BI TP Chng: ANEHIT XETON AXIT CACBOXILIC

1. t chy hon ton 0,1 mol hn hp X gm 2 axit cacboxylic ng ng k tip thu c 6,16 gam CO2 v 2,52 gam H2O. Cng thc ca 2 axit l A. CH3COOH v C2H5COOH. B. C2H3COOH v C3H5COOH. C. HCOOH v CH3COOH. D. C2H5COOH v C3H7COOH. 2. Chia 0,6 mol hn hp 2 axit no thnh 2 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh CO2 (ktc). Phn 2 tc dng va vi 500 ml dung dch NaOH 1M. Cng thc cu to ca 2 axit ban u l A. CH3-COOH v CH2=CH-COOH. B. H-COOH v HOOC-COOH. C. CH3-COOH v HOOC-COOH. D. H-COOH v CH3-CH2-COOH. 3. Cng thc chung ca axit cacboxylic no, n chc, mch h l A. CnH2nO2. B. CnH2n+2O2. C. CnH2n+1O2. D. CnH2n-1O2. 4. Cng thc chung axit cacboxylic no, a chc, mch h l A. CnH2n-m(COOH)m. B. CnH2n+2-m(COOH)m. C. CnH2n+1(COOH)m D. CnH2n-1(COOH)m 5. C4H8O2 c s ng phn axit l A. 1. B. 2. C. 3. D. 4. 6. Trn 20 gam dung dch axit n chc X 23% vi 50 gam dung dch axit n chc Y 20,64% thu c dung dch D. trung ho D cn 200 ml dung dch NaOH 1,1M. Bit rng D tham gia phn ng trng gng. Cng thc ca X v Y tng ng l A. HCOOH v C2H3COOH. B. C3H7COOH v HCOOH. C. C3H5COOH v HCOOH. D. HCOOH v C3H5COOH. 7. Axit icacboxylic mch thng c phn trm khi lng ca cc nguyn t tng ng l % C = 45,46%, %H = 6,06%, %O = 48,49%. Cng thc cu to ca axit l A. HOOC-COOH. B. HOOC-CH2-COOH. C. HOOC-CH2-CH2-COOH. D. HOOC-CH2-CH2-CH2-COOH. 8. Axit X mch thng, c cng thc thc nghim (C3H5O2)n. Cng thc cu to ca X l A. C2H4COOH. B. HOOC-(CH2)4-COOH. C. CH3CH2CH(COOH)CH2COOH. D. HOOCCH2CH(CH3)CH2COOH 9. trung ho 8,8 gam mt axit cacboxylic mch thng thuc dy ng ng ca axit fomic cn 100ml dung dch NaOH 1M. Cng thc cu to ca axit l A. CH3COOH. B. CH3(CH2)2COOH. C. CH3(CH2)3COOH. D. CH3CH2COOH. 10. X, Y l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp A gm 4,6 gam X v 6,0 gam Y tc dng ht vi Na thu c 2,24 lt kh H2(ktc). Cng thc phn t ca X v Y ln lt l A. CH2O2 v C2H4O2. B. C2H4O2 v C3H6O2. C. C3H6O2 v C4H8O2. D. C4H8O2 v C5H10O2. 11. t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. Cng thc phn t ca chng l A. C2H4O2 v C3H6O2. B. C3H6O2 v C4H8O2. C. CH2O2 v C2H4O2. D. C3H4O2 v C4H6O2. 12. t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. S mol ca mi axit ln lt l A. 0,05 v 0,05. B. 0,045 v 0,055. C. 0,04 v 0,06. D. 0,06 v 0,04. 13. Cho 14,8 gam hn hp 2 axit hu c no, n chc tc dng vi lng va Na2CO3 to thnh 2,24 lt kh CO2 (ktc). Khi lng mi mui thu c l A. 23,2. B. 21,2. C. 20,2. D. 19,2. 14. Mt hn hp hai axit hu c c phn ng trng gng. Axit c khi lng phn t ln khi tc dng vi Cl2 (as) thu c ba sn phm monoclo. Cng thc ca hai axit l A. CH3COOH v HCOOH. B. CH3COOH v HOOC-COOH. C. HCOOH v CH3(CH2)2COOH. D. HCOOH v (CH3)2CHCOOH. 15. Trung ho 9 gam mt axit n chc bng lng va NaOH thu c 12,3 gam mui. Cng thc cu to ca axit l A. HCOOH. B. CH2=CHCOOH. C. CH3COOH. D. CH3CH2COOH. 16. Cng thc thc nghim ca mt axit no, a chc l (C3H4O3)n. Cng thc phn t ca axit l 17. t chy hon ton mt axit hu c ta thu c: nCO2 = nH2O. Axit l

A. axit hu c c hai chc, cha no. B. axit vng no. C. axit n chc, no. D. axit n chc, cha no. 18. Trong cc ng phn axit C5H10O2. S lng ng phn khi tc dng vi Cl2(as) ch cho mt sn phm th monoclo duy nht (theo t l 1:1) l A. 4. B. 2. C. 3. D. 1. 19. t chy hon ton 1,44 gam mui ca axit hu c thm n chc ta thu c 0,53 gam Na2CO3 v 1,456 lt kh CO2 (ktc) v 0,45 gam H2O. CTCT ca mui axit thm l A. C6H5CH2COONa. B. C6H5COONa. C. C6H5CH2CH2COONa. D. C6H5CH(CH3)COONa. 20. X l axit hu c tho mn iu kin: m gam X + NaHCO3 x mol CO2 v m gam X + O2 x mol CO2. Axit X l A. CH3COOH. B. HOOC-COOH. C. CH3C6H3(COOH)2. D.CH3CH2COOH. 21. Cho 5,76g axit hu c n chc X tc dng ht vi CaCO3 d, thu c 7,28g mui. Tn gi ca X l A. axit fomic B. axit axetic C. axit butyric. D. axit acrylic. 22. trung ho a gam hn hp X gm 2 axit no, n chc, mch thng l ng ng k tip cn 100 ml dung dch NaOH 0,3M. Mt khc, t chy hon ton a gam X thu c b gam nc v (b+3,64) gam CO2. Cng thc phn t ca 2 axit l A. CH2O2 v C2H4O2. B. C2H4O2 v C3H6O2. 23. Thc hin phn ng este ho m gam CH3COOH bng mt lng va C2H5OH (xc tc H2SO4 c, un nng) thu c 1,76 gam este (h=100%). Gi tr ca m l A. 2,1. B. 1,1. C. 1,2. D. 1,4. 24. Hn hp X gm 1 axit no n chc v 2 axit khng no n chc c 1 lin kt i, l ng ng k tip nhau. Cho X tc dng va vi 100ml dung dch NaOH 2M, thu c 17,04 gam hn hp mui. Mt khc, t chy hon ton X thu c tng khi lng CO2 v H2O l 26,72 gam. Cng thc phn t ca 3 axit trong X l A. CH2O2, C3H4O2 v C4H6O2. B. C2H4O2, C3H4O2 v C4H6O2. C. CH2O2, C5H8O2 v C4H6O2. D. C2H4O2, C5H8O2 v C4H6O2 25. Cho hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip tc dng va vi dung dch NaHCO3 thu c 1,12 lt kh CO2 (ktc). Nu t chy hon ton X th thu c 3,136 lt CO2 (ktc). Cng thc cu to ca 2 axit trong X l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH. C. C2H3COOH v C3H5COOH. D. C2H5COOH v C3H7COOH. 26. (A-07): t chy hon ton a mol mt axit hu c Y c 2a mol CO2. Mt khc, trung ho a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. CH3COOH. B. HOOC-COOH. C. HOOC-CH2-CH2-COOH. D. C2H5COOH. 27. (B-07): trung ho 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l A. CH3COOH. B. C2H5COOH. C. C3H7COOH. D. HCOOH. 28. (B-07): t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 (ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 8,96. B. 11,2. C. 4,48. D. 6,72. c k on vn sau tr li 2 cu sau: Hn hp X gm 1 axit no, mch thng, 2 ln axit (A) v 1 axit khng no c mt ni i trong gc hirocacbon, mch h, n chc (B), s nguyn t cacbon trong A gp i s nguyn t cacbon trong B. t chy hon ton 5,08g X thu c 4,704 lt CO2(ktc).Trung ho 5,08g X cn 350ml dung dch NaOH 0,2M. 29. Cng thc phn t ca A v B tng ng l A. C8H14O4 v C4H6O2. B. C6H12O4 v C3H4O2. C. C6H10O4 v C3H4O2. D. C4H6O4 v C2H4O2. 30. S gam mui thu c sau phn ng trung ho l A. 5,78. B. 6,62. C. 7,48. D. 8,24. 31. Chia hn hp 2 anehit no n chc thnh 2 phn bng nhau. t chy hon ton phn 1 thu c 0,54 gam H2O. Phn 2 cho tc dng vi H2 d (h = 100%) thu c hn hp 2 ru. t chy hon ton 2 ru thu c V lt kh CO2 (ktc). Gi tr ca V l A. 0,112. B. 2,24. C. 0,672. D. 1,344.

32. Cho 10,2 gam hn hp X gm 2 anehit no (c s mol bng nhau) tc dng vi dung dch AgNO3 trong NH3 (d) thu c 64,8 gam Ag v mui ca 2 axit hu c. Mt khc, khi cho 12,75 gam X bay hi 136,5OC v 2 atm th th tch hi thu c l 4,2 lt. Cng thc ca 2 anehit l A. CH3-CHO v OHC-CHO. B. HCHO v OHC-CH2-CHO. C. CH3-CHO v HCHO. D. OHC-CHO v C2H5-CHO. 33. C hai bnh mt nhn cha C2H2 v . Thuc th duy nht c th nhn c 2 bnh trn l A. dung dch AgNO3 trong NH3. B. dung dch NaOH. C. dung dch HCl. D. Cu(OH)2. 34. S lng ng phn anhit ng vi cng thc phn t C5H10O l A. 3. B. 4. C. 5. D. 6. 35. Anehit no X c cng thc n gin nht l C2H3O. CTPT ca X l A. C2H3O. B. C4H6O2. C. C6H9O3. D. C8H12O4. 36. Oxi ho 2,2 gam mt anehit n chc X thu c 3 gam axit tng ng (h = 100%). CTCT ca X l A. CH3-CHO. B. CH3- CH2-CHO. C. (CH3)2CH-CHO. D. CH3-CH2-CH2-CHO. 37. Cho 1,02 gam hn hp gm hai anehit no, n chc, mch h (khc HCHO) k tip nhau trong dy ng ng phn ng vi dung dch AgNO3 trong NH3 d, thu c 4,32 gam Ag (h = 100%). Tn gi ca 2 anehit l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. 38. Cho 2,3 gam hp cht hu c X (cha C, H, O) phn ng ht vi dung dch AgNO3 trong NH3 d, to ra 10,8 gam Ag. Tn gi ca X l 39. t chy mt hn hp anehit l ng ng, thu c a mol CO2 v 18a gam H2O. Hai anehit thuc loi anehit A. no, n chc. B. vng no, n chc. C. no, hai chc. D. khng no c mt ni i, hai chc. 40. Khi cho 0,1 mol X (c t khi hi s vi H2 ln hn 20) tc dng vi dung dch AgNO3 trong NH3 d, thu c 43,2g Ag. X thuc loi anehit A. n chc. B. 2 chc. C. 3 chc. D. 4 chc. 41. Hp cht hu c X un nh vi dung dch AgNO3 trong NH3 (1:2), thu c sn phm X. Cho X tc dng vi dung dch HCl hoc dung dch NaOH u thu c kh. Cng thc cu to ca X l A. HCOOH. B. HCHO. C. CH3COONa. D. CH3CHO. 42. Cho 0,94 g hn hp hai anehit n chc, no, k tip nhau trong dy ng ng tc dng vi dung dch AgNO3 trong NH3 thu c 3,24 gam Ag. CTPT ca hai anehit l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. 43. Trong cng nghip, ngi ta iu ch HCHO bng phng php A. oxi ho CH3OH (Cu, tO). B. nhit phn (HCOO)2Ca. C. kim ho CH2Cl2. D. kh HCOOH bng LiAlH4. 44. Cng thc tng qut ca anehit no, hai chc mch h l A. CnH2n+2O2. B. CnH2nO2. C. CnH2n-2O2. D. CnH2n-4O2. 45. Cho 7,2 gam mt anehit no, n chc X phn ng hon ton AgNO3 trong NH3 thu c 21,6 gam Ag. Nu cho A tc dng vi H2 (Ni, to), thu c ru n chc Y c mch nhnh. CTCT ca A l A. (CH3)2CH-CHO. B. (CH3)2CH-CH2-CHO. C. CH3-CH2-CH2-CHO. D. CH3-CH(CH3)-CH2-CHO. 46. X c CTCT l Cl-CH2-CH(CH3)-CH2-CHO. Danh php IUPAC ca X l A. 1-clo2-metyl butanal. B. 2-metylenclorua butanal. C. 4-clo3-metyl butanal. D. 3-metyl-4-clobutanal. 47. Cho hn hp X gm 2 anehit ng ng k tip tc dng ht vi H2 (Ni, tO), thu c hn hp Y. t chy hon ton Y thu c 6,6 gam CO2 v 4,5 gam H2O. Cng thc phn t ca 2 anehit trong X l A. CH4O v C2H6O. B. CH2O v C2H4O. C. C3H6O v C4H8O. D. C3H8O v C4H10O. 48. t chy hon ton 19,2 gam hn hp X gm 2 anehit ng ng k tip thu c 17,92 lt kh CO2 (ktc) v 14,4 gam H2O. Nu cho 9,6 gam X tc dng ht vi dung dch AgNO3 trong NH3 (d) th thu c m gam Ag. Gi tr ca m l A. 75,6. B. 151,2. C. 37,8. D. 21,6.

49. Hn hp X gm 2 anehit no n chc, mch thng, l ng ng k tip. Khi cho 3,32 gam B tc dng vi dung dch AgNO3 trong NH3 d thu c 10,8 gam Ag. Tn gica 2 anehit trong X l A. etanal v metanal. B. etanal v propanal. C. propanal v butanal. D. butanal v pentanal. 50. Chuyn ho hon ton 4,2 gam anehit X mch h bng phn ng trng gng vi dung dch AgNO3 trong NH3 d ri cho lng Ag thu c tc dng ht vi dung dch HNO3 to ra 3,792 lt NO2 27o C v 740mmHg. Tn gi ca X l anehit A. fomic. B. axetic. C. acrylic. D. oxalic. 51. X l hn hp HCHO v CH3CHO. Khi oxi ho p gam X bng O2 thu c (p+1,6) gam Y gm 2 axit tng ng (h=100%). Cho p gam X tc dng vi dung dch AgNO3trong NH3 d thu c 25,92 gam Ag. Phn trm khi lng HCHO trong hn hp B l A. 14,56%. B. 85,44%. C. 73,17%. D. 26,83%. 52. X l hn hp HCHO v CH3CHO. Khi oxi ho X bng O2 thu c hn hp Y gm 2 axit tng ng (h=100%). T khi hi ca Y so vi X l m. Khong gi tr ca m l A. 1,36 < m < 1,53. B. 1,36 < m < 1,67. C. 1,53 < m < 1,67. D. 1,67 < m < 2,33. 53. Oxi ho 53,2 gam hn hp 1 ru n chc v 1 anehit n chc thu c 1 axit hu c duy nht (h=100%). Cho lng axit ny tc dng ht vi m gam dung dch NaOH 2% v Na2CO313,25% thu c dung dch ch cha mui ca axit hu c nng 21,87%. Tn gi ca anehit ban u l A. etanal. B. metanal. C. butanal. D. propanal. 54. t chy hon ton hn hp 3 anehit no n chc thu c 4,48 lt kh CO2(ktc). Cng lng hn hp , nu oxi ho thnh axit (h = 100%), ri ly axit to thnh em t chy hon ton th thu c m gam nc. Gi tr ca m l A. 1,8. B. 2,7. C. 3,6. D. 5,4. 55. Cho hn hp X gm 2 anehit n chc tc dng vi H2 (Ni,to) thy tn V lt H2 (ktc) v thu c 2 ru no. Nu cho hn hp ru ny tc dng ht vi Na thu c 0,375V lt H2(ktc). Hn hp X gm A. 2 anehit no. B. 2 anehit khng no. C. 1 anehit no v 1 anehit khng no. D. 1 anehit khng no v 1 anehit thm. 56. (A-07): Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. CH3CH(OH)CHO C. OHC-CHO. D. CH3CHO. 57. (A-07): Cho 6,6 gam mt anehit X n chc, mch h tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi HNO3 thot ra 2,24 lt kh NO duy nht (ktc). Cng thc cu to thu gn ca X l A. CH3CHO. B. HCHO. C. CH2=CHCHO. D. CH3CH2CHO. 58. (A-07): Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3 l A. anehit axetic, but-1-in, etilen. B. anehit fomic, axetilen, etilen. C. anehit axetic, but-2-in, axetilen. D. axit fomic, vinylaxetilen, propin. 59. (B-07): t chy hon ton a mol mt anehit X mch h to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. no, hai chc. B. no, n chc. C. khng no c hai ni i, n chc. D. khng no c mt ni i, n chc. 60. (B-07): Khi oxi ho 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l A. C2H3CHO. B. CH3CHO. C. HCHO. D. C2H5CHO. 61. Chia m gam andehit thnh 2 phn bng nhau -Phn 1 b t chy hon ton thu c s mol CO2 bng s mol H2O -Phn 2 cho tc dng vi AgNO3 trong dung dch NH3 d thu c Ag kt ta theo t l mol nandehit : nAg = 1 : 4 . Vy andeht l A. Andehit no, n chc B. Andehit no, hai chc C. Andehit fomic D. Khng xc nh c 62. t chy mt hn hp cc andehit ng ng thu c s mol CO2 bng s mol H2O th l dy ng ng A. Andeht no , n chc B. Andehit no, mch vng C. Andehit no , hai chc D. C A , B , C u ng

63. Chn pht biu sai trong cc pht biu sau y ? A. Phn t HCHO c cu to phng , cc gc HCH v HCO u xp x 1200 . Tng t lin kt C = C , lin kt C = O gm 1 lin kt (xich ma) o v 1 lin kt (pi) , lin kt xich ma bn cn lin kt pi km bn ; tuy nhin khc vi lin kt C = C , lin kt C = O phn cc mnh B. Khc vi ru metylic v tng t nh metylclorua , andehit fomic l cht kh v khng c lin kt hidro lin phn t C. Tng t nh ru metylic v khc vi metylclorua , andehhit fomic tan tt trong nc v trong nc HCHO tn ti ch yu dng HCH(OH)2 (do phn ng cng nc) d tan , nu cn phn t HCHO th phn t ny cng to c lin kt hidro vi nc. D. fomon hay fomalin l dung dch cha 37 40% HCHO trong ru 64. Phn ng ngng t 2 phn t etanal to thnh hp cht andol ( va c nhm andehit va c nhm ru ) c thc hin vi cht xc tc l A. AlCl3 B. Ni C. Axit D. Baz 65. Trong nhiu tinh du tho mc c nhng andehit khng no to nn mi thm cho cc tinh du ny . V d tinh du qu c andehit xinamic C6H5CH=CH-CHO , trong tinh du x v chanh c xitronelal C9H17CHO . C th dng ho cht no tinh ch cc andeht trn ? A. AgNO3/ NH3 B. Cu(OH)2 / NaOH C. NaHSO3 bo ho v HCl D. H2(Ni ,t0) 66. Cng thc phn t ca andehit c dng tng qut CnH2n+2-2a -2kOk . Hy cho bit pht biu sai ? A. Cc ch s n , a , k c iu kin n > 1 ; a > 0 ; k > 1 B. Nu a = 0 ; k = 1 th thu c andehit no , n chc C. Nu andehit hai chc v mt vng no th cng thc phn t c dng CnH2n-4O2 n > 5 D. Tng s li kt pi ( ) v vng trong cng thc cu to l a 67. T khi hi ca 2 andehit no , n chc i vi oxi < 2 . t chy hon ton m gam hn hp gm hai andehit trn thu c 7,04 gam CO2 . Khi cho m gam hn hp trn phn ng hon ton vi AgNO3 d trong dung dch NH3 thu c 12,96 gam Ag . Cng thc phn t ca hai andehit v thnh phn % khi lng ca chng l A. CH3CHO : 27,5% ; CH3CH2CHO : 72,5% B. HCHO : 20,5% ; CH3CHO : 79,5% C. HCHO : 3,82% ; CH3CH2CHO : 96,18% D. C A v C 68. Cho cht A v H2 i qua Ni nung nng thu c cht B . Cht B c t khi hi i vi NO bng 2 . Ho lng cht B v cho 3 gam cht lng B tc dng vi Na d thu c 0,7 lt H2 00C v 0,8 atm . Cho 2,8 gam cht A tc dng vi AgNO3 trong dung dch NH3 d to ra 10,8 gam Ag . Cng thc phn t ca A l A. C2H3CHO B. C2H5CHO C. CH3CHO D. HCHO 69. Hp cht c cng thc phn t C3H6O tc dng c vi Na , H2 , trng hp . Vy C3H6O c th l : A. Propanal B. Axeton C. Ru Anlylic D. Etylvinylete t chy hon ton 19,2 gam hn hp X gm 2 andehit ng ng lin tip thu c 17,92 lt CO2(ktc) v 14,4 gam H2O . Nu cho 9,6 gam hn hp trn tc dng vi AgNO3/NH3 d th thu c m gam Ag kt ta . Nu ly 9,6 gam hn hp trn cho phn ng cng vi H2 hon ton thu c hn hp X1 gm 2 cht mi . t chy hon ton X1 thu c V lt CO2(ktc) v m, gam H2O 70. Cng thc ca 2 andeht l A. CH3CHO v CH3CH2CHO B. HCHO v CH3CHO C. O=CH-CH=O v O=C-CH2-CH=O D. CH3CH2CHO v C3H7CHO 71. Khi lng tnh bng gam ca Ag thu c l A. 75,6g B. 54,0g C. 5,4g D. 21,6g 72. Gi tr V(CO2) v m, (H2O) A. 17,92 lit v 14,4 g B. 8,96 lt v 11,7g C. 4,48 lit v 7,2 g D. 8,96 lit v 7,2g 73. Cho hn hp metanal v hidro i qua ng ng Ni nung nng . Dn ton b hn hp sau phn ng vo bnh nc lnh lm ngng t hon ton hi ca cht lng v ho tan cht kh c th tan c , khi khi lng ca bnh tng 8,65g . Ly dung dch trong bnh ny em un vi AgNO3 trong dung dch NH3 thu c 32,4 gam Ag ( cc phn ng xy ra hon ton) . Khi lng metanal ban u l : A. 7,60g B. 7,25g C. 8,25g D. 8,40g 74. Mt ru no c cng thc thc nghim (C2H5O)n . Vy cng thc phn t ca ru l A. C6H15 O3 B. C4H10O2 C. C4H10O D. C6H14O3

75. Cho hn hp gm khng kh (d) v hi ca 24 gam metanol i qua cht xc tc l Cu nung nng , ngi ta thu c 40 ml fomalin 36% c khi lng ring d = 1,1g/ml . Hiu sut ca qu trnh trn l A. 80,4% B. 70,4% C. 65,5% D. 76,6% 76. Cho 0,94g hn hp 2 andehit no, n chc k tip trong cng mt dy ng ng (khng cha andehit fomic) tc dng vi dung dch vi dung dch AgNO3 trong NH3 d thu c 3,24 gam Ag . Cng thc phn t 2 andehit l A. HCHO v CH3CHO B. CH3CHO v C2H5CHO C. C2H5CHO v C3H7CHO D. C3H7CHO v C4H9CHO 77. Hn hp A gm metanal v etanal . Khi oxi ho m gam A (hiu sut 100%) thu c hn hp B gm 2 axit hu c tng ng c dB/A = a . Gi tr ca a trong khong A. 1,45 < a < 1,50 B. 1,26 < a < 1,47 C. 1,62 < a < 1,75 D. 1,36 < a < 1,53 78. Phng php no sau y c dng trong cng nghip sn xut HCHO ? A. Oxi ho metanol nh xc tc Cu hoc Pt B. Oxi ho metanol nh xc tc nit oxit C. Thu phn CH2Cl2 trong mi trng kim hoc nhit phn (HCOO)2Ca D. Phng php A v B Hn hp Y gm 2 andehit ng ng lin tip . t chy hon ton 2,62 gam hn hp Y thu c 2,912 lit CO2(ktc) v 2,344 gam H2O . Nu cho 1,31 gam hn hp Y tc dng vi dung dch AgNO3 d trong NH3 th thu c m gam Ag 79. Hai andehit thuc dy ng ng A. Cha no 2 chc c lin kt pi mch cacbon B. No n chc C. No 2 chc D. Cha no n chc c 1 lin kt pi mch cacbon 80. Cng thc phn t ca 2 andehit l A. CH2O , C2H4O B. C3H4O , C4H6O C. C2H4O , C3H6O D. C3H6O , C4H8O 81. Khi lng Ag thu c l A. 5,4g B. 10,8g C. 1,08g D. 2,16g 82. Hp cht hu c A c cng thc phn t CxHyO2 c MA < 90 dvC , A tham gia phn ng trng gng v c th tc dng vi H2/Ni,t0 sinh ra mt ancol c cacbon bc bn trong phn t . Cng thc cu to ca A l A. (CH3)3CCHO B. (CH3)2CHCHO C. (CH3)3C-CH2-CHO D. (CH3)2CH-CH2-CHO 83. Hn hp X gm 2 andehit A v B . Oxi ho 7,2 gam hn hp X bng dung dch AgNO3 d trong NH3 sau axit ho thu c 2 axit tng ng . Trung ho ht lng axit bng dung dch NaOH , sau nung nng hn hp vi vi ti xt thu c 3,36 lt hn hp kh , cho hn hp kh vo 300 ml dung dch KMnO4 1M trong H2SO4thy th tch hn hp gim i 1/3 ng thi mu tm ca dung dch b nht mu. Bit s nguyn t cacbon trong A ln hn trong B mt nguyn t (cc kh u o ktc) . Cho bit cng thc cu to ca A v B A. HCHO v CH3CHO B. CH3CHO v C2H5CHO C. CH2=CH-CHO v CH3-CHO D. kt qu khc 84. Cu 27 : Cho 3,6 gam ankanal X phn ng hon ton vi dung dch AgNO3/NH3 , lng Ag sinh ra cho tc dng ho ton vi dung dch HNO3 c thu oc 2,8 lt kh NO2 ( sn phm kh duy nht 136,50C , p sut 1,2 atm) . Cng thc phn t ca ankanal l A. HCHO B. CH3CHO C. C2H5CHO D. Kt qu khc 85. Cho 4,2 gam mt andehit A mch h tc dng vi dung dch AgNO3 d trong NH3 thu c hn hp mui B . Nu cho lng Ag sinh ra tc dng vi dung dch HNO3 c to ra 3,792 lt kh NO2 ( sn phm kh duy nht 270C , p sut 740mmHg) t khi hi ca A so vi nit nh hn 4 . Mt khc khi cho 4,2 gam A tc dng vi 0,5 mol H2(Ni t0) thu c cht C vi hiu sut 100% . Cho C tan vo nc c dung dch D . cho 1/10 dung dch D tc dng vi Na cho 12,04 lt H2(ktc) . Cng thc phn t ca A l A. C2H5CHO B. CH3CHO C. C2H3CHO D. Kt qu khc 86. Hp cht hu c X c cng thc phn t C4H6O2 v ch cha mt loi nhm chc . T X v cc cht v c khc , bng 3 phn ng lin tip c th iu ch c cao su Buna . Cng thc cu to c th c ca X l : A. O=CH-CH2-CH2-CH=O B. HO-CH2-C=C-CH2-OH C. CH3-CO-CO-CH3 D. C A , B , C u ng

87. Ly 0,94 gam hn hp hai andehit no , n chc , k tip trong cng mt dy ng ng tc dng ht vi dung dch AgNO3/NH3 d thu c 3,24 gam Ag . Cng thc phn t hai andehit l : A. HCHO v CH3CHO B. CH3CHO v C2H5CHO 88. Hp cht hu c X khi un nng nh vi dung dch AgNO3/NH3 (d) thu c sn phm Y . Y tc dng c vi dung dch HCl hoc dung dch NaOH . u cho 2 kh v c . Hp cht X l A. HCHO B. HCOOH C. HCOONH4 D. C A , B , C u ng 89. Ba cht hu c X , Y , Z c cng thc phn t dng (CH2O)n vi n < 3 . Cho bit - X ch tham gia phn ng trng gng - Y Va tham gia phn ng trng gng , va phn ng vi Na - Z tc dng vi NaHCO3 va , lm bay hi nc ca dung dch sau phn ng , sn phm khan cn li c th tip tc tc dng vi Na . Oxi ho Z iu kin thch hp to thnh hp cht ch cha mt loi nhm chc . t chy hon ton X , Y , Z vi s mol bng nhau th s mol nc thu c t X nh hn t Y v s mol nc thu c t Y nh hn t Z . Hy xc nh cng thc cu to ca X , Y , Z A. CH3-CHO ; HO-CH2CH2-CHO ; CH3COOH B. C2H5-CHO ; HO-CH2-CH2-OH ; HO-CH2-COOH C. HCHO . HO-CH2-CHO , HO-CH2-CH2COOH D. Kt qu khc 90. Cc hp cht hu c mch h cha cc nguyn t cacbon , hidro v oxi l M , N , P , Q u c khi lng phn t bng 60 dvC . Cc cht N , P , Q tc dng c vi Na gii phng H2 . Khi oxi ho N ( c xc tc) to thnh sn phm c kh nng tham gia phn ng trng gng . Cht P tc dung c vi dung dch NaOH . Cht Q c kh nng tham gia phn ng trng gng Cht M khng tc dng vi Na , khng tc dng vi dung dch NaOH v khng tham gia phn ng trng gng . Cc cht M , N , P ,Q c th l : M N P Q A CH3OC2H5 C3H7OH CH3COOH HOCH2CHO B C3H7OH CH3OC2H5 HOCH2CHO CH3COOH C HOCH2CHO CH3COOH CH3OC2H5 C3H7OH D Kt qu Khc 91. Hai hp cht hu c X v Y ng chc cha cc nguyn t C , H , O khi tc dng vi dung dch AgNO3 trong NH3 th 1 mol X hoc Y to ra 4 mol Ag . Khi t chy X v Y th t l s mol O2 tham gia phn ng t chy , CO2 v H2O to thnh nh sau - i vi X : n(O2) : n (CO2) : n (H2O) = 1 : 1 : 1 - i vi Y : n (O2) : n (CO2) : n (H2O) = 1,5 : 2 : 1 Cng thc cu to thu gn ca X v Y l A. CH3CHO v HCHO B. HCHO v C2H5CHO C. HCOOH v HCHO D. HCHO v O=CH-CH=O 92. Cho hp cht hu c X (phn t ch cha C , H , O v mt loi nhm chc) . Bit khi cho 5,8 gam X tc dng vi dung dch AgNO3 d trong NH3 to ra 43,2 gam Ag . Mt khc 0,1mol X sau khi c hidro ha hon ton phn ng va vi 4,6 gam Na . Cng thc cu to ca X l A. HCOOH B. CH3CHO C. O=CH-CH=O D. CH2=CH-CHO 93. Cho 13,6 gam mt hp cht hu c X cha C , H , O tc dng va vi 300ml dung dch AgNO3 2M trong NH3 thu c 43,2 gam Ag . Bit t khi hi ca X so vi oxi bng 2,125 . Xc nh cng thc cu to ca X A. CH3CH2CHO B. CH2=CH-CH2-CHO C. CH=C-CH2CHO D. CH=C-CHO 94. Mt hp cht hu c Y cha cc nguyn t C , H , O ch cha mt loi nhm chc . khi cho 0,01 mol Y tc dng vi dung dch AgNO3 trong NH3 d thu c 4,32 gam Ag . Y c cu to mch thng v cha 37,21% oxi v khi lng . Cng thc cu to ng ca Y l A. HCHO B. CH3CHO C. O=CH-CH=O D. O=CH-(CH2)2CH=O 95. Cho 0,1 mol andehit X tc dng hon ton vi H2 th cn 6,72 lt H2(ktc) v thu c sn phm Y . Cho ton b lng Y tc dng vi Na d thu c 2,24 lt kh H2(ktc) . Mt khc ly 8,4 gam X tc dng vi dung dch AgNO3 d thu c 43,2 gam Ag . Xc nh cng thc cu to ca X v Y A. CH3CHO v C2H5OH B. C2H2(CHO)2 v HOCH2CH(CH3)CH2OH C. C2H2(CHO)2 v HO-CH2(CH2)2CH2OH D. C B v C

96. Cht hu c X cha C , H , O trong hidro chim 2,439% v khi lng . Khi t chy X thu c s mol ca H2O bng s mol ca X b t chy . Bit 0,1 mol X tc dng hon ton vi dung dch AgNO3 d trong NH3 thu c 43,2 gam Ag . Xc nh cng thc cu to ca X A. HCOOH B. CH3CHO C. CH=C-CHO D. O=CH-C=C-CH=O 97. Cho 2,4 gam mt hp cht hu c X (cha C , H , O) tc dng hon ton vi dung dch AgNO3 d trong NH3 thu c 7,2 gam Ag . Xc nh cng thc cu to thu gn ca X A. CH3CHO B. C2H5CHO C. HCHO D. C3H7CHO 98. Cho 3 hp cht hu c X , Y , Z . Bit X cha 3 nguyn t C, H ,Cl trong clo chim 71,72% theo khi lng . Y cha 3 nguyn t C , H , O trong oxi chim 55,71% theo khi lng . Khi thu phn X trong mi trng kim hoc hidro ho Y u thu c hp cht Z . Xc nh cng thc cu to ca X,Y,Z A. CH3Cl , HCHO , CH3OH B. C2H5Cl , CH3CHO , C2H5OH C. C2H4Cl2 , (CHO)2 , C2H4(OH)2 D. Kt qu khc 99. X l hp cht hu c mch h n chc cha C , H , O . t chy hon ton 1 mol X cn 4 mol oxi v thu c CO2 v hi H2O c th tch bng nhau (o cng iu kin nhit v p sut) . Xc nh cng thc cu to c th c ca X A. CH3-CH2-CHO hoc (CH3)2CO B. CH2=CH-CH2-OH C. CH2=CH-O-CH3 D. c A , B , C 100. t chy hon ton 0,059 gam hp cht hu c X ch thu c 0,140 gam CO2 v 0,072 gam H2O . T khi hi ca X i vi oxi bng 2,31 1-Lp cng thc phn t ca X A. C3H6O B. C2H6O2 C. C4H10O D. C5H12O 2- Ly 7,4 gam hp cht X em oxi ho hon ton thnh hai cht Y v Z . Cht Y c phn ng trng gng . Cht Z b trung ho bi 100 ml dung dch NaOH 0,1M . Cng thc cu to thu gn ca Y v Z A. CH3CHO v CH3COOH B. HCHO v HCOOH C. C3H7CHO v C3H7COOH D. Kt qu khc 101. Cho 47,84 gam ru etylic tc dng vi hn hp K2Cr2O7/H2SO4 . Sn phm ca phn ng c tch ngay ra khi mi trng phn ng bng phng php chng ct v dn vo dung dch AgNO3/NH3 d . Sau khi kt thc phn ng , thu c 124,2 gam Ag . Tnh hiu sut ca phn ng oxi ho ru etylic A. 55% B. 70% C. 75% D. Kt qu khc 102. X l hp cht hu c cha C , H , O . Bit X c phn ng trng gng v phn ng vi dung dch NaOH . t chy hon ton a mol X thu c 3a mol CO2 v H2O . X l A. HCOOH B. HCOOCH3 C. CHO-COOH D. CHO-CH2-COOH 103. C th dng nc Brom phn bit A. Andehit no v xeton no B. Andehit no v ru khng no C. Phenol v anilin D. A hoc C 104. Ngi ta thc hin phn ng trng hp axetandehit ( andehit axetic) trong mi trng axit nhit thp (t0 < 00C) thu c cht t rn gi l cn kh c tn l metandehit . Cng thc ca metandehit l : A. CH3-CH(OH)-CH2-CHO B. [-CH(CH3)-O-]3 C. [-CH(CH3)-O-]4 D. [-CH2-O-]n n = 10 n 100 105. t chy hon ton 0,8 mol hn hp gm imetyl ete v ancol etylic ri cho ton b sn phm chy vo bnh ng dung dch Ca(OH)2 d th khi lng kt ta thu c l A. 80 g B. 160 g C. 170 g D. 150 g 106. Thc hin phn ng ehirat ha (xc tc axit H2SO4 c) mt ancol no n chc X trong iu kin thch hp, sau khi phn ng xy ra hon ton thu c cht hu c Y c t khi so vi X bng 1,7. C.T.P.T ca X l A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH 107. un nng mt hn hp gm hai ancol no n chc vi H2SO4 c 1400C thu c 36 g hn hp ete c s mol bng nhau v 10,8 g nc. C.T.P.T ca hai ancol ny l A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH C. CH3OH v C2H5OH D. C4H9OH v C5H11OH 108. t chy hon ton a mol mt ancol X, thu c 13,2 g CO2 v 7,2 g nc. Gi tr ca a l A. 0,05 B. 0,08 C. 0,2 D. 0,1

109. t chy hon ton 1 mol cht hu c X, thu c s mol nc gp hai ln s mol CO2, cn khi cho X tc dng vi Na d th thu c s mol hiro bng mt na s mol ca X. C.T.P.T ca X l A. CH3OH B. C2H5OH C. C3H5OH D. C2H6O2 110. t chy hon ton 0,15 mol mt ancol no n chc thu c 10,08 lt (ktc) CO2. CTPT ca ancol ny l A. CH3OH B. C2H5OH C. C3H7OH D. C3H5OH 111. t chy hon ton m gam hn hp gm hai ancol no n chc thu c 70,4 g CO2 v 39,6 g nc. Gi tr ca m l A. 33,2 g B. 34,5 g C. 35,4 g D. 32,1 g 112. un nng hn hp X gm 0,1 mol CH3OH v 0,2 mol C2H5OH vi H2SO4 c 1400C thu c m gam ete to thnh, hiu sut phn ng t 90%. Gi tr ln nht ca m l A. 12,4 g B. 6,4 g C. 9,7 g D. 8,73 g 113. t chy hon ton 0,1 mol etilenglicol v 0,2 mol ancol A cn 0,95 mol oxi, thu c 0,8 mol CO2 v 1,1 mol nc. C.T.P.T ca A l A. C3H7OH B. C2H5OH C. C3H6(OH)2 D. C3H5(OH)3 114. Cho 2,84 g mt hn hp gm hai ancol n chc trong cng dy ng ng tc dng vi mt lng Na va , thu c 4,6 g mui v V lt (ktc) kh thot ra. Gi tr ca V l A. 0,672 B. 0,896 C. 1,12 D. 1,344 115. Cho 1,42 g mt hn hp gm hai ancol n chc k tip nhau trong cng dy ng ng tc dng vi mt lng Na va , thu c 2,3 g mui. C.T.P.T ca hai ancol ny l A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C. C2H5OH v C3H5OH D. C3H5OH v C4H7OH 116. Cho 18,7 g mt hn hp gm ba ancol n chc tc dng va vi Na thu c 29,7 g mui. C.T.P.T ca ancol c khi lng phn t nh nht l A. C2H5OH B. C3H7OH C. CH3OH D. C3H5OH 117. Cho a gam hn hp gm hai ancol n chc k tip nhau trong cng dy ng ng tc dng ht vi Na d, thu c 2,24 lt (ktc) kh H2. Mt khc, oxi ha hon ton a gam X bng CuO nung nng th thu c hn hp Y gm hai anehit. Cho ton b Y tc dng ht vi dung dch AgNO3/NH3 th thu c 64,8 g Ag. C.T.P.T ca hai ancol ny l A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH C. CH3OH v C2H5OH D. C4H9OH v C5H11OH 118. un nng 34,5 ml ancol etylic (D=0,8 g/ml) vi H2SO4 c nhit 1700C. Hn hp sn phm dng hi c dn ln lt qua bnh 1 cha dung dch H2SO4 c, bnh 2 cha dung dch NaOH c v bnh 3 cha dung dch Br2 d. Kt thc th nghim thy bnh 3 tng 10,08 g. Hiu sut phn ng tch nc t ancol etylic l A. 50% B. 60% C. 70% D. 80% 119. Cho hi mt ancol no n chc X qua bnh ng CuO (d) nung nng. Sau khi phn ng hon ton, thu c hn hp hi c t khi so vi hiro l 15,5. C.T.P.T ca X l A. C3H7OH B. C3H5OH C. CH3OH D. C2H5OH 120. X l mt ancol no mch h. t chy hon ton 0,05 mol X cn 5,04 lt (ktc) thu c hi nc v 6,6 g CO2. C.T.P.T ca X l A. C3H7OH B. C3H5(OH)3 C. C2H5OH D. C2H4(OH)2 121. Hn hp X gm metanol v etanol. Cho 16,3 g X tc dng ht vi Na thy thot ra 4,48 lt (ktc) kh. Thnh phn % theo khi lng ca metanol v etanol trong X ln lt l A. 29,45% v 70,55% B. 70,55% v 29,45% C. 41,03% v 58,97% D. 58,97% v 41,03% 122. un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y c t khi so vi X l 0,622. C.T.P.T ca X l A. CH4O B. C3H8O C. C2H6O D. C4H10O 123. Cho 6,1 g hn hp hai ancol no n chc k tip nhau trong cng dy ng ng tc dng ht vi 2,76 g Na thu c 8,77 g cht rn. C.T.P.T ca hai ancol ny l A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH C. CH3OH v C2H5OH D. C4H9OH v C5H11OH

124. = Cho hn hp X gm hai ancol no n chc k tip nhau trong cng dy ng ng tc dng vi CuO (d) nung nng, thu c hn hp hi Y c t khi so vi hiro l 13,75. C.T.P.T ca hai ancol l A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH C. CH3OH v C2H5OH D. C4H9OH v C5H11OH 125. t chy hon ton m gam hn hp gm hai ancol no n chc mch h ri dn ton b sn phm vo bnh ng dung dch nc vi trong d. Kt thc th nghim thy bnh tng 47,64 g v c 69 g kt ta. Gi tr ca m l A. 12, 6 g B. 10,2 g C. 10,12 g D. 14,52 g 126. Trn hai ancol no n chc mch h hn km nhau hai nguyn t C trong phn t theo t l mol 1:1 thu c hn hp X. un nng X vi H2SO4 c 1400C. Sau khi cc phn ng kt thc, thu c 10,2 g hn hp ete v 1,8 g nc. C.T.P.T ca hai ancol ny l A. CH3OH v C3H7OH B. C2H5OH v C4H9OH C. C3H7OH v C5H11OH D. C4H9OH v C6H13OH 127. = Cho nc brom d vo dung dch phenol thu c 6,62 g kt ta trng. Khi lng phenol c trong dung dch l A. 3,6 g B. 2,67 g C. 1,52 g D. 1,88 g 128. Hn hp X gm ancol etylic v phenol. Cho a gam X tc dng ht vi Na, thu c 1,68 lt (ktc) H2. Mt khc a gam X tc dng va ht vi 25 ml NaOH 2M. Gi tr ca a l A. 4,6 B. 9,3 C. 13,9 D. 9,2 129. Cho m gam hn hp C2H4(OH)2 v C3H6(OH)2 tc dng vi mt lng va Na thu c 3,36 lt (ktc) H2. C cn dung dch thu c 15,4 g mui khan. Gi tr ca m l A. 8,6 B. 8,8 C. 8,7 D. 9,3 130. t chy hon ton 0,2 mol mt ancol no mch h cn dng va ht 15,68 lt (ktc) oxi, thu c 26,4 g CO2. C.T.P.T ca ancol ny l A. C2H6O B. C3H8O C. C3H8O2 D. C3H8O3 131. = t chy hon ton 0,1 mol mt ancol no mch h cn dng va ht 5,6 lt (ktc) oxi, thu c 5,4 g nc. C.T.P.T ca ancol ny l A. C2H6O2 B. C2H6O C. C3H8O2 D. C3H8O3 132. t chy hon ton 0,1 mol mt ancol no mch h cn dng va ht 8,96 lt (ktc) oxi, thu c 7,2 g nc. Nu cho 0,1 mol ancol ny tc dng vi Na d th th tch (ktc) kh H2 thu c l A. 1,12 lt B. 2,24 lt C. 3,36 lt D. 0,56 lt 133. t chy hon ton 0,3 mol mt ancol no mch h thu c 21,6 g nc. Mt khc, khi cho 0,1 mol ancol ny tc dng vi mt lng va Na th thu c 3,36 lt (ktc) kh. C.T.P.T ca ancol ny l A. C2H6O2 B. C2H6O C. C3H8O2 D. C3H8O3 134. t chy hon ton mt lng ancol mch h, thu c 8,8 g CO2 v 5,4 g nc. Mt khc, khi cho 0,2 mol ancol ny tc dng vi mt lng va Na th thu c 4,48 lt (ktc) H2. C.T.P.T ca ancol ny l A. C2H6O2 B. C2H6O C. C3H8O2 D. C3H8O3 135. Cho 1,28 g mt dung dch ancol A trong nc c nng 71,875% tc dng vi mt lng d Na thu c 5,6 lt (ktc) kh. Bit t khi ca A i vi nit ioxit bng 2. C.T.P.T ca ancol ny l A. C3H5(OH)3 B. C4H10(OH)2 C. C4H8(OH)2 D. C4H6(OH)2 136. Khi t chy hon ton 1 mol cht hu c n chc X mch h thu c CO2 v nc c s mol bng nhau v s mol oxi tiu tn gp 4 ln s mol ca X. Bit X lm mt mu Br2 trong CCl4 v khi cng H2 th to ra ancol no n chc. C.T.C.T ca X l A. CH2=CHCH2OH B. CH3CH=CHCHO C. CH2=CHCH2CH2OH D. CH3CH2CH2CHO 137. Cho mt ancol no n chc X tc dng vi HBr thu c hp cht Y c brom chim 58,4% v khi lng. Nu un nng X vi H2SO4 c 1700C th thu c 3 olefin. Tn gi ca X l A. butan 1 ol B. butan 2 ol C. 2 metyl butan 1 ol D. 2 metyl butan 2 ol

138. Cho 14,5 g hn hp gm mt ancol no n chc X v mt iancol no Y tc dng ht vi kim loi kali, thu c 3,92 lt (ktc) kh thot ra. Mt khc em t chy hon ton 29 g hn hp trn th thu c 52,8 g CO2. C.T.P.T ca X v Y ln lt l A. CH3OH v C2H4(OH)2 B. C2H5OH v C2H4(OH)2 C. CH3OH v C3H6(OH)2 D. C2H5OH v C3H6(OH)2 139. t chy hon ton 13,4 g hn hp hai ankanol X v Y l ng ng k tip nhau (MX<MY), ri cho ton b sn phm chy qua dung dch Ba(OH)2 d th thu c 137,9 g kt ta. Bit khi tch nc hai ancol trn th thu c 4 olefin, tn gi ca X v Y ln lt l A. etanol v propan 1 ol B. propan 1 ol v butan 2 ol C. propan 1 ol v butan 1 ol D. propan 2 ol v butan 1 ol 140. Khi thc hin phn ng tch nc ancol X ch thu c mt anken duy nht. Mt khc, khi oxi ha hon ton mt lng X th thu c 5,6 lt (ktc) CO2 v 5,4 g nc. S C.T.C.T ph hp vi tnh cht ca X l A. 2 B. 3 C. 4 D. 5 141. t chy hon ton 1 mol ancol no mch h cn va 3,5 mol oxi. C.T.C.T thu gn ca ancol ny l: A.C2H4(OH)2 B.C2H5OH C.C3H5(OH)3 D.C3H6(OH)2 142. Cho 1,2 g mt anehit n chc X tc dng vi dung dch AgNO3/NH3 d th thu c 17,28 g bc kim loi. X l A. HCHO B. C2H5CHO C. OHC CHO D. C2H3CHO 143. Cho 2,9 g mt anehit Y tc dng vi dung dch AgNO3/NH3 d th thu c 21,6 g bc kim loi. Y l A. OHC CHO B. HCHO C. OHCCH2CH2CHO D. OHCCH2CHO 144. Cho 5,8 g mt anehit X tc dng vi dung dch AgNO3/NH3 d th thu c 21,6 g bc kim loi. X l A. C2H5CHO B. OHC CHO C. HCHO D. CH3CHO 145. Cho hp cht hu c A cha C, H, O v ch cha mt loi nhm chc. Khi cho 2,9 g A tc dng ht vi dung dch AgNO3/NH3 to ra 21,6 g Ag. Mt khc sau khi hiro ha hon ton 0,1 mol A th thy sn phm thu c phn ng va vi 7,8 g kali. C.T.C.T ca A l A. OHC CHO B. OHCCH2CHO C. CH3CHO D. CH2=CHCHO 146. t chy hon ton 2,9 g mt anehit X thu c 6,6 g CO2 v 2,7 g nc. C.T.C.T ca X l A. HCHO B. CH3CHO C. C2H5CHO D. OHC CHO 147. t chy hon ton 2,9 g mt anehit X thu c 4,4 g CO2 v 0,9 g nc. C.T.C.T ca X l A. HCHO B. CH3CHO C. C2H5CHO D. OHC CHO 148. t chy hon ton 896 ml (ktc) hn hp gm hai anehit X v Y (MX<MY) thu c 1,344 lt (ktc) CO2. C.T.P.T ca X v Y ln lt l A. CH3CHO v C2H3CHO B. CH3CHO v C2H5CHO C. HCHO v C3H7CHO D. CH3CHO v OHC CHO 149. Cho 0,02 mol hn hp gm hai anehit n chc X v Y l ng ng ca nhau. Tin hnh phn ng trng gng hn hp trn th thu c 6,48 g Ag. Mt khc, nu t chy hon ton 0,02 mol hn hp ny th thu c 1,32 g CO2. C.T.C.T thu gn ca X v Y ln lt l A. HCHO v CH3CHO B. HCHO v C2H5CHO C. CH3CHO v C2H5CHO D. C2H3CHO v C2H5CHO 150. Cho 3,6 g mt anehit Y tc dng vi dung dch AgNO3/NH3 d th thu c 21,6 g bc kim loi. C.T.C.T ca Y l A. OHC CHO B. CH2=CHCHO C. OHCCH2CH2CHO D. OHCCH2CHO 151. em 150 g dung dch anehit X nng 5,8% tc dng ht vi dung dch AgNO3/NH3. Kt thc phn ng thu c 32,4 g Ag. C.T.P.T ca X l A. CH3CHO B. C2H3CHO C. C2H5CHO D. C3H7CHO 152. Cho 0,1 mol mt cht hu c X tc dng vi lng d dung dch AgNO3/NH3 thu c 43,2 g Ag. Mt khc, khi hiro ha ht 0,1 mol X thu c cht hu c Y, cho Y tc dng vi Na (d) thu c 1,12 lt (ktc) H2. C.T.C.T ca X l A. HCHO B. HOCH2CHO C. OHC CHO D. CH3CHO

153. Cho 9,6 g hn hp X gm axetilen v axetanehit tc dng vi lng d vi dung dch AgNO3/NH3 thu c 69,6 g kt ta. Thnh phn % theo khi lng ca tng cht trong X ln lt l A. 45,83% v 54,17% B. 54,17% v 45,83% C. 78,54% v 21,46% D. 21,46% v 78,54% 154. Dn hn hp gm hiro (d) v 3,92 lt (ktc) hi axetanehit qua ng ng bt Ni nung nng. Hn hp cc cht sau phn ng c lm lnh v thu vo bnh hng ri cho tc dng ht vi Na, thy thot ra 1,568 lt (ktc) kh. Hiu sut phn ng kh axetanehit l A. 60% B. 70% C. 80% D. 90% 155. Hn hp X gm hai anehit no n chc mch h A, B (MA<MB) l ng ng k tip nhau. Cho 1,02 g hn hp trn phn ng vi dung dch AgNO3/NH3 d, thu c 4,32 g Ag. C.T.P.T ca A v B ln lt l A. HCHO v CH3CHO B. CH3CHO v C2H5CHO C. C2H5CHO v C3H7CHO D. C3H7CHO v C4H9CHO 156. Chia a gam hn hp hai anehit X, Y no n chc k tip nhau trong dy ng ng thnh hai phn bng nhau: em t chy hon ton phn 1 thu c 5,4 g nc. Phn 2 sau khi hiro ha hon ton ri em t chy lng ancol thu c thy trong sn phm c 7,65 g nc. Gi tr ca a l A. 12,4 g B. 14,2 g C. 12,6 g D. 16,2 g 157. t chy hon ton m gam hn hp gm hai anehit no n chc thu c 0,36 g nc. Mt khc, nu thc hin phn ng hiro ha m gam hn hp trn ri em t chy hon ton th thu c a gam CO2. Gi tr ca a l A. 0,44 g B. 0,88 g C. 0,66 g D. 1,344 g 158. t chy hon ton hn hp gm ba anehit no n chc thu c 0,54 g nc. Mt khc, nu thc hin phn ng hiro ha hn hp trn vi hiu sut phn ng t 80% ri em t chy hon ton th thu c a gam CO2. Gi tr ca a l A. 0,22 g B. 0,88 g C. 1,056 g D. 1,32 g 159. Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d dung dch AgNO3/NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam B. 10,8 gam C. 64,8 gam D. 21,6 gam 160. Mt hn hp gm hai ankanal c tng s mol l 0,25 mol. Khi cho hn hp ny tc dng vi dung dch AgNO3/NH3 d th thu c 86,4 g Ag v khi lng dung dch gim 77,5 g. Hai ankanal trong hn hp u l: A. HCHO v CH3CHO B. HCHO v C2H5CHO C. HCHO v C3H7CHO D. C3H5CHO v C3H7CHO 161. Cho 4,2 g anehit X mch h tc dng vi dung dch AgNO3/NH3 (d) thu c hn hp mui Y. Nu ly lng Ag thu c cho tc dng ht vi axit HNO3 thy to ra 3,792 lt kh NO2 ( 270C v 0,9735 atm). T khi ca X so vi N2 nh hn 4. C.T.C.T ca X l: A. CH3CHO B. HCHO C. OHC CHO D. CH2=CHCHO 162. Ha hi hon ton 2,9 g cht hu c X cha C, H, O thu c th tch bng th tch ca 2,2 g CO2 trong cng iu kin nhit , p sut. Mt khc, em 2,9 g X tc dng vi lng d dung dch AgNO3/NH3 thu c 21,6 g Ag.Tn gi ca X l: A. Fomanehit B. Axetanehit C. Etanial D. Propionanehit 163. Cho m gam mt ancol no n chc X qua ng ng CuO (d) nung nng. Sau khi phn ng xy ra hon ton thy khi lng cht rn trong ng gim 0,32 g. Hn hp hi thu c c t khi so vi hiro l 19. Gi tr ca m l A. 1,2 g B. 1,16 g C. 0,92 g D. 0,64 g 164. t chy hon ton mt lng anehit X cn va 2,52 lt (ktc) oxi, thu c 4,4 g CO2 v 1,35 g nc. C.T.P.T ca X l A. C3H4O B. C4H6O C. C4H6O2 D. C8H12O4 165. Cho 5,3 g hn hp gm hai axit cacboxylic no n chc l ng ng k tip nhau tc dng vi mt lng va Na thu c 1,12 lt (ktc) kh hiro. C.T.C.T thu gn ca hai axit ny l: A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH C. C2H5COOH v C3H7COOH D. C2H3COOH v C3H5COOH 166. Cho 5,76 g mt axit hu c n chc mch h tc dng ht vi CaCO3 thu c 7,28 g mui ca axit hu c. C.T.C.T thu gn ca axit ny l:

A. HCOOH B. CH3COOH C. C2H5COOH D. C2H3COOH. 167. t chy hon ton 10,6 g hn hp gm hai axit hu c no n chc l ng ng k tip nhau thu c 6,72 lt (ktc) CO2 v a gam nc. C.T.C.T thu gn ca hai axit ny v gi tr ca a ln lt l: A. HCOOH v C2H5COOH; 5,4 g B. HCOOH v CH3COOH; 2,7 g C. HCOOH v CH3COOH; 5,4 g D. CH3COOH v C2H5COOH; 0,9 g 168. t chy hon ton 0,1 mol mt axit cacboxylic no n chc X cn dng 7,84 lt (ktc) O2. C.T.C.T thu gnca X l: A. HCOOH B. CH3COOH C. C2H5COOH D. C2H3COOH 169. t chy hon ton 0,1 mol mt axit hu c n chc X cn dng 6,72 lt (ktc) O2 v thu c 0,3 mol CO2.C.T.C.T thu gn ca X l: A. HOOC-COOH B. CH3COOH C. C2H5COOH D. C2H3COOH 170. t chy hon ton 5,3 g hn hp hai axit hu c no n chc l ng ng lin tip nhau thu c 9,3 g hn hp gm CO2 v H2O. C.T.P.T ca hai axit ny l: A. C2H5COOH v C3H7COOH B. HCOOH v CH3COOH C. CH3COOH v C2H5COOH D. C2H3COOH v C3H5COOH. 171. t chy hon ton 9 g mt axit cacboxylic X thu c 8,8 g CO2 v 1,8 g nc. Tn gi ca X l: 172. Cho 14,4 g mt hp cht hu c X tc dng va vi dung dch NaOH thu c 18,8 g mui. C.T.C.T ca X l A.CH2=CH COOH B. HCOOCH=CH2 C. HO CH=CH CH2 OH D. CH2=C(CH3)COOH 173. t chy hon ton 0,1 mol mt mui natri ca axit hu c X thu c 6,6 g CO2, hi nc v Na2CO3. C.T.C.T ca X l: A. CH3CH2COONa B. HCOONa C. CH2=CHCOONa D. CH3COONa 174. t chy hon ton 0,1 mol mt axit hu c n chc bng V lt (ktc) oxi, thu c 0,5 mol CO2 v 0,5 mol H2O. Gi tr ca V l A. 11,2 lt B.13,44 lt C.14,56 lt D.20,16 lt 175. t chy hon ton m gam mt axit cacboxylic no a chc mch h thu c 0,6 mol CO2 v 0,5 mol H2O. C.T.C.T thu gn ca axit ny l: A. CH3CH = CHCH2CH2COOH B.HOOC(CH2)2COOH C.HOOC(CH2)3COOH D.HOOC(CH2)4COOH 176. Trung ha 50 g dung dch ca axit cacboxylic n chc X c nng 14,8% cn dng 50 ml dung dch NaOH 2M. Tn gi ca X l A. Axit axetic B. Axit acrylic C. Axit fomic D. Axit propionic 177. t chy hon ton 0,1 mol mt axit cacboxylic X thu c khng qu 8,8 g CO2. Mt khc, cho 0,1 mol X tc dng ht vi dung dch NaHCO3 thy thot ra 4,48 lt (ktc) kh. Tn gi ca X l A. Axit oxalic B. Axit axetic C. Axit fomic D. Axit acrylic 178. Trn 6 g axit axetic vi 17,6 g mt axit hu c X cng dy ng ng ca axit axetic thu c hn hp Y. Hn hp Y phn ng va vi 200 ml dung dch NaOH 1,5M. C.T.P.T ca X l A. HCOOH B. C2H5COOH C. C3H7COOH D. C4H9COOH 179. Cho m gam hn hp X gm mt axit no n chc mch h v mt axit n chc mch h cha 1 lin kt i trong phn t, tc dng ht vi dung dch NaHCO3 th thu c 3,36 lt (ktc) CO2. Mt khc, khi t chy hon ton m gam X th thu c 15,4 g CO2 v 5,4 g nc. C.T.P.T ca hai axit ln lt l A. HCOOH v CH2=CHCOOH B. CH3COOH v CH2=CHCOOH C. CH3COOH v CH2=CHCH2COOH D. HCOOH v CH2=CHCH2COOH 180. Trung ha dung dch cha 6,45 g mt axit cacboxylic n chc X bng mt lng va dung dch NaOH. C cn dung dch sau phn ng thu c 8,1 g mui khan. Tn gi ca axit ny l A. Axit axetic B. Axit acrylic C. Axit fomic D. Axit propionic 181. t chy hon ton hn hp gm hai axit hu c no n chc mch h k tip nhau trong dy ng ng cn dng va 6,72 lt (ktc) oxi, thu c 17,6 g CO2. C.T.P.T ca hai axit ny l A. CH2O2 v C2H4O2 B. C2H4O2 v C3H6O2

C. C3H6O2 v C4H8O2 D. C4H8O2 v C5H10O2 182. Hn hp X gm ancol etylic v axit axetic. Cho m gam X tc dng ht vi Na to ra 1,68 lt (ktc) H2. Mt khc, cho m gam X tc dng ht vi dd NaHCO3 thu c 1,12 lt (ktc) CO2 thot ra. Gi tr ca m l A. 6 B. 8,3 C. 4,15 D. 7,6 183. Mt hn hp gm axit axetic v ancol etylic. Cho m gam X tc dng ht vi Na thu c 3,36 lt (ktc) H2. Cho m gam X tc dng vi dung dch NaHCO3 d, thu c 2,24 lt (ktc) CO2. Nu un nng m gam X vi H2SO4 c th khi lng este thu c l (bit hiu sut phn ng este ha l 66,67%) A. 5,87 g B. 8,8 g C. 11,73 g D. 17,6 g 184. Este ha hn hp gm 9 g axit axetic vi 10,6 g hn hp gm ancol etylic v ancol propylic (c t l mol 1:1) vi hiu sut cc phn ng u t 66,67%. Kt thc phn ng thu c este c khi lng l A. 14,25 g B. 9,5 g C. 19 g D. 12,67 g 185. Cho mt hn hp gm axit acrylic v axit propionic tc dng vi Na d th thu c 2,24 lt (ktc) H2. Tng khi lng axit thu c sau khi hiro ha hon ton hn hp trn l: A. 11,4 g B. 18,4 g C. 14,8 g D. 22,2 g 186. un 12 g axit axetic vi 13,8 g etanol (c H2SO4 c lm xc tc) n khi phn ng t trng thi cn bng, thu c 11 g este. Hiu sut ca phn ng este ha l: A. 55% B. 50% C. 62,5% D. 75% 187. Cho 10,6 g hn hp gm HCOOH v CH3COOH c t l mol l 1:1. Thc hin phn ng este ho vi 9,4 g ancol etylic thu c m g hn hp este. Hiu sut ca c hai phn ng l 80%. Gi tr ca m l: A. 11,41 g B. 13,45 g C. 14,8 g D. 12,96 g 188. Cho 6,6 g axit axetic phn ng vi 4,04 g hn hp gm ancol metylic v ancol etylic c t l mol tng ng l2:3, c H2SO4 c lm xc tc, thu c a gam hn hp este. Hiu sut cc phn ng u t 60%. Gi tr ca a l: A. 4,944 g B. 5,103 g C. 4,44 g D. 8,8 g 189. Cho 7,4 g mt ancol no n chc mch h X tc dng vi axit axetic (ly d), thu c 11,6 g este (hiu sut phn ng 100%). C.T.P.T ca X l: A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH 190. Cho dung dch cha 2 mol axit axetic v dung dch cha 3 mol ancol etylic vo bnh cu 1 lt c xc tc axit H2SO4 c, cho phn ng sau xy ra: CH3COOH + C2H5OH D CH3COOC2H5 + H2O Khi phn ng t ti trng thi cn bng trong hn hp c 1,2 mol este. nhit , hng s cn bng K ca phn ng bng: A.2,8 B.3,2 C.1,2 D.1,0 191. Cho 6,9 g mt axit cacboxylic n chc X tc dng vi 100 ml dung dch hn hp gm Ba(OH)2 0,5M v NaOH 1M. Sau khi phn ng xy ra hon ton, c cn dung dch ny thu c 17,38 g cht rn khan. C.T.P.T ca X l A. CH2O2 B. C2H4O2 C. C3H4O2 D. C5H8O2 192. t chy hon ton 0,05 mol mt axit cacboxylic a chc X thu c 0,2 mol CO2 v 0,15 mol nc. C.T.P.T ca X l A. C3H4O4 B. C2H2O4 C. C4H6O4 D. C5H8O4 193. Cho 10 g hn hp X gm HCHO v HCOOH tc dng vi lng d dung dch AgNO3/NH3 thu c 99,36 g Ag. Phn trm theo khi lng ca HCHO trong X l A. 54% B. 69% C. 64,28% D. 46% 194. Oxi ha 0,125 mol mt ancol n chc X bng oxi (xc tc, t0) thu c 5,6 g hn hp cha axit cacboxylic, anehit, ancol d v nc. C.T.P.T ca X l A. CH4O B. C2H6O C. C3H6O D. C3H8O 195. X l hn hp cha hai axit cacboxylic no mch h, phn t ca mi axit cha khng qu hai nhm COOH. t chy hon ton 9,8 g X th thu c 11 g CO2 v 3,6 g nc. X cha A. HCOOH v CH3COOH B. HCOOH v HOOC COOH C. HCOOH v CH2(COOH)2 D. CH3COOH v CH2(COOH)2 196. Cho 0,840 g mt andehit X c cng thc phn t CnH2n - 2O tc dng vi dd Ag2O/NH3 d, thu c 2,592 g bc. Cng thc ca X l

A. B. C. D.

A. C2H3CHO. B. C3H5CHO. C. C4H7CHO. D. C5H9CHO. 197. Trung ho 8,2 g hn hp gm axit focmic v mt axit n chc X cn dd cha 0,15 mol NaOH. Mt khc khi 8,2 g hn hp tc dng vi dd Ag2O/NH3 d sinh ra 21,6 g Ag. Tn gi ca X l A. axit etanoic. B. axit acrylic. C. axit propanoic. D. axit metacrylic. 198. Y l mt anhyt khng no n chc mch h. t chy hon ton 0,025 mol Y cn dng va ht 2,8 lt oxi ktc. Mt khc khi Y cng hp th cn th tch H2 gp hai ln th tch Y phn ng cng iu kin (t0, P). Cng thc phn t ca Y l A. C3H4O. B. C4H6O. C. C4H4O. D. C5H8O. 199. Khi cho 1 mol anehit A tc dng vi dung dch Ag2O trong NH3 d thu c 2 mol Ag. Vy Ag l: A. Anehit fomic B. Anehit n chc C. Anehit 2 chc D. Anehit n chc nhng khng phi l anehit fomic 200. C th tch ring hn hp benzen, phenol v anilin bng cc cht v c v dng c sau: dung dch NaOH, phiu chit dung dch Br2, phiu lc Ch cn dung dch H2SO4 v phiu chit. dung dch NaOH, dung dch HCl, phiu chit. 201. 13,6 gam hp cht hu c X (phn t ch cha C, H, O; nguyn t O trong phn t ch nm trong mt loi nhm chc) phn ng va vi 300 ml dung dch AgNO3 trong NH3 thu c kt ta, trong c 43,2 gam Ag. T khi hi ca X i vi oxi bng 2,125. Cng thc cu to ca X l: A. CH C-CH2CHO B. OHC-CH2-CHO C. CH2=CH-CH2-CHO D. HC C-CHO 202. Cht hu c A cha cc nguyn t C, H, O v c 37,21% O (theo khi lng) trong phn t. A ch c mt loi nhm chc v 1 mol A khi tc dng vi dung dch AgNO3/NH3 (ly d) thu c 4 mol Ag. T A c th iu ch cao su buna. Xc nh cng thc phn t ca A. (chn p n ng) A. HCHO B. HOC - (CH2)2 CHO C. HOC CH(CH3) CHO D. HOC - CHO 203. Cht A c cng thc phn t l C3H6Br2. Trong s cc ng phn ca A ng phn no thu phn trong dung dch NaOH cho sn phm c kh nng trng gng: (chn p n ng) : A. CH3 CHBr CH2 Br B. CH3 CBr2 CH3 C. CH3 CH2 CHBr2 D. Br CH2 CH2 CH2 Br 204. Mt hn hp gm hai anhit A v B k tip nhau trong dy ng ng ca anhit fomic. Cho 1,02 gam hn hp trn phn ng vi Ag2O trong dung dch NH3 thu c 4,32 gam bc kim loi. Vit cng thc cu to ca A v B bit phn ng xy ra hon ton. (chn p n ng) A. HCHO, CH3CHO B. CH3CHO, C2H5CHO C. C2H5CHO, CH3 - CH2 - CH2 CHO D. C2H5CHO, CH3 CH(CH3) - CHO 205. X l hn hp gm 1 ru n chc no v mt anehit n chc no u mch h v cha cng s nguyn t cacbon trong phn t. t chy hon ton 4,02 gam X cn dng 7,68 gam oxi v thu c 7,92 gam CO2. Tm cng thc phn t hai cht trong X. (chn p n ng) A. CH4O, CH2O B. C2H6O, C2H4O C. C3H8O, C3H6O D. C4H10O, C4H8O 206. trung ha hon ton 2,36 g mt axit hu c X cn 80ml dung dch NaOH 0,5 M. X l. A. CH3COOH. B. C2H5COOH. C. C2H3COOH. D. C2H4(COOH)2. 207. Cho 2,2 gam hp cht n chc X cha C, H, O phn ng ht vi dung dch AgNO3/ NH3 d to ra 10,8 gam Ag. Cng thc cu to ca X l: A. HCHO. B. CH2=CHCHO. C. CH3CHO. D. C2H5CHO. 208. Cho bn hp cht sau: (X): CH3CHClCHClCOOH ; (Y): ClCH2CH2CHClCOOH (Z): Cl2CHCH2CH2COOH ; (T): CH3CH2CCl2COOH Hp cht no c tnh axit mnh nht? A. Hp cht (X). B. Hp cht (Y). C. Hp cht (Z). D. Hp cht (T). 209. Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit.

A . HCHO. 210.
Xenluloz

+ 2O H H+ to ,

B. OHC-CHO. Cho s phn ng:

X
m n r u e

C. CH3CHO.
Z
+ Y xt,to

D. CH2=CH-CHO.
T.

m n gi e m

Cng thc ca T l: A. C2H5COOH. B. C2H5COOCH3. C. CH3COOH. D. CH3COOC2H5. 211. t chy hon ton 0,10 mol hn hp hai axit cacboxylic l ng ng k tip thu c 3,360 lt CO2 (ktc) v 2,70 gam H2O. S mol ca mi axit ln lt l: A. 0,050 v 0,050. B. 0,060 v 0,040. C. 0,045 v 0,055. D. 0,040 v 0,060. 212. Chiu gim dn nhit si (t tri qua phi) ca cc cht: CH3CHO, C2H5OH, H2O l: A. H2O, C2H5OH, CH3CHO. B. CH3CHO, H2O, C2H5OH. C. H2O, CH3CHO, C2H5OH. D. CH3CHO, C2H5OH, H2O. Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc 213. Ag2O) trong. dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO. (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16). A. CH3CH2CHO. B. CH2 = CHCHO. C. CH3CHO. D. HCHO. 214. X l hp cht hu c trong phn t ch cha C, H, O. X tham gia phn ng trng gng v cng tham gia phn ng vi dung dch NaOH. t chy hon ton 0,1 mol X thu c 0,3 mol gm CO2 v H2O. X l. A. HCOOCH3. B. H- CO - CH2 - COOH. C. H - CO - COOH. D. HCOOH. 215. Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16). A. 16,20. B. 6,48. C. 8,10. D. 10,12. 216. Trong cc hp cht di y, hp cht no sau y c tnh axit mnh nht? A. CH3COOH. B. CF3COOH. C. CCl3COOH. D. CBr3COOH. 217. Cho 4 hp cht sau: CH3COOH, CF3COOH, CCl3COOH, CBr3COOH. Hp cht c tnh axit mnh nht l: A. CF3COOH. B. CBr3COOH. C. CH3COOH. D. CCl3COOH. 218. Axit acrylic (CH2=CHCOOH) khng tham gia phn ng vi. A. NaNO3. B. H2/xt. C. dung dch Br2. D. Na2CO3. 219. Anehit X c t khi hi so vi H2 bng 36. S ng phn cu to c th c ca X l: A. 2. B. 1.C. 3. D. 4. 220. S cht c phn ng vi dung dch AgNO3/NH3 l: A. 4. B. 2.C. 1. D. 3. 221. A, B l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp gm 4,60 gam A v 6,0 gam B tc dng ht vi kim loi Na thu c 2,24 lt H2 (ktc). Cng thc phn t ca A v B ln lt l: A. CH3COOH v C2H5COOH. B. C3H7COOH v C4H9COOH. C. HCOOH v CH3COOH. D. C2H5COOH v C3H7COOH. 222. Cho cc cht sau: C2H5OH, CH3COOH, HCOOH, C6H5OH. Chiu tng dn linh ng ca nguyn t H trong cc nhm chc ca 4 cht l: A. C6H5OH, C2H5OH, CH3COOH, HCOOH. B. C2H5OH, C6H5OH, HCOOH, CH3COOH. C. C6H5OH, C2H5OH, HCOOH, CH3COOH. D. C2H5OH, C6H5OH, CH3COOH, HCOOH. 223. C 3 dung dch: CH3CHO, CH3COOH, HCOOH ng trong 3 l mt nhn. Ho cht c th dng phn bit ba dung dch trn l: A. Qu tm, CuO. B. qu tm, Na. C. Qu tm, dung dch AgNO3/NH3. D. dung dch AgNO3/NH3, CuO. 224. Cho axit axetic tc dng vi ancol etylic d (H2SO4 c, to), kt thc th nghim thu c 0,3 mol etyl axetat vi hiu sut phn ng l 60%. Vy s mol axit axetic cn dng l: A. 0,5 mol. B. 0,18 mol. C. 0,05 mol. D. 0,3 mol.

225. Cho 4,52 gam hn hp X gm C2H5OH, C6H5OH, CH3COOH tc dng va vi Na thy thot ra 896 ml kh ( ktc) v m gam hn hp rn. Gi tr ca m l: A. 5,44 gam. B. 6,36 gam. C. 5,40 gam. D. 6,28 gam. 226. Chia a gam CH3COOH thnh hai phn bng nhau. Phn 1: trung ha va bi 0,5 lt dung dch NaOH 0,4M. Phn 2: thc hin phn ng este ha vi C2H5OH thu c m gam este (gi s hiu sut phn ng l 100%). Gi tr ca m l: A. 8,8 gam. B. 35,2 gam. C. 21,2 gam. D. 17,6 gam. 227. t chy mt hn hp cc ng ng ca anehit ta thu c s mol CO2 = s mol H2O th l dy ng ng: A. Anehit hai chc no. B. Anehit n chc no. C. anehit khng no, n chc. D. Anehit vng no. 228. t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit. A. no, n chc. B. no, hai chc. C. khng no c mt ni i, n chc. D. khng no c hai ni i, n chc. 229. Cho s phn ng sau: H2 d O2 Cu 0 O,t X Ni,tY ,xt a is b tiric 0 Z xit o u . Bit X, Y, Z l cc hp cht hu c khc nhau v X cha no. Cng thc cu to ca X l cht no sau y? A. (CH3)2C=CHCHO. B. CH3-H(CH3)CH2OH. C. (CH3)3CCHO. D. CH2=C(CH3)CHO. 230. un nng 18 gam CH3COOH vi 9,2 gam C2H5OH c mt H2SO4 c. Kt thc th nghim thu c 10,56 gam este. Hiu sut phn ng este ho bng. A. 30%. B. 40%. C. 60%. D. 80%. 231. Cho cc cht sau: CH3COOH, C2H5COOH, CH3COOCH3, CH3CH2CH2OH. Chiu tng dn nhit si (t tri qua phi) ca cc cht trn l: A. CH3CH2CH2OH, CH3COOH, CH3COOCH3, C2H5COOH. B. CH3COOCH3, CH3CH2CH2OH, CH3COOH, C2H5COOH. C. CH3CH2CH2OH, CH3COOH, CH3COOCH3, C2H5COOH. D. CH3COOH, CH3COOCH3, CH3CH2CH2OH, C2H5COOH. 232. Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l. A. C3H7COOH. B. CH3COOH. C. C2H5COOH. D. HCOOH. 233. C bao nhiu ng phn cu to ca xeton c cng thc phn t C5H10O? A. 2. B. 3.C. 5. D. 4. 234. Cho cc cht sau: CH3COOH, HCOOH, C6H5OH, CH2=CHCOOH, CH3CHO, CH3COCH3. Dy gm cc cht khng phn ng vi dung dch Br2 l: A. CH3COOH, HCOOH, CH3COCH3. B. CH3COOH, CH3COCH3. C. C6H5OH, CH2=CHCOOH, CH3CHO. D. CH3COOH, CH3COCH3, CH3CHO. 235. Mt hn hp X gm hai anehit A, B n chc. Cho 0,25 mol hn hp X tc dng vi dung dch AgNO3/NH3 d to ra 86,40 gam kt ta. Bit MA < MB. A ng vi cng thc phn t no di y? A. C2H3CHO. B. HCHO. C. CH3CHO. D. C2H5CHO. 236. Cho cc dung dch thuc th: AgNO3/NH3; Br2; Na2CO3; qu tm, KMnO4. S thuc th c th dng phn bit 3 cht: etanal (anehit axetic), propan2on (axeton) v pent1in (pentin1) l: A. 1. B. 4.C. 3. D. 2. 237. phn ng este ho c hiu sut cao hn (to ra nhiu este hn), ta c th dng nhng bin php no trong s cc bin php sau. 1) tng nhit 2) dng H+ xc tc 3) tng nng axit (hay ancol). 4) chng ct dn este ra khi mi trng phn ng. A. 2,3. B. 3,4. C. 3. D. 1,2. 238. C bao nhiu ng phn anehit c cng thc phn t C5H10O? A. 3. B. 6. C. 5. D. 4.

Cho 4 axit: CH3COOH (X), Cl2CHCOOH (Y) ClCH2COOH (Z), BrCH2COOH (T) Chiu tng dn tnh axit ca cc axit cho l: A. Y, Z, T, X. B. T, Z, Y, X. C. X, T, Z, Y. D. X, Z, T, Y. 240. trung ha 6,72 gam axit cacboxylic no, n chc Y, cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l: A. CH3COOH. B. C2H5COOH. C. C3H7COOH. D. HCOOH. 241. Cht X c cng thc phn t C4H8O2 tc dng vi NaOH to thnh cht Y c cng thc phn t A. Axit. B. Phenol. C. Ancol. D. Este. 242. Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z) v imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l: A. T, Z, Y, X. B. T, X, Y, Z. C. Z, T, Y, X. D. Y, T, X, Z. 243. Brom phn ng vi axit butiric (X) sinh ra CH3CHBrCH2COOH (Y) hoc CH3CH2CHBrCOOH (Z) hoc BrCH2CH2CH2COOH (T) ty theo iu kin phn ng. Chiu tng dn tnh axit (t tri qua phi) ca cc axit trn l: A. T, Z, Y, X. B. X, Y, Z, T. C. Y, Z, T, X. D. X, T, Y, Z. 244. Hp cht hu c X (CxHyOz) c phn t khi nh hn 90 g/mol. X tham gia phn ng trng gng v c th tc dng vi H2/Ni, t0, sinh ra mt ancol c cacbon bc bn trong phn t. Cng thc ca X l: A. (CH3)3CCH2CHO. B. (CH3)2CHCHO. C. (CH3)3CCHO. D. (CH3)2CHCH2CHO. 245. Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht c phn ng vi C2H5CHO l: A. 1. B. 2.C. 3. D. 4. 246. Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108). A. CH3CH(OH)CHO. B. OHC-CHO. C. CH3CHO. D. HCHO. 247. Trong cng nghip anehit fomic c iu ch trc tip t cht no di y? A. Cacbon. B. Metyl axetat. C. Metanol. D. Etanol. 248. Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l: A. 3,0 gam. B. 6,0 gam. C. 4,6 gam. D. 7,4 gam. 249. Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 trong dung dch NH3, un nng. Ton b lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l: A. HCHO. B. CH3CH2CHO. C. CH3CHO. D. CH2 = CHCHO. t chy hon ton 1,46 gam mt axit hu c nhiu ln axit ngi ta thu c 1,344 250. lt kh CO2 (o ktc) v 0,9 gam nc. Cng thc nguyn n gin ca axit l: A. (C2H4O2)n. B. (C2H3O2)n. C. (C3H5O2)n. D. (C4H7O2)n. 251. Phn 1: Cho phn ng hon ton vi dung dch AgNO3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l: A. CH3COOH, C2H5COOH. B. CH3COOH, C3H7COOH. C. HCOOH, C3H7COOH. D. HCOOH, C2H5COOH. 252. phn bit axit fomic v axetic c th dng. A. Cu(OH)2 iu kin thng. B. CaCO3. C. AgNO3 trong dung dch NH3. D. Dung dch NH3. 253. Hp cht hu c A cha cc nguyn t C, H, O, trong cacbon chim 50% khi lng. Trong A ch c mt loi nhm chc, khi cho 1 mol A tc dng vi dung dch AgNO3/NH3 d ta thu c 4 mol Ag. Cng thc cu to ca A l: A. OHC-(CH2)2-CHO. B. (CHO)2. C. OHC-CH2-CHO. D. HCHO. 254. Hp cht.

239.

c tn gi l: O A. imetyl xeton. B. Vinyletyl xeton. C. Etylvinyl xeton. D. Penten-3-ol. 255. S bin i tnh cht axit ca dy CH3COOH, CH2ClCOOH, CHCl2COOH l: A. gim. B. tng. C. khng thay i. D. va gim va tng. 256. Cht hu c X n chc trong phn t c cha C,H,O. t chy 1 mol X to ra khng qu. 1 mol CO2. Bit X c phn ng vi Na, NaOH, Na2CO3 v X c phn ng trng gng. X l. A. anehit axetic. B. axit axetic. C. anehit fomic. D. axit fomic. 257. Cng thc chung ca axit cacboxylic no, n chc, mch h l: A. CnH2n+2O2. B. CnH2n+1O2. C. CnH2nO2. D. CnH2n1O2. 258. Xt phn ng: CH3COOH + C2H5OH CH3COOC2H5 + H2O. Trong cc cht trn, cht c nhit si thp nht l: A. C2H5OH. B. CH3COOC2H5. C. H2O. D. CH3COOH. 259. Anehit c th tham gia phn ng trng gng v phn ng vi H2 (Ni, t0). Qua hai phn ng ny chng t anehit. A. khng th hin tnh kh v tnh oxi ho. B. ch th hin tnh oxi ho. C. ch th hin tnh kh. D. th hin c tnh kh v tnh oxi ho. 260. Cho cc axit sau: (CH3)2CHCOOH, CH3COOH, HCOOH, (CH3)3CCOOH. Chiu gim dn tnh axit (tnh t tri qua phi) ca cc axit cho l: A. HCOOH, CH3COOH, (CH3)2CHCOOH, (CH3)3CCOOH. B. (CH3)3CCOOH, (CH3)2CHCOOH, CH3COOH, HCOOH. C. HCOOH, (CH3)3CCOOH, (CH3)2CHCOOH, CH3COOH. D. HCOOH, CH3COOH, (CH3)2CHCOOH, (CH3)3CCOOH. 261. Cho 3 axit: axit pentanoic CH3[CH2]2CH2COOH (1) axit hexanoic CH3[CH2]3CH2COOH (2) axit heptanoic CH3[CH2]4CH2COOH (3) Chiu gim dn tan trong nc (t tri qua phi) ca 3 axit cho l: A. (2), (1), (3). B. (3), (2), (1). C. (1), (2), (3). D. (1), (3), (2). 262. Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht c phn ng vi (CH3)2CO l: A. 4. B. 2.C. 3. D. 1. 263. Trong dy chuyn ho: +H2O +H 2 +O2 +Y C2H2 X Y Z T. Cc cht X, Y, Z, T ln lt l: A. C2H5OH, CH3CHO, CH3COOH, CH3COOC2H5. B. HCOOH, C2H5OH, CH3COOH, HCOOC2H5. C. CH3CHO, C2H5OH, CH3COOH, CH3COOC2H5. D. C2H5CHO, C2H5OH, C2H5COOH, C2H5COOCH3. 264. C3H6O c bao nhiu ng phn mch h, bn c kh nng lm mt mu dung dch Br2? A. 1. B. 4.C. 3. D. 2. 265. Cho 14,80 gam hn hp 2 axit hu c no, n chc tc dng vi lng va Na2CO3 to thnh 2,24 lt CO2 (ktc). Khi lng mui thu c l: A. 16,20 gam. B. 17,10 gam. C. 19,40 gam. D. 19,20 gam. 266. t chy hon ton 1,760 gam mt axit hu c X mnh thng c 1,792 lt kh CO2 (ktc) v 1,440 gam H2O. Cng thc cu to ca X l: A. HOOCCH2COOH. B. CH3CH2CH2COOH. C. CH3CH=CHCOOH. D. C2H5COOH. 267. Xt cc yu t sau y: nhit (1); xc tc(2); nng ca cc cht tc dng(3); bn cht ca cc cht tc dng(4). Yu t no nh hng n tc ca phn ng este ha. A. (1), (3), (4). B. (1), (2), (3). C. (1), (2), (3), (4). D. (1), (2), (4). 268. Axit X mch h, khng phn nhnh c cng thc thc nghim (C3H5O2)n. Cng thc cu to thu gn ca X l: A. C2H4COOH. B. HOOCCH2CH(CH3)CH2COOH. C. HOOC[CH2]4COOH. D. CH3CH2CH(COOH)CH2COOH.

CH2 CH

C CH 2 CH3

269. Cho 10 gam hn hp X gm axit acrylic v axit propionic tc dng va vi 50 gam dung dch Br2 3,2%. Thnh phn % khi lng axit propionic c trong X l: A. 72%. B. 28 %. C. 74%. D. 26%. 270. Dng thuc th no di y phn bit axit fomic v axit acrylic? A. dung dch Br2. B. Dung dch Na2CO3. C. Dung dch AgNO3/NH3. D. Qu tm m. 271. sn xut gim n ngi ta dng phng php no trong cc phng php sau? A. 2CH3 CHO + O2 B. CH3COOCH3 + H 2O C. C 2H2 + H2O D. C2 H5 OH + O2
xt, t0

2CH3 COOH .
CH3COOH + CH 3OH .
[O] xt

H2SO 4 n , un ng

CH 3CHO
enzim

CH3COOH .

CH3 COOH + H 2O .

272. Cho 10 gam fomalin tc dng vi dung dch AgNO3/NH3 d, sau phn ng thu c 54 gam kt ta (coi nng ca axit fomic trong fomalin l khng ng k). Nng % ca anehit fomic l: A. 37,5%. B. 37%. C. 39,5%. D. 75%. 273. Nhit si ca cc axit cacboxylic cao hn ca anehit, xeton, ancol c cng s nguyn t C l do. A. cc axit cacboxylic u l cht lng hoc cht rn. B. axit cacboxylic cha nhm C=O v nhm OH. C. s phn cc nhm cacboxyl v s to thnh lin kt hiro lin phn t cc phn t axit. D. phn t khi ca axit ln hn v nguyn t H ca nhm axit linh ng hn. 274. Ch dng mt ha cht no di y phn bit hai bnh mt nhn cha kh C2H2 v HCHO? A. Dung dch Br2. B. Cu(OH)2. C. Dung dch NaOH. D. Dung dch AgNO3/NH3. 275. X v Y l hai axit hu c no, n chc, mch h, k tip nhau trong cng dy ng ng. Cho hn hp gm 2,30 gam X v 3,0 gam Y tc dng ht vi K d thu c 1,12 lt H2 ( ktc). Cng thc ca hai axit l: A. CH3COOH v C2H5COOH. B. C2H5COOH v C3H7COOH. . C. C3H7COOH v C4H9COOH. D. HCOOH v CH3COOH. 276. Cho hn hp gm 0,10 mol HCOOH v 0,20 mol HCHO tc dng ht vi dung dch AgNO3/NH3 d th khi lng Ag thu c l: A. 216,0 gam. B. 10,80 gam. C. 64,80 gam. D. 108,0 gam. 277. iu ch anehit t ancol bng mt phn ng, ngi ta dng. A. ancol bc 2. B. ancol bc 1. C. ancol bc 1 v ancol bc 2. D. ancol bc 3. 278. 10,6 gam hn hp hai axit n chc phn ng va vi 200 ml NaOH 1M. Khi lng. hn hp mui natri thu c sau phn ng l. A. 21,2 gam. B. 15 gam. C. 20 gam. D. 5,3gam. 279. Cho s phn ng: Cl 2 ,as vi ti xt dd NaOH, t 0 CuO, t 0 CH 3COONa X Y Z T . 1:1 t0 X, Y, Z, T l cc hp cht hu c, cng thc ca T l: A. HCHO. B. CH3OH. C. CH2O2. D. CH3CHO. 280. Bin php no di y khng p dng lm tng hi sut qu trnh tng hp CH3COOC2H5 t axit v ancol tng ng? A. Dng H2SO4 c hp th nc. B. Tng p sut chung ca h. C. Dng d axit hoc ancol. D. Chng ct ui este. 281. t chy hon ton 0,10 mol hn hp hai axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,70 gam H2O. Cng thc phn t ca chng l: A. CH3COOH v C2H5COOH. B. C2H3COOH v C3H5COOH. C. C2H5COOH v C3H7COOH. D. HCOOH v CH3COOH. 282. t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y.

cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l. A. HOOC-COOH. B. HOOC-CH2-CH2-COOH. C. CH3-COOH. D. C2H5-COOH. 283. phn ng este ho mau t ti trng thi cn bng, ta c th dng nhng bin php no trong s cc bin php sau. 2) Dng H+ xc tc. 1) Tng nhit . 3) Tng nng axit (hay ancol). 4) Chng ct dn este ra khi mi trng phn ng. A. 1,2. B. 3,4. C. 2,3. D. 3. 284. Cho 19,2 gam hn hp X gm fomaehit v axetanehit phn ng hon ton vi lng d Cu(OH)2 trong NaOH un nng. Kt thc th nghim thu c 100,8 gam kt ta. Thnh phn % s mol fomaehit c trong X l: A. 33,33%. B. 66,67%. C. 50,0%. D. 75,0%. 285. Cho s phn ng sau:
Toluen
+ Cl2 , as 1:1

+NaOH, to

+CuO, to

+ dd AgNO3 /NH3

T.

Bit X, Y, Z, T l cc hp cht hu c v l nhng sn phm chnh. Cng thc cu to ng ca T l cht no sau y? A. p-HOOC-C6H4-COONH4. B. C6H5-COOH. C. CH3-C6H4-COONH4. D. C6H5-COONH4. un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn 286. ng t ti. trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l. A. 55%. B. 75%. C. 62,5%. D. 50%. 287. Cho 2,9 gam anehit X c t khi hi so vi H2 bng 29,0 tc dng vi dung dch AgNO3/NH3 d thu c 21,6 gam Ag. Cng thc cu to thu gn ca X l: A. CH2=CHCHO. B. CH3CHO. C. (CHO)2. D. CH3CH2CHO. 288. Cho cc thuc th sau: Na; K; AgNO3/NH3; Cu(OH)2/OH -. S thuc th c th dng phn bit 2 bnh ring bit, mt nhn ng ancol etylic 45o v dung dch fomalin l: A. 1. B. 3.C. 2. D. 4. 289. T khi hi ca anhit X so vi H2 bng 29. Bit 2,9 gam X tc dng vi dung dch. AgNO3/NH3 d thu c 10,8 gam Ag. Cng thc cu to ca X l: A. CH3 - CH2 - CHO. B. CH2 = CH - CHO. C. CH2 = CHCH2CHO. D. OHC - CHO. 290. Cho 0,1 mol anehit X tc dng vi lng d AgNO3 trong dd NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l: A. CH3CHO. B. HCHO. C. OHC-CH2-CHO. D. (CHO)2. 291. Axit no di y c phn ng vi Cu(OH)2/OH - khi un nng cho kt ta gch? A. Axit fomic. B. Axit stearic. C. Axit acrylic. D. Axit oxalic. 292. t chy hon ton 6,0 gam axit cacboxylic X ri dn ton b sn phm chy ln lt qua bnh (1) ng axit H2SO4 c, d v bnh (2) ng dung dch NaOH c, d. Kt thc th nghim, bnh (1) tng 3,6 gam; bnh (2) tng 8,8 gam. Cng thc cu to ca X l: A. HOOCCOOH. B. CH3COOH. C. HCOOH. D. CH2=CHCOOH. 293. trung ho 8,8 gam mt axit cacboxylic c mch cacbon khng phn nhnh thuc dy ng ng ca axit axetic cn 100,0 ml dung dch NaOH 1,0M. Cng thc cu to c th c ca axit cacboxylic l: A. CH3CH2CH2COOH. B. CH3CH(CH3)COOH. C. CH3CH2CH2CH2COOH. D. CH3 CH2COOH. 294. iu ch axit trc tip t anehit ta c th dng cht oxi ha no sau y? A. Cu(OH)2/OH-, to. B. O2 (Mn2+, to). C. Dung dch AgNO3/NH3. D. Dung dch AgNO3/NH3 hoc Cu(OH)2/OH-, to. 295. Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. 296. Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3, l: A. axit fomic, vinylaxetilen, propin. B. anehit fomic, axetilen, etilen. C. anehit axetic, butin-1, etilen. D. anehit axetic, axetilen, butin-2.

297. Chia hn hp X gm hai anehit no, n chc, mch h thnh hai phn bng nhau: Phn 1: em t chy hon ton thu c 5,4 gam H2O. Phn 2: Cho tc dng ht vi H2 d (Ni, to) thu c hn hp Y. t chy hon ton hn hp Y, thu c V lt CO2 (ktc). V c gi tr no di y? A. 1,12 lt. B. 3,36 lt. C. 4,48 lt. D. 6,72 lt. 298. Khi t chy hon ton anehit no, n chc, mch h th t l s mol sn phm chy thu c l: n H2 O n H2O n H2O n H2O 1 =1 . >1 . <1 . A. n B. n C. n D. n = 2 . CO2 CO2 CO2 CO 2 299. X l hp cht hu c (cha C, H, O) trong hiro chim 2,439% v khi lng. t chy hon ton X thu c s mol nc bng s mol X, mt khc bit 1 mol X phn ng va vi 4 mol AgNO3 trong dung dch amoniac. Cng thc cu to c th c ca X l: A. HC CHO. CB. HCHO. C. CH3CHO. D. OHC-CC-CHO. 300. Hn hp X gm hai axit hu c no. t chy 0,3 mol hn hp X thu c 11,2 lt CO2 (ktc). Nu trung ha 0,3 mol hn hp X th cn 500ml dung dch NaOH 1M. Cng thc cu to ca hai axit l: A. CH3COOH v C2H5COOH. B. HCOOH v HOOC - COOH. C. CH3COOH v C3H7COOH. D. CH3COOH v HOOC - COOH. 301. Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l. A. C9H12O9. B. C3H4O3. C. C12H16O12. D. C6H8O6. 302. trung ho 3,6 gam mt axit n chc (X) cn 100ml dung dch NaOH 0,5M. Tn gi ca X l: A. axit fomic. B. axit metacylic. C. Axit crylic. D. axit axetic. 303. C4H8O2 c bao nhiu ng phn axit? A. 3 ng phn. B. 1 ng phn. C. 4 ng phn. D. 2 ng phn. 304. Cho hn hp HCHO v H2 d i qua ng ng bt Ni un nng thu c hn hp X. Dn ton b sn phm thu c vo bnh nc lnh thy khi lng bnh tng 11,80 gam. Ly ton b dung dch trong bnh cho tc dng vi dung dch AgNO3/NH3 d thu c 21,60 gam Ag. Khi lng ancol c trong X l gi tr no di y? A. 1,03 gam. B. 8,30 gam. C. 9,30 gam. D. 10,30 gam. 305. Hp cht C4H6O3 c th tc dng vi natri gii phng H2, tc dng vi NaOH v c phn. ng trng gng. Cng thc cu to hp l ca C4H6O3 c th l. A. CH3- CO - CH2 - COOH. B. CH2OH- COO- CH = CH2. C. HCO - O - CH2- CH2 - CHO. D. OHC - CH2 - CH2 - COOH. 306. t chy hon ton hn hp hai axit cacboxylic thu c 3,36 lt CO2 (ktc) v 2,70 gam H2O. Hai axit trn thuc loi no trong nhng loi sau? A. No, n chc, mch h. B. No, a chc. C. Thm, n chc. D. Khng no, n chc. 307. Cho 4 cht: C6H5OH, CH3COOH, H2CO3, HCOOH. Cht c tnh axit yu nht l: A. H2CO3. B. CH3COOH. C. HCOOH. D. C6H5OH. 308. Mt hn hp gm hai anehit X v Y k tip nhau trong dy ng ng ca anehit no n chc, mch h (khc HCHO). Cho 1,02 gam hn hp trn phn ng vi dung dch AgNO3/NH3 d thu c 4,32 gam Ag kim loi (hiu sut phn ng 100%). Cng thc cu to ca X v Y ln lt l: A. HCHO, C2H5CHO. B. C3H7CHO, C4H9CHO. C. CH3CHO, C2H5CHO. D. CH3CHO, HCHO. 309. S lin kt trong cng thc cu to ca axit cacboxylic khng no, n chc, mch h c mt ni i l: A. 0. B. 3.C. 2. D. 1. 310. Cho cc cht sau: CH3CH2CHO, CH2=CHCHO, CH3COCH3, CH2=CHCH2OH. Nhng cht no tc dng hon ton vi H2 d (Ni, to) cho cng mt sn phm? A. CH3CH2CHO, CH2=CH-CHO, CH3-CO-CH3, CH2=CH-CH2OH. B. CH2=CH-CHO, CH3-CO-CH3, CH2=CH-CH2OH.

C. CH3CH2CHO, CH2=CH-CHO, CH2=CH-CH2OH. D. CH3CH2CHO, CH2=CH-CHO, CH3-CO-CH3. 311. Trong cng nghip, axeton c iu ch t. A. xiclopropan. B. propan-2-ol. C. cumen. D. propan-1-ol. 312. t chy hon ton 0,1 mol axit cacbonxylic n chc cn dng va V lt O2 (ktc) thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l: A. 4,48. B. 5,60. C. 8,96. D. 6,72. 313. . t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO2. Mt khc hiro ho hon ton m gam X cn va 0,2 mol H2 (Ni, to), sau phn ng thu c hn hp hai ancol. t chy hon ton hn hp hai ancol ny th s mol H2O thu c l bao nhiu? A. 0,8 mol. B. 0,6 mol. C. 0,3 mol. D. 0,4 mol. 314. Oxi ho 2,2 gam mt anehit n chc X thu c 3,0 gam axit tng ng (hiu sut phn ng bng 100%). X c cng thc cu to no di y? A. CH3CHO. B. CH3CH2CH2CHO. C. CH3CH(CH3)CHO. D. C2H5CHO. 315. Axit fomic HCOOH c th tham gia phn ng vi dung dch AgNO3/NH3 d v phn ng kh Cu(OH)2 trong mi trng baz thnh kt ta mu gch (Cu2O) v. A. axit fomic l axit rt mnh nn c kh nng phn ng c vi cc cht trn. B. y l nhng tnh cht ca mt axit c tnh oxi ha. C. axit fomic th hin tnh cht ca mt axit phn ng vi mt baz l AgOH v Cu(OH)2. D. trong phn t axit fomic c nhm chc anehit. 316. t chy hon ton a mol axit hu c Y c 3a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to ca Y l: A. HOOC -CH2 -COOH. B. CH3 -COOH. C. HOOC -COOH. D. CH3 -CH2 -COOH. Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 317. 7,28 gam. mui ca axit hu c. Cng thc cu to thu gn ca X l. A. CH2=CH-COOH. B. HCC-COOH. C. CH3-CH2-COOH. D. CH3COOH.