan toan V lit (ktc) mt ankin th khi thu c CO2 va H2O co tng khi lng 25,2g. Nu cho san phm chay i qua dd Ca(OH)2 d thu c 45g kt tua.V co gia tri la: A. 6,72 lit B. 2,24 lit C. 4,48 lit B. 3,36 lit t chay hoan toan V lit (ktc) 1 ankin thu c 10,8g H2O. Nu cho tt ca san phm chay hp thu ht vao binh ng nc vi trong thi khi lng binh tng 50,4g. V co gia tri la:A. 3,36 lit B. 2,24 lit C. 6,72 lit D. 4,48 lit t chay hoan toan 0,1 mol ankin thu c 0,2 mol H2O. Nu hidro hoa hoan toan 0,1 mol ankin nay ri t chay thi s mol H2O thu c la :A. 0,3 B. 0,4 C. 0,5 D. 0,6
100

t chay hoan toan hn hp 2 hidrocacbon mach h, lin tip trong day ng ng thu c 22,4 lit CO2 (ktc) va 25,2g H2O. Cng thc phn t 2 hidrocacbon la: A. CH4, C2H6 B. C2H6, C3H8 C. C3H8, C4H10 D. C4H10, C5H12 Cho 14g hn hp 2 anken la ng ng lin tip i qua dung dich nc Br2 thy lam mt mau va u dd cha 64g Br2.Cng thc phn t cua cac anken la: A. C2H4, C3H6 B. C3H8, C4H10 C. C4H10, C5H12 D. C5H10, C6H12 Ty l s mol 2 anken trong hn hp la:A. 1:2 B. 2:1 C. 2:3 D. 1:1 Cho 10,2g hn hp khi A gm CH4 va anken ng ng lin tip i qua dd nc brom d, thy khi lng binh tng 7g, ng thi th tich hn hp giam i mt na.Cng thc phn t cac anken la: A. C2H4, C3H6 B. C3H6, C4H10 C.C4H8,C5H10 D. C5H10, C6H12 2. Phn trm th tich cac anken la:A. 15%, 35% B. 20%, 30% C. 25%, 25% D. 40%. 10% t chay 2 hidrocacbon th khi k tip nhau trong day ng ng thu c 48,4g CO2 va 28,8g H2O. Phn trm th tich mi hidrocacbon la: A. 90%, 10% B. 85%. 15% C. 80%, 20% D. 75%. 25% A, B la 2 ru no n chc k tip nhau trong day ng ng. Cho hn hp gm 1,6g A va 2,3g B tac dung ht vi Na thu c 1,12 lit H2 (ktc). Cng thc phn t 2 ru la: A. CH3OH, C2H5OH B. C2H5OH, C3H7OH C. C3H7OH, C4H9OH D. C4H9OH, C5H11OH t chay a gam C2H5OH c 0,2 mol CO2. t chay 6g C2H5COOH c 0,2 mol CO2. Cho a gam C2H5OH tac dung vi 6g CH3COOH (co H2SO4 xt, t0 Gia s H = 100%) c c gam este. C co gia tri la: A. 4,4g B. 8,8g 13,2g D. 17,6g t chay hn hp 2 anehit no, n chc thu c 0,4 mol CO2. Hidro hoa hoan toan 2 anehit nay cn 0,2 mol H2 thu c hn hp 2 ru no, dn chc. t chay hoan toan hn hp 2 ru thi s mol H2O thu c la: A. 0,4 mol B. 0,6mol C. 0,8 mol D. 0,3 mol Cho hn hp HCHO va H2 i qua ng ng bt nung nong. Dn toan b hn hp thu u sau phan ng vao binh nc lanh ngng tu hi cht long va hoa tan cac cht co th tan c , thy khi lng binh tng 11,8g. Ly dd trong binh cho tac dung vi dd AgNO3/NH3 thu c 21,6g Ag. Khi lng CH3OH tao ra trong phan ng hp H2 cua HCHO la:A. 8,3g B. 9,3g C. 10,3g D. 1,03g Cht hu c X thanh phn gm C, H, O trong o %O: 53,3 khi lng. Khi thc hin phan ng trang gng, t 1 mol X 4 mol Ag. CTPT X la:A. HCHO B. (CHO)2 C. CH2(CHO)2 D. C2H4(CHO)2 un 132,8 hn hp gm 3 ru n chc vi H2SO4 c, 1400C hn hp cac ete co s mol bng nhau va co khi lng la 111,2g. S mol ete la:A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol Cho 20,15g hn hp 2 axit no n chc tac dung va u vi dd Na2CO3 thi thu c V lit CO2 (ktc) va dd mui.C can dd thi thu c 28,96g mui. Gia tri cua V la: A. 4,84 lit B. 4,48 lit C. 2,24 lit D. 2,42 lit E. Kt qua khac Cho 10g hn hp 2 ru no n chc k tip nhau trong day ng ng tac dung va u vi Na kim loai tao ra 14,4g cht rn va V lit khi H2 (ktc). V co gia tri la:A. 1,12 lit B. 2,24 lit C. 3,36 lit D. 4,48 lit cho 2,83g hn hp 2 ru n chc tac dung va u vi Na thi thoat ra 0,896 lit H2 (ktc) va m gam mui khan. Gia tri cua m la:A. 5,49g B. 4,95g C. 5,94g D. 4,59g Cho 4,2g hn hp gm ru etylic, phenol, axit fomic tac dung va u vi Na thy thoat ra 0,672 lit H2 (ktc) va 1dd. C can dd thu c hn hp rn X. Khi lng cua X la:A. 2,55g B. 5,52g C. 5,25g D. 5,05g Chia hn hp 2 anehit no n chc lam 2 phn bng nhau: P1: em t chay hoan toan thu c 1,08g H2O
101

P2: tac dung vi H2 d (Ni, t0) thi thu hn hp A. em A t chay hoan toan thi th tich CO2 (ktc) thu c la: A. 1,434 lit B. 1,443 lit C. 1,344 lit D. 1,444 lit Tach nc hoan toan t hn hp Y gm 2 ru A, B ta c hn hp X gm cac olefin. Nu t chay hoan toan Y thi thu c 0,66g CO2. Vy khi t chay hoan toan X thi tng khi lng CO2 va H2O la: A. 0,903g B. 0,39g C. 0,94g D. 0,93g Hn hp X gm 2 ru no co s nguyn tC,H bng nhau. t chay hoan toan 0,25 mol X thu c 11,2 lit CO2 (ktc). Mt khac 0,25 mol X em tac dung vi Na d thy thoat ra 3,92 lit H2 (ktc). Cac ru cua X la: A.C3H7OH va C3H6(OH)2 B.C4H9OH va C4H8(OH)2 C.C2H5OH va C2H4(OH)2 D.C3H7OH va C3H5(OH)3 1. Cho cc cht sau: (1) HO-CH2-CH2OH (2) HO-CH2-CH2-CH2OH (3) HOCH2-CHOHCH2OH (4) C2H5-O-C2H5 (5) CH3CHO. Nhng cht tc dng c vi Natri l... A. 1, 2 v 3. B. 3, 5 v 2. C. 4, 5 v 3. D. 4, 1 v 3. 2. un nng mt ru X vi H2SO4 m c nhit thch hp thu c mt olefin duy nht. Trong cc cng thc sau:

(1) CH3-CH-CH3
OH

(2) CH3-CH2-CH-CH3
OH

CH3

(3) CH3-CH2-CH2-CH2-OH

(4) CH3-C-CH2-OH
CH3

cng thc no ph hp vi X.?A. (1), (2), (3) B. (1), (2), (3), (4) C. (1), (2), (4) D. (1), (3), (4) 3. Nhng cht trong dy no sau y u tc dng c vi ru etylic ? A. HCl ; HBr ; CH3COOH ; NaOH B. HBr ; CH3COOH ; Natri ; CH3OCH3. C. CH3COOH ; Natri ; HCl ; CaCO3. D. HCl ;HBr ;CH3COOH ; Natri. 4. S ng phn ru c cng thc phn t C5H12O l: A. 8 ng phn B. 5 ng phn C. 14 ng phn D. 12 ng phn 5. S loi nc mt ng phn A ca C4H9OH cho hai olefin . ng phn A l... A. Ru iso butylic. B. Ru n-butylic. C. Ru sec butylic. D. Ru tert butylic. 6. t chy hon ton 2 ru X, Y ng ng k tip nhau ngi ta thy t s mol CO2 v H2O tng dn. Dy ng ng ca X, Y l:A. Ru no. B. Ru khng no C. Ru thm. D. Phenol
2 X 7. Xt chui phn ng: Etanol 1700 C4

H SO

Cl 2 Y c tn l Y , :

A. Etyl clorua. B. MetylClorua. C. 1,2- Dicloetan. D. 1,1- Dicloetan. 9. linh ng ca nguyn t H trong nhm OH ca cc hp cht gim dn theo th t: A. CH3COOH >C2H5OH > C6H5OH. B. CH3COOH > C6H5OH >C2H5OH. C. C2H5OH > C6H5OH > CH3COOH. D. C6H5OH > CH3COOH > C2H5OH. 11. un nng t t hn hp etanol v propanol-2 vi xc tc l axit sunfuric c ta c th thu c ti a bao nhiu sn phm hu c ch cha C, H, O ?A. 2. B. 3. C. 4. D. 5. 12. S ng phn ca hp cht hu c c cng thc C4H10O l: A. 2 ng phn B. 4 ng phn C. 7 ng phn D. 9 ng phn
CH3-CH-CH-CH3
CH3 OH 13. un nng mt ru M vi H2SO4 c 170oC thu c 1 anken duy nht. Cng thc tng qut ng nht ca M l: A. CnH2n+1CH2OH. B. R-CH2OH. C. CnH2n+1OH. D. CnH2n-1CH2OH 14. Cho bit sn phm chnh ca phn ng kh nc ca A. 2-metylbuten-1 B. 3-metylbuten-1 C. 2-metylbuten-2 D. 3-metylbuten-2

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15. t chy mt ru X ta thu c s mol CO2 > s mol H2O. X c th l ru no sau y? A. Ru no n chc. B. Ru khng no c 1 lin kt pi.C. Ru khng no c 2 lin kt pi.D. Ruu no a chc. 16. ng phn no ca C4H9OH khi tch nc s cho hai olefin ng phn? A. 2-metyl propanol-1 B. 2-metyl propanol-2 C. Butanol-1 D. Butanol-2 17. phn bit ru n chc vi ru a chc c t nht 2 nhm OH lin k nhau ngi ta dng thuc th l... A. dung dch Brom. B. dung dch thuc tm. C. dung dch AgNO3. D. Cu(OH)2. 19. Mt ru no c cng thc thc nghim (C2H5O)n. Cng thc phn t ca ru l... A. C2H5O. B. C4H10O2 . C. C6H15O3 . D. C8H20O4 20. Hp cht:
CH3-CH-CH=CH2
CH3

L sn phm chnh (theo quy tc maccopnhicop) ca phn ng loi nc hp cht no sau y? A. 2-metylbutanol-3 B. 3-metylbutanol-2 C. 3-metylbutanol-1 D. 2-metylbutanol 21.A l ng ng ca ru etylic c t khi hi so vi oxi bng 2,3125. S ng phn c mch cacbon khng phn nhnh ca A l... A. 1 B. 2 C. 3 D. 4 22. t chy 1,85 gam mt ru no n chc cn c 3,36 lit O2 (ktc). Cng thc ru l: A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH 23. Mt ru no, n chc, bc 1 b tch mt phn t nc to anken A. C 0,525 gam anken A tc dng va vi 2g brm. Ru ny l... A. Butanol-1 B. Pentanol-1 C. Etanol D. Propanol-1 24. Cho 18,8 gam hn hp 2 ru no, n chc, k tip nhau trong dy ng ng tc dng viNa d thu c 5,6 lit H2 (ktc). Khi lng (g) mi ru l:A. 9,6 v 9,2 B. 6,8 v 12,0 C. 10,2 v 8,6 D. 9,4 v 9,4 25. un nng hn hp hai ru mch h vi H2SO4 c ta c cc ete. Ly X l mt trong cc ete t chy hon ton c t l mol ca X, oxi cn dng , cacbonic v nc to ra ln lt l 0,25: 1,375: 1:1. Cng thc 2 ru trn l... A. C2H5OH v CH3OH. B. C3H7OH v CH2= CH 2 CH OH. C. C2H5OH v CH2= CHOH. D. CH3OH v CH2 = CH CH2OH. 26. un 1,66 gam 2 ru (H2SO4 c) thu c 2 anken l ng ng k tip nhau.t hn hp 2 anken cn 1,956 lit O2 (25oC, 1,5 at). CTPT 2 ru l: A. C2H5OH, C3H7OH B. CH3OH, C2H5OH C. C2H5OH, C3H5OH D. C3h7OH, C4H9OH 27. Cho 5,3g hn hp 2 ankanol ng ng lin tip tc dng vi natri d thu c 1,12 lt H2 (ktc). Cng thc phn t ca 2 ankanol trn l ... A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H7OH v C4H9OH. D. C4H9OH v C5H11OH. 28. Cho 16,6 gam hn hp gm ru etylic v ru n-propylic phn ng ht vi Na d thu c 3,36 lit H2 (ktc). % v khi lng cc ru trong hn hp l. A. 27,7% v 72,3% B. 60,2% v 39,8% C. 40% v 60% D. 32% v 68% 29. X l mt ru no, a chc, mch h c s nhm OH nh hn 5. C 7,6 gam ru X phn ng ht vi Natri cho 2,24 lt kh (o ktc). Cng thc ho hc ca X l... A. C4H7(OH)3. B. C2H4(OH)2. C. C3H6(OH)2. D. C3H5(OH)3. o 30. un nng 1 hn hp gm 2 ru no n chc vi H2SO4 c 140 C thu c 21,6 gam nc v 72 gam hn hp 3 ete. Bit 3 ete c s mol bng nhau (phn ng hon ton). CTPT 2 ru l: A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C. C3H7OH v C4H9OH D. CH3OH v C3H7OH 31. Pht biu no sau y NG khi ni v phenol?
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A. Phenol c nhm OH trong phn t nn c tnh cht ho hc ging ru. B. Phenol c tnh axit nn phenol tan c trong dung dch kim. C.Tnh axit ca phenol mnh hn axit cacbonic v phenol tc dng vi CaCO3 to kh CO2. D. Dung dch phenol trong nc cho mi trng axit, lm qu tm i mu sang . 32. Chn cu ng: Phenol c th tc dng vi A. HCl v Na B. Na v NaOH C. NaOH v HCl D. Na v Na2CO3 33. Cho cc cht c cng thc cu to :
CH3 OH

OH

CH2

OH

(2) (3) Cht no thuc loi phenol? A. (1) v (2). B. (2) v (3). C. (1) v (3). D. C (1), (2) v (3). 34. Khi cho Phenol tc dng vi nc brom, ta thy: A. Mt mu nu ca nc brom B. To kt ta gch C. To kt ta trng D. To kt ta xm bc 35. Ha cht duy nht dng nhn bit 3 cht lng ng ring bit trong ba bnh mt nhn : phenol, stiren v ru etylic l...A. natri kim loi. B. qu tm. C. dung dch NaOH. D. dung dch brom. 36. Phn ng no sau y chng minh phenol c tnh axit yu: A. C6H5ONa + CO2 + H2O B. C6H5ONa + Br2 C. C6H5OH + NaOH D. C6H5OH + Na 37. Khi nh dung dch brom vo dung dch phenol lp tc thy xut hin kt ta trng l do... A. phenol cho phn ng cng vi brom d dng hn so vi benzen. B. phenol c tnh axit yu nn b brom y ra thnh cht khng tan trong dung dch. C. phenol d cho phn ng th vi brom cc v tr octo v para to cht khng tan. D. brom chim ly nc lm phenol tch ra thnh cht kt ta. 38. Cho cht sau y m-HO-C6H4-CH2OH tc dng vi dung dch NaOH. Sn phm to ra l:
ONa

(1)

ONa

OH

ONa

A. ..
CH2ONa

B
CH2ONa

C
CH2OH

D
CH2OH

39. Cho a (mol) hp cht hu c X c cng thc phn t C7H8O2 tc dng vi natri d thu c a (mol) kh H2 (ktc).Mt khc, a (mol)X ni trn tc dng va vi a (mol) Ba(OH)2. Trong phn t X c th cha: A..1 nhm cacboxyl COOH lin kt vi nhn thm. B. 1 nhm 2OH v 1 nhm lin kt vi nhn CH OH thm.C. 2 nhm lin kt trc tip vi nhn thm. OH D. 1 nhm CH2OH lin kt vi nhn O thm. 40. Dng phn ng ha hc no chng minh nguyn t hidro trong nhm hiroxyl ca phenol linh ng hn nguyn t hidro trong nhm hiroxyl ca ru etylic. A. C6H5OH + Na B. C6H5OH + Br C. C6H5OH + NaOH D. c C6H5OH + Na v C6H5OH + NaOH u c. 41. Cho m(gam) phenol C6H5OH tc dng vi natri d thy thot ra 0,56 lt kh H2 (ktc). Khi lng m cn dng l... A. 4,7g. B. 9,4g. C. 7,4g. D. 4,9g. 42. Cho nc brom d vo dung dch phenol thu c 6,62 gam kt ta trng (phn ng hon ton). Khi lng phenol c trong dung dch l:A. 1,88 gam B. 18,8 gam C. 37,6 gam D. 3,76 gam 43. Cho 47 gam phenol tc dng vi hn hp gm 200 gam HNO3 68% v 250 gam H2SO4 96% to axit picric (phn ng hon ton). Nng % HNO3 cn d sau khi tch kt t axit picric ra l: A. 10,85% B. 1,085% C. 5,425% D. 21,7%
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Cu no sau y l khng ng? A.Anehit no, n chc c cng thc phn t tng qut CnH2n+2O. B. Khi tc dng vi hiro, xeton b kh thnh ancol bc II. C. Anehit tc dng vi dung dch bc nitrat trong amoniac sinh ra bc kim loi. D. Anehit cng hiro to thnh ancol bc mt. Th t tng dn nhit si ca cc cht andehit propionic (X); propan (Y); ru etylic (Z) v imetyl ete (T) l: A.Y < T < X < Z B.T < X < Y < Z C.X < Y < Z < T D.Z < T < X <Y Trong cng nghip, andehit fomic c iu ch trc tip t A. ru metylic B. ru etylic C. axit fomic D.metyl axetat Cho 4 cht: benzen, metanol, phenol, andehit fomic. Th t cc ho cht c dng phn bit 4 cht trn l: A. dung dch AgNO3/NH3; nc brom; Na B. Na ; nc brom ; dung dch AgNO3/NH3; C. nc brom; dung dch AgNO3/NH3; Na D. dung dch AgNO3/NH3; Na ; nc brom 1. Trong s cc cht: CH4, C2H6, C3H8, C2H4, C2H2 th cht no c hm lng cacbon cao nht? A / CH4 B / C2H 6 C / C2H4 D/ C2H2 3. t chy hon ton V lt ( ktc) mt ankin th kh thu c H2O v CO2 c tng khi lng l 25,2g. Nu cho sn phm chy i qua dung dch Ca(OH)2 d, c 45g kt ta. 1) V c gi tr l: A / 6,72 lt B / 2,24 lt C / 4,48 lt D / 3,36 lt 2) CTPT ca ankin l: A / C 2H2 B / C3H4 C / C4H6 D / C 5H8 4. t chy hon ton V lt (ktc) mt ankin thu c 5,4g H2O. Tt c sn phm chy cho hp th ht vo bnh nc vi trong thy khi lng bnh tng 25,2g. V c gi tr l: A / 3,36 lt B / 2,24 ltC / 6,72 lt D / 6 lt 5. Chia hn hp gm C3H6, C2H4, C2H2 thnh 2 phn u nhau. Phn 1: em t chy hon ton thu c 22,4 lt CO2 (ktc). Phn 2: em hiro ho hon ton sau mang t chy th th tch CO2 thu c l: A / 22,4 lt B / 11,2 lt C / 44,8 lt D / 33,6 lt 6. t chy hon ton 0,1 mol ankin c 3,6g H2O. Nu hiro ho hon ton 0,1 mol ankin ri t chy th lng nc thu c l: A / 4,2g B / 5,2g C / 6,2g D / 7,2g 7. t chy hon ton mt th tch gm C2H6 v C2H2 thu c CO2 v nc c t l s mol l 1 : 1. Phn trm th tch ca mi kh trong hn hp u l: A / 50% v 50% B / 30% v 70% C / 25% v 75% D / 70% v 30% 8. Dn 4,032 lt (ktc) hn hp kh A gm C2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dch AgNO3 d trong NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2g kt ta. Khi lng bnh 2 tng thm 1,68g. Th tch mi kh trong hn hp A ln lt l: A / 0,672 lt; 1,344 lt; 2,016 lt B / 0,672 lt; 0,672 lt; 2,688 lt C / 1,344 lt; 2,016 lt; 0,672 lt D / 2,016 lt; 0,896 lt; 1,12 lt 9. X l hn hp kh gm 2 hirocacbon. t chy 1 lt hn hp X c 1,5 lt CO2 v 1,5 lt hi H2O. (Cc th tch kh o cng iu kin)CTPT ca 2 hirocacbon l:
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C / C 3H8, C2H6 D / Khng xc nh c 10. t chy hon ton V lt mt ankin thu c 10,8g H2O. Nu cho tt c sn phm chy hp th ht vo bnh ng nc vi trong th khi lng bnh tng 50,4g. Gi tr ca V l: A / 3,36 lt B / 2,24 lt C / 6,72 lt D / 4,48 lt 11. t chy hon ton 2 hiocacbon mch h lin tip trong dy ng ng thu c 44g CO2 v 12,6g H2O. Hai hirocacbon l: A / C3H8, C4H10 B / C2H4, C3H6 C / C3H4, C4H6 D / C5H8, C6H10 12. t chy hon ton V lt (ktc) mt ankin thu c 7,2g H2O. Nu cho tt c sn phm chy hp th ht vo bnh ng nc vi trong d th khi lng bnh tng 33,6g 1) V c gi tr l: A / 3,36 ltB / 6,72 ltC / 2,24 ltD / 4,48 lt 2) Ankin l: A / C3H4 B / C5H8 C / C4H6 D / C 2H2 13. t chy hon ton V lt (ktc) mt ankin th kh thu c CO2 v H2O c tng khi lng l 25,2g. Nu cho sn phm chy i qua bnh ng nc vi trong d thu c 45g kt ta. 1) Gi tr ca V l: A / 6,72 lt B / 2,24 lt C / 4,48 lt D / 3,36 lt 2) CTPT ca ankin l: A / C 2H2 B / C 3H4 C / C4H6 D / C 5H8 1. Cu no ng nht trong cc cu sau y? A / Benzen l mt hirocacbon B / Benzen l mt hirocacbon no C / Benzen l mt hirocacbon khng no D / Benzen l mt hirocacbon thm 5. Khi lng ring ca ru etylic v benzen ln lt l 0,78g/ml v 0,88g/ ml. Khi lng ring ca mt hn hp gm 600 ml ruetylic v 200 ml benzen (cc khi lng ring c o trong cng iu kin v gi s khi pha trn th tch hn hp bng tng th tch cc cht pha trn) l: A / 0,805 g/ml B / 0,795g/ml C / 0,826g/ml D / 0,832g/ml 6. Mt ng ng ca benzen c CTPT C8H10. S ng phn ca cht ny l : A / 1 B/2 C/3 D/4 7. Cc cu sau ng hay sai? A / Benzen c CTPT l C6H6 B/ Cht c CTPT C6H6 phi l benzen C / Benzen c cng thc n gin nht l CH. D / Cht c cng thc n gin nht l CH ch l benzen 8. Th tch khng kh (ktc) cn dng t chy hon ton 0,1 mol benzen l: A / 84 lt B / 74 lt C / 82 lt D / 83 lt 10. Lng clobenzen thu c khi cho 15,6g C6H6 tc dng ht vi Cl2 (xc tc bt Fe) hiu sut phn ng t 80% l: A / 14g B / 16g C / 18g D / 20g eSTE - dng 1: CTPT - CTCT Cu 1: Khi t chy hon ton mt este to (bi cc nguyn t C, H, O) thu c x mol CO2 v y mol H2O. Ta lun lun c A. x < y. B. x > y. C. x y. D. x y. Cu 2: Cng thc phn t tng qut ca este mch h to bi axit no n chc v ru n chc c 1 ni i trong gc hirocacbon l: A. CnH2nO2. B. CnH2n - 2O2. C. CnH2n + 2O2. D. CnH2n 2aO2.

A / CH4, C2H2

B / C 2H6, C2H4

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Cu 3: t chy hon ton 6 gam mt este X thu c 4,48 lt kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca X l: A. C4H8O2. B. C3H6O2. C. C2H 4O 2. D. C4H6O2. Cu 4: S lng ng phn este ng vi cng thc phn t C4H8O2 l A. 2. B. 3. C. 4. D. 5. Cu 5: Khi thu phn este X c cng thc phn t C4H6O2 trong mi trng axit thu c 2 cht c th tham gia phn ng trng gng. Cng thc cu to thu gn ca X l A. CH3-COO-CH=CH2. B. H-COO-CH2-CH=CH2. C. CH2=CH-COO-CH3. D. H-COO-CH=CH-CH2. Cu 6: t chy hon ton 0,88 gam 2 este ng phn thu c 1,76 gam CO2 v 0,72 gam H2O. Cng thc phn t ca 2 este lA. C4H8O2. B. C3H6O2. C. C5H10O2. D. C4H6O2. Cu 7: t chy hon ton m gam hn hp 2 este no, n chc, mch h thu c 1,8 gam H2O. Thu phn hon ton m gam hn hp 2 este trn thu c hn hp X gm axit v ru. Nu t chy hon ton hn hp X thu c V lt kh CO2 (ktc). Gi tr ca V lA. 2,24. B. 3,36. C. 4,48. D. 1,12. Cu 8: X phng ho hon ton 22,2 gam hn hp 2 este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH va thu c 21,8 gam mui. S mol HCOOC2H5 v CH3COOCH3 ln lt l A. 0,15 v 0,15. B. 0,2 v 0,1. C. 0,1 v 0,2. D. 0,25 v 0,05. Cu 9: Mt este ch cha C,H,O c MX< 200 vC. t chy hon ton 1,60 gam X ri dn ton b sn phm chy vo bnh ng dung dch Ba(OH)2 d thy khi lng bnh tng 4,16g v c 13,79g kt ta. Cng thc phn t ca X lA. C8H14O4. B. C7H12O4. C. C8H16O2. D. C7H14O2. Cu 10: Mt cht hu c X c cng thc phn t C7H12O4 ch cha mt loi nhm chc. Khi cho 16 gam X tc dng va vi 200g dung dch NaOH 4% th thu c mt ru Y v 17,8gam hn hp 2 mui. Cng thc cu to ca X l A. CH3-COO-CH2-CH2-OOC-C2H5. B. CH3-OOC-CH2-CH2-OOC-C2H5. C. CH3-OOC-CH2-CH2-COO-C2H5. D. CH3-COO-CH2-CH2-COO-C2H5. Dng cho cu 11, 12, 13: Hn hp X gm 2 este ca 2 axit k tip nhau trong dy ng ng: R1COOR, R2COOR. t chy hon ton 20,1 gam X cn 29,232lt O2 (ktc) thu c 46,2 gam CO2. Mt khc, cho 20,1gam X tc dng vi NaOH thu c 16,86 gam hn hp mui. Cu 11: Cng thc phn t ca 2 este l A. C5H8O2 v C6H8O2. B. C5H10O2 v C6H12O2. C. C5H8O2 v C7H10O2. D. C5H8O2 v C6H10O2. Cu 12: Trong X, phn trm khi lng ca este c khi lng phn t nh hn l A. 14,925%. B. 74,626%. C. 85,075%. D. 25,374%. Cu 13: Cng thc cu to ca 2 este l A. CH3COOC3H5 v C2H5COOC3H5. B. HCOOC4H7 v CH3COOC4H7. C. CH3COOC3H7 v C2H5COOC3H7. D. HCOOC4H9 v CH3COOC4H9. Cu 14: t chy hon ton 8,8 gam 1 este no n chc thu c lng CO2 ln hn lng H2O l 10,4 gam. Cng thc phn t ca este lA. C4H6O2. B. C3H6O2. C. C4H8O2. D. C3H8O2. Dng cho cu 15, 16, 17: Cho 35,2gam hn hp A gm 2 este no n chc l ng phn ca nhau v to bi 2 axit ng ng k tip c t khi hi so vi H2 l 44 tc dng vi 2lt dung dch NaOH 0,4M, ri c cn dung dch sau phn ng thu c 44,6g cht rn B. Cu 15: Cng thc phn t ca 2 este l A. C5H10O2. B. C4H8O2. C. C6H8O2. D. C5H8O2. Cu 16: Khi lng ru thu c l A. 6,6g. B. 22,6g. C. 8,6g. 35,6g.
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Cu 17: Cng thc cu to ca 2 este l A. CH3COOC2H5 v C2H5COOCH3. B. HCOOC3H7 v CH3COOC2H5. C. CH3COOC3H7 v C2H5COOC5H5. D. HCOOC4H9 v CH3COOC3H7. Dng cho cu 18, 19: Cho 16,4 gam mt este X c cng thc phn t C10H12O2 tc dng va vi 200ml dung dch NaOH 1M thu c dung dch Y. Cu 18: Cng thc cu to ca X l A. CH3-COO-CH2-C6H4-CH3. B. C2H5-COO-CH2-C6H5. C. C6H5-CH2-COO-C2H5. D. C3H7-COO-C6H5. Cu 19: Khi lng mui trong Y lA. 11,0g. B. 22,6g. C. 11,6g. 35,6g. Dng cho cu 20, 21: Cho 27,2 gam hn hp E gm 2 cht hu c A v B c cng chc ho hc vi dung dch NaOH d thu c sn phm gm mt mui duy nht ca mt axit n chc, khng no v 11 gam hn hp 2 ru no, n chc, ng ng k tip. t chy hon ton 27,2 gam E cn 1,5 mol O2 v thu c 29,12lt CO2(ktc). Cu 20: Cng thc phn t ca 2 cht trong E l A. C4H8O2 v C5H10O2. B. C4H6O2 v C5H8O2. C. C5H10O2 v C6H12O2. D. C5H8O2 v C6H10O2. Cu 21: Tn gi ca 2 este l A. metyl acrylat v etyl acrylat. B. metyl axetat v etyl axetat. C. etyl acrylat v propyl acrylat. D. metyl propionat v etyl propionat. \Cu 22 (A-07): Mt este c cng thc phn t C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A.CH2=CHCOOCH3. B. CH3COOCH=CH2. C. HCOOC(CH3)=CH2. D. HCOOCH=CH-CH3. Cu 23 (B-07): Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l A. HCOOC2H5 v CH3COOCH3. B. HCOOCH2CH2CH3 v CH3COOC2H5. C. C2H3COOC2H5 v C2H5COOC2H3. D. C2H5COOCH3 v HCOOCH(CH3)3. Cu 24: Cho 8,8 gam mt este X c cng thc phn t C4H8O2 tc dng ht vi dung dch KOH thu c 9,8 gam mui. Tn gi ca X l A. metyl propionat. B. etyl axetat. C. n-propyl fomiat. D. iso-propyl fomiat. Cu 25 (A-07): Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C17H35COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C15H31COOH. Cu 26 (A-07): Mnh khng ng l A. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. B. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. C. CH3CH2COOCH=CH2 c th trng hp to polime. D. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. Cu 27 (A-07): X phng ho 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 3,28 gam. B. 10,4 gam. C. 8,56 gam. D. 8,2 gam. Este Dng 2: Ru Mui CTCT ca este

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Dng cho cu 1, 2, 3: Thu phn hn hp 2 este n chc bng mt lng va dung dch NaOH thu c 49,2 gam mui ca mt axit hu c v 25,5 g hn hp 2 ru no ng ng lin tip. t chy ht 2 ru thu c 1,05 mol CO2. Cu 1: Cng thc ca 2 ru to este l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H7OH v C4H9OH. D. C3H5OH v C4H7OH. Cu 2: S mol ca ru nh trong hn hp ru thu c l A. 0,15. B. 0,20. C. 0,30. D. 0,45. Cu 3: Tn gi ca 2 este l A. metyl axetat v etyl axetat. B. etyl axetat v propyl axetat. C. propyl fomiat v butyl fomiat. D. metyl fomiat v etyl fomiat. Dng cho cu 4, 5, 6: Hn hp A gm 2 este ca cng mt axit hu c n chc v 2 ru n chc, ng ng k tip. Cho 26,5g A tc dng vi NaOH thu c m gam mui v 10,3g hn hp B gm 2 ru. Cho ton b B tc dng vi Na d thu c 3,36 lt H2 (ktc). Cu 4: Gi tr ca m lA. 22,2. B. 28,2. C. 22,8. D. 16,2. Cu 5: Tn ca 2 ru trong B lA. metanol v etanol. B. etanol v propan-1-ol. C. propan-1-ol v butan-1-ol. D. propenol v but-2-en-1-ol. Cu 6: Tn ca axit to 2 este trong A l A. axit fomic. B. axit axetic. C. axit acrylic. D. axit metacrylic. Dng cho cu 7, 8, 9: Hn hp X gm 2 este n chc trong s mol este ny gp 3 ln s mol este kia. Cho a gam X tc dng ht vi NaOH thu c 5,64g mui ca 1 axit hu c n chc v 3,18 gam hn hp Y gm 2 ru no, n chc, u to olefin. Nu t chy ht Y th thu c 3,36 lt kh CO2 (ktc). Cu 7: S nguyn t cacbon ca 2 ru trong Y l A. 1 v 2. B. 2 v 3. C. 2 v 4. D. 3 v 4. Cu 8: Gi tr ca a lA. 6,42. B. 6,24. C. 8,82. D. 8,28. Cu 9: Tn gi ca axit to 2 este trong X l A. axit fomic. B. axit axetic. C. axit acrylic. D. axit metacrylic. Dng cho cu 10, 11, 12: Cho m gam mt este n chc X tc dng hon ton vi 500 ml dung dch KOH 0,24 M ri c cn thu c 10,5 gam cht rn khan Y v 5,4 gam ru Z. Cho Z tc dng vi CuO nung nng, thu c anehit T (h=100%). Thc hin phn ng trng gng hon ton vi T thu c 19,44 gam Ag. Cu 10: Tn gi ca Z lA. butan-2-ol. B. propan-2-ol. C. butan-1-ol. D. propan-1-ol. Cu 11: Gi tr ca m l:A. 8,24. B. 8,42. C. 9,18. D. 9,81. Cu 12: Tn gi ca X l A. n-propyl axetat. B. n-butyl fomiat. C. iso-propyl axetat. D. iso-butyl axetat. Cu 13: Thu phn hon ton 0,1 mol este E (ch cha 1 loi nhm chc) cn va 100gam dung dch NaOH 12%, thu c 20,4gam mui ca mt axit hu c v 9,2gam mt ru. Bit 1 trong 2 cht (ru hoc axit) to E l n chc. Cng thc ca E l A. (C2H3COO)3C3H5. B. (HCOO)3C3H5. C. C3H5(COOC2H5)3. D. C3H5(COOCH3)3. Dng cho cu 14, 15, 16: un nng a gam mt hp cht hu c X mch thng (cha C, H, O) vi dung dch cha 11,2g KOH n khi phn ng hon ton thu c dung dch B. trung ho KOH d trong B cn 80 ml dung dch HCl 0,5 M v thu c 7,36g hn hp 2 ru n chc v 18,34g hn hp 2 mui. Cu 14: Cng thc ca 2 ru to X l
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A. C2H5OH v C3H5OH.B. C3H5OH v CH3OH. C. CH3OH v C3H7OH. D. C3H7OH v C2H5OH. Cu 15: Cng thc ca axit to X l A. HOOC-COOH. B. HOOC-[CH2]4-COOH. C. HOOC-CH=CH-COOH. D. HOOC-CH2CH=CH-CH2-COOH. Cu 16: Gi tr ca a lA. 11,52. B. 14,50. C. 13,76. D. 12,82. Dng cho cu 17, 18, 19, 20: un nng 0,1 mol este no, n chc E vi dung dch cha 0,18 mol MOH (M l kim loi kim). C cn dung dch sau phn ng, thu c m gam cht rn A v 4,6 g ru B. t chy A thu c 9,54 g M2CO3 v 4,84 gam CO2 v a gam H2O. Cu 17: Kim loi kim M lA. Li. B. Na. C. K. D. Rb. Cu 18: Tn gi ca E lA. etyl axetat. B. etyl fomiat. C. metyl axetat. D. metyl fomiat. Cu 19: Gi tr ca m lA. 14,1. B. 22,3. C. 11,4. D. 23,2. Cu 20: Gi tr ca a lA. 3,42. B. 2,70. C. 3,60. D. 1,44. Dng cho cu 21, 22: un nng 7,2 gam A (l este ca glixerin) vi dung dch NaOH d, phn ng kt thc thu c 7,9 gam hn hp mui ca 3 axit hu c no, n chc mch h D, E, F; trong E, F l ng phn ca nhau, E l ng ng k tip ca D. Cu 21: A c s lng ng phn lA. 2. B. 3. C. 4. D. 5. Cu 22: Tn gi ca axit c khi lng phn t nh nht to A l A. axit fomic. B. axit axetic. C. axit propionic. D. axit butyric. Dng cho cu 23, 24, 25: Cho 0,1 mol mt este X tc dng va vi 100ml dung dch NaOH 2M thu c hn hp 2 mui ca 2 axit hu c mch h Y, Z u n chc v 6,2 gam mt ru T. Axit Y no, khng tham gian phn ng trng gng. Axit Z khng no, ch cha mt lin kt i (C=C), c mch cacbon phn nhnh. t chy ht hn hp hai mui thu c trn to ra H2O, m gam Na2CO3, v 0,5 mol CO2. Cu 23: Tn gi ca T l A. etan-1,2-iol. B. propan-1,2-iol. C. glixerol. D. propan-1-ol. Cu 24: Gi tr ca m lA. 21,2. B. 5,3. C. 10,6. D. 15,9. Cu 25: Tn gi ca Y lA. axit propionic. B. axit axetic. C. axit butyric. D. axit iso butyric. Cu 26 (B-07): X l mt este no n chc, c t khi hi so vi CH4 l 5,5. Nu em un 2,2 gam X vi dung dch NaOH d th thu c 2,05g mui. Cng thc cu to thu gn ca X l A. CH3COOC2H5. B. HCOOCH2CH2CH3. C. C2H5COOCH3. D. HCOOCH(CH3)3. Cu 27 (B-07): Thu phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm X v Y. t X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic. Dng cho cu 28, 29: X l este ca - aminoaxit (c mch thng cha 1 nhm amino v 2 nhm cacboxyl). Thu phn hon ton mt lng X trong 100ml dung dch NaOH 1M ri c cn, thu c 1,84 gam mt ru Y v 6,22 gam cht rn khan Z. un nng Y vi H2SO4 c 1700C (h = 75%), thu c 0,672 lt olefin (ktc). Cu 28: Danh php IUPAC ca Y lA. etanol. B. propan-1-ol. C. propan-2ol. D. butan-1-ol. Cu 29: Tn gi ca X l A. i(n-propyl) aminosucxinat. B. i(n-propyl) glutamat. C. ietyl glutamat. D. ietyl aminosucxinat

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