12 CB

Gio n Ha 12-CB GV: Phan Th Thanh Huyn THPT C - Ngh An
Ngy son 18/08/2009

Tiet 1
ON TAP AU NAM
-------------------
I- MUC CH YEU CAU
1. Kien thc
On tap nhng noi dung c ban cua thuyet CTHH.
ong phan, ac iem ve cau tao, tnh chat cua moi loai
hirocacbon la nhng phan lien quan en lp 12 e chuan b tiep
thu kien thc mi ve cac hp chat hu c co nhom chc.
Trong tam
- Ba luan iem chnh cua thuyet CTHH.
- Cac loai ong phan: mach cacbon; v tr noi oi, ba, nhom the
va nhom chc;
- ong phan nhom chc va ong phan cis-trans cua HC va dan
xuat cua chung.
- ac iem CT, tnh chat hoa hoc cua ba loai C
x
H
y
: no, khong no
va thm.
2. Ky nang
Giai mot so bai tap ap dung kien thc.
II- PHNG PHAP DAY HOC
am thoai, neu van e
III- CHUAN B
GV : S o lien quan gia cau tao cac loai HC va tnh chat.
HS: On tap kien thc Hoa hu c 11.
IV- TIEN TRNH TIET DAY
1. On nh to chc
2. Noi dung

Hoat ong cua tro Hoat ong cua thay
I-NHNG IEM C BAN CUA THUYET
CAU TAO HOA HOC
HS trnh bay
V vay, thuyet CTHH lam c s e nghien cu
cac hp chat hu c:
HS: thao luan, ly v du minh hoa
1. VD : C
2
H
6
O

CH
3
CH
2
OH

CH
3
OCH
3

Hoat ong 1
Hoi: Hay neu noi dung c ban cua
thuyet cau tao hoa hoc ?

GV: Nhan xet, bo sung

Ru etylic imetylete
2. IV IV IV VI VI
VD : CH
4
, CH
3
CH
2
OH , CHCH
CH
3
CH
2
CH
2
CH
3
, CH
3
CHCH
3
,
|
CH
3

CH
2
CH
2

| |
CH
2
CH
2

3. VD: Tnh chat phu thuoc vao:
- Ban chat: CH
4
: Kh, de chay,CCl
4
: Long ,
khong chay
-So lng nguyen t : C
4
H
10
:kh, C
5
H
12
: long
-Th t lien ket:
CH
3
CH
2
OH: Long, khong tan.
CH
3
OCH
3
: Kh, khong tan
II- ONG ANG, ONG PHAN
1. ong ang: la hien tng cac chat co cau
tao va tnh chat tng t nhau nhng ve thanh
phan phan t khac nhau mot hay nhieu nhom:
- CH
2
-.
VD: Tm cong thc chung day ong ang cua
ancol etylic?
Giai :
Ta co: C
2
H
5
OH + xCH
2
= C
2+x
H
5+2x
OH
at : n =2+x. Do o: 6 + 2x = 2n + 2.
Vay cong thc chung day ong ang ru etylic
GV: Hng dan hoc sinh lay v du
minh hoa.

GV: Cho hs thay s thay oi: ban chat,
so lng, th t ngt --- thay oi
chat.


Hoat ong 2
Hoi: Em hay nhac lai nh ngha
ong ang ? lay v du.

Hoi: Em hay nhac lai nh ngha
ong phan ? co may loai phan, lay
v du.


la: C
n
H
2n+1
OH Hay C
n
H
2n+2
O.

2. ong phan: la hien tng cac chat co cung
CTPT, nhng co cau tao khac nhau nen co tnh
chat khac nhau.
- Phan loai ong phan:
a) ong phan cau tao: (3 loai)
- ong phan mach cacbon: mach khong
nhanh, mach co nhanh.
- ong phan v tr: noi oi, ba, nhom the
va nhom chc.
- ong phan nhom chc: cac ong phan
khac nhau ve nhom chc, tc la oi
t nhom chc nay sang nhom chc
khac.
VD: Ankaien Ankin - Xicloanken
Anken Xicloankan.

b) ong phan hnh hoc : (cis trans):

VD: Buten 2

H H H C H
3

\ / \ /
C=C C=C
/ \ / \
CH
3
CH
3
CH
3
H

Cis Trans
VD: C
4
H
10
co 2 ong phan:
CH
3
CH
2
CH
2
CH
3

Butan

CH
3
CHCH
3
| iso-butan
CH
3

VD: icloetan C
2
H
4
Cl
2
co 2p:
CH
2
CH
2
CH
3
CHCH
3
| | |
Cl Cl CH
3

1,2-icloetan 1,1-icloetan
VD: C
3
H
6
co 2p
CH
2
=CHCH
3
, propen
CH
2

/ \
CH
2
CH
2
xiclopropan

Mach
h
No:lk n
Khong no :Lk oi ba
Ankan
Anken,ankn, an kanien

Mach vong
Vong no :lk n
Xiclo ankan
Thm: Co nhan Benzen
A ren
C
x
H
y


* ieu kien e co ong phan cis trans:
a e
\ / a = b
C=C
/ \ e = d
b d
+ ong phan ete : O (3p)
CH
3
OCH
2
CH
2
CH
3
CH
3
OCHCH
3

|
CH
3

CH
3
CH
2
OCH
2
CH
3

III- CAU TAO VA TNH CHAT HOA HOC
CUA CAC HIROCACBON
1. ANKAN (PARAFIN): C
n
H
2n+2

( n > 1)
a) Cau tao: Mach C h, ch co lien ket n (lk
o).
b) Hoa tnh:
- Phan ng the: Cl
2
, Br
2
.
- Phan ng huy.
- Phan ng tach H
2
.
- Phan ng crackinh.
2. ANKEN (OLEFIN): C
n
H
2n
( n > 2)
a) Cau tao: mach C h, co 1 lien ket oi ( 1 lk o
va 1 lk t).
b) Hoa tnh:
- Phan ng cong: H
2
, X
2
, HX, H
2
O
- Phan ng trung hp.
- Phan ng oxi hoa khong hoan toan :
Lam mat mau dung dch thuoc tm.

GV: Trc het xac nh xem chat a
cho thuoc loai chat g : no, khong no,
co the cha nhng loai nhom chc
nao ?
* Th t viet:
- ong phan mach cacbon
- ong phan v tr.
- ong phan nhom chc.
- Cuoi cung xem trong so cac
ong phan va viet, ong
phan nao co ong phan cis-
trans (hp chat cha noi
oi).

Hoat ong 3
GV: lp 11 cac em a nghien cu
nhng hirocacbon nao?

Hoi:Tnh chat hoa hoc cua nhng
hp chat hu c o?


3. ANKIN: C
n
H
2n-2
(n > 2)
a) Cau tao : mach C h, co 1 lien ket ba ( 1lk o
va 2lk t ).
b) Hoa tnh:
- Phan ng cong
- Phan ng trung hp. ( nh hp va tam
hp)
- Phan ng the bi ion kim loai.
- Phan ng oxi hoa: lam mat mau dung
dch KMnO
4
.
4. AREN: C
n
H
2n-6
(n > 6)
a) Cau tao: mach C vong, cha nhan benzen.
b) Hoa tnh:
- Phan ng the : Br
2
, HNO
3
.
- Phan ng cong: H
2
, Cl
2
.

Chu y : Phan ng the cua Ankan
co 3 cacbon tr len u tien the
cacbon co bac cao nhat.
Can lu y: phan ng cong anken
khong oi xng vi tac nhan khong
oi xng (HX, H
2
O) tuan theo qui tac
Maccopnhicop:
3CH
2
=CH
2
+ 2KMnO
4
+ 4H
2
O
CH
2
CH
2
+ 2MnO
2
+2KOH
| |
OH OH
Co kha nang tham gia phan ng cong
hp 2 lan:
VD :
HCCH + Ag
2
O
3
NH
AgCCAg+ +
H
2
O

Bacaxetilua(vang)
Chu y: qui luat the vong benzen
3. Cng c kin thc
On lai ky tnh chat hoa hoc cua cac hirocacbon.
4. Hng dn v nh
HS lm bi trong SBT Ha 11
V- RT KINH NGHIM, B SUNG


Ngy son 20/08/2009
Tit 2 Ch-ng 1.
Este lipit
Bi 1. este
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
Khi nim, cng thc chung ca dy ng ng ca este, bit phn loi v
gi tn mt s este n gin.
Cu to, phn ng thy phn este, phn ng gc hirocacbon, iu ch
v mt s ng dng ca este.
Tnh cht vt l ca este.

HS hiu:
Mi lin h gia cu to este v sn phm ca phn ng thy phn este.
Nguyn nhn gy ra phn ng gc hirocacbon.
Ti sao este c nhit si thp hn axit v ancol tng ng.
2. K nng
T cng thc bit gi tn v ngc li t tn gi vit c cng thc
nhng este n gin.
Vit phng trnh ha hc minh ha tnh cht ca este.
Gii thnh tho cc bi tp v este.
Rn luyn k nng tnh ton cho hc sinh.
Vn dng cc kin thc hc gii cc bi
tp.
3. Tnh cm, thi
Este v sn phm trng hp c nhiu ng dng trong i sng sn xut v
vy gip hc sinh thy c tm quan trng ca vic nghin cu este t
to cho HS nim hng th trong hc tp, tm ti sng to chim lnh
tri thc.
II. Trng tm
Tnh cht ho hc ca este.
III. Chun b
Gio vin: Ha cht: H
2
O, dd H
2
SO
4
long, dd NaOH, etyl axetat, mt t m ln.
Hc sinh: n tp cc kin thc hc.
IV. Ph-ng php
m thoi gi m nu vn hot ng nhm.
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Kt hp trong qu trnh dy hc.
3. Cc hot ng dy hc
Hot ng ca gio vin v hc
sinh
Ni dung kin thc

4. Cng c, dn d
G nhc li pp thng bng electron.
5. H-ng dn v nh
n tp cc kin thc v pu oxi ho - kh.

VI. Rt kinh nghim, b sung

Ngy son 23/08/2009
Tit 3 Ch-ng 1.
Este lipit
Bi 1. este
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:

HS hiu:
2. K nng
nhng este n gin.
tp.
3. Tnh cm, thi
tri thc.
II. Trng tm
III. Chun b
Gio vin: Ha cht: H
2
O, dd H
2
SO
4
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc

4. Cng c, dn d
5. H-ng dn v nh


Ngy son 26/08/2009
Tit 4 Ch-ng 1.
Este lipit
Bi 1. este
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:

HS hiu:
2. K nng
nhng este n gin.
tp.
3. Tnh cm, thi
tri thc.
II. Trng tm
III. Chun b
Gio vin: Ha cht: H
2
O, dd H
2
SO
4
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc


4. Cng c, dn d
5. H-ng dn v nh

Ngy son 01/09/2009
Tit 5
Bi 4. luyn tp este v cht bo
-------------------
I. Mc tiu bi hc

1. Kin thc
HS bit:
HS hiu:
2. K nng
nhng este n gin.
tp.
3. Tnh cm, thi
tri thc.
II. Trng tm
III. Chun b
Gio vin: Ha cht: H
2
O, dd H
2
SO
4
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
Hot ng ca gio vin v hc Ni dung kin thc

sinh
Hoat ong 1
H Nhac lai khai niem este, chat beo.
Cong thc phan t.
H Nh lai tnh chat hoa hoc ac trng
cua este, chat beo: thuy phan trong MT
axit va trong MT baz (xa phong hoa),
phan ng cong hiro vao goc HC cha no
/v chat beo long.
Hoat ong 2
G Hng dan cho hs mau so sanh
H So sanh trnh bay len bang phu
G va h nhan xet bo sung
H Viet phng trnh phan ng bt 2
H Trnh bay ptp bt 3, sau o chon phng
an ung.
Gv va hs: nhan xet bo sung
Hoat ong 3
Gv: Hng dan cho hs phng phap giai
bai tap
Hs: Viet ptp, giai toan hoa hoc

Gv: Hng dan cho hs phng phap giai
bai tap
Hs: Viet ptp, giai toan hoa hoc, sau o
chon phng an ung

I. KIEN THC CAN NH
1. Khai niem

2. Tnh chat hoa hoc
II. BAI TAP

Bai tap l thuyet
Bai tap 1: So sanh chat beo va este ve:
Thanh phan ng.to, . cau tao phan t
va t/c hh.

Bai tap 2,3:

Bai toan
Bai tap 4:

Bai tap 6, 8 :
4. Cng c, dn d
Chuan b kien thc chng mi.
5. H-ng dn v nh
Bai tap ve nha: 5, 7 (sgk trang 18)
Kim tra 15 pht
Cu 1: T cc ancol C
3
H
8
O v cc axit C
4
H
8
O
2
c th to bao nhiu este l ng phn cu to
ca nhau?
A. 4 B. 6 C. 5 D. 3
Cu 2: ng vi cng thc phn t C
3
H
6
O
2
c bao nhiu ng phn no, n chc,mch h tc
dng c vi dung dch NaOH?
A. 5 B. 2 C. 3 D. 4

Cu 3: Metyl propionat l tn gi ca hp cht no sau y?
A. CH
3
COOCH
3
B. CH
3
CH
2
OOCCH
3
C. CH
3
COOCH
2
CH
3
D. CH
3
OOCCH
2
CH
3

Cu 4: Este X c t khi hi so vi CO
2
l 2.Cng thc phn t ca X l
A. C
3
H
6
O
2
B. C
4
H
8
O
2
C. CH
2
O D. C
2
H
4
O
2

Cu 5: Thu phn hon ton 4,4 gam este n chc,mch h X vi 50ml dung dch NaOH 1M
(va ) thu c 2,3 gam ancol Y.Tn gi ca X l :
A. propyl axetat B. etyl axetat C. etyl propionat D. propyl fomat
Cu 6: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C
2
H
4
O
2
ln lt
tc dng vi: Na, NaOH, NaHCO
3
. S phn ng xy ra l
A. 4. B. 2. C. 3. D. 5.
Cu 7: Khi x phng ha tristearin ta thu c sn phm l
A. C
15
H
31
COONa v etanol. B. C
17
H
35
COONa v glixerol.
C. C
15
H
31
COOH v glixerol. D. C
17
H
35
COOH v glixerol.
Cu 8: Cht X c cng thc phn t C
4
H
8
O
2
.Khi X tc dng vi dung dch NaOH sinh ra cht
Y c cng thc phn t C
3
H
5
O
2
Na.Cng thc cu to ca X l :
A. CH
3
COOC
2
H
5
B. C
2
H
5
COOCH
3
C. HCOOC
3
H
5
D. HCOOC
3
H
7

Cu 9: Lm bay hi 8,6 gam mt este X thu c mt th tch hi bng th tch ca 3,2 gam kh
oxi cng iu kin nhit ,p sut.Cng thc phn t ca este l
A. C
4
H
6
O
2
B. C
4
H
8
O
2
C. C
2
H
4
O
2
D. CH
2
O
Cu 10: Khi thu phn cht bo X trong dung dch NaOH thu c glixerol v hn hp hai
mui C
17
H
35
COONa , C
15
H
31
COONa c khi lng hn km nhau 2,201 ln.Trong phn t X c
:
A. 3 gc C
17
H
35
COONa B. 2 gc C
15
H
31
COONa
C. 3 gc C
15
H
31
COONa D. 2 gc C
17
H
35
COONa
Cu 11: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol etylic
46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l
0,8 g/ml)
A. 5,0 kg. B. 4,5 kg. C. 5,4 kg. D. 6,0 kg.

Cu 12: Cht no sau y c mi chui chn?
A. Benzyl axetat B. Isoamyl axetat C. Etyl propionat D. Etyl butirat
Cu 13: Este X n chc c phn trm khi lng cc nguyn t C , H ,O ln lt l 48,65% ;
8,11% ; 43,24% .Cng thc phn t ca X l :
A. C
2
H
4
O
2
B. C
4
H
8
O
2
C. CH
2
O D. C
3
H
6
O
2

Cu 14: Cht c nhit si cao nht l
A. CH
3
COOH. B. CH
3
CHO. C. C
2
H
5
OH. D. HCOOCH
3
.
Cu 15: Cp cht no sau y c th phn ng c vi nhau?
A. CH
3
CH
2
OH v dung dch NaNO
3
. B. CH
3
COOC
2
H
5
v dung dch NaOH.
C. Dung dch CH
3
COOH v dung dch NaCl. D. C
2
H
6
v CH
3
CHO.
Cu 16: Phn t khi trung bnh ca xenluloz to thnh si bng l 1750000.S mt xch
C
6
H
10
O
5
trung bnh c trong mt phn t ca loi xenluloz trn l
A. 1750000 B. 283,5x10
5
C. 10,802 D. 10802
Cu 17: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO
3
trong
dung dch NH
3
thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz
dng l
A. 0,01M. B. 0,10M. C. 0,02M. D. 0,20M.
Cu 18: trung ho 5,6 gam cht bo cn 6,0 ml dung dch KOH 0,1M .Ch s axit ca mu
cht bo ni trn l
A. 0,006 B. 33,6 C. 6,0 D. 0,107
Cu 19: Dung dch saccaroz khng phn ng vi
A. Cu(OH)
2
. B. dung dch AgNO
3
trong NH
3
, un nng.
C. vi sa Ca(OH)
2
. D. H
2
O (xc tc axit, un nng).
Cu 20: un nng 3,7 gam mt este no,n chc c cng thc phn t C
3
H
6
O
2
vi dung dch
NaOH va n khi phn ng xy ra hon ton ,thu c 4,1 gam mui rn khan.Tn gi ca
este l
A. natri etylat B. metyl fomat C. metyl axetat D. etyl fomat
p n, thang im

Cu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
p
n
A C D B B A A B A D C B D B D D C C A C

- Mi cu ng -c 0,5

Ngy son 02/09/2009
Tit 6 Ch-ng 2.
Cacbohirat
Bi 5. glucoz
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
o Cau truc phan t dang mach h cua glucoz.

o Tnh chat cac nhom chc co trong phan t glucoz, van dung
tnh chat cua cac nhom chc o e giai thch cac tnh chat
hoa hoc cua glucoz.
HS hiu:
- Phng phap /c, ng dung cua glucoz va fuctoz.
2. K nng
Khai thac moi quan he: cau truc phan t va tnh chat hoa
hoc
Ren luyen k nang quan sat, phan tch cac ket qua th nghiem.
Giai cac bai tap co lien quan en hp chat glucoz va
fuctoz.
3. Tnh cm, thi
II. Trng tm
Tnh cht ho hc ca glucoz.
III. Chun b
Gio vin:
- Dung cu: kep go, ong nghiem, ua thuy tinh, en con, tha, ong nho giot,
ong th nghiem nho.
- Hoa chat: glucoz, cac dung dch: AgNO
3
, NH
3
, CuSO
4
, NaOH.
- Mo hnh, hnh ve, tranh anh lien quan en bai hoc.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
Hot ng ca gio vin v
hc sinh
Ni dung kin thc
Hoat ong 1
GV: Cho hs quan sat mau glucoz va
t nghien cu SGK.
GV: Em hay cho biet nhng tnh chat
vat l va trang thai thien nhien cua
glucoz?
Hs: Quan sat mau glucoz va nghien
cu sgk t o rut ra nhan xet
I. TNH CHAT VAT L VA TRANG
THAI THIEN NHIEN
Glucoz la chat ran ket tinh, khong mau ,
nong chay 146
0
C (dang ) va 150
0
C (dang
|
) de tan trong nc. Co v ngot, co trong
hau het cac bo phan cua cay ( la, hoa,
re).Co nhieu trong qua nho, mat ong... Trong
mau ngi co mot lng nho glucoz, t le

Hoat ong 2
GV: Yeu cau hoc sinh nghien cu k
sgk
?: Cho biet e xac nh c CTCT
cua glucoz phai tien hanh cac th
nghiem nao? Hs tham khao va i en
ket luan.
Hs: Tra li:
- Glucoz co phan ng trang bac,
vay trong phan t glucoz co nhom
CHO.
- Glucoz tac dung vi Cu(OH)
2

cho dung dch mau xanh lam, vay trong
phan t glucoz co nhieu nhom OH
v tr ke nhau.
- Glucoz tao este cha 5 goc axit
vay trong phan t co 5 nhom OH .
- Kh hoan toan phan t glucoz
thu c n - hexan. Vay 6 nguyen t C
cua phan t glucoz tao thanh mot
mach khong phan nhanh.
Hs ket luan:

GV lu y hs: Thc te glucoz ton tai
2 dang mach vong la va
|
.
Hoat ong 3

GV: Cho hs lam TN sgk
HS: Nghien cu TN SGK , trnh bay
TN, neu hien tng viet ptp
Gv: Nhan xet, bo xung, lu y hs p
xay ra nhiet o thng.
Gv: cho hs hieu c trong phan t
glucoz cha 5 nhom OH, cac nhom
OH v tr lien ke.
GV: Hs thao luan ket luan

Hoat ong 4
GV: Bieu dien th nghiem oxi hoa
glucoz bang dd AgNO
3
trong dung dch
NH
3
(chu y ong nghiem phai sach
hau nh khong oi la 0,1%
II. CAU TAO PHAN T

o-Glucoz Glucoz
|-Glucoz

5 nhom - OH

Glucoz
1 nhom - CHO

Phan t glucoz co CTCT dang mach h thu
gon la:
CH
2
OH-CHOH-CHOH-CHOH-CHOH-CHO

III. TNH CHAT HOA HOC
1. Tnh chat cua ancol a chc (poliancol)
a. Tac dung vi Cu(OH)
2

2C
6
H
12
O
6
+ Cu(OH)
2
(C
6
H
12
O)
2
Cu +
2 H
2
O

b. Phan ng tao este (sgk)

Glucoz la ancol a chc trong phan t co
cha 5 nhom chc OH.
2 .Tnh chat cua nhom anehit
a. Oxi hoa glucoz

CH
2
OH(CHOH)
4
CHO + 2AgNO
3
+ 3NH
3
+ H
2
O
to

CH
2
OH(CHOH)
4
COONH
4
+ 3NH
4
NO
3

+ 2Ag

CH OH

2
H
H
H
H
H
HO
OH
OH
OH
CH OH

2
H
H
H
H
HO
OH
OH
O
C
1
2
3
4
5
6
1
2
3
4
5
6
CH OH

2
H
H
H
H
H
HO
OH
OH
OH
1
2
3
4
5
6

va un nhe hon hp phan ng)
HS: Theo doi gv lam th nghiem, neu
hien tng, giai thch va viet phng
trnh phan ng.
GV: Bieu dien th nghiem oxi hoa
glucoz bang Cu(OH)
2
trong dung dch
NaOH .
HS: Theo doi gv lam th nghiem, neu
hien tng, giai thch va viet phng
trnh phan ng.
GV: Yeu cau hoc sinh viet phng trnh
hoa hoc cua phan ng kh glucoz
bang hiro.

GV: Hs thao luan ket luan

GV: yeu cau hoc sinh viet phng trnh
hoa hoc len men glucoz.

Hoat ong 5
GV: Cho hs oc sgk

HS: Hay nghien cu SGK cho biet
ac iem cau tao cua ong phan
quan trong nhat cua glucoz la
fructoz.
HS: Cho biet tnh chat vat l va trang
thai t nhien cua fructoz.
HS: cho biet cac tnh chat hoa hoc
ac trng cua fructoz. Giai thch
nguyen nhan gay ra cac tnh chat o.
CH
2
OH(CHOH)
4
CHO + Cu(OH)
2
+ NaOH
to

CH
2
OH(CH
2
OH)
4
COONa + Cu
2
O1 +
H
2
O

b. Kh glucoz bang hiro
CH
2
OH(CHOH)
4
CHO + H
2

. Ni,to

CH
2
OH(CHOH)
4
CH
2
O
H
Sobitol
Phan t glucoz co cha nhom chc
anehit CHO.

3. Phan ng len men:

2C
6
H
12
O
6
. enzim, 30-35 C
2C
2
H
5
OH + 2CO
2

IV. IEU CHE VA NG DUNG:
1. ieu che:(sgk)
2. ng dung: (sgk)
V. ONG PHAN CUA GLUCOZ: LA
FRUCTOZ
Ket luan
- Fructoz la polihiroxixeton
- Co the ton tai dang vong 5 canh hoac
6 canh ( dang 5 canh co 2 ong phan va
| )
- Fuctoz co tnh chat tng t glucoz va co
s chuyen hoa gia 2 dang ong phan trong
mt baz:

Glucoz Fructoz

4. Cng c, dn d
G li tnh cht ho hc ca glucoz.
So snh tnh cht ho hc ca glucoz v saccaroz.
5. H-ng dn v nh
n tp cc kin thc hc.
Lm bi tp trong SGK.
- OH

Ngy son 07/09/2009
Tit 7
Bi 6. saccaroz, tinh bt v xenluloz
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Biet cau truc phan t cua saccaroz.
HS hiu: - Hieu cac nhom chc cha trong phan t saccaroz va mantoz.
- Hieu cac phan ng hoa hoc ac trng cua chung.
2. K nng

Ren luyen cho hoc sinh phng phap t duy khoa hoc, t cau tao cua cac hp
chat hu c phc tap (dang vong cua saccaroz va mantoz, d oan tnh
chat hoa hoc cua chung)
Quan sat phan tch cac ket qua th nghiem.
Thc hanh th nghiem.
Giai cac bai tap ve saccaroz va mantoz.
3. Tnh cm, thi
II. Trng tm
Tnh cht ho hc ca saccaroz.
III. Chun b
Gio vin: Dung cu: coc thuy tinh, ua thuy tinh en con, ong nho giot.
- Hoa chat: dung dch CuSO
4
, dung dch NaOH, saccacroz, mantoz.
- Hnh ve phong to cau tao dang vong saccaroz, mantoz.
- S o san xuat ng saccaroz trong cong nghiep.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
So snh tnh cht ho hc ca glucoz v saccaroz.
Trnh by tnh cht ho hc ca glucoz, vit pthh
minh ho.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

Hs oc tnh chat vat l va trang thai t
nhien cua saccaroz, tinh bot, xenluloz
ve: trang thai, mau sac, mui v, o tan
trong nc.
Hs: oc sgk ket luan.
Gv: Phan tch bo sung.

Hs so sanh cau tao phan t cua
A. Saccaroz
I. Tnh chat vat l va tttn
- Chat ran ket tinh, ko mau, ko mui,
ngot, t
o
nc 185
o
C. Tan tot trong nc.
- Co trong ma ng, cu cai ng, hoa
thot not.

II. Cau truc phan t
Disaccarit

saccaroz
Hs: oc sgk tong hp, phan tch hnh cau
tao ket luan ac iem cau tao quan
trong can nh

Gv: Tnh chat hoa hoc saccaroz.
Hs: Thao luan viet ptp rut ra tchh cua
cac chat.
HS: Giai thch hien tng va viet phan
ng hoa hoc.

Hs oc sgk ng dung cua saccaroz.
Hs: oc sgk san xuat saccaroz, xem tranh
minh hoa sx t ma ng.
Gv: Phan tch bo ung, cho hs thay c vai
tro cac chat tren trong /s va sx.

Goc - glucoz va | - fructoz
Ko co mot nhom CHO, co nhieu
nhom OH
CTPT C
12
H
22
O
11
III. Tnh chat hoa hoc
1. Phan ng thuy phan
a. Thuy phan nh xuc tac axit
C
12
H
22
O
11

H+
C
6
H
12
O
6
+ C
6
H
12
O
6

Saccaroz Glucoz Fructoz
b. Thuy phan nh enzim
Saccaroz
enzim
Glucoz.
2.. Phan ng cua ancol a chc
Phan ng vi Cu(OH)
2

2C
12
H
22
O
11
+ Cu(OH)
2

(C
12
H
21
O
11
)
2
Cu + H
2
O
IV. ng dung va san xuat

4. Cng c, dn d
Da vo cu trc phn t hy trnh by tnh cht ho hc
ca saccaroz.
5. H-ng dn v nh


Ngy son 10/09/2009
Tit 8
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
o Bit cu trc phn t v tnh cht ca tinh bt.
o Bit s chuyn ho v s to thnh tinh bt.
HS hiu:
2. K nng
- Vit cu trc phn t ca tinh bt.
- Nhn bit tinh bt.

3. Tnh cm, thi
II. Trng tm
Cu to v t/c ha hc ca tinh bt.
III. Chun b
Gio vin: - Dng c: ng nghim, dao, ng nh git.
- Ho cht: tinh bt, dd iot.
- Cc hnh v phng to v cu trc phn t ca tinh bt v cc
tranh nh c lin quan n bi hc.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ho hc ca saccaroz, vit pthh
minh ho.
3. Cc hot ng dy hc
Hot ng ca gio
vin v hc sinh
Ni dung kin thc
Hot ng 1
* HS quan st mu
tinh bt v nghin
cu SGK cho bit cc
tnh cht vt l v
trng thi thin
nhin ca tinh bt.
Hot ng 2
* HS:
- Nghin cu SGk, cho
bit cu trc phn t
ca tinh bt.
B. Tinh bt
I- TNH CHAT VAT L VA TRANG THAI T
NHIEN
(khoai, san,) va qua (tao, chuoi,). Ham lng
tinh bot trong gao khoang 80%, trong ngo khoang 70%,
trong cu khoai tau ti khoang 20%.

II. Cu trc phn t

CH OH

2
H
H
H
H
H
OH
OH
1
2
3
4
5
6
CH OH

2
H
H
H
H
H
OH
OH
1
2
3
4
5
6
O ....
CH OH

2
H
H
H
H
H
OH
OH
1
2
3
4
5
O
O
....

- Cho bit c im
lin kt gia cc mt
xch o-glucoz trong
phn t tinh bt.
* HS tr li:
Trong phn t
amoloz, cc mt xch
o-glucoz lin kt
vi nhau gia nguyn
t C
1
mt xch ny
v nguyn t C
4
mt
xch kia qua cu oxi,
gi l cc lin kt
o[1-4] glicozit
Phn t amolipectin
-c cu to bi mt
s mch amiloz, cc
mch ny ni vi nhau
gia nguyn t C
1

mt xch u ca mch
ny vi nguyn t C
6

mt xch gia ca
mch kia, qua nguyn
t oxi, gi l lin
kt o[1-6] glicozit.
Hot ng 3

- Nu hin t-ng khi
un nng dung dch

III. Tnh cht ho hc
L mt polisaccarit c cu trc vng xon,
tinh bt biu hiu rt yu tnh cht ca
mt poliancol, ch biu hin r tnh cht
thu phn v phn ng mu vi iot.
1. Phn ng thu phn
a) Thu phn nh xc tc axit
- D kin : sgk
- Gii thch (C
6
H
10
O
5
)
n
+ nH
2
O
= 0
,t H
n
C
6
H
12
O
6

Thc ra tinh bt b thu phn tng bc qua
cc giai on trung gian l etrin
[C
6
H
10
O
5
]
n
, mantoz.
b) Thu phn nh enzim
glucozo Mantozo extrin bt Tinh
mantaza
O H
amilaza -
O H
amilaza -
O H
2 2 2

2. Phn ng mu vi dung dch iot
a) Th nghim
+ Nho dung dch iot vao ong nghiem ng dung dch
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
6
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
6
O ....
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
O
O
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
6
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
O ....
CH OH

2
H
H
H
H H
OH
OH
1
2
3
4
5
O
O ....

tinh bt vi axit v
c long. Vit PTHH.

- Cho bit s tm
tt qu trnh thu
phn tinh bt xy ra
nh enzim.
* GV biu din:
- Th nghim gia
dung dch I
2
v dung
dch tinh bt nhit
th-ng, un nng
v ngui.
- Th nghim gia
dung dch I
2
cho ln
mt ct ca c khoai
lang.
* HS nu hin t-ng.
* GV gii thch v
nhn mnh y l phn
ng c tr-ng nhn
ra tinh bt.

Hot ng 4
* HS nghin cu SGK,
cho bit qu trnh
ho tinh bot hoac vao mat cat cua cu khoai lang.
+ Hien tng : Dung dch ho tinh bot trong ong
nghiem cung nh mat cat cua cu khoai lang eu
nhuom mau xanh tm. Khi un nong,mau xanh tm bien
mat, khi e nguoi mau xanh tm lai xuat hien.

b) Gii thch
+Phan t tinh bot hap thu iot tao ra mau xanh tm. Khi
un nong,iot b giai phong ra khoi phan t tinh bot
lam mat mau xanh tm o. Khi e nguoi, iot b hap
thu tr lai lam dung dch co mau xanh tm. Phan ng
nay c dung e nhan ra tinh bot bang iot va ngc
lai.
IV. S chuyn ha tinh bt trong c th
mantaza
O H
amilaza -
O H
amilaza -
O H
2 2 2

glicogen
enzim enzim
O H CO Glucozo
2 2
enzim
[O]
+

V. S to thnh tinh bt trong cy xanh
6nCO
2
+ 5n H
2
O
clorophin
tri mt sng nh
(C
6
H
10
O
5
)
n
+ 6nCO
2


chuyn ho tinh bt
trong c th ng-i.
to thnh tinh bt
trong cy xanh.
* GV phn tch
ngha ca ph-ng
trnh tng hp tinh
bt.

4. Cng c, dn d
Tnh cht ho hc ca tinh bt, s thu phn tinh bt
5. H-ng dn v nh
Bi tp trong SGK.


Ngy son 12/09/2009
Tit 9
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: - Bit cu trc phn t ca xenluloz.
HS hiu: - Hiu tnh cht ho hc c trng v ng dng ca
xenluloz.
2. K nng
Phn tch v nhn dng cu trc phn t ca xenluloz.
Quan st, phn tch cc hin tng th nghim, vit
PTHH.
Gii cc bi tp v xenluloz.
3. Tnh cm, thi
II. Trng tm
Cu to v tnh cht hh ca xenluloz ?
III. Chun b
Gio vin: - Dng c: Cc thu tinh, ng nghim, dim, ng nh
git.
- Ho cht: xenluloz, cc dung dch AgNO
3
, NH
3
, NaOH H
2
SO
4
, HNO
3
.
- Cc tranh nh c lin quan n bi hc.
IV. Ph-ng php

V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ho hc ca tinh bt, vit pthh
minh ho.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

Hot ng 1
* HS quan st mu xenluloz
(bng thm n-c), tm hiu
tnh cht vt l v trng thi
thin nhin ca xenluloz.

Hot ng 2
* HS nghin cu SGK cho bit:
- Cu trc ca phn t
xenluloz.
- Nhng c im chnh v cu
to phn t ca xenluloz. So
snh vi cu to ca phn t
tinh bt.

Hot ng 3

C. Xenluloz
I. Tnh cht vt l. Trng thi
thin nhin
sgk

II. Cu trc phn t
Xenluloz l mt polime hp
thnh t cc mt xch
|(1,4)glucozit, c cng thc
(C
6
H
10
O
5
)
n
, mch ko di khng
phn nhnh.

Mi mt xch C
6
H
10
O
5
c 3 nhm -
OH t do, nn c th vit cng
thc ca xenluloz l
[C
6
H
7
O
2
(OH)
3
]
n

III. Tnh cht ho hc
Xenluloz l polisaccarit v mi
mt xch c 3 nhm -OH t do nn
xenluloz c phn ng thu phn
CH OH

2
H
H
H
H
H
OH
OH
O
n

* GV biu din th nghim phn
ng thu phn xenluloz theo
cc b-c:
- Cho bng nn vo dung dch
H
2
SO
4
70%.
- Trung ho dung dch thu -c
bng dung dch NaOH 10 %.
- Cho dung dch thu -c tc
dng vi dung dch AgNO
3
/NH
3
,
un nh.
* HS quan st, gii thch v
vit PTHH.
* GV lin h cc hin tng
thc t, v d: tru b nhai
li...

Hot ng 4
* GV biu din th nghim phn
ng este ho xenluloz theo
trnh t sau:
- Cho vo ng nghim ln l-t:
+ 4 ml dung dch HNO
3
c
+ 8 ml dung dch H
2
SO
4
c,
ngui.
+ 1 nhm bng
+ Ly sn phm ra p kh.
* HS nhn xt mu sc ca sn
phm thu -c. Nu hin t-ng
khi t chy sn phm. Vit
PTHH.
* HS nghin cu SGK cho bit
v phn ng ca ancol a chc.
1. Phn ng ca polisaccarit
a) M t th nghim sgk
b) Gii thch sgk
(C
6
H
10
O
5
)
n
+ nH
2
O
o
t SO H ,
4 2
nC
6
H
12
O
6

2. Phn ng ca ancol a chc
a) Phn ng vi nc Svayde
Xenluloz phn ng vi nc
Svayde cho dung dch phc ng
xenluloz dng sn xut t
ng-amonic.
b) Phn ng este ho
* [C
6
H
7
O
2
(OH)
3
]
n
+3nHNO
3

o
t SO H ,
4 2
[C
6
H
7
O
2
(ONO
2
)
3
]
n
+ 3nH
2
O.
*[C
6
H
7
O
2
(OH)
3
]
n
+2n(CH
3
CO)
2
O
[C
6
H
7
O
2
(OCOCH
3
)
2
(OH)]
n
+ 2n CH
3
COOH
*[C
6
H
7
O
2
(OH)
3
]
n
+3n(CH
3
CO)
2
O
[C
6
H
7
O
2
(OCOCH
3
)
3
]
n
+ 3n CH
3
COOH

IV. ng dng (sgk)


sn phm phn ng khi cho
xenluloz tc dng vi
anhirit axetic.
Hot ng 5
* HS lin h kin thc thc t
v tm hiu SGK cho bit cc
ng dng ca xenluloz.
* GV : Xenluloz c rt nhiu
ng dng trong i sng v sn
xut, to ra ngun nguyn
liu qu gi ny, chng ta
phi tch cc trng cy ph
xanh mt t.

4. Cng c, dn d
Tng kt kin thc trong hai bi 5 v bi 6.
5. H-ng dn v nh
Bi tp SGK

Ngy son 14/09/2009
Tit 10
Bi 8. thc hnh iu ch, tnh cht ho hc
Ca este v cacbohrat

-------------------
I. Mc tiu bi hc
1. Kin thc
Cng c nhng tnh cht quan trng ca este,
gluxit nh- p- x phng ho, p- vi dd Cu(OH)
2
ca
glucoz, p- vi dd iot ca h tinh bt, khi nim
v phn ng iu ch este, x phng.
2. K nng
Rn luyn k nng thc hin cc p-hh hu c nh-
va un nng hn hp lin tc, va khuy u hn
hp, lm lnh spp-,...
Rn luyn k nng lp rp dng c th nghim k
nng thc hin v quan st cc hin t-ng th
nghim xy ra.
3. Tnh cm, thi
Yu thch khoa hc.
II. Trng tm
Tnh cht ho hc ca este, gluxit.
III. Chun b
Ho cht, dng c cho 1 nhm
DUNG CU TH NGHIEM HOA CHAT TH NGHIEM
- ong nghiem 6
- coc thuy tinh 100ml 1
- cap ong nghiem go 1
- en con 1
- ong hut nho giot 1
- tha xuc hoa chat 2
- gia e ong nghiem 1
- dd NaOH 10%
- dd CuSO
4
5%
- dd glucozo 1%
- H
2
SO
4
10%
- tinh bot
- dd I
2
0,05%

IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
Gv chia Hs thnh 4 nhm, kim tra tng nhm trong qu
trnh thc hnh.
2. Cc hot ng dy hc
sinh
Ni dung kin thc
1. Th nghiem 1: ieu che etyl axetat

Thi nghiem 1: dan do HS can than khi
tiep xuc vi H
2
SO
4
nhat la khi un
nong

Th nghiem 3: Phan ng cua glucozo vi
Cu(OH)
2

GV: lu y
- Cac em co the dung ong nho giot e
c lng hoa chat thc hien phan
ng.
- Cho vao ong nghiem 3 giot dd
CuSO
4
5% va 6 giot dd NaOH 10%. Lac
nhe e co ket tua Cu(OH)
2
. Gan bo
phan dd
- Cho them vao ong nghiem 10 giot dd
glucozo 1% lac nhe.
- un nong dd en soi, e nguoi.

Th nghiem 4: Phan ng cua HTB vi I
2

Khong nen cho qua nhieu dd I
2

Cho vao ong nghiem kho (dai 14 -
18 cm) 1 ml ancol etylic, 1 ml axit axetic
nguyen chat va 1 giot axit sunfuric ac.
Lac eu, ong thi un cach thuy 5 - 6
phut trong noi nc nong 65 - 70
0
C
(hoac un nhe tren ngon la en con,
khong c un soi). Lam lanh roi rot
them vao ong nghiem 2 ml dung dch
NaCl bao hoa. Quan sat hien tng, giai
thch va viet phng trnh hoa hoc.
2. Th nghiem 2: Phan ng xa phong
hoa
3. Th nghiem 3: Phan ng cua glucoz
vi Cu(OH)
2

Cho vao ong nghiem 2 - 3 giot dung
dch CuSO
4
5% va 1 ml dung dch NaOH.
Lac nhe, gan bo phan dung dch, gi lai
ket tua Cu(OH)
2
. Cho them vao ong
nghiem 2 ml dung dch glucoz 1%. Lac
nhe,nhan xet hien tng xay ra, giai
thch.Sau o un nong hon hp, e
nguoi. Nhan xet hien tng.

4. Th nghiem 4: Phan ng cua ho
tinh bot vi iot
Cho vao ong nghiem kho 2 ml dung
dch ho tinh bot 2% roi them vai giot dung
dch iot 0,05%, lac nhe .un nong dung dch
co mai tren roi lai e nguoi. Quan sat
hien tng, giai thch

3. Cng c, dn d, cng vic sau bui thc hnh
Vit bi t-ng trnh th nghim
4. H-ng dn v nh
n tp cc kin thc hc v este, gluxit.

Ngy son 17/09/2009
Tit 11
Bi 7. luyn tp cu to v tnh cht ca cacbohirat

-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: c im cu trc phn t ca cc hp cht cacbonhirat
tiu biu.
HS hiu: - Hiu mi lin quan gia cu trc phn t v tnh cht
ho hc ca cc hp cht cacbonhirat tiu biu.
- Hiu mi lin h gia cc hp cht cacbonhirat trn.
2. K nng
Lp bng tng kt ch-ng.
Gii cc bi ton v cc hp cht cacbonhirat.
3. Tnh cm, thi
II. Trng tm
Cu trc v tnh cht ca mt s cacbohidra.
III. Chun b
Gio vin: - Dng c: Cc thu tinh, ng nghim, dim, ng nh
git.
- Ho cht: xenluloz, cc dung dch AgNO
3
, NH
3
, NaOH, H
2
SO
4
,
HNO
3
.
- Cc tranh nh c lin quan n bi hc.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1
GV: Chuan b bang on tap l thuyet
GV: Goi 3 hs len bang
A.L THUYET CAN NH
1. Cau tao
a) Glucoz va frutoz (C
6
H
12
O
6
)

HS th 1: Viet cong thc phan t cua
monosaccarit va neu nhng ac
iem cua hp chat nay.
isaccarit va neu nhng ac iem
cua hp chat nay.
poli saccarit va neu nhng ac iem
cua hp chat nay.
GV: Sa cha cau truc phan t cua
hoc sinh, ghi vao bang tong ket va
neu nhng ac iem ve cau truc
phan t hoc sinh can lu y.
GV: Qua o cac em co ket luan g ve
cau truc cua cac cacbohirat?
HS: Len bang trnh bay cau tra li cua
mnh
Hoat ong 2
H: Em hay cho biet nhng hp chat
cacbohirat nao tac dung c vi
dd AgNO
3
/ NH
3
, tai sao?
cacbohirat nao tac dung c vi
CH
3
OH/HCl, tai sao?
cacbohirat nao co tnh chat cua
ancol a chc. Phan ng nao ac
trng nhat?
cacbohirat nao thuy phan trong moi
trng H
+
?
cacbohirat nao co phan ng mau
vi I
2
?
GV: Qua o em co ket luan g ve tnh
chat cua cac cacbohirat?
Hoat ong 3
GV: Hng dan hoc sinh giai mot so
bai tap SGK va SBT
GV: Cho bai tap bo sung
- Phan t glucoz co cong thc cau tao
thu gon dang mach h la :
CH
2
OH CHOH CHOH CHOH CHOH
CH = O
Hoac viet gon la :
CH
2
OH[CHOH]
4
CHO
-Phan t Fructoz (C
6
H
12
O
6
) dang
mach h la mot polihiroxi xeton, co
cong thc cau tao thu gon la :
CH
2
OH CHOH CHOH CHOH C
CH
2
OH

Hoac viet gon la :
CH
2
OH[CHOH]
3
COCH
2
OH

un nong trong moi trng kiem no
chuyen thanh glucoz theo can bang sau :

Fructoz Glucoz

b) Saccaroz (C
12
H
22
O
11
)
Trong phan t khong co nhom CHO
c) Tinh bot (C
6
H
10
O
5
)
n

Amiloz : polisaccaric khong phan nhanh,
do cac mat xch o - glucoz
Amolopectin : polisaccaric phan nhanh, do
cac mat xch o - glucoz noi vi nhau,
phan nhanh

d) Xenluloz (C
6
H
10
O
5
)
n
Polisaccaric khong phan nhanh, do cac
mat xch | - glucoz noi vi nhau

2. Tnh chat hoa hoc (xem bang tong ket)

B. BAI TAP
4. Cng c, dn d
Tng kt kin thc trong hai bi 5 v bi 6.
i t cac hp chat cacbohirat tieu bieu glucozo, fuctozo, mantozo, saccaroz, xenlulozo
va tinh bot hay neu s o tong hp ra etanol.
1
1
O
OH
-

5. H-ng dn v nh
Bi tp SGK

Ngy son 20/09/2009
Tit 12
kim tra 1 tit
-------------------

I. Mc tiu bi hc
1. Kin thc
Hs nm -c kin thc trong ch-ng 1, ch-ng 2.
2. K nng
Vn dng kin thc gii cc bi ton ho hc.
II. Trng tm
III. Chun b
Gio vin: thi v p n
IV. Ph-ng php
Hnh thc kim tra: T lun.
V. bi
Cau 1(3):Viet phng trnh hh cua phan ng theo s o sau:
( Chat hu c viet di dang cong thc cau tao thu gon, ghi ro ieu kien
phan ng can thiet, neu co)
Tinh bot C
6
H
12
O
6
C
2
H
6
O C
4
H
6
Cao su buna

C
2
H
4
C
2
H
6
O
2
C
2
H
2
O
2
C
2
H
2
O
4

Cau 2(3):Viet phng trnh phan ng hoa hoc xay ra (neu co) gia
saccarozo vi Cu(OH)
2
( nhiet o thng va un nong), vi dung dch
AgNO
3
trong NH
3
( un nhe) va vi dung dch H
2
SO
4
(loang, un nhe)
Cau 3(4): Len men 1 tan tinh bot cha 10% tap chat thanh ru etylic,
hieu suat cua moi qua trnh len men la 85%
a)Tnh khoi lng ru thu c.
b) em pha loang ru o thanh ru 40
0
, biet khoi lng rieng cua ru
etylic la 0,8 gam /cm
3
.Hoi the tch dung dch ru thu c bang bao nhieu.

VI. p n, thang im
Cu 1. Mi pt ng -c 0,5
[C
6
H
10
O
5
]
n
+ H
2
O/xt H
+
C
6
H
12
O
6
Ln men
Cu 2. 3
2C
12
H
22
O
11
+ Cu(OH)
2
(C
12
H
21
O
11
)
2
Cu + H
2
O
Khng c nhm CHO
Cu 3. 4

Hs vit -c s p- sau
mantaza
O H
amilaza -
O H
amilaza -
O H
2 2 2

2C
6
H
12
O
6
. enzim, 30-35 C
2C
2
H
5
OH + 2CO
2

Vdd = m/d

VII. Rt kinh nghim, b sung

Ngy son 27/09/2009
Tit 13 Ch-ng 3. amin, amino axit
v protein
Bi 9. amin
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Bit cc loi amin, danh php ca amin.

HS hiu: Hiu cu to phn t, tnh cht, ng dng v
iu ch ca amin.
2. K nng
Nhn dng cc hp cht ca amin.
Gi tn theo danh php (IUPAC) cc hp cht amin.
Vit chnh xc cc PTHH ca amin.
Quan st, phn tch cc TN chng minh.
3. Tnh cm, thi
Thy -c tm quan trng ca cc hp cht amin
trong i sng v sn xut, cng vi hiu bit v cu
to, tnh cht ho hc ca cc hp cht amin t
to cho HS nim hng th trong hc tp, tm ti sng to chim lnh tri
thc.
II. Trng tm
Nghin cu khi nim, phn loi, danh php, ng phn ca
amin. Tnh cht vt l ca cc amin. to v tnh cht ho
hc ca cc amin. iu ch v ng dng ca cc amin.
III. Chun b
Gio vin: Dng c: ng nghim, a thu tinh, ng nh git.
Ho cht: Cc dd CH
3
NH
2
, HCl, anilin, nc Br
2
.
M hnh phn t amin
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Cc hot ng dy hc
Hot ng ca gio vin v
hc sinh
Ni dung kin thc
Hoat ong 1

G: Viet CTCT cua NH
3
va 4 amin
khac .
H: Nghien cu k cac chat trong v
du tren va cho biet moi quan he
gia cau tao amoniac va cac amin.
G: nh hng cho hs sinh phan
tch.
H: T o hs hay cho biet nh
I.KHAI NIEM, PHAN LOAI, VA DANH
PHAP
1. Khai niem, phan loai

Khi thay the mot hay nhieu nguyen t hiro

ngha tong quat ve amin?
H: Tra li va ghi nhan nh ngha

G: Cac em hay nghien cu k
SGK va t cac v du tren .Hay
cho biet cach phan loai cac amin
va cho v du?

H: Nghien cu va tra li, cho
cac v du minh hoa.

G: Cac em hay theo doi bang3.1
SGK ( danh phap cac amin) t o
cho biet:
Qui luat goi ten cac amin theo
danh phap goc chc.
Qui luat goi ten theo danh phap
thay the.
G: Nhan xet, bo sung .
H: Tren c s tren, em hay goi
ten cac amin sau:
G: Lay vai amin co mach phc
tap e hoc
Hoat ong 2
G: Cac em hay nghien cu SGK
phan tnh chat vat l cua amin va
anilin.
H: Cho biet cac tnh chat vat l
ac trng cua amin va chat tieu
bieu la anilin?
Hoat ong 3
G: Gii thieu biet CTCT cua vai
amin
H: Hay phan tch ac iem cau
tao cua amin mach h va
anilin.
G: Bo sung va phan tch k e hoc
sinh hieu k hn.
H: T CTCT va nghien cu SGK
em hay cho biet amin mach h
va anilin co tnh chat hoa hoc
g?
G: Chng minh TN 1 cho quan sat.
H:, cho biet khi tac dung vi
trong phan t NH
3
bang mot hay nhieu goc
hirocacbon ta c amin.
Th du : CH
3
- NH
2
; CH
3
- NH - CH
3
;
CH
2
= CH - CH
2
NH
2
; C
6
H
5
NH
2

Amin c phan loai theo 2 cach:
Theo goc hirocacbon:
- Amin beo: CH
3
NH
2
, C
2
H
5
NH
2
- Amin thm: C
6
H
5
NH
2

Theo bac cua amin.
- Bac 1: CH
3
NH
2
, C
2
H
5
NH
2
, C
6
H
5
NH
2
- Bac 2: (CH
3
)
2
NH

- Bac 3: (CH
3
)
3
N
2. Danh phap:
Cach goi ten theo danh phap
Goc chc: Ankyl + amin
Thay the: Ankan + v tr + amin
Ten thong thng ch ap dung cho mot so
amin.
Ten cua amin c goi theo danh phap goc -
chc va danh phap thay the.Ngoai ra mot so
amin c goi theo ten thng (ten rieng) nh
bang 3.1

II. TNH CHAT VAT L
Metylamin, imetylamin, trimetylamin va
etylamin la nhng chat kh co mui kho chu,
oc , de tan trong nc, cac amin ong ang
cao hn la chat long hoac ran,
III. CAU TAO PHAN T VA TNH CHAT
HOA HOC
1. Cau tao phan t
Cac amin mach h eu co cap electron t do
cua nguyen t nit trong nhom chc, do o
chung co tnh baz. Nen amin mach h va
anilin co kha nang phan ng c vi cac
chat sau ay

2. Tnh chat hoa hoc
a. Tnh baz
C
6
H
5
NH
2
+ HCl [C
6
H
5
NH
3
]
+
Cl

CH
3
CH
2
CH
2
NH
2
+ H
2
O
[CH
3
CH
2
CH
2
NH
3
]
+
+ OH
-


metylamin va anilin qu tm co hien
tng g? V sao?
H: Neu hien tng

G: Giai thch hien tng
G: Bieu dien th nghiem gia
C
6
H
5
NH
2
vi dd HCl.
H: Quan sat th nghiem va neu
cac hien tng xay ra trong th
nghiem tren va giai thch va viet
phng trnh phan ng xay ra.
H: So sanh tnh baz cua metylamin,
amoniac va anilin.
G: Bieu dien th nghiem cua anilin
vi nc brom:
H: Quan sat va neu hien tng
xay ra?
H: Nghien cu va viet phng
trnh phan ng.
H: Giai thch tai sao nguyen t
brom lai the vao 3 v tr
2,4,6 trong phan t anilin.
H: Do anh hng cua nhom NH
2
,
nguyen t brom de dang
thay the cac nguyen t H
v tr 2,4,6 trong nhan thm
cua phan t anilin.

Tnh baz : CH
3
NH
2
> NH
3
>C
6
H
5
NH
2

b. Phan ng the nhan thm cua anilin

NH
2
+ 3Br
2

Br
Br
Br
NH
2
+ 3HBr

2, 4, 6 tribromanilin
Phan ng nay dung nhan biet anilin.

3. Cng c, dn d
G nhc li tnh cht ha hc ca amin no v amin thm.
Vit cng thc cu to v gi tn cc amin c cng thc C
3
H
9
N
4. H-ng dn v nh
Bt trong SGK
Ngy son 30/09/2009
Tit 14
Bi 10. Amino axit
-------------------
I. Mc tiu bi hc
1. Kin thc

HS bit: - Bit ng dng v vai tr ca amino axit.
HS hiu:- - Cu trc phn t v tnh cht ha hc c bn ca amino axit.
2. K nng
- Nhn bit, gi tn cc amino axit
- Vit cc PTHH ca amino axit
- Quan st, gii thch cc th nghim chng minh.
3. Tnh cm, thi
Amino axit c tm quan trng trong vic tng hp ra
protein, quyt nh s sng, khi ta nm -c bn
cht ca n (nh ngha, danh php v cc tnh
cht c tr-ng ca n) s to cho HS nim hng th trong
hc tp, tm ti sng to chim lnh tri thc.
II. Trng tm
Tnh cht ho hc c bn ca nhm chc - NH2. COOH, -CO-NH-
III. Chun b
Gio vin:
- Dng c: ng nghim, ng nh git.
- Ha cht: dung dch glyxin 10%, axit glutamic, dung dch NaOH 10%, CH
3
COOH tinh
khit.
- Cc hnh v, tranh nh lin quan n bi hc
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ho hc ca amin?
Gi tn cc ng phn amin c cng thc phn t C
4
H
11
N?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1: I-KHAI NIEM

G: Viet mot vai cong thc aminoaxit
thng gap sau o cho hoc sinh nhan
xet nhom chc.
H: Hay nh ngha aminoaxit (HSTB)

Hoat ong 2:
G: Ten goi cua cac amino axit xuat
phat t ten cua axit cacboxilic tng
ng (ten thay the, ten thong thng),
co them tiep au ng amino va ch
so (2,3,...) hoac ch cai Hi Lap (o, |,...)
ch v tr cua nhom NH
2
trong mach.
H: Tham khao sgk xem cac v du hieu
c cach goi ten amino axit.
(Bang 3.2. Ten goi cua mot so o -
amino axit)
G: Phan tch cach oc ten sau o hnh
thanh cac oc ten tong quat.

Hoat ong 3:
G: Da vao cau tao aminoaxit hay cho
biet cac aminoaxit tham gia phan ng
hoa hoc nao?
H: Phan tch cau tao biet c
aminoaxit va co tnh chat axit va co
tnh baz (lng tnh).
H: Hay viet phng trnh phan ng
NH
2
CH
2
COOH + HCl ?
NH
2
CH
2
COOH + NaOH ?
G:Trong phan t Aminoaxit va cha
nhom - NH
2
va cha nhom -COOH
vay gia cac phan t aminoaxit co
the tac dung vi nhau c khong
(HSTB)
Hoat ong 4:
G: Hay nghien cu SGK va cho biet
tnh chat vat ly?

Aminoaxit la nhng HCHC tap chc
va cha nhom chc amin (-NH
2
) va cha
nhom chc cacboxyl (-COOH)
Th du:
H
2
N CH(CH3)- COOH

(alanin)

CTTQ: CxHyOzNt (x, y cung chan hoac
cung le)
(NH
2
)
a
R(COOH)
b

Neu a=b=1 va goc R no th CTPT co dang
NH
2
-C
n
H
2n
-COOH (n>=1) hay C
n
H
2n+1
NO
2

(n>=2)
Danh phap:
+> Thay the: Axit + v tr (so) amino + ten
axit
VD: CH
3
CH CH COOH
CH
3
NH
2

Axit 2 amino 3 metylbutanoic
+>Ban he thong: Axit + v tr (ch Hilap
) amino + ten thong thng cua axit
VD: H
2
N CH
2
COOH Axit - amino axetic
+> Thong thng: khong theo QT (Bang 3.2.
Ten goi cua mot so o - amino axit)
ong phan aminoaxit: viet ong phan axit
sau o di chuyen nhom - NH
2

VD: C
4
H
9
NO
2

II. CAU TAO PHAN T VA TNH
CHAT HOA HOC
1. Cau tao phan t
V nhom COOH co tnh axit, nhom
NH
2
co tnh baz nen trang thai ket tinh
amino axit ton tai dang ion lng cc.
Trong dung dch, dang ion lng cc chuyen
mot phan nho thanh dang phan t :

R
+
COOH CH
NH
3
NH
2
COO
-
R CH

dang ion lng cc dang phan
t

Tnh chat vat ly: Chat ran dang tinh
the khong mau, v hi ngot, de tan trong
nc, nhiet o nong chay cao.
2. Tnh chat hoa hoc

Aminoaxit va co tnh chat axit va co
tnh baz (lng tnh)
a- Tnh lng tnh
Tnh baz: Tac dung axit manh
HOOC-CH
2
-NH
2
+ HCl HOOC-CH
2
-
NH
3
Cl
Tnh axit: Tac dung vi baz manh
H
2
N-CH
2
COOH + NaOH H
2
N-CH
2
COONa
+ H
2
O)

4. Cng c, dn d
Bang 3.2. Ten goi cua mot so o - amino axit
Cong thc Ten thay the Ten ban he thong Ten
thng
K
hieu
CH
2
-COOH
NH
2

Axit aminoetanoic Axit aminoaxetic Glyxin Gly
CH
3
- CH - COOH

NH
2

Axit
2 - aminopropanoic
Axit
- aminopropanoic
Alanin Ala
CH
3
- CH CH -COOH
CH
3
NH
2

Axit - 2 amino -3 -
metylbutanoic
Axit o - aminoisovaleric Valin Val
COOH
NH
2
CH
2
CH HO

Axit - 2 - amino -3(4 -
hiroxiphenyl)propanoic
Axit o - amino -|
(p - hiroxiphenyl)
propionic
Tyrosin Tyr
HOOC(CH
2
)
2
CH - COOH
NH
2

Axit
2 - aminopentanioic
Axit
2 - aminopentanioic
Axit
glutamic
Glu
H
2
N - (CH
2
)
4
- CH - COOH
NH
2

Axit
2,6 - iaminohexanoic
Axit
o, c - iaminocaproic
Lysin Lys

G nhc li tnh cht l-ng cc ca amino axit.
5. H-ng dn v nh
Bi tp trong SGK.


Ngy son 03/10/2009
Tit 15
Bi 10. Amino axit
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: - Bit ng dng v vai tr ca amino axit.
HS hiu:- - Cu trc phn t v tnh cht ha hc c bn ca amino axit.
2. K nng
- Nhn bit, gi tn cc amino axit
- Vit cc PTHH ca amino axit
- Quan st, gii thch cc th nghim chng minh.
3. Tnh cm, thi

Amino axit c tm quan trng trong vic tng hp ra
protein, quyt nh s sng, khi ta nm -c bn
cht ca n (nh ngha, danh php v cc tnh
cht c tr-ng ca n) s to cho HS nim hng th trong
hc tp, tm ti sng to chim lnh tri thc.
II. Trng tm
Tnh cht ho hc c bn ca nhm chc - NH2. COOH, -CO-NH-
III. Chun b
Gio vin:- Dng c: ng nghim, ng nh git.
- Ha cht: dung dch glyxin 10%, axit glutamic, dung dch NaOH 10%, CH
3
COOH tinh
khit.
- Cc hnh v, tranh nh lin quan n bi hc
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Ti sao amino axit c tnh l-ng cc?
Cch gi tn cc amino axit ?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
G: Viet dang tong quat ntn?
H: Viet ptp (sgk)

G l-u H cc poliamit, l
cc polime do cc gc amino
axit kt hp vi nhau = lin
kt amit

b-Tnh chat axit baz cua dd amino axit
Phu thuoc vao so lng nhom chc
amino hoac chc axit.
c- Phan ng trung ngng
Khi un nong: Nhom - COOH cua phan
t nay tac dung vi nhom -NH
2
cua
phan t kia cho san pham co khoi lng
phan t ln, ong thi giai phong H
2
O
n H
2
N[CH
2
]
5
COOH
T
(- HN[CH
2
]
5
CO -)
n
+
n H
2
O
d-Phan ng este hoa cua nhom COOH
Tng t axit cacboxylic, amino axit

Hoat ong 5:
H: oc SGK va rut ra ng dung cua
amino axit

G: Goi mot hoc sinh oc phan ng dung
cua aminoaxit trong SGK
H ket luan: Amino axit la chat c s tao
protein.
phan ng c vi ancol (co axt voc
manh xuc tac) cho este.
Th du :
H
2
NCH
2
COOH + C
2
H
5
OH

H
2
NCH
2
COOC
2
H
5
+ H
2
O
III.NG DUNG
Cac aminoaxit thien nhien (hau het la -
aminoaxit) la hp chat c s e tao nen
cac loai protein cua c the song
Mot so amino axit c dung pho bien
trong i song nh muoi mononatri cua axit
glutamic dung lam gia v thc an (goi la
m chnh) la thuoc ho tr than kinh, thuoc
bo gan
Mot so aminoaxit e san xuat t ni lon

4. Cng c, dn d
G nhc li tnh cht ho hc ca amino axit.
5. H-ng dn v nh
Bi tp trong SGK.

Ngy son 07/10/2009
Tit 16
Bi 11. peptit v protein
-------------------
I. Mc tiu bi hc
1. Kien thc:
Biet khai niem ve peptit, protein, enzim, axit nucleic va vai tro cua
chung trong cuoc song.
Biet s lc ve cau truc phan t va tnh chat c ban cua protein.
2. K nang:
Goi ten peptit, nhan dang mach peptit.
Phan biet cau truc bac 1 va cau truc bac 2 cua protein.
Viet cac phng trnh hoa hoc cua protein.

Quan sat th nghiem chng minh, giai cac bai tap hoa hoc phan peptit
va protein.
3.Tnh cam, thai o
Qua noi dung bai, HS thay khoa hoc co the kham pha c nhng hp chat cau tao
nen c the song va the gii xung quanh, cung co cho hoc sinh niem tin vao khoa
hoc.
II. CHUAN B:
Dung cu: ong nghiem , ong hut hoa chat.
Hoa chat: dd CuSO
4
2%, dd NaOH 30%, long trang trng.
Cac tranh anh , hnh ve phong to lien quan en bai hoc.
III. Trng tm
Lien ket peptit, nhom peptit.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Ti sao amino axit c tnh l-ng cc?
Cch gi tn cc amino axit ?
3. Cc hot ng dy hc
sinh
Ni dung kin thc

GV: Cac em hay nghien cu SGK va cho
biet k/n peptit?
HS: Nghien cu SGK va tra li

GV: Lay v du ve mot mach peptit va
yeu cau hoc sinh ch ra lien ket peptit
cho biet nguyen nhan hnh thanh mach
peptit tren?
HS: Theo doi va tra li
GV: Yeu cau cac em hoc sinh nghien
cu SGK va cho biet cach phan loai
peptit.
HS: Nghien cu SGK va tra li
GV thong bao: Phan t peptit tao thanh
t cac o - aminoaxit bang lien ket peptit
theo mot trat t nhat nh.
- Amino axit au N con nhom NH
2

- Amino axit au C con nhom COOH
GV yeu cau HS: Viet cong thc va goi
I. PEPTIT
1. Khai niem:
Peptit la loai chat cha t 2 en 50
goc
o - aminoaxit lien ket vi nhau bi cac
lien ket peptit.
Lien ket peptit: CONH gia hai n
v o - aminoaxit.

Tuy theo so lng n v amino axit chia
ra: i peptit, tri peptit, . . . va poli peptit
(tren 10 ).


ten thng mot so o - aminoaxit n
gian.
GV thong bao: Ngi ta thng bieu
dien cau tao cac peptit bang cach ghep
t ten viet tat cac o - aminoaxit theo trat
t cua chung.
HS cho v du: Ala Gly; Gly Ala Lys; ...

GV: Cac em hay nghien cu SGK va cho
biet qui luat cua phan ng thuy phan
cua peptit trong moi trng axit, baz hoac
nh xuc tac enzim?
HS: Khi un nong vi dung dch axit baz
hay nh xuc tac cua enzim peptit b thuy
phan thanh hon hp cac o - aminoaxit.
HS: Viet phng trnh phan ng thuy
phan mach peptit trong phan t protein co
cha 3 amino axit khac nhau?
GV: Gii thieu phan ng mau cua
peptit.
Cho 1 2 ml dd peptit vao ong nghiem
ng Cu(OH)
2
mi ieu che, sau o lac
nhe
HS: Quan sat, nhan xet.

2. Tnh chat hoa hoc:
a. Phan ng thuy phan

b. Phan ng mau biure

Hin t-ng : Cu(OH)
2
tan cho dd
mu tm c tr-ng.
Gii thch : Do peptit c nhm
CONH phn ng vi Cu(OH)
2
cho
hp cht mu tm c tr-ng.

4. Cng c, dn d
G nhc li khi nim peptit.
Tnh cht ho hc ca peptit.
5. H-ng dn v nh
G yu cu H lm bi tp trong SGK.


Ngy son 10/10/2009
Tit 17
Bi 11. peptit v protein
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
Khi nim v peptit, protein, axit nucleic, enzim.
Cu to phn t v tnh cht c bn ca peptit, protein.
2. K nng
Nhn bit lin kt peptit
Goi tn peptit
Vit phng tnh ho hc ca peptit, protein
Phn bit cu trc bc I v bc 2 ca protein
3. Tnh cm, thi

Qua noi dung bai, HS thay khoa hoc co the kham pha c nhng hp
chat cau tao nen c the song va the gii xung quanh, cung co cho hoc
sinh niem tin vao khoa hoc.

II. Trng tm
Tnh cht ho hc ca protein.
III. Chun b
Gio vin: Tranh cu trc xon kp ca ADN, cu trc bc I ca phn t insulin.
Dng c v ho cht lm th nghim peptit tc dng vi Cu(OH)
2
, protein tc dung vi
HNO
3
.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Khi nim peptit? Tnh cht ca peptit.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

GV: Cac em hay nghien cu SGK cho
biet nh ngha ve protein va phan loai.

HS: oc SGK e nam c thong tin

GV: Treo hnh ve phong to cau truc phan
t protein cho HS quan sat, so sanh vi
hnh ve trong SGK
HS: Nghien cu SGK cho biet cau tao
phan t protein
GV: Cac em hay nghien cu SGK va
cho biet nhng tnh chat ac trng cua
II. PROTEIN
1.Khai niem
Protein la nhng polipeptit cao
phan t co phan t khoi t vai chuc
ngan en vai trieu vC.
Protein c chia lam 2 loai:
protein n gian la protein c cau tao
t cac o - aminoaxit nh abumin cua long
trang trng, fibroin cua t tam,...
protein phc tap la protein c tao
thanh t protein n gian vi cac thanh
phan phi protein nh nucleoprotein,
lipoprotein,...
2. Cau tao phan t
Tng t peptit (nhieu lien ket peptit)
nhng phc tap hn nhieu. Thng cau
tao t 50 goc o - aminoaxit tr len.

3. Tnh chat

protein?
HS: oc SGK va suy ngh tra li
GV: Lam th nghiem
GV : Giai thch hien tng p

HS: Xem phan ng hoa hoc phan peptit

HS: oc sgk e hieu vai tro cua protein
trong i song.
Hoat ong 4:
1. Enzim:
cho biet :
- nh ngha ve enzim
- Cac ac iem cua enzim.
HS: Nghien cu SGK va tra li.

2. Axit nucleic:
cho biet ac iem chnh cua axit nucleic
HS: Cho biet s khac nhau cua phan t
ADN va ARN khi nghien cu SGK?

a. Tnh chat vat l
Protein tan trong nc tao thanh dung dch
keo.
Khi un nong long trang trng b ong
tu.

b. Tnh chat hoa hoc

4.Vai tro cua protein /v i song

IV. Khai niem ve enzim va axit nucleic:
1. Enzim:
Enzim la nhng chat hau het co
ban chat protein, co kha nang xuc tac
cho cac qua trnh hoa hoc, ac biet
trong c the sinh vat.
Xuc tac enzim co 2 ac iem :
+ Co tnh chon loc cao, moi enzim
ch xuc tac cho mot s chuyen hoa
nhat nh,
+ Toc o phan ng nh xuc tac
enzim rat ln gap 10
9
10
11
toc o phan
ng nh xuc tac hoa hoc.
2. Axit nucleic:
- Axit nucleic la polieste cua axit
photphoric va pentoz ( monosaccarit co 5
C)moi pentoz lai co mot nhom the la
mot baz nit.
+ Neu pentoz la riboz: tao axit
ARN.
+ Neu pentoz la eoxiriboz: tao
axit ADN.
+ Khoi lng ADN t 4 8 trieu
vC, thng ton tai dang xoan kep.
Khoi lng phan t ARD nho hn ADN,
thng ton tai dang xoan n.

4. Cng c, dn d
G yu cu H lp bng so snh tnh cht ca protein v
peptit.
5. H-ng dn v nh
Bi tp trong SGK.

Ngy son 12/10/2009
Tit 18
Bi 12. Luyn tp
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Nam c tong quat ve cau tao va tnh chat hoa hoc c ban
cua amin, amino axit, protein.
HS hiu:
2. K nng
Viet phng trnh phan ng dang tong quatcho cac hp chat: amin, amino
axit.protein.
Giai cac bai tap ve phan amin,amino axit va protein.
3. Tnh cm, thi
II. Trng tm

Tnh cht ho hc ca nhm chc - NH2. COOH, -CO-NH-.
III. Chun b
Gio vin: Sau khi ket thuc bai 9, GV yeu cau hoc sinh on tap toan bo chng
va lam bang tong ket theo qui nh cua GV.
- Chuan b them mot so bai tap cho hoc sinh e cung co kien thc trong
chng.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
Hot ng ca gio vin
v hc sinh
Ni dung kin thc
Hoat ong 1:
G: Cac em a nghien cu va
hoc l thuyet cua cac bai trong
toan chng em hay cho biet
CTCT chung cua amin, amino axit
va protein?
H: Cho biet ac iem cau tao
cua cac hp chat amin, amino
axit, protein va ien vao bang
sau?
H: Tra li va ghi vao bang

H: T bang tren va bang sgk hs
rut ra nhan xet ve nhom ac
trng va t/c hh cua cac chat.
G: Cac em hay cho biet tnh chat
hoa hoc ac trng cua amin,
aminoaxit va protein?
H: Em hay cho biet nguyen nhan
gay ra phan ng hoa hoc cua
cac hp chat amin, aminoaxit va
protein?
H: Em hay so sanh tnh chat hoa
hoc cua amin va aminoaxit?
H: Em hay cho biet nhng tnh
I. KIEN THC CAN NH
1. Cau tao phan t
R - NH
2
R CH COOH
NH
2

Amin o - amino axit
H
2
N CH

CO .... NH CH COOH
R
1
R
n
Peptit
2. Tnh chat
a) Tnh chat cua nhom NH
2
- Tnh baz : RNH
2
+ H
2
O [RNH
3
]
+
OH
-

RNH
2
+ HCl [RNH
3
]
+
Cl
-

b) Amino axit co tnh chat cua nhom COOH
- Tnh axit: RCH(NH
2
)COOH + NaOH
RCH(NH
2
)COONa + H
2
O
- Phan ng este hoa
RCH(NH
2
)COOH + ROH
HCl

RCH(NH
2
)COOR + H
2
O
c) Amino axit co phan ng gia nhom COOH
va NH
2

Tao muoi noi (ion lng cc) :
H
2
N - CH(R) - COOH H
3
N
+
- CH(R) - COO
-

Phan ng trung ngng cua cac c - va e
- amino axit tao poliamit:

chat giong nhau gia anilin va
protein? Nguyen nhan cua s
giong nhau ve tnh chat hoa hoc
o?

Hoat ong 2:
H: lam bai tap 1,2
H: Giai bai tap bang phng
phap t luan, chon phng an
ung khoanh tron.
Gv va hs nhan xet bo sung
Hoat ong 3:
G: Cac em hay thao luan nhom
giai cac bai tap 3, 4,5 SGK
G: Goi 3 em hoc sinh ai dien 3
nhom len bang giai 3 bai tap
tren.
Gv va hs nhan xet bo sung
nH
2
N - [CH
2
]
5
- COOH
t
( NH - [CH
2
]
5
CO
)
n
+ nH
2
O
d) Proteinco phan ng cua nhom peptit CO
- NH

e) Anilin co phan ng the de dang 3
nguyen t cua vong benzen

NH
2
+
3Br
2

Br
Br
NH
2
+ 3HBr
Br
(dd)
(trang)
(dd)

4. Cng c, dn d
Chuan b kien thc chng polime
5. H-ng dn v nh
Bai tap 1,2 sgk trang 58
Bai tap3, 4,5 sgk trang 58


Ngy son 20/10/2009
Tit 19 Ch-ng 4. polime v
vt liu polime
Bi 13. i c-ng v polime
-------------------
I. Mc tiu bi hc
1. Kin thc
- HS bit: Biet c khai niem chung ve polime :nh ngha, phan loai, cau
truc, tnh chat.
- HS hiu: Hieu phan ng trung hp, trung ngng va nhan dang c polime
e tong hp c polime.

2. K nng
Phan loai, goi ten cac polime.
So sang phan ng trung hp vi phan ng trung ngng,
Viet phng trnh phan ng tong hp ra cac polime.

3. Tnh cm, thi

II. Trng tm
Tnh cht ho hc ca polime.
III. Chun b
Gio vin: Nhng bang tong ket s o, hnh ve lien quan en tiet hoc.
He thong cau hoi cua bai.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1
G: Em hay tm hieu SGK va cho biet the
nao la polime?

H: oc sgk va cho mot vai v du ve
polime

G: Cac em hay nghien cu SGK va cho
biet cach phan loai polime?
H: Cho vd minh hoa ve polime nao thuoc
polime thien nhien, polime tong hp, ban
tong hp.

Hoat ong 2
H: oc sach giao khoa trang 60, rut ra
kien thc quan trong ve ac iem cau
truc polime

I- KHAI NIEM

Polime la nhng hp chat hu c
co khoi lng phan t rat ln do
nhieu v c so (goi la mach xch) lien
ket vi nhau tao nen.
Vd: PE, Tinh bot...
Phan loai:

Thien nhien

Polime Tong hp( trung hp, trung
ngng)

Ban trung hp

II. AC IEM CAU TRUC
Cac polime thien nhien va tong hp co
the co 3 dang cau truc c ban:
- Dang mach thang : PE, PVC,
xenluloz
- Dang phan nhanh: amilopectin cua
tinh bot...
- Dang mang li khong gian:
VD: Cao su lu hoa (cac mach thang trong

H: oc sach giao khoa trang 61, rut ra
kien thc quan trong ve l tnh polime.

Hoat ong 3
H: Viet ptp the hien cac tnh chat hoa
hoc cua polime
Phan cat, gi nguyen va tang mach
polime.
H: Chon v du minh hoa.

cao su lu hoa gan vi nhau bi nhng
cau noi isunfua SS).
III. TNH CHAT VAT L
- Cac polime la nhng chat ran,
khong bay hi, t
0
nc
co khoang kha rong.
- a so polime khong tan trong cac
dung moi thong thng.
- Nhieu polime co tnh deo (PE,
PVC) co tnh an hoi (cao su), cach
nhiet, cach ien(PE, PVC..).
IV.TNH CHAT HOA HOC:
1. Cac p phan cat mach polime :
- Phan ng thuy phan: Tinh bot,
xenluloz
- P nhiet phan(giai trung hp)
2. Cac phan ng gi nguyen mach
polime : o la phan ng the va cong
vao mach polime.
3. Cac phan ng lam tang mach polime
phan ng khau mach cacbon.

4. Cng c, dn d
Phng phap ieu che Polime
Hay cho biet cong thc cau tao cac polime : PE; PVC; PP; PVA.
Tnh chat cac polime?
Viet phan ng tao : Cao su Buna-S; Cao su Buna-N; Thuy tinh hu c.
5. H-ng dn v nh
Bai tap 1-6 sgk trang 64


Ngy son 22/10/2009
Tit 20
Bi 13. i c-ng v polime
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Biet c khai niem chung ve polime :nh ngha, phan loai,
cau truc, tnh chat.
HS hiu: Hieu phan ng trung hp, trung ngng va nhan dang c
polime e tong hp c polime.

2. K nng

II. Trng tm
Cc loi p- ca polime.
III. Chun b
Gio vin: H thng cu hi.
IV. Ph-ng php

V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ha hc ca polime?
3. Cc hot ng dy hc
Hot ng ca gio vin
v hc sinh
Ni dung kin thc
Hoat ong 1
G: Em hay cho biet phan ng
nao co the ieu che c
polime t monome?

H: Nh vay, ieu kien ve cau
tao monome tham gia phan ng
trung hp la phai co noi oi.

H: Viet phng trnh phan ng

G: Gii thieu phan ng trung
ngng hoac xay ra gia 2 loai
monome co cau tao khac nhau,
hoac t cung mot loai monome.
Nh vay, ieu kien can ve
cau tao monome tham gia phan
ng trung ngng la phai co t
2 nhom chc tr len trong
phan t .
H: Viet ptp.

H: oc sgk
V- ieu che polime : 2pp.
1. Phan ng trung hp:
Phan ng trung hp la qua trnh cong lien
hp lien tiep nhieu phan t nho (monome)
giong nhau hay tng t nhau thanh phan t ln
(polime).

ieu kien can ve cau tao monome
Phn t phi c lin kt bi CH
2
CH
2
, CH
2
CHC
6
H
5
,...
Phn t l vng khng bn CH
2
CH
2
O

VD:
nCH
2
=CH
P t xt , ,
0
(CH
2
CH)
n
| | PVC
Cl Cl

2. Phan ng trung ngng:
Phan ng trung ngng la qua trnh cong hp
lien tiep nhieu phan t nho thanh phan t
ln ong thi tao ra nhng phan t nho
(H
2
O0

n HOOC C
6
H
4
COOH + n HO CH
2
CH
2
OH
t
0

(
CO C
6
H
4
COO C
2
H
4
O )
n
+ 2n H
2
O

iu kin cn v cu to ca monome tham gia phan
ng trung ngng la trong phan t phai co t nhat
hai nhom chc co kha nang phan ng tr len.
VD:
HOOC C
6
H
4
COOH, HO C
2
H
4
OH

VI. NG DUNG
Polime co nhieu ng dung nh lam cac loai vat
lieu polime phuc vu cho cuoc song: Chat deo, t si,
cao su, keo dan

4. Cng c, dn d
c im ca phn ng trng hp v trng ng-ng?
5. H-ng dn v nh
Bi tp trong SGK.

Ngy son 25/10/2009
Tit 21
Bi 14. vt liu polime
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Biet khai niem ve cac vat lieu: chat deo, cao su, t, si va keo dan.
Biet thanh phan, tnh chat, ng dung cua chung.
HS hiu: Hieu phan ng trung hp, trung ngng va nhan dang c polime e
tong hp c polime.
2. K nng
a. So sanh cac vat lieu.
b. Viet phng trnh phan ng hoa hoc tong hp ra cac vat lieu tren.
c. Giai cac vat bai tap ve vat lieu polime.
3. Tnh cm, thi
II. Trng tm
III. Chun b
Gio vin: Chuan b cac vat lieu polime: chat deo, cao su, t, si va keo dan.
Cac tranh anh , hnh ve, t lieu, lien quan en bai hoc.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp

2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1
Gv yeu cau:
Hs nghien cu SGK cho biet nh ngha
chat deo.
Hs cho biet tnh deo la g?

Hs: Tm hieu SGK va cho biet thanh
phan cua vat lieu mi(compozit) va
nhng thanh phan phu them cua chung.

Hoat ong 2
Hs: Lien he kien thc a hoc xac nh
cong thc cua cac polime sau: PE, PVC,
thuy tinh hu c, PPF.
Gv: T CT tren hs xac nh monome tao ra
cac polime tren.
Hs: Viet ptp ieu che
Hs: Tham khao sgk e nam tnh chat, ng
dung cua cac polime.

A- CHAT DEO:
I- Kh niem ve chat deo va vat lieu
compozit
Chat deo la nhng vat lieu polime
co tnh deo.
Tnh deo la nhng vat the b bien
dang khi chu tac dung nhiet o va ap
suat va van gi nguyen s bien dang
o khi thoi tac dung.
VD: PE, PVC, Cao su buna ...
Thanh phan compozit:
1- Chat nen (Polime): Nha nhiet deo hay
nha nhiet ran.
2- Chat on: Si hoac bot
3- Chat phu gia
II - Mot so hp chat polime dung lam
chat deo:
1- Polietilen (PE)
nCH
2
= CH
2
(-CH
2
- CH
2
-)
n

2- Polivinylclorua (PVC)
nCH
2
= CH (-CH
2
- CH -)
n

Cl Cl
3- Polimetyl meta crylat (Thuy tinh hu
c)
COOCH
3

nCH
2
= C - COOCH
3
(-CH
2
-C-)
n

CH
3
CH
3

4- Nha phenol fomandehit:
SGK
5- Polistiren:
nCH = CH
2
(-CH - CH
2
-)
n
C
6
H
5
C
6
H
5

4. Cng c, dn d
- Phan ng ieu che chat deo, ieu che cac loai t
- T Xenluloz hay viet phng trnh phan ng ieu che nha PE, PP,
PVC,

- T CaCO
3
va cac chat vo c can thiet ieu che nha
phenolfomandehit.
5. H-ng dn v nh
Bai tap 1-6 sgk trang 64

Ngy son 30/10/2009
Tit 22
Bi 14. vt liu polime
-------------------
I. Mc tiu bi hc
1. Kin thc
- HS bit: Biet c khai niem chung ve polime: nh ngha, phan loai, cau
truc, tnh chat.
- HS hiu: Hieu phan ng trung hp, trung ngng va nhan dang c polime
e tong hp c polime.
2. K nng

3. Tnh cm, thi
II. Trng tm
III. Chun b
Gio vin Nhng bang tong ket s o, hnh ve lien quan en tiet hoc.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c

3. Cc hot ng dy hc
sinh
Ni dung kin thc

GV yeu cau HS neu khai niem.

HS lay VD mot so vat lieu bang t
GV thong bao

GV hng dan hoc sinh viet phng trnh
phan ng ieu che t nilon-6,6; t nitron

GV thong bao

GV hng dan hoc sinh viet phng trnh
phan ng ieu che.
B- T
I. Khai niem
T la nhng polime hnh si dai va
manh vi o ben nhat nh.
Polime dung lam t tng oi ben vi
nhiet va vi cac dung moi thong
thng: mem, dai, khong oc va co kha
nang nhuom mau
II.Phan loai
1- T t nhien: T tam, si, bong, len
2- T hoa hoc: ieu che t phan
ng hoa hoc.
a- T nhan tao: T vat lieu co
san trong t nhien va che bien bang
phng phap hoa hoc.
VD: Xenluloz.
b- T tong hp: T cac polime
tong hp
III-Vai loai t tong hp thng gap
Xem sgk trang 68-69
C- CAO SU THIEN NHIEN VA CAO
SU TONG HP
I. nh ngha
Cao su la loai vat lieu polime co tnh an
hoi
II. Cao su thien nhien
Cao su thien nhien lay t mu cua cay
cao su
III. Cao su tong hp
D-KEO DAN TONG HP
1.Khai niem
La loai vat lieu co kha nang ket dnh 2
manh vat lieu giong nhau hoac khac nhau
ma khong lam bien chat cac vat lieu c
ket dnh.
2.Mot so loai keo dan tong hp thong
dung
a. Nha va sam
b.Keo dan epoxi
c.Keo dan ure fomanehit
4. Cng c, dn d
- Phan ng ieu che chat deo, ieu che cac loai t

PVC,
- T CaCO
3
phenolfomandehit..
5. H-ng dn v nh
Bai tap 1-6 sgk trang 72,73.

Ngy son 31/10/2009
Tit 23
Bi 16. THC HNH: MT S TNH CHT CA
PROTEIN V vt liu polime
-------------------
I. Mc tiu bi hc
1. Kin thc
Cng c nhng tnh cht c tr-ng ca protein v vt
liu polime.
2. K nng
S dng dng c, ho cht tin hnh thnh cng mt
s th nghim v tnh cht ca polime v vt liu
polime thng gp.
3. Tnh cm, thi
II. Trng tm
Tnh cht ho hc ca protein v vt liu polime.
III. Chun b
Gio vin: Dng c: ng nghim, bt s nh, a thy tinh,
ng thy tinh, nt cao su, gi th nghim.
Ha cht: Cc dd CuSO
4
, NaOH, AgNO
3
, HNO
3
, mu PVC,
si len.
IV. Ph-ng php
V. Ni dung ln lp

1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1
GV hng dan HS cach lay long
trang trng va cac thao tac thc
hanh

Hoat ong 2
GV hng dan HS lam t/n 2
Lu y: khong lay CuSO
4
qua nhieu

Hoat ong 3

Hoat ong 4
GV hng dan hoc sinh lam t/n 4
phai can than v co nhieu giai oan
phc tap

Th nghiem 1
S ong tu protein khi un nong
Cho vao ong nghiem 2-3 ml dd long
trang trng un soi 5 phut
Quan sat hien tng va giai thch.
Th nghiem 2
Phan ng mau biure
Cho vao ong nghiem 1ml dd protein +
1ml dd NaOH 30% + 1g CuSO
4
.
Quan sat hien tng. Giai thch.
Th nghiem 3.
Tnh chat cua mot vai vat lieu
polime khi un nong.
Dung 4 kep sat kep 4 mau vat
lieu:P.E, PVC,si len, vai si
xenluloz. H cac vat gan ngon la
vai phut.
Quan sat hien tng, giai thch?
ot. Quan sat, mui, giai thch?
Th nghiem 4
Phan ng cua vai vat lieu polime
vi kiem.
Cho vao 4 ong nghiem 1,2,3,4, mau
PE, PVC,si len, si xen luloz, sau o
them vao 2ml dd NaOH 10%,un soi,
e nguoi, Lay dd thu c cho vao
1' ; 2'; 3'; 4'. Sau o axit hoa 1'; 2',bang
dd HNO
3
10% vacho vao 3'; 4' vai giot
dd NaOH 10%.
Quan sat va un nong en soi.
Quan sat hien tng giai thch.
4. Cng c, dn d
PVC,
- T CaCO
3
phenolfomandehit..
5. H-ng dn v nh
Hs chuan b cac bai tap trong bai luyen tap.


Ngy son 01/11/2009
Tit 24
Bi 15. luyn tp: POlime V vt liu
polime
-------------------
I. Mc tiu bi hc
1. Kin thc
Cng c nhng tnh cht c tr-ng ca protein v vt
liu polime.
Cung co khai niem ve cau truc va tnh chat cua polime
2. K nng
S dng dng c, ho cht tin hnh thnh cng mt
s th nghim v tnh cht ca polime v vt liu
polime thng gp.
So sanh cac loai vat lieu chat deo, cao su, t va keo dan.
- Viet cac phng trnh hoa hoc tong hp ra cac vat lieu.
- Giai cac bai tap ve cac hp chat cua polime

3. Tnh cm, thi
II. Trng tm
Tnh cht ho hc ca polime v vt liu polime.
III. Chun b
Gio vin: Chuan b he thong cac cau hoi ve l thuyet.

Chon cac bai tap chuan b cho tiet luyen tap.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1:
GV: Yeu cau hoc sinh:
- Hay neu nh ngha polime. Cac khai niem
ve he so polime hoa.
- Hay cho biet cach phan biet cac polime.
- Hay cho biet cac loai phan ng tong hp
polime. So sanh cac loai phan ng o?

GV: Em hay cho biet cac dang cau truc
phan t cua polime, nhng ac iem cua
dang cau truc o?

Hoat ong 2:
GV: Em hay cho biet tnh chat vat l ac
trng cua polime?

HS: Cho biet cac loai phan ng cua polime,
cho v du, cho biet ac iem cua cac loai
phan ng nay?

I- KIEN THC CAN NH
1. Khai niem ve polime
Polime la nhng hp chat co phan t
khoi rat ln do nhieu n v nho goi la
mat xch lien ket vi nhau tao nen.
- So mat xch (n) c goi la he so polime
hoa hay o polime hoa.
- Theo nguon goc, ta phan biet polime thien
nhien, polime tong hp, polime nhan tao (ban
tong hp).
- Theo phan ng polime hoa, ta phan biet
polime trung hp va polime trung ngng.
2. Cau truc
- Phan t polime co the ton tai dang
mach khong phan nhanh, dang mach phan
nhanh va dang mach phan gian.
- Phan t polime co the co cau tao ieu
hoa (neu cac mat xch noi vi nhau theo
mot trat t xac nh) va khong ieu hoa
(neu cac mat xch noi vi nhau khong theo
mot trat t nao ca)
3. Tnh chat
a) Tnh chat vat l
Hau het cac polime la chat ran, khong bay
hi, khong co nhiet o nong chay xac
nh, mot so tan trong cac dung moi hu c.
a so polime co tnh deo; mot so polime
co tnh an hoi, mot so co tnh dai, ben,
co the keo thanh si.
b) Tnh chat hoa hoc
Co 3 loai phan ng
Phan ng gi nguyen mach polime : Phan
ng cong vao lien ket oi hoac thay the

Hoat ong 3:
Neu cac phng phap ieu che polime?
Ke ten cac vat lieu polime? Tnh chat
cac vat lieu nay?

Hoat ong 4:
GV: Goi hs giai cac bai tap 4,5,6/104 sgk

cac nhom chc ngoai mach.
Th du :
( CH
2
- CH )
n
+ nNaOH
O H
2

OH
( CH
2
- CH )
n
+ nCH
3
COONa
OCOCH
3

Phan ng cat mach polime : polime co the
b giai trung hp nhiet o cao. Polime co
nhom chc trong mach nh -CO-NH-, -
COOCH
2
- de b thuy phan khi co mat axit
hay baz.
Phan ng khau mach polime : Phan ng
tao cau noi gia cac mach (cau -S-S- hay -
CH
2
-) thanh polime dang khong gian hoac
phan ng keo dai them mach polime.
4. ieu che
a) Trung hp
b) Trung ngng
5 . Khai niem ve cac vat lieu polime
- Chat deo : vat lieu polime co tnh deo.

T : vat lieu polime hnh si dai va manh.

Cao su: vat lieu polime co tnh an hoi. Keo
dan hu c : vat lieu polime co kha nang
ket noi hai manh vat lieu khac.

Vat lieu compozit : vat lieu gom polime lam
nha nen to hp vi cac vat lieu vo c,
hu c khac.
II- BAI TAP (Sgk)
4. Cng c, dn d
- Hs gii bi tp trong SGK cng c tnh cht polime.
5. H-ng dn v nh
Hs chuan b ni dung n tp kim tra 1 tit.


Ngy son 07/11/2009
Tit 25
kim tra 1 tit
-------------------
I. Mc tiu bi hc
1. Kin thc
Hs nm -c kin thc trong ch-ng 1, ch-ng 2.
2. K nng
II. Trng tm
Tnh cht ho hc ca amino axit v polime.
III. Chun b
Gio vin: thi v p n
IV. Ph-ng php
Hnh thc kim tra: T lun.
V. bi
Cau 1(3): Axit amino axetic phan ng c vi nhng dung dch nao trong cac dung
dch HCl, KOH, K
2
SO
4
, C
2
H
5
OH. Viet phng trnh phan ng xay ra va ghi ro ieu
kien neu co.
Cau 2(3): T tinh bot va cac chat vo c can thiet khac. Hay viet s o va
phng trnh phan ng ieu che ra: PE, cao su buna.
Cau 3(4): Cho 10,3 gam 1 amino axit no (trong phan t ch cha mot nhom NH
2
va
mot nhom COOH) tac dung vi dung dch HCl d ta thu c dung dch A trong o

co cha 13,95 gam muoi. Xac nh CTPT cua amino axit.Tnh the tch dung dch
NaOH 1M u tac dung vi dung dch A. Biet HCl a lay d 25% so vi lng can
thiet.
VI. p n, thang im
Cu 1. Mi pt ng -c 0,7
H
2
N - CH
2
- COOH
Tc dng vi HCl, KOH, C
2
H
5
OH
Cu 2. Mi pt -c 0,5
Tinh bt thy phn cho glucoz
Glucoz ln men gim cho ancol etylic
Ancol etylic hirat ha cho etilen
Trng hp etilen cho PE
Etilen tc dng vi clo t l 1:1, nh sng
Cng hp 1-clo etylen v Na
Trng hp buta-1,3-ien, Na xc tc.
Cu 3. 4
Hs vit -c CTPT NH
2
-C
n
H
2n
-COOH
Vit pthh, da vo t l tnh -c n = 3
S mol HCl phn ng.


Ngy son 15/11/2009
Tit 26 Ch-ng 5. i c-ng v kim
loi
Bi 17. v tr ca kim loi trong bth v
cu to ca kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc
- Biet v tr cua cac nguyen to kim loai trong bang tuan hoan.
- Hieu c nhng tnh chat vat l va tnh chat hoa hoc cua kim loai.
2. K nng
Biet van dung l thuyet chu ao e giai thch nhng tnh chat cua kim
loai.
Dan ra nhng phan ng hoa hoc va th nghiem hoa hoc chng minh cho
nhng tnh chat hoa hoc.
Biet cach giai cac bai tap trong SGK.
3. Tnh cm, thi
Rn luyn cho HS pht trin t duy v khng gian.
II. Trng tm
Cu to kim loi, v tr kim loi trong BTH.
III. Chun b
Gio vin:
- Chuan b mot so th nghiem chng minh cho tnh kh cua kim loai:
+ Dung cu: ong nghiem c nho, ong nho giot, en con.
+ Hoa chat: cac kim loai Al, Cu, Fe ( inh sat sach), Na, Mg, cac phi kim:
kh O
2
, Cl
2
; cac axit: ddH
2
SO
4
loang va H
2
SO
4
ac, dung dch HNO
3
, dd
muoi CuSO
4
.
- Chuan b tranh ve 3 loai mang tinh the cua kim loai: mang tinh the lap
phng tam khoi, mang lap phng tam dien va mang luc phng trong SGK hoa hoc
10.

IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
sinh
Ni dung kin thc

GV hi: cho bit v tr ca kim loi trong bng
tun hon?

GV hi: Cho bit cu to nguyn t kim loi?
HS: Nguyn t kim loi hu ht c t electron
lp ngoi cng.
Trong cng mt chu k nguyn t kim loi c
bn knh nguyn t ln hn bn knh nguyn
t phi kim
GV yu cu HS nghin cu SGK v cho bit
ta thng gp nhng cu trc mng tinh th
no trong kim loi

GV hi: Mng tinh th lc phng l g?

GV: Mng tinh th lp phng tm din l g?
I. V TR CA KIM LOI TRONG H
THNG TUN HON
Cc nguyn t ho hc c phn thnh kim
loi v phi kim.
Nhm IA(tr hiro), nhm IIA, nhm IIIA, v
mt s nguyn t nhm IA, VA, VIA.
Nhm B
H lantan v actini
II. CU TO CA KIM LOI
1. Cu to nguyn t
Nguyn t kim loi hu ht c t electron lp
ngoi cng.
Trong cng mt chu k nguyn t kim loi c
bn knh nguyn t ln hn bn knh nguyn t
phi kim

2. Cu to tinh th
Trong tinh th kim loi, nguyn t v ion kim
loi nm nhng nt mng tinh th. Cc
electron ho tr lin kt yu vi ht nhn
nguyn t nn d tch ra khi nguyn t v
chyn ng t do trong mng tinh th.
a) Mng tinh th lc phng

Thuc loi ny c cc kim loi: Be, Mg, Zn
b) Mng tinh th lp phng tm din
nguyn t v ion kim loi
chim 74% cn li l rng
chim 26%

GV hi: Cu trc mng tinh th lp phng
tm khi l g?

T cc cu trc mng tinh th ca kim loi
trn yu cu HS so snh c kht ca cc
kiu mng tinh th.

GV: Gii thieu lien ket kim loai
HS: oc nh ngha sgk

Thuc loi ny c cc kim loi: Cu, Ag, Al,
c) Mng tinh th lp phng tm khi
th tch cc nguyn t chim 68% cn li l
khong trng chim 32%

3. Lien ket kim loai
La lien ket c hnh thanh
gia cac ng.t va ion kim loai
trong mang tinh the do s tham gia
cua cac e t do.

4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li cu to nguyn t ca kim loi v s nh
hng ca cu to n tnh cht ho hc ca kim loi. T lin h bi hc sau.
5. H-ng dn v nh
HS lam bai tap 1-9 trong SGK trang 82.

th tch cc nguyn t
chim 74% cn li l
khong trng chim
26%

Ngy son 23/11/2009
Tit 27
Bi 18. tnh cht ca kim loi.
dy in ha ca kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc
- Biet c nhng tnh chat vat l va tnh chat hoa hoc cua kim loai.
- Hieu c nhng tnh chat vat l va tnh chat hoa hoc cua kim loai.
2. K nng
loai.
3. Tnh cm, thi
Rn luyn cho HS pht trin t duy v khng gian.
II. Trng tm
Tnh cht vt l ca kim loi.
III. Chun b
Gio vin: Chun b ni dung bi dy.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by c im cu to nguyn t v cu to tinh
th kim loi?

3. Cc hot ng dy hc
sinh
Ni dung kin thc
GV: Yeu cau hoc sinh nhac lai tnh chat
vat ly cua kim loai a hoc lp 9
GV: bo sung: deo, dan ien, dan nhiet
va anh kim.
The nao la tnh deo? Cho vd.

GV: Giai thch tnh deo cua kim loai do
cac e t do.

Tnh dan ien la g ? Cho vd va cho biet
nhng ng dung cu the cua no trong
i song va SX ?
GV: Yeu cau hoc sinh kha giai thch v
sao kim loai dan ien c.
Gi y: Dong ien la g?
- Do cac kim loai khac mat o e t do
khac
- Khi nhiet o tang cac Ion (+) dao
ong ln can tr s chuyen ong
cac e t do.
Tnh dan nhiet la g ? ng dung cua
chung.
Theo em nhng kl nao co tnh dan ien
tot ? V sao.
Tinh dan nhiet cua kl t le thuan vi
tnh dan ien: Ag, Cu, Al, Zn, Fe,...

Anh kim la g ? Cho vd.

V sao kl co nhng t/c vat l chung nh
tren ?
Hay neu nhng t/c vat l khac cua kl ?

Nh nht Cs (d=0,5 g/cm
3
)
Nng nht Os (d=22,6g/cm
3
)

- Khoi lng, o cng, nhiet o nong
chay cua cac kim loai co giong nhau hay
I. TNH CHT VT L
* Tnh cht vt l chung
1. Tnh deo:
Khi tac dung mot lc u manh len
mot vat bang KL no b bien dang.
Nguyen nhan: Khi tac dung mot lc th
cac mang tinh the trt len nhau, nhng
nh cac e t do chuyen ong qua lai
gia cac lp mang ma chung khong
tach ri nhau.
2. Tnh dan ien:
- Noi au KL vi 1 nguon ien th kim
loai cho dong ien chay qua.
Do cac e t do chuyen ong thanh dong.
Lu y:
+ Cac KL khac nhau th chung dan ien
khac nhau.
+ Khi nhiet o cang cao th kha nang
dan ien cang giam.

3. Tnh dan nhiet:
Khi KL b un nong cac e t do chuyen
ong nhanh va cham vao cac Ion(+) va
truyen nang lng cho cac Ion co nang
lng thap hn.

4. Anh kim:
Cac e t do co kha nang phan xa cac
anh sang va bc song ma mat nhn
thay c.
Ket luan: Cac e t do la thanh phan c
ban gay nen tnh chat vat ly chung cua
kim loai.
* Tnh chat vat ly rieng cua kim loai:
1- T khoi: Cac KL co ty khoi khac
nhau (nang, nhe khac nhau)
d<5 kim loai nhe.
VD: K, Na, Mg, Al
d>5 kim loai nang
VD: Fe, Pb, Ag
2- o cng:
Cac kim loai co o cng khac nhau
Kim loai mem: Na, K

khong?

Kim loai cng: Cr, W
3- Nhiet o nong chay:
Cac kim loai co nhiet o nong chay
khac nhau
VD: t
0
nc W = 3410
0C
t
0
nc Hg = -39
0C

Nguyen nhan do: R = va Z + khac

4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li tnh cht vt l ca kim loi.
- Qua tnh chat vat ly chung cua kim loai hay cho biet yeu to nao gay ra tnh chat
vat ly chung cua kim loai?
5. H-ng dn v nh
HS lam bai tap 1 trong SGK trang 88.


Ngy son 28/11/2009
Tit 28
dy in ha ca kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc
- Biet c nhng tnh chat vat l va tnh chat hoa hoc cua kim loai.
- Hieu c nhng tnh chat hoa hoc cua kim loai.
2. K nng
loai.
3. Tnh cm, thi
II. Trng tm
Tnh cht hh ca kim loi.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by c im tnh cht ca kim loi? Gii thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc

ac iem ve cau tao cua ngt kim loai:
+ Ban knh ngt tng oi ln so vi
ngt phi kim.
II. TNH CHAT HOA HOC CHUNG
CUA KIM LOAI:
Kim loai de nhng e
M - ne = M
n+


+ So e hoa tr thng t (t 1 en 3e),
lc lk vi hat nhan cua nhng ion nay
tng oi yeu.
Nang lng can dung e tach cac
e ra khoi ngt kl (nang lng ion hoa) la
nho.

Yeu cau hoc sinh nhan xet khi kim loai
tac dung vi axit thong thng, sau o
cho v du.
Phan nay giao vien yeu cau hoc sinh
cho biet san pham tao thanh khi kim loai
tac dung tng loai axit nay.

- Giao vien lu y cho hoc sinh
Vay e chuyen ch axit ac t nha
may san xuat en ni tieu thu ngi ta
dung bnh g e ng.

Giao vien bieu dien TN: Fe + dd CuSO
4

cho hoc sinh quan sat va nhan xet hien
tng
- Viet phng trnh phan ng va giai
thch.
kim loai the hien tnh kh manh nen
tac dung vi chat oxi hoa ((PK, dd axit,
dd muoi)

1- Tac dung vi PK: (O
2
, Cl, S, P ...)
a- Vi oxi oxit KL
4M + nO
2
2M
2
O
n

VD: 2Al + 3/2 O
2
Al
2
O
3

b-Tac dung vi phi kim khac Muoi
khong co oxi
Cu + Cl
2
CuCl
2

2Fe + 3Cl
2
2FeCl
3
2- Tac dung vi axit:
Axit thong thng: HCl, H
2
SO
4

KL HCl muoi + H
2

H
2
SO
4

K: KL ng trc Hidro
- Trong muoi KL co mc oxi hoa thap
VD: Fe + 2HCl FeCl
2
+ H
2

Fe + H
2
SO
4
l FeSO
4
+ H
2

b- Vi axit co tnh oxh manh HNO
3
, H
2
SO
4

SO
2

M + H
2
SO
4
M
2
(SO
4
)n + S +
H
2
O
H
2
S
NO
2

NO
M + HNO
3
M(NO
3
)n + N
2
O +
H
2
O
N
2

NH
4
NO
3

Lu y: Tr Au, pt
- Kim loai trong muoi co mc oxh cao
nhat
- Fe, Al, Cu khong tac dung HNO
3
, H
2
SO
4
ac
nguoi
- HNO
3
ac NO
2

VD: Fe + 4HNO
3
Fe(NO
3
)
3
+ NO + 2H
2
O
3- Tac dung vi dung dch muoi:
a- TN: Cho Fe + dd CuSO
4

Hien tng: Cu co mau o bam vao Fe
Dung dch co mau xanh luc
PTPU: Fe + CuSO
4
FeSO
4
+ Cu
Fe + Cu
2+
Fe
2+
+ Cu

b- TN: Cu + dd AgNO
3

Hien tng: Ag tao thanh bam vao Cu
Dd co mau xanh tham
PTPU: 2AgNO
3
+ Cu Cu(NO
3
)
2

+ 2Ag
2Ag
+
+ Cu Cu
2+
+ 2Ag
Nhan xet:
Kim loai ng trc co the ay kim loai
ng sau ra khoi dung dch muoi cua no.
Lu y: Tr kim loai tac dung c vi
nc nh: Na; K; Ca; Ba

4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li tnh cht ha hc ca kim loi.
Ti sao kim loi c tnh cht nh vy?
5. H-ng dn v nh
HS lam bai tap 2-6 trong SGK trang 88, 89.

Ngy son 30/11/2009
Tit 29
dy in ha ca kim loi

-------------------
I. Mc tiu bi hc
1. Kin thc
+Hieu c s cua s thanh lap day ien hoa cua kl.
+ Nam trnh t cac cap oxi hoa kh trong day.
+ Hs nam c chieu cua p hh gia cac cap oxi hoa kh.
2. K nng
3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by c im tnh cht hh ca kim loi? Gii
thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc

Goi hs viet cac pt cho e va cho biet chat
kh, chat oxi hoa ?

Hd cho hs viet pt p va rut ra ket luan ?
Cho hs thc hien tng t nh tren ?
T 2 trng hp tren, hay rut ra ket
luan chung ?

III. DY IN HA CA KIM LOI
1. Cap oxi hoa kh cua kl:
Fe
2+
+ 2e Fe
Ag
+
+ e Ag
Chat oxi hoa Chat kh
Fe
2+
/ Fe ; Ag
+
/ Ag; ... tao nen cap oxi
hoa kh.
2. So sanh t/c nhng cap oxi hoa kh:
a. Fe
2+
/ Fe va Cu
2+
/ Cu:
Fe + Cu
2+
Fe
2+
+ Cu
Fe
2+
: la ion co t/c oxi hoa yeu
hn ion Cu
2+

Fe : la kl co t/c kh manh hn Cu.
b. Cap Cu
2+
/ Cu va Ag
+
/ Ag:
Cu + 2Ag
+
Cu
2+
+ 2Ag

Hd cho hs neu /n.

Goi hs neu lai day hoat ong hoa hoc
cua kl?

Goi hs viet cac pt p c/minh ?
Trnh bay qui tac o

Cu
2+
la ion co t/c oxi hoa yeu hn
ion Ag
+
.
Cu la kl co t/c kh manh hn Ag.
Kl: T/c oxi hoa cua ion: Fe
2+
< Cu
2+
<
Ag
+

T/c kh cua kl: Fe > Cu > Ag
c. Mot so cap oxi hoa kh khac:
Sgk.
3. Day ien hoa cua kim loai:
a. /n: La 1 day nhng cap oxi hoa
kh c sap xep theo chieu tang t/c oxi
hoa cua cac ion kl va chieu giam t/c
kh cua kl.

K
+
Na
+
Mg
2+
Al
3+
Zn
2+
Fe
2+
Ni
2+
Sn
2+
Pb
2+
2H
+

Cu
2+
Hg
2+
Ag
+
Pt
2+
Au
3+

K Na Mg Al Zn Fe Ni Sn Pb H
2

Cu Hg Ag Pt Au
T/c oxi hoa cua ion kl tang. T/c kh
cua kl giam
b. Y ngha: D/oan c chieu cua p
gia hai cap oxi hoa kh.
4. Cng c, dn d
- GV h thng li bi hc dy in ha ca kim loi.
5. H-ng dn v nh
HS lam bai tap 7, 8 trong SGK trang 89.

Ngy son 03/12/2009
Tit 30
Bi 22. luyn tp tnh cht ca kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc

+Cung co kien thc ve cau tao nguyen t kim loai, n chat kim loai
va lien ket kim loai.
+Giai thch c nguyen nhan gay ra cac tnh chat vat l chung va tnh
chat hoa hoc ac trng cua kim loai.
2. K nng
Ren luyen cho HS cac k nang:
Viet Che nguyen t cua cac nguyen to kim loai.
Suy dien: T cau tao nguyen t kim loai va n chat kim loai suy ra tnh
chat vat l va hoa hoc cua kim loai.
Biet cach giai cac bai tap ve kim loai:
+ Bai tap nh tnh nh: nhan biet cac mau kim loai, tach kim loai ra khoi
hon hp kim loai bang pp hoa hoc.
+ Bai tap nh lng: xac nh nong o, lng chat tham gia va tao thanh
sau phan ng hoa hoc, x NTK cua kim loai.
+ Bai tap trac nghiem.
3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc

Hot ng 1. HS lp bng h thng ha kin
thc v tnh cht ca kim loi.
Hot ng 2. Khc su kin thc v cu to ca
kim loi.
G: Nguyn t kim loi c c im cu to
ntn?
G: n cht kim loi c cu to ntn?
G: Lin kt kim loi l g? So snh lin kt kim
I. Kin thc cn nh


loi vi lk ion v lk CHT.
Hot ng 3. Rn k nng vn dng kin thc
v cu to nguyn t KL gii thch tnh cht
ca kim loi.
+ G: Da vo cu to ca n cht KL, hy
gthch nguyn nhn ca tnh dn in, dn
nhit, do v c nh kim ca kim loi?
+ G: Tnh cht hh chung ca kim loi l g?
Gii thch nguyn nhn, dn ra nhng puhh c
th minh ha.
+ G: Cp oxi ha kh ca kim loi, ng
dng.
Hot ng 4. Bi tp
G gi H ln lt lm bi tp trong SGK, sau
yu cu H nhn xt, G nh gi, cho im.
Bi 1/100
Bi 2/100
Bi 3/100
Bi 6/101

Bi 7/101

Bi 8/101

Bi 9/101
Bi 10/101

II. Bi tp

B
C
C
B
Gii
S mol H
2
= = 0,5 mol
S mol H
+
= 1 mol
Trong pt HCl c c 1 mol H
+
l c 1 mol Cl
-

m mui = m kim loi + m gc axit
= 20 + 35,5 = 55,5 (g)
D
Gii
Theo pp NTK trung bnh
M = 10 g/mol
B
M
2
O
n

M = 9n
Al
D
Cu + 2AgNO
3
Cu(NO
3
)
2
+ 2Ag
Cu + 2Fe(NO
3
)
3
2Fe(NO
3
)
2
+ Cu(NO
3
)
2

Cht rn A gm Ag v Cu d.
Dd B cha cc mui Cu(NO
3
)
2
v Fe(NO
3
)
2

4. Cng c, dn d
- GV h thng li ng dng ca dy in ha ca kim loi.
5. H-ng dn v nh
HS lam li bai tap trong SGK trang 101.


Ngy son 05/12/2009
Tit 31
Bi 19. hp kim
-------------------
I. Mc tiu bi hc
1. Kin thc
HS biet:
+Khai niem ve hp kim.
+Tnh chat va ng dung cua hp kim trong cac nganh kinh te quoc
dan.

HS hieu:
+V sao hp kim co tnh chat c hoc u viet hn cac kim loai va thanh
phan cua hp kim.
2. K nng
Ren luyen cho HS cac k nang:
Suy dien: T cau tao nguyen t kim loai va n chat kim loai suy ra tnh
chat vat l va hoa hoc cua kim loai.
Biet cach giai cac bai tap ve kim loai:
+ Bai tap nh tnh nh: nhan biet cac mau kim loai, tach kim loai ra khoi
hon hp kim loai bang pp hoa hoc.
+ Bai tap nh lng: xac nh nong o, lng chat tham gia va tao thanh
sau phan ng hoa hoc, x NTK cua kim loai.
+ Bai tap trac nghiem.
3. Tnh cm, thi
II. Trng tm
Tnh cht ca hp kim.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hd cho hs neu k/ n ?
Thep la hp kim cua sat vi cacbon va
mot so nguyen to khac.
uyra la hp kim cua nhom vi ong,
mangan, magie, silic.
Vang tay : Au, Ag, Cu.
Hp kim co cau tao nh the nao ? Sau o
cho vd.

I. Khai niem:
Hp kim la chat ran thu c sau khi nung
nong chay mot hon hp nhieu kl khac nhau
hoac hon hp kl va phi kim.

II. Cau tao cua hp kim:
1. Tinh the hon hp: Nhng tinh the cua
cac n chat khi nung nong chay khong tan
vao nhau.
2. Tinh the dd ran: Nhng tinh the cua cac
n chat khi nong chay hoa tan vao nhau.
3. Tinh the hp chat hoa hoc: La tinh the

Trong hp kim co nhng loai lk hh nao ?

Hp kim co nhng t/c nao so vi n chat kl
?
Hp kim khong b an mon: Fe Cr Mn
(thep inoc)
Hp kim sieu cng: W Co; Co Cr W Fe
Hp kim co nhiet o nong chay thap: Sn
Pb (210
o
C); Bi Pb Sn (65
o
C)
Hp kim nhe, cng va ben: Al Si; Al Cu
Mn Mg.
Hp kim co nhng ng dung g ?

cua nhng hp chat hoa hoc c tao ra khi
nung nong chay cac n chat trong hon hp.
III. Lien ket hoa hoc trong hp kim:
+ Tinh the hon hp va tinh the dd ran: Lk
kim loai.
+ Tinh the hp chat hoa hoc:Lk cong hoa
tr.
IV. T/ c cua hp kim:
+ Tnh dan ien, dan nhiet: Thng kem
hn cac kl.
+ Cng va gion hn cac kl.
+ Nhiet o nong chay thng thap hn
cac kl.

V. ng dung cua hp kim: Sgk.
4. Cng c, dn d
- GV h thng li tnh cht ca hp kim.
5. H-ng dn v nh
HS lam bai tap 1 4 trong SGK trang 91.

Ngy son 10/12/2009
Tit 32
Bi 21. iu ch kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc
HS biet:
+Cac pp ieu che kim loai.
HS hieu:
+Nguyen tac chung cua viec ieu che kim loai.
2. K nng
Ren luyen cho HS cac k nang t duy: T tnh kh khac nhau cua kim loai
biet cach chon pp thch hp e ieu che kim loai.

3. Tnh cm, thi
II. Trng tm
Nguyen tac ieu che kim loai.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hot ng 1:
GV hi: Nu nguyn tc iu ch
kim loi?
HS: Kh ion d-ng kim loi
thnh nguyn t kim loi

Hot ng 2:
GV hi: ta c th dng my
ph-ng php iu ch kim
loi.
HS: 3 ph-ng php
GV hi: Nu ph-ng php nhit
luyn?
HS: Nhng kim loi c hot
ng trung bnh nh- Zn, Fe, ...
th-ng -c iu ch bng
ph-ng php nhit luyn, l kh
ion kim loi trong cc hp cht
bng cc cht kh nhit
cao bng cc cht kh mnh nh-
CO, C, H
2
hoc cc kim loi hot
ng.
GV yu cu HS ly v d.
I. Nguyn tc iu ch kim loi
Trong t nhin, ch c mt s
t kim loi tn ti trng
thi t do, hu ht cc kim
loi tn ti trng thi hp
cht. Trong hp cht kim loi
tn ti dng ion d-ng M
n+

Mun iu ch ta phi kh ion
kim loi
M
n+
+ ne M
II. Ph-ng php
Ty thuc vo hot ng ca
kim loi m ng-i ta chn
ph-ng php thch hp
1. Ph-ng php nhit luyn.
Nhng kim loi c hot ng
trung bnh nh- Zn, Fe, ...
th-ng -c iu ch bng
ph-ng php nhit luyn, l kh
ion kim loi trong cc hp cht
bng cc cht kh nhit
cao bng cc cht kh mnh nh-
CO, C, H
2
hoc cc kim loi hot
ng.
V d:

Vn dng lm bt 4/SGK
Hot ng 3:
GV hi: nu ph-ng php iu
ch kim loi bng ph-ng php
thu luyn. v sau yu cu
HS cho bit ph-ng php ny c
th iu ch kim loi no?

PbO + H
2
Pb +
H
2
O
Fe
2
O
3
+ 3CO 2Fe
+ 3CO
2

Ph-ng php ny dng iu ch
kim loi trong cng nghip
2. Ph-ng php thy luyn
Dng cc dung dch thch hp
nh- dung dch H
2
SO
4
, NaOH,
NaCN,... ha tan kim loi
hoc hp cht ca kim loi v
tch ra khi dung dch phn
khng tan c trong qung. Sau
kh nhng ion kim loi ny
trong dung dch bng kim loi
c tnh kh mnh nh- Fe, Zn,...
VD: Fe + CuSO
4

FeSO
4
+ Cu
Fe + Cu
2+

Fe
2+
+ Cu

4. Cng c, dn d
- GV h thng li nguyn tc iu ch kim loi.
C s khoa hc ca cc pp nhit luyn v pp thy luyn.
5. H-ng dn v nh
HS lam bai tap 4 trong SGK trang 98.

Ngy son 15/12/2009
Tit 33

Bi 21. iu ch kim loi
-------------------
I. Mc tiu bi hc
1. Kin thc
HS biet:
+Cac pp ieu che kim loai.
HS hieu:
+Nguyen tac chung cua viec ieu che kim loai.
2. K nng
Ren luyen cho HS cac k nang t duy: T tnh kh khac nhau cua kim loai
biet cach chon pp thch hp e ieu che kim loai.
3. Tnh cm, thi
II. Trng tm
Pp ien phan trong ieu che kim loai.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
C s khoa hc ca pp nhit luyn v pp thy luyn
trong iu ch kim loi? Gii thch?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
GV yu cu HS nhc li khi
nim s in phn.
ieu che hau het cac kl
Kl co tnh kh manh (Li Al): ien
phan nong chay muoi, kiem, oxit
(goc axit khong co oxi)

GV yu cu HS Vit ph-ng trnh
xy ra mi in cc khi in
phn nng chy Al
2
O
3
3. Ph-ng php in phn
a) in phn hp cht nng chy
Nhng kim loi hot ng ha hc
mnh -c iu ch bng ph-ng
php in phn nng chy cc hp
cht ca kim loi.
VD1: in phn nng chy Al
2
O
3

catt (-): Al
3+
+ 3e
Al
ant ( +): 2O
2--
- 2e
O
2


pnc

/che kim loai co tnh kh yeu va
trung bnh: ien phan dd muoi ma
goc axit khong co oxi.
Catot CuCl
2

Anot
(H
2
O)

Cu
2+
, H
2
O Cl
,
H
2
O
Cu
2+
+ 2e Cu
0
Cl
+ 1e
Cl
2

Pt ien phan: CuCl
2
Cu + Cl
2

H vn dng cng thc tnh
lm bi tp trong SGK.

2Al
2
O
3
4Al + 3O
2

dpnc

y l ph-ng php sn xut nhm
trong cng nghip
VD2: in phn nng chy MgCl
2

iu ch Mg
catt: Mg
2+
+ 2e
Mg
anot: 2Cl
-
- 2e
Cl
2

MgCl
2

Mg + Cl
2

b) in phn dung dch

c) Tnh lng chat thu c cac
ien cc
nh luat Faraday: m =
AIt
nF

4. Cng c, dn d
- GV h thng li nguyn tc iu ch kim loi.
C s khoa hc ca cc pp in phn?.
5. H-ng dn v nh
HS lam bai tap 1,2,3,5 trong SGK trang 98.


Ngy son 21/12/2009
Tit 34
n tp hc k i
-------------------
I. Mc tiu bi hc
1. Kin thc
HS biet:
+Noi dung on tap hoc k I.
+Cac kien thc can nh phan hoa hu c.
HS hieu:
+Khac sau kien thc a hoc.
2. K nng
Ren luyen cho HS cac k nang t duy giai toan hoa hoc hu c.
3. Tnh cm, thi
II. Trng tm
Bai tap este, aminoaxit, amin.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
G h-ng dn hc sinh n tp theo h thng cu hi sau
HNG DN N TP HC K I
Chng 1: ESTE- LIPIT
Cu 1: Este rt t tan trong nc do nguyn nhn chnh sau y:
A. Khng c tnh axit, cng khng c lien kt phn cc O H
B. Khng c H linh ng, khng to c lien kt H vi H
2
O

C. Nhm chc este COO c tnh k nc
D. C nhiu gc hidrocacbon, gia tng tnh k nc.
Cu 2: Chn pht biu sai: Este l:
A. sn phm ca phn ng este ha gia axit v ru
B. B. hp cht hu c cha nhm COO
C.Sn phm th nhm O H trong axit bng O R
(R
khc H).
D.Sn phm kh nc gia axit v ru
Cu 3: Este hu c A c thnh phn khi lng m
C
: m
O
= 9:8. CTCT A l:
A. CH
3
COO CH
3
B. (CH
3
COO)
2
C
2
H
4
C. HCOO-C
2
H
5
D. A, B, C u ng
Cu 4: S ng phn este mch h c CTPT C
4
H
6
O
2
l: A. 3 B. 5 C. 4 D. 6
Cu 5: Tn gi ca este c cu to sau:
CH
3
- CH - C - O - CH - CH
3
CH
3
O
CH
3

A. isopropylpentanonat B. propyl 2-metylpropanonat
C. isopropylisobutyrat D.2-metylpropanonat propyl
Cu 6: Cht no sau y khng phi l este:
A. isoamylaxetat B. natri axetat C. bezylbenzoat D. ety nitrat
Cu 7: Xp theo trt t tng dn nhit si: 1) CH
3
COOH 2) C
2
H
5
OH 3) HCOO-CH
3
4)
CH
3
CHO
A. 4,3,2,1 B. 3,4,2,1 C. 4,3,1,2 D. 3,4,1,2
Cu 8: Du chui trong thc phm l este c tn l:
A. axetat isoamyl B. isoamyl axetat C. metyl fomiat D. etyl
propionate

Cu 9: Phn ng thy phn este trong mi trng axit long c c im:
A. Xy ra hon ton B. Khng thun nghch C. Xy ra nhanh D. Thun
nghch
Cu 10: un nng hn hp c xc tc H
2
SO
4
gm etyl glycol, axit fomic, axit axetic, s lng
este ti a thu c l: A. 4 B. 3 C. 5
D. 6
Cu 11: Thy phn este aC
4
H
8
O
2
ta c axit X v ru Y. Oxi ha Y vi xc tc thch hp ta
c X. Este c CTCT l: A. CH
3
COO C
2
H
5
B. HCOO CH
2
CH
2

CH
3
C. C
2
H
5
COO CH
3
D.HCOOCH(CH
3
) CH
3

Cu 12: Cht hu c X (C
4
H
6
O
2
) tc dng vi dung dch NaOH, cc sn phm thu c u c
phn ng trng gng. CTCT ca X l: A. CH
2
= CH CH
2
COOH B.
HCOO- CH = CH CH
3

C. HCOO CH
2
CH = CH
2
D. HCOO C(CH
3
) = CH
2

Cu 13: t 6 gam este Y ta c 4,48 lt CO
2
(ktc) v 3,6 gam H
2
O. CTCT Y l:
A. H- COO CH
3
B. CH
3
COO CH
3
C. H COO CH = CH
2
D. H COO
C
2
H
5

Cu 14: un nng 1,1 gam este n chc no E vi dung dch KOH d, thu c 1,4 gam mui.
CTCT E l:
A. C
2
H
5
COO CH
3
B. CH
3
COO C
2
H
5
C. H COO .- CH
2
CH
2
CH
3
D. CH
3

COO CH
3

Cu 15: Thy phn hon ton 2,22 gam hn hp 2 este ng phn X, Y cn dng 30 ml dd
NaOH 1M. t chy este thu c CO
2
v H
2
O vi s mol bng nhau. CTCT ca X, Y l:
A. CH
3
CH
2
COO CH
3
, CH
3
COO C
2
H
5
B. C
3
H
7
COO CH
3
, CH
3
COO
C
3
H
7


C. CH
3
COO CH
3
, H COO CH
2
CH
3
D. CH
2
= CH COO - CH
3
, CH
3
COO
CH = CH
2

Cu 16.Chn pht biu ng
A.lipit l trieste ca glixerol vi cc axit bo
B.lipit l hp cht hu c khng tan trong nc v nh hn nc
C.cht bo l nhng hp cht hu c thuc nhm lipit
D. nhit thng, cht bo ng vt lun lun trng thi rn
Cu17. iu ch etyl axetat th cch no sau y l tt nht?
A.un hi lu hn hp etanol , gim v axit sunfuric c
B.un hi lu hn hp axit axetic v ru trng
C.un hi lu hn hp axit axetic v etanol
D.un hi lu hn hp axit axetic vi etanol v axit sunfuric c
Cu 18. Trung ha 14 gam cht bo cn 15 ml dung dch KOH 0,1 M. Ch s axit ca cht bo
l:
A. 6,5 B. 8 C. 6 D. 8,4
Cu 19. Tri lein c cng thc l:
A.
(C
17
H
31
COO)
3
C
3
H
5
B(C
17
H
29
COO)
3
C
3
H
5
C.(C
15
H
31
COO)
3
C
3
H
5
D(C
17
H
33
COO)
3
C
3
H
5

Cu 20. bin cht bo lng thnh cht bo rn ta dng phn ng no
A. Thc hin phn ng trng bc B. Cng hidro
C. Thy phn trong NaOH D. Tc dng Cu(OH)
2
un nng
Cu 21. Trung ha 10 gam mt cht bo c ch s axit l 5,6 cn m gam NaOH. Gi tr m:
A. 0,05 gam B. 0,04 gam C. 0,07 gam D. 0,06 gam
Cu 22. X phng v cht git ra c c im chung l
A. Cc mui ly c t phn ng x phng ha cht bo
B. Cha mui Natri c kh nng lm gim sc cng b mt ca cc cht bn

C. C ngun gc t ng vt hoc thc vt D. Sn phm ca cng ngh ha du
Chng 2: CACBONHIDRAT
1. Thuc th dng nhn bit c tt c dung dch trong dy sau: Glucoz. glyxerin,
fomanehyt, propanol-1? A. Dung dch AgNO
3
/NH
3
; B. Na; C. Nc brom;
D. Cu(OH)
2
/OH
-
.
2. phn bit cc dung dch cc cht ring bit: sacaroz, mantoz , etanol, fomanlin. Ngi ta
c th dung mt trong nhng ha cht sau:
A. dd AgNO
3
/NH
3
; B. Nc brom; C. Cu(OH)
2
/OH
-
; D. Tt c u sai.
3. Phn ng khng to ra etanol l:
A. Ln men glucoz ; B. Cho kh etilen tc dng vi dd H
2
SO
4
long, nng;
C. Thy phn etylclorua trong mi trng kim; D. Cho axetilen tc dng vi H
2
O/t
o
,xt.
4. Thuc th c dng nhn bit c tt c cc dung dch trong dy sau: ru etylic, ng
c ci; ng mch nha. A. dd AgNO
3
/NH
3
; B. Cu(OH)
2
; C. Na kim loi; D. dd
CH
3
COOH.
5. Saccaroz c th tc dng vi:A. H
2
/Ni, t
o
C v Cu(OH)
2
; B. Cu(OH)
2
v H
2
SO
4
c;
C. Cu(OH)
2
v AgNO
3
/NH
3
; D. H
2
/Ni, t
o
C v H
2
SO
4
c
6. phn bit cc dd cc cht ring bit: dd to xanh, dd to chn, dd KI. Ngi ta c th dung
mt trong nhng ha cht: A. O
3
; B. H tinh bt; C. Vi sa; D. AgNO
3
/NH
3
.
7. Tnh cht c trng ca saccaroz l:I/ Cht rn, tinh th, mu trng; II/ Polysaccarit;
III/ Khi thy phn to thnh glucoz v fructoz; IV/ Tham gia phn ng trng gng;
V/ Khi un nng vi H
2
SO
4
c cho cacbon. Nhng tnh cht ng l:
A. III, IV, V; B. I, III, V; C. I, II, III, IV; D. Tt c u ng.
8. Khi ln men 1 tn ng cha 65% tinh bt (hiu sut phn ng ln men l 80%). Khi lng
ru etylic thu c: A. 290 kg; B. 295,3 kg; C. 300 kg; D. 350 kg.
9. Bit hiu sut thu hi saccaroz l 80%. S kg saccaroz c th thu c t 1 tn nc ma
cha 13% saccaroz l: A. 104 kg; B. 130kg; C. 165,2 kg; D. 124 kg.
10. Cho a gam tinh bt ln men sn xut ru etylic, ton b lng CO
2
sinh ra cho qua dd
Ca(OH)
2
d, thu c 750 g kt ta. Bit hiu sut mi giai on ln men l 80%. Khi lng a
gam em dng l:

A. 949,2 g; B. 1186,5 g; C. 759,36 g; D. 1000 g.
11.Thy phn 1kg khoai cha 10% tinh bt trong mi trng axit. Nu hiu sut phn ng l
75% th lng glucoz thu c l: A. 166,66 g; D. 200 g; C. 8333,3 g; D. 222,2 g.
12. Hai cht ng phn ca nhau l: A. Glucoz v mantoz ; B. fructoz v glucoz ;
C. fructoz v mantoz ; D. saccaroz v glucoz
13. sn xut 1 tn thuc n xenluloz trinitrat nguyn cht th khi lng xenluloz cn dng
l:
A. 545,45 kg; B. 1000 kg; C. 682,8 kg; D. 700 kg.
14. Dung dch saccaroz khng c tnh kh, nhng khi un nng vi dd H
2
SO
4
li c th phn
ng trng gng. l do:
A. c s to thnh anehit sau phn ng; B. V phn ng trng gng ch xy ra khi c
un nng;
C. V saccaroz ch cho phn ng trng gng trong mi trng axit;
D. Saccaroz cho phn ng thy phn to ra glucoz v fructoz, nn cho phn ng trng
gng.
15. Thy phn hon ton 1 kg saccaroz c:A. 1 kg glucoz v 1kg frutoz ; B. 2 kg
glucoz ; C. 2 kg frutoz ; D. 0,563 kg glucoz v 0,5263 kg frutoz
16. Thy phn hon ton 1 kg mantoz c:
A. 1 kg glucoz ; B. 1,0526 kg glucoz ; C. 1,0526 kg frutoz ; D.1 kg glucoz v 1 kg
frutoz
17. Thy phn hon ton 1kg tinh bt c:
A. 1 kg glucoz ; B. 1,11 kg glucoz ; C. 1,18 kg glucoz ; D. 1 kg glucoz v 1 kg
frutoz .
18. Ti mt nh my ru, c 10 tn tinh bt s sn xut c 1,5 tn ru etylic. Hiu sut c
qu trnh iu ch l: A. 26,4%; B. 15%; C. 85%; D. 32,7%.
19. Trng gng hon ton mt dung dch cha 27 gam glucoz . Lng AgNO
3
phn ng l:
A. 32,4 g; B. 51 g; C. 25,5 g; D. 16,2 g.
20. Cho s chuyn ha sau:

Tinh bt X Y axit axetic. X v Y ln lt l: A. Ancol etylic, anehit
axetic;
B. Glucoz , ancol etylic; C. Glucoz , etyl axetat; D. Mantoz , glucoz .
Chng 3: AMIN , AMINOAXIT v PROTEIN
Cu 1: Cho bit s amin bc II ca C
4
H
11
N: A. 1 B. 2 C. 3
D. 4
Cu 2: Tnh baz ca cht no mnh nht trong s cc cht sau ?
A. C
6
H
5
NH
2
B. NH
3
C. CH
3
-NH
2
d C
3
H
7
NH
2
.
Cu 3: C 3 l mt nhn cha ring l: ancol etylic, anilin, nc. C th nhn bit Anilin bng:
A. H
2
O B. dung dch NaOH C. dung dch Br
2
D. A,C u
ng.
Cu 4: Cho cc cht sau: amonic (1) , Metylamin (2) , anilin (3) , dimetylamin (4).
Tnh baz tng dn theo th t:
A. (1),(3),(2),(4) B.(3),(1),(2),(4) C.(1),(2),(3),(4)
D.(3),(1),(4),(2)
Cu 5: Mt amin n chc cha 19,718% Nit theo khi lng. Tm CTPT ca amin:
A. C
3
H
7
N B. C
4
H
7
N C. C
4
H
9
N D. C
4
H
11
N
Cu 6: Cho 3,04g hn hp A gm 2 amin no n chc tc dng va vi 400ml dung dch HCl
0,2M c 5,96g mui. Tnh th tch N
2
(ktc) sinh ra khi t chy ht hn hp A trn.
A. 0,224lt B. 0,448lt C. 0,672lt D.. 0,896lt
- Nu t chy ht hn hp trn v dn sn phm chy qua nc vi trong d th bnh tng bao
nhiu gam.
Cu 7:.Cho cc cht sau: NH
3
, CH
3
-NH
2
, (CH
3
)
2
NH, C
2
H
5
-NH
2
, C
6
H
5
-NH
2
. Th t tng dn tnh
baz l:
A) C
6
H
5
-NH
2
,

NH
3
, CH
3
-NH
2
, C
2
H
5
-NH
2
, (CH
3
)
2
NH
B) NH
3
, CH
3
-NH
2
, (CH
3
)
2
NH , C
2
H
5
-NH
2
, C
6
H
5
-NH
2
C) C
6
H
5
-NH
2
,

NH
3
, CH
3
-NH
2
, (CH
3
)
2
NH , C
2
H
5
-NH
2

D) (CH
3
)
2
NH , CH
3
-NH
2
, C
2
H
5
-NH
2
, C
6
H
5
-NH
2
, NH
3

Cu 8:.Cho 9,3 gam mt amin no n chc (A) tc dng vi dung dch FeCl
3
d thi thu c
10,7 g kt ta. Cng thc ca amin l:A) C
2
H
5
-NH
2
B) CH
3
-NH
2
C)
C
3
H
7
-NH
2
D) C
4
H
9
-NH
2

Cu 9:Cho m gam anilin vo nc brom d, c 16,5 gam kt ta (phn ng hon ton). M c
gi tr:
A) 4,65 gam B) 46,5 gam C) 2,325 gam
D) Khng xc nh c v khng bit lng brom phn ng.
Cu 10: Hy ch ra cu sai:
A/ Amin bc 1 c to thnh bng cch thay th 1 nguyn t hidrro trong phn t amoniac
bng 1 gc hidrocacbon.
B/ Cng thc chung ca amin mch h no l: C
n
H
2n+3
N, n > 1
C/ Trn nguyn t Nit ca amin c cp e cha tham gia lin kt, cp e ny c kh nng nhn
proton nn amin c tnh baz.
D/ Anilin lm qu tm ho xanh.
Cu 11:.Cho metylamin tc dng vi d.d. FeCl
3
, c hin tng no xy ra?
A/ Si bt kh. B/ C kt ta trng sau tan li.
C/ C kt ta mu nu . D/ Khng c hin tng g?
Cu 12:.Khi t chy cc ng ng ca metylamin, t l th tch VCO
2
/VH
2
O bin i nh th
no theo s lngnguyn t cacbon trong phn t .
A/ 0,4 < K < 1,2 B/ 0,8 < K < 2,5 C/ 0,4 < K < 1 D/ 0,75 < K <
1 .
Cu 13:.Cho 20 g hn hp 3 amin no n chc, l ng ng k tip ca nhau tc dng va
vi d.d HCl, c cn d.d thu c 31,68 g hn hp mui. Nu 3 amin trn c trn theo t l s
mol 1 : 10 ; 5 v th t phn t khi tng dn th CTPT ca 3 amin l:
A/ C
2
H
7
N, C
3
H
9
N, C
4
H
11
N B/ C
3
H
9
N, C
4
H
11
N, C
5
H
13
N.
C/ C
3
H
7
N, C
4
H
9
N, C
5
H
11
N D/ CH
5
N, C
2
H
7
N, C
3
H
9
N
Cu 14: t chy ht amol mt Aminoaxit A c 2 amol CO
2
v a/2 mol N
2
. A l ?
A. H
2
NCH
2
CH
2
COOH B. H
2
NCH
2
COOH

C. H
2
NCH(NH
2
)COOH D. HOOCCH(NH
2
)COOH
Cu 15: Cng thc n gin nht ca hp cht hu c A l: C
2
H
7
NO
2
. A c cng thc phn t l
:
A. C
2
H
7
NO
2
B. C
4
H
14
N
2
O
4
C. C
6
H
21
N
3
O
6
D. Kt qu khc
Cu16: A l mt Aminoaxit c khi lng phn t l 147. Bit 1mol A tc dng va vi 1
mol HCl; 0,5mol tc dng va vi 1mol NaOH. Cng thc phn t ca A l:
A. C
5
H
9
NO
4
B. C
4
H
7
N
2
O
4
C. C
5
H
25
NO
3
D. C
8
H
5
NO
2

Cu 17: C 0,01 mol Aminoaxit A phn ng va vi 40ml dung dch NaOH 0,25M. Mt khc
1,5Aminoaxit A phn ng va vi 80ml dung dch NaOH 0,25M. Khi lng phn t ca A
l :
A. 150 B. 75 C. 105 D. 89
Cu 18: t chy hon ton amol mt Aminoaxit X c 2amol CO
2
v 2,5 amol nc. X c
cng thc phn t l: A. C
2
H
5
NO
4
B. C
2
H
5
N
2
O
2
C. C
2
H
5
NO
2
D. C
4
H
10
N
2
O
2

Cu 19: t chy ht amol 1Aminoaxit A bng Oxi va ri ngng t hi nc c 2,5mol
hn hp CO
2
v N
2
. Cng thc phn t ca A l:
A. C
2
H
5
NO
2
B. C
3
H
7
NO
2
C. C
3
H
7
N
2
O
4
D. C
5
H
11
NO
2

Cu 20: 0,1 mol Aminoaxit A phn ng va vi 100ml dung dch HCl 2M. Mt khc 18g A
cng phn ng va vi 200ml dung dch HCl trn. A c khi lng phn t l:
A. 120 B. 90 C. 60 D. 80
Cu 21: 0,01mol Aminoaxit A tc dng va vi 50ml dung dch HCl 0,2M. C cn dung dch
sau phn ng c 1,835g mui khan. Khi lng phn t ca A l :
A. 89 B. 103 C. 117 D. 147
Cu 22: Amino axit l nhng hp cht hu c ........, trong phn t cha ng thi nhm chc
....... v nhm chc ......... Ch trng cn thiu l :
a. n chc, amino, cacboxyl b. Tp chc, cacbonyl, amino
c. Tp chc, amino, cacboxyl d. Tp chc, cacbonyl, hidroxyl
Cu 23: S ng phn aminoaxit c cng CTPT: C
4
H
9
O
2
N l :
a. 5 b. 6 c. 7 d. 8
Cu 24: Hp cht no sau y khng phi l amino axit :
a. CH
3
CONH
2
b. HOOC CH(NH
2
)CH
2
COOH

c. CH
3
CH(NH
2
)COOH d. CH
3
CH(NH2)CH(NH
2
)COOH
Cu 25: Axit amino axetic khng tc dng vi cht :
a. CaCO
3
b. H
2
SO
4
long c. CH
3
OH d. KCl
Cu 26: Axit -amino propionic p c vi cht :
a. HCl b. C
2
H
5
OH c. NaCl d. a&b ng
Cu 27: C 4 dung dch sau : dung dch CH
3
COOH, glixerin , h tinh bt , lng trng trng.
Dng dung dch HNO
3
c nh vo cc dung dch trn, nhn ra c:
a. glixerin b. h tinh bt c. Lng trng trng d.ax CH
3
COOH
Cu 28: C 3 ng nghim khng nhn cha 3 dung dch sau :
NH
2
(CH
2
)
2
CH(NH
2
)COOH ; NH
2
CH
2
COOH ; HOOCCH
2
CH
2
CH
2
CH(NH
2
)COOH.
C th nhn ra c 3 dung dch bng :
a. Giy qu b. Dung dch NaOH c. Dung dch HCl d. Dung dch Br
2

Cu 29: Cho C
4
H
11
O
2
N + NaOH A + C
2
H
5
OH
Vy A l :
a. NH
2
CH
2
COONa b. CH
3
COONH
4
c. H
2
N(CH
2
)
3
COONa d. Kt qu khc
Cu 30: Cho cc cht sau : etilen glicol (A) , hexa metylen diamin (B) ,
ax -amino caproic ( C), axit acrylic (D) , axit aipic (E).
Cht c kh nng tham gia phn ng trng ngng l
a. A, B b. A, C, E c. D, E d. A, B, C, E.
Cu 31: Cho C
4
H
11
O
2
N + NaOH A + CH
3
NH
2
+ H
2
O
Vy cng thc cu to ca C
4
H
11
O
2
N l :
a.C
2
H
5
COOCH
2
NH
2
b. C
2
H
5
COONH
3
CH
3

b. CH
3
COOCH
2
CH
2
NH
2
d. C
2
H
5
COOCH
2
CH
2
NH
2

Cu 32: Mt amino axit A c 40,4% C ; 7,9% H ; 15,7 % N; 36%O v M
A
= 89. Cng thc
phn t ca A l : a. C
3
H
5
O
2
N b. C
3
H
7
O
2
N c. C
2
H
5
O
2
N d.
C
4
H
9
O
2
N

Cu 33: C 0,01 mol amino axit A phn ng va vi 20 ml dung dch KOH 0,5M. Mt khc,
3 gam amino axit A p va vi 80 ml dung dch KOH 0,5M. Khi lng phn t ca A l :
a. 98 b . 100 c. 75 d. 150
Cu 34: Cho 0,01 mol amino axit A tc dng va 80 ml dung dch HCl 0,125 M.C cn
dung dch thu c 1,835 gam mui . Khi lng phn t ca A l :
a. 147 b. 150 c.97 d.120
Cu 35: Trung ho 2,94 gam amino axit A c khi lng phn t l 147 bng mt lng va
dung dch NaOH, em c cn dung dch thu c 3,82 gam mui. Bit A l mt aminoaxit c
cu to mch cc bon khng phn nhnh, cng thc cu to ca A l :
a. NH
2
C
3
H
5
COOH b. NH
2
C
3
H
5
(COOH)
2
c. NH
2
C
6
H
4
COOH d.NH
2
CH
2
COOH
4. Cng c, dn d
G yu cu H nhc li tnh cht ha hc ca mt s hp cht.
5. H-ng dn v nh
H n tp tnh cht ha hc ca kim loi.

Ngy son 24/12/2009

Tit 35
n tp hc k i
-------------------
I. Mc tiu bi hc
1. Kin thc
HS biet:
+Noi dung on tap hoc k I.
+Cac kien thc can nh phan kim loai.
HS hieu:
+Khac sau kien thc a hoc.
2. K nng
Ren luyen cho HS cac k nang t duy giai toan hoa hoc.
3. Tnh cm, thi
II. Trng tm
Bai tap kim loai + axit co tnh oxi hoa.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
G h-ng dn hc sinh n tp theo h thng cu hi sau
HNG DN N TP HC K I
Chng 4,5: POLIME - I CNG V KIM LOI
Cu1.Polime no sau y c tng hp bng phn ng trng hp:
A.Poli(vinyl clorua) B.Poli saccarit C. Protein D.Nilon-6
Cu2.Cho s (X) (Y) (Z) P.S.cc cht X,Y,Z ph hp vi s trn l:
A.C
6
H
6
, C
6
H
5
C
2
H
5
, C
6
H
5
C
2
H
3


B.C
6
H
5
CHCl

CH
3
, C
6
H
5
CHOHCH
3
, C
6
H
5
C
2
H
3
C.C
6
H
5
C
2
H
5
,

C
6
H
5
CHCl

CH
3
, C
6
H
5
C
2
H
3
D.C A,B,C
Cu3.Polime (- CH
2
-CH (OOCCH
3
)-)
n
c tn l:
A.Poli(metyl acrylat) B.Poli (vinyl Axetat) C.Poli(metyl metacrylat) D.Poli acrilonitrin
Cu4. Mt loi polime c cu to mch nh sau: -CH
2
-CH
2
-CH
2
-CH
2
-CH
2
-CH
2
-CH
2
-CH
2
-CH
2
-.
Polime trn c tng hp t:
A.Propilen B.Etilen C.Axetilen D.Stiren
Cu5: T Axetilen c th iu ch c poli (vinyl Axetat) bng t nht bao nhiu phn ng:
A.3 B.4 C.5 D.6
Cu6:Cht khng c kh nng tham gia phn ng trng ngng l:
A.Glyxin B.Axit terephtalic C.Axit axetic D.Etylen Glycol
Cu7: cho cc polime sau: (-CH
2
-CH
2
-)
n
, (-CH
2
-CH=CH-CH
2
-)
n
, (-NH-[CH
2
]
5
-CO-)
n
.Cng
thc cc monome to nn cc polime trn (bng cch trng hp hoc trng ngng) ln lt l:
A.CH
2
=CH
2
, CH
3
-CH=CH-CH
3
, H
2
N-CH
2
-CH
2
-COOH
B.CH
2
=CHCl,CH
3
-CH=CH-CH
3
, H
2
N-CH
2
(NH
2
)-COOH
C.CH
2
=CH
2
, CH
3
-CH=CH-CH
3
, H
2
N-(CH
2
)
5
COOH
D.CH
2
=CH
2
, CH
3
-CH=C=CH
2
, H
2
N-CH
2
-CH
2
-COOH
Cu8: Polime c iu ch bng phn ng trng ngng l:
A.Poli(metyl metacrylat) B.Poli acrilonitrin C.Poli Stiren D.poli peptit
Cu9.Trong cc loi t di y, cht no l t nhn to:
A.T visco B.T Capron C.Nilon-6,6 D.T tm
Cu 10.Nha phenol fomandehit c iu ch bng cch un nng phenol vi dung dch:
A.CH
3
COOH trong mi trng axit B.CH
3
CHO trong mi trng axit
C.HCOOH trong mi trng axit D.HCHO trong mi trng axit

Cu11:Kim loi c nhit nng chy cao nht v kim loi nh nht ln lt l nhng kim loi
no sau y: A.Vonfram, Liti B.ng, Kali C.St , Natri
D.Km, Rubidi
Cu12:Tng s ht proton, ntron, electron ca ngt 1 ngt l155.S ht mang in nhiu hn
s ht khng mang in l 33 ht.Ngt l:
A.ng B,Bc C.Ch D.St
Cu13:Mt ngtuwr c tng s ht proton, ntron, electron l 40 ht. l ngt ca ngtoos no
sau y:
A.Canxi B.Bari C.Nhm D.St
Cu14:Nguyn nhn gy ra tnh do, tnh dn nhit, in v nh kim ca kim loi l:
A.Bn knh ngt kim loi ln B.S e ho tr ca ngt kim loi t
C.Cc e t do trong mng tinh th D.in tch ht nhn ca ngt kim loi nh
Cu15:Cho cu hnh e ca ngt cc ngt:1)1s
2
2s
2
2p
6
3s
1

, 2)1s
2
2s
2
2p
6
, 3)1s
2
2s
2
2p
6
3s
2

3p
1
,
4)1s
2
2s
2
2p
6
3s
2

3p
3
, 5)1s
2
2s
2
2p
6
3s
2

3p
6
3d
5
4s
2
. Nhng ngt kim loi l:
A.2,5 B.1,3 C.1,3,5 D.1,3,4
Cu16:Dy kim loi tc dng c vi nc nhit thng l:
A.Fe,Zn,Li,Sn B.Cu, Pb, Rb, Ag C.L, Na,Ba, Ca D.Al, Hg, Cs, Sn
Cu17: Cho 4,8 g kim loi R ho tr II tan hon ton trong dung dch HNO
3
long thu c 1,12
lit kh NO duy nht (kc).Kim loi R l:
A.Zn B.Mg C.Fe D.Cu
Cu18: Kh hon ton hn hp gm FeO v ZnO thnh kim loi cn 2,24 lit kh H
2
(kc).Nu
em hn hp kim loi thu c cho tc dng ht vi dung dch HCl th V H
2
( ddkc) thu c l:
A.4,48 lt B.1,12 lt C.3,36 lt D.2,24 lt
Cu19: Ngm 1 l Zn nng 10 g trong 500g dung dch CuSO
4
4%, khi ly l Zn ra th lng
CuSO
4
gim 16%.Khi lng l Zn sau phn ng l:
A.8,7g B.9,98g C.10,02g D.10,65g
Cu20: Nhng kim loi no sau y y c St ra khi dung dch mui Fe(III):
A.Mg,Zn B.Sn,Cu C.Ag D.Mg, Zn, Fe, Sn, Cu

Cu21:Cho hn hp Fe v Zn tc dng vi dung dch hn hp cha 0,01 mol HCl v 0,05 mol
H
2
SO
4
.Sau phn ng thu c cht rn X, dung dch Y v kh Z. Cho kh Z qua CuO d, nung
nng c m g Cu. Gi tr ca m l:
A.5,32 B.2,35 C.3,52 D.2,53
Cu22:Hai dung dch mui no sau y c th phn ng vi nhau:
A.Cu
2+
+ Fe
2+
B.Fe
2+
+ Fe
3+
C.Fe
2+
+ Ag
+
D.Fe
3+
+ Ag
+
Cu23:Trong hp kim Al-Mg c c 9 mol Al th c 1 mol Mg.Thnh phn % khi lng ca
hp kim:
A.80% Al v 20% Mg B.81% Al v 19% Mg
C.91% Al v 9% Mg D.83% Al v 17% Mg
Cu24:Mt vt lm bng hp kim Fe-Zn trong khng kh m b n mn theo c ch no:
A.Cc (-) :3Fe + 2O
2
Fe
3
O
4
, Cc (+) : 2Zn+O
2

2ZnO
B.Cc (-) Fe: Fe
Fe
2+
+ 2e , Cc (+) Zn: 2H
+
+ 2e
H
2

C.Cc (-) Zn: Zn
Zn
2+
+ 2e , Cc (+) Fe: Fe
Fe
2+
+ 2e
D.Cc (-) Zn: Zn
Zn
2+
+ 2e , Cc (+) Fe: 2 H
2
O + O
2
+ 4e
4OH
-

Cu25: inh st b mn nhanh nht trong trng hp no sau y:
A.Ngm trong dung dch HCl B.Ngm trong dung dch H
2
SO
4

C.Ngm trong dung dch H
2
SO
4
long
D.Ngm trong dung dch H
2
SO
4
long c thm vi git dung dch CuSO
4
Cu26:Cho 2,06 g hn hp Fe, Al, Cu tc dng vi dung dch HNO
3
long d thu c 0,896 lit
NO duy nht (kc). Khi lng mui Nitrat sinh ra l:
A.9,5g B.7,44,g C.7,02g D.4,54g
Cu27:Cho 3 kim loi Al, Fe, Cu v 4 dung dch mui ring bit ZnSO
4
, AgNO
3
, CuCl
2
,
MgSO
4
.Kim loi no tc dng c vi c 4 dung dch mui cho:
A.Al B.Fe C.Cu D.Khng c kim loi no
Cu28: iu ch kim loi Cu t Cu(OH)
2
ngi ta khng th dng phng php no sau y:
A.Chuyn thnh CuCl
2
ri dng phng php in phn nng chy

B.Chuyn thnh CuSO
4
ri dng phng php Thu luyn
C. Chuyn thnh CuO ri dng phng php Nhit luyn
D.Chuyn thnh CuSO
4
ri dng phng php in phn nng chy
Cu29:Ngi ta dng phng php no sau y iu ch kim loi Na:
A.in phn nng chy NaOH B.in phn dung dch NaCl
C.Nhit luyn Na
2
O D.Thu luyn NaCl
Cu30: in phn bng in cc tr dung dch mui Sunfat ca 1 kim loi ho tr II vi dng
in c cng 6A.Sau 29 pht thy khi lng catot tng 3,45g.kim loi l:
A.Zn B.Cu C.Ni D.Sn
4. Cng c, dn d
G yu cu H nhc li tnh cht ha hc ca kim loi.
5. H-ng dn v nh
H n tp tnh cht ha hc ca kim loi.

Ngy son 18/12/2009
Tit 36

kim tra hc k i
-------------------
I. Mc tiu bi hc
1. Kin thc
Hs nm -c kin thc trong ch-ng 1, 2, 3, 4, 5.
2. K nng
II. Trng tm
Tnh cht ho hc cc cht hc.
III. Chun b
Gio vin: thi v p n
IV. Ph-ng php
Hnh thc kim tra: 25 cu trc nghim.
V. bi
VI. p n, thang im

Ngy son 28/12/2009
Tit 37
Bi 20. s n mn kim loi.

-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- Khi nim n mn kim loi v cc dng n mn chnh.
- Cch bo v cc dng bng kim loi v my mc khi b
n mn.
HS hiu: Bn cht ca s n mn kim loi l qu trnh oxi ha
kh trong kim loi b oxi ha thnh ion d-ng.
2. K nng
Biet van dung c nhng hieu biet ve pin ien hoa e giai thch hien
tng an mon ien hoa hoc.
3. Tnh cm, thi
Co y thc bao ve kim loai, chong an mon kim loai do hieu ro
nguyen nhan va tac hai cua hien tng an mon kim loai.
II. Trng tm
C ch n mn ca kim loi.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ha hc ca kim loi? Vit pthh
minh ha tnh cht.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

G neu cau hoi: V sao kim loai hay hp
kim de b an mon?
Ban chat cua an mon kim loai la g?
Hd cho hs neu /n va viet qua trnh ?
I. Khai niem

La s pha huy kl hoac hp kim do td

Theo em an mon kl co may loai ?

An mon hoa hoc la g ? ac iem,
ban chat va cho vd.

An mon ien hoa la g ?

Nghien cu c che cua s an mon ien
hoa
H quan sat hnh ve 5.5/sgk

Hd cho mo ta TN va neu hien tng ?

V sao la Zn b an mon, con la Cu th
khong ?

Gv hd cho hs neu va dien giang.

Xet c che ve s g cua Fe trong khong
kh am.

hoa hoc cua cac chat trongmoi trng
xung quanh : M
0
M
n+
+ ne (n = 1, 2, 3).
Ket qua : Lam mat nhng t/c quy
bau cua kl.
II. Cac dang an mon kim loai
Phan loai: Co hai loai chnh:
1. An mon hoa hoc: La s pha huy
kl do kl p hh vi chat kh hoac hi nc
t
o
cao.

2
: Khong phat sinh dong ien, toc
o an mon phu thuoc vao t
o
.
Ban chat: La mot qua trnh oxi hoa
kh.
Vd: 3Fe + 2O
2
Fe
3
O
4

Fe + 3/2Cl
2
FeCl
3

2. An mon ien hoa: La s pha
huy cua kl do kl tiep xuc vi dd chat
ien li tao nen dong ien.
a. TN: Hnh ve sgk.
Mo ta:
Hien tng:
+ La Zn cc am: B an mon
nhanh trong dd.
+ Kim von ke b lech hoac
bong en sang.
+ La Cu cc dng: Co bot kh
hro thoat ra.
Giai thch:
+ Cc am: La Zn b am mon
nhanh v: Zn
0
2e Zn
2+
va i vao dd.
+ Kim von ke lech: Cac e di
chuyen t la Zn Cu.
+ Cc dng: Cac ion H
+
trong dd
axit di chuyen en va b kh thanh hiro
t do va thoat ra khoi dd: 2H
+
+ 2e H
2
.

b. C che cua an mon ien hoa:
Xet mot vat bang gang (hoac
thep: Fe C) trong moi trng khong kh
am ( H
2
O, CO
2
, SO
2
, O
2
, ...).
+ Cc am (tinh the Fe): Xay ra s
oxi hoa Fe (an mon Fe) thanh ion Fe
2+
:
Fe
0
2e Fe
2+
va i vao dd ien li. Tai
ay b oxi hoa tiep: Fe
2+
-- 1e Fe
3+
(G
sat mau nau o).
+ Cc dng (tinh the C): Cac ion H
+


H tm hieu k xay ra an mon ien hoa
hoc

e bao ve kl, ta dung nhng pp nao ?
Cho vd.
G gi y e H tra li: phai cach li kim
loai vi moi trng.
V sao e bao ve vo tau bien bang
thep, ngi ta gan cac ban kem vao
thanh tau? (phan chm di nc bien)

trong dd chat ien li (neu la dd axit ) di
chuyen en, b kh: 2H
+
+ 2e H
2
va
thoat ra khoi dd.
Neu nc co hoa tan O
2
, hoac dd
trung tnh, hoac dd baz th xay ra s kh
O
2
: 2H
2
O + O
2
+ 4e 4OH

d. Ban chat cua an mon ien hoa: La
1 qua trnh oxi hoa kh xay ra tren be
mat cac ien cc.
c. Cac k an mon ien hoa:
+ Cac ien cc phai khac chat
nhau.
+ Cac ien cc phai tiep xuc nhau
trc tiep hoac gian tiep.
+ Cac ien cc phai cung tiep
xuc vi 1 dd ien li.

II. Chong an mon kim loai:
1. Cach li kl vi moi trng.
2. Dung hp kim chong g.
3. Dung chat chong an mon (Chat km
ham).
4. Dung pp ien hoa.
4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li:
+ Nguyen nhan g gay nen hien tng an mon kim loai va hp kim? Ba
ieu kien cua s an mon ien hoa hoc?
+ S an mon ien hoa hoc khac s an mon hoa hoc ntn?
+ Trnh bay th nghiem minh hoa s an mon ien hoa hoc cua kim loai?
5. H-ng dn v nh
HS lam bai tap 1- 6 trong SGK trang 95.


Ngy son 03/01/2010
Tit 38
Bi 23. Luyn tp: iu ch kim loi v s n mn kim
loi.
-------------------
I. Mc tiu bi hc
1. Kin thc
Cng c kin thc v:
- Nguyn tc iu ch kim loi v cc pp iu ch kim loi.

- Bn cht ca s n mn kim loi, cc dng n mn kim loi
chnh v cch chng n mn.
2. K nng
K nng tnh ton l-ng kim loi iu ch -c theo cc pp hoc
cc i l-ng c lin quan.
3. Tnh cm, thi
Nhn thc -c tc hi nghim trng ca s n mn kim loi, nht
l n-c ta vo vng nhit i gi ma, nng nhiu v m
cao. T , c thc v hnh ng c th bo v kim loi,
tuyn truyn vn ng mi ng-i cng thc hin nhim v ny.
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
? /c Ca t CaCO
3

? /c Cu t CuSO
4

Vit pthh
CaCO
3

ddHCl +
CaCl
2
cocan
CaCl
2
khan
dpnc
Ca
Fe + CuSO
4
FeSO
4
+ Cu
Hoc 2CuSO
4
+2H
2
O 2Cu + O
2
+ 2H
2
SO
4

Hoc CuSO
4
Cu(OH)
2
CuOCu
? BT s 2:
Cu(OH)
2
CuO
C +
Cu
MgO
ddHCl +
MgCl
2

cocandd
MgCl
2

dpnc
Mg
Fe
2
O
3
+ 3CO
0
t
2Fe + 3CO
2

3. Cc hot ng dy hc
sinh
Ni dung kin thc
A. Kin thc cn nh:
1. iu ch kim lai


Nguyn tc chung ?
HS: kh ion kim lai thnh kim lai
Cc phng php ?
HS: nhit luyn, thy luyn, in phn
Mi lin h gia pp iu ch kim loi v mc
hot ng ca kim loi.

2. S n mn kim lai?
Khi nim?
HS: S n mn kim lai l s ph hy kim lai
hoc hp kim do tc dng ca cc cht trong
mi trng xung quanh.
Phn lai n mn ?
HS: n mn ha hc l qu trnh oxi ha kh
trong cc electron ca kim lai c
chuyn trc tip n cc cht trong mi
trng.
HS: n mn in ha l qu trnh oxi ha kh
trong kim lai b n mn do tc dng ca
dung dch cht in li v to nn dng electron
chuyn di t cc m sang cc dng.
Cc chng n mn kim lai ?
HS: Phng php bo v b mt, phng php
in ha.
B. Bi tp
1.SGK T dd AgNO
3
c th c 3 phng php
iu ch kim lai?

- Kim loi mnh ( Li Al) : pp in
phn nng chy.
- Kim loi c tnh kh TB (sau Al n
trc H): pp in phn v nhit luyn.
- Kim loi c tnh kh yu (sau H): 3 pp.

- ging nhau: c 2 u l qu trnh oxi ha -
kh.
- khc nhau:
n mn ha hc: kim loi nhng e trc tip
cho cht tc dng, khng pht sinh dng in.
n mn in ha hc: qu trnh oxi ha - kh
xy ra ti b mt ca cc in cc, to nn
dng e chuyn di t cc m sang cc dng,
kim loi c tnh kh mnh hn b n mn.

Dng kim lai mnh kh ion kim lai c tnh
kh yu
Cu + 2AgNO
3
Cu(NO
3
)
2
+ 2Ag
in phn dung dch AgNO
3

4AgNO
3
+ 2H
2
O
dpdd
4Ag + O
2
+ 4HNO
3

C cn , nhit phn 2AgNO
3

0
t
2Ag +
O
2
+2NO
2

T MgCl
2
/c Mg ch c mt cch c cn dung
dch , in phn nng chy
MgCl
2
dpnc
Mg

+ Cl
2

Catot anot

4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li:
Cc dng n mn ha hc, pp bo v kim loi.
5. H-ng dn v nh
HS lam bai tap 2- 5 trong SGK trang 103.


Ngy son 05/01/2010
Tit 39
Bi 23. Luyn tp: iu ch kim loi v s n mn kim
loi.
-------------------
I. Mc tiu bi hc
1. Kin thc
Cng c kin thc v:
- Nguyn tc iu ch kim loi v cc pp iu ch kim loi.

- Bn cht ca s n mn kim loi, cc dng n mn kim loi
chnh v cch chng n mn.
2. K nng
K nng tnh ton l-ng kim loi iu ch -c theo cc pp hoc
cc i l-ng c lin quan.
c bit pp in phn.
Vn dng -c bi ton in phn trong ha hc.
3. Tnh cm, thi
Nhn thc -c tc hi nghim trng ca s n mn kim loi, nht
l n-c ta vo vng nhit i gi ma, nng nhiu v m
cao. T , c thc v hnh ng c th bo v kim loi,
tuyn truyn vn ng mi ng-i cng thc hin nhim v ny.
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Nguyn tc iu ch kim loi? C s khoa hc ca pp in phn?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
A. Kin thc cn nh:
S in phn.
Nu cc cu hi:
* Du v tn ca cc in cc trong thit b
in phn
Du v tn ca cc in cc trong thit b in
phn v trong pin in ha c g khc nhau?
Phn ng ha hc xy ra anot v catot trong
thit b in phn v trong pin in ha c g
khc nhau?
H tho lun v rt ra nhn xt.

- anot: xy ra s oxi ha.
- catot: xy ra s kh.

* Phn ng ha hc trong qu trnh in phn.
- Nhng p ha hc no xy ra anot v catot
trong qu trnh in phn.
- Mui NaBr khan nng chy (cc in
cc tr).
- Dung dch NaBr ( cc in cc tr)
- Dd AgNO
3
(cc in cc tr); dd
CuSO
4
(anot bng Cu)
- Vit pt in phn cho cc trng hp trn.
B. Bi tp
2.SGK

3.SGK

4.SGK

* V du cc in cc:
Trong pin in ha anot l cc m cn trong
thit b in phn anot l cc dng.
* V bn cht
Trong pin in ha: p oxi ha kh xy ra
gii phng nng lng di dng in nng.
S in phn l qu trnh s dng in nng
to ra s bin i ha hc.

Khi lng ca AgNO
3
c trong 250ml dd l
250.4
10
100
g =
S mol AgNO
3
phn ng l ;
10.17
0, 01
100.170
mol =
Cu + 2AgNO
3
Cu(NO
3
)
2
+ 2Ag
0,005mol 0,01mol 0,01mol
Khi lng ca vt sau phn ng l : 10 +
(108.0,01) 64.0,005= 10,76g

M
x
O
y
+ yH
2
xM + yH
2
O
S mol H
2
l
8, 96
0, 4
22, 4
mol =
S mol trong oxi trong xit l 0,4mol .
Khi lng ca kim lai M trong oxit l : 23,2-
0,4.16=16,8g
Ch c s mol kim lai M l o,3 mol v nguyn
t ca M l 56 mi ph hp. kim lai M l Fe

2M + 2nHCl 2MCl
n
+ nH
2

S mol ca H
2
l
5, 376
0, 24
22, 4
mol =
S mol kim lai M l
0, 24.2 0, 48
mol
n n
=
Ta c M=
9, 6
0, 48
n
bin lun M=40 n=2 l ph

5.SGK

hp l Ca

2MCl
n

dpnc

2M + nCl
2

0,15.2
n
0,15
S mol Cl
2
l 3,36/22,4=0,15mol nn s
0,15.2 0, 3
M
n
n n
= =
Ch c n=2 , M=40 l ph hp

4. Cng c, dn d
- GV h thng li bi hc v yu cu HS nhc li c s khoa hc ca pp in phn?
5. H-ng dn v nh
HS lam bai tap trong SBT.

Ngy son 08/01/2010
Tit 40
Bi 24. Thc hnh: tnh cht, iu ch kim loi
v s n mn kim loi.
-------------------
I. Mc tiu bi hc
1. Kin thc

Cung co kien thc ve: day ien hoa cua kim loai, ieu che kim loai, s
an mon kim loai.
Tien hanh mot so th nghiem:
- So sanh phan ng cua Al, Fe, Cu vi ion H
+
trong dung dch HCl (day ien
hoa cua kim loai).
- Fe phan ng vi Cu
2+
trong dung dch CuSO
4
(ieu che kim loai bang cach
dung kim loai manh kh kim loai yeu trong dung dch).
- Zn phan ng vi dung dch H
2
SO
4
, dung dch H
2
SO
4
them CuSO
4
(s an
mon ien hoa hoc).
2. K nng
Tiep tuc ren luyen cac k nang thc hanh hoa hoc: lam viec vi dung cu
th nghiem, hoa chat, quan sat hien tng.
Van dung e giai thch cac van e lien quan en day ien hoa cua kim
loai, ve s an mon kim loai, chong an mon kim loai
3. Tnh cm, thi
Can than trong cac th nghiem hoa hoc.
II. Trng tm
III. Chun b
Gio vin: Dung cu: Ong nghiem, gia e ong nghiem, en con,
keo, dua hoac giay giap.
Hoa chat: Kim loai: Al, Cu, Zn, Fe (inh sat nho hoac day sat);
Dung dch: HCl, H
2
SO
4
, CuSO
4

Chun b ni dung bi dy.
IV. Ph-ng php
Trc quan nu vn hot ng nhm.
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Tin hnh trong qu trnh thc hnh th nghim.

3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1: Cong viec au buoi
thc hanh
- GV neu muc tieu, yeu cau tiet thc
hanh va mot so iem can lu y
trong buoi thc hanh.
- GV co the lam mau mot so th
nghiem.
Hoat ong 2:
- HS tien hanh cac th nghiem nh
yeu cau cua SGK
Hoat ong 3:
- HS tien hanh th nghiem nh SGK.
- Lu y la anh that sach g sat
e phan ng xay ra nhanh va ro
hn.
Hoat ong 4:
- HS tien hanh th nghiem nh SGK.
- GV hng dan HS quan sat hien
tng.
Hoat ong 5: Cong viec cuoi buoi
thc hanh.
- GV nhan xet, anh gia buoi thc
hanh.
- HS thu don dung cu, hoa chat, ve
sinh PTN, lp hoc, viet tng trnh th
nghiem theo mau.

Th nghiem 1: Day ien hoa cua
kim loai

Th nghiem 2: ieu che kim loai
bang cach dung kim loai manh
kh ion kim loai trong dung dch.

Th nghiem 3: An mon ien hoa

4. Cng c, dn d
- GV h thng li ni dung cn nh trong bi thc hnh.
5. H-ng dn v nh
Xem tr-c ni dung bi hc trong ch-ng ti.

Ngy son 10/01/2010
Tit 41 Ch-ng 6. kim loi kim, kim loi kim th,
nhm

Bi 25. kim loi kim v hp cht quan trng
ca kim loi kim
-------------------
I. Mc tiu bi hc
1. Kin thc
HS hiu: v tr, tnh cht ca kim lai kim, tnh cht v ng dng mt s hp cht quan trng
ca kim lai kim, nguyn tc iu ch kim loi kim.
HS bit: nguyn nhn ca tnh kh mnh kim lai kim.
2. K nng
Lm mt s th nghim n gin v kim loi kim.
Gii bi tp v kim loi kim.
3. Tnh cm, thi
II. Trng tm
Tnh cht ca kim loi.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Bng cc pp iu ch kim loi hc, hy iu ch Ag t dd
AgNO
3
, vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

Hat ng 1: Tm hiu v tr ca kim lai
kim

A. Kim lai kim
I. v tr trong BTH, cu hnh electron nguyn t

Dng BTH, vit cu hnh electron, v tr ca
cc nguyn t kim lai kim.

Hat ng 2: Tm hiu tnh cht vt l ca kim
lai kim
Th nghim xem tnh cht vt l ca kim
lai kim.

a ra qui lut bin i tnh cht ca cc
nguyn t trong nhm IA
Hot ng 3: Tm hiu tnh cht ha hc ca
kim lai kim
Nu cu to nguyn t ca kim
lai kim suy ra tnh cht ha hc.

TN minh ha tnh cht ca kim lai kim
Yu cu vit pthh

Hot ng 4: Tm hiu v ng dng v iu
ch
H t nghin cu Sgk

H nu nguyn tc iu ch di s dn dt ca
G.
G dng tranh v hng dn H nghin cu s
thit b in phn NaCl nng chy trong
cng nghip.
IA gm: liti, natri, kali, rubii, xesi v franxi
Cu hnh: Li: [He] 2s
1

Na: [Ne] 3s
1

K : [Ar]4s
1

Rb: [Kr] 5s
1

Cs: [Xe] 6s
1

II. Tnh cht vtl
Cc kim lai kim c mu trng bc v c nh
kim , dn in tt,nhit nng chy v nhit
si thp, khi lung ring nh, cng
thp.
Cu to: mng tinh th lp phng tm khi c
cu trc rng, nguyn t l ion lin kt rt yu.

III. Tnh cht ho hc
Cc nguyn t kim lai kim c nng lng ion
ha rt nh, v vy kim lai kim c tnh kh
rt mnh, tnh kh tng dn t Li n xesi
MM
+
+ e
Trong hop cht cc kim lai kim c s oxi ha
l +1

1. Tc dng vi phi kim
a. Tc dng vi oxi
2Na + O
2
(kh) Na
2
O
2
(natripeoxit)
4Na + O
2
( khng kh) 2Na
2
O
b. Tc dng vi clo
2K + Cl
2
2KCl
2. Tc dng vi nc
K + H
2
O ( nhit thng) KOH + H
2

3. Tc dng vi axit
Tt c cc kim lai kim u n khi tip xc
vi dd axit, kh ion H
+
trong HCl, H
2
SO
4
lang
thnh H
2

2Na + 2HCl 2NaCl +H
2
IV. ng dng, trng thi t nhin v iu ch
1. ng dng
Sgk
2. Trng thi t nhin
3. iu ch

4. Cng c, dn d

- GV h thng li ni dung cn nh trong bi.
- Cng c bng cc bi tp 1, 2, 3/SGK.
5. H-ng dn v nh
Xem tr-c ni dung phn hc ti.

Ngy son 13/01/2010
Tit 42
Bi 25. kim loi kim v hp cht quan trng

ca kim loi kim
-------------------
I. Mc tiu bi hc
1. Kin thc
HS hiu: v tr, tnh cht ca kim lai kim, tnh cht v ng dng mt s hp cht quan trng
ca kim lai kim, nguyn tc iu ch kim loi kim.
Tnh cht ho hc v phng php iu ch NaOH bng in phn, hiu c nhng qu trnh
ho hc xy ra trn cc in cc, vit s v phng trnh in phn
Nhng tnh cht ho hc ca cc mui NaHCO
3
, Na
2
CO
3
; ng dng ca chng.
HS bit: nguyn nhn ca tnh kh mnh kim lai kim.
2. K nng
3. Tnh cm, thi
II. Trng tm
Tnh cht ca kim loi.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Bng cc pp iu ch kim loi hc, hy iu ch Ag t dd
AgNO
3
, vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

HOT NG 1
B. Mt s hp cht quan trng ca kim loi
kim

pdd

m.n
GV: cho HS quan st l cha NaOH rn
HS: quan st v cho bit mu sc, trng thi
tn ti
GV: Biu din TN ho tan NaOH vo nc,
cho hc sinh cm ng nghim, nhn xt hin
tng.
Hi: NaOH l baz mnh hay yu, trong nc
phn li cho ra nhng ion no, vit p?
Hi : Hy cho bit nhng tnh cht ca dung
dch baz? V hon thnh cc phong trnh
phn ng sau y?
NaOH + Cu(NO
3
)
2

HOT NG 2
Hi: Trong thc t em bit NaOH c
nhng ng dng g ?

GV: NaOH c iu ch bng phng php
in phn dung dch mui NaCl.

GV: Treo s thng in phn dung ch
NaCl v m t.

HS: Vit cc qu trnh xy ra ti in cc v
vit phn ng in phn

HOT NG 3
GV: NaHCO
3
bn nhit thng, b phn
hu nhit cao.

Hi: Hy vit p chng minh rng
NaHCO
3
l cht lng tnh ?
GV: Lm th nghim: cho HCl vo ng
nghim cha NaHCO
3
.
HS: Cho bit tnh lng tnh ca NaHCO
3
l
do ion no gy ra ?
GV: tnh baz vn l u th

HS: Nghin cu nhng ng dng trong sgk
HOT NG 4
HS: Quan st l cha Na
2
CO
3
v nhn xt tnh
cht vt l ca n
Hi: Na
2
CO
3
l mui ca axit no? Hy vit
I. Natrihidroxit: NaOH
1. Tnh cht:
- NaOH l cht rn khng mu, d ht
m, d nng chy, tan nhiu trong nc.
- NaOH l mt baz mnh, phn li hon
ton thnh ion khi tan trong nc.
NaOH Na
+
+ OH
-

- Tc dng vi dung dch axit, oxit axit,
mui.
VD: NaOH + HCl
CO
2
+ NaOH

2. ng dng v iu ch:
a) ng dng: c nhiu ng dng quan
trng trong cng nghip: sx nhm , x
phng......
b) iu ch: in phn dung dch NaCl c
mng ngn
s : d
2
NaCl
(NaCl, H
2
O)
catot anot
Na
+
, H
2
O Cl
-
, H
2
O
2H
2
O + 2e H
2
+ 2OH
-

2Cl
-
Cl
2
+ 2e
Ptp:
2NaCl + 2H
2
O H
2
+2NaOH
+Cl
2
II. Natrihidro cacbonat NaHCO
3

a) tnh cht:
- l cht rn mu trng t tan trong nc,
b phn hu nhit cao.
2NaHCO
3
Na
2
CO
3
+CO
2
+H
2
O
- L mui ca axit yu, khng bn, tc
dng vi axit mnh.
NaHCO
3
+HCl NaCl + CO
2
+ H
2
O
HCO
3
-
+ H
+
CO
2
+ H
2
O
- L mui axit nn p c vi dung dch
baz
VD: NaHCO
3
+ NaOH Na
2
CO
3
+ H
2
O
HCO
3
-
+ OH
-
CO
3
-
+ H
2
O
b) ng dng : sgk

III. Natri cacbonat Na
2
CO
3

a) Tnh cht:
- L cht rn mu trng d tan trong
nc, t
o
nc = 850
o
C , khng phn hu nhit

ptp ca Na
2
CO
3
vi HCl dng phn t v ion
thu gn , t nhn xt tnh cht ca n ?

Hi: Hy cho bit dung dch Na
2
CO
3
c mi
trng g ? v sao? pH ln hay nh hn 7 ?
HS: c nhng ng dng ca Na
2
CO
3

G gii thiu thuc sng 68% KNO
3
+ 15% S +
17% C
cao.
- L mui ca axit yu nn p vi axit
mnh.
Na
2
CO
3
+ 2HCl 2NaCl + CO
2
+H
2
O
CO
3
-
+ 2H
+
CO
2
+ H
2
O
ion CO
3
2-
nhn proton, nn c tnh baz
b) ng dng: sgk
IV. Kali nitrat KNO
3
1. Tnh cht
333
o
C phn hy thnh KNO
2
v O
2

2. ng dng

Phn ng t nng
2KNO
3
+ 3C + S N
2
1 + 3CO
2
1 + K
2
S

4. Cng c, dn d
- Cng c bng cc bi tp 6, 7/SGK.
5. H-ng dn v nh
Bi tp 4,5,8/SGK trang 111.

Ngy son 15/01/2010
Tit 43
Bi 26. kim loi kim th v hp cht quan trng

ca kim loi kim th
-------------------
I. Mc tiu bi hc
1. Kin thc
- HS bit: + V tr, cu to nguyn t, tnh cht ca kim
loi kim th.
+ Nguyn tc v pp iu ch kim loi kim th.
+ V tr, cu hnh e, nng lng ion ho, s oxi ho ca kim loi kim th, mt s
ng dng ca kim loi kim th.
- HS hiu: Nguyn nhn tnh kh mnh ca kim loi kim th.
Tnh cht vt l: t
o
nc v t
o
s tong i thp, khi lng ring nh.
Tnh cht ho hc c trng ca kim loi kim th l tnh kh mnh nhng yu hn Kim
loi kim, tnh kh tng dn t Be Ba.
Phng php iu ch kim loi kim th l in phn nng chy mui clorua.
2. K nng
- T cu to suy ra tnh cht, t tnh cht suy ra ng dng v
iu ch.
- Gii bi tp v kim loi kim th.
- Bit thc hin thao tc t duy: v tr, CTNT tnh cht pp iu ch.
- Vit ptp ho hc.

3. Tnh cm, thi
II. Trng tm
V tr, tnh cht ca kim loi kim th.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Kim tra 15 pht
Cu 1 (5 ). Vit cc pthh minh ha tnh cht ca kim loi kim.

Cu 2 (5 ). in phn nng chy hon ton 14,9 gam mui clorua
ca kim loi ha tr I thu -c 2,24 lt kh (ktc) anot. Xc
nh tn kim loi.
p n: Cu 1. Theo phn tnh cht ha hc ca kim loi kim
trnh by.
Cu 2. Vit pt in phn.
Theo t l mol x kim loi.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

HOT NG 1
Hi: KLK th nm nhn no trong BTH?
Bao gm nhng nguyn t no?

GV: BTH.
HS: vit cu hnh e ca Mg, Ca cu hnh e
ngoi cng TQ.
Hi: cho bit KLKT c my e ho tr nm
phn lp no? xu hng ca KLKT trong
p ho hc.

HOT NG 2
GV: Hy quan st vo bng s liu
- Cho bit t
o
nc, t
o
s, nhn xt ?
- So snh cng ca KLK vi kl nhm
IIA ?
Hi: Do nhng yu t no m kim loi nhm
IIA c cng thp, t
o
nc, t
o
s thp?
- Cc kim loi ny c kiu mng ging nhau
hay khng ? t
o
nc, t
o
s c bin i theo quy
lut ?
HOT NG 3
Hi: Hy nhc li s bin i bn kmh nguyn
t trong mt chu k, so snh vi kim loi kim
tnh cht c trng l g ? so snh tnh cht
vi KLK ?
GV: nhit thng Be, Mg p chm vi
O
2
, khi t nng KLK th u bc chy trong
khng kh.
GV: TN: Mg chy trong kk
HS: Vit p ca KLK th vi O
2
,Cl
2
...
A. KIM LOI KIM TH
I. V tr v cu to:
1. V tr ca KLKT trong bng tun hon:
- Thuc nhm Iia , gm: Be, Mg, Ca, Sr,
Ba v Ra(px).
- Trong mi chu k ng sau KLK.
2. Cu to ca KLK th:
- l nguyn t s
- Cu hnh e ngoi cng TQ: ns
2
.
- Xu hng nhng 2e to ion M
2+
.
VD Mg Mg
2+
+ 2e
[Ne]3s
2
[Ne]
II. Tnh cht vt l:
- T
o
nc v t
o
s tng i thp
- Kim loi thuc nhm IIA c cng
cao hn KLK nhng mm hn nhm v nhng
kim loi nh, v c d<g/cm
3

- Kiu mng tinh th: khng ging nhau.

III. Tnh cht ho hc:
KLK th c tnh kh mnh, yu hn KLK.
Tnh kh tng dn t Be Ba.
1. Tc dng vi phi kim:
- Khi t nng, KLK th p vi
oxi(chy).
VD: 2Mg + O
2
2MgO
TQ: 2M + O
2
2MO
- Tc dng vi Hal:
VD: Ca + Cl
2
CaCl
2


t
o

pnc
pnc

GV: Cho bit E
o
ca KLK th t -2,9V
-1,85V; E
o
H
+
/H
2
= 0,00V
Hi: KLKT c kh c ion H
+
trong dung
dch axit? Gt?
GV: TN: Mg + dd HCl
HS: Vit p, xc nh s oxh
Hi: Hy n/c SGK v cho bit kh nng p ca
KLKT vi H
2
O.

HS: Vit ptp ca kim loi Ba, ca vi H
2
O to
ra dung dch baz.

HOT NG 4
Hs: c SGK v cho bit kloi nhm IIA c
nhng ng dng g ?
Hs: Hp kim ca Mg ch to my bay, tn
la .

GV: Trong t nhin, KLKT tn ti dng M
2+

trong cc hp cht.

PP iu ch KLK th l pnc mui ca
chng.

2. Tc dng vi axit:
- KLK th kh c ion H
+
trong dung
dch axit thnh H
2
v E
o
M
2+
/M < E
o
H
+
/H
2
.
VD: Ca + 2HCl CaCl
2
+ H
2

TQ: M + 2H
+
M
2+
+ H
2

3. Tc dng vi nc:
- Be khng p
- Mg: p chm nhit thng.
- Ca,Sr,Ba p nhit thng.
VD: Ca + 2 H
2
O Ca(OH)
2
+H
2

Mg + 2H
2
O MgO + H
2

IV. ng dng v iu ch:
1. ng dng:
- Kim loi Be to ra nhng hp kim bn, c
tnh n hi cao.
- Kim loai Mg to ra hp kim nh ,bn.
- Ca: Dng tch oxi, S ra khi thp.
2. iu ch:
* P
2
: pnc mui halogenua.
Vd:
MgCl
2
Mg + Cl
2

TQ:
MX
2
M + X
2

4. Cng c, dn d
- GV h thng li ni dung cn nh trong bi nh tnh cht ha hc ca kim loi
kim th, so snh kh nng phn ng ca kim loi kim v kim loi kim th.
- HS lm bi tp 1 trong SGK trang 118.
5. H-ng dn v nh
Bi tp 4/SGK trang 119.

Ngy son 16/01/2010

Tit 44
ca kim loi kim th
-------------------
I. Mc tiu bi hc
1. Kin thc
- HS bit: + Tnh cht v ng dng mt s hp cht quan
trng ca kim loi kim th.
+ HS hiu tnh cht ho hc ca hdroxit, cacbonat,sunfat ca kim loi kim th.
+ Mt s ng dng quan trng ca mt s h/c KLKT
- HS hiu: Nguyn nhn tnh kh mnh ca kim loi kim th.
2. K nng
iu ch.
- Bit cch tin hnh mt s th nghim kim tra nh gi tnh cht ho hc ca Ca(OH)
2
,
CaCO
3
, CaSO
4
.
- Vn dng kin thc bit v s hu phn, quan nim axit, baz, tnh cht ha hc ca axit,
baz,... tm hiu tnh cht ca mt s hp cht.
- Bit cch nhn bit tng cht Ca(OH)
2
, CaCO
3
, CaSO
4.

3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Trnh by tnh cht ha hc ca kim loi kim th, vit pthh
minh ha.

t
o

t
o

t
o

3. Cc hot ng dy hc
sinh
Ni dung kin thc

HOT NG 1
Gv: Yu cu HS vit cc p nhit phn mt s
hp cht ca KLKT.

HS: vit p v rt ra nhn xt.

Hi: Hy nghin cu bng tnh tan ca cc
cht v cho bit tnh tanca cc mui v
hidroxit ca KLKT ?
HOT NG 2
HS: nghin cu tnh cht vt l ca Ca(OH)
2

da vo quan st mu Ca(OH)
2
.
Hi: dung dch Ca(OH)
2
c tnh cht g ? hy
nu nhng tnh cht ho hc c trng v vit
p minh ho.

HS:
Ca(OH)
2
+ CO
2

GV: hng dn HS lp t l: nOH
-
/n
CO2
.

Ca(OH)
2
+ FeCl
2

Hi: hy cho bit nhng ng dng trong thc
t ca Ca(OH)
2
m em bit ?
HS: nghin cu SGK v tr li.
HOT DNG 3
Hi: CaCO
3
l mui ca axit no ? hy nu
nhng tnh cht hoa hc ca CaCO
3
?

HS: vit ptp minh ho.

GV: CaCO
3
phn ng vi CO
2
v H
2
O to
ra mui axit, hy vit phn ng xy ra
chiu thun gii thch s xm thc ca nc
ma i vi vi, chiu nghch gt s to
thnh thch nh trong cc hang ng, cn
vi trong m un nc.
B. MT S HP CHT QUAN TRNG
CA CANXI
I. Mt s tnh cht chung ca hp
cht KLKT.
1. Tnh bn i vi nhit:
- Cc mui nitrat,cacbonat, hidroxit ca
KLKT b phn hu khi un nng.
VD:
2Mg(NO
3
)
2
2MgO +4NO
2
+O
2

CaCO
3
CaO + CO
2

Mg(OH)
2
MgO + H
2
O
2. Tnh tan trong H
2
O.
SGK
II. Mt s hp cht ca KLKT:
1. Canxihidroxit:
a) Tnh cht:
- L cht rn mu trng, t tan trong nc
- dung dch Ca(OH)
2
(nc vi trong) l
mt baz mnh.
Ca(OH)
2
Ca
2+
+ 2OH
-

- Dung dch Ca(OH)
2
c nhng tnh cht
ca mt dung dch baz kim.
VD: Ca(OH)
2
+ HNO
3

Ca(OH)
2
+ CuSO
4

b) ng dng:
SGK
2. Canxicacbonat:
a) Tnh cht:
- L cht rn mu trng khng tan trong
nc
- L mui ca axit yu nn p vi nhng
axit mnh hn
VD: CaCO
3
+ HCl
CaCO
3
+ CH
3
COOH
- Phn ng vi CO
2
v H
2
O:
CaCO
3
+ CO
2
H
2
O Ca(HCO
3
)
2

b) ng dng :

HOT NG 4
HS: c nhng ng dng ca CaCO
3

Hi: canxicacbonat kt tinh c my loi ?

- c thch cao nung v thch cao khan ta
phi thc hin qu trnh no ?

HS: tm hiu cc ng dng ca thch cao.

3. Canxi sunfat: CaSO
4

- L cht rn, mu trng , t tan trong
nc.
- Tu theo lng nc kt tinh m ta c 3
loi:
. CaSO
4
.2H
2
O: thch cao sng
. 2CaSO
4
. H
2
O: thch cao nung
. CaSO
4
: thch cao khan.
2CaSO
4
. 2H
2
O 2CaSO
4
.H
2
O + 3 H
2
O
* ng dng:
4. Cng c, dn d
- GV h thng li ni dung cn nh trong bi, tnh cht ca mt s hp
cht nh-: Ca(OH)
2
, CaCO
3
, CaSO
4
.
5. H-ng dn v nh
Bi tp 5,6,7/SGK trang 119.

Ngy son 17/01/2010

Tit 45
ca kim loi kim th
-------------------
I. Mc tiu bi hc
1. Kin thc
- HS bit: + Hc sinh bit c nc t nhin khc vi nc ct hoc nc ma ly
trc tip, v sao c cha cation Ca
2+
, Mg
2+
. Sau nh ngha c nc cng v nc mm.
+ Bit cch phn loi nc cng, nm c nhng anion gc axit no c trong
mi loi nc cng.
+ Tc hi ca nc cng i vi i sng v sn xut.
+ Bit cch lm mm nc cng, HS nm c nguyn tc v phng php ca
vic lm ny, vit c phn ng minh ho.
+ N-c cng l g?
- HS hiu: Nguyn tc v pp lm mm n-c cng.
2. K nng
iu ch.
3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c

t
o

Trnh by tnh cht ha hc ca mt s hp cht nh-: Ca(OH)
2
, CaCO
3
,
CaSO
4
, vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc
HOT NG 1
Hi: 1) Nc c vai tr nh th no i vi
i sng con ngi v sn xut?
2) Nc sinh hot hng ngy ly t u? L
ngun nc g?
GV: thng bo

- Nc t nhin ly t sng sui, ao h.
nc ngm l nc cng, vy nc
cng l g?
- Nc mm l g? ly vd

HOT NG 2
GV: Tu thuc vo thnh phn anion gc axit
c trong nc cng , ngi ta chia lm 2 loi:
GV: Ly vd cc mui trong nc cng tm
thi
HS: tm ra c im ca nc cng tm thi

HS: Nghin cu sgk v cho bit nc cng
tm thi v nc cng vnh cu khc nhau
im no ?
HOT NG 3
Hi: Trong thc t em bit nhng tc hi
no ca nc cng ?
HS: c sgk v tho lun
HOT NG 4
Gv: Nh chng ta bit nc cng c cha
cc ion Ca
2+
, Mg
2+
, vy theo cc em ngyun
tc lm mm nc cng l g?

Hi: Nc cng tm thi c cha nhng mui
no ? khi ung nng th c nhng phn ng
ho hc no xy ra ?

- C th dng nc vi trong va
trung ho mui axit tnh mui trung
ho khng tan , lc b cht khng tan
I. Nc cng:
- Nc c vai tr cc k quan trng i
vi i sng con ngi v sn xut.
- Nc thng dng l nc t nhin c
ho tan mt s hp cht ca canxi,
magie nh: Ca(HCO
3
)
2
, Mg(HCO
3
)
2
...,
CaSO
4
, MgSO
4
, CaCl
2
...= v vy nc
t nhin c cha cc ion Ca
2+
, Mg
2+
.
- Nc c cha nhiu ion Ca
2+
, Mg
2+
gi
l nc cng. nc c cha t hoc
khng cha cc ion trn gi l nc
mm.
II. Phn loi nc cng:
Tu thuc vo thnh phn anion gc axit c
trong nc cng, chia lm 2 loi:
1. Nc cng tm thi: l nc cng c
cha anion HCO
3
-
. ( ca cc mui
Ca(HCO
3
)
2
, Mg(HCO
3
)
2
)
2. Nc cng vnh cu: l nc cng c
cha cc ion Cl
-
, SO
4
2-
hoc c 2. ( ca
cc mui CaCl
2
, CaSO
4
, MgCl
2
...).

III. Tc hi ca nc cng:

GV m thoi vi hc sinh cc tc hi ca nc
cng .

IV. Cch lm mm nc cng:
Nguyn tc: lm gim nng ion Ca
2+
, Mg
2+

trong nc cng bng cch chuyn 2 ion t do
ny vo hp cht khng tan hoc thay th
chng bng nhng cation khc.
= c 2 phng php:
1. Phng php kt ta:
a) i vi nc cng tm thi:
- un si trc khi dng
M(HCO
3
)
2
MCO
3
1 + CO
2
+ H
2
O
lc b kt ta c nc mm.
- Dng nc vi trong va :

c nc mm.
Hi: Khi cho dung dch Na
2
CO
3
, Na
3
PO
4
vo
nc cng tm thi hoc vnh cu th c hin
tng g xy ra ? Vit p di dng ion.

HOT NG 5
Gv: Da trn kh nng c th trao i ion ca
mt s cht cao phn t t nhin hoc nhn
to.
Vd: natri silicat.
M(HCO
3
)
2
+ Ca(OH)
2
MCO
3
1 + CaCO
3
1 +
2H
2
O
b) i vi nc cng vnh cu:
dng cc dung dch Na
2
CO
3
, Na
3
PO
4
lm
mm nc.
M
2+
+ CO
3
2-
MCO
3

3M
2+
+ 2PO
4
3-
M
3
(PO
4
)
2

2. Phng php trao i ion: cho nc cng i
qua cht trao i ion( ionit), cht ny hp th
Ca
2+
, Mg
2+
, gii phng Na
+
, H
+
nc mm .

4. Cng c, dn d
5. H-ng dn v nh
Bi tp 8, 9/SGK trang 119.


Ngy son 19/01/2010
Tit 46
Bi 28. luyn tp
tnh cht ca kim loi kim, kim loi kim th
v hp cht ca chng
-------------------
I. Mc tiu bi hc
1. Kin thc
+ Hieu c moi quan he gia kim loai kiem va kim loai kiem tho,
nhom ve cau tao nguyen t, tnh chat hoa hoc cua n chat va hp chat.
2. K nng
- So sanh tnh baz gia cac hp chat hiroxit gia cac kim loai tren.
Viet PTHH.
- Rn k nng gii bi tp v kim loi kim v kim
loi kim th.
3. Tnh cm, thi
II. Trng tm
Tnh cht ca kim loi kim, kim loi kim th.
III. Chun b
Gio vin: Chun b ni dung bi dy, mot so bang e hoc sinh ghi tiep
kien thc ma cac em a c hoc
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
GV neu muc ch cua bai luyen tap.

I. Kin thc cn nh.
Hot ng 1. Cng c kin thc v v tr v cu to
- V tr, Che lp ngoi cng ca nguyn t cc nguyn t nhm IA
v IIA.
- Nguyn nhn tnh kh rt mnh ca nhm IA to ra s oxi ha +1
v tnh kh mnh ca nhm IIA to ra s oxi ha +2.
Hot ng 2. Cng c quy lut bin i tnh cht vt l
- HS nhn xt bng mt s hng s vt l quan trng ca kim loi
nhm IA v IIA, so snh, nhn xt nhit si, nhit nng
chy.
Hot ng 3. Cng c kin thc v cc hp cht: NaOH, NaHCO
3
,
Na
2
CO
3
, KNO
3
, Ca(OH)
2
, CaCO
3
, CaSO
4
.2H
2
O.
- HS tm th d v phn ng minh ha cho tnh cht tiu biu.
Hot ng 4. Cng c kin thc v n-c cng.
GV tien hanh phat cac phieu hoc tap cho tng nhom va yeu cau cac em viet cac
kien thc ma phieu hoc tap yeu cau, sau o ai dien cua tng nhom len trnh
bay phan kien thc cua to mnh trc lp.
GV hng dan cac em trnh bay va chot lai cac kien thc can nh.
GV sau khi on lai kien thc can nh gv yeu cau hoc sinh giai bai tap
II. Bi tp.
1. Hay neu phng phap hoa hoc nhan biet :
a. 3 kim loai: Al, Mg, Na
b. 3 oxit: Al
2
O
3
, MgO, Na
2
O
c. 3 hiroxit: AlOH
3
, Mg(OH)
2
, NaOH
d. 3 muoi ran: NaCl, AlCl
3
, MgCl
2

2. Hay neu iem chung ve phng phap ieu che kim loai kiem, kim loai kiem tho,
nhom. Lay v du minh hoa, viet PTHH
GV chon bai tap 2, 3, 4 SGK e hoc sinh lam tai lp.
GV cho mot bai tap lien quan en 3 kim loai tren.

GV anh gia ket qua bang tra li cua tng nhom va cho iem tng nhom.
4. Cng c, dn d
5. H-ng dn v nh
Bi tp 1, 5, 6/SGK trang 132.

Ngy son 29/01/2010

Tit 47
Bi 27. nhm v hp cht ca nhm
-------------------
I. Mc tiu bi hc
1. Kin thc
Bit c v tr ca nhm trong bng tun hon, bit cu to nguyn t v bit c cu
hnh electron v s e ho tr ca Al.
Bit nhng tnh cht vt l quan trng ca Al: dn in, dn nhit tt, nh v bn.
Nm c tnh cht ho hc ca Al l tnh kh mnh, trong cc phn ng ho hc n d
b oxi ho thnh ion c in tch duy nht l Al
3+
. Gii thch c tnh cht ny v c kh
nng dn ra c nhng phn ng ho hc minh ho tnh kh mnh ca Al.
T nhng tnh cht vt l, ho hc ca Al, HS suy ra nhng ng dng quan trng.
Hiu nguyn nhn tnh kh mnh nhm v v sao nhm ch c
s oxi ha +3 trong cc hp cht.
2. K nng
- Tin hnh mt s th nghim n gin.
- Gii bi tp v nhm.
3. Tnh cm, thi
C thc bo qun nhng vt bng nhm.
II. Trng tm
V tr, tnh cht ha hc ca nhm.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy so snh c im cu to nguyn t v t/c ha hc ca kim
loi kim v kim loi kim th.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

A. NHM
I. V tr trong bng tun hon, cu

t
o

HOT NG 1
HS: vit cu hnh e ca nhm v cho bit v tr
ca nhm trong BTH.
GV: yu cu hs xem BTH.
HS: xc nh trong mi chu k , nhm III A,
kim loi nhm ng sau v trc nguyn t
no ?
Hi:
1) Hy cho bit nhm thuc loi nguyn t g
? c bao nhiu e ho tr ?

2) Nhn xt g v nng lng ion ho ca
nhm t cho bit tnh cht c bn ca nhm
v s oxi ho ca n trong cc hp cht
HOT NG 2
HS: nghin cu sgk v tho lun rt ra nhng
tnh cht vt l quan trng ca nhm.
HOT NG 3
Hi: da vo cu to nguyn t, E
o
Al
3+
/Al ;
Nng lng ion ho ca nhm, hy cho bit
tnh cht ho hc ca nhm l g ?

HS: ly vd v mt s phn ng ca nhm vi
phi kim hc.

HS: xc nh s oxi ho v vai tr ca nhm
trong phn ng trn.
HOT NG 4
GV lm th nghim: cho mt mu nhm vo
dung dch HCl, cho HS quan st hin tng v
yu cu HS vit ptp xy ra dng phn t v
ion thu gn.

Hi:
1) Al c p c vi dung dch HNO
3
c
ngui, H
2
SO
4
c ngui? v sao ?

2) Hy vit p ca Al vi HNO
3
long, H
2
SO
4

c, nng ?

hnh electron nguyn t:
1. V tr ca nhm trong bng tun hon:
Al
13
: 1s
2
2s
2
2p
6
3s
2
3p
1

V tr: chu k 3, nhm IIIA
- Trong chu k Al ng sau Mg, trc Si
- Trong nhm IIIA: Al ng sau B.

2. Cu to ca nhm:
- L nguyn t p, c 3 e ho tr. Xu
hng nhng 3 e to ion Al
3+

Al Al
3+
+ 3e
[Ne]3s
2
3p
1
[Ne]
- Trong hp cht nhm c s oxi ho +3
vd: Al
2
O
3
, AlCl
3

- Cu to n cht : LPTD
II. Tnh cht vt l ca nhm
(sgk)
III. Tnh cht ho hc:
E
o
Al
3+
/Al = -1,66 V; I
1
, I
2
, I
3
thp - Al l
kim loi c tnh kh mnh. (yu hn KLK,
KLK th)
1. Tc dng vi phi kim: tc dng trc
tip v mnh lit vi nhiu phi kim.
Vd: 4 Al + 3O
2
2 Al
2
O
3

2 Al + 3Cl
2
2 AlCl
3

- Al kh nhiu phi kim thnh ion m .
2. Tc dng vi axit:
a) Vi cc dung dch axit HCl,
H
2
SO
4
long:
Vd: 2Al + 6HCl 2AlCl
3
+ 3H
2

2Al + 3 H
2
SO
4
Al
2
(SO
4
)
3
+ 3 H
2

Pt ion: 2Al + 6H
+
2 Al
3+
+ 3H
2

- Al kh ion H
+
trong dung dch axit thnh
hidro t do.
b) Vi dung dch HNO
3
, H
2
SO
4
c:
- Al khng p vi HNO
3
c ngui,
H
2
SO
4
c ngui.
- Vi cc axit HNO
3
c nng, HNO
3

long, H
2
SO
4
c nng: Al kh c
5 +
N
v
6 +
S xung nhng mc oxi ho thp
hn.
Al + 6HNO
3
Al(NO
3
)
3
+ 3NO
2
+ 3H
2
O
Al + H
2
SO
4


t
o

pnc, xt

HOT NG 5
Hi:
1) Cho E
o
Al
3+
/Al < E
o
H
2
O/H
2
, vy nhm
c tc dng c vi nc khng ?
2) V sao nhng vt bng nhm hng ngy tip
xc vi nc d nhit cao nhng khng
xy ra phn ng ?
HOT NG 6
Gv: nhit cao, Al c th kh c nhiu
ion kim loi trong oxit thnh kim loi t do,
phn ng to nhiu nhit.

Hi: Hy xc nh s oxi ho ca cc phn
ng trn v cho bit loi ca p.
HS: Vit p: Al + Ba(OH)
2
+ H
2
O

Hi: Vai tr ca nhm trong phn ng?

HOT NG 7
HS: Nghin cu nhng ng dng trong sgk

HS: Nghin cu sgk cho bit dng tn ti ca
nhm trong t nhin

GV: Treo s thng in phn Al
2
O
3
nng
chy.

HS: Quan st, m t cc phn ca thng in
phn v vit cc qu trnh xay ra ti in cc.

3. Tc dng vi H
2
O:
Do E
o
Al
3+
/Al < E
o
H
2
O/H
2
- Al kh c
nc.
2Al + 6H
2
O 2 Al(OH)
3
+ 3 H
2

- phn ng dng li nhanh v c lp Al(OH)
3

khng tan trong H
2
O bo v lp nhm bn
trong.

4. Tc dng vi oxit kim loi:
- nhit cao, Al kh c nhiu ion
kim loi km hot dng hn trong oxit (
FeO, CuO, ...) thnh kim loi t do.
Vd: Fe
2
O
3
+ 2 Al Al
2
O
3
+ 2 Fe
2 Al + 3 CuO
= phn ng nhit nhm.
5. Tc dng vi baz: nhm tc dng vi
dung dch baz mnh: NaOH, KOH,
Ca(OH)
2
....
Vd:2Al +2NaOH +6H
2
O2Na[Al(OH)
4
] +3H
2

natri aluminat
IV. ng dng v trng thi t nhin:
1. ng dng:
2. Trng thi t nhin:
Hp cht nh t st(Al
2
O
3
.2SiO
2
.2H
2
O),
mica(K
2
O.Al
2
O
3
.6SiO
2
), boxit(Al
2
O
3
.2H
2
O),
criolit(3NaF.AlF
3
)
V. Sn xut:
Nguyn liu: Qung boxit (Al
2
O
3
.2H
2
O) ln
tp cht l Fe
2
O
3
v SiO
2

Qua 2 cng on:
cng on tinh ch qung boxit.
cng on pnc Al
2
O
3

- h nhit nng chy ca Al
2
O
3
t
2050
o
C xung 900
o
C, ho tan Al
2
O
3

trong criolit n/c.

ptp: Al
2
O
3
2Al + 3/2O
2

4. Cng c, dn d
- GV h thng li ni dung cn nh trong bi, cng c bng
bi tp 1, 2 trong SGK/128.
5. H-ng dn v nh
Bi tp 3, 4/SGK trang 128, 129.

Ngy son 01/02/2010
Tit 48
Bi 27. nhm v hp cht ca nhm
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Tnh cht v ng dng ca mt s hp cht ca
nhm.
Nm c tnh cht ho hc quan trng ca Al
2
O
3
l cht lng tnh v dn ra c
nhng phn ng ho hc minh ha nhng tnh cht ny.
Nm c nhng tnh cht ca Al(OH)
3,
l :
a) Tnh cht lng tnh, gii thch v dn ra c nhng phn ng minh ho.
b) Tnh cht khng bn i vi nhit.
Vn dng nhng kin thc ttng hp v tinh cht ho hc ca Al, Al
2
O
3
v Al(OH)
3
l
gii hin tng mt vt bng nhm b ph hu trong mi trng kim.
Bit cch phn bit nhng hp cht ca nhm, hp cht ca nhm vi kim loi nhm IA.
IIA.
2. K nng
- Tin hnh mt s th nghim n gin.
- Gii bi tp v nhm.
3. Tnh cm, thi
C thc bo qun nhng vt bng nhm.
II. Trng tm
Tnh cht ha hc ca cc hp cht cha nhm.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by tnh cht ha hc ca nhm, vit pthh minh ha.
3. Cc hot ng dy hc
Hot ng ca gio vin v hc Ni dung kin thc

t
o

sinh

HOT NG 1
Hi: Hc sinh quan st mu ng Al
2
O
3
, nhn
xt cc hin tng vt l.

- Trong t nhin Al
2
O
3
tn ti nhng
dng no?

- rubi v saphia, hin nay iu ch
nhn to.

HOT NG 2
Gv; Thng bo, ion Al
3+
c in tch ln nn
lc ht gia ion Al
3+
v ion O
2-
rt mnh, to
ra lin kt trong Al
2
O
3
rt bn vng.

GV; Lm th nghim: cho Al
2
O
3
tc dng vi
dung dch HCl, NaOH, cho hc sinh quan st
hin tng.
HS: Vit cc phng trnh phn ng xy ra
Kt lun tnh cht ca Al
2
O
3

C) ng dng ca Al
2
O
3
:
- HS nghin cu sgk v cho bit cc ng dng
ca nhm oxit.(sx nhm, lm trang sc...)

HOT NG 3
GV: Al(OH)
3
l hp cht km bn i vi
nhit, b phn hu khi un nng. Hy vit
phng trnh phn ng xy ra ?
GV: Lm th nghim:
Dung dch HCl

Al(OH)
3

Dung dch NaOH

B. MT S HP CHT QUAN TRNG
CA NHM
I. Nhm oxit: Al
2
O
3

1. Tnh cht vt l v trng thi t nhin:
- L cht rn mu trng, khng tan v
khng tc dng vi nc.t
o
n/c > 2050
o
C
- Trong v qu t, Al
2
O
3
tn ti cc
dng sau:
+ Tinh th Al
2
O
3
khan l qu rt cng:
+Corinon: trong sut, khng mu.
+ rubi(hng ngc): (ion Cr
3+
)mu
+ saphia: (ln Fe
2+
, Fe
3+
v Ti
4+
)mu
xanh.
2. Tnh cht ho hc:
a) Al
2
O
3
l hp cht rt bn:
- Al
2
O
3
l hp cht ion, dng tinh th
n rt bn v mt ho hc, t
o
n/c =
2050
o
C.
- Cc cht: H
2
, C, CO, khng kh c
Al
2
O
3
.
b) Al
2
O
3
l cht lng tnh:
- Tc dng vi axit mnh:
Al
2
O
3
+ 6HCl 2AlCl
3
+ 3 H
2
O
Al
2
O
3
+ 6H
+
2Al
3+
+ 3 H
2
O
- C tnh cht ca oxit baz.
- Tc dng vi cc dung dch baz mnh:
AL
2
O
3
+2NaOH + 3H
2
O 2Na[Al(OH)
4
]
Al
2
O
3
+2OH
-
+ 3H
2
O 2[Al(OH)
4
]
-

- C tnh cht ca oxit axit .
II. Nhm hidroxit: Al(OH)
3
.
1. Tnh cht ho hc:
a) Tnh bn vi nhit:
2 Al(OH)
3
Al
2
O
3
+ 3 H
2
O
b) L hp cht lng tnh:
- Tc dng vi cc dung dch axit mnh:
3 HCl + Al(OH)
3
AlCl
3
+ 3 H
2
O
3 H
+
+ Al(OH)
3
Al
3+
+ 3 H
2
O
- Tc dng vi cc dung dch baz mnh:
Al(OH)
3
+ NaOH Na[Al(OH)
4
]
Al(OH)
3
+ OH
-
[Al(OH)
4
]
-

- Nhng vt bng nhm b ho tan
trong dung dch NaOH, Ca(OH)
2
..l do
mng bo v:
Al
2
O
3
+2NaOH + 3H
2
O 2Na[Al(OH)
4
]
2 Al + 6 H
2
O 2 Al(OH)
3
+ 3 H
2


Al(OH)
3

HS: Quan st hin tng xy ra v vit
phng trnh phn ng chng minh hin tng
.
Hi: V sao nhng vt bng nhm khng tan
nc nhng b ho tan trong dung dch
NaOH?
HOT NG 4
Hi: V sao phn chua c th lm trong nc
c ?
Al(OH)
3
+ NaOH Na[Al(OH)
4
]
III. Nhm sunfat: Al
2
(SO
4
)
3
.
Quan trng l phn chua:
Cng thc ho hc: K
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O
Hay KAl(SO
4
)
2
.12H
2
O

* ng dng: Phn chua c dng trong cng
nghip thuc da, CN giy....

IV. Cch nhn bit ion Al
3+
trong
dung dch
Thuc th: dd NaOH
Hin tng: c kt ta keo xut hin ri tan
trong NaOH d.
Al
3+
+ 3OH
-
Al(OH)
3
1
Al(OH)
3
+ OH
-
(d) AlO
2
-
+ 2H
2
O
4. Cng c, dn d
5. H-ng dn v nh
Bi tp 5, 6, 7, 8/SGK trang 129.

Ngy son 03/02/2010
Tit 49
Bi 30. Thc hnh: tnh cht ca Na, Mg, Al

v HP CHT CA CHNG.
-------------------
I. Mc tiu bi hc
1. Kin thc
Cung co kien thc ve: day ien hoa cua kim loai, ieu che kim loai, s
an mon kim loai.
- So sanh phan ng cua Al, Fe, Cu vi ion H
+
trong dung dch HCl (day ien
hoa cua kim loai).
- Fe phan ng vi Cu
2+
trong dung dch CuSO
4
(ieu che kim loai bang cach
dung kim loai manh kh kim loai yeu trong dung dch).
- Zn phan ng vi dung dch H
2
SO
4
, dung dch H
2
SO
4
them CuSO
4
(s an
mon ien hoa hoc).
2. K nng
Tiep tuc ren luyen cac k nang thc hanh hoa hoc: lam viec vi dung cu
th nghiem, hoa chat, quan sat hien tng.
Van dung e giai thch cac van e lien quan en day ien hoa cua kim
loai, ve s an mon kim loai, chong an mon kim loai
3. Tnh cm, thi
II. Trng tm
III. Chun b
Gio vin:
Dung cu th nghiem Hoa chat
- Coc thuy tinh 500ml: 3
- Ong hnh tru co e: 1
- Ong nghiem : 5
- Pheu thuy tinh c nho : 1
- Ong hut nho giot: 3
- Gia e ong nghiem: 1
- ua thuy tinh: 1
- Kep kim loai: 1
- Na
- Mg si hoac bang dai
- Al la
- Dung dch CuSO
4
ac
- Dung dch Al
2
(SO4)
3
ac
- Dung dch NaOH
- Dung dch H
2
SO
4
hoac HCl.

Chun b ni dung bi dy.

IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
Th nghiem 1: Phan ng cua Na, Mg, Al vi nc.
Chuan b va tien hanh th nghiem a, b nh SGK a viet.
1. Na tac dung vi nc nhiet o thng:
- Tien hanh th nghiem nh SGK
- Can lu y cho hoc sinh:
- Can at ong hnh tru trong coo thuy tinh 500ml. o nc vao coc cho en
khi mc nc dang len trong ong hnh tru ch cach mep di cua nut cao su
chng 1cm. Nham muc ch:
* am bao an toan hn do s tao thanh hon hp kh no ( H
2
mi tao
thanh va oxi cuakhong kh co san trong ong hnh tru) giam i nhieu.
* Tiet kiem hoa chat.
- Ong ot H
2
phai co au vuot nhon.
- e n gian hn ta co the thc hien phan ng trong mot th nghiem . at
ong nghiem tren gia e ong nghiem va rot nc vao ong cho en khi
mc nc cach nut di nut cao su chng 1cm.
Dung kep sat cho vao ong nghiem mieng Na bang hat au xanh. Mot tay
ay nhanh mieng nut cao su co ong dan kh xuyen qua, tay kia a que om
ang chay vao gan au ong dan kh. Co tieng no bep va ngon la hiro
chay.
2. Mg tac dung vi nc nhiet o thng:
- Thc hien th nghiem nh SGK.

- Lu y: at vao coc nc oan day Mg a lam sach va c uon theo hnh
lo so. Up ngc ong nghiem a cha ay nc len oan day Mg noi tren.
-GV: hng dan hoc sinh quan sat co rat t bot liti H
2
xuat hien tren day Mg
roi noi len tu lai ay ong nghiem up ngc. Hien tng xay ra rat
cham. Thay Mg bang kim loai nhomphan ng hoa hoc xay ra khong ro v
nhiet o thng tuy nhom co the kh c nc giai phong kh H
2
nhng
phan ng nhanh chong dng lai v lp nhom hiroxit khong tan trong nc a
ngan can khong cho nhom tiep xuc vi nc.
Th nghiem 2: Phan ng cua nhom vi dung dch CuSO
4
:
a. Chuan b va tien hanh th nghiem nh SGK
o Co the nhung la nhom vao dung dch HCl loang roi ra bang nc
sach e lam mat lp Al
2
O
3
bao phu ngoai la nhom.
o Can dung dch CuSO
4
ac.
o Co the thc hien phan ng trong hom nho cua e s gia th nghiem
thc hanh.
b. Quan sat hien tng xay ra va giai thch:
- Nhung la nhom vao ong nghiem cha dung dch CuSO
4
. khong co phan
ng hoa hoc say ra v trong khong kh be mat cua nhom c phu kn bang
mang Al
2
O
3
rat mong nhng rat vng chac.
- Sau khi dung giay rap mn anh sach lp Al
2
O
3
phu ngoai la nhom ta
nhung la nhom vao dung dch CuSO
4
th sau vai phut co lp vay mau o
bam len mat la nhom.
Th nghiem 3: Tnh chat cua nhom hiroxit:
a) Tien hanh th nghiem nh SGK va lu y khi ieu che ket tua Al(OH)
3
t dung
dch Al
2
(SO
4
)
3
ac va dung dch NaOH khong dung d NaOH.
b) Quan sat hien tng say ra va ket luan.
- Khi nho vai giot dung dch HCl vao Al(OH)
3
cha trong coc nc (1) th
Al(OH)
3
tao thanh AlCl
3
va nc.
- Nho vai giot dung dch NaOH ac vao Al(OH)
3
cha trong coc nc (2) th
Al(OH)
3
cung tan, tao thanh Na[ Al(OH)
4
]
- HS: viet phng trnh phan ng minh hoa.
- Ket luan: Al(OH)
3
la hp chat co tnh lng tnh
4. Cng c, dn d
5. H-ng dn v nh

Xem tr-c ni dung bi hc ti.

Ngy son 20/02/2010
Tit 50
Bi 29. Luyn tp: tnh cht ca nhm v hp cht ca
nhm
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: - Hieu c moi quan he gia kim loai kiem va kim loai kiem tho,
nhom ve cau tao nguyen t, tnh chat hoa hoc cua n chat va hp chat.
2. K nng

- So sanh cau hnh electron, nang lng ion hoa, ien tch ion, so oxi hoa cua
mot so nguyen to tieu bieu la Na, Mg va Al e thay c s khac nhau
va giong nhau gia chung.
- So sanh the ien cc chuan gia cac kim loai e thay c s giong nhau
va khac nhau gia chung.
- So sanh tnh baz gia cac hp chat hiroxit gia cac kim loai tren. Viet
PTHH.
3. Tnh cm, thi

II. Trng tm
Tnh cht ha hc ca cc hp cht.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
GV neu muc ch cua bai luyen tap.
GV tien hanh phat cac phieu hoc tap cho tng nhom va yeu cau cac
em viet cac kien thc ma phieu hoc tap yeu cau, sau o ai dien
cua tng nhom len trnh bay phan kien thc cua to mnh. Trc lp
GV hng dan cac em trnh bay va chot lai cac kien thc can nh.
BAI TAP:
GV: Sau khi on lai kien thc can nh gv yeu cau hoc sinh giai bai
tap.
V du:
1. Hay neu phng phap hoa hoc nhan biet :
a. 3 kim loai: Al, Mg, Na
b. 3 oxit: Al
2
O
3
, MgO, Na
2
O
c. 3 hiroxit: AlOH
3
, Mg(OH)
2
, NaOH
d. 3 muoi ran: NaCl, AlCl
3
, MgCl
2


2. Hay neu iem chung ve phng phap ieu che kim loai kiem, kim
loai kiem tho, nhom. Lay v du minh hoa, viet PTHH
3. Bai tap 2, 3, 4 SGK e hoc sinh lam tai lp.
4. GV cho mot bai tap lien quan en 3 kim loai tren.
5. GV anh gia ket qua bang tra li cua tng nhom va cho iem
tng nhm.
4. Cng c, dn d
5. H-ng dn v nh
Bi tp cn li trong SGK.

Ngy son 23/02/2010
Tit 51
kim tra 1 tit
-------------------
I. Mc tiu bi hc
1. Kin thc
Hs nm -c kin thc trong ch-ng 6.
2. K nng
II. Trng tm
Tnh cht ho hc cc cht hc.

III. Chun b
Gio vin: thi v p n
IV. Ph-ng php
V. bi
Chn kt qu ng mi cu v nh cho (x) vo bng sau :
1/ bo qun kim loi Na trong phng th nghim, ngi ta dng cch no sau y
A Ngm trong ru B Bo qun trong bnh kh NH
3

C Ngm trong nc D Ngm trong du ha
2/ Dy gm cc kim loi u phn ng d dng vi nc nhit thng l
A Mg, Na B Na, Ba C Mg, Ba D Cu, Al
3/ Hidroxit no sau y c tnh lng tnh
A NaOH B Cu(OH)
2

C Al(OH)
3
D Mg(OH)
2

4/ Kim loi kim c th iu ch c trong cng nghip theo phng php no sau y
A Nhit luyn B Thy luyn
C in phn dung dch D in phn nng chy
5/ Cc nguyn t nhm IA ca bng tun han c c im no chung sau y
A S e lp ngai cng B S lp e
C S ntron D S in tch ht nhn
6/ Cht no sau y c s dng kh tnh cng ca nc cng vnh cu
A NaNO
3
B Ca(OH)
2

C Cht trao i ion(Zeolit) D CaCl
2

7/ Loi qung no sau y c cha nhm xit trong thnh phn ha hc
A Pirit B Boxit
C lmit D vi
8/ Cc nguyn t kim loi no c sp xp theo chiu tng ca tnh kh
A Al, Fe, Zn, Mg B Ag, Cu , Al , Mg
C Na, Mg,Al, Fe D Ag, Cu, Mg, Al
9/ Trong s cc phng php lm mm nc cng sau , phng php no ch lm mm nc
cng tm thi ?
A Phng php ha hc B Phng php trao i ion
C Phng php ct nc D Phng php un si nc
10/ Trng hp no sau y l n mn in ha ?
A Km b ph hy trong kh clo B Km trong dung dch H
2
SO
4
lang
C Natri chy trong khng kh D Thp trong khng kh m
11/ Hin tng hp kim dn in v dn nhit km kim loi nguyn cht v lin kt ha hc
trong hp kim l :

A Lin kt ion B Lin kt kim loi v lin kt cng ha tr
C Lin kt kim loi D Lin kt cng ha tr lm gim mt e t do
12/ Dy gm cc kim loai u phn ng vi dung dch CuSO
4
l :
A Al , Fe, Mg , Cu B Na, Al, Fe, Ba
C Na, Al, Cu D Ba, Mg, Ag ,Cu
13/ Dung dch A cha 5 ion : Mg
2+
, Ba
2+
, Ca
2+
v 0,1 mol Cl
-
, 0,2 mol NO
3
-
. Thm dn V
lt dung dch K
2
CO
3
1M vo dung dch A n khi c lng kt ta ln nht . V c
gi tr l :
A 0,15 B 0,25 C 0,3 D 0,2
14/ Hin tng no xy ra khi cho t t dung dch HCl cho n d vo dung dch
natrialuminat
A Khng c hin tng no xy ra
B C kt ta dng keo , kt ta khng tan
C Ban u c kt ta dng keo, lng kt ta tng dn n cc i, sau kt
ta tan dn
D Ban u c kt ta dng keo, sau tan n
15/ Dy kim loi no sau y c sp xp theo chiu tng tnh dn in tng dn :
A Fe, Al, Cu, AG B Ca, Mg, Al, Fe
C Fe, Mg, Au , Hg D Cu, Ag, Au, Ti
16/ Ha tan 0,5 gam hn hp gm Fe v mt kim loi ha tr 2 trong dung dch HCl thu c
1,12 lit kh (ktc) . kim loi ha tr 2 l
A Zn B Mg C Ca D Be
17/ Cho 16,2 gam mt kim loi M c ha tr n tc dng vi 0,15 mol oxi. cht rn thu c
sau phn ng dem ha tan vo dung dch HCl d thy that ra 13,44 lt kh H
2
(ktc), phn
ng xy ra han tan . kim loi M l
A Mg B Ca C Al D Fe
18/ ha tan han tan 20 gam hn hp Fe v Mg trong dung ch HCl thu c 1 gam kh H
2

. c cn dung dch th thu c bao nhiu gam mui khan
A 55,5gam B 50gam C 56,5 gam D 27,55 gam
19/ Ha tan 4,59 gam Al bng dung dch HNO
3
lang thu c hn hp kh gm NO v N
2
O
c t khi hi i vi H
2
l 16,75. t l th tch ca kh N
2
O/NO l :
A 2/3 B 1/3 C 3/1 D 3/2
20/ Ha tan han tan 0,1 mol hn hp Na
2
CO
3
v KHCO
3
vo dung dch HCl d, dn
kh thu c vo bnh ng dung dch Ca(OH)
2
d th lng kt ta to ra l m gam.
Gi tr ca m l :
A 7,5 B 10 C 15 D 0,1
21/ C 6 dung dch ng trong 6 l : NH
4
Cl, (NH
4
)
2
SO
4
, MgCl
2
, AlCl
3
, FeCl
2
, FeCl
3
. ch
dng mt cht no sau y gip nhn bit 6 cht trn
A Dung dch NaOH B Dung dch Ba(OH)
2

C Dung dch ZnSO
4
D Dung dch NH
3


22/ Cho 3,87 gam bt nhm phn ng va vi dung dch mui XCl
3
to thnh dung dch
Y. khi lng cht tan trong dung dch Y gim 4,06 gam so vi dung dch XCl
3
. Cng thc
phn t cu mui XCl
3
l cht no sau y :
A CrCl
3
B FeCl
3
C BCl
3
D AlCl
3

23/ Ha tan han tan 23,8 gam hn hp mt mui cacbonat ca kim loi ha tr I v mt
mui cacbonat ca kim lai ha tr II vo dung ch HCl thy that ra 0,2 mol kh. khi c cn
dung dch sau phn ng th thundcc bao nhiu gam mui khan:
A 26gam B 26,8 gam C 28 gam D 28,6 gam
24/ Hn hp X gm 2 kim lai A v B nm k tip nhau trong bng tun han. Ly 6,2 gam
X ha tan han t5an vo nc thu c 2,24 lt H
2
(ktc). A v B l 2 kim lai
A Na, K B K, Rb C Li, Na D Rb, Cs
25/ Nhng mt thanh nhm nng 50 gam v 400 ml dung dch CuSO
4
0,5 M . sau mt thi
gian ly thanh nhm ra cn nng 51,38 gam . khi lng Cu that ra l:
A 0,64 gam B 1,92 gam C 1,28 gam D 2,56 gam

VI. p n, thang im

Ngy son 28/02/2010
Tit 52 Ch-ng 7. st v mt s kim loi quan trng
Bi 31. st
-------------------
I. Mc tiu bi hc
1. Kin thc
HS hiu: - Bit v tr nguyn t st trong bng tun hon
- Bit cu hnh e nguyn t cu cc ion Fe
2+
, Fe
3+

- Hiu c tnh cht ho hc c bn ca n cht st.
2. K nng

- Tip tc rn luyn k nng vit cu hnh e nguyn t v cu hnh e ca ion
- Rn luyn kh nng hc tp theo phng php so snh, i chiu v suy lun logic
3. Tnh cm, thi
II. Trng tm
Tnh cht ca kim loi.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Vit pthh minh ha tnh cht ha hc ca nhm.
3. Cc hot ng dy hc
sinh
Ni dung kin thc

HOT NG 1
GV: Treo bng tun hon.
HS: tm v tr ca Fe trong BTH v cho bit s
hiu nguyn t v NTKTB ca Fe .
Hi: Cho bit cc nguyn t nm ln cn
nguyn t st ?
GV t cc cu hi sau:
1) Hy vit cu hnh e ca nguyn
t Fe, ion Fe
2+
, Fe
3+
?
2) Phn b cc e vo cc lng
t.
3) Yu cu HS xc nh s xi ha
ca Fe trong cc hp cht sau: FeO, Fe
2
O
3
,
FeCl
3
, Fe
2
(SO
4
)
3
.
HS: c sgk v tm hiu mt s tnh cht khc
ca Fe nh: r, th in cc chun...

I. V tr v cu to:
1. V tr ca Fe trong BTH
v tr: stt : 26
chu k 4, nhm VIIIB
- Nhm VIIIB, cng chu k vi st cn
c cc nguyn t Co, Ni. Ba nguyn t
ny c tnh cht ging nhau.
2. Cu to ca st:
- Fe l nguyn t d, c th nhng 2 e
hoc 3 e phn lp 4s v phn lp 3d
to ra ion Fe
2+
,Fe
3+
.
- Mng tinh th: ph thuc vo nhit
- Trong hp cht, st c s oxi ho l
+2, +3. Vd: FeO, Fe
2
O
3

3. Mt s tnh cht khc ca st:
E Fe
2+
/Fe = -0,44V; E Fe
3+
/Fe
2+
= +....V

t
o

HOT NG 2
Hi: Da vo kin thc c, sgk hy cho bit
st c nhng tnh cht vt l c bit g ?

GV: b sung v kt lun.

HOT NG 3
GV: phn tch: St c bao nhiu e lp ngoi
cng ? Trong cc phn ng ha hc nguyn t
st d nhng bao nhiu e ?
HS: Do st l nguyn t d nn e ha tr nm
phn lp s v d. Khi tc dng vi cht oxi ha
mnh Fe c th nhng thm 1e phn lp 3d.
Vy tnh cht ha hc ca st l g ?
HOT NG 4
Hi: Hy nu mt s v d v p tc dng ca
st vi phi kim ?
- nhit thng st tc dng vi oxi
hay khng ? Nu vt bng st trong
khng kh m s c hin tng g ?
GV: Tu vo tnh oxi ha ca phi kim m Fe b
oxi ha thnh +2 hoc +3.
- hy xc nh vai tr ca cc cht trong
p.
HOT NG 5
Hi: Hy vit p xy ra khi cho Fe tc dng
vi dd HCl, H
2
SO
4
long? Xc nh vai tr ca
cc cht /
GV: lm th nghim Fe + HCl
- Cht oxi ha l ion H
+
, ch oxi ha Fe
thnh Fe
2+
.
GV: Fe tc dng c vi HNO
3
c ngui,
H
2
SO
4
c ngui hay khng ?
Hi: HNO
3, nng;
H
2
SO
4c nng
l nhng cht oxi
ha mnh, s oxi ha Fe v mc oxi ha no ?
HS: vit ptp ?
- HS vit ptp ca Fe vi dung dch
HNO
3
long, v cho bit sp khc vi t/h
trn hay khng ?

HOT NG 6
GV: Hy vit p xy ra khi cho Fe vo cc
dung dch CuSO
4
; FeCl
3
, xc nh vai tr ca
II. Tnh cht vt l:
- St l kim loi mu trng hi xm,
do, dai, d rn, nhit nng chy
kh cao( 1540
o
C)
- dn nhit, dn in tt, c tnh nhim
t.
III. Tnh cht ho hc:
- Khi tham gia phn ng ho hc,
nguyn t st nhng 2 e phn lp
4s , khi tc dng vi cht oxi ho
mnh th st nhng thm 1 e phn
lp 3d. to ra cc ion Fe
2+
, Fe
3+
.
Fe Fe
2+
+ 2e
Fe Fe
3+
+ 3 e
- Tnh cht ho hc ca st l tnh kh.
- Vi oxi, phn ng khi un nng.

3Fe + 2O
2
Fe
3
O
4
( FeO.Fe
2
O
3
)
- vi S, Cl: p cn ung nng.
2Fe + 3Cl
2
2FeCl
3

2Fe + 3 Br
2
2 FeBr
3

Fe + I
2
FeI
2

Fe + S FeS
3. Tc dng vi axit:
a) Vi cc dung dch axit HCl, H
2
SO
4

long:
VD: Fe + 2 HCl FeCl
2
+ H
2
Fe + H
2
SO
4
FeSO
4
+ H
2

Pt ion: Fe + 2H
+
Fe
2+
+ H
2

- St kh ion H
+
trong dung dch axit thnh
H
2
t do.
b) Vi cc axit HNO
3
, H
2
SO
4
c:
- Vi HNO
3
c, ngui;H
2
SO
4
c,
ngui: Fe khng phn ng.
- Vi H
2
SO
4
c, nng; HNO
3
c,
nng:
vd: 2Fe + 6H
2
SO
4
Fe
2
(SO
4
)
3
+ 3SO
2
+
6H
2
O
st (III) sunfat
Fe + 6HNO
3
Fe(NO
3
)
3
+ 3 NO
2
+ 3H
2
O
- Vi HNO
3
long:
Fe + 4HNO
3
Fe(NO
3
)
3
+ NO + 2H
2
O
4. Tc dng vi dung dch mui:
vd: Fe + CuSO
4
FeSO
4
+ Cu
kh oxh

cc cht ?
FeCu
Vd: cho Fe d tc dng vi dung dch HNO
3
.
Ch : Quy tc alpha.
FeCu HOT NG 7
GV: nhit thng Fe c kh c nc
hay khng ?

Hi: 1) C my phng php iu ch kim
loi ?
2) ta c th iu ch Fe bng cch no ?
Fe + 2 Fe(NO
3
)
3
3 Fe(NO
3
)
2

Vd: Cho Fe d tc dng vi dung dch HNO
3

c, nng.

5. Tc dng vi nc:
- Nu cho hi nc i qua st nhit
cao, Fe kh nc gii phng H
2
.
P:
3 Fe + 4 H
2
O Fe
3
O
4
+ 4 H
2

Fe + H
2
O FeO + H
2

IV . iu ch: trong cng nghip t
qung st.
- Dng phng php nhit luyn:
vd: Fe
2
O
3
+ 3 CO 2Fe + 3 CO
2

cc p khc:
FeCl
2
Fe + Cl
2

Mg + FeSO
4
MgSO
4
+ Cu
4. Cng c, dn d
Vit ptp Fe FeCl
3
FeCl
2
Fe(NO
3
)
3

Fe
3
O
4
FeCl
3

5. H-ng dn v nh
Xem tr-c ni dung phn hc ti, lm bi tp trong SGK.
Ngy son 05/03/2010
Tit 53
Bi 32. hp cht ca st
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit: Nm c tnh cht ho hc chung ca cc oxit st (FeO, Fe
3
O
4
, Fe
2
O
3
) l
oxit baz, ca cc hidroxit st Fe(OH)
2
, Fe(OH)
3
l baz v minh ha tnh cht ho hc
ny bng cc p ca chng i vi axit.
Bit nguyn tc v phn ng ho hc c th iu ch Fe(OH)
2
, Fe(OH)
3
. nhng hidroxit
ny b phn hu khi t nng to ra nhng oxit tng ng v iu ch.

Hp cht st (II) c tnh kh, khi b oxi ho n bin thnh hp cht st (III), dn ra c
nhng phn ng ho hc minh hc.
Hp cht st (III) l cht oxi ho, khi b kh n bin thnh hp cht st (II), Fe, dn ra
c nhng phn ng ho hc minh ho.
Nhn bit cc ion Fe
2+
, Fe
3+
trong dung dch bng phn ng ho hc.
HS hiu: Nguyn nhn tnh kh ca cc hp cht st (II) v tnh oxi ha ca cc hp cht
st (III).
2. K nng
- T cu to nguyn t, phn t v mc oxi ha suy ra tnh cht.
- Gii bi tp v hp cht ca st.
3. Tnh cm, thi
C thc.
II. Trng tm
Tnh cht ha hc ca cc hp cht cha st.
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by tnh cht ha hc ca st, vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc
HOT NG 1
Hi:
1) Hy ly v d v mt s hp cht st (II) ?
2) Fe c th nhng bao nhiu e ? Nh vy
ion Fe
2+
c th nhng thm bao nhiu e
phn lp 3d ?
3) Khi no ion Fe
2+
nhng e trong cc phn
ng ha hc ?
T cho bit hp cht st (II) c tnh cht
ha hc chung l g ?

HOT NG 2
I. Hp cht st (II):
gm mui, hidroxit, oxit ca Fe
2+

Vd: FeO, Fe(OH)
2
, FeCl
2

1. Tnh cht ho hc chung ca hp cht
st (II):
- Hp cht st (II) tc dng vi cht oxi
ho s b oxi ho thnh hp cht st
(III). Trong p ho hc ion Fe
2+
c kh
nng cjo 1 electron.

t
o

Hs vit p xy ra v cho bit vai tr ca st
trong cc trng hp v d sau:
Hi: clo l cht oxi ha mnh hay yu, khi sc
kh clo vo dung dch FeCl
2
, hy vit p xy
ra ?
FeCO
3
+ HNO
3
c nng

Hi: s oxi ha ca st trong FeO l bao
nhiu, cao nht cha? Khi tc dng vi
dung dch HNO
3
long l cht oxi ha th c
hin tng g xy ra ?
Vd: FeO + H
2
SO
4
long
FeO + H
2
SO
4
c
HS: vit p chng minh FeO v Fe(OH)
2

c tnh baz.

HOT NG 3
iu ch Fe(OH)
2
ta i t nhng hp cht
no ?
GV: Trong p iu ch Fe(OH)
2
, cc cht
khng c ln cht oxi ha nh O
2
...nu
khng s c mt phn Fe(OH)
3
.
Hi :
1) Hy nu nhng tnh cht vt l
ca FeO ?
2) iu ch FeO, theo cc em
phi thc hin nhng phn ng no ? V nu
p nung Fe(OH)
2
thc hin trong khng kh
th c thu c FeO ?
3) Hy vit pt phn ng ca FeO,
Fe(OH)
2
vi cc dung dch HCl, H
2
SO
4

long ? t hy cho bit cch aiu ch
mui Fe(II).
HOT NG 4
Hy ly v d mt s hp cht st (III) ?

GV: ion Fe
3+
c th nhn e tr thnh ion
Fe
2+
hoc nguyn t Fe khi tc dng vi cht
kh. T hy cho bit tnh cht ho hc
chung ca hp cht st (III) l g ?

Hi: Hy ly mt s v d m trong hp
cht st (III) ng vai tr l mt cht oxi ha ?

Fe
2+
Fe
3+
+ 1e
- Tnh cht ho hc chung ca hp cht st
(II) l tnh kh.
V d 1: nhit thng, trong khng kh (
c O
2
, H
2
O) Fe(OH)
2
b oxi ho thnh Fe(OH)
3
.
P: 4Fe(OH)
2
+ O
2
+ 2H
2
O 4 Fe (OH)
3

kh oxh
V d 2: Sc kh clo vo dung dch mui FeCl
2

P: 2 FeCl
2
+ Cl
2
2 FeCl
3

Fe(NO
3
)
2
+ HNO
3
NO + ...
V d 3: Cho FeO vo dung dch HNO
3
long:
3FeO + 10 HNO
3
3 Fe(NO
3
)
3
+ NO + 5H
2
O
V d 4: cho t t dung dch FeSO
4
vo dung
dch hn hp ( KMnO
4
+ H
2
SO
4
)
- Kt lun:
c) Oxit v hidroxit st c tnh baz:
2. iu ch mt s hp cht st (II):
a) Fe(OH)
2
: Dng phn ng trao i ion
gia dung dch mui st (II) vi dung
dch baz.
V d: FeCl
2
+ 2 NaOH Fe(OH)
2
+ 2 NaCl
Fe
2+
+ 2 OH
-
Fe(OH)
2

b) FeO :
- Phn hu Fe(OH)
2
nhit cao trong
mi trng khng c khng kh .
Fe(OH)
2
FeO + H
2
O
- Hoc kh oxit st nhit cao.

Fe
2
O
3
+ CO 2 FeO + CO
2

c) Mui st (II):
cho Fe hoc FeO, Fe(OH)
2
tc dng vi cc
dung dch HCl, H
2
SO
4
long.
II. Hp cht st (III):
1. Tnh cht ho hc ca hp cht st
(III):
a) Hp cht st (III) c tnh oxi ho:
khi tc dng vi cht kh, hp cht st (III) b
kh thnh hp cht st (II) hoc kim loi st t
do.
Trong p ho hc : Fe
3+
+ 1e Fe
2+

Fe
3+
+ 3e Fe
= tnh cht chung ca hp cht st (III) l tnh
oxi ho.
V d 1: Nung hn hp gm Al v Fe
2
O
3

nhit cao:
Fe
2
O
3
+ 2Al Al
2
O
3
+ 2 Fe

HS: Ly vd, vit p v xc nh s oxi ha
kt lun.
VD: 2FeCl
3
+ 2KI 2FeCl
2
+ 2KI+ I
2

HS: Vit ptp ca Fe
2
O
3
, Fe(OH)
3
vi cc
axit tng ng.

HOT NG 5

Hy cho bit tnh cht vt l ca Fe(OH)
3
?
iu ch Fe(OH)
3
ta cn thc hin phn
ng no ?
HS: vit p xy ra dng phn t v ion thu
gn.

Hi: Nu trong p iu ch Fe(OH)
3
, Fe
2
O
3

thc hin trong mi trng khng kh hoc c
ln cht oxi ha th c nh hng g ti sp hay
khng ?

HS: vit cc p xy ra.

V d 2: Ngm mt inh st sch trong dung
dch mui st (III) clorua.
2 FeCl
3
+ Fe 3 FeCl
2

V d 3: cho Cu tc dng vi dung dch FeCl
3
.
Cu + 2 FeCl
3
CuCl
2
+ 2 FeCl
2

- Sc kh H
2
S vo dung dch FeCl
3
c
hin tng vn c:
2 FeCl
3
+ H
2
S 2 FeCl
2
+ 2 HCl + S1
2. iu ch mt s hp cht st (III):
a. Fe(OH)
3
: Cht rn, mu nu .
- iu ch: p trao i ion gia dung dch mui
st (III) vi dung dch kim.
V d :Fe(NO
3
)
3
+3NaOH Fe(OH)
3
+3
NaNO
3

Pt ion: Fe
3+
+ 3 OH
-
Fe(OH)
3

b. St (III) oxit: Fe
2
O
3

phn hu Fe(OH)
3
nhit cao
2 Fe(OH)
3
- Fe
2
O
3
+ 3 H
2
O
c. Mui st (III):

3. ng dng ca hp cht st (III):
phn st amoni: NH
4
Fe(SO
4
)
2
. 12H
2
O
4. Cng c, dn d

- GV h thng li ni dung cn nh trong bi v cng c ton bi:
tnh cht ca hp cht st (II). (III).
- Vit cc ptp theo dy chuyn ho sau:

Fe FeCl
2
Fe(OH)
2
Fe(OH)
3
Fe
2
O
3
Fe
1
FeCl
3
Fe(NO
3
)
3
Cu(NO
3
)
2

5. H-ng dn v nh
Bi tp 5, 6, 7, 8/SGK trang 129.


Ngy son 07/03/2010
Tit 54
Bi 33. hp kim ca st
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
-Thnh phn, tnh cht v ng dng ca gang, thp.
-Nguyn tc v quy trnh sn xut gang, thp.
2. K nng
- Gii bi tp v lin quan n gang, thp.

- Van dung kien thc ve tnh chat hoa hoc cua sat va cac hp chat cua sat e
giai thch cac qua trnh hoa hoc xay ra trong lo luyen gang va thep.
3. Tnh cm, thi
- Biet gia tr ve kinh te va gia tr s dung cua gang va thep.
- Co y thc va biet cach s dung, bao ve cac vat dung bang gang va
thep.
II. Trng tm
III. Chun b
- Tranh ve s o lo cao va cac phan ng xay ra trong lo cao.
- Tranh ve s o lo thoi oxi.
- Tranh v l Mac-tanh v l in.
- Mot so mau vat bang gang thep.
- Su tam cac thong tin ve ng dung cua gang thep trong i song va trong k
thuat.
- Hoc k tnh chat hoa hoc cua n chat sat va cac oxit sat.
- Xem lai cac kien thc ve hp kim .
- Su tam cac mau vat ve gang, thep

IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by tnh cht ha hc ca hp cht st (II), st
(III), vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1: (5 phut) I. GANG:

GV: Cho hoc sinh quan sat mau vat bang
gang, mau gang trang, gang xam
H: Gang la g?
H: Co may loai gang? Gang trang khac
gang xam cho nao?
H: Tnh chat va ng dung cua cac loai
gang o la g?

Hoat ong 2: (10 phut)
GV: Yeu cau hs oc SGK tm hieu qua
trnh luyen gang.
H: e luyen gang can nhng nguyen
lieu g?
GV thong bao cac quang sat thng
dung e san xuat gang la quang hematit
o (Fe
2
O
3
), quang hematit nau
(Fe
2
O
3
.nH
2
O), quang manhetit (Fe
3
O
4
).
Khong dung quang pirit (FeS
2
) e luyen
gang v cha nhieu lu huynh ma ch
dung e san xuat H
2
SO
4
.
H: Nguyen tac cua viec luyen gang la
g?

H: Cho biet nhng phan ng hoa hoc
xay ra trong lo cao?
GV dung tranh ve s o lo cao va cac
phan ng xay ra trong lo cao e
ch cho hoc sinh thay ro cac vung
xay ra phan ng.
(HS ch can biet ma khong can nh
nhiet o xay ra phan ng moi
vung)
Hoat ong 3: ( 7 phut)
GV yeu cau hoc sinh nghien cu SGK
va cho biet :
H: Thanh phan nguyen to trong thep so
vi gang co g khac?
GV thong bao them: Hien nay co ti
8000 chung loai thep khac nhau. Hang
nam, toan the gii tieu thu c 1 t tan
gang thep. Khu lien hp gang thep Thai
Nguyen co 3 lo cao luyen gang, 2 lo
Mac-tanh va mot so lo ien luyen
thep.
Gang la hp kim cua sat cacbon va mot
so nguyen to khac, trong o ham
lng cacbon bien ong trong gii
han 2% - 5%.
Co 2 loai gang: gang trang va gang xam.
Gang trang cng, gion, c dung e
luyen thep.
Gang xam t cng va t gion hn, c
dung e uc cac vat dung.

Nguyen lieu e luyen gang la quang sat,
than coc va chat chay CaCO
3

Nguyen tac luyen gang la dung chat
kh CO e kh cac oxit sat thanh sat
Cac phan ng kh sat xay ra trong lo
cao

II. THEP:
Thep la hp kim cua sat vi cacbon va
mot lng rat t nguyen to Si, Mn . . .
Ham lng cacbon trong thep chiem
0,01 2%.

Da tren ham lng cua cac nguyen to
co trong tng loai thep, chia thanh 2 loai
thep:
- Thep thng hay thep cacbon cha

H: Thep c chia lam may loai ? da
tren c s nao?

H: Cho biet ng dung cua thep?
GV: Hay cho biet nguyen tac san xuat
thep?
Hoat ong 4: ( 10 phut)
HS: Nguyen tac e san xuat thep la
oxihoa e giam t le cacbon, silic,
lu huynh, photpho co trong gang.
GV: Hay cho biet nguyen lieu e san
xuat thep?

GV: hay neu cac phng phap, u nhc
iem cua moi phng phap?
GV: Co the dung s o lo thoi oxi e
ch dan cho hoc sinh thay c s
van chuyen cac nguyen lieu trong
lo

t cacbon, silic, mangan va rat t S,P.
- Thep ac biet la thep co cha
them cac nguyen to khac nh Si,
Mn, Ni, W, Vd
Thep co nhieu ng dung trong cuoc
song va trong k thuat.

Nguyen lieu e san xuat thep la:
- Gang trang hoac gang xam, sat
thep phe lieu.
- Chat chay la CaO
- Chat oxihoa la oxi nguyen chat
hoac khong kh giau oxi.
- Nguyen lieu la dau mazut, kh
ot hoac dung nang lng ien.
Co 3 phng phap luyen thep la:
- Phng phap lo thoi oxi, thi gian
luyen thep ngan, chu yeu dung
e luyen thep thng.
- Phng phap lo bang: thng
dung e luyen thep co chat
lng cao.
- Phng phap ho quang ien: dung
e luyen thep ac biet, thanh
phan co nhng kim loai kho chay
nh W, Mo, Cr, . . .

4. Cng c, dn d
Cu 1: Trn hon ton 15 gam hn hp Cu v Fe trong dung dch HCl d thy to ra 8,96
lt kh (ktc) v 3,4 gam cht rn khng tan v dung dch C. Sau em c cn v sy
kh C th thu c m mui khan. Gi tr m l:
A. 40 g B. 30 g C. 42 g D. 38 g
Cu 2: Cho 26 gam hn hp kim loi X gm K,Mg,Cu vo dung dch HCl th thu c
4,48 lt kh (ktc) v 3,2 gam cht rn khng tan v dung dch Y. Sau khi c cn v sy
kh dung dch Y th thu c m gam mui. Gi tr m l:
A. 29,2 g B. 30,1 g C. 37 g D. 28 g
5. H-ng dn v nh
Bi tp 1, 2, 3, 4, 5/SGK trang 151.


Ngy son 10/03/2010
Tit 55
Bi 37. Luyn tp tnh cht ha hc ca st
v hp cht ca st
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- Cung co va he thong hoa tnh chat hoa hoc cua cac kim loai Fe va mot
so hp chat quan trong cua chung.
- Thiet lap c moi quan he gia cac n chat va hp chat, gia cac hp
chat vi nhau cua moi nguyen to da vao tnh chat hoa hoc cua chung.
2. K nng

- Ren luyen k nang viet phng trnh hoa hoc, ac biet la phan ng
oxihoa kh
- Van dung kien thc e giai cac bai tap co lien quan en tnh chat
hoa hoc cua cac n chat va hp chat cua Fe.
3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
GV: Chuan b phieu hoc tap da theo muc tieu cua bai hoc va s o ve moi quan
he ve tnh chat hoa hoc cua cac n chat va hp chat trong SGK.
GV: Yeu cau tng ai dien len bao bao trc lp ve noi dung cua nhom mnh
am nhan.
GV: Cho hoc sinh trong lp thao luan va ket luan kien thc c ban nhat cua bai
hoc
GV: Kiem tra v bai tap cua hoc sinh (bai tap a giao trc tiet luyen tap)
HOT NG 1: Cng c kin thc.
GV: chia HS theo nhm v yu cu mi nhm thc hin nhng cng vic sau:
1. vit cu hnh electron ca Fe
2. cho bit nhng tnh cht ho hc c trng ca nhng nguyn t ny, c v d minh ho
3. cho bit hp cht ca chng gm: oxit, hidroxit, mui ca cc nguyn t ny, nu nhng
phng php c trng, vit ptp chng minh.
4. cc phng php iu ch kim loi Fe
HS: nghin cu s tm tt trong sgk, tho lun kt lun

HOT NG 2: Gii cc bi tp.
Cu 1: S n mn st, thp l mt qu trnh oxi ho kh.
a) hy gii thch v vit pt ho hc ca p xy ra khi st thp b n mn.
b) km hoc thic trng ngoi vt bng st, thp c tc dng bo v chng n mn. Hy gii
thch mt thc t l sau mt thi gian s dng th vt c trng bng km li c hiu
qu bo v tt hn ?
Cu 2: Vit cc phng trnh phn ng theo s d :
Fe FeSO
4
Fe Fe(NO
3
)
3
Fe(NO
3
)
2
Fe(NO
3
)
3
CuCl
2
Cu CuCl
2
FeCl
2

FeCl
3
Fe(OH)
3
Fe
2
O
3
Fe
Cu 3: ho tan 4 gam oxit Fe
x
O
y
cn va 52,14 ml dung dch HCl 10% (d=1,05g/ml). Tm
cng thc ca oxit st?
4. Cng c, dn d
Bi tp 1, 2/SGK 165.
5. H-ng dn v nh
Bi tp 3, 4, 5, 6/SGK trang 165.

Ngy son 12/03/2010
Tit 56
Bi 34. crom v hp cht ca crom
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
-V tr, cu to nguyn t, tnh cht ca crom.
-Tnh cht ca cc hp cht ca crom.
- Bit cu hnh electron v v tr ca crom trong bng tun hon.
- Hiu c tnh cht l, ho hc ca n cht crom
- Hiu c s hnh thnh cc trng thi oxi ho ca crom.
- Hiu c phng php s dng sn xut crom.
2. K nng
- Vit pthh ca cc phn ng biu din tnh cht ha hc ca crom v hp cht ca crom.

- Vn dng c im cu to nguyn t v cu to n cht gii thch nhng tnh cht l, ho
hc c bit ca crom.
- Rn luyn k nng hc tp theo phng php nghin cu, t duy logic.
3. Tnh cm, thi
II. Trng tm
III. Chun b
IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
C s phn loi gang, thp?
Hy trnh by khi nim gang, thp?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
HOT NG 1

GV: Cho Z = 24
HS: Tm s th t ca crom, v tr ca crom
trong bng tun hon.

Hi: T s hiu nguyn t ca crom trong sgk.
1. Vit cu hnh electron nguyn
t
2. Phn b e vo lng t
3. Nhn xt v s lp e, s e c
thn.
Hi: t s e c thn hy d on s oxi ho
c th c ca crom?
HS: Quan st sgk v cho bit cu to ca crom
n cht, E
o
, m in, bn knh nguyn t,
ion, nng lng ion ho.

I. V tr trong BTH v cu
hnh electron nguyn t :
1. V tr ca crom trong BTH:
Crm l kim loi chuyn tip
V tr: STT: 24
Chu k: 4
Nhm: VIB
2. Cu to ca crom:
Cr
24
1s
2
2s
2
2p
6
3s
2
3p
6
3d
5
4s
1

- Trong hp cht, crom c s oxi ho
bin i t +1 n +6. s oxi ho ph
bin l +2,+3,+6. ( crom c e ho tr
nm phn lp 3d v 4s)
- nhit thng: cu to tinh th lc
phng.
3. Mt s tnh cht khc:
E
o
Cr
3+
/Cr = - 0,74 V


HOT NG 2
Hi: Hy nghin cu sgk tm hiu tnh cht
vt l c bit ca crom, da vo cu trc
mng tinh th, hy gii thch nhng tnh cht
vt l ?
HOT NG 3

Gv: Da vo bng 1 s tnh cht khc ca
crom, hy d on kh nng hot ng ca
crom?
- Crom l kim loi chuyn tip kh hot
ng, nhit cao n c th phn
ng mnh lit vi hu ht phi kim nh:
Hal, O
2
, S...
Hi: V sao E
o
Cr
2+
/Cr = - 0,86 V < E
o

H
2
O/H
2

Nhng crom khng tc dng vi nc ?

HS: So snh E
o
H
+
/H
2
vi E
o
Cr
2+
/Cr .

Yu cu: crom kh c H
+
trong dung dch
axit HCl, H
2
SO
4
long , gii phng H
2
. Hy
vit ptp xy ra dng phn t v ion thu gn.
- Lu :

HOT NG 4
HS: Nghin cu sgk v cho bit cc ng dng
ca crom.

- Crom c sx nh th no ? nguyn liu v
phng php ?

GV: Cr
2
O
3
c dng to mu lc cho s,
thy tinh.

GV: ion Cr
3+
trong dd c tnh oxi ha trong
mi trng axit, c tnh kh trong mi
trng baz.
2CrCl
3
+ Zn -> 2CrCl
2
+ ZnCl
2

II. Tnh cht vt l:
- Crom c mu trng bc, rt cng (
cng thua kim cng)
- Kh nng chy, l kim loi nng, d =
7,2 g/cm
3
.
III. Tnh cht ho hc:
a. Tc dng vi phi kim:
4Cr + 3 O
2
2 Cr
2
O
3

2Cr + 3Cl
2
2 CrCl
3

- nhit thng trong khng kh, kim
loi crom to ra mng mng crom (III)
oxit c cu to mn, bn vng bo v.
- nhit cao kh c nhiu phi kim.
b. Tc dng vi nc:
Khng tc dng vi nc do c mng oxit bo
v.
c. Tc dng vi axit:
Vi dung dch axit HCl, H
2
SO
4
long nng,
mng axit b ph hu Cr kh c H
+
trong
dung dch axit.
Vd: Cr + 2HCl CrCl
2
+ H
2

Cr + H
2
SO
4
CrSO
4
+ H
2

Pt ion:
2H
+
+ Cr Cr
2+
+ H
2

- Crom th ng trong axit H
2
SO
4
v
HNO
3
c ,ngui.
-
IV. ng dng v sn xut:
a. ng dng: Sgk
b. Sn xut
- Trong TN, crom tn ti dng hp
cht. qung ch yu ca crm l crmit:
FeO.Cr
2
O
3
.
- P
2
: tch Cr
2
O
3
ra khi qung, dng
phng php nhit nhm.
Cr
2
O
3
+ 2 Al 2Cr + Al
2
O
3

V. Hp cht ca crom
1. Hp cht crom (III)
a. Crom (III) oxit
Cr
2
O
3
l cht rn, mu lc thm, khng tan
trong nc.
Cr
2
O
3
l oxit lng tnh.
b. Crom (III) hiroxit
Cht rn, mu lc xm, khng tan trong nc.
Hiroxit lng tnh.

2NaCrO
2
+ 3Br
2
+ 8NaOH -> 2Na
2
CrO
4
+
6NaBr + 4H
2
O

Gv lu HS: trong dd ion Cr
2
O
7
2-
(mu da
cam) lun lun c c ion CrO
4
2-
(mu
vng) trng thi cn bng vi nhau:
Cr
2
O
7
2-
+ H
2
O ~ 2 CrO
4
2-
+ 2H
+

2. Hp cht crom (VI)
a. Crom (VI) oxit
CrO
3
l cht rn, mu thm.
L oxit axit, tc dng vi nc to ra axit
CrO
3
+ H
2
O H
2
CrO
4

Axit cromic
2CrO
3
+ H
2
O H
2
Cr
2
O
7

Axit icromic
C tnh oxi ha mnh.
b. Mui crom (VI)
L hp cht bn
Ion cromat (CrO
4
2-
) c mu vng.
Ion icromat (Cr
2
O
7
2-
) c mu da cam.
Mui cromat v icromat c tnh oxi ha mnh
trong mtrng axit Crom (VI) Crom (III)

4. Cng c, dn d
Hs lm bi tp 1, 2, 3 trong SGK cng c bi hc.
5. H-ng dn v nh
Bi tp 4, 5/SGK trang 155.
Ngy son 15/03/2010
Tit 57
Bi 35. ng v hp cht ca ng
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- V tr cua nguyen to Cu trong bang tuan hoan.
- Biet cau hnh electron nguyen t cua Cu.
- Hieu c tnh chat hoa hoc c ban cua ong.
- Biet tnh chat, ng dung mot so hp chat va hp kim cua ong.
- Biet cac cong oan cua qua trnh san xuat ong.

2. K nng
- Ren luyen k nang s dung day the ien cc cua kim loai e xet oan
chieu hng cua phan ng oxi hoa- kh
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc hp cht cha ng.
III. Chun b
IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by tnh cht ha hc ca hp cht crom (III), crom
(VI), vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc
HOT NG 1
GV: treo BTH v yu cu hs xc nh v tr ca Cu
trong BTH ?
Hi:
1) Xung quanh nguyn t Cu gm nhng nguyn
t no ? hy cho bit Z
Cu
v NTK ca n ?
2) Hy vit cu hnh e ca Cu, cho bit s e tng
lp ? v cho bit Cu thuc loi nguyn t g ?
(s,p,d)

3) So snh vi cu to ca Fe ? Cu c my e ha
tr ? Nh vy trong hp cht Cu c nhng mc oxi
ha no ?
HS: Vit cu hnh e ca Cu
+
v Cu
2+
v quan st
mng tinh th ca Cu.

HS: Quan st hnh v mng tinh th ng.

HOT NG 2
HS: Da vo kin thc thc t v sgk, hy nu ln
nhng tnh cht vt l ca Cu.
A. NG
I. V tr v cu to:
1. V tr ca ng trong BTH:
- L kim loi chuyn tip
- V tr: STT: 29; chu k 4; nhm IB
2. Cu to ca ng:
29
Cu : 1s
2
2s
2
2p
6
3s
2
3p
6
3d
10
4s
1

- L nguyn t d, c electron ho tr nm 4s
v 3d
- Trong hp cht: Cu c mc oxi ho ph
bin l: +1 v +2
to ra c 2 ion: Cu
+
(Ar) 3d
10
; Cu
2+
(Ar) 3d
9

3. Mt s tnh cht khc ca ng :
X
Cu
= 1,9; E
o
Cu
2+
/Cu = + 0,34 V. I
1
, I
2
l 744; 1956
( KJ/mol)

II. Tnh cht vt l:


+O
2

+O
2

+O
2

+Cu
2
S

HOT NG 3
Hi: 1) da vo cu to nguyn t, m in, cc
gi tr th in cc ca Cu, hy d on kh nng
hot ng ha hc ca ng ?

2) ng c bn trong khng kh hay khng?
Ti sao trong khng kh ng thng b
ph mt lp mng c mu xanh ?

3) Hy vit ptp xy ra khi cho Cu tc dng
vi Cl
2
, Br
2
, S

HOT NG 4
Gv: th nghim: Cu + H
2
SO
4
long.

HS: quan st TN v khng nh mt ln na: Cu
khng kh c ion H
+
trong dung dch axit.

GV: lm cc th nghim: cho mu Cu vo HNO
3

c v H
2
SO
4
c.
HS: quan st , vit p gii thch hin tng.

GV: Cho mt mu Cu vo dung dch AgNO
3
, dd
Fe(NO
3
)
3

HS: vit p
HOT NG 5
HS: Nu nhng ng dng ca Cu trong thc t

Ngihn cu sgk v cho bit nhng hp kim c
nhiu ng dng trong cng nghip v i sng.

HOT NG 6
Hi: 1) trong t nhin , ng tn ti nhng dng
no ?
2) Loi khong sn no c gi tr trong cng
nghip sn xut ng.

3) Nu nhng cng on chnh ca qu
trnh sn xut Cu.

4) Vit cc p xy ra trong qu trnh sn
xut Cu.

III. Tnh cht ho hc:
E
o
Cu
2+
/Cu = + 0,34 V > E
o
H
+
/H2
- ng l kim loi km hot ng, c tnh kh yu
- Cu phn ng vi oxi khi un nng to CuO
bo v nn Cu khng b oxi ho tip tc.
2Cu + O
2
CuO
- Khi tip tc un nng ti (800-1000
o
C)
CuO + Cu ---> Cu
2
O ()
- Tc dng trc tip vi Cl
2
, Br
2
, S...
Cu + Cl
2
CuCl
2

Cu + S CuS
2. Tc dng vi axit:
- Cu khng tc dng vi dung dch HCl,
H
2
SO
4
long.
- Khi c mt oxi, Cu tc dng vi dung dch
HCl, ni tip xc gia dung dch axit vi
khng kh.
2 Cu + 4HCl + O
2
2 CuCl
2
+ 2 H
2
O
* vi HNO
3
, H
2
SO
4
c :
Cu + 2 H
2
SO
4
CuSO
4
+ SO
2
+ H
2
O
Cu + 4 HNO
3

Cu + HNO
3
long
3. Tc dng vi dung dch mui:
- Kh c ion kim loi ng sau n trong
dung dch mui.
vd: Cu + 2 AgNO
3
Cu(NO
3
)
2
+ 2 Ag
IV. ng dng ca ng:
Da vo tnh do, dn in, dn nhit, bn ca ng
v hp kim.
1. ng thau : Cu-Zn
2. ng bch : Cu-Ni
3. ng thanh : Cu-Sn
4. Cu-Au : ( vng ty)
V. Sn xut ng:
- Trong t nhin : phn ln tn ti dng
hp cht.
- Cc loi qung : pirit ng CuFeS
2
,
malachit Cu(OH)
2
.CuCO
3
, chancozit : Cu
2
S
- Sn xut ng t CuFeS
2
: chia lm 2 giai
on:
- Lm giu qng bng phng php tuyn
ni.
- Chuyn ho qung ng thnh ng , gm
3 bc:
CuFeS
2
Cu
2
S Cu
2
O Cu

HOT NG 7
GV: cho hs quan st cc l ng CuO, yu cu hs
cho bit cc tnh cht vt l ca CuO.

Hi: 1) Hy cho bit phng php iu ch CuO ?
2) Xc nh s oxi ha ca Cu trong CuO v nu
tnh cht c trng ca CuO ?

GV: lm th nghim: cho dung dch NaOH vo
dung dch CuSO
4

HS quan st v vit p xy ra; nu cch iu ch
Cu(OH)
2
v cho bit cc tnh cht ca n ?

Hi: c hin tng g xy ra khi cho t t dung
dch NH
3
cho n d vo dung dch CuSO
4
?
- Tinh luyn ng th bng phng php
in phn.
B. MT S HP CHT CA NG:
I. ng (II) oxit: CuO
- L cht rn mu en.
- iu ch: nhit phn.
2 Cu(NO
3
)
2
2 CuO + 4 NO
2
+ O
2

CuCO
3
. Cu(OH)
2
2 CuO + CO
2
+ H
2
O
Cu(OH)
2
CuO + H
2
O
- CuO c tnh oxi ho:
Vd : CuO + CO Cu + CO
2

3 CuO + 2 NH
3
N
2
+ 3Cu + 3 H
2
O
II. ng (II) hidroxit: Cu(OH)
2

- L cht rn mu xanh.
- iu ch: t dung dch mui Cu
2+
v dung
dch baz.
Vd: CuSO
4
+ 2 NaOH Cu(OH)
2
+ Na
2
SO
4

- Cu(OH)
2
d tan trong dung dch NH
3
to
dung dch mu xanh thm gi l nc
Svayde.
Vd: Cho t t dung dch NH
3
cho n d vo dung
dch CuSO
4
.
4. Cng c, dn d
1) Cng c ton bi.
2) HS lm mt s bi tp.

1. Vit ptp thc hin dy chuyn ho sau:
Cu CuO CuCl
2
Cu(OH)
2
CuO Cu
2. Bng cch no c th tinh ch dung dch Fe (II) sunfat khi tp cht CuSO
4
?

5. H-ng dn v nh
Bi tp 1, 2, 3, 4, 5, 6/SGK trang 158, 159.


Ngy son 21/03/2010
Tit 58
Bi 36. s l-c v niken, km, ch, thic
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- V tr cua nguyen to Ni, Zn, Pb, Sn trong bang tuan hoan.
- Biet cau hnh electron nguyen t cua Ni, Zn, Pb, Sn.
- Hieu c tnh chat hoa hoc c ban cua Ni, Zn, Pb, Sn.
2. K nng
- Ren luyen k nang s dung day the ien cc cua kim loai e xet oan
chieu hng cua phan ng oxi hoa- kh.

- Vit pthh dng phn t v ion rt gn ca phn ng xy ra
(nu c) khi cho tng kim loi Ni, Zn, Pb, Sn tc dng vi cc
dung dch axit, vi cc phi kim.
- Ren luyen k nang hoc tap theo phng phap oi chieu va so sanh.
- Ren luyen kha nang suy luan logic, kha nang khai quat, he thong hoa van
e.
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc cht Ni, Zn, Pb, Sn.
III. Chun b
Gio vin: Chun b ni dung bi dy, bi kim tra 15 pht.
IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by tnh cht ha hc ca ng, vit pthh minh ha.
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hot ng 1. Tm hiu v niken
T Z, HS xc nh v tr ca Ni trong BTH.
HS nghin cu tnh cht vt l v ng dng
trong SGK.
HS vit pthh ca cc phn ng Ni tc dng vi
O
2
v Cl
2
.

I. Niken (Ni)
1. V tr trong bng tun hon
Ni (Z = 28), s 28, chu k 4, nhm VIIIB.
2. Tnh cht v ng dng
a. Tnh cht
TCVL: k loi mu trng bc, rt cng,...
TCHH: tnh kh yu hn st, khng tc dng
vi H
2
.
500
o
C: 2Ni + O
2
2NiO
t
o
C: Ni + Cl
2
NiCl
2

t
o
thng, Ni bn vi khng kh v nc.
b. ng dng
- Ngnh luyn kim
- M ln st chng g cho st.
- Lm cht xc tc.

Hot ng 2. Tm hiu v km
T Z, HS xc nh v tr ca Zn trong BTH.
trong SGK.
HS vit pthh ca cc phn ng Zn tc dng vi
O
2
v S.

Hot ng 3. Tm hiu v ch
T Z, HS xc nh v tr ca Pb trong BTH.
trong SGK.
HS vit pthh ca cc phn ng Zn tc dng vi
O
2
, S v dd HNO
3
long.

Hot ng 4. Tm hiu v thic
T Z, HS xc nh v tr ca Sn trong BTH.
trong SGK.
HS vit pthh ca cc phn ng Sn tc dng vi
O
2
v dd HCl.

II. Km (Zn)
Zn (Z = 30), s 30, chu k 4, nhm IIB
2. Tnh cht v ng dng
a. Tnh cht
TCVL: k loi c mu lam nht. Trong kk m,
km b ph mt lp oxit mng nn c mu
xm.
k thng 100-150
o
C 200
o
C
Zn kh gin do v dai gin v c th
tn thnh bt
Hi ca ZnO rt c.
TCHH: tnh kh mnh hn st.
Tan c trong dd axit v dd kim.
b. ng dng
M ln st (tn)
III. Ch (Pb)
Pb (Z = 82), s 82, chu k 6, nhm IVA
2. Tnh cht v ng dng
a. Tnh cht
TCVL: k loi c mu trng hi xanh, mm d
dt thnh l mng.
TCHH: k thng, Pb tc dng vi oxi ca
khng kh to mng oxit bo v cho kl khng
tip tc b oxi ha.
b. ng dng
- Thit b bo v khi tia phng x.
- Bnh xm men rng, gy ri lon thn kinh.
IV. Thic (Sn)
Sn (Z = 50), s 50, chu k 5, nhm IVA
2. Tnh cht v ng dng
a. Tnh cht
TCVL: k loi mu trng bc (thic trng), mm,
d nng chy.
C 2 dng th hnh: thic trng ~ thic xm
Tn ti nhit cao hn, tng V
(bt vn mu xm).
TCHH: tnh kh, tan chm trong ddHCl long.
b. ng dng

Kt lun chung: Trong s cc kim loi Ni, Zn,
Pb, Sn ch c Zn c tnh kh mnh hn
Fe. Ni, Sn, Pb u ng trc hiro
trong dy in ha ca kim loi v u
c tnh kh yu. C 4 kim loi trn u
l cc kim loi thng dng, c nhiu ng
dng trong thc t.
St ty l st trng thic, giy thic
Que hn l hp kim thic ch (nc 180
o
C)
SnO
2
lm men trong gm s, thy tinh m.
4. Cng c, dn d
Bi tp 1B, 2C.
Kim tra 15 pht(GV pht trc nghim)
5. H-ng dn v nh

Ngy son 25/03/2010
Tit 59
Bi 39. Thc hnh: tnh cht ha hc ca fe, Cr, Cu
v HP CHT CA CHNG.
-------------------
I. Mc tiu bi hc
1. Kin thc
Cung co kien thc ve mt s tnh cht ha hc ca cc kim loi Cr, Fe, Cu v nhng
hp cht ca chng.
- iu ch FeCl
2
, Fe(OH)
2


- Th tnh oxi ha ca K
2
Cr
2
O
7

- Cu tc dng vi H
2
SO
4
c, nng.
2. K nng
Tip tc rn luyn k nng lm th nghim ha hc nh k nng lm vic vi cc ha cht (rn,
lng), vi dng c th nghim, un nng dd, k nng quan st gii thch cc hin tng ha
hc,
Tip tc rn luyn k nng tin hnh th nghim vi lng nh ho cht.
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc kim loi.
III. Chun b
Gio vin:
1. Dng c:
ng nghim, ng ht nh git, gi ng nghim, n cn, a thu tinh.
2. Ha cht:
Cc dung dch: NaOH, HCl, K
2
Cr
2
O
7
, FeSO
4
, Fe
2
(SO
4
)
3
, H
2
SO
4
c, H
2
SO
4
long, dd
KMnO
4
, HNO
3
long, FeCl
3
, KI.
Kim loi: Fe (inh st), Cu (ng mnh).
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
Hot ng 1. Cng vic u bui thc hnh

GV nu mc tiu, yu cu ca tit thc hnh, n tp nhng kin thc c bn v st, crom, ng,
v phn ng oxi ha kh.
Lm mu mt s th nghim.
HS lng nghe, tip thu, chun b lm thc hnh.
Hot ng 2. GV chia hc sinh ra thnh nhiu nhm v cho hc sinh tin hnh th nghim.
Th nghim 1: iu ch FeCl
2
nh tht sch mt inh st cho vo ng nghim, cho khong 3 ml dd HCl vo ng nghim, un
nng nh, quan st hin tng xy ra. t ng nghim vo gi s dng tip sn phm phn
ng trong th nghim sau.
Th nghim 2: iu ch Fe(OH)
2

- Cho khong 3 4 ml dd NaOH vo ng nghim, un si dd trong khong 1 pht ui ht O
2

tan trong dd. ngui dd, rt khong 3 ml dd FeCl
2
va iu ch trong th nghim trn vo dd
NaOH.
- Quan st mu ca kt ta. ng nghim ln gi ng nghim, sau mt thi gian quan st mu
ca kt ta trong ng nghim, c mu nu do Fe(OH)
2
b oxi ha thnh Fe(OH)
3
4Fe(OH)
2
+ 2H
2
O + O
2
4Fe(OH)
3
a) Cch tin hnh th nghim: Nh vo 2 ng nghim, mi ng 10 git nc ct un si.
Ho tan mt t FeSO
4
vo ng nghim (1), mt t Fe
2
(SO
4
)
3
vo ng nghin (2), nh tip
vo mi ng nghim vi git dung dch NaOH long.
b) Hin tng v gii thch:
- Trong ng nghim (1) xut hin kt ta mu trng xanh, ng nghim (2) xut hin kt ta
mu nu .
P: FeSO
4
+ 2 NaOH Fe(OH)
2
+ Na
2
SO
4

Fe
2
(SO
4
)
3
+ 6 NaOH 2 Fe(OH)
3
+ 3 Na
2
SO
4

- Dng a thu tinh ly nhanh tng loi kt ta, sau nh tip vo mi ng nghim vi
git dung dch HCl.
- Trong ng nghim (1) kt ta tan dn, thu c dung dch c mu lc nht ca FeCl
2
.
Trong ng nghim (2) kt ta tan dn to ra dung dch c mu nu ca FeCl
3
.
- Kt lun: St (II) hidroxit v st (III) hidroxit c tnh baz.
Th nghim 3: Th tnh oxi ha ca kali icromat K
2
Cr
2
O
7

nh sch mt vi inh st cho vo ng nghim cha khong 3 4 ml dd H
2
SO
4
long. Sau khi
phn ng xy ra mnh vi pht, rt phn dung dch FeSO
4
sang mt ng nghim khc, nh dn
tng git dd K
2
Cr
2
O
7
mu da cam vo dd FeSO
4
, lc u ng nghim. Quan st mu ca dd.

Trong dd cc ion Fe
2+
s b cc ion Cr
2
O
7
2-
oxi ha chuyn thnh Cr
3+
. Mu ca thuc th
K
2
Cr
2
O
7
mu da cam s khng cn.
K
2
Cr
2
O
7
+ 6 FeSO
4
+ 7 H
2
SO
4
Cr
2
(SO
4
)
3
+ K
2
SO
4
+ 3 Fe
2
(SO
4
)
3
+ 7 H
2
O
Lu : Phn ng ny xy ra trong mi trng H
2
SO
4
nn phi cho H
2
SO
4
d trong phn ng
iu ch FeSO
4
.
a) Tin hnh: Nh vo ng nghim 10 git dung dch K
2
Cr
2
O
7
. Nh tip vi git dung dch
H
2
SO
4
long, lc nh. Sau nh tip dn dn vo ng nghim tng git dung dch
FeSO
4
, lc nh.
- Dung dch lc u c mu gia cam ca ion Cr
2
O
7
2-
sau chuyn dn sang mu xanh ca
ion Cr
3+
.
P: K
2
Cr
2
O
7
+ 6 FeSO
4
+ 7 H
2
SO
4
Cr
2
(SO
4
)
3
+ K
2
SO
4
+ 3 Fe
2
(SO
4
)
3
+ 7 H
2
O.
-
Kt lun: K
2
Cr
2
O
7
c tnh oxi ha mnh , c bit trong mi trng axit, Cr
+6
b kh
thnh ion Cr
3+
.

Tnh cht ha hc ca mui st:
a) Tin hnh th nghim:
Nh vo ng nghim 10 git dung dch FeCl
3
. Nh tip vi git dung dch KI v lc.
b) Dung dch trong ng nghim chuyn dn t mu vng sang mu nu sm v cui cng
xut hin kt ta tm en.
P: 2 FeCl
3
+ 2 KI 2 FeCl
2
+ 2 KCl + I
2

- Kt lun: Mui Fe
3+
c tnh oxi ha.
Th nghim 4: Phn ng ca ng vi H
2
SO
4
c, nng
Cho vi mnh ng vo ng nghim cha khong 3 ml H
2
SO
4
c, kp trn gi th nghim.
Dng n cn un nng ng nghim. Quan st hin tng xy ra. Ngng un, ngui ng
nghim, rt dd CuSO
4
sang mt ng nghim khc, nh tng git dd NaOH vo dd CuSO
4
, quan
st hin tng xy ra.
H
2
SO
4
c, nng oxi ha Cu thnh Cu
2+
, sau Cu
2+
tc dng vi dd NaOH to kt ta
Cu(OH)
2
.
Cc pthh:
Cu + 2H
2
SO
4

c, to
CuSO
4
+ SO
2
1 + 2H
2
O
CuSO
4
+ 2NaOH
long
Cu(OH)
2
1 + Na
2
SO
4

a) Tin hnh th nghim:
- Nh 5 git dung dch H
2
SO
4
long vo ng nghim (1) c vi mnh ng.

- Nh 5 git dung dch H
2
SO
4
c vo ng nghin (2) c vi mnh ng.
- Nh 5 git dd HNO
3
long vo ng nghim (3) c mnh ng.
ng nghim (1) khng c p xy ra
ng nghim (2) p ha hc cng khng xy ra.
ng nghim (3) sau mt thi gian ming ng nghim c kh mu nu , dung dch c mu
xanh.
c) Phn ng chng minh.

4. Cng vic cui bui thc hnh, cng c, dn d
- GV: nhn xt, rt kinh nghim bui thc hnh, giao nhim v
hc tp nh cho HS.
- HS: thu dn dng c, ha cht, v sinh phng th nghim, lp
hc, vit bn t-ng trnh.
5. H-ng dn v nh
Xem tr-c ni dung bi hc.
Ngy son 27/03/2010
Tit 60
Bi 38. Luyn tp tnh cht ca Cu, cr
v hp cht quan trng ca chng
-------------------
I. Mc tiu bi hc
1. Kin thc
- Cung co va he thong hoa tnh chat hoa hoc cua cac kim loai Cr, Fe,
Cu va mot so hp chat quan trong cua chung.
- Thiet lap c moi quan he gia cac n chat va hp chat, gia
cac hp chat vi nhau cua moi nguyen to da vao tnh chat hoa hoc
cua chung.
- Hs biet : CHe bat thng cua nguyen t Cr, Cu.

V sao Cu co so oxi hoa +1 va +2, con Cr co so oxi hoa
t +1 +6.
2. K nng
- Ren luyen k nang viet phng trnh hoa hoc, ac biet la phan ng
oxihoa kh
- Van dung kien thc e giai cac bai tap co lien quan en tnh chat
hoa hoc cua cac n chat va hp chat cua Cr, Fe, Cu.
- Viet pthh dang phan t va ion thu gon cua cac phan ng the hien
tnh chat hoa hoc cua crom, ong.
- Ren luyen k nang hoc tap theo phng phap oi chieu va so sanh.
- Ren luyen kha nang suy luan logic, kha nang khai quat, he thong hoa van
e.
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc cht Cu, Cr.
III. Chun b
IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
3. Cc hot ng dy hc
HOT NG 1: Cng c kin thc.
GV: chia HS theo nhm v yu cu mi nhm thc hin nhng cng vic sau:
vit cu hnh electron ca Cr, Cu
cho bit nhng tnh cht ho hc c trng ca nhng n cht ny, c v d minh ho.
cho bit hp cht ca chng gm: hp cht Cu(II), Cr(III), Cr(VI), (oxit, hidroxit, mui
ca cc nguyn t ny), nu nhng phng php c trng, vit ptp chng minh.
cc phng php iu ch kim loi Cr, Cu
HS: nghin cu s tm tt trong sgk, tho lun kt lun
HOT NG 2: Gii cc bi tp.

Bi 2/SGK: %mAl = 5,4%
%mFe = 86,8%
%mCr = 7,8%
Bi 3/SGK: D
mCu = 14,8.43,24/100 = 6,4 g
mFe = 8,4 g
VH
2
= 3,36 l (ktc)
Bi 4/SGK: B
S mol CuO b kh = s mol Cu to thnh = 3/2 s mol NO = 0,3 mol
Tng s mol CuO ban u = 0,1 + 0,3 = 0,4 mol
Hiu sut = 75%
Bi 5/SGK: D
Bi 6/SGK: B
3Cu + 2NaNO
3
+ 4H
2
SO
4
3CuSO
4
+ Na
2
SO
4
+ 2NO + 4H
2
O
HOT NG 3: Gii cc bi tp sau khi lm xong bi tp trong SGK.

Cu 1: Vit cc phng trnh phn ng theo s d :
Cr Cr
2
O
3
Cr
2
(SO
4
)
3
Cr(OH)
3
Na[Cr(OH)
4
] Na
2
CrO
4
Na
2
Cr
2
O
7
Cr
2
O
3
.
Cu 2: ho tan 4 gam oxit Fe
x
O
y
cn va 52,14 ml dung dch HCl 10% ( d=1,05g/ml).
Tm cng thc ca oxit st ?
4. Cng c, dn d
n tp li kin thc lm tt bi kim tra 1 tit.
5. H-ng dn v nh
Bi tp trong SBT.


Ngy son 30/03/2010
Tit 61
kim tra 1 tit
-------------------
I. Mc tiu bi hc
1. Kin thc
Hs nm -c kin thc trong ch-ng 7.
2. K nng
II. Trng tm
Tnh cht ho hc cc kim loi hc.
III. Chun b
Gio vin: thi v p n

IV. Ph-ng php
V. bi
Cu 1: Hin tng xy ra khi a mt dy ng mnh, c un thnh l xo, nng
vo l thu tinh ng y kh clo, y l cha mt lp nc mng l
A. dy ng khng chy.
B. dy ng chy to khi mu .
C. ng chy mnh, c khi mu nu, khi khi tan, lp nc y l thu tinh c
mu xanh nht.
D. ng chy mnh, c khi mu nu, lp nc sau p khng mu.
Cu 2: Dng 100 tn qung c cha Fe
3
O
4
luyn gang (cha 95% Fe), cho bit
rng hm lng Fe
3
O
4
trong qung l 80%, hiu sut qu trnh l 93%. Khi lng
gang thu c l:
A. 55,8 tn B. 56,712 tn C. 56,2 tn D. 60,9 tn
Cu 3: Mun kh ion Fe
3+
trong dung dch thnh ion Fe
2+
, ta phi thm cht no sau
y vo dung dch Fe
3+

A. Zn B. Na C. Cu D. Ag
Cu 4: kh 6,4 gam mt oxit kim loi cn 2,688 lit H
2
(ktc). Nu ly lng kim
loi cho tc dng vi dung dch HCl th gii phng 1,792 lt kh H
2
(ktc). Kim
loi l
A. Mg B. Al C. Fe D. Cr
Cu 5: t chy hon ton 2 gam st bt trong khng kh thu c 2,762 gam mt
oxit st duy nht. Cng thc ca oxit st l
A. FeO B. Fe
2
O
3
C. Fe
3
O
4
D. Fe
x
O
y

Cu 6: Khng th iu ch Cu t CuSO
4
bng cch
A. in phn nng chy mui.
B. in phn dung dch mui
C. dng Fe kh ht Cu
2+
ra khi dung dh mui.
D. cho tc dng vi dd NaOH d, sau ly kt ta Cu(OH)
2
em nhit phn ri kh
CuO to ra bng C.
Cu 7: Nung x mol Fe trong khng kh mt thi gian thu c 16,08 gam hn hp
gm 4 cht rn. Ho tan hn hp cht rn ny vo dung dch HNO
3
long, thu c
672ml kh NO duy nht (ktc). Gi tr ca x l
A. 0,15 B. 0,21 C. 0,24 D. 0,12
Cu 8: in phn 250ml dung dch CuSO
4
vi in cc tr, khi catot bt u c bt
kh th ngng in phn, thy khi lng catot tng 4,8 gam. Nng mol/lit ca
dung dch CuSO
4
ban u l
A. 0,3M B. 0,35M C. 0,15M D. 0,45M

Cu 9: Thi mt lung kh CO i qua ng s ng m gam hn hp gm Fe
3
O
4
v
CuO nung nng thu c 2,32 gam hn hp rn. Ton b kh thot ra cho hp th ht
vo dung dch cha Ca(OH)
2
d th thu c 5 gam kt ta. m c gi tr l
A. 3,22g B. 3,12g C. 4,0g D. 4,2 g
Cu 10: Cho 19,2 g Cu tc dng ht vi dung dch HNO
3
, kh NO thu c em hp
th vo nc cng dng oxi chuyn ht thnh HNO
3
. Th tch kh oxi (ktc)
tham gia qu trnh trn l
A. 2,24 lit B. 3,36 lit C. 4,48 lit D. 6,72 lit
Cu 11: Khi cho dung dch Ba(OH)
2
d vo dung dch cha FeCl
3
, CuSO
4
, AlCl
3
thu
c kt ta. Nung kt ta trong khng kh n khi lng khng i th thu c
cht rn X. Cht rn X gm
A. FeO, CuO, Al
2
O
3

B. Fe
2
O
3
, CuO, BaSO
4

C. Fe
3
O
4
, CuO, BaSO
4

D. Fe
2
O
3
, CuO
Cu 12: Cho tan hon ton 58g hn hp A gm Fe, Cu, Ag trong dung dch HNO
3

2M thu c 0,15 mol NO; 0,05mol N
2
O v dung dch D. S gam mui khan thu
c khi c cn dung dch D l
A. 120,4 g B. 89,8 g C. 116,9 g D. 90,3 g
Cu 13: Khi lng CuSO
4
.5H
2
O cn thm vo 300 gam dung dch CuSO
4
10%
thu c dung dch c nng CuSO
4
25% l
A. 115,4g B. 121,3 g C. 60 g D. 40 g
Cu 14: a) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO
3
1M thot ra V
1
lit
NO.
b) Cho 3,84 gam Cu phn ng vi 80ml dung dch cha HNO
3
1M v H
2
SO
4

0,5M thot ra V
2
lit NO.
Bit NO l sn phm kh uy nht, cc th tch kh o cng iu kin nhit v
p sut. Quan h gia V
1
v V
2
l
A. V
1
=V
2
B. V
2
=2V
1
C. V
2
=2,5V
1
D. V
2
=1,5V
1

Cu 15: Hn hp A gm Fe
3
O
4
, FeO, Fe
2
O
3
mi oxit u c 0,5 mol. Th tch dung
dch HCl 1M cn ho tan hn hp A l
A. 4 lit B. 8 lit C. 6 lit D. 9 lit
Cu 16: Hp kim no sau y khng phi l ca Cu?
A. ng thau B. ng thic C. Vng ty D. Electron
Cu 17: St tc dng vi nc nhit cao hn 570
0
C th to ra sn phm
A. FeO v H
2
B. Fe
3
O
4
v H
2

C. Fe
2
O
3
v H
2
D. Fe(OH)
2
v H
2

Cu 18: Trong s cc cp kim loi sau y, cp no c tnh cht bn vng trong
khng kh, nc, nh c lp mng oxt mng, rt bn vng bo v?

A. Al v Cr B. Fe v Al
C. Mn v Al D. Fe v Cr
Cu 19: ng thau l hp kim no sau y?
A. Cu Ni B. Cu - Zn
C. Cu Fe D. Cu- Cr
Cu 20: Kim loi no sau y dn in tt nht
A. Al B. Ag C. Au D. Cu
Cu 21: Cho bit Cu ( z = 29). Trong cc cu hnh electron sau, cu hnh electron no
l ca Cu?
A. 1s
2
2s
2
2p
6
3s
2
3p
6
3d
10
4s
1
B. 1s
2
2s
2
2p
6
3s
2
3p
6
4s
2
3d
9

C. 1s
2
2s
2
2p
6
3s
2
3p
6

4s
1
3d
10
D. 1s
2
2s
2
2p
6
3s
2
3p
6
3d
9
4s
2

Cu 22: Nc svayde c cng thc ho hc l
A. Cu(NH
3
)
4
B. [Cu(NH
3
)
2
] (OH)
C. [Cu(NH
3
)
4
] (OH)
2
D. Cu(NH
3
)
2
. 2H
2
O
Cu 23: Cho 4 kim loi Al, Fe, Ag, Cu v 4 dung dch ZnSO
4
, AgNO
3
, CuCl
2
, FeSO
4

.Kim loi kh c c 4 dung dch mui l
A. Ag B. Cu C. Al D. Fe
Cu 24: Cht no sau y c gi l phn chua, dng nh trong nc?
A. Li
2
SO
4

. Al
2

(SO
4
)
3
. 24 H
2
O B. K
2
SO
4

. Al
2
(SO
4
)
3
. 24 H
2
O
C. Na
2
SO
4

. Al
2

(SO
4
)
3
. 24 H
2
O D. (NH
4
)
2
SO
4

. Al
2
(SO
4
)
3
. 24 H
2
O
Cu 25: Trong dung dch Al
2
(SO
4
)
3
long c cha 0,6 mol SO
4
2-
th trong dung dch
c cha
A. 1,8 mol Al
2
(SO
4
)
3
B. 0,2 mol Al
2
(SO
4
)
3

C. 0,8 mol Al
3+
D. 0,6 mol Al
3+

Cu 26: Ho tan hon ton 16,2 gam mt kim loi cha r ho tr, bng dung dch
HNO
3
c 5,6 lit (ktc) hn hp kh A nng 7,2 gam gm NO v N
2
. Kim loi
cho l
A. Cr B. Fe C. Al D. Zn
Cu 27: C cc dung dch AlCl
3
, NaCl, MgCl
2
, H
2
SO
4
. Ch c dng thm mt
thuc th, th c th dng thm thuc th no sau y nhn bit cc dung dch ?
A. Dung dch Ba(OH)
2
d B. Dung dch qu tm
C. Dung dch BaCl
2
d D. Dung dch AgNO
3

Cu 28: Tch Ag ra khi hn hp Ag, Cu, Fe m vn gi nguyn khi lng Ag ban
u ta dng dung dch no sau y?
A. AgNO
3
B. H
2
SO
4
c nng
C. Fe
2
(SO
4
)
3
D. FeSO
4


Cu 29: Ho tan 2 gam st oxit cn 26,07 ml dung dch HCl 10% (d = 1,05 g/ml).
Cng thc oxit st trn l
A. Hn hp Fe
2
O
3
, Fe
3
O
4
B. FeO
C. Fe
2
O
3
D. Fe
3
O
4

Cu 30: Phn ng : Cu + FeCl
3

CuCl
2
+ FeCl
2
cho thy
A. Cu c th kh Fe
3+
thnh Fe
2 +

B. Cu kim loi c oxiho km hn st kim loi
C. Cu kim loi c tnh kh mnh hn st kim loi
D. Fe kim loi b Cu y ra khi dung dch mui
VI. p n, thang im
Mi ph-ng n ng -c 0,3 im.

Ngy son 02/04/2010
Tit 62 Ch-ng 8. phn bit mt s
cht v c
Bi 40. nhn bit mt s ion trong dung dch
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- Bit nguyn tc nhn bit mt s ion trong dd, cch chn mt s thuc th c trng nhn
bit mt s ion trong dd.
- Bit cch nhn bit cc cation Na
+
, NH
4
+
, Ba
2+
, Al
3+
, Fe
3+
, Fe
2+
, Cu
2+

- Bit cch nhn bit cc anion NO
3
-
, SO
4
2-
, Cl
-
, CO
3
2-
.
2. K nng
C k nng tin hnh th nghim nhn bit cc cation v anion trong dd.
Rn luyn k nng vit pthh dng ion rt gn.
3. Tnh cm, thi

II. Trng tm
Tnh cht ca kim loi.
III. Chun b
Gio vin: Dng c: ng nghim, cp ng nghim, gi ng nghim, n cn.
Ha cht: Cc dd: NaCl, BaCl
2
, AlCl
3
, NH
4
Cl, FeCl
3
, NaNO
3
, Na
2
SO
4
, Na
2
CO
3
, CuCl
2
,
NH
3
, HCl, H
2
SO
4
.
Kim loi: Fe ( iu ch dd FeCl
2
) v cc l Cu mng.
IV. Ph-ng php
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Tnh cht ha hc c trng ca kim loi l g?
3. Cc hot ng dy hc
Hot ng 1. Tm hiu nguyn tc nhn bit mt ion trong dd.
I. NGUYN TC NHN BIT MT ION TRONG DUNG DCH
GV nu cu hi: Bng mt thng, da vo u ta c th nhn bit sn phm ca mt p ha
hc?
HS c th tr li: Da vo mu ca sn phm, sn phm l cht kt ta hoc cht khi (dd si
bt).
HS t nu ra c nguyn tc chung: Dng thuc th to vi ion mt hp cht c mu,
mt kt ta hoc mt cht kh t tan (si bt khi bay ra khi dd).
GV: Chuan b cac mau can phan tch, giao noi dung th nghiem va dung cu hoa chat
cho tng nhom hoc sinh. Nen co 2 nhom hoc sinh co cung noi dung th nghiem
e so sanh ket qua. Cho cac nhom hoc sinh tien hanh phan tch.
Hot ng 2. Tm hiu cch nhn bit mt s cation trong dd.
II. NHN BIT MT S CATION TRONG DUNG DCH

1. NHAN BIET CAC CATION KIM LOAI KIEM Na
+

GV: at cau hoi:
- Da vao tnh chat nao e nhan biet cac cation kim loai kiem?
- Dung cu va cac thuoc th dung e nhan biet cac cation nay
la g?
GV: Co the cung cap them thong tin hoac gi y e hoc sinh nh lai cac ac iem
ve tnh chat cua cac ion nay.
Ket luan: - Nhan biet cation kim loai kiem (Na
+

, K
+
) bang cach th mau ngon
la.
(B mui ht vo la).
GV: Thc hien mot so th nghiem khong co ieu kien cho hoc sinh lam nh th
mau ngon la e nhan biet ion Na
+
.
GV: Cach tien hanh nh SGK
HS: Quan sat va cho nhan xet.
2. NHAN BIET CAC CATION NH
4
+

GV: at cau hoi:
- Da vao tnh chat nao e nhan biet cation amoni?
- Dung cu va cac thuoc th dung e nhan biet cac cation nay
la g?
GV: Co the cung cap them thong tin hoac gi y e hoc sinh nh lai cac ac iem
ve tnh chat cua cac ion nay.
Ket luan: - Thuoc th dung e nhan biet ion NH
4
+

la dung dch kiem, nho dd
NaOH vao ong nghiem ng khoang 2 ml dd NH
4
Cl roi un nong ong nghiem.
Dung giay quy tm tam t e nhan biet kh NH
3
hoac nhan biet bang mui
khai.
3. NHAN BIET CAC CATION Ca
2+
, Ba
2+

GV: Yeu cau hoc sinh da vao SGK tra li cau hoi:
- Co the dung thuoc th g e nhan biet cac ion Ba
2+

HS lam th nghiem: Nho dd H
2
SO
4
loang vao ong nghiem ng khoang 1 ml dd BaCl
2

e thu c ket tua trang BaSO
4
. Nho them dd H
2
SO
4
loang, lac ong nghiem e
thay rang ket tua khong tan trong H
2
SO
4
d.
4. CACH NHAN BIET CAC CATION Al
3+


GV: Neu van e:
- Thuoc th cua nhom cac ion nay la g?
- Bang phng phap hoa hoc, phan biet 2 ion nay bang cach
nao?
- Viet cac PTHH dung e nhan biet di dang ion rut gon.
GV: gi y hoc sinh nh lai tnh chat hoa hoc cua ion Al
3+
, Tai sao thuoc th nhom
cua cac ion nay la dung dch kiem.
5. NHAN BIET CAC CATION Fe
2+
, Fe
3+
, Cu
2+

GV: Neu cau hoi:
- Cac ion Fe
2+
, Fe
3+

, Cu
2+
, Mg
2+

co nhng tnh chat g giong va
khac nhau?
- Thuoc th nhom cua nhom cac ion nay lag?
- Bang cach nao co the phan biet c cac ion nay? Viet
PTHH a dung di dang ion rut gon
- Cac ion Fe
2+
, Fe
3+

, Cu
2+
, Mg
2+

kha quen vi hoc sinh. HS hieu
c phng phap nhan biet va cac thuoc th can dung nh
SGK a trnh bay
GV: Can nhac hoc sinh lu y :
- Ket tua Mg(OH)
2
khac vi cac ket tua cua hiroxt con lai cho no co
the tan c trong dung dch muoi amoni. Thuoc th ac trng cua ion Mg
2+
la
dung dch Na
2
HPO
4
.
- Ket tua Cu(OH)
2
khac vi cac ket tua cua hiroxt con lai cho no co
the tan c trong dung dch amoniac. Thuoc th ac trng cua ion Cu
2+
la dung
dch amoniac.
- Cac ion Fe
2+
, Fe
3+

, Cu
2+
, Mg
2+

eu co thuoc th ac trng nen nhan biet c
rat de dang.
Hot ng 3. Tm hiu cch nhn bit mt s anion trong dd.
III. NHN BIT MT S ANION TRONG DUNG DCH
NHAN BIET MOT SO ANION NO
3
-
, Cl
-
, SO
4
2-
, CO
3
2-
HS: Tra li cau hoi:
- Thuoc th dung e nhan biet cac onion NO
3
-
, Cl
-
, SO
4
2-
, CO
3
2-

la g?
- Thuoc th nhom cua cac halogenua la g, da vao ac iem
g e phan biet cac ion Cl
-
vi cac halogenua con lai.
- Viet cac PTHH cua cac phan ng a dung e nhan biet
di dang ion rut gon.

4. Cng c, dn d
GV: s dung bai tap 1, 2, 4 SGK e cung co kien thc trng tam.
5. H-ng dn v nh
Xem tr-c ni dung phn hc ti, lm bi tp 3, 5, 6trong
SGK/174.

Ngy son 05/04/2010
Tit 63
Bi 41. nhn bit mt s cht kh
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- Nguyn tc chung nhn bit mt cht kh.
- Biet cch nhn bit cc kh CO
2
, SO
2
, H
2
S, NH
3
bng pp thch hp.
2. K nng
- Lm th nghim thc hnh nhn bit mt s cht kh.
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc cht CO
2
, SO
2
, H
2
S, NH
3
.
III. Chun b
Gio vin: Chun b ni dung bi dy, dng c th nghim.

IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by nguyn tc nhn bit cc ion trong dd?
3. Cc hot ng dy hc
sinh
Ni dung kin thc
Hoat ong 1
GV at van e: Co bnh kh Cl
2
va
bnh kh O
2
. lam the nao e nhan
biet cac kh o ?
- Kh Cl
2
co mau vang luc: Nhan
biet bang tnh chat vat l.
- a than hong vao bnh kh O
2
no
bung chay: Nhan biet bang tnh
chat hoa hoc.
Rut ra ket luan.

Hoat ong 2
HS nghien cu SGK e biet c
nhng ac iem cua kh CO
2
.
GV at van e: Trong th nghiem
thoi kh CO i qua ong s ng CuO,
un nong, ta co the nhan biet san
pham kh cua phan ng bang cach
nao ?

HS chon thuoc th e tra li.

GV at van e: Lam the nao
e phan biet kh SO
2
vi kh CO
2
?
Co the dung dung dch Ca(OH)
2
hay
khong ?
I NGUYEN TAC CHUNG E
NHAN BIET MOT CHAT KH

Da vao tnh chat vat l hoac tnh
chat hoa hoc ac trng cua chat kh
o.
Th du: Nhan biet kh H
2
S da vao
mui trng thoi, kh NH
3
bang mui khai
ac trng cua no.
II NHAN BIET MOT SO CHAT
KH
1. Nhan biet kh CO
2

ac iem cua kh CO
2
: Khong
mau, khong mui, nang hn khong
kh, rat t tan trong nc Khi tao
thanh t cac dung dch nc no tao
nen s sui bot kha manh va ac
trng.
2
3
CO + 2H
+
CO
2
| + H
2
O
3
HCO + H
+
CO
2
| + H
2
O
Thuoc th: Dung dch Ca(OH)
2

hoac Ba(OH)
2
d.
Hien tng: Co ket tua trang tao
thanh, lam dung dch thu c b van
uc.
CO
2
+ Ca(OH)
2
CaCO
3
+ + H
2
O
CO
2
+ Ba(OH)
2
BaCO
3
+ + H
2
O

nhng ac iem cua kh SO
2
.

Ket luan: Thuoc th tot nhat e
nhan biet kh SO
2
la dung dch nc
Br
2
.

nhng ac iem cua kh H
2
S.
GV at van e: Co the nhan
biet kh H
2
S da vao tnh chat vat l
va tnh chat hoa hoc nao ?
- Tnh chat vat l: Mui trng thoi.
- Tnh chat hoa hoc: Tao c ket
tua en vi ion Cu
2+
va Pb
2+
.

nhng ac iem cua kh NH
3
.
GV at van e: Lam the nao
nhan biet kh NH
3
bang phng phap
vat l va phng phap hoa hoc ?
- Phng phap vat l: Mui khai.
- Phng phap hoa hoc: NH
3
lam
giay quy tm am hoa xanh.
Chu y: Cac kh SO
2
va SO
3
cung
tao c ket tua trang vi dung dch
Ca(OH)
2
va dung dch Ba(OH)
2
.
2. Nhan biet kh SO
2

ac iem cua kh SO
2

- Kh SO
2
khong mau, nang hn
khong kh, gay ngat va oc.
- Kh SO
2
cung lam uc nc voi
trong nh kh CO
2
.
Thuoc th: Dung dch nc Br
2
d.
Hien tng: Nc Br
2
b nhat mau.
SO
2
+ Br
2
+ 2H
2
O H
2
SO
4
+ 2HBr
3. Nhan biet kh H
2
S
ac iem cua kh H
2
S: Kh H
2
S
khong mau, nang hn khong kh, co
mui trng thoi va rat oc.

Thuoc th: Dung dch muoi Cu
2+

hoac Pb
2+
.
Hien tng: Co ket tua mau en
tao thanh.
H
2
S + Cu
2+
CuS+ + 2H
+
mau en
H
2
S + Pb
2+
PbS+ + 2H
+
mau en
4. Nhan biet kh NH
3
ac iem cua kh NH
3
: Kh H
2
S
khong mau, nhe hn khong kh, tan
nhieu trong nc, co mui khai ac
trng.
Thuoc th: Ngi bang mui hoac
dung giay quy tm am.
Hien tng: Co mui khai, lam
giay quy tm am hoa xanh.
4. Cng c, dn d
1. Co the dung dung dch nc voi trong e phan biet 2 kh CO
2
va SO
2

c khong? Tai sao?
2. Cho 2 bnh kh rieng biet ng cac kh CO
2
va SO
2
. Hay trnh bay cach
nhan biet tng kh. Viet cac PTHH.
5. H-ng dn v nh


Ngy son 10/04/2010
Tit 64
Bi 42. nhn bit mt s cht kh
-------------------
I. Mc tiu bi hc
1. Kin thc
HS bit:
- Nguyn tc chung nhn bit mt cht kh.
- Biet cch nhn bit cc kh CO
2
, SO
2
, H
2
S, NH
3
bng pp thch hp.
2. K nng
- Lm th nghim thc hnh nhn bit mt s cht kh.
3. Tnh cm, thi
II. Trng tm
Tnh cht ha hc ca cc cht CO
2
, SO
2
, H
2
S, NH
3
.
III. Chun b
Gio vin: Chun b ni dung bi dy, dng c th nghim.

IV. Ph-ng php
m thoi gi m nu vn .
V. Ni dung ln lp
1. n nh lp
2. Kim tra bi c
Hy trnh by nguyn tc nhn bit cc ion trong dd?
3. Cc hot ng dy hc
Hot ng ca gio vin v
hc sinh
Ni dung kin thc

Hoat ong 1
HS da vao phan ng ac trng
dung e nhan biet cac cation e
giai quyet bai toan.
GV quan sat, theo doi, giup
HS hoan thanh bai tap.

Hoat ong 2
GV yeu cau HS cho biet cac
hien tng xay ra khi cho t t
dung dch NaOH vao moi dung dch,
t o xem co the nhan biet c
toi a bao nhieu dung dch.

Hoat ong 3
GV yeu cau HS xac nh moi
trng cua cac dung dch.
HS giai quyet bai toan.

Bai 1: Trnh bay cach nhan biet cac
ion trong cac dung dch rieng re sau:
Ba
2+
, Fe
3+
, Cu
2+
.
Giai
Ba
2+
, Fe
3+
, Cu
2+
+ dd SO
4
2-
trang khong hien tng
Ba
2+
Fe
3+
, Cu
2+
+ dd NH
3
d
nau o xanh, sau o tan
Fe
3+
Cu
2+

Bai 2: Co 5 ong nghiem khong nhan,
moi ong ng mot trong cac dung dch
sau ay (nong o khoang 0,1M): NH
4
Cl,
FeCl
2
, AlCl
3
, MgCl
2
, CuCl
2
. Ch dung dung
dch NaOH nho t t vao tng dung
dch, co the nhan biet c toi da
cac dung dch nao sau ay ?
A. Hai dung dch: NH
4
Cl, CuCl
2
.
B. Ba dung dch: NH
4
Cl, MgCl
2
, CuCl
2
.
C. Bon dung dch: NH
4
Cl, AlCl
3
, MgCl
2
,
CuCl
2
.
D. Ca 5 dung dch.
Bai 3: Co 4 ong nghiem khong nhan,
moi ong ng mot trong cac dung dch
sau (nong o khoang 0,01M): NaCl,
Na
2
CO
3
, KHSO
4
va CH
3
NH
2
. Ch dung
giay quy tm lan lt nhung vao 4 dung
dch, quan sat s thay oi mau sac
cua no co the nhan biet c day
cac dung dch nao ?

Hoat ong 4
GV lu y HS ay la bai tap
chng to s co mat cua cac
chat nen neu co n chat th ta phai
chng minh c s co mat cua
ca n chat. Dang bai tap nay khac
so vi bai tap nhan biet (nhan
biet n chat th ta ch can nhan
biet c n 1 chat).

HS giai quyet bai toan di s
hng dan cua GV.
A. Dung dch NaCl.
B. Hai dung dch NaCl va KHSO
4
.
C. Hai dung dch KHSO
4
va CH
3
NH
2
.
D. Ba dung dch NaCl, KHSO
4
va Na
2
CO
3
.
Bai 4: Hay phan biet hai dung dch
rieng re sau: (NH
4
)
2
S va (NH
4
)
2
SO
4
bang
mot thuoc th.
Giai
Cho mot mau giay loc tam dung dch
Pb(NO
3
)
2
vao 2 dung dch tren, dung dch
nao lam cho mau giay loc chuyen
sang mau en la dung dch (NH
4
)
2
S.
(NH
4
)
2
S + Pb(NO
3
)
2
PbS+ + 2NH
4
NO
3

Bai 5: Co hon hp kh gom SO
2
,
CO
2
va H
2
. Hay chng minh trong hon
hp co mat tng kh o. Viet PTHH
cua cac phan ng.
Giai
Cho hon hp kh i qua nc Br
2
d,
thay nc Br
2
b nhat mau chng to
co kh SO
2
.
SO
2
+ Br
2
+ 2H
2
O H
2
SO
4
+ 2HBr (1)
Kh i ra sau phan ng tiep tuc dan
vao dung dch Ca(OH)
2
d thay co ket
tua trang chng to co kh CO
2
.
CO
2
+ Ca(OH)
2
CaCO
3
+ + H
2
O (2)
Kh i ra sau phan ng (2) dan qua
ong ng CuO un nong thay tao ra Cu
mau o chng to co kh H
2
.
CuO + H
2
Cu + H
2
O
t
0

4. Cng c, dn d
1. Co the dung dung dch nc voi trong e phan biet 2 kh CO
2
va SO
2

c khong? Tai sao?
2. Cho 2 bnh kh rieng biet ng cac kh CO
2
va SO
2
. Hay trnh bay cach
nhan biet tng kh. Viet cac PTHH.
5. H-ng dn v nh


12 CB

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

12 CB

Uploaded by

Copyright:

Available Formats

Gio n Ha 12-CB GV: Phan Th Thanh Huyn THPT C - Ngh An

Ngy son 18/08/2009

You might also like