PHENOL PRODUCTION C 3 nh sn xut ln trong lnh vc sn xut phenol t Oxi ha cumen bao gm: Sunoco/UOP, KBR v GE/Lummus. 3.

1 Oxi ha cumen thnh phenol Phng php sn xut ca Sunoco/UOP sn xut phenol v aceton tinh khit cao bng cumen ha s dng oxi t khng kh. Qu trnh c tin hnh di p sut thp tng hiu sut v an ton. Cumen hidro peroxit tch ra cho sn phm c tnh chn lc, mt tin trnh trung ha sn phm trc tip mi gim thiu hao ph sn phm v gi thnh thp. Kt qu l t c t l rt nh khi lng ca cumen so vi phenol m khng c tun hon (ti ch) axeton v khng c sn phm cracking nha. Tin trnh cng to ra sn phm cht lng cao vi chi ph thp. Th h sn xut Phenol th 4 ca KBR cng cng b nhng ci tin trong oxi ha cumen da vo cng ngh oxi ha p sut cao, bao gm c ci thin hiu sut oxi ha v h thng tch tin tin, loi tr sn phm nha cracking, v h thng qun l nng lng hiu qu. Cui cng l GE/Lummus cng tuyn b nhiu ci tin trong cng ngh oxi ha cumen. Cng ging nh KBR, da trn oxi ha p sut cao, ci thin trong tc phn ng v h tch tin tin s dng xc tc hn hp, loi tr sn phm nha cracking 4.3. B phn phn ly dng Khu vc phn hy hay tch ca qu trnh bao gm phn hy xc tc ca Cumen hidro peroxit s dng lng rt nh axit thnh phenol th v axeton. Cng ngh hiu qu nht l phng php 2 bc c bit, c gii thiu trong US Patent 435618 ca Sifniades v Allied nm 1982. Tin trnh bao gm s dng thit b khuy lin tc nhit thp v thi gian din ra lu hn cho bc phn hy

CHP chnh. Sau l thit b hidrat ha t nhit cao v thi gian ngn cho chuyn ha Dicumylperoxide (DCP) thnh -Metyl Stiren (AMS). S :

S gm thit b phn ng n gin hnh tr, l ni ngng t (c c) CHP t khu vc ngng t (c c) chy vo thng quay (thng trn), cng vi lng nc thm vo duy tr iu kin phn ng trong thit b phn ly. Axit sulfuric c bm vo thng qua bm vo trong thng lm xc tc cho s phn hy CHP thnh phenol v axeton. Mt chu trnh bm c a vo tun hon cc content ca thit b phn hy. Axit sulfuric c a vo chu trnh nh sn phm phn hy ca CHP v dehidrat ha cu Dimetylphenylcarbinol (DMPC). Dieeu quan trng trong phn ng oxi ha ny l s kim sot cht ch. Lng CHP cha phn ng c gim st qua nhit lng k, ti phn m xc tc axit chy qua c phn ng. Dng chy t thit b phn hy c bm vo thit b de hydrat ha, y dng ny c ung nong ti nhit m ch cn lai DMPC b hydrat ha v DCP chuyn thnh AMS hiu sut cao.

PP ny cho hiu sut cao mc d cumen tiu th t hn v t b (VD nha..) to thnh. 4.4. Khu vc trung ha Xc tc axit c thm vo trong qu trnh phn hy phi c trung ha trnh gim hiu sut do nhng phn ng ph v trnh s n mn trong thit b chng ct phn on. Qu trnh Sunoco/UPO s dng cch tip cn mi l cho qu trnh trugn ha. Xc tc axit c trung ha bi 1 lng Diamin m khng cn phi loi i khi qu trnh theo hnh sau y:

Mui ddiamin ha tan c qua b trng ct v ri thit b theo dng b. Mui diamin khng hnh thnh SO2 hay NO2 nn b c s dng lm nhin liu un. Thun li chnh ca trung ha trc tip bng Diamin trong ton b h thng l: - (1) thit k mi v c n gin nn d vn hnh v gim chi ph u t

- (2) qu trnh s dng mui ha tan nn gim c thit b un si li v duy tr chi ph thp - (3) Khng cn thm nc trung ha do gim t i lng nc thi v gim cc thit b chng ct. 4.5. Lm sch aceton Axeton l mt trong s nhng sn phm chnh ca qu trnh oxi ha cumen sn xut phenol. Vic chng ct phn on i t bnh chng ct phn on ti ct axeton th. Nc c thm vo t y ct axeton th tng bay hi ca aceton, nc v mt t cumen chy n ct axeton thu c (finished acetone column-FAC). Nhng cht cn loi b trong FAC l cc aldehit, c phn tch theo phng php Permanganat fading, v nc?. Gn y cht lng aceton i hi cao, hu ht nh sn xut phenol s dng Gas Chromatography (GC) l phng php xc nh aldehit.

Cht n da c thm vo FAC lm xc tc ngng t cc vt aldehit. Sn phm ngng t nng hn, t bay hi hn v i ra y ct FAC. Axeton tinh khit cao chy ra nh trng lc t FAC side cut gn nh ct v tr thnh sn phm aceton, Dng hi di FAC chy n y FAC y phn chia ra cumen v nc. Nc i ra cng thot cn cumen c ti ch tr li qu trnh oxi ha. 4.6. Chng ct phn on phenol v tinh ch Khi thu c phenol th, phi tinh ch. S sau ca Sunoco/UOP dng AMS hidro ha l cch tun hon li ng sn phm AMS tng sn phm phenol.

Nguyn liu y t ct aceton th chy n cumen/ ct AMS, y cumen v AMS c ti to pha trn v c chuyn i ra cht n da. Mt lng ha cht c thm vo na y ct loi b Carbonly nh aceton v mestyl oxi t phenol. Dng t thit b phn ng chy vo ct phenol th, cc thnh phn nng chng ct y v ri chy vo ct b.

Ct phenol th c vng thanh trng pha trn loi b lng sn phm nh, nh ng sinh ra trong qu trnh chng ct. Sn phm chnh t ct c ly ra t bn cnh v chy vao IX x l nha, y ion trao i xc tc nha gia Metylbenzofuran (MBF) v AMS cn li n thit b bc hi cao. MBF v AMS kh loi b bng chng ct. Dng t nha x l IX n my ct li, thnh phn nng hn cng vi 1 t phenol c ct ra y v tun hon li ct phenol th. Thit b ct li cng c vng thanh trng nh

 loi b sn phm nh ng sinh ra trong qu trnh chng ct. Sn phm phenol chy t thit b ct li qua cnh bn vo lu tr nh trng lc.