Cng ty CP ho cht Phc Lm

Phng th nghim KCS

2. XC NH CC THNH PHN TRONG QUNG APATT 2.2.1 Xc nh hm lng P2O5 trong qung apatit (Phng php th tch Molipdat) 2.2.1.1. Nguyn tc: Ph mu Apatit bng dd HNO3 chuyn hon ton cc mui photphat trong mu vo dd di dng H3PO4 Ca5 ( PO4 )3 F + 10 HNO3 = 5Ca ( NO3 ) 2 + 3H 3 PO4 + HF - Sau kt ta hon ton gc Photphat di dng kt ta vng Amoni Photphat molipdat trong mi trng axid dd nng H 3 PO4 + ( NH 4 ) 2 MoO4 + 21HNO3 = ( NH 4 )3 H 4 P ( Mo2O7 ) 6 (mauvang ) + 21NH 4 NO3 +10 H 2O Lc ra kt ta cho sch axid, ho tan kt ta bng 1 lng NaOH tiu chun 0,14N cho d chnh xc ( NH 4 )3 H 4 P ( Mo2O7 ) 6 + NaOH = 23 Na2 MoO4 + ( NH 4 ) 2 MoO4 + 2( NH 4 ) 2 HPO4 +26 H 2O Chun lng kim d bng dd H2SO4 tiu chun 0,14N theo ch th PP, im tng ng dd mt mu hng H2SO4 + NaOH = Na2SO4 +2H2O 2.2.1.2. Ho cht, dng c: 2.2.1.2.1 Ho cht: - Dung dch NaOH 0,14N - Dung dch H2SO4 0,14N - HNO3 2/3, NH4NO3 30% - Dung dch (NH4)2MoO4 7,5 % - Ch th PP 0,1% cn - Dung dch NH4OH 1:1 - Dung dch Citrat Amon (17% 2.2.1.2.2 Dng c - Cc thu tinh chu nhit 250ml - Bnh col 250ml - Bnh nh mc 250ml - ng ht c bu 10ml - Mt knh ng h 8cm Ngy 21/03/2011

Cng ty CP ho cht Phc Lm - ng ong chia vch 50ml - Cn phn tch, bp in - Buret chun 25ml, 50ml - Phu lc 8 cm - Bng + giy lc v nt 2.2.1.3. Tin hnh:

Phng th nghim KCS

Cn chnh xc 1g ( 0,0001)g mu qung apatt nghin mn v sy kh 105oC chuyn vo bnh col chu nhit 250ml. Tm t mu bng nc ct + 30ml HNO3 2/3, y cc bng mt knh ng h, un si nh mu 30 pht. Ly ra ngui trng mt knh ng h. Chuyn ton b vo bnh nn 250ml, nh mc ti vch - xc trn u. em lc kh qua giy lc thng b 2 ln nc lc u trng ra dng c. Dng ng ht c bu ht chnh xc 10ml dd lc chuyn vo bnh col 250. Dng NH4OH 1:1 trung ho n kt ta trng + 2ml dd Amon Citrat 17% + 15ml NH4NO3 30% (NH4)2MoO4 7,5% ( 30ml), lc k 30 pht lng 1: 2 gi. em lc kt ta qua bng lc v giy lc nt, ra kt ta n ht phn ng axid (th 20ml nc ra bng 1 git NaOH 0,14N + 3 git ch th PP 0,1% m mu hng khng mt i trong 20ml nc ra l sch). Chuyn giy lc v kt ta vo bnh col va lm kt ta trn, dng NaOH tiu chun 0,14N ho tan kt ta vi lng d chnh xc sau thm vi git ch th PP 0,1% v chun lng d NaOH bng H2SO4 tiu chun 0,14N. im tng ng dd mt mu hng. Ghi th tch NaOH v tiu tn trong qu trnh chun + Tnh kt qu: % P2O5 = mDgP2O5 ( NV ) NaOH ( NV ) H 2 SO4 Vdm 100 G Vxd mDg P2O5 = 142 46 1000

Ngy 21/03/2011