IM LUYN THI I HC THNH CNG

THI TH TUYN SINH I HC NM 2012 Mn: HO HC; Khi A Thi gian lm bi: 90 pht, khng k thi gian pht

H, tn th sinh: .......................................................................... S bo danh: ............................................ Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: in phn dung dch gm 14,9 gam KCl v 37,6 gam Cu(NO3)2 (in cc tr, mng ngn xp) n khi khi lng dung dch gim i 21,5 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3, HNO3 v Cu(NO3)2. C. KNO3 v Cu(NO3)2. B. KNO3, KCl v KOH. D. KNO3 v HNO3

Cu 2: Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th A. bn knh nguyn t v m in u gim. B. bn knh nguyn t v m in u tng. C. bn knh nguyn t gim, m in tng. D. bn knh nguyn t tng, m in gim..

Cu 3: t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h gia x, y v V l

Cu 4: Dy kim loi phn ng c vi FeCl3 l A. Fe, Mg, Cu, Ag, Al B. Fe, Zn, Cu, Al, Mg C. Cu, Ag, Au, Mg, Fe D. Au, Cu, Al, Mg, Zn

Cu 5: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,8m gam cht rn, dung dch X v 4,48 lt hn hp kh (ktc) gm NO v N2 t khi so vi khng kh bng 1 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 31,5 gam. Gi tr ca m l A. 16,8. B. 22,4. C. 28,0. D. 14,0.

Cu 6: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 26,88 lt. C. 44,8 lt. D. 33,6 lt.

Cu 7: Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH)2 0,0125M, thu c m gam mui . Gi tr ca m l A. 2,885. B. 2,000. C. 1,250. D. 2,7500.

Cu 8: Trong cc th nghim sau: (1) Cho Silic ioxit tc dng vi axit HF. (2) Cho kh SO2 tc dng vi kh H2S.

(3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho Clorua vi tc dng vi dung dch HCl c.

(5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch Natrinitrit un nng. S th nghim to ra n cht l A. 7. B. 6. C. 5. D. 4.

Cu 9: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l: A. HCl, NaOH, Na2CO3. C. KCl, Ca(OH)2, Na2CO3. B. NaOH, Na3PO4, Na2CO3. D. HCl, Ca(OH)2, Na2CO3.

Cu 10: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht.Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 7. B. 9. . 3. D. 10.

Cu 11: S ng phn c cng thc phn t C4H6 l A. 5. B. 6. C. 3. D. 4.

Cu 12: Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam kt ta. Gi tr ca m l A. 32,20. B. 24,15. C. 17,71. D. 16,10.

Cu 13: Cho 7,8 gam cht hu c X c cng thc phn t C6H6 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 29,2 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 2. B. 5. C. 4. D. 6.

Cu 14: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 3. B. 1. C. 4. D. 2.

Cu 15: Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (1), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (2), (3), (4).

Cu 16: Ho tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,788. B. 4,480. C. 1,680. D. 3,920.

Cu 17: in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l

A. kh Cl2 v H2.

B. kh Cl2 v O2.

C. kh H2 v O2.

D. ch c kh Cl2.

Cu 18: Khi ni v peptit v protein, pht biu no sau y l sai? A. Protein c phn ng mu biure vi Cu(OH)2. B. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. C. Thy phn hon ton protein n gin thu c cc anpha-amino axit. D. Tt c cc protein u tan trong nc to thnh dung dch keo. Cu 19: t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi ). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l A. axit oxalic. B. axit acrylic. C. axit aipic. D. axit fomic.

Cu 20: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 26,7 gam Ala, 32 gam Ala-Ala v 23,1 gam Ala-Ala-Ala. Gi tr ca m l A. 81,54. B. 75,50. C.81,80. D. 90,60.

Cu 21: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau. - Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc). - Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ho tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp X ln lt l: A. 0,39; 0,54; 1,40. B. 0,78; 1,08; 0,56. C. 0,39; 0,54; 0,56. D. 0,78; 0,54; 1,12.

Cu 22: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 3. B. 4 C. 2 D. 1.

Cu 23: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CHC-CH3, CH2=C=C=CH2. C. CHC-CH3, CH2=CH-CCH. B. CH2=C=CH2, CH2=CH-CCH. D. CH2=C=CH2, CH2=C=C=CH2.

Cu 24: Trng hp no sau y khng xy ra phn ng ho hc? A. Sc kh Cl2 vo dung dch FeCl2. C. Sc kh H2S vo dung dch FeCl2. B. Sc kh H2S vo dung dch CuCl2. D. Cho Fe vo dung dch H2SO4 long, ngui.

Cu 25:Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, FeS Fe2(SO4)3 , FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6

Cu 26: Cho cn bng: 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit th t khi ca hn hp kh so vi H2 gim i. Pht biu ng khi ni v cn bng ny l: A. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . B. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit . C. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .

D. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . Cu 27: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit no, mch h, hai chc. C. anehit fomic. B. anehit axetic. D. anehit khng no, mch h, hai chc.

Cu 28: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l A. 4/7. B. 3/7. C. 3/14. D. 1/7.

Cu 29: Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng hp metyl metacrylat. B. Trng hp vinyl xianua. C. Trng ngng hexametyleniamin vi axit aipic. D. Trng ngng axit -aminocaproic.

Cu 30: Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l A. 2,24 lt. B. 4,48 lt. C. 1,12 lt. D. 3,36 lt.

Cu 31: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l A. 59,46%. B. 42,31%. C. 26,83%. D. 19,64%.

Cu 32: Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng mui khan thu c l A. 19,76 gam. B. 22,56 gam. C. 20,16 gam. D. 19,20 gam.

Cu 33: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 5. B. 3. C. 4. D. 6.

Cu 34: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,2. B. 0,3. C. 0,6. D. 0,8.

Cu 35: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 0,224 lt v 3,750g. B. 0,112 lt v 3,750g. C. 0,224 lt v 3,865g D. 0,112 lt v 3,865g

Cu 36: Khi lng ring ca canxi kim loi l 1,55 g/cm3 Gi thit rng, trong tinh th canxi cc nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l A. 0,185 nm. B. 0,196 nm. C. 0,155 nm. D. 0,168 nm.

Cu 37: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 7,38 gam. B. Tng 2,70 gam. C. Tng 7,92 gam. D. Gim 7,74 gam.

Cu 38: Tin hnh cc th nghim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO3)2. (2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (3) Sc kh H2S vo dung dch FeCl2. (4) Sc kh NH3 ti d vo dung dch AlCl3. (5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (6) Sc kh etilen vo dung dch KMnO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 6. B. 3. C. 5. D. 4.

Cu 39: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 17,5. B. 14,5. C. 15,5. D. 16,5.

Cu 40: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (oCH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,72. ________________ II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta A. Fe(OH)3. C. Fe(OH)2, Cu(OH)2 v Zn(OH)2. B. Fe(OH)2 v Cu(OH)2. D. Fe(OH)3 v Zn(OH)2. B. 0,24. C. 0,48. D. 0,96.

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Cu 42: Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng Fe trn nhng khi b ho tan l A. 2x. B. 3x. C. y. D. 2y.

Cu 43: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 3. C. 4. D. 1.

Cu 44: Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc cu to ca X, Y ln lt l

A. H-COOH v HOOC-COOH. C. CH3-CH2-COOH v HOOC-COOH.

B. CH3-COOH v HOOC-CH2-CH2-COOH. D. CH3-COOH v HOOC-CH2 -COOH.

Cu 45: X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O. X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH. B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO. C. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3. D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH. Cu 46: Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch glyxin. B. Dung dch alanin. C. Dung dch lysin. D. Dung dch valin.

Cu 47: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d), sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l A. 48,15%. B. 51,85%. C. 58,52%. D. 41,48%.

Cu 48:Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l A. 550. B. 810. C. 650. D. 750.

Cu 49: Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi nng ca chng trong kh quyn vt qu tiu chun cho php? A. CH4 v H2O. B. CO2 v CH4. C. N2 v CO. D. CO2 v O2.

Cu 50: C cc pht biu sau: (1) Lu hunh, photpho u bc chy khi tip xc vi CrO3. (2) Ion Fe3+c cu hnh electron vit gn l [Ar]3d5 (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. Cc pht biu ng l: A. (1), (3), (4). B. (2), (3), (4). C. (1), (2), (3). D. (1), (2), (4).

B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch Na2CrO4 l: A. Dung dch chuyn t mu vng sang khng mu. B. Dung dch chuyn t mu da cam sang mu vng. C. Dung dch chuyn t mu vng sang mu da cam. D. Dung dch chuyn t khng mu sang mu da cam.

Cu 52: Cho s phn ng:

Y v Z ln lt dng ch to vt liu polime no sau y? A. T olon v cao su buna-N. C. T nitron v cao su buna-S. B. T nilon-6,6 v cao su cloropren. D. T capron v cao su buna.

Cu 53: Dung dch X gm CH3COOH 1M v HCl 0,001M. Gi tr pH ca dung dch X l (Ka=1,75.10-5 ) A. 1,77. B. 2,33. C. 2,43. D. 2,55.

Cu 54: Cho dy chuyn ho sau: (trong X, Y, Z l sn phm chnh). Tn gi ca Y, Z ln lt l A. benzylbromua v toluen. C. 1-brom-2-phenyletan v stiren. B. 2-brom-1-phenylbenzen v stiren. D. 1-brom-1-phenyletan v stiren.

Cu 55: Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l A. 8,15 gam. B. 7,09 gam. C. 7,82 gam. D. 16,30 gam.

Cu 56: Pht biu no sau y v anehit v xeton l sai? A. Axetanehit phn ng c vi nc brom. B. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. C. Axeton khng phn ng c vi nc brom. D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn. Cu 57: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l A. 4. B. 6. C. 2. D. 5.

Cu 58: Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi l: A. Ag + , Cu 2 + , Fe 3 + , Fe 2 + C. Ag + , Fe 3 + , Cu 2 + , Fe 2 + B. Fe 3 + , Fe 2 + , Cu 2 + , Ag + D. Fe 3 + , Ag +, Cu2+, Fe 2 +

Cu 59: Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt vo khng kh dung dch no sau y? A. Dung dch NaOH. C. Dung dch NH3. B. Dung dch NaCl. D. Dung dch H2SO4 long.

Cu 60: Ho tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l A. 0,96. B. 1,24. C. 3,2. D. 0,64.