TRNG THPT NGUYN KHUYN CHUYN S 3 :

TON V AMIN - AMINOAXIT

AMIN V AMINOAXIT I. Amin

DNG 1: Vit ng phn gi tn xc nh CTPT Xc nh lc baz ca cc amin Cng thc tnh s ng phn ca amin no, n chc ( CnH2n+3N) l : 2n-1vi n<5 Amin bc I ( R NH2 ) ; amin bc II ( R1 NH- R2) v amin bc III ( R)3N Lc baz ca cc amin th t nh sau : amin bo bc II> amin bo bc I> amin bo bc III> NH3> amin thm 1 nhn > amin thm 2 nhn Danh php gc chc : c tn gc HC + amin Cu 1. S ng phn amin bc 2 c cng thc phn t l C4H11N l A. 3 B.2 C. 4 D.8 Cu 2. S ng phn amin thm bc 1 c cng thc phn t C7H9N l : A.3 B.4 C.5 D. 2 Cu 3. S lng ng phn amin thm c cng thc phn t C7H9N l A.6 B.5 C.4 D.3 Cu 4. Mt amin no n trong phn t c 7 nguyn t H. S lng ng phn ca amin trn l : A.3 B. 2 C.1 D.4 Cu 5.Dy cc cht no sau y c sp xp theo th t tng dn lc baz t tri sang phi? A.(CH3)2NH ; CH3NH2 ; NH3 ; C6H5NH2 ; (C6H5)2NH B. C6H5NH2 ; NH3; CH3NH2 ; (CH3)2NH ; (C6H5)2NH C. (C6H5)2NH ; C6H5NH2 ; NH3; CH3NH2 ; (CH3)2NH ; D. (CH3)2NH ; NH3; (C6H5)2NH ; CH3NH2 ; C6H5NH2 Cu 6. Mt amin no n mch h c % theo khi lng ca Cacbon bng 65,75%. S lng ng phn amin bc 2 ca amin trn l : A.6 B. 5 C. 4 D.3 Cu 7. Mt amin no n chc bc 1 c t khi hi so vi kh H2 bng 29,5. Tn gi ca amin l A. Butyl amin B. Propyl amin C. metyl amin D. Etyl amin Cu 8. Hp cht : CH3 N(C2H5)2 c tn l A. imetyletanamin B.N,N etylmetyletanamin C. N ietylmetylamin D. Etylmetylamin DNG 2: BI TP V PHN NG CHY CA AMIN 1) amin n chc * t CTTQ ca amin no n chc ( CnH2n+3N) hoc amin n chc l: CxHyN nCO2 x p dng CT: = y 2nH 2O * Amin no n chc: 2 CnH2n+3N + (6n+3)/2 O2 2nCO2 + (2n+3)H2O+ N2 nCO 2 2n 2 S mol amin = ( nH2O n CO2) v = n =? 3 2n + 3 nH O
2

*Amin khng no n chc c 1 lk i (CnH2n+1N) 2 CnH2n+1N + (6n+1)/2 O2 2nCO2 + (2n+1)H2O + N2 nCO 2n 2 S mol amin = 2 ( nH2O n CO2) v = 2n + 1 nH O
2

* Amin thm: 2CnH2n 5 N + (6n-5)/2 O2 2nCO2 + (2n-5)H2O +N2 CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 1

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT 2) Amin bt k: t CTTQ l : CxHyNt Phng trnh chy: CxHyNt + ( x+y/4)O2 xCO2 + y/2 H2O + t/2 N2 T LBTKL ta c: nO2 phn ng = nCO2 + nH2O Lu : Khi t chy mt amin ngoi khng kh th nN2 sau phn ng =nN2 sinh ra t phn ng chy ca amin + nN2 c sn trong khng kh mC = 12nCO2 ; mH=2nH2O ; mN= a-(mC+ mH) Cu 1. t chy hon ton mg hn hp gm 3 amin thu c 3.36lt kh CO2 ( kc) ; 5.4g nc v 1.12 lt kh N2( ktc) . Gi tr m l A. 3.6 B. 3.8 C. 4 D. 3.1 Cu 2. t chy hon ton x mol mt amin no n chc sau phn ng thu c 13.2g CO2 v 8,1 g nc . Gi tr x v CTPT ca amin l A. 0.2mol v C3H9N B. 0.1mol v C4H11N C. 0.1 mol v C3H9N D. 0.3 mol v C2H7N Cu 3. t chy hon ton mg mt amin n chc thu c 0.2 molCO2 v 0.35 mol nc . CTPT amin l A. C4H7N B. C2H7N C. C4H14N D. C2H5N Cu 4. Khi t chy hon ton mt amin n chc X thu c 8,4 lt kh CO2, 1,4 lt kh N2 (V cc kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (H K.B 2007) A. C3H7N B. C3H9N C. C2H9N D. C4H9N Cu 5. t chy mt ng ng ca metylamin, ngi ta thy t l th tch cc kh v hi VCO2:VH2O sinh ra bng 2:3 Cng thc phn t ca amin l: A. C3H9N B. CH5N C. C2H7N D. C4H11N Cu 6. t chy hon ton m (g) hn hp 3 amin thu c 3,36lt CO 2; 1,12lt N2(ktc) v 5,4g H2O. Gi tr ca m l: A.3,6 B.3,8 C.4 D.3,1 Cu 7. t chy hon ton m gam mt amin n chc thu c 0,2 mol CO 2 v 0,35 mol H2O. Cng thc phn t ca amin l A. C4H7N B. C2H7N C. C4H14N D. C2H5N CO2 6 Cu 8. t chy hon ton mt amin n chc b 1 thu c CO2 v H2O theo t l = . Vy CT amin H2O 7 l: A. C3H7N B. C4H9N C. CH5N D. C2H7N CO2 8 Cu 9. t chy hon ton mt amin n chc cha no thu c CO2 v H2O theo t l = . Vy amin H2O 9 l: A. C3H6N B. C4H9N C. C4H8N D. C3H7N Cu 10. t chy hon ton 10,4 gam hai amin no, n chc, ng ng lin tip nhau, thu c 11,2 lt kh CO2 (ktc). Hai amin c cng thc phn t l A. CH4N v C2H7N B. C2H5N v C3H9N C. C2H7N v C3H7N D. C2H7N v C3H9N Cu 11. Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C2H7N. B. C4H9N. C. C3H7N. D. C3H9N. Cu 12. t chy mt amin no n chc mch thng ta thu c CO2 v H2O c t l mol nCO2 : nH2 O = 8 : 11 . CTCT ca X l : A. (C2H5)2NH B. CH3(CH2)3NH2 C. CH3NHCH2CH2CH3 D. C 3 Cu 13. t chy mt amin n chc no (h) thu c t l s mol CO2 : H2O l 2 : 5. Amin cho c tn gi no di y? A. imetylamin. B. Metylamin. C. Trimetylamin. D. Izopropylamin Cu 14. t chy hon ton 5,9 gam mt amin no h n chc X thu c 6,72 lt CO2, . Cng thc ca X l A. C3H6O. B. C3H5NO3. C. C3H9N. D. C3H7NO2. Cu 15. t chy hon ton 6,2 gam mt amin no h n chc, cn 10,08 lt O2 ktc. CTPT l A. C4H11N. B. CH5N. C. C3H9N. D. C5H13N. CHUYN 3 N THI TN H 2 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 16. t chy hon ton amin no n chc X, thu c 16,8 lt CO2 ; 2,8 lt N2 (ktc) v 20,25 g H2O. Cng thc phn t ca X l A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. Cu 17. C hai amin bc mt: A (ng ng ca anilin) v B (ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra 336ml kh N2 (ktc). Khi t chy hon ton amin B cho VH 2O : VCO2 = 3 : 2 . Cng thc phn t ca hai amin l: A. CH3C6H4NH2 v CH3CH2CH2NH2 B. C2H5C6H4NH2 v CH3CH2CH2NH2 C. CH3C6H4NH2 v CH3CH2CH2CH2NH2 D. C2H5C6H4NH2 v CH3CH2CH2CH2NH2 Cu 18. t chy hon ton a mol amin no, n chc thu c 13,2g CO2 v 8,1g H2O.Gi tr ca a l: A.0,05 B.0,1 C.0,07 D.0,2 Cu 19. t chy hon ton amin no, n chc bc mt ,mch h thu c t l mol CO 2 v H2O l 4:7 .Tn gi ca amin l: A.etyl amin B. imetyl amin C.etyl metyl amin D.propyl amin Cu 20. t chy hon ton hn hp 2 amin no n chc ng ng lin tip nhau, thu c nH 2O : nCO2 = 2 :1 . Hai amin c Cng thc phn t l: A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C. C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 Cu 21.t chy hon ton m gam mt amin A bng mt lng khng kh va thu c 17,6 gam CO2 ; 12,6 gam hi nc v 69,44 lt nito.Gi thit khng kh ch gm nito v oxi trong nito chim 80% th tch khng kh.Cc th tch kh o ktc.Gi tr ca m v CTPT ca amin l A.4,5 v C2H7N B.9 v CH5N C.4,5 v CH5N D.9 v C2H7N DNG 3: TNH KHI LNG AMIN (MUI) TRONG PHN NG VI AXT HOC VI BROM * Cn nh 2 phng trnh: + Vi HCl: RNH2 + HCl RNH3Cl (1) R+16 36,5 R+52,5 Tng 36,5g +Vi Brom: C6H5NH2 + 3Br2 C6H2Br3NH2 + 3HBr kt ta trng 93 330 Xg Yg *PP: 1) p dng nh lut bo ton khi lng khi lng: mamin + maxit = mmui 2) Tnh mol ca cht bi cho ri t vo ptrnh suy ra s mol ca cht bi hi => tnh m 3) p dng nh lut tng gim khi lng C6H5NH2 + HCl C6H5NH3Cl 93 Tng 36,5 Ag m = = B mMui = A + B 1. Cho 5,9 gam Propylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu c l (Cho H = 1, C = 12, N = 14) A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam. 2. Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. 3. Cho anilin tc dng 2000ml dd Br2 0,3M. Khi lng kt ta thu c l A.66.5g B.66g C.33g D.44g 4. Cho 0,1 mol anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui phenylamoniclorua ( C6H5NH3Cl) thu c l A. 25,900 gam . B. 6,475gam. C. 19,425gam. D. 12,950gam CHUYN 3 N THI TN H 3 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT 5. Cho m gam Anilin tc dng ht vi dung dch Br2 thu c 9,9 gam kt ta. Gi tr m dng l A. 0,93 gam B. 2,79 gam C. 1,86 gam D. 3,72 gam 6. Th tch nc brom 5 % (d = 1,3g/ml) cn dng iu ch 3,96 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C 88,61 ml. D. s khc . 7. Cho 20g hn hpX gm ba amin no n chc l ng ng k tip nhau tc dng va vi dung dch HCl 1M, c cn dung dch thu c 31,68g mui. Xc nh th tch HCl dng ? A 16ml B 32ml C 160ml D 320ml DNG 4: XC NH CTPT,CTCT CA AMIN DA VO PHN NG TO MUI ( PHN NG VI DUNG DCH AXIT) * Phn ng to mui: 1) Amin n chc: t CTTQ ca amin no n chc CnH2n+3N hoc amin n chc l: R-NH2( hoc CxHyN) V n chc nn ta lun c nHCl = nNH2 + Vi HCl: RNH2 + HCl RNH3Cl (1) Amin bc 1, n chc mRNH 2 M RNH 2 p dng CT: = n = a => MR =a -16 => CTPT
HCl

(hoc M = = A M = A - 14 => CTPT) 2) Amin a chc Vd: amin bc 1 : R(NH2)a + aHCl R(NH3Cl)a S chc ca amin: a=nHCl /nA v LBTKL : mmui = mamin + mHCl 1. trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C3H7N. B. C2H7N. C. C3H5N. D. CH5N. 2. trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C2H7N B. CH5N C. C3H5N D. C3H7N 3. Trung ha 3,1 gam mt amin n chc cn 100 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N 4.Cho 0,4 mol amin no, n chc X tc dng vi dd HCl va thu c 32,6g mui.CTPT ca X l: A.CH3NH2 B.C2H5NH2 C.C3H7NH2 D.C4H9NH2 5. Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N 6. Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 5. B. 8. C. 7. D. 4. 7. Cho 20 hn hp 3 amin n chc no, ng ng lin tip nhau tc dng vi dung dch HCl 1M va ,sau c cn dung dch thu c 31,68 gam hn hp mui. Bit t l mol ca cc amin theo th t t amin nh n amin ln l 1:10:5 th ba amin c Cng thc phn t l: A. CH3NH2, C2H5NH2, C3H7NH2 B. C2H5NH2, C3H7NH2, C4H9NH2 C. C3H7NH2, C4H9NH2, C5H11NH2 D. Tt c u sai. DNG 5: AMIN TC DNG VI DUNG DCH MUI Mt s mui d to kt ta hidroxit vi dd amin 3RNH2 + 3H2O + FeCl3 Fe(OH)3 + 3RNH3+ClLu : Tng t NH3,cc amin cng to phc cht tan vi Cu(OH)2, Zn(OH)2,AgCl 1. Cho 9,3 gam mt amin no n chc bc 1 tc dng vi dung dch FeCl3 d thu c 10,7 gam kt ta. Cng thc ca amin trn l: A. C2H5N B. CH5N C. C3H9N D. C3H7N CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 4

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT 2. Cho hn hp 2 amin n chc bc I c t khi hi so vi hiro l 19 (bit c mt amin c s mol bng 0,15) tc dng vi dung dch FeCl3 d thu c kt ta A. em nung A n khi lng khng i thu c 8 gam cht rn. Cng thc ca 2 amin l A. CH3NH2 v C2H5NH2 B. CH3NH2 v C2H3NH2 C. C2H5NH2 v C2H3NH2 D. CH3NH2 v CH3NHCH3 3. Cho m gam hn hp hai amin n chc bc I c t khi hi so vi hiro l 30 tc dng vi FeCl 2 d thu c kt ta X. ly kt ta nung trong khng kh n khi lng khng i c 18,0 gam cht rn. Vy gi tr ca m l A. 30,0 gam B. 15,0 gam C. 40,5 gam D. 27,0 gam 4. Cho 17,4 gam hn hp 2 amin n chc bc I c t khi so vi khng kh bng 2. Tc dng vi dung dch FeCl 3 d thu c kt ta, em nung kt ta n khi lng khng i c m gam cht rn. Gi tr ca m l A. 16,0 gam B. 10,7 gam C. 24,0 gam D. 8,0 gam 5.Hn hp X gm 2 mui AlCl3 v CuCl2 .Ha tan hn hp X vo nc thu c 200 ml dung dch A.Sc kh metyl amin ti d vo dung dch A thu c 11,7 g kt ta.Mt khc cho t t dung dch NaOH ti d vo dd A thu c 9,8 gam kt ta.Nng mol/l ca AlCl3 v CuCl2 trong dd A ln lt l: A. 0,1 M ; 0,75 M B.0,5 M ; 0,75 M C.0,75M;0,5M D.0,75M ; 0,1 M

II - AMINOAXIT
DNG 1: BI TON AMINOAXIT VI DUNG DCH AXIT HOC DUNG DCH BAZO 1) Amino axit n gin nht dng : H2N-R-COOH * Phi vit c 2 phng trnh c dng: + Vi axt HCl: H2N R COOH + HCl ClH3N R COOH R + 61 R+ 97,5 tng 36,5 + Vi baz NaOH: H2N R COOH+ NaOH H2N R COONa+ H2O R + 61 R+ 83 tng 22 2) Amino axit phc tp: (H2N)a R (COOH)b *T/ dng vi NaOH:. Ptpu: (H2N)a R (COOH)b + bNaOH (H2N)a R (COONa)b + bH2O = b = s nhm chc axit ( COOH) * T/d vi HCl Ptpu: (H2N)a R (COOH)b + aHCl (ClH3N)a R (COOH)b = a = s nhm chc bazo (NH2) Lu :khng ch aminoaxxit c tnh lng tnh m mui amoni dng RCOONH4 cng c tnh lng tnh. 1. Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. Glixin 2. 0,1 mol aminoaxit X phn ng va vi 0,2 mol HCl hoc 0,1 mol NaOH. Cng thc ca X c dng l. A. (H2N)2R(COOH)2. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH 3. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23,4 gam X tc dng vi HCl d thu c 30,7 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH C.CH2-CH(CH3)CH(NH2)COOH D.CH2=C(CH3)CH(NH2)COOH 4. X l mt aminoaxit no ch cha 1 nhm - NH 2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH.C. CH3-CH(NH2)-CH2-COOH. D. C3H7-CH(NH2)-COOH CHUYN 3 N THI TN H 5 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d 5. X l mt thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH 6. X l mt amino axit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dung dch HCl 0,125 M v thu c 1,835 g mui khan. Cn khi cho 0,01 mol X tc dng vi dung dch NaOH th cn 25 gam dung dch NaOH 3,2%. Cng thc no sau y l ca X ? A. C7H12-(NH)-COOH COOH B. C3H6-(NH)-COOH C. NH2-C3H5-(COOH)2 D. (NH2)2-C3H5-

7. Cho 4,41g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. X CTCT ca X. A. HOOC-CH2CH2CH(NH2)COOH B. CH3CH(NH2)COOH C. HOOCCH2CH(NH2)CH2COOH D.C A,B 8. 0,1 mol aminoaxit A phn ng va vi 0,2 mol HCl, sn phm to thnh p va ht vi 0,3 mol NaOH. Gi tr n, m ln lt l: A. (H2N)2R(COOH)3. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH 9. Cho 1 mol aminoaxit X tc dng vi dung dch NaOH d m1 g mui Y. Mt khc cng 1 mol X nh trn nu cho tc dng vi dung dch HCl d thu c m2 g mui Z. Bit m1 - m2 = 7,5. X CTPT ca X. A. C5H9O4N B. C4H10O2N2 C. C5H11O4N D. C5H8O4N2 10. Cho 14,7 gam mt amino axit X (c 1 nhm NH2) tc dng vi NaOH d thu c 19,1 gam mui. Mt khc cng lng amino axit trn phn ng vi HCl d to 18,35 gam mui. Cng thc cu to ca X c th l: A. NH2-CH2-COOH B. CH3-CH(NH2)COOH C. NH2-(CH2)6 -COOH D. HOOC-CH2-CH2-CH(NH2)COOH 11. Cho 0,1 mol cht X ( CH6O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dung dch Y.C cn dung dch Y thu c m gam cht rn khan.Gi tr ca m l: A.5,7 B.12,5 C.15 D.21,8 12. Amino axit X cha 1 nhmCOOH v 2 nhm NH 2. Cho 0,1 mol X tc dng ht vi 270ml dung dch NaOH 0,5M c cn thu c 15,4g cht rn. Cng thc phn t c th c ca X l A. C4H10N2O2 B. C5H12N2O2 C. C5H10NO2 D. C3H9NO4 13. X l mt a amino axit cha 1 nhm COOH v 1 nhm NH2. Cho 8,9g X tc dng vi 200ml dung dch HCl 1M. Thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn dng 300ml dung dch NaOH 1M. CTCT ca X l. A. CH3 - CH2 COOH NH2 B. CH3 CH2 CH COOH NH2 CH3 C. CH2(NH2) - CH2 COOH D. CH3 C NH2 COOH

DNG 2: BI TP T CHY AMINOAXIT t CTTQ CxHyOzNt

CHUYN 3 N THI TN H

BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN m m m m m x: y: z :t = C : H : O : N = nCO2 : 2.nH2O : O : 2.nN2 12 1 16 14 16 Hay x: y: z :t = %C % H %O % N : : : 12 1 16 14

TON V AMIN - AMINOAXIT

Lu v peptit: + T n phn t - amino axit khc nhau to ra n! ng phn peptit v c n2 s peptit c to thnh. 1. Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy hon ton a mol X thu c 6,729 (l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l : A. CH2NH2COOH v C B. CH2NH2CH2COOH C. CH3CH(NH2)COOH D. C B

2. Este X c to bi ancol metylic v - amino axit A. T khi hi ca X so vi H2 l 51,5. Amino axit A l A. Axit - aminocaproic B. Alanin C. Glyxin D. Axit glutamic 3. Hp cht X c 40,45%C, 7,86%H, 15,73%N v cn li l oxi. Khi lng mol phn t ca X nh hn 100 gam. Bit X tc dng c vi hiro nguyn t. Cng thc cu to ca X l A. CH3CH(NH2)COOH B. CH3-CH2-CH2-CH2NO2 C. H2NCH2CH2COOH D. CH3-CH2-CH2-NO2 4. Phn tch nh lng hp cht hu c X ta thy t l khi lng gia 4 nguyn t C, H, O, N l mC : mH : mO : mN = 4,8 : 1 : 6,4 : 2,8. T khi hi ca X so vi He bng 18,75. Cng thc phn t ca X l A. C2H5O2N. B. C3H7O2N. C. C4H10O4N2. D. C2H8O2N2
5.Este A c iu ch t amino axit B v ancol metylic.t chy hon ton 0,1 mol A thu c 1,12 lt N2 ( ktc) ; 13,2 gam CO2 v 6,3 gam H2O.Bit t khi ca A i vi hidro l 44,5.CTCT ca A l: A.H2N-CH2-COOCH3 B.H2N-CH2-CH2-COOCH3 C.CH3-CH(NH2)COOCH3 D.CH3-CH=C (NH2)COOCH3 THI I HC Cu 1 (Cu 29-DH-10-A): Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l : A. 0,70. B. 0,50. C. 0,65. D. 0,55. Cu 2 (Cu 40-DH-10-A): C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 6. B. 9. C. 4. D. 3. Cu 3 (Cu 41-DH-10-A): Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 7 v 1,0. B. 8 v 1,5. C. 8 v 1,0. D. 7 v 1,5. Cu 4 (Cu 16-DH-10-B): Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. amoni acrylat v axit 2-aminopropionic. B. axit 2-aminopropionic v amoni acrylat. C. vinylamoni fomat v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. Cu 5 (Cu 19-DH-10-B): Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 171,0. B. 112,2. C. 123,8. D. 165,6. CHUYN 3 N THI TN H 7 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 6 (Cu 23-DH-10-B): ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 45. B. 120. C. 30. D. 60. Cu 7 (Cu 47-DH-10-B): Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Ala-Val-Val-Phe. B. Gly-Phe-Gly-Ala-Val. C. Val-Phe-Gly-Ala-Gly. D. Gly-Ala-Val-Phe-Gly. Cu 8 (Cu 6-CD-10-A): Dung dch no sau y lm qu tm chuyn mu xanh? A. Glyxin. B. Etylamin. C. Anilin. D. Phenylamoni clorua. Cu 9 (Cu 10-CD-10-A): ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 2. B. 3. C. 1. D. 4. Cu 10 (Cu 48-DH-10-B): Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3. B. 1. C. 2. D. 4. Cu 11 (Cu 14-DH-09-A): Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 12 (Cu 20-DH-09-A): Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 13 (Cu 48-DH-09-A): Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6. Cu 14 (Cu 15-DH-09-B): Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. (H2N)2C3H5COOH. B. H2NC2C2H3(COOH)2. C. H2NC3H6COOH. D. H2NC3H5(COOH)2. Cu 15 (Cu 22-DH-09-B): S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 2 B. 3 C. 4 D. 1 Cu 16 (Cu 24-DH-09-B): Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2 . Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2 B. C2H5OH v N2 C. CH3OH v NH3 D. CH3NH2 v NH3 Cu 17 (Cu 48-DH-09-B): Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75 B. 27,75 C. 26,25 D. 24,25 Cu 18 (Cu 18-CD-09-A): Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l : A. metyl aminoaxetat. B. axit -aminopropionic. C. axit -aminopropionic. D. amoni acrylat. Cu 19 (Cu 50-CD-09-A): Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 8

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT A. 453. B. 382. C. 328. D. 479. Cu 20 (Cu 58-CD-09-A): Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (to) v vi dung dch HCl (to). S phn ng xy ra l: A. 3. B. 6. C. 4. D. 5. Cu 21(C-07): Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan.Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O =16; Na = 23) A. H2NCOO-CH2CH3. B. CH2=CHCOONH4. C. H2NC2H4COOH. D. H2NCH2COO-CH3. Cu 22(C-07): Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau: A. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic. B. glucoz, mantoz, glixerin (glixerol), anehit axetic. C. lng trng trng, glucoz, fructoz, glixerin (glixerol). D. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic. Cu 23(A-07): Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 8,9 gam. B. 15,7 gam. C. 16,5 gam. D. 14,3 gam Cu 24(A-07): t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2COONa. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A.H2N-CH2-COO-C3H7. B.H2N-CH2-COO-CH3. C.H2N-CH2-COO-C2H5. D.H2N-CH2-CH2-COOH. Cu 25(B-07): Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z. B. X, Y, T. C. X, Y, Z, T. D. Y, Z, T. Cu 26(B-07): C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. nc brom. B. giy qu tm. C. dd phenolphtalein. D. dd NaOH. Cu 27(B-07): Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, amoniac, natri hiroxit. B. anilin, metyl amin, amoniac. C. metyl amin, amoniac, natri axetat. D. amoni clorua, metyl amin, natri hiroxit. Cu 28(B-07): Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3. B. 4. C. 5. D. 6. Cu 29(B-07): Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun l cht hu c no. B. protit lun cha nit. C. protit c khi lng phn t ln hn. D. protit lun cha chc hiroxyl. Cu 30(C-08): Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 4. B. 3. C. 2. D. 5 Cu 31(B-2010): t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,4. C. 0,3. D. 0,2. Cu 32 (B-2010): Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2. D. H2NCH2CH2CH2NH2 CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 9

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 33(A-2010): t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH3-CH2-CH2-NH2. B. CH2=CH-CH2-NH2. C. CH3-CH2-NH-CH3. D. CH2=CH-NH-CH3. Cu 34(A-2010): Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l A. C3H9N. B. C3H7Cl. C. C3H8O. D. C3H8. Cu 35(A-2011): Khi ni v peptit v protein, pht biu no sau y l sai? A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. B. Tt c cc protein u tan trong nc to thnh dung dch keo. C. Protein c phn ng mu biure vi Cu(OH)2. D. Thy phn hon ton protein n gin thu c cc -amino axit. Cu 36(A-2011):: Thnh phn % khi lng ca nit trong hp cht hu c C xHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 2. B. 3. C. 4. D. 1. Cu 37(A-2011):: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 90,6. B. 111,74. C. 81,54. D. 66,44. Cu 38 (A-2011):: Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch alanin B. Dung dch glyxin C. Dung dch lysin D. Dung dch valin III. PEPTIT - PROTEIN Cu 1: chng minh tnh lng tnh ca H2NCH2COOH (X), ta cho X tc dng vi A. HCl, NaOH. B. Na2CO3, HCl. C. HNO3, CH3COOH. D. NaOH, NH3. Cu 2: Aminoaxit no sau y c hai nhm amino. A. Axit GlutamiC. B. Lysin. C. Alanin. D. Valin. Cu 3: C bao nhiu tn gi ph hp vi cng thc cu to: (1). H2NCH2COOH : Axit amino axetic. (2). H2N[CH2]5COOH : axit amino caproic. (3). H2N[CH2]6COOH : axit amino enantoic. (4). HOOC[CH2]2CH(NH2)COOH : Axit amino glutaric. (5). H2N[CH2]4CH (NH2)COOH : Axit , iamino caproic. A. 2 B. 3 C. 4 D.5 Cu 4: Cho cc nhn nh sau: (1). Alanin lm qu tm ha xanh. (2). Axit Glutamic lm qu tm ha . (3). Lysin lm qu tm ha xanh. (4). Axit amino caproic l nguyn liu sn xut nilon 6. S nhn nh ng l: A. 1 B. 2 C.3 D.4 Cu 5: Cho cc cu sau y: (1). Khi cho axit glutamic tc dng vi NaOH d th to sn phm l bt ngt, m chnh. (2). Phn t cc amino axit ch c mt nhm NH2 v mt nhm COOH. (3). Dung dch ca cc amino axit u c kh nng lm qu tm chuyn mu. (4). Cc mino axit u l cht rn nhit thng. (5). Khi cho amino axit tc dng vi hn hp NaNO2 v CH3COOH kh thot ra l N2. S nhn nh ng l: A. 1 B. 2 C. 3 D. 4 CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 10

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 6: 1 thuc th c th nhn bit 3 cht hu c : axit aminoaxetic, axit propionic, etylamin l A. NaOH. B. HCl. C. Qu tm. D. CH3OH/HCl. Cu 7: Bradikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l : Arg Pro Pro GlyPheSerProPheArg. Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tri peptit m thnh phn c cha phenyl alanin ( phe). A. 3 B. 4 C. 5 D. 6 Cu 8: Cho cc cng thc sau. S CTCT ng vi tn gi ng (1). H2N CH2COOH : Glyxin (2). CH3CHNH2COOH : Alanin. (3). HOOC CH2CH2CH(NH2)COOH : Axit Glutamic. (4). H2N (CH2)4CH(NH2)COOH : Lizin. A. 1 B.2 C.3 D.4 Cu 9: Amino axit c bao nhiu phn ng cho sau y : phn ng vi axit, phn ng vi baz, phn ng trng bc, phn ng trng hp, phn ng trng ngng, phn ng vi ancol, phn ng vi kim loi kim. A. 3 B.4 C.5 D.6 Cu 10: Alanin c th phn ng c vi bao nhiu cht trong cc cht cho sau y: Ba(OH)2 ; CH3OH ; H2NCH2COOH; HCl, Cu, CH3NH2, C2H5OH, Na2SO4, H2SO4. A. 4 B.5 C.6 D.7 Cu 11: Thuc th thch hp nhn bit 3 dung dch sau y: Axit fomic, Glyxin, axit , diaminobutyric. A. AgNO3/NH3 B. Cu(OH)2 C. Na2CO3 D. Qu tm. Cu 12: C 4 dung dch long khng mu ng trong bn ng nghim ring bit, khng dn nhn: Abumin, Glixerol, CH3COOH, NaOH. Chn mt trong cc thuc th sau phn bit 4 cht trn: A. Qu tm B. Phenol phtalein. C. HNO3 c. D. CuSO4. aminoaxit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287%. Cu 13: 1 mol CTCT ca X l A. CH3 CH(NH2) COOH. B. H2N CH2 CH2 COOH. C. H2N CH2 COOH. D. H2N CH2 CH(NH2) COOH. Cu 14: Khi trng ngng m g axit aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c p gam polime v 1,44g nC. Gi tr m l A. 10,48g. B. 9,04g. C. 11,02g. D. 13,1g. Cu 15: Este X c iu ch t aminoaxit A v ancol etyliC. 2,06 gam X ha hi hon ton chim th tch bng th tch ca 0,56 gam N2 cng iu kin nhit , p sut . Nu cho 2,06 gam X tc dng va vi dung dch NaOH s thu c dung dch cha bao nhiu gam mui? A. 2,2 gam B. 1,94 gam C. 2,48 gam D. 0,96 gam Cu 16: Mt hp cht X c cng thc phn t C3H7O2N. X khng phn ng vi dung dch brom, khng tham gia phn ng trng ngng. X c cng thc cu to no sau y? A. H2NCH2CH2COOH B. CH2=CHCOONH4 C. H2NCH(CH3)COOH D. CH3CH2CH2NO2 Cu 17: C qu trnh chuyn ho sau: +Y +Z C6H12O3N2 X C3H6NO2K X, Y, Z l nhng cht no sau y? A. amino butanoic, NaOH, HCl. (1) B. amino propanoic, HCl, KOH. (2) C. amino axetic, KOH, HCl. (3) D. C (1), (2), (3) u sai. Cu 18: t chy ht a mol amino axit X c 2a mol CO2 v a/2 mol N2. Aminoaxit trn c cng thc cu to l: A. H2NCH2COOH B. H2NCH2CH2COOH C. H2NCH2CH2CH2COOH D. H2NCH(COOH)2 CHUYN 3 N THI TN H 11 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 19: t chy hon ton 17,4 gam amino axit X (axit n chc) th thu c 0,6 mol CO2; 0,5 mol H2O v 0,1 mol N2. X c cng thc cu to l: A. H2NCH2CH2COOH hoc CH3CH(NH2)COOH B. H2NCH = CHCOOH hoc CH2 = C(NH2)COOH C. H2NCH2COOH D. H2NCH2CH(NH2)COOH. Cu 20: Mt hp cht hu c X mch thng c Cng thc phn t l C3H10O2N2. X tc dng vi dung dch kim to cht kh lm qu tm m ho xanh, mt khc X tc dng vi dung dch axit to thnh mui amin bc mt. X c Cng thc phn t no sau y? A. H2NCH2CH2COONH4 B. CH3CH(NH2)COONH4 C. CH3CH2CH(NH2)COONH4. D. A v B ng Cu 21: nhn bit cc cht lng du ho, du m, gim n v lng trng trng ta c th tin hnh theo th t no sau y: A. Dng qu tm, dng vi git HNO3 c, dng dung dch NaOH. B. Dng dung dch Na2CO3, dng dung dch HCl, dng dung dch NaOH. C. Dng dung dch Na2CO3, dng dung dch iot, dng Cu(OH)2. D. Dng phenolphtalein, dng HNO3 c, dng H2SO4 C. Cu 22: Cc amino axit no c th phn ng vi tt c cc cht trong nhm no sau y: A. Dung dch NaOH, dung dch HCl, C2H5OH, C2H5COOH. B. Dung dch NaOH, dung dch HCl, CH3OH, dung dch brom. C. Dung dch H2SO4, dung dch HNO3, CH3OC2H5, dung dch thuc tm. D. Dung dch Na2SO4, dung dch HNO3, CH3OH, dung dch brom. Cu 23: un nng 100ml dung dch mt aminoaxit 0,2 M tc dng va vi 80ml dung dch NaOH 0,25M. Sau phn ng ngi ta c cn dung dch thu c 2,5 g mui khan. Mt khc, ly 100g dung dch aminoaxit trn c nng 20,6 % phn ng va vi 400ml dung dch HCl 0,5 M. Cng thc phn t ca aminoaxit l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. CH3CH2CH(NH2)COOH. D. CH3COONH4 Cu 24: Khi t chy hon ton mt ng ng ca glixin thu c nH 2O : nCO2 = 7 : 6 (phn ng chy sinh ra kh N2). X c cng thc cu to l: A. H2NCH2COOH B. CH3CH(NH2)COOH C. NH2CH2CH2COOH. D. B v C ng. Cu 25: T l th tch CO2: H2O (hi) sinh ra khi t chy hon ton mt ng ng (X) ca glixin l 6:7 (phn ng chy sinh ra kh N2). (X) tc dng vi glixin cho sn phm l mt ipeptit (X) l: A. H2N CH2 CH2 COOH (1) B. C2H5 CH(NH2) COOH (3) C. CH3 CH(NH2) COOH(2) D. (1) v (2) ng Cu 26: Cho cc cht: 1) Natri glutamat, 2) Glixin hiroclorua, 3) Lizin, 4) Natri alanat, 5) Axit aspactic, 6) inatri glutamat v 7) Alanin. Cht phn ng c vi KOH l: A. 1, 2, 3, 5 v 7. B. Khng c cht no. C. 2, 3, 4, 5, v 6. D. 1, 3, 4, 5, 6 v 7. Cu 27: Hn hp X gm hai aminoaxit mch h no n chc ng ng k tip c phn trm khi lng oxi l 37,427%. Cho m gam X tc dng vi 600ml dung dch KOH 1M (d) sau khi phn ng kt thc c cn dung dch thu c 60,6gam cht rn khan. m c gi tr l A. 34,2 gam B.38,65 gam C. 26,7 gam D. 37,8 gam Cu 28: Khi thy phn cc pentapeptit di y : (1) : AlaGliAlaGluVal (2) : GluGliValAlaGlu (3) : AlaGliValValGlu (4) : GliGliValAlaAla pentapeptit no di y c th to ra ipeptit c khi lng phn t bng 188? A. (1), (3) B. (2),(3) C. (1),(4) D. (2),(4) Cu 29: Tripeptit X to thnh t 3 amino axit no n chc mch h v c phn t khi nh nht. Thy phn 55,44 gam X bng 200 ml dung dch NaOH 4,8M un nng, sau c cn dung dch thu c bao nhiu gam cht rn khan? CHUYN 3 N THI TN H 12 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT A. 89,520 gam B. 92,096 gam C. 93,618 gam D. 73,14 gam Cu 30: Hn hp M gm hai amino axit X v Y u cha 1 nhmCOOH v 1 nhm NH2 (t l mol nX:nY= 3:2). Cho 17,24 gam M tc dng ht vi 110 ml dung dch HCl 2M c dung dch Z. tc dng ht vi cc cht trong Z cn 210 ml dung dch KOH 2M. Cng thc cu to ca X v Y l : A. H2NC2H4COOH, H2NC3H6COOH B. H2NCH2COOH, H2NC2H4COOH C. H2NCH2COOH, H2NC3H6COOH D. H2NCH2COOH, H2NC4H8COOH Cu 31: Cho 1 ipeptit phn ng vi NaOH c un nng. H2NCH2CONHCH2COOH + 2NaOH Y+ H2O . Y l hp cht hu c g? A. Natri aminoaxetat B. Natri axetat C. Metylamin D. Amoniac Cu 32: Cho 0,012 mol aminoaxit X phn ng va vi HCl to ra 1,506 g mui Y. Cng thc cu to ca X l: A. H2NCH2COOH. B. H2NCH2CH(NH2)COOH. C. H2NCH2CH2COOH. D. HOOCCH2CH2CH(NH2)COOH. Cu 33: un nng cht H2NCH2CONHCH(CH3)CONHCH2COOH trong dung dch NaOH (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2NCH2 COOH, H2NCH(CH3)COOH. B. H2NCH2 COOH, H2NCH2CH2COOH. C. H2NCH2 COONa, H2NCH(CH3)COONa D. H2NCH2 COONa, H2NCH2CH2COONa Cu 34: trung ho 200 ml dung dch aminoaxit M 0,5M cn 100 gam dung dch Na0H 8%, c cn dung dch sau phn ng c 16,3 gam mui khan. M c cng thc cu to: A. H2NCH2 COOH B. H2NCH(COOH)2 C. H2NCH2CH(COOH)2 D. (H2N)2CHCOOH Cu 35: Cho cc dung dch ring bit sau : ClH3NCH2CH2NH3Cl, C6H5ONa, CH3COOH, NaOOCCH2 CH2CH(NH2)COONa, H2NCH2CH2CH(NH2)COOH, H2NCH2COONa, Na2CO3, NaOOCCOONa, KNO2. S lng cc dung dch c pH>7 l : A. 5 B. 6 C. 7 D. 8 Cu 36: Cho 1ml anbumin (lng trng trng) vo mt ng nghim, thm vo 0,5ml HNO3 c. Hin tng quan st c l: A. dung dch chuyn t khng mu thnh mu vng. B. dung dch chuyn t khng mu thnh mu da cam. C. dung dch chuyn t khng mu thnh mu xanh tm. D. dung dch chuyn t khng mu thnh mu en. Cu 37: Hp cht hu c A c M = 89 cha C, H, O, N. Hp cht A va tc dng vi NaOH, va tc dng vi HCl, c tham gia phn ng trng ngng. A c trong t nhin. Cng thc cu to thu gn ca A l: A. H2NCH2CH2COOH B. CH3CH(NH2)COOH C. C3H7NHCOOH D. HCOO H3NCH3 Cu 38: Hp cht hu c X c cng thc tng qut CxHyOzNt c % N = 15,7303% ; %O = 35,9551%. Bit X tc dng HCl to mui c dng R(Oz) NH3Cl. Bit X c tnh lng tnh v tham gia phn ng trng ngng. Vy CTCT ca X l: A. H2N(CH2)2COOH ; CH3CH(NH2)COOH B. H2N (CH2)3 COOH ; CH3 CH2 CH(NH)2 COOH C. H2N CH = CH COOH ; CH2 = C(NH2) COOH D. Tt c u sai Cu 39: Mt hn hp (X) gm 2 aminoaxit c cng s mol. Ly m gam (X) cho phn ng vi H2SO4 th thu c 2 mui c khi lng bng m + 9,8g. Mt khc, ly cng khi lng m gam (X) phn ng vi NaOH to ra 2 mui c tng khi lng bng m + 3,3g. Xc nh s mol ca mi aminoaxit. Hai aminoaxit ny thuc loi aminoaxit trung tnh, baz hay axit? A. 0.05mol. mt aminoaxit trung tnh, 0.05 mol aminoaxit l axit B. 0.2mol. mt aminoaxit trung tnh, 0,2 mol aminoaxit l axit C. 0.1mol c hai l aminoaxit trung tnh D. 0.2mol. mt aminoaxit baz, mt aminoaxit l axit CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 13

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 40: Thy phn 73,8 gam mt peptit ch thu c 90 gam glixin (axit aminoaxetic). Peptit ban u l : A. Dipeptit B. Tripeptit C. Tetrapeptit D. Pentapeptit Cu 41: Mt poli peptit c to ra t glyxin v alanin c phn t khi 587 vC. Hi c bao nhiu mt xch to ra t glyxin v alanin trong chui peptit trn? A. 5 v 4 B. 2 v 6 C. 4 v 5 D. 4 v 4 Cu 42: t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2, H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l : (C=12; H=1; O=16; N=14) A. 59,20% v 40,80% B. 49,33% v 50,67% C. 39,47% v 60,53% D. 35,52% v 64,48% Cu 43: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 B. 26,05 C. 34,6 D. 35,5 Cu 44: Thy phn hon ton 14,6g mt ipeptit thin nhin X bng dung dch NaOH, thu c sn phm trong c 11,1g mt mui cha 20,72% Na v khi lng. Cng thc ca X l : A. H2N CH2 CO NH CH2 COOH. B. H2N CH(CH3) CO NH CH(CH3) COOH. C. H2N CH(CH3) CO NH CH2 COOH hoc H2N CH2 CO NH CH(CH3) COOH. D. H2N CH(C2H5) CO NH CH2 COOH hoc H2N CH2 CO NH CH(C2H5) COOH. Cu 45: Khi thu phn mt cht protein (A) ta thu c mt hn hp 3 amino axit k tip trong dy ng ng. Mi amino axit cha mt nhm amino, mt nhm cacboxyl. Nu t chy 0,2 mol hn hp 3 amino axit trn ri cho sn phm chy qua bnh ng dung dch NaOH c, khi lng bnh tng 32,8 g, bit rng sn phm chy c kh N2. Cc amino axit l: A.CH5O2N, C2H5O2N, C2H7O2N B.CH3O2N, C2H5O2N, C3H7O2N C.C2H5O2N, C3H7O2N, C4H9O2N D.C2H7O2N, C3H9O2N, C4H11O2N Cu 46: (X) l hp cht hu c c cng thc phn t C5H11O2N. un X vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca (X) l: A. CH3(CH2)4NO2 B. H2N CH2COO CH2 CH2 CH3 C. H2N CH2 COO CH(CH3)2 D.H2N CH2 CH2 COOC2H5 Cu 47: X l 1 amino axit ch c 1 nhm amino NH2 v 1 nhm cacboxyl COOH. Cho 66,75 gam X phn ng va vi HCl to ra 94,125 gam mui. Vy cng thc cu to ca X l : A. H2NCH2COOH B. H2NCH=CHCOOH C. H2NCH(CH3)COOH D. CH3CH(NH2)CH2COOH Cu 48: X l mt aminoaxit no ch cha 1 nhm NH2 v 1 nhm COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l: (C=12; H=1; O=16; N=14) A. H2N CH2 COOH B. CH3 CH(NH2) COOH C. C6H5 CH(NH2) COOH D. C3H7 CH(NH2) COOH Cu 49: X c cng thc phn t l C4H12O2N2. Cho 0,1 mol X tc dng vi 135 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 11,1 gam cht rn. X l: A. H2NC3H6COONH4 B. H2NCH2COONH3CH2CH3 C. H2NC2H4COONH3CH3 D. (H2N)2C3H7COOH Cu 50: Khi thy phn 1 protit X thu c hn hp gm 2 amino axit no k tip nhau trong dy ng ng. Bit mi cht u cha 1 nhm NH2 v 1 nhm COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d , thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2 aminoaxit l : A. H2NCH(CH3)COOH v C2H5CH(NH2)COOH B. H2NCH2COOH v H2NCH(CH3)COOH C. H2NCH(CH3)COOH v N2N[CH2]3COOH D. H2NCH2COOH v v H2NCH2CH2COOH Cu 51: X l mt tripeptit cu thnh t cc aminoaxit thit yu A, B v C (u c cu to mch thng). Kt qu phn tch cc aminoaxit A, B v C ny cho kt qu nh sau: CHUYN 3 N THI TN H BIN SON NGUYN NGC TUN 14

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cht %mC %mH %mO %mN M A 32,00 6,67 42,66 18,67 75 B 40,45 7,87 35,95 15,73 89 C 40,82 6,12 43,53 9,52 147 Khi thy phn khng hon ton X, ngi ta thu c hai phn t ipeptit l AC v CB. Vy cu to ca X l: A. GlyGluAla B. GlyLysVal C. LysValGly D. GluAlaGly Cu 52: Hn hp A gm 2 amino axit no mch h ng ng k tip , c cha 1 nhm amino v 1 nhm chc axit trong phn t. Ly 23,9 gam hn hp A cho tc dng vi 100 ml dung dch HCl 3,5M (c d). tc dng ht cc cht trong dung dch D cn dng 650 ml dung dch NaOH 1M. Cng thc hai cht trong hn hp A l : A. CH3CH(NH2)COOH, CH3CH2CH(NH2)COOH B. CH3CH2CH(NH2)COOH, CH3CH2CH2CH(NH2)COOH C. H2NCH2COOH, CH3CH(NH2)COOH D. CH3CH2CH2CH(NH2)COOH, CH3CH2CH2CH2CH(NH2)COOH Cu 53: Cc cht trong dy no sau y u c tnh lng tnh: A. H2NCH2COONa, ClH3NCH2COOH, NH2CH2COOH. B. H2NCH2COOH, H2NCH2COONH4, CH3COONH4. C. CH3COOCH3, H2NCH2COOCH3, ClH3NCH2CH2NH3Cl. D. ClH3NCH2COOH, NH2CH2COOCH3, H2N CH2COONH4 Cu 54: X,Y,Z l 3 amino axit no n chc mch h. t chy X thu c hn hp sn phm CO2, hi H2O v N2 trong VCO2 : VH2O = 8 : 9 . MY=1,1,136MX. Trong Z phn trm khi lng C l 54,96%. Peptit no di y c phn t khi l 273? A. XXX B. XZX C. XXY D.XZY Cu 55: Cht hu c X (cha C,H,O,N) c phn t khi l 89. X tc dng vi c HCl v NaOH. Khi cho 0,1 mol X tc dng vi dung dch NaOH d thu c 9,4 gam mui. X l : A. Axit amino propionic B. Axit amino propionic. C. Metyl aminoaxetat D. amoni acrylat Cu 56: X l tetrapeptit , Y tripeptit u to nn t 1 loi aminoaxit (Z) c 1 nhm COOH v 1 nhm NH2 v MX =1,3114 MY. Cho 0,12 mol pentapeptit to thnh t Z tc dng vi dung dch NaOH va sau c cn thu c bao nhiu cht rn khan? A. 75,0 gam B. 58,2 gam C. 66,6 gam D. 83,4 gam Cu 57: Cho s bin ha :
H X N2 O N Y a O NH a O H Z T C a 0O , t

X l 1 aminoaxit mch thng c 1 nhm NH2 v 1 nhm COOH, T l 1 ancol v % khi lng oxi trong T l 34,78%.M l este ca X v T c phn trm khi lng oxi l : A. 35,955% B. 27,350% C. 22,069% D. 18,497% Cu 58: Cho 0,02 mol cht X (X l mt amino axit) phn ng va ht vi 160 ml dd HCl 0,125M th to ra 3,67 g mui. Mt khc 4,41 gam X khi phn ng vi 1 lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l: A.HOOCCH(NH2)CH(NH2)COOH B.HOOCCH2CH2CH(NH2)COOH C.CH3CH2CH(NH2)COOH D.CH3CH2CH2CH(NH2)COOH Cu 59: Khi cho 3,0 g axit aminoaxetic tc dng ht vi dung dch HCOOH, khi lng mui to thnh l : A. 3,84g. B.3,88g. C.4,84g. D.4,76g. Cu 60: Hn hp A gm hai aminoaxit no cha mt chc amin, mt cha axit, lin tip nhau trong dy ng ng. Dng khng kh d t chy hon ton 3,21 g hn hp A. Hn hp thu c sau phn ng em lm kh c hn hp kh B. Cho B qua dung dch Ca(OH)2 d thu c 9,5 g kt tA. Phn trm s mol cc amino axit trong hn hp A ln lt l : A. 50% v 50% B. 62,5% v 37,5% C. 40% v 60% D.27,5% v 72,5% CHUYN 3 N THI TN H 15 BIN SON NGUYN NGC TUN

TRNG THPT NGUYN KHUYN TON V AMIN - AMINOAXIT Cu 61: tc dng va vi 29,94 gam hn hp X gm 1 s amino axit (ch c nhm chc COOH v NH2 , khng c nhm chc khc) cn 380 ml dung dch KOH 1M. Mt khc t chy 29,94 gam hn hp X cn 24,528 lt O2 (ktc) thu c m gam CO2; p gam H2O v 3,36 lt N2(ktc). a)m c gi tr l : A.39,60 gam B. 42,24 gam C. 52,80 gam D.38,72 gam b)p c gi tr l : A. 18,54 gam B. 18,72 gam C. 19,44 gam D. 20,16 gam Cu 62: Hn hp X gm 1 s amino axit no (ch c nhm chc COOH v NH2 , khng c nhm chc khc) c t l khi lng mO:mN=48:19. tc dng va vi 39,9 gam hn hp X cn 380 ml dung dch HCl 1M. Mt khc t chy 39,9 gam hn hp X cn 41,776 lt O2 (ktc) thu c m gam CO2. m c gi tr l : A. 66 gam B. 59,84 gam C. 61,60 gam D. 63,36 gam Cu 63: X v Y l 2 tetrapeptit, khi thy phn trong mi trng axit u thu c 2 loi amino axit no n chc mch h l A v B. Phn trm khi lng oxi trong X l 23,256% v trong Y l 24,24%. A v B ln lt l : A. alanin v valin B. glixin v alanin C. glixin v axit aminobutiric D. alanin v axit aminobutiric Cu 64: X v Y ln lt l tripeptit v tetrapeptit to thnh t 1 loi aminoaxit no mch h c 1 nhm NH2 v 1 nhm COOH. t chy 0,1 mol Y thu c CO2, H2O v N2 trong tng khi lng CO2 v H2O l 47,8 gam. Nu t 0,1 mol X cn bao nhiu mol O2? A. 0,560 mol B. 0,896 mol C. 0,675 mol D. 0,375 mol Cu 65: X l hexapeptit AlaGliAlaValGliVal. Y l tetrapeptit GliAlaGliGlu Thy phn m gam hn hp gm X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30 gam glixin v 28,48 gam alanin. m c gi tr l : A. 87,4 gam B. 73,4 gam C. 77,6 gam D. 83,2 gam Cu 66: A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c l 19,346%. Cng thc ca A l : A. HOOCCH2CH2CH(NH2)COOH B. CH3CH2CH(NH2)COOH C. HOOCCH2CH2 CH2CH(NH2)COOH D. CH3CH(NH2)COOH Cu 67: Cht hu c A c 1 nhm amino v 1 chc este. Hm lng nit trong A l 15,73%.X phng ha m gam cht A, hi ancol bay ra cho i qua CuO nung nng c anehit B. Cho B thc hin phn ng trng bc thy c 16,2 gam Ag kt tA. Gi tr ca m l : A. 7,725 gam B. 3,375 gam C.6,675 gam D. 5,625 gam Cu 68: X l 1 pentapeptit cu to t 1 amino axit no mch h c 1 nhm COOH v 1 nhm NH2 (A), A c tng phn trm khi lng oxi v nit l 51,685%. Khi thy phn ht m gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6 gam ipeptit v 88,11 gam A. m c gi tr l : A. 149,2 gam B. 167,85 gam C. 156,66 gam D. 141,74 gam Cu 69: Thy phn ht 1 lng pentapeptit trong mi trng axit thu c 32,88 gam AlaGliAlaGli; 10,85 gam AlaGliAla; 16,24 gam AlaGliGli; 26,28 gam AlaGli; 8,9 gam Alanin cn li l GliGli v Glixin. T l s mol GliGli:Gli l 5:4. Tng khi lng GliGli v Glixin trong hn hp sn phm l : A. 43,2 gam B. 32,4 gam C. 19,44 gam D. 28,8 gam Cu 70: Mt peptit X to thnh t 1 aminoaxit no mch h c 1 nhm COOH v 1 nhm NH2 trong phn trm khi lng oxi l 19,324%. X l : A. ipeptit B. tripeptit C. tetrapeptit D. pentapeptit Cu 71: Khi thy phn 500 gam mt polipeptit thu c 170 gam alanin. Nu polipeptit c khi lng phn t l 50000 th c bao nhiu mt xch ca alanin? A. 175 B. 170 C. 191 D.210 ---------------------Ht----------------------

CHUYN 3 N THI TN H

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TRNG THPT NGUYN KHUYN

TON V AMIN - AMINOAXIT

CHUYN 3 N THI TN H

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