Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

BI TP CHNG AMIN
Cu 1 (C-08). Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Cu 2. Nguyn nhn gy nn tnh baz ca C2H5NH2 l do A. C2H5NH2 to lin kt hiro vi nc nn tan nhiu trong nc. B. gc C2H5- y electron v pha N nn phn t C2H5NH2 phn cc. C. m in ca N ln hn H nn cp electron gia N v H b lch v pha N. D. nguyn t N cn c cp electron t do nn c kh nng nhn proton. Cu 3. S lng ng phn ng vi cng thc phn t C4H11N l A. 5. B. 6. C. 7. D. 8. Cu 4 (B-08). Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3NH2. B. CH3COOCH3. C. CH3OH. D. CH3COOH. Cu 5. Cho cc cht sau: C6H5NH2 (X), (CH3)2NH (Y), CH3NH2 (Z), C2H5NH2 (T). Th t tng dn tnh baz ca cc cht ni trn l A. Y < Z < X < T. B. X < Z < T < Y. C. T < Y < Z < X. D. T < X < Y < Z. Cu 6. Cho cc cht sau: NH3 (X) ; (C6H5)2NH (Y); C6H5NH2 (Z); CH3NH2 (T); C6H5NHCH3 (M). Th t gim dn tnh baz ca cc cht trn l A. T > X > M > Z > Y. B. T > X > Z > M > Y. C. M > X > Y > Z > T. D. X > M > T > Y > Z. Cu 7 (B-2011). Ancol v amin no sau y cng bc? A. (CH3)3COH v (CH3)3CNH2. B. (C6H5)2NH v C6H5CH2OH. C. (CH3)2CHOH v (CH3)2CHNH2. D. C6H5NHCH3 v C6H5CH(OH)CH3. Cu 8 (B-2011). Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (2), (1), (3). B. (3), (1), (2). C. (1), (2), (3). D. (2), (3), (1). Cu 9 (A - 2010). Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l A. C3H9N. B. C3H7Cl. C. C3H8O. D. C3H8. Cu 10 (C - 2010). Dung dch no sau y lm qu tm chuyn mu xanh? A. Phenylamoni clorua. B. Anilin. C. Glyxin. D. Etylamin. Cu 11 (C - 2010). S amin thm bc mt ng vi cng thc phn t C7H9N l A. 3. B. 2. C. 5. D. 4. Cu 12. t chy hon ton hn hp 2 amin n chc no bc 1. Trong sn phm chy thy t l mol CO2 v H2O tng ng l 1: 2. Cng thc ca 2 amin l A. C3H7NH2 v C4H9NH2. B. C2H5NH2 v C3H7NH2. C. CH3NH2 v C2H5NH2. D. C4H9NH2 v C5H11NH2. Cu 13. A l hp cht hu c cha C, H, N; trong nit chim 15,054% v khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cng thc ca A l A. CH3-C6H4-NH2. B. C6H5-NH2. C. C6H5-CH2-NH2. D. C2H5-C6H4-NH2. Cu 14. S lng ng phn amin cha vng bezen ng vi cng thc phn t C7H9N l A. 3. B. 4. C. 5. D. 6. Cu 15. Mt amin n chc cha 19,718% nit v khi lng. CTPT ca amin l A. C4H5N. B. C4H7N. C. C4H9N. D. C4H11N. Cu 16. t chy hon ton mt amin no n chc thu c VH2O = 1,5VCO2 . CTPT ca amin l A. C2H7N. B. C3H9N. C. C4H11N. D. C5H13N.

GV: Nguyn Ph Hot

Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 17. Cho 3,04g hn hp A gm 2 amin no n chc tc dng va vi 400ml dd HCl 0,2M c 5,96g mui. Tm th tch N2 (ktc) sinh ra khi t ht hn hp A trn ? A. 0,224 lt. B. 0,448 lt. C. 0,672 lt. D. 0,896 lt. Cu 18. Cho 17,7g mt ankylamin tc dng vi dd FeCl3 d thu c 10,7g kt ta. CTPT ca ankylamin l A. C2H7N. B. C3H9N. C. C4H11N. D. CH5N. Cu 19. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100ml B. 50ml C. 200ml D. 320ml Cu 20. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Bit phn t khi ca cc amin u < 80. Cng thc phn t ca cc amin l p n A, B, C hay D? A. CH3 NH2; C2H5NH2 v C3H7NH2 B. C2H3 NH2; C3H5NH2 v C4H7NH2 C. C2H5 NH2; C3H7NH2 v C4H9NH2 D. C3H7 NH2; C4H9NH2 v C5H11NH2 Cu 21. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l cng thc no sau y? A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 22. Hp cht hu c to bi cc nguyn t C, H, N l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO2 v c th tc dng vi nc brom to kt ta. Hp cht o c cng thc phn t nh th no? A. C2H7N B. C6H13N C. C6H7N D. C4H12N2 Cu 23. t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 24. Trung ha 3,1 gam mt amin n chc X cn 100ml dung dch HCl 1M. Cng thc phn t ca X l p n no? A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 25. t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t l th tch nCO2: nH2O = 8 : 17. Cng thc ca hai amin l p n no? A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2 C. CH3NH2, C2H5NH2 D. C4H9NH2, C5H11NH2 Cu 26. t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO2 v H2O theo t l mol = 8:9. Vy cng thc phn t ca amin l cng thc no? A. C3H6N B. C4H9N C. C4H8N D. C3H7N Cu 27. Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc. A. Nng mol ca dung dch HCl bng 0,2M. B. S mol ca mi cht l 0,02mol C. Cng thc ca hai amin l CH5N v C2H7N D. Tn gi hai amin l metylamin v etylamin Cu 28. Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on 78%? A. 346,7gam B. 362,7gam C. 463,4gam D. 358,7 gam Cu 29. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05mol H2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1gam B. 14,2gam C. 19,1gam D. 28,4 gam Cu 30. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH3 v C6H5OH ln lt bng bao nhiu? A. 0,01 mol; 0,005mol v 0,02mol B. 0,05 mol; 0,005mol v 0,02mol C. 0,05 mol; 0,002mol v 0,05mol. D. 0,01 mol; 0,005mol v 0,02mol

GV: Nguyn Ph Hot

Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 30. t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng bao nhiu? A. 20%; 20%; 60% B. 25%; 25%; 50% C. 30%; 30%; 40% D. 20%; 60%; 20% Cu 31. t chy ht 6,72 lt hn hp kh (ktc) X gm 2 amin n chc bc mt A v B l ng ng k tip. Cho hn hp kh v hi sau khi t chy ln lt qua bnh 1 ng H 2SO4 c, bnh 2 ng KOH d thy khi lng bnh 2 tng 21,12 gam. Tn gi ca 2 amin l A. metylamin v etylamin. B. etylamin v n-propylamin. C. n-propylamin v n-butylamin. D. iso-propylamin v iso-butylamin. Cu 32. DD X gm HCl v H2SO4 c pH=2. trung ho hon ton 0,58g hn hp 2 amin no n chc bc 1 (c s nguyn t C nh hn hoc bng 4) phi dng 1 lt dd X. Cng thc ca 2 amin c th l A. CH3NH2 v C4H9NH2. B. C2H5NH2 v C4H9NH2. C. C3H7NH2 v C4H9NH2. D. C A v B. Cu 33 (C-08). Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 4. C. 2. D. 3. Cu 34 (B-09). Ngi ta iu ch anilin bng s sau: HNO3 (c) Fe + HCl Nitrobenzen Anilin Benzen H2SO4 (c) t0 Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam. B. 55,8 gam. C. 93,0 gam. D. 111,6 gam. Cu 35. t chy hon ton mt amin n chc, no, bc 2 thu c CO2 v H2O vi t l mol tng ng l 2:3. Tn gi ca amin l A. etyl metylamin. B. ietylamin. C. metyl iso-propylamin. D. imetylamin. Cu 36. t chy hon ton hn hp 2 amin n chc, no, bc 1, l ng ng k tip thu c t l mol CO2 v H2O tng ng l 1:2. Cng thc ca 2 amin l A. C2H5NH2 v C3H7NH2. B. C4H9NH2 v C3H7NH2. C. CH3NH2 v C2H5NH2. D. C4H9NH2 v C5H11NH2. Cu 37 (C - 2007). trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N. Cu 38 (A - 2010). Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. Cu 39. t chy hon ton 100 ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140 ml CO2 v 250 ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 + Cu 40 (B-08). Mui C6 H5 N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-50C). iu ch c 14,05 gam + C6 H5 N2 Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1mol v 0,4mol. B. 0,1mol v 0,2mol. C. 0,1mol v 0,1mol. D. 0,1mol v 0,3mol. Cu 41 (B-2011). Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh o cng iu kin nhit , p sut). T l V1 : V2 l A. 2 : 1. B. 1 : 2. C. 3 : 5. D. 5 : 3.
GV: Nguyn Ph Hot Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 42 (A-2011). Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 3. B. 4. C. 2. D. 1. Cu 43 (A - 2010). t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH3-CH2-CH2-NH2. B. CH2=CH-CH2-NH2. C. CH3-CH2-NH-CH3. D. CH2=CH-NH-CH3. Cu 44 (B - 2010). t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,4. C. 0,3. D. 0,2. Cu 45 (B - 2010). Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2. D. H2NCH2CH2CH2NH2. Cu 46 (C - 2010). Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C3H7NH2 v C4H9NH2. B. CH3NH2 v C2H5NH2. C. CH3NH2 v (CH3)3N. D. C2H5NH2 v C3H7NH2.

BI TP V AMINOAXIT - PEPTIT
Cu 1 (C-2011). Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 3. B. 4. C. 2. D. 5. Cu 2 (B-2011). Pht biu khng ng l: A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit. B. Etylamin tc dng vi axit nitr nhit thng to ra etanol. C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu. D. Metylamin tan trong nc cho dung dch c mi trng baz. Cu 3 (C-2011). Pht biu no sau y ng? A. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit. B. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm. C. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit. D. Amino axit l hp cht c tnh lng tnh. Cu 4 (A-2011). S ng phn amino axit c cng thc phn t C3H7O2N l A. 2. B. 3. C. 4. D. 1. Cu 5 (A-2011). Khi ni v peptit v protein, pht biu no sau y l sai? A. Protein c phn ng mu biure vi Cu(OH)2. B. Tt c cc protein u tan trong nc to thnh dung dch keo. C. Thy phn hon ton protein n gin thu c cc -amino axit. D. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. Cu 6 (B-09). S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 1. C. 2. D. 4. Cu 7. Cho cc loi hp cht sau: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Cc loi cht va tc dng vi dung dch NaOH, va tc dng vi dung dch HCl l A. X, Y, Z, T. B. X, Y, Z. C. X, Y, T. D. Y, Z, T.
GV: Nguyn Ph Hot Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 8. S lng ng phn aminoaxit ng vi cng thc H2N-C3H6-COOH l A. 4. B. 5. C. 6. D. 7. Cu 9. Trong dung dch, H2N-CH2-COOH tn ti dng A. phn t trung ho. B. cation. C. anion. D. ion lng cc. Cu 10 (B-07). Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng vi dung dch NaOH v dung dch HCl l A. Y, Z, T. B. X, Y, T. C. X, Y, Z, T. D. X, Y, Z. Cu 11. X c cha nhm amino v c cng thc phn t l C3H7O2N. Khi cho X phn ng vi dung dch NaOH, thu c mui C2H4O2NNa. Cng thc cu to ca X l A. H2N-CH(CH3)-COOH. B. H2N-CH2-CH2-COOH. C. H2N-CH2-COOCH3. D. CH3-NH-CH2-COOH. Cu 12 (A-09). Pht biu no sau y l ng? A. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. B. Benzen lm mt mu nc brom nhit thng. C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. Cu 13 (A-08). Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3 N- CH 2 - COO- . B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm -NH2 v nhm -COOH. C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). Cu 14 (A-08). C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3. Cu 15 (B-08). un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH(CH3)-COOH. Cu 16 (A - 2010). Pht biu ng l: A. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz. B. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit. C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m. D. Axit nucleic l polieste ca axit photphoric v glucoz. Cu 17 (A - 2010). C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 6. B. 9. C. 4. D. 3. Cu 18 (B - 2010). Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. Cu 19 (C - 2010). ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 4. B. 2. C. 1. D. 3.
GV: Nguyn Ph Hot Nm hc: 2011 - 2012
+

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 20 (C - 2010). Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 1. B. 4. C. 2. D. 3. Cu 21. Khi thy phn tripeptit H2N-CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc aminoaxit A. H2NCH2COOH v CH3CH(NH2)COOH B. H2NCH2CH(CH3)COOH v H2NCH2COOH C. H2NCH(CH3)COOH v H2NCH(NH2)COOH D. CH3CH(NH2)CH2COOH v H2NCH2COOH Cu 22. Thu phn khng hon ton tetra peptit (X), ngoi cc - amino axit cn thu c cc ipetit: Gly-Ala; Phe-Val; Ala-Phe. Cu to ng ca X l A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly. C. Gly-Ala-Val-Phe D. Gly-Ala-Phe-Val. Cu 23. Hp cht no sau y thuc loi ipeptit?
A. H2N-CH2CONH-CH2CONH-CH2COOH. C. H2N-CH2CH2CONH-CH2CH2COOH.

Cu 24. S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l A. 2. B. 3. C. 5. D. 4. Cu 25. Peptit c cng thc cu to nh sau: H2 N-C H-CO-NH-CH 2 -CO-NH-C H-COOH
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B. H2N-CH2CONH-CH(CH3)-COOH. D. H2N-CH2CH2CONH-CH2COOH.

CH3 CH(CH3 )2 Tn gi ng ca peptit trn l: A. Ala-Ala-Val. B. Ala-Gly-Val. C. Gly-Ala-Gly. D. Gly-Val-Ala. NaOH HCl Cu 26. Cho dy chuyn ha: Glyxin X Y. HCl NaOH Glyxin Z T. Y v T ln lt l: A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 27. S ng phn tripeptit to thnh t 1 phn t glyxin v 2 phn t alanin l A. 2. B. 3. C. 5. D. 4. Cu 28. Cng thc no sau y ca pentapeptit (A) tha iu kin sau: - Thy phn hon ton 1 mol A th thu c cc - amino axit l: 3 mol Glyxin, 1 mol Alanin, 1 mol Valin. - Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 ipeptit: AlaGly; Gly-Ala v 1 tripeptit Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. B. Gly-Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly. NaOH HCl Cu 29. Cho s bin ha sau: Alanin X Y. Cht Y l cht no sau y: A. CH3-CH(NH2)-COONa. B. H2N-CH2-CH2-COOH. C. CH3-CH(NH3Cl)COOH D.CH3-CH(NH3Cl)COONa. Cu 30 (A-2011). Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch glyxin. B. Dung dch lysin. C. Dung dch alanin. D. Dung dch valin. Cu 31 (A-2011). Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l A. 7,82 gam. B. 16,30 gam. C. 7,09 gam. D. 8,15 gam. Cu 32 (A-07). Cho hn hp X gm 2 cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp kh Z (ktc) gm 2 kh (u lm xanh giy qu m). T khi hi ca Z so vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 8,9 gam. B. 14,3 gam. C. 16,5 gam. D. 15,7 gam.
GV: Nguyn Ph Hot Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 33 (C-08). Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. Cu 34 (C-2011). Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l A. glyxin. B. valin. C. alanin. D. phenylalanin. Cu 35 (C-2011). Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng? A. Trong phn t X c mt lin kt . B. Phn t X c mch cacbon khng phn nhnh. C. Tn thay th ca Y l propan-2-ol. D. Tch nc Y ch thu c mt anken duy nht. Cu 36 (B-2011). Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45. Cu 37 (B-09). Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 38. X l mt - aminoaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 17,8 gam X tc dng vi dung dch HCl d thu c 25,1 gam mui. Tn gi ca X l A. axit amino axetic. B. axit - amino propionic. C. axit - amino butiric. D. axit - amino glutaric. Cu 39. X l -aminoaxit mch thng. Bit rng: 0,01mol X tc dng va vi 80ml dung dch HCl 0,125M thu c 1,835g mui. Mt khc, nu cho 2,94g X tc dng va vi NaOH th thu c 3,82g mui. Tn gi ca X l. A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 40. Cho hn hp 2 aminoaxit no cha 1 chc axit v 1 chc amino tc dng vi 110ml dung dch HCl 2M c dung dch A. tc dng ht vi cc cht trong A cn dng 140ml dung dch KOH 3M. Tng s mol 2 aminoaxit l A. 0,1. B. 0,2. C. 0,3. D. 0.4. Cu 41. X l mt amino axit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dung dch HCl 0,125M v thu c 1,835 g mui khan. Cn khi cho 0,01 mol X tc dng vi dung dch NaOH th cn 25 gam dung dch NaOH 3,2%. Cng thc no sau y l ca X? A. C7H12-(NH)-COOH B. C3H6-(NH)-COOH C. NH2-C3H5-(COOH) D. (NH2)2-C3H5-COOH Cu 42. Cho 13,35 g hn hp X gm H2NCH2CH2COOH v CH3CH(NH2)COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l A. 100 ml B. 150 ml C. 200 ml D. 250 ml Cu 43. Cho 4,41g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73 g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. Xc nh CTCT ca X A. HOOC-CH2CH2CH(NH2)COOH B.CH3CH(NH2)COOH C. HOOCCH2CH(NH2)CH2COOH D. C A v B Cu 44. Cho 0,15 mol H2NC3H5(COOH)2 vo 175ml dung dch HCl 2M thu c dung dch X, X tc dng va vi Vml dung dch NaOH 1M. Tnh V? A. 550 B. 650 C. 300 D. 350
GV: Nguyn Ph Hot Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 45. Mt aminoaxit X ch cha mt chc -NH2 v mt chc -COOH. Cho m gam X tc dng vi 300 ml dung dch HCl 1M thu c dung dch Y. Dung dch Y phn ng va vi 500 ml dung dch NaOH 1M v thu c dung dch Z. C cn dung dch Z thu c 39,75 gam mui khan. Aminoaxit X l A. NH2C2H4COOH. B. NH2C4H8COOH. C. NH2C3H6COOH. D. NH2CH2COOH. Cu 46. X c cng thc H2NR(COOH)n. Cho 50 ml dung dch X tc dng va vi 80 ml dung dch HCI 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt khc nu trung ha 250 ml dung dch X bng dung dch KOH ri em c cn th thu c 35 gam mui. Gc R v gi tr ca n l A. C3H6 v 1. B. C2H4 v 2. C. C6H4 v 1. D. C3H6 v 2. Cu 47 (A-07). -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH. B. H2NCH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. Cu 48 (A-07). t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2; 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-C2H5. C. H2N-CH2-COO-CH3. D. H2N-CH2-CH2-COOH. Cu 49 (A-09). Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 8. B. 7. C. 5. D. 4. Cu 50 (A-09). Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m1 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H10O2N2. B. C5H9O4N. C. C4H8O4N2. D. C5H11O2N. Cu 51. 1 mol -aminoaxit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287%. CTCT ca X l A. CH3-CH(NH2)-COOH. B. H2N-CH2-CH2-COOH. C. NH2-CH2-COOH. D. H2N-CH2-CH(NH2)-COOH. Cu 52. Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 5,15. t chy hon ton 10,3 gam X thu c 17,6gam kh CO2, 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng thc no sau y? A. H2N- (CH2)2 - COO-C2H5. B. H2N- CH(CH3) - COOC. H2N- CH2 CH(CH3) - COOH D. H2N-CH2 -COO-CH3 Cu 53. X l mt aminoaxit no ch cha 1 nhm - NH2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to ra 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH. C. CH3-CH(NH2)-CH2-COOH. D. C3H7-CH(NH2)-COOH Cu 54. t chy hon ton a mol aminoaxit A thu c 2a mol CO2 v a/2 mol N2. Aminoaxit A l A. H2NCH2COOH. B. H2N[CH2]2COOH. C. H2N[CH2]3COOH. D. H2NCH(COOH)2. Cu 55. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH Cu 56. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23,4 gam X tc dng vi HCl d thu c 30,7 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH C. H2N-CH2CH2 -COOH D.CH2=C(CH3)CH(NH2)COOH Cu 57 (A - 2010). Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,70. B. 0,50. C. 0,65. D. 0,55.
GV: Nguyn Ph Hot Nm hc: 2011 - 2012

Bi tp chng Amin - Aminoaxit: n thi i hc

Ti liu lu hnh ni b

Cu 58. Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no? A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 59. Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A < 100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 60. Este A c iu ch t aminoaxit B (ch cha C, H, O, N) v ancol metylic. T khi hi ca A so vi H2 l 44,5. CTCT ca A l A. H2N-CH2-CH2-COOCH3. B. H2N-CH2-COOCH3. C. H2N-CH2-CH(NH2)-COOCH3. D. CH3-CH(NH2)-COOCH3. Cu 61. t chy hon ton ng ng X ca axit aminoaxetic, thu c t l s mol CO2 : H2O l 6 : 7. Cc CTCT c th c ca X l A. CH3CH(NH2)COOH; H2NCH2CH2COOH. B. CH3CH2CH(NH2)COOH; H2NCH2CH2CH2COOH. C. CH3CH2CH2CH(NH2)COOH; H2N[CH2]4COOH. D. CH3[CH2]3CH(NH2)COOH; H2N[CH2]5COOH. Cu 62 (C - 07). Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NCOO-CH2CH3. C. H2NCH2COO-CH3. D. H2NC2H4COOH. Cu 63 (A - 2010). Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 7 v 1,0. B. 8 v 1,5. C. 8 v 1,0. D. 7 v 1,5. Cu 64 (B - 2010). ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. Cu 65 (B - 2010). Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 112,2. B. 165,6. C. 123,8. D. 171,0. Cu 66 (B - 2010). Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. Cu 67 (A-2011). Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 66,44. B. 111,74. C. 81,54. D. 90,6. MI CHI TIT XIN LIN H: phuhoat@gmail.com hoc s in thoi 01639194057
GV: Nguyn Ph Hot Nm hc: 2011 - 2012