Professional Documents
Culture Documents
Nguyn nh triu
Cc phng php ph
trong ho hc hu c
v ho sinh
Mc lc
Li ni u ................................................................................................................. 7
Chng 1. M u ................................................................................................... 10
1.1. Vng ph quang hc...................................................................................... 10
1.2. nh lut Lambert Beer ....................................Error! Bookmark not defined.
1.3. S khi ca ph k quang hc......................Error! Bookmark not defined.
Chng 2. Phng php ph hng ngoi v ph RamanError!
defined.3
Bookmark
not
Bookmark
not
Bookmark
not
Bookmark
not
Bookmark
not
3.2.1. Hp cht cha nhm mang mu bit lp.Error! Bookmark not defined.
3.2.2. Hp cht polien......................................Error! Bookmark not defined.
3.2.3. Hp cht polienin v poliin ....................Error! Bookmark not defined.
3.2.4. Hp cht cacbonyl , -khng no C=CC=OError!
defined.
Bookmark
not
Bookmark
not
Bookmark
4.8.1. Ph 2DJ.........................................................................................137
4.8.2. Ph COSY .............................................Error! Bookmark not defined.
4.8.3. Ph HETCOR, HMQC v HSQC. ......Error! Bookmark not defined.9
4.8.4. Ph 2DINADEQUAT. .....................................................................144
LI NI U
Ngy nay ha hc hu c ang pht trin mnh m c l thuyt v ng dng,
hng nm c hng vn cht mi c tng hp hoc tch t thin nhin ra do yu
cu tch tinh khit v xc minh cu to ca chng l rt cn thit, n i hi phi nhanh
v chnh xc. Xa kia chng minh cu to mt cht c th mt hng nm hoc c khi
ko di c chc nm th nay c th thc hin c sau vi gi, s d lm c nh vy
l nh c cc phng php vt l hin i h tr nh cc phng php sc k v cc
phng php ph. V th s hiu bit v cc phng php vt l ni chung v phng
php ph ni ring l rt cn thit cho tt c nhng ai hc tp v nghin cu ha hc
hu c v ha sinh.
Ni dung ca cun sch ny khng i su v l thuyt cc phng php ph m
tp trung vo phn ng dng cc phng php ph hng ngoi, ph t ngoi v kh
kin, ph cng hng t ht nhn 1H v 13C v ph khi lng phn tch cu trc cc
hp cht hu c, trong cun sch ny cn c a vo mt lng bi tp ng k gip
cho ngi c c th t mnh c c cc ph v gii thch cu to ca hp cht.
Cun sch ny c th dng lm ti liu hc tp v tham kho cho sinh vin, hc
vin cao hc, nghin cu sinh v cn b ngnh ha hu c v ha sinh ca cc trng
i hc v Vin nghin cu.
H Ni, ngy 30 thng 8 nm 2007
Tc gi
Chng 1
M U
phn tch cu to cc hp cht hu c c th s dng cc phng php ph
nh ph hng ngoi, ph t ngoi v kh kin, ph cng hng t ht nhn, ph khi
lng. Mi phng php cho php xc nh mt s thng tin khc nhau ca cu to
phn t, nh phng php ph hng ngoi cho php xc nh s c mt ca cc nhm
chc trong phn t nh nhm OH, NH, CH, C=C, CC, C=O, C=N, N=N..; phng
php ph t ngoi, kh kin cho php xc nh hp cht l h ni i lin hp, h
vng thm hay vng bo ho; phng php ph cng hng t ht nhn cho php
xc nh cu trc khng gian ca phn t v phng php ph khi lng cho php xc
nh chnh xc khi lng phn t, t l phn trm ca cc nguyn t C, S, Br, Clv
chng minh cu to phn t.
C s ca cc phng php ph hng ngoi, Raman, t ngoi v kh kin gi
chung l phng php quang ph l s tng tc ca nh sng vi phn t.