THI HA VO C HC SINH GII TNH AN GIANG NGAY 1

Trng hc Lp hc Nm hc Mn thi Thi gian Thang im Hc sinh gii tnh An Giang 12 2006 Ha hc 180 pht 10

Cu 1: (5). 1. Hp cht A c to thnh t cation X+ v anion Y-. Phn t A cha 9 nguyn t thuc, gm 3 nguyn t phi kim, t l s nguyn t ca mi nguyn t l 2:3:4. Tng s prton trong A l 42 v trong anion Y- cha hai nguyn t cng chu k v thuc 2 phn nhm chnh lin tip . a/ Vit cng thc phn t v gi tn A b/ Vit cng thc electron v cng thc cu to ca A 2. Mt dung dch c cha ion Ca2+ v Ba2+ cng nng 0.01 M. Thm axit c pH = 4.0. pH ny nu ta thm dung dch K2Cr04 vi nng l 0.1 M c kt ta xut hin khng ? Kt lun cho pT CaCr04 = 0.2; pT BaCrO4 = 9.9 H2CrO4 c pK1 = 1.0 v pK2 = 6.5 Cu 2: (5) 1. Tnh pH v in li ca dung dch NaCN 0.1 M (dd A) cho pKa HCN = 9.35 2. n li thay i th no khi : a. C mt NaOH 0.005M b. C mt HCl 0.002 M c. C mt NaHS04 0.01 M bit pk HS04- = 2 Cu 3: (5) 1. Mt dung dch c cha 4 ion ca 2 mui v c trong c ion S042- khi tc dng v vi dd BA(OH)2 un nng cho kh X, kt ta Y v dung dch Z. dd Z sau khi axit ha tan bng HNO3 to vi AgNO3 kt ta trng ha en ngoi nh sng. Kt ta Y em nung c a g cht rn T. Ga tr ca A thay i ty theo lng Ba(OH)2 em dng: nu va ,a cc i, nu ly d a gim n cc tiu. Khi ly cht rn T vi gi tr cc i a=7.204 gam thy T ch phn ng ht vi 60 ml dd HCl 1.2 M, cn li 5.98 gam cht rn. Hy lp lun xc nh cc ion c trong dung dch. 2. Trnh by phng php phn bit 3 dung dch sau b mt nhn: dung dch NaHS04 0.1 M (dd A), dung dch H2S04 0.1 M (dd B) v dung dich hn hp H2S04 0.1 M v HCl 0.1 M (dd C). Ch c dng qu tm v dung dch NaOH 0.1 M. Tnh s mol cc cht trong cc dung dch. Cu 4: (5) Mt hn hp gm km v st. Thc hin 2 th nghim sau : TN1: Ly 3.07 gam hn hp cho vo 200 ml dung dch HCl, phn ng xong, c cn thu c 5.91 gam cht rn. TN2: Ly 3.07 gam hn hp cho vo 300 ml dung dc HCl ( dung dich HCl nh trn ), phn ng xong, c cn thu c 6.62 gam cht rn. 1) Tnh th tch kh H2 sinh ra TN1 (ktc) v nng mol dd HCl 2) Tnh % theo khi lng hn hp 2 kim loi.

THI HA HU C HC SINH GII TNH AN GIANG NGAY 2

Trng hc Lp hc Hc sinh gii tnh An Giang 12

Nm hc Mn thi Thi gian Thang im

2006 Ha hc 180 pht 10

Cu 1: (5) 1. Vit cc phng trnh phn ng km theo iu kin thc hin s chuyn ha sau, cht hu c vit di dng cng thc ct to thu gn. - C2H2 -> A -> C2H5OH -> C2H4O -> C2H3O2NH4 - C2H2 -> B -> C2H4O2 -> C2H5OOCCH3 -> C -> CH4 - C2H2 -> C2H3Cl -> B -> D -> CH2=CHOC2H5 - C2H2 -> C2H4Cl -> B -> C2H4O2 -> CH2=CHOOCCH3 -> PVA 2. Cc cht A, B, C c cng CTPT C4H9O2N. Bit A tc dng vi c HCl v Na2O. B tc dng vi hidro mi sinh to ra B' ; B' tc dng vi HCl to ra B ; B tc dg NaOH to li B ; C tc dung vi NaOH to ra mui v NH3. Cho bit A, B, C ng vi ng phn chc no ? Vit cc phng trnh phn ng dng . Cu 2: (5) 1. C 3 hp cht hu c A, B , C ln lt c CTPT l CH4O , CH2O, CH2O2. a. Vit CTCT v gi tn chng theo danh php IUPAC v thng thng. b. Vit cc PTP thc hin chuyn ha sau: (1) A -> B (2) B -> A (3) B -> C (4) A -> C c. Mt dung dich ha tan 3 cht trn. Bng nhng th nghim no chng minh s c mt ca chng. Vit cc phng trnh phn ng. 2. So snh v gii thch mnh cc axit sau : phenol, o-nitrophenol, m-nitrophenol, p-nitrophenol. 3. So snh v gii thch mnh baz ca cc dung dch cng nng : NaOH, CH3COONa, C2H5ONa , C6H5ONa Cu 3: (5). t 11,7 gam cht hu c A th thu c 9.9 g H2O, 22g CO2, 1.4 g N2. Xc nh CTPT A bit MA < 120 g/mol t 7.1 g B cn 8.4 l oxi (ktc) th thu c 4.5 g nc v hn hp kh C02 v N2 c d/H2 = 20.857 Cht C c cng thc n gin C2H60. Bit rng khi nhit phn A ta c B v C vi t l nA :nB = 2 : 1 a. Xc inh CTCT A, B, C b. T B vit cc PTP iu ch A. Cu 4: (5) Ngi ta chia 1.792 lt (ktc) hn hp kh X gm 1 ankan, 1 anken, 1 ankin lm 2 phn bng nhau: + Phn 1: Cho qua dung dc AgNO3 trong amoniac d to thnh 0.735 gam kt ta v th tch hn hp gim 12.5% + Phn 2: t chy hon ton ri hp th ton b sn phm vo 9.2 lt dung dc Ca(OH)2 0.0125 M thy c 11 gam kt ta. Xc nh CTPT ca cc hidrcacbon

THI HC SINH GII TNH NAM NH

Trng hc S GD-T Nam nh

Lp hc Nm hc Mn thi Thi gian Thang im

12 2007 Ha hc 180 pht 20

Cu 1: Hy ghi li ch ch p n ng trong cc bi sau vo bi lm: 1. Cho Na vo dung dch (dd) AlCL3 th s phn ng ha hc xy ra l: A. 2 B. 3 C. 4 D. Khng xc nh 2. Dn t t V lt hn hp kh X gm CO v H2 qua ng s dng 16,8g hn hp 3 oxit (CuO, Fe3O4, Al2O3) nung nng. Phn ng xong thu c m gam cht rn v mt hn hp kh v hi. Hn hp kh v hi ny nng hn khi lng X l 0,32g. Gi tr ca V v m l: A. 0,336 lt v 16,42 gam B. 0,448 lt v 16,42 gam C. 0,448 lt v 16,48 gam D. 0,336 lt v 16,48 gam 3. Khi lng CuSO4.5H2O v khi lng dd CuSO4 8% cn dng pha thnh 280 gam dd CuSO4 16% l: A. 80 gam v 200 gam B. 40 gam v 240 gam C. 60 gam v 220 gam D. 100 gam v 180 gam Cu 2: 1. Trn 30ml dd HCL 0,05M vi 20ml dd Ba(OH)2 aM c 50ml dd c pH = b. C cn dd sau khi trn thu c 0,19875 gam cht rn khan. Hy tnh a v b bit rng dung mi l nc v trong dd c [H+][OH-] = 1014 2. Sn xut NaOH bng cch in phn dd NaCl c mng ngn xp gia 2 in cc (in cc tr). Hy vit s , phng trnh in phn. Dung dch thu c cn ln NaCl, hy nu cch loi NaCl ra khi dd . 3. It bn trn th trng cha tp cht l Cl2, Br2, H2O. Hy trnh by cch tinh ch mt lng nh I2 . Cu 3: 1. Cht hu c X cha vng benzen c cng thc phn t (CTPT) l C9H8O2. un nng X vi dd Ba(OH)2 d thu c 1 mui A v 1 andehit B. X phn ng vi Br2 trong dd theo t l s mol 1:1. Hy bin lun xc nh cng thc cu to (CTCT) ca X v vit cc phng trnh phn ng (PTPU) xy ra. 2. Mui hu c A lm ngn la n cn chuyn thnh mu vng, khi tc dng vi dd H2SO4 c nng thch hp c cht B n chc. Cht B tc dng vi etanol to ra cht D c mi d chu v tan t trong nc. t chy D ch thu c CO2 v H2O trong th tch CO2 thu c gp i th tch CO2 thu c khi t chy cng s mol B. Hy bin lun xc nh CTCT ca A, B, D v vit cc PTPU xy ra. Cu 4: Cho m gam hn hp 2 cht hu c n chc, mch h X, Y tc dng vi dd Ba(OH)2 un nng, trung ha Ba(OH)2 d cn thm tip 100ml dd HCl 0,5M. Sau th nghim, c cn dd, thu c hn hp 2 ru hn km nhau 1 nguyn t ccbon trong phn t v c 23,525 gam hn hp 3 mui khan. Cho ton b lng ru trn vo bnh ng Na d thy thot ra 1,68 lt kh H2, khi lng trong bnh ng Na tng 5,35g. Hy tnh m v xc nh CTCT ca X v Y bit rng cc phn ng xy ra hon ton. Cu 5: Hn hp X gm MO v R2O3 c t l s mol tng ng l 2:1. Dn H2 d i qua 12,3g X, un nng, th c phn rn nng 10,7g. Nu cho 12,3g X vo dd KOH d thy c 7,2g cht rn khng tan.

Xc nh cng thc cc oxit trong X bit rng MO, R2O3 l cc oxit kim loi khng tc dng vi nc v hiu sut cc phn ng u l 100%. Cu 6: Phn ng tng hp NH3 t N2 v H2 l phn ng thun nghch, ta nhit. 1. Vit phng trnh nhit ha hc ca phn ng . 2. T khi ca hn hp N2, H2 (trc khi a vo thp tng hp) so vi kh hidro l 3,6. T khi ca hn hp kh (lc cn bng) so vi khi hidro l 3,96. Hy tnh hiu sut phn ng . Cu 7: Khi tch nc t 9,9g hn hp X gm 4 ru no, n chc, mch h (c cng s mol) bng H2SO4 c 140C (hiu sut 100%) c 8,1 gam hn hp Y gm 10 ete. 1. Tnh s mol, xc nh CTCT mi ru trong X. 2. Vit CTCT cc ete c cu to i xng v gi tn cc ete . CH : 1. Hc sinh c s dng Bng h thng tun hon cc nguyn t ha hc. 2. Th tch cc kh cc bi qui v iu kin tiu chun.

THI HA HU C HC SINH GII TNH GIA LAI Vng 2

Trng hc Lp hc Nm hc Mn thi Thi gian Thang im Hc sinh gii tnh Gia Lai 12 2006 Ha hc 150 pht 10

Cu I (4im) Cho s chuyn ha sau vi A,B,....,F l cc sn phm chnh Hnh:Http://img6.imageshack.us/img6/2975/13ar1.gif 1.Ghi cng thc cc tc nhn phn ng v cc iu kin thch hp nu c,thch hp vo du ? trn s phn ng . 2.Vit cc phng trnh phn ng theo s phn ng ( cc cht A,B,...,F vit di dng cng thc cu to .Trong cc hp cht trn, hp cht no c ng phn hnh hc .Vit cu trc khng gian ca cc ng phn . 3.Trnh by c ch ca cc phn ng 1 v 4 Cu II (3im) Hon thnh cc phn ng sau, ch ra tnh lp th ng ca sn phm . Hnh:Http://img15.imageshack.us/img15/1496/26kn.gif Cu III (5im) 1.Dng cng thc phi cnh v Niumen biu din cc sn phm cu cc phn ng dehydrobrom ha theo E2 a. (R,R)-2,3 dibrombutan b. meso-(R,S)-2,3 dibrombutan 2. Xut pht t brombenzen c cha v tr s 1 v cc cht v c cn thit khc (khng cha (khng cha )Hy vit cc phng trnh phn ng iu ch -anilin c v tr s 3 . -axit benzoic c cha v tr s 1 v axit benzoic c v tr s 3 .

Cu IV (4im) 1.Khi oxi ha etylenglycol bng HNO3 to thnh hn hp c 5 cht . Hy vit cng thc cu to ca 5 cht v sp xp theo trt t gim dn nhit si ca chng . Gii thch ? 2. Hp cht hu c A c tnh quang hot tc dng vi cho mt cht kh X . Nu un nng A vi m c nhit thch hp th cho 1 hidrocacbon B . Phn ng ozon phn B cho hp cht C v cht D Bit rng D cho phn ng trng gng cn C khng cho phn ng ny . Xc nh cng thc cu to ca A,B,C,D,X . Vit cc phng trnh phn ng sy ra . Cu V (4im) X l hp cht thm c cng thc. xc nh cng thc cu to X ngi ta thc hin cc th nghim sau . TN1 : oxi ha mnh X vi m c thu c 2 axit TN2 : X cho phn ng vi thuc th Grinha , sau thy phn trong mi trng axit thu c ancol bc 3 c mt nguyn t cacbon bt i . 1.Xc nh cng thc ca X tha mn th nghim 2.Xc nh cng thc ca X tha mn c hai th nghim trn . Vit cc phng trnh phn ng sy ra c 2 th nghim.

THI THNH LP I TUYN HC SINH GII D THI QUC GIA

Trng hc Lp hc Nm hc Mn thi Thi gian Thang im S GD-T Bnh Thun 12 2006 Ha hc 180 pht 10

Cu 2: (4 im) 1/ Sp xp theo chiu gim dn tnh axit v ghi cc hng s Ka (pKa) km theo bn cnh mi cht trong tng dy sau: a. CH3CH2CH2COOH; CH3CH2CHClCOOH; CH3CHClCH2COOH; CH2ClCH2CH2COOH.(vi Ka.10-5 khng theo th t trn l: 1,5; 3,0 ; 8,9 ; 139) b. Phenol; m-nitrophenol; p-nitrophenol; m-metylphenol; p-metylphenol. (Vi pKa khng theo th t l: 7,15; 8,4; 9,98; 10,08; 10,14) c. Axit benzoic; axit m-nitrobenzoic; axit p-hidroxibenzoic; axit p-nitrobenzoic; axit o-bitrobenzoic ( Vi pKa khng theo th t l : 4,54; 4,18; 3,49; 3,43; 2,17) 2/ T vi, than v cc cht v c cn thit khng cha cacbon, hy iu ch: p-bromnitrobenzen; 2-brom-4-nitrophenol. Cu 3: (4 im) 1/ Nu hin tng, gii thch, vit phng trnh phn ng xy ra cc th nghim sau: a. un nng dung dch KHCO3 ri ngui, dung dch thu c c mi trng axit hay baz? b. Thm ln lt cc dung dch: BaCl2, AlCl3, ZnCl2 vo dung dch thu c th nghim trn. c. Thm dung dch K2S vo ln lt cc dung dch: Ba(NO3)2, AlCl3, ZnSO4. 2/ Ha tan 1 gam NH4Cl v 1 gam Ba(OH)2.8H2O vo 80 ml nc. Pha long dung dch bng nc n 100 ml, ti 25OC. a. Tnh pH ca dung dch sau khi pha long. Bit pKa(NH4+) = 9,24. b. Tnh nng ca tt c cc ion trong dung dch.

c. Nu thm 10 ml dung dch HCl 1M vo dung dch trn th pH ca dung dch thu c l bao nhiu? Hy tnh [NH3] ca dung dch mi. Cu 4: (4 im) 1/ Cn bng ca phn ng : C + CO2 <=> 2CO xy ra 1090OC vi hng s cn bng Kp = 10. a. Tnh hm lng kh CO trong hn hp kh cn bng, bit p sut chung ca h l 1,5 atm. b. c hm lng CO bng 50% v th tch, th p sut chung l bao nhiu? 2/ Ha tan x gam mt kim loi trong 200 gam dung dch HCl 7,3% (lng axit va ) thu c dung dch A trong nng ca mui M to thnh l 11,96% (theo khi lng). a. Tnh x v xc nh kim loi M. b. B l hp cht ca M vi oxi trong M c s oxi ha l +4. Hp cht ny c kh nng oxi ha Brthnh Br2 v Cl- thnh Cl2. B ch oxi ha Br- thnh Br2 nn dng mi trng H2SO4 long hay m c? Gii thch s la chn , bit rng: M4+ + 2e = M2+ E0 = 1,23 V Br2 + 2e = 2Br- E0 = 1,07 V Cl2 + 2e = 2Cl- E0 = 1,36 V Cu 5: (4 im) Trong mt bnh kn dung tch 10 lt cha hn hp 3 andehit n chc X,Y,Z (phn t khng ch lin kt ba) v 32 gam oxi (d). un nng bnh n 136,50C cho andehit bay hi han tan, p sut trong bnh lc l 3,695 atm. Bt tia la in t chy hon tan hn hp, sau a nhit bnh v 100OC, p sut trong bnh l P (atm). Cho ton b sn phm chy ln lt i qua 2 bnh: bnh (1) ng dung dch H2SO4 c, bnh (2) ng 100 ml dug dch Ba(OH)2 1M, khi lng bnh (1) tng 2,34 gam, bnh (2) thu c 11,82 gam kt ta. un nng bnh (2) li thu thm c m gam kt ta na. 1/ Tnh m v P. 2/ Tm cng thc phn t v vit cng thc cu to ca X,Y,Z. Bit Y v Z c cng s nguyn t C, s mol X gp 4 ln tng s mol Y v Z Din n Olympia Vit Nam Ly t