THI TH I HC ( thi c 06 trang)

THI TH TUYN SINH I HC NM 2012 Mn: HA HC; Khi A, B Thi gian lm bi: 90 pht, khng k thi gian pht Thi ngy ... Thng... Nm .
M thi 2012 BBB

H, tn th sinh: S bo danh:.

Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n 40) Cu 1: un nng m gam hn hp c s mol bng nhau ca glucoz, fructoz, saccaroz, mantoz trong dung dch H2SO4 long. Sau phn ng thm lng d dung dch AgNO 3 trong NH3 to ra 30,456 gam Ag. Vy m c gi tr l: A. 24,5340 gam B. 29,4408 gam C. 36,8010 gam D. 12,2670 gam Cu 2: t chy hon ton 5,1 gam cht hu c A cn va 10,08 lt O 2 (iu kin tiu chun). Hp th ht sn phm chy (ch gm CO2 v H2O) vo nc vi trong c 20 gam kt ta. Lc b kt ta ri un nng nc lc li c 5 gam kt ta. Bit A khng tc dng vi Na. Vy A c th c bao nhiu cng thc cu to ?. A. 14 B. 15 C. 16 D. 17 Cu 3: Cho mt lung hi nc qua than , sau khi loi ht hi nc thu c hn hp kh X gm CO, H2 v CO2. Trn hn hp X vi oxi d vo bnh kn dung tch khng i thu c hn hp kh A (0 0C, P1 atm). t chy hon ton A ri a nhit v 00C th p sut trong bnh (hn hp B) l P 2 = 0,5P1. Nu cho NaOH rn vo bnh hp th ht kh CO2, cn li mt kh duy nht 00C c p sut P3 = 0,3P1. Cn bao nhiu kg than c cha 4% tp cht tr thu c 1000m3 hn hp X o 136,50C v 22,4 atm . Bit rng c 90% cacbon b t chy: A. 370 kg B. 300 kg C. 276 kg D. 341 kg Cu 4: Cho cc pht biu sau: (a) K2Cr2O7 + KI + H2SO4 I2 + Cc cht cn li l K2SO4, Cr2(SO4)3, H2O. (b) FeSO4 + K2Cr2O7 + H2SO4 Fe2(SO4)3 + Cc cht cn li l K2SO4, Cr2(SO4)3, H2O. (c) As2S3 + HNO3 + H2O H3AsO4 + Cc cht cn li l NO, H2S. (d) Ca3(PO4)2 + SiO2 + C CaSiO3 + Cc cht cn li l P, CO. (e) Na2SO3 + KMnO4 + H2O Na2SO4 + Cc cht cn li l MnO2, KOH. (f) CaOCl2 + CO2 + H2O CaCO3 + Cc cht cn li l CaCl2, HClO. (g) F2 + NaOH NaF + H2O + Cht cn li l OF2. (h) H2O2 + KMnO4 + H2SO4 MnSO4 + Cc cht cn li O2, H2O, K2SO4. S pht biu sai l: A. 4 B. 3 C. 2 D. 1 Cu 5: Cho 226,75 gam hn hp gm axit glutamic, glyxin, alanin, valin, tyrosin, lysin v metyl salixilat c t l hn hp cc cht u bng nhau v s mol, tc dng vi 5 lt dung dch NaOH 0,7M. Sau phn ng xy ra hon ton, c cn thu c khi lng cht rn khan l: A. 278,25 gam B. 326,25 gam C. 318,25 gam D. 329,75 gam Cu 6: Hn hp X c FeS2 v MS (c t l mol 1 : 1, M c ha tr khng i). Cho 6,51 gam X tc dng hon ton vi dung dch HNO3 d c dung dch Y v 0,59 mol hn hp kh Z gm (NO v NO2) c khi lng 26,34 gam. Thm dung dch BaCl2 d vo Y c m gam kt ta trng khng tan trong dung dch axit d trn. Tnh gi tr m v thnh phn phn trm khi lng MS trong hn hp X l: A. 20,97 v 44,7% B. 20,97 v 55,3% C. 6,99 v 44,7% D. 6,99 v 55,3% Cu 7: X c cng thc l C4H14O3N2 khi cho X tc dng vi dung dch KOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S cng thc cu to ph hp ca X l ?. A. 4 B. 5 C. 6 D. 7 Cu 8: Hn hp A gm hai ru. Thc hin phn ng ete hn hp A, thu c hn hp gm 3 ete n chc. Ly 0,1 mol mt trong ba ete ny em t chy ri cho sn phm chy ny hp th vo bnh ng dung dch nc vi c ha tan 0,3 mol Ca(OH)2. Khi lng bnh tng 24,8 gam. Lc kt ta trong bnh, un nng phn dung dch thu c thm 10 gam kt ta na. Cc phn ng xy ra hon ton. Tm hai ru trong hn hp A. A. Methanol v Propenol B. Methanol v Penanol C. Propenol v Butanol D. Penanol v Butanol
Trang 1/6 M thi 2012 BBB

Cu 9: X phng ha hon ton 95 kg gam lipit cn 13,7 kg NaOH, sau phn ng ngi ta thm mui n vo v lm lnh thy tch ra m kg mui. Dung dch cn li c loi tp cht, c c ri li tm tch mui n thu c 10,12 kg glixerol. em ton b mui thu c p cng cc ph gia th c bao nhiu gam x phng (gi s trong x phng cc cht ph gia chim 40% v khi lng) ?. A. 53,58 gam B. 54,57 gam C. 53,85 gam D. 58,35 gam Cu 10: Cho hai nguyn t A, B (Z A < ZB) cng nm trong mt phn nhm chnh ca hai chu k lin tip. Tng s in tch ht nhn ca A v B bng 24. Hai nguyn t C, D (Z C < ZD) ng k tip nhau trong mt chu k, tng s khi ca D v C bng 51, s ntron ca D ln hn C l 2. S electron ca C bng s ntron ca n. Th t sp xp cc nguyn t trn theo chiu tng dn tnh kh l: A. A < D < B < C B. A < B < C < D C. A < C < B < D D. A < B < D < C Cu 11: Cho cc pht biu sau: (a) Thc hin phn ng este ha gia butan-1,2-4-triol v hn hp axit axetic, axit fomic th s dn xut Trieste ti a thu c l 8. (b) iu ch 3-etylpental-3-ol ta c th dng anken thch hp l 3-etylpent-2en. (c) Ta c th dng t nht 4 phn ng t nhm cacbua iu ch but-1,3-ien. (d) Ta c th dng t nht 2 phn ng tch anilin khi hn hp anilin, benzen, phenol. (e) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng l: A. 2 B. 3 C. 4 D. 5 Cu 12: Hp cht hu c X c cng thc phn t C 3H7O2N tc dng c vi c dung dch NaOH v dung dch HCl. S lng cng thc cu to ph hp vi tnh cht X l: A. 7 B. 8 C. 9 D. 10 Cu 13: Thc hin phn ng crackinh m gam isobutan, thu c hn hp A gm cc hirocacbon. Dn hn hp A qua bnh ng nc brom c ha tan 11,2 gam. Nc brom mt mu ht, c 7,392 lt hn hp kh B (iu kin tiu chun) gm cc hirocacbon thot ra. T khi hi B so vi hiro bng 117/7. Gi tr ca m l: A. 13,97 gam B. 8,46 gam C. 25 gam D. 14,11 gam Cu 14: C bao nhiu ng phn l dn xut benzen, c cng thc phn t C 8H8O2. C kh nng tham gia phn ng trng gng v tc dng c vi natri kim loi. A. 15 B. 16 C. 17 D. 18 Cu 15: Insulin (dng cha bnh tiu ng) l mt protein c cha 3,2% lu hunh (v khi lng). Thy phn hon ton insulin c mt hn hp cc amino axit, trong ch c xistein l amino axit c cha lu hunh trong phn t. Tnh phn t khi ca insulin. Bit cng thc cu to ca xistein l HSCH 2CH(NH2)COOH, v thy phn hon ton 1 mol insulin thu c hn hp cc amino axit, trong c 6 mol xistein. A. 3000 B. 6000 C. 9000 D. 12000 Cu 16: t chy hon ton 0,012 mol cht hu c A mch h cn dng 50,4 lt khng kh. Sau phn ng cho ton b sn phm chy gm CO2, H2O, N2 hp th hon ton vo bnh ng dung dch Ba(OH)2 d thy c khi lng bnh tng 2,34 gam v c 7,092 gam kt ta. Kh thot ra khi bnh c th tch 4,1664 lt. Bit rng A va tc dng vi HCl va tc dng c vi NaOH. C bao nhiu cng thc cu to ca A tha bi. (cc kh o iu kin tiu chun). A. 5 B. 6 C. 7 D. 8 Cu 17: Oxi ha m gam ru etylic bng CuO (xt, to) t nng trong khng kh, thu c 33 gam hn hp gm anehit, axit, ru cha phn ng v nc. Hn hp ny tc dng vi Na d sinh ra 8,4 lt kh hiro ( iu kin tiu chun) v thu c 29 gam mui. Tnh m ca ru etylic: A. 23 gam B. 46 gam C. 2,3 gam D. 4,6 gam Cu 18: Ha tan ht 35,84 gam hn hp Fe v Fe2O3 bng dung dch HNO3 1M ti thiu thu c dung dch A trong s mol Fe(NO3)2 bng 4,2 ln Fe(NO3)3 v V lt kh NO (iu kin tiu chun). Tnh th tch ca HNO3. A. 1,24 lt B. 1,5 lt C. 1,6 lt D. 1,8 lt Cu 19: Thc hin cc th nghim sau: (a) Sc kh SO2 vo dung dch KMnO4 (b) Cho MnO2 vo dung dch HCl c, nng (c) Sc kh SO2 vo dung dch H2S (d) Cho Fe2O3 vo dung dch H2SO4 c nng (e) Sc hn hp kh NO2 v O2 vo nc (g) Cho SiO2 vo dung dch HF S th nghim c phn ng oxi ha kh xy ra l: A. 3 B. 4 C. 5 D. 6 Cu 20: Khi chng ct nha than , ngi ta thu c mt phn on cha phenol v anilin ha tan trong ankylbenzen (dung dch A). Sc kh HCl vo 150ml dung dch A th thu c 1,9425 gam kt ta. Nh t t nc brom vo 150ml dung dch A v lc k cho n khi ngng to m gam kt ta trng th ht 450 gam nc brom 3,2%. Tnh nng mol ca anilin v phenol trong dung dch A v m l: A. CM phenol = 0,1M; CM anilin = 0,2M v 29,79 B. CM phenol = 0,2M; CM anilin = 0,1M v 29,79 C. CM phenol = 0,1M; CM anilin = 0,2M v 9,93 D. CM phenol = 0,2M; CM anilin = 0,1M v 9,93 Trang 2/6 M thi 2012 BBB

Cu 21: Cho hn hp A gm Al v Fe3O4. Nung A nhit cao phn ng xy ra hon ton thu c hn hp B. Nghin nh hn hp B, trn u, chia lm hai phn khng bng nhau. - Phn 1 (phn t): Tc dng vi dung dch NaOH d thu c 1,176 lt kh H2. Tch ring cht khng tan em ha tan trong dung dch HCl d thu c 1,008 lt kh. - Phn 2 (phn nhiu): Cho tc dng vi dung dch HCl d thu c 6,552 lt kh. Tnh thnh phn phn trm khi lng cc cht c trong hn hp A. (th tch cc kh o iu kin tiu chun). A. 36,78% v 63,22% B. 35,76% v 64,24% C. 25,93% v 74,07% D. 45,56% v 54,44% Cu 22: Cho m gam hn hp gm X gm cc cht metylisopropylamin, pentylamin, etylamin, hexylamin, metylamin, isopropylamin, amoniac. em t chy hon ton hn hp trn thu c 1,8144 lt kh CO 2 v x gam H2O. Vy m v x bng bao nhiu ?. (bit s mol cc cht metylisopropylamin, pentylamin, etylamin, hexylamin, metylamin, amoniac u bng nhau.) A. 0,531 v 0,792 B. 1,593 v 2,187 C. 1,593 v 4,372 D. 0,531 v 1,458 Cu 23: Cho 4,93 gam hn hp gm Mg v Zn vo mt cc cha 430ml dung dch H 2SO4 0,5M (long). Sau khi phn ng hon ton thm tip vo cc 0,6 lt dung dch hn hp gm Ba(OH) 2 0,05M v NaOH 0,7M khuy u cho phn ng hon ton, ri lc ly kt ta v nung n khi lng khng i th thu c 13,04 gam cht rn. Khi lng mi kim loi trong hn hp ban u l: A. mMg = 2,4 gam v mZn = 2,53 gam B. mMg = 3,63 gam v mZn = 1,3 gam C. mMg = 1,3 gam v mZn = 3,63 gam D. mMg = 2,53 gam v mZn = 2,4 gam Cu 24: Cho cc pht biu sau: (a) Ion Be2+ c cu hnh electron ging kh him Ne. (b) Cc ion v nguyn t Na+, F- v Ne c c im chung l c cng cu hnh electron. (c) Ion K+ c cu hnh electron ging kh him Ar. (d) Nguyn t K c cu hnh electron l 1s22s22p63s23p64s1. (e) Cc ng v ca nguyn t ha hc c phn bit bi yu t l s ntron. S pht biu ng l: A. 2 B. 5 C. 4 D. 3 Cu 25: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. Gi tr ca m l: A. 68,1 gam B. 64,86 gam C. 77,04 gam D. 65,13 gam Cu 26: Cho dung dch KI tc dng vi cc cht sau: Cl2, Br2, S, H2SO4 (c), H2O2, AgNO3, HgSO4, FeCl3, O2, O3. S cht xy ra phn ng l: A. 6 B. 8 C. 7 D. 9 Cu 27: Ha tan hn hp gm FeCl3, Fe(NO3)3, CuCl2 v Cu(NO3)2 vo nc thnh 200 ml dung dch A. in phn 100ml dung dch A cho n khi ht ion Cl- th dng in phn thy khi lng catot tng 6,4 gam, ng thi khi lng dung dch gim 17,05 gam. Dung dch sau in phn phn ng vi NaOH va thu c kt ta B, nung B trong khng kh n khi lng khng i thu c 16 gam hn hp hai oxit kim loi. C cn 100ml dung dch A cn li thu c m gam hn hp mui khan. Gi tr ca m l: A. 80 gam B. 90 gam C. 40 gam D. 75 gam Cu 28: Thc hin cc th nghim sau: (a) Nhit phn AgNO3. (b) Nung FeS 2 trong khng kh. (c) Nhit phn KNO3. (d) Cho dung dch CuSO4 vo dung dch NH3 (d). (e) Cho Fe vo dung dch CuSO4. (g) Cho Zn vo dung dch FeCl3 (d). (h) Nung Ag2S trong khng kh. (i) Cho Ba vo dung dch CuSO4. (j) Cho Al vo dung dch FeCl3 (d) (k) Nhit phn Cu(NO3)2. S th nghim thu c kim loi sau khi cc phn ng kt thc l: A. 3 B. 4 C. 5 D. 2 Cu 29: Ha tan hon ton hn hp MgO, Zn(OH)2, Al, FeCO3, Cu(OH)2, Fe trong dung dch H2SO4 long d, sau phn ng thu c dung dch X. Cho vo dung dch X mt lng Ba(OH) 2 d thu c kt ta Y. Nung Y trong khng kh n khi lng khng i c hn hp rn Z, sau dn lung kh CO d ( nhit cao) t t i qua Z n khi phn ng xy ra hon ton thu c cht rn G. Trong G cha. A. BaO, Fe, Cu, Mg, Al2O3 B. MgO, BaSO4, Fe, Cu C. MgO, BaSO4, Fe, Cu, ZnO D. BaSO4, MgO, Zn, Fe, Cu Cu 30: Cho cc phn ng sau: 0 0 (1) NH4Cl + NaNO2 t (2) F2 + H2O (3) CaOCl2 + HCl (c) t 0 (4) Fe2O3 + HI (5) AgBr as (6) Ca3(PO4)2 + SiO2 + C t 0 (7) KNO3 + C + S t (8) AgNO3 + Fe(NO3)2 (9) SiO2 + HF S phn ng m to c n cht sau phn ng l: A. 6 B. 7 C. 8 D. 9 Trang 3/6 M thi 2012 BBB

Cu 31: X l hn hp gm axit cacboxylic n chc Y v ancol no Z, tt c u mch h v c cng s C trong phn t. t chy hon ton 0,4 mol X cn va 50,4 gam O2, sau phn ng thu c 26,88 lt kh CO2 ( iu kin tiu chun ) v 23,4 gam H2O. Este ha cng 0,4 mol X trn c th thu c khi lng este ln nht l: A. 19,50 gam B. 23,00 gam C. 21,33 gam D. 25,00 gam Cu 32: Cho cc pht biu sau: (a) Photpho trng c cu trc mng tinh th phn t cn photpho c cu trc polime. (b) Kh than t c sn xut bng cch cho hi nc i qua than nung . (c) Hai phng php ch yu ch ha du m l rifominh v crckinh. (d) Anehit va th hin tnh oxi ha va th hin tnh kh. (e) Este c nhit si thp hn so vi axit v ancol c cng s nguyn t C. (f) Trong phn t saccaroz khng c nhm OH hemiaxetal. (g) Lu hunh v photpho u bc chy khi tip xc CrO3. S pht biu ng l : A. 4 B. 5 C. 6 D. 7 Cu 33: Hn hp X gm hai cht hu c A v B ch cha mt loi nhm chc (t l mol tng ng l 1 : 1). Cho m gam X tc dng ht vi NaOH thu c mt mui ca axit hu c n chc v hn hp hai ancol, tch nc hon ton hai ancol ny iu kin thch hp ch thu c mt anken lm mt mu 37,76 gam Br 2. Bit A, B cha khng qu 5 nguyn t C trong phn t. Gi tr ca m: A. 10,384 gam B. 41,536 gam C. 20,768 gam D. 31,152 gam Cu 34: un si a gam mt triglixerit (X) vi dung dch KOH n khi phn ng hon ton c 0,92 gam glixerol v hn hp Y gm m gam mui ca axit oleic vi 3,18 gam mui ca axit linoleic. Gi tr ca m l: A. 3,2 gam B. 6,4 gam C. 5,7 gam D. 4,6 gam Cu 35: Tng h s cn bng ca cc cht tham gia trong phn ng sau l: Zn + H2SO4 ZnSO4 + S + H2S + SO2 + H2O Bit t l mol ca S : H2S : SO2 = 3a : 2b : 5c A. 12a + 10b + 10c B. 21a + 18b + 15c C. 27a + 22b + 20c D. 30a + 26b + 25c Cu 36: Cho 50ml dung dch Fe2(SO4)3 a mol/l tc dng vi 100ml dung dch Ba(OH) 2 b mol/l. Kt ta thu c sau khi lm kh v nung nhit cao th cn c 0,859 gam. Nc lc cn li phn ng vi 100ml dung dch H2SO4 0,05 mol/l to ra kt ta. Sau khi phn ng kt ta cn c 0,466 gam. Gi tr ca a v b l: A. 0,02 v 0,05 B. 0,015 v 0,025 C. 0,02 v 0,02 D. 0,02 v 0,08 Cu 37: Cho cc pht biu sau: (a) Stiren l mt cht lng khng mu, nh hn nc v khng tan trong nc. (b) ng dng axeton c th tng hp cht hu c bisphenol-A, ioofom. (c) Tinh bt, saccaroz, glucoz ln lt l polisacarit, isaccarit v monosaccrit. (d) T nilon-6 c th iu ch bng c phn ng trng hp hoc phn ng trng ngng. (e) Tam hp propin trong iu kin thch hp s to ra iso propyl benzen. (f) Cc dung dch phn ng c vi Cu(OH)2 nhit thng l axit axetic. S pht biu ng l: A. 3 B. 4 C. 5 D. 6 Cu 38: Cho m gam hn hp hai kim loi Fe, Cu (trong Fe chim 30% v khi lng) vo 50ml dung dch HNO3 nng 63% (d = 1,38 g/ml) un nng, khuy u hn hp ti cc phn ng hon ton thu c rn A cn nng 0,75m, dung dch B v 6,72 lt hn hp kh NO2 v NO ( iu kin tiu chun). Hi c cn dung dch B th thu c bao nhiu gam mui khan ?. (gi s trong qu trnh un nng HNO3 bay hi khng ng k). A. 37,8 gam B. 35,1 gam C. 45 gam D. 36 gam Cu 39: Hn hp kh X gm metylamin, etylamin, trimetylamin v hirocacbon A. t chy hon ton V ml hn hp X bng mt lng oxi va , thu c V1 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li V2 ml kh (cc th tch kh v hi o cng iu kin ). Bit V = V1 2V2. Vy cng thc phn t ca hirocacbon A l: A. C3H4 B. C3H8 C. C4H8 D. C2H4 Cu 40: Cho cc s sau: xt LiAlH4 H2SO4() 1700C (1) CH3OH + CO X (duy nht) Y Z + O2, PdCl2, CuCl2 M 0 KOH/ancol (2) Cumen + Br2/as C9H11Br C9H10 Br2, 500 C E (C9H9Br) Na CuCl2 15000C + HCl/HgCl2 (3) CH4 A B C D CH3OH NH3 (4) Glyxin H K HCl bo ha Hy cho bit cht M, E, D v K l: A. M l C2H2, E l 1-brom-2-phenylpropen, D l Cao su Buna v K l CH3CH(NH2)COOCH3. B. M l CH3CHO, E l 3-brom-2-phenylpropen, D l Cao su Buna v K l CH3CH(NH2)COONH4. C. M l C2H2, E l 1-brom-2-phenylpropen, D l Cao su cloropren. v K l CH3CH(NH2)COONH4. D. M l CH3CHO, E l 3-brom-2-phenylpropen, D l Cao su cloropren v K l CH3CH(NH2)COOCH3 Trang 4/6 M thi 2012 BBB

II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh chun (10 cu, t cu 41 n 50)
Cu 41: Ha tan 4m gam hn hp A gm Cu, CuO, Cu2O trong dung dch axit H2SO4 long thy cn m gam kim loi, cng m gam hn hp A ha tan vo axit HCl m c, nng th 3,4m gam tan. Bit trong axit HCl m c, nng Cu2O tan to thnh H.[CuCl2]. Tnh thnh phn phn trm ca cc cht trong hn hp ln lt l ?. A. 18,5%; 58,5% v 23% B. 15%; 62,5% v 22,5% C. 18,5%; 62,5% v 19% D. 15%; 58,5% v 26,5% Cu 42: Cho cc pht biu sau: (a) Cng thc ha hc ca bng thch (cryolit) l Na3AlF6 v 3NaF.AlF3. (b) Thnh phn chnh ca t st l cao lanh c cng thc l Al2O3.2SiO2.2H2O. (c) Trong sn xut gang thp c phn ng x. Cng thc phn t ca x l CaSiO 3. (d) Cng thc ng ca qung malachit l Cu(OH)2.Cu(CO)3. S pht biu ng l: A. 1 B. 2 C. 3 D. 4 Cu 43: Cho glucoz ln men thnh ru etylic vi hiu sut 90%. Hp th ton b sn phm kh thot ra vo 1 lt dung dch NaOH 2M (d = 1,05 g/ml) thu c dung dch cha hai mui c nng 12,27%. Khi lng glucoz ng l: A. 150 gam B. 121,5 gam C. 300 gam D. 243 gam Cu 44: Hn hp X gm Al, Fe v Mg. Cho 15,5 gam hn hp X vo 1 lt dung dch HNO 3 2M. Sau phn ng thu c dung dch Y v 8,96 lt NO duy nht (iu kin tiu chun). Mt khc cho 0,05 mol X vo 500ml dung dch H2SO4 0,5M thu c dung dch Z. Cho dung dch Z tc dng vi dung dch NaOH d ri ly ton b kt ta thu c em nung nng trong khng kh n khi lng khng i thu c 2 gam cht rn. Thnh phn % khi lng mi kim loi trong X ln lt l: A. 36,13%; 11,61% v 52,26% B. 17,42%; 46,45% v 36,13% C. 52,26%; 36,13% v 11,61% D. 17,42%; 36,13% v 46,45% Cu 45: Cho hn hp gm Fe3O4 v Cu, c s mol mi cht l 0,15 vo dung dch HCl va . Sau phn ng thu c dung dch X. Cho dung dch X tc dng vi dung dch AgNO 3 d th thu c m gam kt ta. Gi tr ca m l: A. 172,2 gam B. 48,6 gam C. 220,8 gam D. 121,2 gam Cu 46: Khi cho axit benzonic tc dng vi tng cht KOH; Al; HNO3 (c) / H2SO4 (c); PCl5; dung dch KMnO4, nng; LiAlH4; CaO; Na2CO3; dung dch NH3; H2, xc tc Ni, 200C, 1atm; H2SO4 bc khi; CH3Cl, AlCl3. C bao nhiu phn ng khng xy ra l: A. 2 B. 3 C. 4 D. 5 Cu 47: Cho m gam hn hp gm hai cht X v Y u thuc dy ng ng ca axit metacrylic tc dng vi 300ml dung dch Na2CO3 0,5M. Thm tip vo dung dch HCl 1M cho n khi kh CO 2 ngng thot ra th thy tiu tn ht 100m. Mt khc, t chy hon ton m gam hn hp A ri dn sn phm chy qua bnh I cha dung dch H2SO4 c, sau bnh II cha dung dch NaOH c th thy tng khi lng ca bnh II nhiu hn bnh I l 20,5 gam. Gi tr ca m l: A. 12,15 gam B. 15,1 gam C. 15,5 gam D. 12,05 gam Cu 48: Cho 150ml dung dch Ba(OH) 2 1M vo 250ml dung dch Al2(SO4)3 xM c 42,75 gam kt ta. Thm tip 200ml dung dch Ba(OH)2 1M vo hn hp phn ng th lng kt ta thu c l 94,2375 gam. Gi tr ca x l: A. 0,25 B. 0,15 C. 0,3 D. 0,45 Cu 49: Cht bo A c ch s axit v ch s x phng ha ln lt l 9,8 v 210. Tnh khi lng x phng thu c khi x phng ha hon ton 300 gam cht bo ny bng dung dch KOH va . A. 329,165 gam B. 329,242 gam C. 295,565 gam D. 272,465 gam Cu 50: t chy hon ton 3,2 gam sunfua kim loi M2S (kim loi M trong hp cht th hin s oxi ha + 1 v + 2) trong oxi. Sn phm rn thu c em ha tan ht trong mt lng va dung dch H 2SO4 39,2% nhn c dung dch mui c nng 48,5%. em lm lnh dung dch mui ny thy tch ra 2,5 gam tinh th, khi nng mui gim cn 44,9%. Tm cng thc tinh th mui tch ra. A. MgSO4.5H2O B. CuSO4.3H2O C. MgSO4.3H2O D. CuSO4.5H2O B. Theo chng trnh nng cao (10 cu, t cu 51 n 60) Cu 51: t chy hon ton mt este n chc, mch h X, thu c th tch kh CO 2 bng 8/9 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 300 ml dung dch NaOH 0,65M thu c dung dch Y. C cn Y thu c 12,93 gam cht rn khan. Mt khc khi cho m gam X tc dng vi 100 ml dung dch KOH 0,25M th thu c bao nhiu gam mui khan. A. 2,75 gam B. 8,77 gam C. 10,45 gam D. 4,75 gam Trang 5/6 M thi 2012 BBB

Cu 52: Cho s : Hn hp ( K, Al, Zn )

H2 O

Dung dch Y

HCl (d )

dung dch P

+ tm Al

thy tm Al tng khi lng

Rn X dung dch Q kt ta H Hy cho bit cc cht tng ng vi cc ch ci P v H l: A. P (ZnCl2), H (Zn(OH)2) B. P (KCl, AlCl3), H (Al(OH)3) C. P (ZnCl2, AlCl3), H (Zn(OH)2) D. P (KCl, ZnCl2, AlCl3), H (Al(OH)3) Cu 53: Hirocacbon X c t khi hi so vi hiro l 46. X khng lm mt mu dung dch KMnO 4 nhit thp, nhng khi un nng s lm mt mu KMnO4 v to ra sn phm Y c cng thc phn t l C 7H5O2K. Cho Y tc dng vi dung dch H2SO4 long th to thnh sn phm Z c cng thc phn t l C 7H6O2. Cng thc cu to ca X, Y, Z ln lt l: A. C6H5CH3, CH3C6H3(OH)OK, CH3C6H3(OH)2. B. C6H5CH3, CH3C6H3(OK)2, CH3C6H3(OH)2. C. C6H5CH3, C6H5COOK, C6H5COOH. D. C6H5CH=CH2, C6H5CH(OH)-CH2OK, C6H5COOH Cu 54: T 1 tn pirit cha 75,3% FeS2, 13,1% CuFeS2 v 11,6% tp cht tr c th iu ch c bao nhiu lt dung dch H2SO4 78,04% (d = 1,71 g/ml) bit lng SO2 b mt khi nung l 1,5% v lng axit b mt mt l 0,2%. A. 1008,6 lt B. 787,13 lt C. 733,92 lt D. 2017,2 lt Cu 55: Hn hp cht rn A gm Na2SO3, NaHSO3 v Na2SO4. Cho 28,56 gam A tc dng vi dung dch H2SO4 long d. Kh SO2 sinh ra lm mt mu hon ton 675ml dung dch brom 0,2 M. Mt khc 7,14 gam A tc dng va vi 21,6ml NaOH 0,125M. Tnh thnh phn phn trm Na 2SO3 v Na2SO4 trong hn hp A l: A. 39,32% v 11,91% B. 39,32% v 45,56% C. 48,77% v 39,32% D. 11,91% v 48,77% Cu 56: Mt hn hp kh gm ba hirocacbon A, B, C trong B, C c cng s nguyn t cacbon trong phn t v s mol A gp 4 ln s mol B v C trong hn hp. t chy hon ton 1,12 lt hn hp trn ( iu kin tiu chun) thu c 3,08 gam CO2 v 2,2025 gam H2O. Cng thc phn t ca A, B, C c th l: A. C3H6, C3H8, C3H4 B. CH4, C3H6, C3H4 C. C2H4, C3H6, C2H2 D. CH4, C3H8, C3H4 Cu 57: Cho cc pht biu sau: (a) phn bit cc kh ng trong cc l mt nhn: NO, NO2, NH3, CO2. S ha cht ti thiu cn s dng l 3. (b) phn bit cc kh ng trong cc l mt nhn: N2, NO2, SO2, CO2, O2. S S ha cht ti thiu cn s dng l 3. (c) phn bit 8 dung dch ng trong cc l mt nhn: NaNO3, Na2SO4, Mg(NO3)2, Fe(NO3)2, Cu(NO3)2, MgSO4, FeSO4, CuSO4. S ha cht ti thiu phi s dng l 1. (d) phn bit 5 dung dch ng trong cc l mt nhn: NH4Cl, Ba(NO3)2, Cu(NO3)2, Na2SO4, FeCl2. S ha cht ti thiu cn phi s dng l 1. (e) Cho dung dch cc cht NH3, FeSO4, BaCl2, HNO3, AgNO3. C 7 cp cht tc dng vi nhau. S pht biu ng l: A. 1 B. 2 C. 3 D. 4 Cu 58: Trong cc chui phn ng ha hc sau, chui no c phn ng ha hc khng th thc hin c? A. P P2O5 H3PO4 CaHPO4 Ca3(PO4)2 CaCl2 Ca(OH)2 CaOCl2 B. Cl2 KCl KOH KClO3 O2 O3 KOH CaCO3 CaO CaCl2 Ca C. NH3 N2 NO NO2 NaNO3 NaNO2 N2 Na3N NH3 NH4Cl HCl D. S H2S SO2 HBr HCl Cl2 H2SO4 H2S PbS H2S NaHS Na2S Cu 59: Cho 47 gam hn hp hi ca hai ancol i qua Al2O3 nung nng thu c hn hp A gm ete, anken, ancol d v hi nc. Tch hi nc ra khi hn hp A thu c hn hp kh B. Ly nc tch ra cho tc dng ht vi Na thu c 4,704 lt H2 (iu kin tiu chun). Lng anken c trong B c no ha va bi 1,35 lt dung dch Br 2 0,2M. Phn ancol v ete c trong B chim th tch 16,128 lt 136,5 0C v 1 atm. Tnh hiu sut ancol tch nc to thnh anken, bit hiu sut i vi mi ancol nh nhau ?. A. 70% B. 85% C. 40% D. 30% Cu 60: Khi ha tan cng mt lng kim loi R vo dung dch HNO 3 c, nng v dung dch H2SO4 long th th tch kh NO2 thu c gp 3 ln th tch H2 cng iu kin nhit v p sut. Khi lng mui sunfat thu c bng 62,81% khi lng mui nitrat to thnh. Mt khc khi nung cng 1 lng kim loi R nh trn cn th tch O 2 bng 22,22% th tch ni trn (cng iu kin) v thu c rn A l 1 oxit R. Ha tan 20,88 gam A vo dung dch HNO3 (d 25% so vi lng cn thit) thu c 0,672 lt kh B (iu kin tiu chun) l oxit ca nit N xOy. Tnh khi lng HNO3 ly ha tan A. A. 66,51 gam B. 78,75 gam C. 52,92 gam D. 66,15 gam --------------------HT-------------------Trang 6/6 M thi 2012 BBB

HCl (d )

+ NH3 (d)