BI TP V pH Bi 11: H Y Thi Bnh 1999 a.

Tnh pH ca cc dung dch sau Dung dch NaCl 0,1M ; dung dch H2SO4 0,005M ; dung dch Ba(OH)2 0,05M b. Tnh pH ca dung dch NaOH, bit 1 lt dung dch c cha 4 gam NaOH c. Ho tan 0,56 lt kh HCl (ktc) vo H2O thu c 250 ml dung dch. Tnh pH ca dung dch thu c? d. ho tan m gam Ba vo nc thu c 1,5 lt dung dch X c pH = 13. Tnh m ? Bi 2: Cho 1,44 gam Mg vo 5 lt dung dch axit HCl c pH =2 a. Mg c tan ht trong dung dch axit hay khng ? b. Tnh tht tch kh H2 bay ra (ktc)? c. tnh nng mol/ lt ca dung dch sau phn ng (coi Vdd khng i)? Bi 3: a. (C Cng ng Tin Giang 2005). Trn 1 lt dung dch H2SO4 0,15M vi 2 lt dung dch KOH 0,165M thu c dung dch E. Tnh pH ca dung dch E? b.Trn 50 ml dung dch HCl 0,12M vi 50 ml dung dch NaOH 0,1M. Tnh pH ca dung dch thu c ? Bi 4: Cho dung dch A gm HCl v H2SO4. Trung ho 2 lt dd A cn 400ml dung dch NaOH 0,5M . C cn dung dch to thnh th thu c 12,95 gam mui khan. a. Tnh nng mol/lt ca cc axit trong dung dch A? b. Tnh pH ca dung dch A? Bi 5: H Y H Ni 1999: in li ca axit axetic (CH 3COOH ) trong dung dch CH3COOH 0,1M l 1%. Tnh pH ca dung dch axit ny Bi 6: thi H khi B 2002 Cho hai dung dch H2SO4 c pH = 1 v pH = 2. thm 100 ml dung dch KOH 0,1M vo 100 ml mi dung dch trn. Tnh nng mol / lt ca dung dch thu c? Bi 7 : H Y Dc TP HCM 2000 Tnh in li ca axit focmic HCOOH. Nu dung dch HCOOH 0,46% (d = 1g/ml) ca axit c pH = 3 Bi 8: H S Phm H Ni 1 2000 Tnh in li ca axit focmic HCOOH trong dung dch HCOOH 0,007M c pH = 3 Bi 9: Cho dung dch CH3COOH c pH = 4, bit in li = 1%. Xc nh nng mol /lt ca dung dch axit ny Bi 10: a. Cho dung dch HCl c pH = 3. Cn pha long dung dch axit ny (bng nc) bao nhiu ln thu c dung dch HCl c pH = 4. b. ( H S Phm TP HCM 2000) Cho dung dch HCl c pH = 4. Hi phi thm mt lng nc gp bao nhiu ln th tch dung dch ban u thu c dung dch HCl c pH = 5. Bi 11: 8, H Dc 1998, Cho dung dch NaOH c pH = 12 (dung dch A). Cn pha long bao nhiu ln thu c dung dch NaOH c pH = 11. Bi 12: H Kinh T Quc Dn 1999. Pha long 10 ml dung dch HCl vi nc thnh 250 ml dung dch. Dung dch thu c c pH = 3. hy tnh nng ca HCl trc khi pha long v pH ca dung dch . Bi 13: H Thng Mi 2000. Pha long 200 ml dung dch Ba(OH) 2 vi 1,3 lt H2O thu c dung dch c pH = 12. Tnh nng mol/l ca dung dch Ba(OH)2 ban u, bit rng Ba(OH)2 phn li hon ton Bi 14: H Thu li 1997. Dung dch Ba(OH)2 c pH = 13 (dd A), dung dch HCl c pH = 1 (dd B). em trn 2,75 lt dung dch A vi 2,25 lt dung dch B a. xc nh nng mol/l ca cc cht trong dung dch to thnh? b. tnh pH ca dung dch ny Bi 15: H Quc Gia H Ni 2000 a. (Ban B). Trn 250 ml dung dch hn hp gm HCl 0,08 M v H2SO4 0,01M vi 250 ml dung dch NaOH amol/lt thu c 500ml dung dch c pH = 12. Tnh a b. (CPB). Trn 300 ml dung dch HCl 0,05 M vi 200 ml dung dch Ba(OH) 2 amol/lt thu c 500ml dung dch c pH = 12Tnh a

c. (Ban A, thi H khi B 2003). Trn 250 ml dung dch hn hp gm HCl 0,08 M v H 2SO4 0,01M vi 250 ml dung dch Ba(OH)2 amol/lt thu c m gam kt ta v 500ml dung dch c pH = 12 Tnh m v a Bi 16: Hc Vin Qun Y 2001 A l dung dch H2SO4 0,5M. B l dung dch NaOH 0,6M. Cn trn VA v VB theo t l no c dung dch c pH = 1 v dung dch c pH = 13 (gi thit cc cht phn ly hon ton ). Bi 17: H S Phm H Ni I 2001 Tnh th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch gm HNO3 v HCl c pH = 1 pH ca dung dch thu c bng 2. Bi 18: H kinh t TP HCM 2001 Trn 3 dung dch H2SO4 0,1M; HNO3 0,2 M; HCl 0,3M vi nhng th tich bng nhau c dung dch A. Ly 300 ml dung dch A cho tc dng vi mt dung dch B gm NaOH 0,2M v KOH 0,29M. Tnh th tch dung dch B cn dng sau khi tc dng vi 300ml dung dch A c dung dch c pH = 2. Bi 19: C 2004: Ho tan m gam BaO vo nc c 200ml dung dch A c pH = 13. Tnh m (gam). Bi 20 ; C SP Qung Ninh 2005 Cho m gam Ba vo 500 ml dung dch Ba(OH)2 0,04M th c mt dung dch c pH = 13 . tnh m ( Coi th tch dung dch khng i ) Bi 21: thi H Khi A 2006 Nung 6,58 gam Cu(NO3)2 trong bnh kn, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton hn hp X vo nc, c 300 ml dung dch Y. vit phng trnh phn ng xy ra v tnh pH ca dung dch Y. Bi 22: thi H khi A 2004 Cho 40 ml dung dch HCl 0,75M vo 160 ml dung dch cha ng thi Ba(OH) 2 0,08M v KOH 0,04M. Tnh pH ca dung dch thu c. Cho [H+]. [OH-] = 10-14. Bi 23: C SP H Ni 2005 Cho dung dch NaOH c pH = 13 (dung dch A). a. Cn pha long dung dch A bao nhiu ln thu c dung dch B c pH = 12? b. Cho 2,14 gam NH4Cl vo mt cc cha300 ml dung dch B. un si sau ngui ri thm mt t qu tm vo cc. Qu tm c mu g? ti sao? Bi 24: thi H khi B 2008 Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H+][OH-] = 10-14) A. 0,15. B. 0,30. C. 0,03. D. 0,12.

BI TP HIROXIT LNG TNH 1) Mt cc thu tinh cha 200ml dung dch AlCl3 0,2M. Cho t t vo cc V ml dung dch NaOH 0,5M. Tnh khi lng kt ta nh nht khi V bin thin trong on 200ml V 280ml. A. 1,56g B. 3,12g C. 2,6g D. 0,0g 2) Ho tan hon ton 8,2 gam hn hp Na2O, Al2O3 vo nc thu c dung dch A ch cha mt cht tan duy nht. Tnh th tch CO2 (ktc) cn phn ng ht vi dung dch A. A. 1,12 lt B. 2,24 lt C. 4,48 lt D. 3,36 lt 3) Thm 150ml dung dch NaOH 2M vo mt cc ng 100ml dung dch AlCl3 nng x mol/l, sau khi phn ng hon ton thy trong cc c 0,1 mol cht kt ta. Thm tip 100ml dung dch NaOH 2M vo cc, sau khi phn ng hon ton thy trong cc c 0,14 mol cht kt ta. Tnh x. A. 1,6M B. 1,0M C. 0,8M D. 2,0M 4) Cho m gam hn hp B gm CuO, Na2O, Al2O3 ho tan ht vo nc thu c 400ml dung dch D ch cha mt cht tan duy nht c nng 0,5M v cht rn G ch gm mt cht. Lc tch G, cho lung kh H 2 d qua G nung nng thu c cht rn F. Ho tan ht F trong dung dch HNO 3 thu c 0,448 lt (ktc) hn hp kh gm NO2 v NO c t khi so vi oxi bng 1,0625. Bit cc phn ng xy ra hon ton. Tnh m. A. 34,8g B. 18g C. 18,4g D. 26g 5) Cho 200 ml dung dch AlCl3 1M tc dng vi dung dch NaOH 0,5M thu c mt kt ta keo, em sy kh cn c 7,8 gam. Th tch dung dch NaOH 0,5M ln nht dng l bao nhiu? A. 0,6 lt B. 1,9 lt C. 1,4 lt D. 0,8 lt 6) Thm NaOH vo dung dch cha 0,01 mol HCl v 0,01 mol AlCl 3. Lng kt ta thu c ln nht v nh nht ng vi s mol NaOH ln lt l: A. 0,04 mol v 0,05 mol B. 0,03 mol v 0,04 mol C. 0,01 mol v 0,02 mol D. 0,02 mol v 0,03 mol 7) Ho tan 0,54 gam Al trong 0,5 lt dung dch H2SO4 0,1M c dung dch A. Thm V lt dung dch NaOH 0,1M cho n khi kt ta tan tr li mt phn. Nung kt ta n khi lng khng i ta c cht rn nng 0,51 gam. Gi tr ca V l? A. 1,2 lt B. 1,1 lt C. 1,5 lt D. 0,8 lt 8) Cho m gam Kali vo 250ml dung dch A cha AlCl3 nng x mol/l, sau khi phn ng kt thc thu c 5,6 lt kh (ktc) v mt lng kt ta. Tch kt ta, nung n khi lng khng i thu c 5,1 gam cht rn. Tnh x. A. 0,15M B. 0,12M C. 0,55M D. 0,6M 9) Cho dung dch cha 0,015 mol FeCl2 v 0,02 mol ZnCl2 tc dng vi V ml dung dch NaOH 1M, sau khi phn ng xy ra hon ton tch ly kt ta nung trong khng kh n khi lng khng i c 1,605 gam cht rn. Gi tr ln nht ca V thu c lng cht rn trn l: A. 70m B. 100ml C. l40ml D. 115ml 10) Ho tan hon ton m gam hn hp Na2O, Al2O3 vo nc c dung dch trong sut A. Thm dn dn dung dch HCl 1M vo dung dch A nhn thy khi bt u thy xut hin kt ta th th tch dung dch HCl 1M cho vo l 100ml cn khi cho vo 200ml hoc 600ml dung dch HCl 1M th u thu c a gam kt ta. Tnh a v m. A. a=7,8g; m=19,5g B. a=15,6g; m=19,5g C. a=7,8g; m=39g D. a=15,6g; m=27,7g 11) Cho 200ml dung dch KOH vo 200ml dung dch AlCl 3 1M thu c 7,8 gam kt ta. Nng mol ca dung dch KOH dng l: A. 1,5M hoc 3,5M B. 3M C. 1,5M D. 1,5M hoc 3M 12) Cho m gam Na vo 50ml dung dch AlCl31M, sau khi phn ng xy ra hon ton thu c 1,56 gam kt ta v dung dch X. Thi kh CO2 vo dung dch X thy xut hin kt ta. Tnh m. A. 1,44g B. 4,41g C. 2,07g D. 4,14g 13) Thm 240ml dung dch NaOH 1M vo mt cc thu tinh ng 100ml dung dch AlCl 3 nng x mol/l, khuy u n phn ng hon ton thy trong cc c 0,08 mol cht kt ta. Thm tip 100ml dung dch NaOH 1M vo cc, khuy u n phn ng hon ton thy trong cc c 0,06 mol cht kt ta. Tnh x. A. 0,75M B. 1M C. 0,5M D. 0,8M

14) Trong mt cc thu tinh ng dung dch ZnSO4. Thm vo cc 200ml dung dch KOH nng x mol/l th thu c 4,95 gam kt ta. Tch kt ta, nh dung dch HCl vo nc lc th thy xut hin kt ta tr li, tip tc cho HCl vo n khi kt ta tan ht ri cho dung dch BaCl2 d vo th thu c 46,6 gam kt ta. Tnh x. A. 2M B. 0,5M C. 4M D. 3,5M 15) Cho m gam Na vo 200 gam dung dch Al2(SO4)3 1,71%, sau khi phn ng hon ton thu c 0,78 gam kt ta. Tnh m. A. 1,61g B. 1,38g hoc 1,61g C. 0,69g hoc 1,61g D. 1,38g 16) Dung dch A cha m gam KOH v 40,2 gam K[Al(OH)4]. Cho 500 ml dung dch HCl 2M vo dung dch A thu c 15,6 gam kt ta. Gi tr ca m l? A. 22,4g hoc 44,8g B. 12,6g C. 8g hoc22,4g D. 44,8g 17) Cho 3,42 gam Al2(SO4)3 tc dng vi 200 ml dung dch NaOH, sau phn ng thu c 0,78 gam kt ta. Nng mol/l nh nht ca dung dch NaOH dng l? A. 0,15M B. 0,12M C. 0,28M D. 0,19M 18) Cho V lt dung dch NaOH vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n phn ng xy ra hon ton thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l: A. 0,9 B. 0,45 C. 0,25 D. 0,6 19) Cho 120 ml dung dch AlCl3 1M tc dng vi 200 ml dung dch NaOH thu c 7,8 gam kt ta. Nng mol/l ln nht ca NaOH l? A. 1,7M B. 1,9M C. 1,4M D. 1,5M 20) Mt cc thu tinh cha 200ml dung dch AlCl3 0,2M. Cho t t vo cc V ml dung dch NaOH 0,5M. Tnh khi lng kt ta ln nht khi V bin thin trong on 250ml V 320ml. A. 3,12g B. 3,72g C. 2,73g D. 8,51g 21) Ho tan hon ton 19,5 gam hn hp Na2O, Al2O3 vo nc c 500ml dung dch trong sut A. Thm dn dn dung dch HCl 1M vo dung dch A n khi bt u thy xut hin kt ta th dng li nhn thy th tch dung dch HCl 1M cho vo l 100ml. Tnh nng mol ca cc cht tan trong dung dch A. A. [Na[Al(OH)4]]=0,2M; [NaOH]=0,4M B. [Na[Al(OH)4]]=0,2M; [NaOH]=0,2M C. [Na[Al(OH)4]]=0,4M; [NaOH]=0,2M D. [Na[Al(OH)4]]=0,2M 22) Cn t nht bao nhiu ml dung dch HCl 1M cn cho vo 500 ml dung dch Na[Al(OH) 4]0,1M thu c 0,78 gam kt ta? A. 10 B. 100 C. 15 D. 170 23) Cho V lt dung dch NaOH 0,4M vo dung dch c cha 58,14 gam Al 2(SO4)3 thu c 23,4 gam kt ta. Gi tr ln nht ca V l? A. 2,68 lt B. 6,25 lt C. 2,65 lt D. 2,25 lt 24) Rt V ml dung dch NaOH 2M vo cc ng 300 ml dung dch Al2(SO4)3 0,25M thu c mt kt ta. Lc kt ta ri nung n khi lng khng i c 5,1 gam cht rn. V c gi tr ln nht l? A. 150 B. 100 C. 250 D. 200 25) Cho 100 ml dung dch Al2(SO4)30,1M. S ml dung dch NaOH 0,1M ln nht cn thm vo dung dch trn cht rn c c sau khi nung kt ta c khi lng 0,51 gam l bao nhiu? A. 500 B. 800 C. 300 D. 700 26) Cho dung dch NaOH 0,3M vo 200 ml dung dch Al 2(SO4)3 0,2M thu c mt kt ta trng keo. Nung kt ta ny n khi lng khng c 1,02 gam cht rn. Th tch dung dch NaOH ln nht dng l? A. 2 lt B. 0,2 lt C. 1 lt D. 0,4 lt 27) Ho tan m gam ZnSO4 vo nc c dung dch B. Tin hnh 2 Th nghim sau: TN1: Cho dung dch B tc dng vi 110ml dung dch KOH 2M thu c 3a gam kt ta. TN2: Cho dung dch B tc dng vi 140ml dung dch KOH 2M thu c 2a gam kt ta.Tnh m. A. 14,49g B. 16,1g C. 4,83g D. 80,5g 28) Thm dung dch HCl vo dung dch hn hp gm 0,1 mol NaOH v 0,1 mol Na[Al(OH)4] thu c 0,08 mol cht kt ta. S mol HCl thm vo l: A. 0,16 mol B. 0,18 hoc 0,26 mol C. 0,08 hoc 0,16 mol D. 0,26 mol 29) Cho 250ml dung dch NaOH 2M vo 250ml dung dch AlCl3 nng x mol/l, sau khi phn ng hon ton thu c 7,8 gam kt ta. Tnh x. A. 1,2M B. 0,3M C. 0,6M D. 1,8M 30) Trong 1 cc ng 200 ml dung dch AlCl3 0,2M. Rt vo cc 100 ml dung dch NaOH, thu c mt kt ta, em sy kh v nung n khi lng khng i thu c 1,53 gam cht rn. Nng mol/l ca dung dch NaOH dng l? A. 0,9M B. 0,9M hoc 1,3M C. 0,5M hoc 0,9M D. 1,3M

31) Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch Ba(OH)2 0,25M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l? A. 2,4 lt B. 1,2 lt C. 2 lt D. 1,8 lt 32) Thm dn dn Vml dung dch Ba(OH)2 vo 150ml dung dch gm MgSO4 0,1M v Al2(SO4)3 0,15M th thu c lng kt ta ln nht. Tch kt ta, nung n khi lng khng i thu c m gam cht rn. Tnh m. A. 22,11g B. 5,19g C. 2,89g D. 24,41g 33) Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Thm t t dung dch X vo 200ml dung dch Al 2(SO4)3 0,1M thu c kt ta Y. thu c lng Y ln nht th gi tr ca m l: A. 1,71g B. 1,59g C. 1,95g D. 1,17g 34) Hn hp A gm Al v Al2O3 c t l khi lng tng ng l 1,8:10,2. Cho A tan ht trong dung dch NaOH va thu c dung dch B v 0,672 lt kh (ktc). Cho B tc dng vi 200ml dung dch HCl thu c kt ta D, nung D nhit cao n khi lng khng i thu c 3,57 gam cht rn. Tnh nng mol ln nht ca dung dch HCl dng. A. 0,75M B. 0,35M C. 0,55M D. 0,25M 35) Cho V lt dung dch NaOH 0,1M vo cc cha 200 ml dung dch ZnCl 2 0,1M thu c 1,485 gam kt ta. Gi tr ln nht ca V l? A. 1 lt B. 0,5 lt C. 0,3 lt D. 0,7 lt 36) Cho p mol Na[Al(OH)4] tc dng vi dung dch cha q mol HCl. thu c kt ta th cn c t l : A. p: q < 1: 4 B. p: q = 1: 5 C. p: q > 1:4 D. p: q = 1: 4 37) Cho dung dch A cha 0,05 mol Na[Al(OH)4] v 0,1 mol NaOH tc dng vi dung dch HCl 2M. Th tch dung dch HCl 2M ln nht cn cho vo dung dch A xut hin 1,56 gam kt ta l? A. 0,06 lt B. 0,18 lt C. 0,12 lt D. 0,08 lt 38) Khi cho V ml hay 3V ml dung dch NaOH 2M tc dng vi 400ml dung dch AlCl3 nng x mol/l ta u cng thu c mt lng cht kt ta c khi lng l 7,8 gam. Tnh x. A. 0,75M B. 0,625M C. 0,25M D. 0,75M hoc 0,25M 39) Ho tan hon ton m gam hn hp K 2O, Al2O3 vo nc c dung dch A ch cha mt cht tan duy nht. Cho t t 275ml dung dch HCl 2M vo dung dch A thy to ra 11,7 gam kt ta. Tnh m A. 29,4 gam B. 49 gam C. 14,7 gam D. 24,5 gam 40) Cho 200 ml dung dch NaOH tc dng vi 500 ml dung dch AlCl 3 0,2M thu c mt kt ta trng keo, em nung kt ta trong khng kh n khi lng khng i th c 1,02 gam cht rn. Nng mol/l ln nht ca dung dch NaOH dng l? A. 1,9M B. 0,15M C. 0,3M D. 0,2M