s 21

thi mn: Ho hc (Dnh cho th sinh Ban Khoa hc T nhin)

Cu 1: Cho 500 gam benzen phn ng vi HNO3 (c) c mt H2SO4 (c), sn phm thu c em kh thnh anilin. Nu hiu sut chung ca qu trnh l 78% th khi lng anilin thu c l A. 465 gam. B. 546 gam. C. 456 gam. D. 564 gam. Cu 2: Cho 5,58 gam anilin tc dng vi dung dch brom, sau phn ng thu c 13,2 gam kt ta 2,4,6-tribrom anilin. Khi lng brom phn ng l A. 7,26 gam. B. 9,6 gam. C. 28,8 gam. D. 19,2 gam. Cu 3: Khi trng ngng 7,5 gam axit amino axetic vi hiu sut l 80%, ngoi amino axit d ngi ta cn thu c m gam polime v 1,44 gam nc. Gi tr ca m l A. 4,25 gam. B. 5,25 gam. C. 5,56 gam. D. 4,56 gam. Cu 4: Nha phenolfomanehit c iu ch bng cch un nng phenol (d) vi dung dch A. CH3CHO trong mi trng axit. B. CH3COOH trong mi trng axit. C. HCOOH trong mi trng axit. D. HCHO trong mi trng axit. Cu 5: Cho s chuyn ha sau: Tinh bt X Y axit axetic. X v Y ln lt l A. mantoz, glucoz. B. glucoz, ancol etylic. C. ancol etylic, anehit axetic. D. glucoz, etyl axetat. Cu 6: Cht khng phn ng vi dung dch AgNO3/NH3 (un nng) to thnh Ag l A. CH3COOH. B. HCOOH. C. C6H12O6 (glucoz). D. HCHO. Cu 7: Cho cc polime sau: (-CH2- CH2-)n, (- CH2- CH=CH- CH2-)n, (- NH-CH2-CO-)n. Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l A. CH2=CH2, CH2=CH- CH= CH2, H2N- CH2- COOH. B. CH2=CH2, CH3- CH=CH- CH3, H2N- CH2- CH2- COOH. C. CH2=CH2, CH3- CH=C= CH2, H2N- CH2- COOH. D. CH2=CHCl, CH3- CH=CH- CH3, CH3- CH(NH2)- COOH. Cu 8: chng minh amino axit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi A. dung dch KOH v dung dch HCl. B. dung dch HCl v dung dch Na2SO4 . C. dung dch KOH v CuO. D. dung dch NaOH v dung dch NH3. Cu 9: Mt trong nhng im khc nhau gia protein vi gluxit v lipit l A. phn t protein lun c cha nguyn t nit. B. protein lun l cht hu c no. C. phn t protein lun c nhm chc -OH. D. protein lun c khi lng phn t ln hn. Cu 10: Nhm m tt c cc cht u tc dng c vi H2O (khi c mt cht xc tc trong iu kin thch hp) l B. Tinh bt, C2H4, C2H2. A. Saccaroz, CH3COOCH3, benzen. C. C2H6, CH3-COO-CH3, tinh bt. D. C2H4, CH4, C2H2. Cu 11: Trung ho 1 mol - amino axit X cn 1 mol HCl to ra mui Y c hm lng clo l 28,286% v khi lng. Cng thc cu to ca X l A. H2N-CH2-COOH. B. CH3-CH(NH2)-COOH. C. H2N-CH2-CH2-COOH. D. H2N-CH2-CH(NH2)-COOH. Cu 12: Cho cc cht C2H5-NH2 (1), (C2H5)2NH (2), C6H5NH2 (3). Dy cc cht c sp xp theo chiu tnh baz gim dn l A. (2), (3), (1). B. (1), (2), (3). C. (2), (1), (3). D. (3), (1), (2). Cu 13: S ng phn ca C3H9N l A. 2 cht. B. 5 cht. C. 3 cht. D. 4 cht. Cu 14: phn bit 2 kh CO2 v SO2 ta dng A. qu tm. B. dung dch Ca(OH)2. C. dung dch BaCl2. D. dung dch nc brom. Cu 15: Dy gm cc dung dch u tc dng vi Cu(OH)2 l 1

A. glucoz, glixerol, mantoz, natri axetat. B. glucoz, glixerol, anehit fomic, natri axetat. C. glucoz, glixerol, mantoz, axit axetic. D. glucoz, glixerol, mantoz, ancol etylic. Cu 16: Trng hp 5,6 lt C2H4 (iu kin tiu chun), nu hiu sut phn ng l 90% th khi lng polime thu c l A. 4,3 gam. B. 7,3 gam. C. 5,3 gam. D. 6,3 gam. Cu 17: C th dng Cu(OH)2 phn bit c cc cht trong nhm A. C3H5(OH)3, C12H22O11 (saccaroz). B. C3H7OH, CH3CHO. C. CH3COOH, C2H3COOH. D. C3H5(OH)3, C2H4(OH)2. Cu 18: Cht khng c kh nng tham gia phn ng trng hp l A. stiren. B. isopren. C. toluen. D. propen. Cu 19: Hai cht ng phn ca nhau l A. fructoz v glucoz . B. saccaroz v glucoz. C. glucoz v mantoz . D. fructoz v mantoz. Cu 20: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l A. CH4, C6H5-NO2. B. C6H12(xiclohexan), C6H5-CH3. C. C2H2, C6H5-CH3. D. C2H2, C6H5-NO2. Cu 21: t chy hon ton m gam mt amin mch h n chc, sau phn ng thu c 5,376 lt CO2; 1,344 lt N2 v 7,56 gam H2O (cc th tch kh o iu kin tiu chun). Amin trn c cng thc phn t l A. C2H7N. B. C2H5N. C. C3H7N. D. CH5N. Cu 22: Trong nhm IA, theo chiu in tch ht nhn tng dn, nng lng ion ho th nht ca cc nguyn t A. gim dn. B. tng dn. C. khng i. D. tng dn ri gim. Cu 23: Mantoz, xenluloz v tinh bt u c phn ng A. vi dung dch NaCl. B. thu phn trong mi trng axit. C. mu vi it. D. trng gng. Cu 24: Mt cacbohirat X c cng thc n gin nht l CH2O. Cho 18 gam X tc dng vi dung dch AgNO3/NH3 (d, un nng) thu c 21,6 gam bc. Cng thc phn t ca X l A. C6H12O6. B. C3H6O3. C. C2H4O2. D. C5H10O5. Cu 25: un nng dung dch cha 27 gam glucoz vi dung dch AgNO3/NH3 (d) th khi lng Ag ti a thu c l A. 16,2 gam. B. 10,8 gam. C. 32,4 gam. D. 21,6 gam. Cu 26: Nhng mt thanh Cu vo 200ml dung dch AgNO31M, khi phn ng xy ra hon ton, ton b Ag to ra u bm vo thanh Cu, khi lng thanh Cu s A. gim 6,4 gam. B. tng 15,2 gam. C. tng 4,4 gam. D. tng 21,6 gam. Cu 27: Trong phn t ca cc cacbohyrat lun c A. nhm chc anehit. B. nhm chc xetn. C. nhm chc ancol. D. nhm chc axit. Cu 28: Trng hp hon ton 6,25 gam vinyl clorua c m gam PVC. S mt xch CH2-CHCl- c trong m gam PVC ni trn l A. 6,02.1021. B. 6,02.1022. C. 6,02.1020. D. 6,02.1023. Cu 29: Mt thanh Zn ang tc dng vi dung dch HCl, nu thm vi git dung dch CuSO4 vo th A. lng bt kh H2 bay ra khng i. B. bt kh H2 khng bay ra na. C. lng bt kh H2 bay ra nhiu hn. D. lng bt kh H2 bay ra t hn. Cu 30: tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng c, iu kin th nghim y ) l A. dung dch NaOH, dung dch NaCl, kh CO2. B. dung dch NaOH, dung dch HCl, kh CO2. C. dung dch Br2, dung dch NaOH, kh CO2. D. dung dch Br2, dung dch HCl, kh CO2. Cu 31: Cng thc cu to ca alanin l A. C6H5NH2. B. H2N-CH2-CH2-COOH. C. H2N-CH2-COOH. D. CH3-CH(NH2)-COOH. Cu 32: T cc cp oxi ho kh sau: Fe2+/Fe, Mg2+/Mg, Cu2+/Cu v Ag+/Ag, s pin in ho c th lp c ti a l A. 5. B. 4. C. 6. D. 3. 2

Cu 33: Trong s cc loi t sau: [-NH-(CH2)6-NH-OC-(CH2)4-CO-]n (1). [-NH-(CH2)5-CO-]n (2). [C6H7O2(OOC-CH3)3]n (3). T thuc loi poliamit l A. (1), (2), (3). B. (2), (3). C. (1), (2). D. (1), (3). Cu 34: Phn bit 3 dung dch: H2N-CH2-COOH, CH3COOH v C2H5-NH2 ch cn dng 1 thuc th l A. dung dch NaOH. B. natri kim loi. C. dung dch HCl. D. qu tm. Cu 35: Cho E 0 Zn2+ / Zn0 =-0,76 V; E 0Cu 2+ / Cu 0 =0,34 V; E 0 Ni2+ / Ni0 =-0,23 V. Dy cc cation sp xp theo chiu tnh oxi ho gim dn l A. Ni2+,Cu2+, Zn2+. B. Ni2+,Zn2+,Cu2+. C. Cu2+, Ni2+, Zn2+. D. Cu2+, Zn2+,Ni2+. 2+ Cu +Zn2+ Cu 36: Cho phn ng ho hc xy ra trong pin in ho: Zn+Cu (Bit E 0 Zn2+ / Zn0 =-0,76 V; E 0Cu 2+ / Cu 0 =0,34 V). Sut in ng chun ca pin in ho trn l A. +1,10V. B. -1,10V. C. +0,42V. D. -0,42V. Cu 37: Cht phn ng c vi dung dch AgNO3/NH3 (un nng) to thnh Ag l A. CH3 - CH(NH2) - CH3. B. CH3 - CH2-CHO. C. CH3 - CH2 - COOH. D. CH3 - CH2 - OH. Cu 38: Cho m gam anilin tc dng vi dung dch HCl (c, d). C cn dung dch sau phn ng thu c 15,54 gam mui khan. Hiu sut phn ng l 80% th gi tr ca m l A. 11,16 gam. B. 13,95 gam. C. 12,5 gam D. 8,928 gam. Cu 39: Cht khng c kh nng lm xanh nc qu tm l A. natri hiroxit. B. natri axetat. C. anilin. D. amoniac. Cu 40: Nhm c cha dung dch (hoc cht) khng lm giy qu tm chuyn sang mu xanh l A. NH3, CH3-NH2. B. NaOH, CH3-NH2. C. NaOH, NH3. D. NH3, anilin. -----------------Ht-----------------