TUYN TP CC THI I HC, CAO NG T NM 2007 N 2011

A. HA HC I CNG 1. Nguyn t, bng tun hon cc nguyn t ha hc lin kt ha hc: 2 - Tp nguyn t Cu 1: Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35. S hiu nguyn
t ca nguyn t X l A. 18. B. 23. C. 17. D. 15. thi TSC 2009 Cu 2: Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l D. LiF thi TSHC khi B 2007 A. MgO B. AlN C. NaF

Cu 3: Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt

nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t ca nguyn t: Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26) A. Fe v Cl. B. Na v Cl. C. Al v Cl. D. Al v P. thi TSC 2008

- ng v Cu 4: Trong t nhin, nguyn t ng c hai ng v l

65

63 29

Cu v

65 29

Cu . Nguyn t khi trung bnh ca ng l 63,54.

Thnh phn phn trm tng s nguyn t ca ng v 29 Cu l A. 27% B. 50 C. 54% D. 73%. thi TSC 2007 2 Cu 5: Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s 2s22p63s1; 1s22s22p63s2; 1s22s22p63s23p1. Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l: A. Z, X, Y. B. Y, Z, X. C. Z, Y, X. D. X, Y, Z. (TSC 2010) 26 55 26 Cu 6: Nhn inh nao sau y ung khi noi v 3 nguyn t : 13 X, 26 Y, 12 Z ? A. X, Y thuc cung mt nguyn t hoa hoc B. X va Z co cung s khi C. X va Y co cung s ntron D. X, Z la 2 ng vi cua cung mt nguyn t hoa hoc (H A 2010) 37 35 Cu 7: Trong t nhin clo c hai ng v bn: 17 Cl chim 24,23% tng s nguyn t, cn li l 17 Cl . Thnh phn % theo khi lng ca A. 8,92%
37 17

Cl trong HClO4 l:
B. 8,43% C. 8,56% D. 8,79% (H khi B 2011)

- Cu hnh, v tr, bin thin tnh cht Cu 8: Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:
+ + + + A. Na , Cl , Ar.B. Li , F , Ne. C. Na , F , Ne. D. K , Cl , Ar. thi TSHC khi A 2007 2+ 2 6 Cu 9: Anion X v cation Y u c cu hnh electron lp ngoi cng l 3s 3p . V tr ca cc nguyn t trong bng tun hon cc nguyn t ha hc l A. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). B. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). C. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). D. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 3, nhm IIA (phn nhm chnh nhm II). thi TSHC khi A 2007 2+ 2 2 6 2 6 6 Cu 10: Cu hnh electron ca ion X l 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc A. chu k 4, nhm VIIIA. B. chu k 4, nhm IIA. C. chu k 3, nhm VIB. D. chu k 4, nhm VIIIB. thi TSHC khi A 2009 Cu 11: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l A. kim loi v kim loi. B. phi kim v kim loi. C. kim loi v kh him. D. kh him v kim loi. thi TSC 2009 Cu 12: Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu tng ca in tch ht nhn nguyn t th A. m in gim dn, tnh phi kim tng dn. B. tnh phi kim gim dn, bn knh nguyn t tng dn. C. tnh kim loi tng dn, m in tng dn. D. tnh kim loi tng dn, bn knh nguyn t gim dn. thi TSHC khi B 2007 Cu 13: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t

Trang 1/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

tng dn theo th t A. Y < M < X < R. B. R < M < X < Y. C. M < X < Y < R. D. M < X < R < Y. thi TSC 2007 Cu 14: Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri sang phi l A. F, Na, O, Li. B. F, Li, O, Na. C. F, O, Li, Na. D. Li, Na, O, F. thi TSHC khi A 2008 Cu 15: Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: A. N, Si, Mg, K. B. K, Mg, Si, N. C. K, Mg, N, Si. D. Mg, K, Si, N. thi TSHC khi B 2009 Cu 16: Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l: A. P, N, O, F. B. P, N, F, O. C. N, P, O, F. D. N, P, F, O. thi TSHC khi B 2008 Cu 17: Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt A. cng ho tr khng phn cc. B. cng ho tr phn cc. C. ion. D. hiro. (TSC 2010) Cu 18: Cac nguyn t t Li n F, theo chiu tng cua in tich hat nhn thi A. Ban kinh nguyn t va m in u tng B. Ban kinh nguyn t tng, m in giam C. Ban kinh nguyn t giam, m in tng D. Ban kinh nguyn t va m in u giam (H A 2010) Cu 19: Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l A. [Ar]3d54s1. B. [Ar]3d64s2. C. [Ar]3d64s1. D. [Ar]3d34s2. (H B 2010) - Ha tr cao nht vi oxi, trong hp cht kh vi H Cu 20: Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l A. As. B. N. C. S. D. P. thi TSHC khi B 2008 2 4 Cu 21: Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns np . Trong hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong oxit cao nht l A. 50,00%. B. 27,27%. C. 60,00%. D. 40,00%. thi TSHC khi A 2009 - D on lin kt, x s lin kt, phn cc lin kt, mng tinh th Cu 22: Hp cht trong phn t c lin kt ion l A. NH4Cl. B. HCl. C. H2O. D. NH3. thi TSHC khi A 2008 Cu 23: Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l: A. O2, H2O, NH3. B. H2O, HF, H2S. C. HCl, O3, H2S. D. HF, Cl2, H2O. thi TSC 2009 2 2 Cu 24: Nguyn t ca nguyn t X c cu hnh electron 1s 2s 2p63s23p64s1, nguyn t ca nguyn t Y c cu hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn t Y thuc loi lin kt A. kim loi. B. cng ho tr. C. ion. D. cho nhn. thi TSC 2008 Cu 25: Pht biu no sau y l ng ? A. Photpho trng c cu trc tinh th nguyn t. B. th rn, NaCl tn ti di dng tinh th phn t. C. Nc thuc loi tinh th phn t. D. Kim cng c cu trc tinh th phn t. thi TSHC khi B 2009 Cu 26: Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng thc ca hp cht to thnh 2 nguyn t trn c dng l: A. X3Y2 B. X2Y3 C. X5Y2 D. X2Y5 (C 2011)

- D on lin kt, x s lin kt, phn cc lin kt, mng tinh th

Cu 27: Mc phn cc ca lin kt ho hc trong cc phn t c sp xp theo th t gim dn t tri sang phi l: A. HBr, HI, HCl B. HI, HBr, HCl C. HCl , HBr, HI D. HI, HCl , HBr (C 2011) Cu 28: Cc cht m phn t khng phn cc l: A. HBr, CO2, CH4. B. Cl2, CO2, C2H2. C. NH3, Br2, C2H4. D. HCl, C2H2, Br2. (H B 2010) Cu 29: Khi so snh NH3 vi NH4+, pht biu khng ng l: A. Trong NH3 v NH4+, nit u c s oxi ha -3. B. NH3 c tnh baz, NH4+ c tnh axit. C. Trong NH3 v NH4+, nit u c cng ha tr 3. D. Phn t NH3 v ion NH4+ u cha l/k cng ha tr. (H khi A 2011) Cu 30: Pht biu no sau y l sai? A. Tinh th nc , tinh th iot u thuc loi tinh th phn t. B. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. C. Tt c cc tinh th phn t u kh nng chy v kh bay hi. D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ha tr. (H khi B 2011)

2. Phn ng oxi ha kh, tc phn ng v cn bng ha hc: 2 + 0,5 - Vai tr oxh kh, cn bng PT Trang 2/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

Cu 31: Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c, nng) c) Al2O3 + HNO3 (c, nng) d) Cu + dung dch FeCl3 e) CH3CHO + H2 f) glucoz + AgNO3 trong dung dch NH3 g) C2H4 + Br2 h) glixerol (glixerin) + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l: A. a, b, d, e, f, h. B. a, b, d, e, f, g. C. a, b, c, d, e, h. D. a, b, c, d, e, g. thi TSHC khi A 2007 Cu 32: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. thi TSHC khi A 2007 Cu 33: Cho cc phn ng: Ca(OH)2 + Cl2 CaOCl2 2H2S + SO2 3S + 2H2O 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O 4KClO3 + SO2 3S + 2H2O O3 O2 + O S phn ng oxi ho kh l A. 5. B. 4. C. 2. D. 3. thi TSHC khi B 2008 Cu 34: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi dung dch HNO3 c, nng l A. 10. B. 11. C. 8. D. 9. thi TSHC khi A 2007 Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Sau khi cn bng Cu 35: phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 13x - 9y. B. 46x - 18y. C. 45x - 18y. D. 23x - 9y. thi TSHC khi A 2009 Cu 36: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhn 12 electron. B. nhn 13 electron. C. nhng 12 electron. D. nhng 13 electron. thi TSHC khi B 2007 Cu 37: Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2 Pht biu ng l: 2+ 3+ A. Tnh kh ca Br mnh hn ca Fe . B. Tnh oxi ha ca Cl2 mnh hn ca Fe . C. Tnh kh ca Cl mnh hn ca Br . D. Tnh oxi ha ca Br2 mnh hn ca Cl2. thi TSHC khi B 2008 2+ Cu 38: Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu , Cl . S cht v ion c c tnh oxi ha v tnh kh l A. 7. B. 5. C. 4. D. 6. thi TSHC khi A 2009 + 2+ 2+ 3+ 2+ 2Cu 39: Cho dy cc cht v ion: Cl2, F2, SO2, Na , Ca , Fe , Al , Mn , S , Cl . S cht v ion trong dy u c tnh oxi ho v tnh kh l A. 5. B. 4. C. 3. D. 6. thi TSHC khi B 2008 Cu 40: Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l A. 47. B. 27. C. 31. D. 23. (TSC 2010) Cu 41: Nguyn t S ng vai tr va l cht kh, va l cht oxi ho trong phn ng no sau y? t0 t0 A. S + 2Na Na2S. B. S + 6HNO3 (c) H2SO4 + 6NO2 + 2H2O.
t t C. S + 3F2 SF6. D. 4S + 6NaOH(c) 2Na2S + Na2S2O3 + 3H2O. (TSC 2010) Cu 42: Cho phn ng : 6FeSO4 + K2Cr2O7 + 7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3 + K2SO4 +7H2O Trong phn ng trn, cht oxi ha v cht kh ln lt l A. FeSO4 v K2Cr2O7. B. K2Cr2O7 v FeSO4. C. H2SO4 v FeSO4. D. K2Cr2O7 v H2SO4. (C 2011) Cu 43: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l A. 4/7. B. 1/7. C. 3/14. D. 3/7. (H A 2010) Cu 44: Cho x mol Fe tan hoan toan trong dung dich cha y mol H 2SO4 (ti l x : y = 2 : 5), thu c mt san phm kh duy nht va dung dich chi cha mi sunfat. S mol electron do lng Fe trn nhng khi bi hoa tan la A. 3x B. y C. 2x D. 2y (H A 2010) Cu 45: Cho cc phn ng: (a) Sn + HCl (long) t (b) FeS + H2SO4 (long) t0 (c) MnO2 + HCl (c) (d) Cu + H2SO4 (c) (e) Al + H2SO4 (long) (g) FeSO4 + KMnO4 + H2SO4 S phn ng m H+ ca axit ng vai tr oxi ha l:
0

Trang 3/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

A. 3

B. 6

C. 2

D. 5(H khi B 2011)

- Tc phn ng Cu 46: Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 ( ktc).
Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l A. 5, 0.10 4 mol/(l.s). B. 5, 0.10 5 mol/(l.s). C. , 0.10 3 mol/(l.s). D. 2, 5.10 4 mol/(l.s). thi TSHC khi B 2009

Cu 47:

Cho phng trnh ha hc ca phn ng tng hp amoniac

o

t N 2 (k) + 3H 2 (k) 2NH 3(k) xt

Khi tng nng ca hiro ln 2 ln, tc phn ng thun: A. tng ln 8 ln. B. tng ln 2 ln. C. tng ln 6 ln. D. gim i 2 ln. thi TSC 2007 Cu 48: Cho phn ng: Br2 + HCOOH 2HBr + CO2. Nng ban u ca Br2 l a mol/lt, sau 50 giy nng Br2 cn li l 0,01 mol/lt. Tc trung bnh ca phn ng trn tnh theo Br2 l 4.10-5 mol/(l.s). Gi tr ca a l A. 0,018. B. 0,016. C. 0,014. D. 0,012. (TSC 2010)

- Hng s cn bng, Chuyn dch CB Cu 49: Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l
o 0,3M v 0,7M. Sau khi phn ng tng hp NH3 t trng thi cn bng t C, H2 chim 50% th tch hn hp o thu c. Hng s cn bng KC t C ca phn ng c gi tr l A. 2,500. B. 3,125. C. 0,609. D. 0,500. thi TSHC khi A 2009 Cu 50: Cho cc cn bng sau:

(1) H 2 (k) + I 2 (k) 2HI (k) 1 H 2 (k) + 1 I 2 (k) (3) HI (k) 2 2 (5) H 2 (k) + I 2 (r) 2HI (k)

1 1 (2) H 2 (k) + I 2 (k) HI (k) 2 2 (4) 2HI (k) H 2 (k) + I 2 (k)

nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn bng A. (4). B. (2). C. (3). D. (5). thi TSC 2009 2SO3 (k); phn ng thun l phn ng ta nhit. Pht biu ng l: Cho cn bng ha hc: 2SO2 (k) + O2 (k) A. Cn bng chuyn dch theo chiu thun khi tng nhit . B. Cn bng chuyn dch theo chiu nghch khi gim nng O2. C. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng. D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3. thi TSHC khi A 2008 Cu 51: Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k)

CO2 (k) + H2 (k)

H < 0

Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l: A. (1), (4), (5). B. (1), (2), (3). C. (2), (3), (4). D. (1), (2), (4). thi TSC 2009

Cu 52:

Cho cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k); phn ng thun l phn ng to nhit. Cn

bng ho hc khng b chuyn dch khi A. thay i nng N2. B. thm cht xc tc Fe. C. thay i nhit . D. thay i p sut ca h. thi TSHC khi B 2008 Cu 53: Cho cc cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k)(1) H2 (k) + I2 (k) 2HI (k)(2) 2SO2 (k) + O2 (k) 2SO3 (k)(3) 2NO2 (k) N2O4 (k)(4) Khi thay i p sut nhng cn bng ha hc b chuyn dch l: A. (1), (2), (3). B. (2), (3), (4). C. (1), (3), (4). D. (1), (2), (4). thi TSC 2008 Cu 54: Cho cc cn bng sau: (1) 2SO2(k) +

O2(k) 2SO3(k)

(2) N2 (k) +

3H2 (k)

2NH3 (k)

(3) CO2(k) + H2(k) CO(k) + H2O(k)

(4) 2HI (k) H2 (k) + I2 (k)

Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l A. (1) v (2). B. (1) v (3). C. (3) v (4). D. (2) v (4). thi TSC 2009

Trang 4/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

Cu 55:

Cho cn bng sau trong bnh kn: 2NO2

N2O4

(mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c: A. H < 0, phn ng to nhit B. H > 0, phn ng to nhit C. H < 0, phn ng thu nhit D. H > 0, phn ng thu nhit thi TSHC khi A 2009 Hng s cn bng ca phn ng xc nh ch ph thuc vo A. nhit . B. p sut. C. cht xc tc. D. nng . thi TSC 2008 Cu 56: Cho cn bng ho hc: PCl5 (k) PCl3 (k) + Cl2 (k); Cn bng chuyn dch theo chiu thun khi A. tng p sut ca h phn ng. B. thm Cl2 vo h phn ng. C. thm PCl3 vo h phn ng. D. tng nhit ca h phn ng. (TSC 2010) Cu 57: Cho cn bng ho hc : N2 (k) +3H2 (k) 2NH3 (k) H< 0 Cn bng trn chuyn dch theo chiu thun khi: A. tng p sut ca h phn ng B. tng nhit ca h phn ng C. gim p sut ca h phn ng D. thm cht xc tc vo h phn ng (C 2011) Cu 58: Cho phn ng: H2 (k) + I2 (k) 2HI (k) nhit 4300C, hng s cn bng KC ca phn ng trn bng 53,96. un nng mt bnh kn dung tch khng i 10 lt cha 4,0 gam H2 v 406,4 gam I2. Khi h phn ng t trng thi cn bng 4300C, nng ca HI l A. 0,275M. B. 0,320M. C. 0,225M. D. 0,151M. (C 2011) Cu 59: Cho cn bng 2SO2 (k) + O2 (k) 2SO3 (k). Khi tng nhit thi ti khi cua hn hp khi so vi H2 giam i. Phat biu ung khi noi v cn bng nay la : A. Phan ng nghich toa nhit, cn bng dich chuyn theo chiu thun khi tng nhit . B. Phan ng thun toa nhit, cn bng dich chuyn theo chiu nghich khi tng nhit . C. Phan ng nghich thu nhit, cn bng dich chuyn theo chiu thun khi tng nhit . D. Phan ng thun thu nhit, cn bng dich chuyn theo chiu nghich khi tng nhit . (H A 2010) Cu 60: Xt cn bng: N2O4 (k) 2NO2 (k) 250C. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2 A. tng 9 ln. B. tng 3 ln. C. tng 4,5 ln. D. gim 3 ln. (H A 2010) Cu 61: Cho cac cn bng sau (I) 2HI (k) H2 (k) + I2 (k) ; (II) CaCO3 (r) CaO (r) + CO2 (k) ; (III) FeO (r) + CO (k) Fe (r) + CO2 (k) ; (IV) 2SO2 (k) + O2 (k) 2SO3 (k) Khi giam ap sut cua h, s cn bng bi chuyn dich theo chiu nghich la A. 4 B. 3 C. 2 D. 1 (H B 2010) Cu 62: Cho cn bng ha hc: H2 (k) + I2 (k) 2HI (k) ; H > 0. Cn bng khng b chuyn dch khi A. gim p sut chung ca h. B. gim nng HI. C. tng nhit ca h. D. tng nng H2. (H khi A 2011) Cu 63: Cho cn bng ha hc sau: 2SO2 (k) + O2 (k) 2SO3 (k) ; H < 0 Cho cc bin php : (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (2), (3), (4), (6) B. (1), (2), (4) C. (1), (2), (4), (5) D. (2), (3), (5) (H khi B 2011) Cu 64: Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng bnh mt thi gian 8300C h t n trng thi cn bng: CO (k) + H2O (k) CO2 (k) + H2 (k) (hng s cn bng Kc = 1). Nng cn bng ca CO, H2O ln lt l A. 0,018M v 0,008 M B. 0,012M v 0,024M C. 0,08M v 0,18M D. 0,008M v 0,018M(H khi B 2011)

3. S in li: 2 + 0,5 - pH, , Ka, Kb Cu 65: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v
y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) A. y = 100x. B. y = 2x. C. y = x - 2. D. y = x + 2. thi TSHC khi A 2007 o Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 C, Ka ca -5 o CH3COOH l 1,75.10 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 C l A. 1,00.B. 4,24. C. 2,88. D. 4,76. thi TSHC khi B 2009 Cu 67: Dung dch X gm CH3COOH 1M (Ka = 1,75.10-5) v HCl 0,001M . Gi tr pH ca dung dch X l: A. 2,43 B. 2,33 C. 1,77

Cu 66:

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Cu 68: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N +5). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l: A. 1 B. 3 C. 2 D. 4(H khi B 2011)

- Vai tr, mi trng dung dch mui, tn ti cc ion

Cu 69: Dy gm cc ion cng tn ti trong mt dung dch l: A. Al3+, PO43, Cl, Ba2+. B. Na+, K+, OH, HCO3. + 2+ C. K , Ba , OH , Cl . D. Ca2+, Cl, Na+, CO32. (TSC 2010) Cu 70: Dung dch no sau y c pH > 7? A. Dung dch Al2(SO4)3. B. Dung dch CH3COONa. C. Dung dch NaCl. D. Dung dch NH4Cl. (TSC 2010) Cu 71: Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH = 3,0 thu c dung dch Y c pH = 11,0. Gi tr ca a l: A. 0,12 B. 1,60 C. 1,78 D. 0,80 (C 2011) 2 + Cu 72 : Dung dich X co cha: 0,07 mol Na ; 0,02 mol SO4 va x mol OH . Dung dich Y co cha ClO4 , NO3 va y mol
H+; tng s mol ClO4 va NO3 la 0,04. Trn X va Y c 100 ml dung dich Z. Dung dich Z co pH (bo qua s in li cua H2O) la A. 1 B. 2 C. 12 D. 13 (H A 2010) Cu 73: Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l A. 2. B. 4. C. 5. D. 3. thi TSHC khi B 2008 Cu 74: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 5. C. 2. D. 4. thi TSHC khi A 2007 Cu 75: Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dyc tnh cht lng tnh l A. 5. B. 2. C. 3. D. 4. thi TSC 2008 Cu 76: Cc hp cht trong dy cht no di y u c tnh lng tnh? A. Cr(OH)3, Zn(OH)2, Pb(OH)2` B. Cr(OH)3, Zn(OH)2, Mg(OH)2 C. Cr(OH)3, Pb(OH)2, Mg(OH)2 D. Cr(OH)3, Fe(OH)2, Mg(OH)2 thi TSC 2007 Cu 77: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 6. B. 4. C. 5. D. 7. thi TSHC khi A 2008 Cu 78: Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l: A. NaHCO3, MgO, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. NaHCO3, Ca(HCO3)2, Al2O3. D. Mg(OH)2, Al2O3, Ca(HCO3)2. thi TSC 2009 Cu 79: Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. Na2CO3, C6H5ONa, CH3COONa. B. Na2CO3, NH4Cl, KCl. C. NH4Cl, CH3COONa, NaHSO4. D. KCl, C6H5ONa, CH3COONa. thi TSC 2007 Cu 80: Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (3), (2), (4), (1). B. (4), (1), (2), (3). C. (1), (2), (3), (4). D. (2), (3), (4), (1). thi TSC 2008 Cu 81: t chay hoan toan m gam FeS2 bng mt lng O2 va u, thu c khi X. Hp thu ht X vao 1 lit dd cha Ba(OH)2 0,15M va KOH 0,1M, thu c dd Y va 21,7 gam kt tua. Cho Y vao dd NaOH, thy xut hin thm kt tua. Gia tri cua m la A. 23,2 B. 12,6 C. 18,0 D. 24,0 (H B 2010) Cu 82: dd axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng? A. Khi pha long 10 ln dd trn th thu c dd c pH = 4. B. in li ca axit fomic s gim khi thm dd HCl. C. Khi pha lang dd trn th in li ca axit fomic tng. D. in li ca axit fomic trong dd trn l 14,29%. (H B 2010)

- Hn hp axit td hn hp baz. Pt ion thu gn. Bt in tch Cu 83: Cho 4 phn ng:
(1) Fe + 2HCl FeCl2 + H2 (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O

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(3) BaCl2 + Na2CO3 BaCO3 + 2NaCl (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4 Cc phn ng thuc loi phn ng axit - baz l A. (1), (2). B. (2), (4). C. (3), (4). D. (2), (3). thi TSHC khi B 2007 Cu 84: Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng mt phng trnh ion rt gn l: A. (1), (2), (3), (6). B. (1), (3), (5), (6). C. (2), (3), (4), (6). D. (3), (4), (5), (6). thi TSHC khi B 2009 Cu 85: Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 2. B. 3. C. 1. D. 4. thi TSHC khi A 2008 Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 Cu 86: 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l A. 1. B. 2. C. 7. D. 6. thi TSHC khi B 2007 Cu 87: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 13,0. B. 1,2. C. 1,0. D. 12,8. thi TSHC khi B 2009 Cu 88: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l A. 0,30. B. 0,12. C. 0,15. D. 0,03. thi TSHC khi B 2008 Cu 89: Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l A. 19,7. B. 39,4. C. 17,1. D. 15,5. thi TSC 2009 22+ Cu 90: Mt dung dch cha 0,02 mol Cu , 0,03 mol K+, x mol Cl- v y mol SO 4 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,01 v 0,03. B. 0,05 v 0,01. C. 0,03 v 0,02. D. 0,02 v 0,05. thi TSC 2007 Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c Cu 91: dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. thi TSHC khi A 2007 Cu 92: Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha A. NaCl. B. NaCl, NaOH, BaCl2. C. NaCl, NaOH. D. NaCl, NaHCO3, NH4Cl, BaCl2. thi TSHC khi B 2007 Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc Cu 93: dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, NaCl, Na2SO4. thi TSHC khi B 2007 3+ 2+ Cu 94: Dung dch X cha cc ion: Fe , SO4 , NH4 , Cl . Chia dung dch X thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; - Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi) A. 3,73 gam. B. 7,04 gam. C. 7,46 gam. D. 3,52 gam. thi TSC 2008 Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch Cu 95: mui trung ho c nng 27,21%. Kim loi M l A. Cu. B. Zn. C. Mg. D. Fe. thi TSC 2007 + 2+ Cu 96: Cho dung dich X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl ; 0,006 HCO3 va 0,001 mol NO3 . loai bo ht Ca2+ trong X cn mt lng va u dung dich cha a gam Ca(OH)2 Gia tri cua a la A. 0,222 B. 0,120 C. 0,444 D. 0,180 (H A 2010) 2+ + Cu 97: dd X cha cac ion: Ca , Na , HCO3 va Cl , trong o s mol cua ion Cl la 0,1. Cho 1/2 dd X phan ng vi dd NaOH (d), thu c 2 gam kt tua. Cho 1/2 dd X con lai phan ng vi dd Ca(OH)2 (d), thu c 3 gam kt tua. Mt khac, nu un si n can dd X thi thu c m gam cht rn khan. Gia tri cua m la A. 9,21 B. 9,26 C. 8,79 D. 7,47 (H B 2010)

B. HA HC V C Trang 7/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

4. Phi kim (halogen oxi, lu hunh cacbon, silic nit, photpho): 2 - iu ch, nhn bit, tnh cht ha hc
Cu 98 : Hn hp khi X gm N2 va H2 co ti khi so vi He bng 1,8. un nong X mt thi gian trong binh kin (co bt Fe lam xuc tac), thu c hn hp khi Y co ti khi so vi He bng 2. Hiu sut cua phan ng tng hp NH3 la A. 50% B. 36% C. 40% D. 25% Cu 99: Cht c dng ty trng giy v bt giy trong cng nghip l A. CO2. B. SO2. C. N2O. D. NO2. (H A 2010) Cu 100: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn X (gi s phn ng xy ra hon ton). Phn trm khi lng ca Cu trong X l A. 12,37%. B. 87,63%. C. 14,12%. D. 85,88%. (H A 2010) Cu 101: Trong phng th nghim, ngi ta thng iu ch clo bng cch A. in phn nng chy NaCl. B. cho dung dch HCl c tc dng vi MnO2, un nng. C. in phn dung dch NaCl c mng ngn. D. cho F2 y Cl2 ra khi dung dch NaCl. thi TSHC khi A 2007 Cu 102: Trong phng th nghim, ngi ta iu ch oxi bng cch A. in phn nc. B. nhit phn Cu(NO3)2. C. nhit phn KClO3 c xc tc MnO2. D. chng ct phn on khng kh lng. thi TSHC khi A 2008 Cu 103: ng dng no sau y khng phi ca ozon? A. Ty trng tinh bt, du n. B. Cha su rng. C. iu ch oxi trong phng th nghim. D. St trng nc sinh hot. thi TSHC khi B 2009 Cu 104: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit bo ho. Kh X l A. NO. B. NO2. C. N2O. D. N2. thi TSHC khi A 2007 Cu 105: Trong phng th nghim, ngi ta thng iu ch HNO3 t A. NaNO3 v H 2 SO 4 c. B. NaNO2 v H 2 SO 4 c. C. NH3 v O2. D. NaNO3 v HCl c. thi TSHC khi B 2007 Cu 106: Cho Cu v dung dch H 2 SO 4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l A. amophot. B. ure. C. natri nitrat. D. amoni nitrat. thi TSHC khi A 2008 Cu 107: Phn bn no sau y lm tng chua ca t? A. KCl. B. NH4NO3. C. NaNO3. D. K2CO3. thi TSHC khi B 2009 Cu 108: Thnh phn chnh ca qung photphorit l A. CaHPO4. B. Ca3(PO4)2. C. Ca(H2PO4)2. D. NH4H2PO4. thi TSHC khi B 2008 Cu 109: Pht biu no sau y l ng? + A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3 ) v ion amoni (NH4 ). B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3. C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK. D. Phn ur c cng thc l (NH4)2CO3. thi TSHC khi A 2009 Cu 110: Phn bn nitrophotka (NPK) l hn hp ca A. (NH4)2HPO4 v KNO3. B. NH4H2PO4 v KNO3. C. (NH4)3PO4 v KNO3. D. (NH4)2HPO4 v NaNO3. thi TSC 2009 Cu 111: Cho cc phn ng sau: (1) Cu(NO ) t 3 2
850 (3) NH + O C,Pt 3 2 0 0 0

(2) NH NO t 4 2
t (4) NH + Cl 3 2 0 0

t t (5) NH Cl (6) NH + CuO 4 3 Cc phn ng u to kh N2 l: A. (1), (3), (4). B. (1), (2), (5). C. (2), (4), (6). D. (3), (5), (6). thi TSHC khi A 2008 Cu 112: Cho cc phn ng sau: o 4HCl + MnO2 t MnCl2 + Cl2 + 2H2O.

2HCl + Fe FeCl2 + H2. o 14HCl + K2Cr2O7 t 2KCl + 2CrCl3 + 3Cl2 + 7H2O. 6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 3. B. 4. C. 2. D. 1. thi TSHC khi A 2008

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Cu 113: Cho cc phn ng sau: (a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O. (b) HCl + NH4HCO3 NH4Cl + CO2 + H2O. (c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O. (d) 2HCl + Zn ZnCl2 + H2. S phn ng trong HCl th hin tnh kh l A. 2. B. 3. C. 1. D. 4. thi TSHC khi B 2009 Cu 114: Cho cc phn ng : 0 (1) O3 + dung dch KI (2) F2 + H2O t t0 (3) MnO2 + HCl c (4) Cl2 + dung dch H2S Cc phn ng to ra n cht l : A. (1), (2), (3) B. (1), (3), (4) C. (2), (3), (4) D. (1), (2), (4) thi TSHC khi B 2008 Cu 115: Phn ng nhit phn khng ng l : 0 0 A. 2KNO3 t 2KNO2 + O2 B. NH4NO2 t N2 + 2H2O
t C. NH4Cl NH3 + HCl D. NaHCO3 t NaOH + CO2 thi TSHC khi B 2008 Cu 116: Trng hp khng xy ra phn ng ha hc l to A. 3O2 + 2H2S 2SO2 + 2H2O B. FeCl2 + H2S FeS + 2HCl C. O3 + 2KI + H2O O2 + 2KOH + I2 D. Cl2 + 2NaOH NaCl + NaClO + H2O thi TSC 2008 Cu 117: Dy gm cc cht u tc dng c vi dung dch HCl long l: A. KNO3, CaCO3, Fe(OH)3. B. FeS, BaSO4, KOH. C. AgNO3, (NH4)2CO3, CuS. D. Mg(HCO3)2, HCOONa, CuO. thi TSHC khi A 2009 Cu 118: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. KMnO4. B. MnO2. C. CaOCl2. D. K2Cr2O7. thi TSHC khi A 2009 Cu 119: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l A. KClO3. B. KMnO4. C. KNO3. D. AgNO3. thi TSHC khi B 2009 Cu 120: Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm thnh v c th c dng lm cht ty mu. Kh X l A. NH3. B. CO2. C. SO2.D. O3. thi TSC 2009 Cu 121: SO2 lun th hin tnh kh trong cc phn ng vi A. H2S, O2, nc Br2. B. dung dch NaOH, O2, dung dch KMnO4. C. O2, nc Br2, dung dch KMnO4. D. dung dch KOH, CaO, nc Br2. thi TSC 2007 Cu 122: Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat, cn li gm cc cht khng cha photpho. dinh dng ca loi phn ln ny l A. 48,52%. B. 42,25%. C. 39,76%. D. 45,75%. (H B 2010) Cu 123: Cho s chuyn hoa : + H 3 PO4 + KOH + KOH P2O5 X Y Z
0 0

Cac cht X, Y, Z ln lt la : A. K3PO4, K2HPO4, KH2PO4 B. KH2PO4, K2HPO4, K3PO4 C. K3PO4, KH2PO4, K2HPO4 D. KH2PO4, K3PO4, K2HPO4 (H B 2010) Cu 124: Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ha tan ton b Y bng dung dch HNO 3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l: A. 18,42% B. 28,57% C. 14,28% D. 57,15%(H khi B 2011)

- Halogen, lu hunh
Cu 125: Pht biu no sau y ng? A. Dung dch NaF phn ng vi dung dch AgNO3 sinh ra AgF kt ta. B. Iot c bn knh nguyn t ln hn brom. C. Flo c tnh oxi ho yu hn clo. D. Axit HBr c tnh axit yu hn axit HCl. (TSC 2010) Cu 126: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml dung dch X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l A. 35,95%. B. 37,86%. C. 32,65%. D. 23,97%.(TSC 2010)

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Cu 127: Cho 3,16 gam KMnO4 tc dng vi dung dch HCl (d), sau khi phn ng xy ra hon ton th s mol HCl b oxi ho l A. 0,02 B. 0,16 C. 0,10 D. 0,05 (C 2011) Cu 128: Kh no sau y khng b oxi ha bi nuc Gia-ven. A. HCHO. B. H2S. C. CO2. D. SO2. (C 2011) Cu 129: Pht biu no sau y khng ng? A. Mui AgI khng tan trong nc, mui AgF tan trong nc B. Flo c tnh oxi ho mnh hn clo. C. Trong cc hp cht, ngoi s oxi ho -1, flo v clo cn c s oxi ho +1, +3, +5, +7 D. Dung dch HF ho tan c SiO2 (C 2011) Cu 130: Cho cc cht : KBr, S, SiO2, P, Na3PO4, FeO, Cu v Fe2O3. Trong cc cht trn, s cht c th oxi ho bi dung dch axit H2SO4 c nng l: A. 4 B. 5 C. 7 D. 6 (C 2011) Cu 131: Hn hp khi nao sau y khng tn tai nhit thng ? A. H2 va F2 B. Cl2 va O2 C. H2S va N2 D. CO va O2 (H A 2010) Cu 132: Pht biu khng ng l: A. Hiro sunfua b oxi ha bi nc clo nhit thng. B. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon. C. Tt c cc nguyn t halogen u c cc s oxi ha: -1, +1, +3, +5 v +7 trong cc hp cht. D. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung photphorit, ct v than cc 12000C trong l in. (H A 2010) Cu 133: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l A. 2,80.B. 3,36. C. 3,08. D. 4,48. thi TSC 2008 o Cu 134: Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100 C. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l A. 0,24M. B. 0,2M. C. 0,4M. D. 0,48M. thi TSHC khi B 2007 Cu 135: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 58,2%. B. 41,8%. C. 52,8%. D. 47,2%. thi TSHC khi B 2009 Cu 136: Pht biu no sau y l sai? A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo. B. m in ca brom ln hn m in ca iot. C. Tnh axit ca HF mnh hn tnh axit ca HCl. D. Tnh kh ca ion Br- ln hn tnh kh ca ion Cl-.(H khi A 2011) Cu 137: Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl . Ton b lng O2 tc dng ht vi cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi lng ca KMnO4 trong X l: A. 62,76% B. 74,92% C. 72,06% D. 27,94%(H khi B 2011) NO 3 trong H+, nhit phn ca mui nitrat Cu 138: Khi cho Cu tc dng vi dung dch cha H 2 SO 4 long v NaNO3, vai tr ca NaNO3 trong phn ng l A. cht oxi ho. B. mi trng. C. cht kh. D. cht xc tc. thi TSHC khi B 2007 Cu 139: Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H 2 SO 4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l A. V2 = 1,5V1. B. V2 = 2V1. C. V2 = 2,5V1. D. V2 = V1. thi TSHC khi B 2007 Cu 140: Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H 2 SO 4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,746. B. 0,672. C. 0,448. D. 1,792. thi TSHC khi A 2008 Cu 141: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 10,8 v 2,24. C. 17,8 v 2,24. D. 17,8 v 4,48. thi TSHC khi B 2009 Cu 142: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm

Trang 10/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 360. B. 240. C. 400. D. 120. thi TSHC khi A 2009 Cu 143: Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng A. 4. B. 2. C. 1. D. 3. thi TSHC khi A 2009 Cu 144: Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu c hn hp kh X (t khi ca X so vi kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hn hp ban u l A. 8,60 gam. B. 20,50 gam. C. 11,28 gam. D. 9,40 gam. thi TSC 2008 Cu 145: Sn phm ca phn ng nhit phn hon ton AgNO3 l: A. Ag, NO2, O2. B. Ag2O, NO2, O2. C. Ag2O, NO, O2. D. Ag, NO, O2. (TSC 2010) Cu 146: Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca). Gi tr ca a l A. 11,0. B. 11,2. C. 8,4. D. 5,6. (TSC 2010) Cu 147: Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l A. kim loi Cu v dung dch HCl. B. dung dch NaOH v dung dch HCl. C. ng(II) oxit v dung dch HCl. D. ng(II) oxit v dung dch NaOH. (TSC 2010) Cu 148: nhn ra ion NO3- trong dung dch Ba(NO3)2, ngi ta un nng nh dung dch vi: A. dung dch H2SO4 long B. kim loi Cu v dung dch Na2SO4 C. kim loi Cu v dung dch H2SO4 long D. kim loi Cu (C 2011) Cu 149: Cho 0,3 mol bt Cu va 0,6 mol Fe(NO3)2 vao dd cha 0,9 mol H2SO4 (loang). Sau khi cac phan ng xay ra hoan toan, thu c V lit khi NO (san phm kh duy nht, ktc). Gia tri cua V la A. 6,72 B. 8,96 C. 4,48 D. 10,08 (H B 2010) Cu 150: Cho 0,87 gam hh gm Fe, Cu v Al vo bnh ng 300 ml dd H2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO 3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dd l A. 0,224 lt v 3,750 gam. B. 0,112 lt v 3,750 gam. C. 0,112 lt v 3,865 gam. D. 0,224 lt v 3,865 gam. (H khi A 2011) Cu 151: Cho 7,68 gam Cu vo 200 ml dd gm HNO 3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dd sau P th khi lng mui khan thu c l A. 20,16 gam. B. 19,76 gam. C. 19,20 gam. D. 22,56 gam. (H khi A 2011) Cu 152 : Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam X? A. 10,56 gam B. 7,68 gam C. 3,36 gam D. 6,72 gam(H khi B 2011) Cu 153: Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X phn ng l A. B. 60% C. 70% D. 75%(H khi B 2011)

- P to NH4NO3 Cu 154:

Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X l A. H2SO4 c. B. HNO3. C. H3PO4. D. H2SO4 long. thi TSC 2009 Cu 155: Ha tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c dung dch X v 0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l A. 18,90 gam B. 37,80 gam C. 39,80 gam D. 28,35 gam (C 2011) Cu 156: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l A. 13,32 gam. B. 6,52 gam. C. 8,88 gam. D. 13,92 gam. thi TSHC khi B 2008 Cu 157: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 38,34. B. 34,08. C. 106,38. D. 97,98. thi TSHC khi A 2009

5. i cng v kim loi: 2 Dy th in cc chun: 1 - Tc vt l, ha hc, dy th in cc chun Cu 158: Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe 3 + /Fe 2 +
ng trc cp Ag + /Ag):

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A. Ag + , Cu 2 + , Fe 3 + , Fe 2 + B. Fe 3 + , Fe 2 + , Cu 2 + , Ag + + 3+ 2+ 2+ C. Ag , Fe , Cu , Fe D. Fe 3 + , Ag +, Cu2+, Fe 2 + thi TSHC khi A 2007 Cu 159: Cho cc phn ng xy ra sau y: (1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag (2) Mn + 2HCl MnCl2 + H2 Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l A. Ag + , Mn2+, H+, Fe 3 + . B. Mn2+, H+, Ag + , Fe 3 + . + 3+ + 2+ C. Ag , Fe , H , Mn . D. Mn2+, H+, Fe 3 + , Ag + . thi TSHC khi B 2007 Cu 160: Cho cc ion kim loi: Zn2+, Sn2+, Ni2+, Fe 2 + , Pb2+. Th t tnh oxi ho gim dn l 2+ 2+ 2+ A. Pb > Sn > Fe > Ni2+ > Zn2+. B. Pb2+ > Sn2+ > Ni2+ > Fe 2 + > Zn2+. C. Sn2+ > Ni2+ > Zn2+> Pb2+ > Fe 2 + . D. Zn2+>Sn2+ > Ni2+ > Fe 2 + > Pb2+. thi TSC 2007 Cu 161: Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra A. s kh Fe 2 + v s oxi ha Cu. B. s kh Fe 2 + v s kh Cu2+. C. s oxi ha Fe v s oxi ha Cu. D. s oxi ha Fe v s kh Cu2+. thi TSC 2008 Cu 162: Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng ha hc sau: X + 2YCl3 XCl2 + 2YCl2; Y + XCl2 YCl2 + X. Pht biu ng l: A. Ion Y2+ c tnh oxi ha mnh hn ion X2+. B. Kim loi X kh c ion Y2+. C. Kim loi X c tnh kh mnh hn kim loi Y. D. Ion Y3+ c tnh oxi ha mnh hn ion X2+. thi TSC 2008 Cu 163: Th t mt s cp oxi ho - kh trong dy in ho nh sau: Fe 2 + Fe; Cu2+/Cu; Fe 3 + /Fe 2 + . Cp cht khng phn ng vi nhau l A. Cu v dung dch FeCl3. B. dung dch FeCl2 v dung dch CuCl2. C. Fe v dung dch CuCl2. D. Fe v dung dch FeCl3. thi TSC 2007 Cu 164: Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. B. Fe + dung dch HCl. C. Fe + dung dch FeCl3. D. Cu + dung dch FeCl2. thi TSC 2008 kh ion Fe 3 + trong dung dch thnh ion Fe 2 + c th dng mt lng d A. kim loi Cu. B. kim loi Ag. C. kim loi Ba. D. kim loi Mg. thi TSC 2007 Cu 166: Mnh khng ng l: 2+ A. Fe oxi ho c Cu. B. Fe kh c Cu2+ trong dung dch. C. Fe 3 + c tnh oxi ha mnh hn Cu2+. D. Tnh oxi ha ca cc ion tng theo th t: Fe 2 + , H+, Cu2+, Ag +. thi TSHC khi A 2007 kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi A. K. B. Na. C. Fe. D. Ba. thi TSC 2007 Cu 168: X l kim loi phn ng c vi dung dch H 2 SO 4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe 3 + /Fe 2 + ng trc Ag +/Ag) A. Ag, Mg. B. Cu, Fe C. Fe, Cu. D. Mg, Ag. thi TSHC khi A 2008 Cu 169: Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg2+/Mg; Fe2+/Fe; Cu2+/Cu; 2+ + Fe3+/Fe ; Ag /Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l: + 2+ 2+ A. Fe, Cu, Ag . B. Mg, Fe , Ag. C. Mg, Cu, Cu . D. Mg, Fe, Cu. thi TSC 2009 Cu 170: Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3? A. Fe, Ni, Sn. B. Al, Fe, CuO. C. Zn, Cu, Mg. D. Hg, Na, Ca. thi TSC 2009 Cu 171: Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO3)2, dung dch HNO3 (c, ngui). Kim loi M l A. Al. B. Zn. C. Fe. D. Ag. thi TSC 2008 Cu 172: Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in ho (dy th in cc chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Cc kim loi v ion u phn ng c vi ion Fe2+ trong dung dch l: A. Zn, Ag+. B. Zn, Cu2+. C. Ag, Cu2+. D. Ag, Fe3+. (TSC 2010)

Cu 165:

Cu 167:

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Cu 173: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc dng vi dung dch HNO 3 c , ngui l: A. Fe, Al, Cr B. Cu, Fe, Al C. Fe, Mg, Al D. Cu, Pb, Ag (C 2011) Cu 174: Dy gm cc ion u oxi ha c kim loi Fe l A. Cr2+, Au3+, Fe3+. B. Fe3+, Cu2+, Ag+. C. Zn2+, Cu2+, Ag+. D. Cr2+, Cu2+, Ag+. (C 2011) Cu 175: Cho cac cp cht vi ti l s mol tng ng nh sau : (a) Fe3O4 va Cu (1:1) (b) Sn va Zn (2:1) (c) Zn va Cu (1:1) (d) Fe2(SO4)3 va Cu (1:1) (e) FeCl2 va Cu (2:1) (g) FeCl3 va Cu (1:1) S cp cht tan hoan toan trong mt lng d dung dich HCl loang nong la A. 4 B. 2 C. 3 D. 5 (H B 2010) Cu 176: Phat biu nao sau y khng ung ? A. Trong mi trng kim, mui Cr(III) co tinh kh va bi cac cht oxi hoa manh chuyn thanh mui Cr(VI). B. Do Pb2+/Pb ng trc 2H+/H2 trong day in hoa nn Pb d dang phan ng vi dd HCl loang ngui, giai phong khi H2. C. CuO nung nong khi tac dung vi NH3 hoc CO, u thu c Cu D. Ag khng phan ng vi dd H2SO4 loang nhng phan ng vi dd H2SO4 c nong. (H B 2010) Cu 177: Cho cc phn ng sau: Fe + 2Fe(NO3)3 3Fe(NO3)2 AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag . Dy sp xp theo th t tng dn tnh oxi ha cc ion kim loi l: A. Ag+, Fe2+, Fe3+ B. Fe2+, Fe3+, Ag+ C. Fe2+, Ag+, Fe3+ D. Ag+, Fe3+, Fe2+(H khi A 2011)

- n mn in ha, pin in Cu 178: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn; Fe v Sn; Fe v
Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hu trc l B. 2. C. 4. D. 3. thi TSC 2007 Cu 179: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v IV. B. I, II v III. C. I, III v IV. D. II, III v IV. thi TSHC khi A 2009 2+ Cu 180: Bit rng ion Pb trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. ch c Pb b n mn in ho. B. ch c Sn b n mn in ho. C. c Pb v Sn u khng b n mn in ho. D. c Pb v Sn u b n mn in ho. thi TSHC khi A 2008 Cu 181: C 4 dung dch ring bit: a) HCl, b) CuCl2 , c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l A. 1. B. 2. C. 0. D. 3. thi TSHC khi B 2007 Cu 182: Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4 ; - Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 3. B. 4. C. 1. D. 2. thi TSHC khi B 2008 Cu 183: Trong pin in ha Zn-Cu, qu trnh kh trong pin l + A. Cu Cu2+ + 2e. B. Zn Zn2 + 2e. C. Zn2+ + 2e Zn. D. Cu2+ + 2e Cu. thi TSHC khi B 2007 Cu 184: Cho bit phn ng oxi ho - kh xy ra trong pin in ho Fe Cu l: 0 0 Fe + Cu2+ Fe 2 + + Cu ; E (Fe 2 + /Fe) = 0,44 V, E (Cu2+/Cu) = + 0,34 V. A. 1. Sut in ng chun ca pin in ho Fe - Cu l A. 1,66 V. B. 0,10 V. C. 0,78 V. D. 0,92 V. thi TSC 2008 o o o Cu 185: Cho sut in ng chun E ca cc pin in ho: E (Cu-X) = 0,46V; E (Y-Cu) = 1,1V; o E (Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Y, Z, Cu, X. B. Z, Y, Cu, X. C. X, Cu, Z, Y. D. X, Cu, Y, Z. thi TSHC khi B 2008 Cho cc th in cc chun: E Al3+ /Al = -1,66V; E Zn2+ / Zn = -0,76V; E Pb2+ / Pb = -0,13V; E Cu 2+ /Cu = +0,34V. Trong cc pin sau y, pin no c sut in ng ln nht: A. Pin Zn Cu. B. Pin Zn Pb. C. Pin Al Zn. D. Pin Pb Cu. thi TSHC khi B 2009 Cu 187: Cho sut in ng chun ca cc pin in ho: Zn-Cu l 1,1V; Cu-Ag l 0,46 V. Bit th in cc

Cu 186:

o o chun E Zn2+ / Zn v E Cu 2+ /Cu c gi tr ln lt l:

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A. -0,76V v +0,34V. B. -1,46V v -0,34V. C. +1,56V v +0,64V. D. -1,56V v +0,64V. thi TSHC khi A 2009 Cu 188: Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi lng A. in cc Zn gim cn khi lng in cc Cu tng. B. c hai in cc Zn v Cu u tng. C. in cc Zn tng cn khi lng in cc Cu gim. D. c hai in cc Zn v Cu u gim. thi TSHC khi A 2008 Cu 189: Cho bit: Pin in ho c sut in ng chun bng 1,61V c cu to bi hai cp oxi ho - kh A. Pb2+/Pb v Cu2+/Cu. B. Zn2+/Zn v Cu2+/Cu. 2+ 2+ C. Mg /Mg v Zn /Zn. D. Zn2+/Zn v Pb2+/Pb. (TSC 2010) Cu 190: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn A. km ng vai tr catot v b oxi ho B. st ng vai tr anot v b oxi ho C. km ng vai tr anot v b oxi ho D. st ng vai tr catot v ion H+ b oxi ho Cu 191: Cho gi tr th in cc chun ca mt s cp oxi ha - kh: Cp oxi ha/ kh E (V)
0

M 2+

X 2+

Y 2+

Z 2+

-2,37

-0,76

-0,13

+0,34

Phn ng no sau y xy ra? A. X + Z2+ X2+ + Z B. X + M2+ X2+ + M C. Z + Y2+ Z2+ + Y D. Z + M2+ Z2+ + M (C 2011) Cu 192: Trong qu trnh hot ng ca pin in ha Zn Cu th A. khi lng ca in cc Zn tng B. nng ca ion Cu2+ trong dung dch tng 2+ C. nng ca ion Zn trong dung dch tng D. khi lng ca in cc Cu gim(H khi B 2011)

- in phn, iu ch, tinh ch Cu 193: Nguyn tc chung c dng iu ch kim loi l

A. cho hp cht cha ion kim loi tc dng vi cht kh. B. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi. C. kh ion kim loi trong hp cht thnh nguyn t kim loi. D. cho hp cht cha ion kim loi tc dng vi cht oxi ho. thi TSC 2009 Cu 194: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca chng, l: A. Na, Ca, Al. B. Na, Ca, Zn. C. Na, Cu, Al. D. Fe, Ca, Al. thi TSHC khi A 2007 Cu 195: Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Al v Mg. B. Na v Fe. C. Cu v Ag. D. Mg v Zn. thi TSC 2008 Cu 196: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l: A. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. D. Ba, Ag, Au. thi TSHC khi A 2009 Cu 197: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s oxi ho ion ClB. s oxi ho ion Na+. C. s kh ion Cl-. D. s kh ion Na+. thi TSHC khi A 2008 Cu 198: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al 3 catot v 67,2 m ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l A. 108,0. B. 75,6. C. 54,0. D. 67,5. thi TSHC khi B 2009 Cu 199: in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l A. b < 2a. B. b = 2a. C. b > 2a. D. 2b = a. thi TSHC khi B 2007 in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v Cu 200: mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. thi TSHC khi A 2007 Cu 201: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l

Trang 14/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

A. 4,05. B. 2,70. C. 1,35. D. 5,40. thi TSHC khi B 2009 Cu 202: Kim loi M c th c iu ch bng cch kh ion ca n trong oxit bi kh H2 nhit cao. Mt khc, kim loi M kh c ion H+ trong dung dch axit long thnh H2. Kim loi M l A. Mg. B. Al. C. Cu. D. Fe. (TSC 2010) Cu 203: in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l A. catot xy ra s kh: Cu2+ + 2e Cu. B. catot xy ra s oxi ho: 2H2O + 2e 2OH + H2. C. anot xy ra s oxi ho: Cu Cu2+ + 2e. D. anot xy ra s kh: 2H2O O2 + 4H+ + 4e. (TSC 2010) Cu 204: in phn 500 ml dung dch CuSO4 O,2M (in cc tr) cho n khi catot thu c 3,2 gam kim loi th th tch kh (ktc) thu c anot l: A. 3,36 lt B. 1,12 lt C. 0,56 lt D. 2,24 lt (C 2011) Cu 205: Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ha xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng xy ra lun km theo s pht sinh dng in. B. u sinh ra Cu cc m. C. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. D. Phn ng cc dng u l s oxi ha Cl-. (H A 2010) Cu 206: in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l A. kh Cl2 va2 O2. B. kh H2 v O2. C. ch c kh Cl2. D. kh Cl2 v H2. (H A 2010) Cu 207: in phn (in cc tr) dung dch X cha 0,2 mol CuSO 4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l A. 2,240 lt. B. 2,912 lt. C. 1,792 lt. D. 1,344 lt. (H A 2010) Cu 208: in phn (vi in cc tr) 200 ml dd CuSO4 nng x mol/l, sau mt thi gian thu c dd Y vn con mau xanh, co khi lng giam 8g so vi dd ban u. Cho 16,8g bt Fe vao Y, sau khi cac phan ng xay ra hoan toan, thu c 12,4g kim loai. Gia tri cua x la A. 2,25 B. 1,5 C. 1,25 D. 3,25 (H B 2010) Cu 209: Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,480. B. 3,920. C. 1,680. D. 4,788. (H khi A 2011) Cu 210: in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp) n kh khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3 v KOH. B. KNO3, KCl v KOH. C KNO3 v Cu(NO3)2. D. KNO3, HNO3 v Cu(NO3)2. (H khi A 2011) Cu 211: Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th: A. cc dng xy ra qu trinh oxi ha ion Na+ v cc m xy ra qu trnh kh ion Cl-. B. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ha Cl-. C. cc m xy ra qu trnh oxi ha H2O v cc dng x ra qu trnh kh ion Cl-. D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ha ion Cl-.(H khi A 2011)

- Kl tc dng axit HCl, H2SO4 long Cu 212: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch
H 2 SO 4 long, thu c 1,344 lt hiro (ktc) v dung dch cha m gam mui. Gi tr ca m l B. 9,52. C. 8,98. D. 7,25. thi TSC 2007 Cu 213: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l A. 101,68 gam. B. 88,20 gam. C. 101,48 gam. D. 97,80 gam. thi TSHC khi A 2009 Cu 214: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H 2 SO 4 0,28M thu c dung dch X v 8,736 lt kh H2 (ktc). C cn dung dch X thu c lng mui khan l A. 38,93 gam. B. 103,85 gam. C. 25,95 gam. D. 77,86 gam. thi TSC 2008 Cu 215: Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H 2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc).C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l A. 42,6 B. 45,5 C. 48,8 D. 47,1 thi TSC 2008 Cu 216: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H 2 SO 4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y A. 10,27.

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c pH l A. 1. B. 6. C. 7. D. 2. thi TSHC khi A 2007 Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l A. Be v Mg. B. Ca v Sr. C. Sr v Ba. D. Mg v Ca. thi TSHC khi B 2007 Cu 218: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 12,3. B. 15,6. C. 10,5. D. 11,5. thi TSHC khi B 2008 Cu 219: X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H 2 SO 4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l A. Ba. B. Ca. C. Sr. D. Mg. thi TSC 2008 Cu 220: Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch Y l A. 24,24%. B. 15,76%. C. 28,21%. D. 11,79%. thi TSC 2007

Cu 217:

- Kl tc dng HNO3, H2SO4 c Cu 221: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu
c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Fe(NO3)3. B. Fe(NO3)2. C. HNO3. D. Cu(NO3)2. thi TSHC khi B 2007 Cho hn hp X gm Mg v Fe vo dung dch axit H 2 SO 4 c, nng n khi cc phn ng xy ra Cu 222: hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v Fe2(SO4)3. B. MgSO4, Fe2(SO4)3 v FeSO4. C. MgSO4 v FeSO4. D. MgSO4. thi TSC 2007 Cu 223: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 0,8 lt. B. 1,0 lt. C. 0,6 lt. D. 1,2 lt. thi TSHC khi B 2008 Cu 224: Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy nht, ktc). Kh X l A. N2O. B. NO2. C. N2. D. NO. thi TSC 2008 Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (ktc) Cu 225: hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l A. 2,24. B. 4,48. C. 5,60. D. 3,36. thi TSHC khi A 2007 Cu 226: Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l A. 19,53%. B. 12,80%. C. 10,52%. D. 15,25%. thi TSC 2009 Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2 SO 4 c, nng (gi thit SO2 l sn phm kh Cu 227: duy nht). Sau khi phn ng xy ra hon ton, thu c A. 0,12 mol FeSO4. B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. thi TSHC khi B 2007 Cu 228: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml khNxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l A. NO v Mg. B. NO2 v Al. C. N2O v Al. D. N2O v Fe. thi TSHC khi A 2009 Cu 229: Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO 3. Sau khi cc phn ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam mui khan. Kh X l A. N2. B. NO. C. N2O. D. NO2. (TSC 2010) Cu 230: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO 3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12 . B. 0,14. C. 0,16. D. 0,18. (H B 2010) Cu 231: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO 2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l

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A. 44,8.

B. 40,5.

C. 33,6.

D. 50,4. (H khi A 2011)

- Kl tc dng dung dch mui Cu 232: Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra
hon ton, thu c hn hp rn gm ba kim loi l: A. Fe, Cu, Ag. B. Al, Cu, Ag. C. Al, Fe, Cu. D. Al, Fe, Ag. thi TSC 2008 Cu 233: Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l A. Fe(NO3)3 v Zn(NO3)2. B. Zn(NO3)2 v Fe(NO3)2. C. AgNO3 v Zn(NO3)2. D. Fe(NO3)2 v AgNO3. thi TSHC khi A 2009 Cu 234: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th in ho: Fe 3 + /Fe 2 + ng trc Ag +/Ag) A. 32,4. B. 64,8. C. 59,4. D. 54,0. thi TSHC khi A 2008 Cu 235: Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l A. 8,10 v 5,43. B. 1,08 v 5,43. C. 0,54 v 5,16. D. 1,08 v 5,16. thi TSC 2009 Cu 236: Tin hnh hai th nghim sau: - Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M; - Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so vi V2 l A. V1 = 10 V2. B. V1 = 5V2. C. V1 = 2 V2. D. V1 = V2. thi TSHC khi B 2008 Cu 237: Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l A. 13,1 gam. B. 14,1 gam. C. 17,0 gam. D. 19,5 gam. thi TSHC khi B 2008 2+ + Cu 238: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu v 1 mol Ag n khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn? A. 1,8. B. 1,5. C. 1,2. D. 2,0. thi TSHC khi A 2009 Cu 239: Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l A. 90,27%. B. 12,67%. C. 85,30%. D. 82,20%. thi TSHC khi B 2007 Cu 240: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam. D. 1,72 gam. thi TSHC khi B 2009 Cu 241: Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dung dch, em c cn thu c 18,8 gam mui khan. Kim loi M l A. Fe. B. Cu. C. Mg. D. Zn. thi TSC 2009 Cu 242 : Cho 19,3 gam hn hp bt Zn va Cu co ti l mol tng ng la 1 : 2 vao dung dich cha 0,2 mol Fe 2(SO4)3. Sau khi cac phan ng xay ra hoan toan, thu c m gam kim loai. Gia tri cua m la A. 6,40 B. 16,53 C. 12,00 D. 12,80 (H A 2010) - Kl tc dng vi phi kim Cu 243: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H 2 SO 4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. thi TSHC khi A 2007 Cu 244: Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 50 ml. B. 57 ml. C. 75 ml. D. 90 ml. thi TSHC khi A 2008 Cu 245: Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn X l A. 400 ml. B. 200 ml. C. 800 ml. D. 600 ml. thi TSC 2009

Trang 17/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

 ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,16. B. 0,18. C. 0,23. D. 0,08. thi TSHC khi A 2008 Cu 247: Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 8,75. B. 9,75. C. 6,50. D. 7,80. thi TSHC khi B 2008 Cu 248: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. thi TSHC khi A 2008 Cu 249: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l A. Mg. B. Ca. C. Be. D. Cu. thi TSC 2009 Cu 250: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G 4 va V lt kh O2 (ktc). Gi tr ca cn 4 V l A. 2,80. B. 3,36. C. 3,08. D. 4,48. thi TSC 2008 Cu 251: t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c 30,2 gam hn hp oxit. Th tch kh oxi (ktc) tham gia phn ng l: A. 17,92 lt B. 4,48 lt C. 11,20 lt D. 8,96 lt (C 2011)

Cu 246:

- Phn ng nhit luyn Cu 252: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau
phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO. thi TSHC khi A 2007 Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu Cu 253: c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm A. Mg, Fe, Cu. B. MgO, Fe3O4, Cu. C. MgO, Fe, Cu. D. Mg, Al, Fe, Cu. thi TSC 2007 Cu 254: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120. B. 0,896. C. 0,448. D. 0,224. thi TSC 2008 Cu 255: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,112. B. 0,560. C. 0,224. D. 0,448. thi TSHC khi A 2008 Cu 256: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. thi TSHC khi A 2009 Cu 257: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng A. Fe3O4; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. FeO; 75%. thi TSC 2007 6. Kim loi kim, kim loi kim th, nhm, st: 5 - iu ch, tinh ch Cu 258: Trong cng nghip, natri hiroxit c sn xut bng phng php NaNO3, khng c mng ngn in cc. A. in phn dung dch B. in phn dung dch NaCl, c mng ngn in cc. C. in phn dung dch NaCl, khng c mng ngn in cc. D. in phn NaCl nng chy. thi TSC 2007 Cu 259: Thc hin cc th nghim sau: (I) Cho dung dch NaCl vo dung dch KOH. (II) Cho dung dch Na2CO3 vo dung dch Ca(OH)2. (III) in phn dung dch NaCl vi in cc tr, c mng ngn. (IV) Cho Cu(OH)2 vo dung dch NaNO3. (V) Sc kh NH3 vo dung dch Na2CO3. (VI) Cho dung dch Na2SO4 vo dung dch Ba(OH)2.

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Cc th nghim u iu ch c NaOH l: A. II, III v VI. B. I, II v III. C. I, IV v V. D. II, V v VI. thi TSHC khi B 2009 Cu 260: Phn ng ho hc xy ra trong trng hp no di y khng thuc loi phn ng nhit nhm? A. Al tc dng vi Fe3O4 nung nng. B. Al tc dng vi axit H 2 SO 4 c, nng. C. Al tc dng vi CuO nung nng. D. Al tc dng vi Fe2O3 nung nng. thi TSC 2007 thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt: Cu 261: A. dng dung dch NaOH (d), kh CO2 (d), ri nung nng. B. dng kh H2 nhit cao, dung dch NaOH (d). C. dng kh CO nhit cao, dung dch HCl (d). D. dng dung dch NaOH (d), dung dch HCl (d), ri nung nng. thi TSHC khi B 2007 Cu 262: Nguyn tc luyn thp t gang l: A. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp. B. Dng cht kh CO kh oxit st thnh st nhit cao. C. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp. D. Tng thm hm lng cacbon trong gang thu c thp. thi TSHC khi B 2008 Cu 263: Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H 2SO4 (d), thu c dung dch cha 7,5 gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l A. NaHCO3. B. Ca(HCO3)2. C. Mg(HCO3)2. D. Ba(HCO3)2. (TSC 2010) Cu 264: Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l: A. Li, Na, Ca. B. Na, K, Mg. C. Be, Mg, Ca. D. Li, Na, K. (TSC 2010) Cu 265: Ho tan hon ton 6,645 gam hn hp mui clorua ca hai kim loi kim thuc hai chu k k tip nhau vo nc c dung dch X. Cho ton b dung dch X tc dng hon ton vi dung dch AgNO 3 (d), thu c 18,655 gam kt ta. Hai kim loi kim trn l: A. Na v K B. Rb v Cs C. Li v Na D. K v Rb (C 2011) Cu 266: Dy gm cc kim loi u c cu to mang tinh th lp phng tm khi l: A. Na, K, Ca, Ba B. Li, Na, K, Rb C. Li, Na, K , Mg D. Na, K, Ca, Be (C 2011) Cu 267: Nung nong tng cp cht trong binh kin: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2 (k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r) , (6) Al + NaCl (r). Cac trng hp xay ra phan ng oxi hoa kim loai la : A. (1), (3), (6) B. (2), (3), (4) C. (1), (4), (5) D. (2), (5), (6) (H A 2010) Cu 268: Phat biu nao sau y ung ? A. Cac kim loai: natri, bari, beri u tac dung vi nc nhit thng B. Kim loai xeri c dung ch tao t bao quang in C. Kim loai magie co kiu mang tinh th lp phng tm din D. Theo chiu tng dn cua in tich hat nhn, cac kim loai kim th (t beri n bari) co nhit nong chay giam dn (H A 2010) Cu 269: Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht vi lng d dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l A. natri v magie. B. liti v beri. C. kali v canxi. D. kali v bari. (H A 2010) Cu 270: Ha tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H 2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ha dung dch X bi dung dch Y, tng khi lng cc mui c to ra l A. 13,70 gam. B. 18,46 gam. C. 12,78 gam. D. 14,62 gam. (H A 2010) Cu 271: Phat biu nao sau y khng ung ? A. dd m c cua Na2SiO3 va K2SiO3 c goi la thuy tinh long B. am chay magie co th c dp tt bng cat kh C. CF2Cl2 bi cm s dung do khi thai ra khi quyn thi pha huy tng ozon D. Trong phong thi nghim, N2 c iu ch bng cach un nong dd NH4NO2 bao hoa (H B 2010) Cu 272: Hoa tan hoan toan 2,45 gam hn hp X gm hai kim loai kim th vao 200 ml dd HCl 1,25M, thu c dung dich Y cha cac cht tan co nng mol bng nhau. Hai kim loai trong X la A. Mg va Ca B. Be va Mg C. Mg va Sr D. Be va Ca (H B 2010) Cu 273: Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ha hc ca phn chua l A. Li2SO4.Al2(SO4)3.24H2O. B. K2SO4.Al2(SO4)3.24H2O. C. (NH4)2SO4.Al2(SO4)3.24H2O. D. (NH4)2SO4.Al2(SO4)3.24H2O. (H khi A 2011) Cu 274: Hp cht no ca canxi c dng c tng, b bt khi gy xng? A. Vi sng (CaO). B. Thch cao sng (CaSO4.2H2O). C. vi (CaCO3). D. Thch cao nung (CaSO4.H2O). (H khi A 2011) Cu 275: Khi lng ring ca canxi kim loi l 1,55 g/cm 3. Gi thit rng, trong tinh th canxi cc ngt l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l A. 0,155nm. B. 0,185 nm. C. 0,196 nm. D. 0,168 nm. (H khi A 2011)

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- Tc ha hc, s phn ng Cu 276: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng
vi lng d dung dch Ba(OH)2 to thnh kt ta l B. 4. C. 1. D. 3. thi TSC 2008 Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l Cu 277: A. NaOH v NaClO. B. NaOH v Na2CO3. C. Na2CO3 v NaClO. D. NaClO3 v Na2CO3. thi TSC 2007 Cu 278: T hai mui X v Y thc hin cc phn ng sau: to X X1 + CO2 X1 + H2O X2 X2 + Y X + Y1 + H2O X2 + 2Y X + Y2 + 2H2O Hai mui X, Y tng ng l A. BaCO3, Na2CO3 B. CaCO3, NaHSO4 C. MgCO3, NaHCO3 D. CaCO3, NaHCO3 thi TSHC khi A 2008 Cu 279: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v dung dch X. Nh t t dung dch NH3 n d vo dung dch X thu c kt ta, lc ht lng kt ta, nung n khi lng khng i thu c 2,04 gam cht rn. Gi tr ca V l A. 0,448. B. 0,224. C. 1,344. D. 0,672. (TSC 2010) A. 5. Cu 280: Cho s chuyn ho sau: +X +Y +Z CaO CaCl2 Ca(NO3)2 CaCO3. Cng thc ca X, Y, Z ln lt l: A. HCl, AgNO3, (NH4)2CO3. B. Cl2, AgNO3, MgCO3. C. Cl2, HNO3, CO2. D. HCl, HNO3, Na2CO3. (TSC 2010) Cu 281: ho tan hon ton 6,4 gam hn hp gm kim loi R (ch c ho tr II) v oxit ca n cn va 400 ml dung dch HCl 1M. Kim loi R l: A. Ba B. Ca C. Be D. Mg (C 2011) Cu 282: Cho m gam NaOH vao 2 lit dung dich NaHCO3 nng a mol/l, thu c 2 lit dung dich X. Ly 1 lit dung dich X tac dung vi dung dich BaCl2 (d) thu c 11,82 gam kt tua. Mt khac, cho 1 lit dung dich X vao dung dich CaCl2 (d) ri un nong, sau khi kt thuc cac phan ng thu c 7,0 gam kt tua. Gia tri cua a, m tng ng la A. 0,04 va 4,8 B. 0,07 va 3,2 C. 0,08 va 4,8 D. 0,14 va 2,4 (H A 2010) Cu 283: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l: A. Na, K, Ba B. Mg, Ca, Ba C. Na, K , Ca D. Li , Na, Mg(H khi B 2011)

- Nc cng Cu 284:

2Mt mu nc cng cha cc ion: Ca2+, M g 2 + , HCO 3 , Cl-, SO 4 . Cht c dng lm mm mu nc cng trn l A. HCl. B. H 2 SO 4 . C. Na2CO3. D. NaHCO3. thi TSHC khi B 2008 Cu 285: Hai cht c dng lm mm nc cng vnh cu l A. Na2CO3 v HCl. B. Na2CO3 v Na3PO4. C. Na2CO3 v Ca(OH)2. D. NaCl v Ca(OH)2. thi TSC 2008 Cu 286: Mt cc nc c cha cc ion : Na+ (0,02 mol), Mg2+ (0,02 mol), Ca2+ (0,04 mol), Cl- (0,02 mol), HCO3- (0,10 mol) v SO42- (0,01 mol) . un si cc nc trn cho n khi phn ng xy ra hon ton th nc cn li trong cc A. c tnh cng ton phn B. c tnh cng vnh cu C. l nc mm D. c tnh cng tm thi (C 2011) Cu 287: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l: A. HCl, NaOH, Na2CO3 B. NaOH, Na3PO4, Na2CO3. C. KCl, Ca(OH)2, Na2CO3. D. HCl, Ca(OH)2, Na2CO3. (H khi A 2011)

- Kl tc dng vi nc, axit, baz, mui Cu 288: Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2
(ktc). Th tch dung dch axit H 2 SO 4 2M cn dng trung ho dung dch X l B. 150ml. C. 30ml. D. 75ml. thi TSC 2007 Cu 289: Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l A. 0,75M. B. 1M. C. 0,5M. D. 0,25M. thi TSC 2007 Cu 290: Chia m gam Al thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh H2; - Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht). Quan h gia x v y l A. x = 2y. B. y = 2x. C. x = 4y. D. x = y. thi TSC 2008 Cu 291: Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l A. 60ml.

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B. 7,8. C. 10,8. D. 43,2. thi TSHC khi A 2008 Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th tch kh o trong cng iu kin) A. 77,31%. B. 39,87%. C. 49,87%. D. 29,87%. thi TSHC khi B 2007 Cu 293: Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l A. Na. B. Ca. C. Ba. D. K. thi TSHC khi B 2009 Cu 294: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l A. 0,55. B. 0,60. C. 0,45. D. 0,40. thi TSHC khi A 2008 Cu 295: Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO 4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l A. 37,58%. B. 56,37%. C. 64,42%. D. 43,62%. (TSC 2010) A. 5,4.

Cu 292:

- CO2, SO2, P2O5 td dung dch kim Cu 296: Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v
kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l A. 5,8 gam. B. 4,2 gam. C. 6,3 gam. D. 6,5 gam. thi TSHC khi B 2007 Cu 297: Hp th hon ton 4,48 lt kh CO2 (ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l A. 9,85. B. 11,82. C. 19,70. D. 17,73. thi TSHC khi A 2008 Cu 298: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l A. 1,182. B. 3,940. C. 1,970. D. 2,364. thi TSHC khi A 2009 Hp th hon ton 2,688 lt kh CO2(ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu Cu 299: c 15,76 gam kt ta. Gi tr ca a l A. 0,032. B. 0,048. C. 0,06. D. 0,04. thi TSHC khi A 2007 Cu 300: Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l A. KH2PO4 v K3PO4. B. KH2PO4 v K2HPO4. C. KH2PO4 v H3PO4. D. K3PO4 v KOH. thi TSHC khi B 2009 Cu 301: Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht: A. K2HPO4, KH2PO4. B. K3PO4, KOH. C. H3PO4, KH2PO4. D. K3PO4, K2HPO4. thi TSHC khi B 2008 Cu 302: Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M, thu c dung dch X. Coi th tch dung dch khng thay i, nng mol ca cht tan trong dung dch X l A. 0,4M. B. 0,6M. C. 0,1M. D. 0,2M. (TSC 2010) Cu 303: Hp th hon ton 0,672 lt kh CO 2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH) 2 0,0125M, thu c x gam kt ta. Gi tr ca x l A. 2,00. B. 0,75. C. 1,00. D. 1,25. (H khi A 2011) Cu 304: Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K 2CO3 0,2M v KOH x mol/lt , sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl 2 (d), thu c 11,82 gam kt ta. Gi tr ca x l: A. 1,0 B . 1,4 C. 1,2 D. 1,6(H khi B 2011) 2+ - CO3 tc dng H Cu 305: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l: A. V = 22,4(a - b). B. V = 11,2(a - b). C. V = 11,2(a + b). D. V = 22,4(a + b). thi TSHC khi A 2007 Cu 306: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 2,24. D. 1,12. thi TSHC khi A 2009 Cu 307: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l A. Na. B. Li. C. K. D. Rb. thi TSHC khi B 2008 Cu 308: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO2(ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l

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A. 50%. B. 84%. C. 40%. D. 92%. thi TSHC khi B 2008 Cu 309: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na 2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l A. 0,030. B. 0,010. C. 0,020. D. 0,015. (H A 2010)

- Tnh lng tnh ca Al(OH)3, Zn(OH)2 Cu 310: Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l
A. c kt ta keo trng, sau kt ta tan. B. ch c kt ta keo trng. C. c kt ta keo trng v c kh bay ln. D. khng c kt ta, c kh bay ln. thi TSHC khi A 2007 Cu 311: Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 2,568. B. 1,560. C. 4,128. D. 5,064. thi TSC 2009 Cu 312: Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l A. 7,8. B. 46,6. C. 54,4. D. 62,2. thi TSC 2009 Cu 313: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. thi TSHC khi A 2007 Cu 314: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l A. 1,2. B. 1,8. C. 2,4. D. 2. thi TSHC khi B 2007 Cu 315: Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H 2 SO 4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l A. 0,35. B. 0,45. C. 0,25. D. 0,05. thi TSHC khi A 2008 Cu 316: Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l A. 1,59. B. 1,17. C. 1,95. D. 1,71. thi TSC 2007 Cu 317: Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 20,125. B. 22,540. C. 12,375. D. 17,710. thi TSHC khi A 2009 Cu 318: Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l A. 8,3 v 7,2. B. 11,3 v 7,8. C. 13,3 v 3,9. D. 8,2 v 7,8. thi TSC 2009 Cu 319: Nh t t dung dch NaOH n d vo dung dch X. Sau khi cc phn ng xy ra hon ton ch thu c dung dch trong sut. Cht tan trong dung dch X l A. CuSO4. B. Fe(NO3)3. C. AlCl3. D. Ca(HCO3)2. (TSC 2010) Cu 320: Hoa tan hoan toan m gam ZnSO4 vao nc c dung dich X. Nu cho 110 ml dung dich KOH 2M vao X thi thu c 3a gam kt tua. Mt khac, nu cho 140 ml dung dich KOH 2M vao X thi thu c 2a gam kt tua. Gia tri cua m la A. 32,20 B. 24,15 C. 17,71 D. 16,10 (H A 2010) Cu 321: Cho cac cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tac dung c vi dung dich NaOH loang nhit thng la A. 4 B. 5 C. 3 D. 6 (H A 2010) Cu 322: Cho 150 ml dd KOH 1,2M tac dung vi 100 ml dd AlCl3 nng x mol/l, thu c dd Y va 4,68 gam kt tua. Loai bo kt tua, thm tip 175 ml dd KOH 1,2M vao Y, thu c 2,34 gam kt tua. Gia tri cua x la A. 1,2 B. 0,8 C. 0,9 D. 1,0 (H B 2010) Cu 323: Pht biu no sau y l sai? A. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. B. nhit thng, tt c kim loi kim th u tc dng c vi nc. C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn(H khi B 2011) Cu 324: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl 2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 4 : 3 B. 3 : 4 C. 7 : 4 D. 3 : 2(H khi B 2011) Cu 325: Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH( c, nng) l A. 6 B. 3 C. 5 D. 4(H khi B 2011)

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- Phn ng nhit nhm Cu 326: iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca
phn ng l 90% th khi lng bt nhm cn dng ti thiu l A. 81,0 gam. B. 54,0 gam. C. 40,5 gam. D. 45,0 gam. thi TSC 2009 Cu 327: Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 (ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 7,84. D. 10,08. thi TSHC khi B 2007 Cu 328: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l A. 20,33%. B. 50,67%. C. 36,71%. D. 66,67%. thi TSC 2007 Cu 329: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H 2 SO 4 long (d), sinh ra 3,08 lt kh H2 (ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 (ktc). Gi tr ca m l A. 22,75 B. 29,43. C. 29,40. D. 21,40. thi TSHC khi A 2008 Cu 330: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l A. 45,6. B. 48,3. C. 36,7. D. 36,7. thi TSHC khi B 2009 Cu 331: t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 (ktc). Gi tr ca V l A. 150. B. 100. C. 200. D. 300. thi TSC 2008 Cu 332: Thc hin cc phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H 2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi phn ng kt thc th s mol NaOH phn ng l: A. 0,06 mol B. 0,14 mol C. 0,08 mol D. 0,16 mol(H khi B 2011)

- Fe p dng cng thc kinh nghim Cu 333: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X
trong dung dch HNO3(d), thot ra 0,56 lt (ktc) NO (l sn phm kh duy nht). Gi tr ca m l B. 2,22. C. 2,32. D. 2,62. thi TSHC khi B 2007 Cu 334: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. thi TSHC khi A 2008 Cu 335: Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng c khng kh), sau khi phn ng xy ra hon ton thu c cht rn Y. Khi lng kim loi trong Y l: A. 5,6 gam B. 22,4 gam C. 11,2 gam D.16,6 gam (C 2011) Cu 336: Dy gm cc oxit u b Al kh nhit cao l: A. FeO, CuO, Cr2O3 B. PbO, K2O, SnO C. FeO, MgO, CuO D. Fe3O4, SnO, BaO (C 2011) Cu 337: Trn 10,8g bt Al vi 34,8g bt Fe3O4 ri tin hanh phan ng nhit nhm trong iu kin khng co khng khi. Hoa tan hoan toan hn hp rn sau phan ng bng dd H 2SO4 loang (d) thu c 10,752 lit khi H 2 (ktc). Hiu sut cua phan ng nhit nhm la A. 80% B. 90% C. 70% D. 60% (H B 2010) Cu 338: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ha tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l A. Cr2O3. B. FeO. C. Fe3O4. D. CrO. (H B 2010) A. 2,52.

- Fe, Cu tc dng HNO3, H2SO4 c Cu 339: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu
c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Fe(NO3)3 B. Fe(NO3)2 C. HNO3. D. Cu(NO3)2. thi TSHC khi B 2007 Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng xy ra Cu 340: hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v Fe2(SO4)3. B. MgSO4, Fe2(SO4)3 v FeSO4. C. MgSO4 v FeSO4. D. MgSO4. thi TSC 2007

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Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2 SO 4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c A. 0,12 mol FeSO4. B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. thi TSHC khi B 2007 Cu 342: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 0,8 lt. B. 1,0 lt. C. 0,6 lt. D. 1,2 lt. thi TSHC khi B 2008 Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (ktc) Cu 343: hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l A. 2,24. B. 4,48. C. 5,60. D. 3,36. thi TSHC khi A 2007 Cu 344: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 1,92. B. 3,20. C. 0,64. D. 3,84. thi TSHC khi A 2009 Cu 345: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l B. 137,1. C. 97,5. D. 108,9. thi TSHC khi B 2009

Cu 341:

A. 151,5.

Trong cc loi qung st, qung c hm lng st cao nht l B. xierit. C. hematit nu. D. manhetit. thi TSHC khi A 2008 Cu 347: Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO 3 trong khng kh n khi lng khng i, thu c mt cht rn l A. Fe3O4. B. FeO. C. Fe. D. Fe2O3. thi TSHC khi A 2007 Cu 348: Ha tan hon ton Fe3O4 trong dung dch H 2 SO 4 long (d) c dung dch X1. Cho lng d bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c dung dch X2 cha cht tan l A. Fe2(SO4)3 v H 2 SO 4 . B. FeSO4. C. Fe2(SO4)3. D. FeSO4 v H 2 SO 4 . thi TSC 2008 Cu 349: Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha khi tc dng vi dung dch HNO3 c, nng l A. 3. B. 5. C. 4 D. 6. thi TSC 2008 Cu 350: Trong cc cht: FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ho v tnh kh l A. 2. B. 3. C. 5. D. 4. thi TSC 2009 Cu 351: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3 , FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. thi TSHC khi A 2007 Ho tan 5,6 gam Fe bng dung dch H 2 SO 4 long (d), thu c dung dch X. Dung dch X phn Cu 352: ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l A. 80. B. 40. C. 20. D. 60. thi TSHC khi A 2007 Cu 353: ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,16. B. 0,18. C. 0,23. D. 0,08. thi TSHC khi A 2008 Cu 354: Cho 9,12 gam hn hp gm FeO, Fe3O4 v Fe2O3 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 8,75. B. 9,75. C. 6,50. D. 7,80. thi TSHC khi B 2008 Cu 355: Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m2 gam mui khan. Bit m2 m1 = 0,71. Th tch dung dch HCl dng l A. 240 ml. B. 80 ml. C. 320 ml. D. 160 ml. thi TSC 2009 Cu 356: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. thi TSHC khi A 2008 A. hematit .

- Hp cht ca Fe Cu 346:

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Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l A. 52,2. B. 54,0. C. 58,0. D. 48,4. thi TSHC khi B 2009 Cho 0,01 mol mt hp cht ca st tc dng ht vi H 2 SO 4 c nng (d), thot ra 0,112 lt Cu 358: (ktc) kh SO2 l sn phm kh duy nht). Cng thc ca hp cht st l A. FeS. B. FeS2. C. FeO D. FeCO 3 . thi TSHC khi B 2007 Cu 359: Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l A. Fe3O4 v 0,224. B. Fe3O4 v 0,448. C. FeO v 0,224. D. Fe2O3 v 0,448. thi TSC 2009 Cu 360: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l A. Fe3O4; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. FeO; 75%. thi TSC 2007 Cu 361: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l A. 2,16. B. 5,04. C. 4,32. D. 2,88. thi TSC 2009 Cu 362: Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO3 2M, thu c m gam kt ta. Gi tr ca m l A. 34,44. B. 47,4. C. 30,18. D. 12,96. thi TSC 2009 Cu 363: Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 57,4. B. 28,7. C. 10,8. D. 68,2. thi TSHC khi B 2009 Cu 364: Nung mt hn hp rn gm a mol FeCO 3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4) A. a = 4b. B. a = 2b. C. a = b. D. a = 0,5b. thi TSHC khi B 2008 Cu 365: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi tr ca V l A. 2,80. B. 3,36. C. 3,08. D. 4,48. thi TSC 2008 Cu 366: Ho tan hon ton hn hp X gm 0,2 mol Fe v 0,2 mol Fe 2O3 vo dung dch axit H2SO4 long (d), thu c 2,24 lt kh (ktc) v dung dch Y. Cho lng d dung dch NaOH vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Gi tr nh nht ca m l: A. 54,0 B. 59,1 C. 60,8 D. 57,4 (C 2011) Cu 367: Cho hn hp X gm Cu, Ag, Fe, Al tc dng vi oxi d khi un nng c cht rn Y. Cho Y vo dung dch HCl d, khuy k, sau ly dung dch thu c cho tc dng vi dung dch NaOH long, d. Lc ly kt ta to thnh em nung trong khng kh n khi lng khng i thu c cht rn Z. Bit cc phn ng xy ra han tan. Thnh phn ca Z gm: A. Fe2O3, CuO, Ag. B. Fe2O3, CuO, Ag2O. C. Fe2O3, Al2O3.D. Fe2O3, CuO. (C 2011) Cu 368: Cho dd X cha KMnO4 va H2SO4 (loang) ln lt vao cac dd : FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp co xay ra phan ng oxi hoa - kh la A. 3 B. 5 C. 4 D. 6 (H B 2010) Cu 369: Cho s chuyn ha: Fe3O4 + dd HI (d) X + Y + H2O Bit X v Y l sn phm cui cng ca qu trnh chuyn ha. Cc cht X v Y l A. Fe v I2. B. FeI3 v FeI2. C. FeI2 v I2. D. FeI3 v I2. (H B 2010) Cu 370: Qung st manhetit c thnh phn chnh l A. FeS2. B. Fe3O4. C. Fe2O3. D. FeCO3. (H khi A 2011) Cu 371: Nung m gam hn hp X gm FeS v FeS 2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l A. 42,31%. B. 59,46%. C. 19,64%. D. 26,83%.(H khi A 2011) Cu 372: Thc hin cc th nghim sau: (1) t dy st trong kh clo. (2) t nng hn hp bt Fe v S (trong iu kin khng c oxi).

Cu 357:

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(3) Cho FeO vo dung dch HNO3 (long, d). (4) Cho Fe vo dung dch Fe2(SO4)3. (5) Cho Fe vo dung dch H2SO4 (long, d). C bao nhiu th nghim to ra mui st (II) ? A. 4 B. 2 C. 3 D. 1(H khi A 2011) Cu 373: luyn c 800 tn gang c hm lng st 95% , cn dng x tn qung manhetit cha 80% Fe 3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr ca x l: A. 959,59 B. 1311,90 C. 1394,90 D. 1325,16(H khi B 2011) Cu 374: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l: A. Bt Mg, dung dch NaNO3, dung dch HCL B. Bt Mg, dung dch BaCl2, dung dch HNO3 C. Kh Cl2, dung dch Na2CO3, dung dch HCL D. Kh Cl2, dung dch Na2S, dung dch HNO3(H khi B 2011) Cu 375: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l A.32,50 B. 20,80 C. 29,25 D. 48,75(H khi B 2011)

7. Crom, ng, niken, ch, km, bc, vng, thic: 2 Cu 376: Pht biu khng ng l:
A. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh. B. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh. C. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng c vi dung dch NaOH. D. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat. thi TSHC khi A 2007 Cu 377: Cho s chuyn ho gia cc hp cht ca crom:
+ (Cl 2 + KOH) + H2 SO4 + FeSO + H SO + KOH 4 2 4 Cr(OH) 3 X Y Z T

Cc cht X, Y, Z, T theo th t ln lt l: A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3. B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3. C. KCrO2; K2Cr2O7; K2CrO4; CrSO4. D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3. Cu 378: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 2. B. 1. C. 3. D. 4. thi TSHC khi B 2008 Cu 379: Cho cc phn ng: o o (1) Cu2O + Cu2S t (2) Cu(NO3)2 t (3) CuO + CO t (4) CuO + NH3 t S phn ng to ra kim loi Cu l : A. 1 B. 2 C. 3 D. 4 thi TSHC khi B 2007 Cu 380: Trng hp xy ra phn ng l A. Cu + Pb(NO3)2 (long) B. Cu + HCl (long) C. Cu + H2SO4 (long) D. Cu + HCl (long) + O2 thi TSHC khi A 2009 Cu 381: Cho s chuyn ha qung ng thnh ng :
2 CuFeS2 2 X Y Cu Hai cht X, Y ln lt l A. Cu2O, CuO B. CuS, CuO C. Cu2S, CuO D. Cu2S, Cu2O thi TSHC khi A 2008 Cu 382: iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l A. 81,0 gam. B. 54,0 gam. C. 40,5 gam. D. 45,0 gam. thi TSC 2009 Cu 383: Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 (ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 7,84. D. 10,08. thi TSHC khi B 2007 Cu 384: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l A. 20,33%. B. 50,67%. C. 36,71%. D. 66,67%. thi TSC 2007 Cu 385: oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v KOH tng ng l A. 0,03 mol v 0,08 mol. B. 0,015 mol v 0,08 mol. C. 0,015 mol v 0,04 mol. D. 0,03 mol v 0,04 mol. thi TSHC khi A 2008 Cu 386: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong + O ,t0 +O ,t0 + X,t0
o o

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hn hp X v gi tr ca m ln lt l A. 21,95% v 2,25. B. 78,05% v 2,25.C. 21,95% v 0,78.D. 78,05% v 0,78. thi TSHC khi B 2009 Cu 387: Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l A. 2,80 lt. B. 1,68 lt. C. 4,48 lt. D. 3,92 lt. thi TSHC khi A 2009 Cu 388: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l A. 0,03 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,06 v 0,02. thi TSHC khi B 2009 Cu 389: Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l A. 95,00%. B. 25,31%. C. 74,69%. D. 64,68%. thi TSHC khi A 2009 Cu 390: Cht rn X phn ng vi dung dch HCl c dung dch Y. Cho t t dung dch NH 3 n d vo dung dch Y, ban u xut hin kt ta xanh, sau kt ta tan, thu c dung dch mu xanh thm. Cht X l A. CuO. B. Cu. C. Fe. D. FeO. (TSC 2010) Cu 391: Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn hp gm HCl v NaNO3. Nhng dung dch phn ng c vi kim loi Cu l: A. (1), (3), (4). B. (1), (2), (3). C. (1), (4), (5). D. (1), (3), (5). (TSC 2010) Cu 392: Pht biu no sau y khng ng? A. Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+. B. Crom(VI) oxit l oxit baz. C. Ancol etylic bc chy khi tip xc vi CrO3. D. Crom(III) oxit v crom(III) hiroxit u l cht c tnh lng tnh. Cu 393: Cho m gam bt crom phn ng hon ton vi dung dch HCl (d), thu c V lt kh H2 (ktc). Mt khc, cng m gam bt crom trn phn ng hon ton vi kh O2 (d), thu c 15,2 gam oxit duy nht. Gi tr ca V l A. 4,48. B. 6,72. C. 3,36. D. 2,24. (TSC 2010) Cu 394: Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan han tan 2m gam hn hp X vo nc thu c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl3 1M n phn ng han tan thu c kt ta c khi lng l A. 54,0 gam. B. 20,6 gam. C. 30,9 gam. D. 51,5 gam. (C 2011) Cu 395: Khi cho lng d dung dch KOH vo ng nghim ng dung dch kali icromat, dung dch trong ng nghim A. Chuyn t mu da cam sang mu xanh lc. B. Chuyn t mu da cam sang mu vng. C. Chuyn t mu vng sang mu . D. Chuyn t mu vng sang mu da cam. (C 2011) Cu 396: Co cac phat biu sau : (1) Lu huynh, photpho u bc chay khi tip xuc vi CrO3 (2) Ion Fe3+ co cu hinh electron vit gon la [Ar]3d5 (3) Bt nhm t bc chay khi tip xuc vi khi clo (4) Phen chua co cng thc Na2SO4.Al2(SO4)3.24H2O Cac phat biu ung la A. (1), (3), (4) B. (2), (3), (4) C. (1), (2), (3) D. (1), (2), (4) (H A 2010) Cu 397: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca nhm v crom? A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui. B. Nhm c tnh kh mnh hn crom. C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. D. Nhm v crom u bn trong khng kh v trong nc. (H B 2010) Cu 398: Ha tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dd H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 39,34%. B. 65,57%. C. 26,23%. D. 13,11%. (H B 2010) Cu 399: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 4. B. 1. C. 3. D. 2. (H khi A 2011) Cu 56: Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch Na2CrO4 l: A. Dung dch chuyn t mu vng sau khng mu B. Dung dch chuyn t mu da cam sang mu vng. C. Dung dch chuyn t mu vng sang mu da cam. D. Dung dch chuyn t khng mu sang mu da cam(H khi A 2011) Cu 400: Cho dy cc oxi sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l: A. 5 B. 6 C. 8 D. 7(H khi B 2011)

8. Tng hp ni dung cc kin thc ha v c thuc chng trnh ph thng: 6 Tinh ch, phn bit, s , phn ng Cu 401: C th dng NaOH ( th rn) lm kh cc cht kh Trang 27/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

A. N2, NO2, CO2, CH4, H2. B. NH3, SO2, CO, Cl2. C. N2, Cl2, O2, CO2, H2. D. NH3, O2, N2, CH4, H2. thi TSC 2007 Cu 402: Cht dng lm kh kh Cl2 m l A. nc brom. B. CaO D. dung dch NaOH thi TSC 2009 C. dung dch Ba(OH)2 Cu 403: thu ly Ag tinh khit t hn hp X (gm a mol Al 2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%) A. c mol bt Al vo Y. B. c mol bt Cu vo Y. C. 2c mol bt Al vo Y. D. 2c mol bt Cu vo Y. thi TSHC khi A 2007 Cu 404: phn bit CO2 v SO2 ch cn dng thuc th l A. nc brom. B. CaO. C. dung dch Ba(OH)2. D. dung dch NaOH. thi TSC 2009 Cu 405: nhn bit ba axit c, ngui: HCl, H 2 SO 4 , HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l A. Fe. B. CuO. C. Al. D. Cu. thi TSHC khi A 2007 Cu 406: C th phn bit 3 dung dch: KOH, HCl, H 2 SO 4 (long) bng mt thuc th l A. Zn. B. Al. C. giy qu tm. D. BaCO3. thi TSHC khi B 2007 Cu 407: Ch dng dung dch KOH phn bit c cc cht ring bit trong nhm no sau y? A. Mg, Al2O3, Al. B. Mg, K, Na C. Zn, Al2O3, Al D. Fe, Al2O3, Mg thi TSC 2009 Cu 408: Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl 2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha A. NaCl. B. NaCl, NaOH, BaCl 2 . C. NaCl, NaOH. D. NaCl, NaHCO3, NH4Cl, BaCl 2 . thi TSHC khi B 2007 Cu 409: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 3. B. 2. C. 1. D. 4. thi TSHC khi A 2009 Cu 410: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l A. 4. B. 1. C. 3. D. 2. thi TSHC khi A 2007 Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2 dy gm cc cht u Cu 411: tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, NaCl, Na2SO4. thi TSHC khi B 2007 Cu 412: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 2. B. 1. C. 3. D. 4. thi TSHC khi B 2008 Cu 413: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch A. NH3 (d). B. NaOH (d). C. AgNO3 (d). D. HCl (d). thi TSHC khi B 2008 Cu 414: Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh kt ta khi phn ng vi dung dch BaCl 2 l A. 4. B. 6. C. 3. D. 2. thi TSC 2008 Cu 415: C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l A. 4. B. 2. C. 5. D. 3. thi TSHC khi A 2009 Cu 416: Th nghim no sau y c kt ta sau phn ng? A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. B. Cho dung dch NH3 n d vo dung dch AlCl3 C. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]) D. Thi CO2 n d vo dung dch Ca(OH)2. thi TSHC khi B 2009 Cu 417: Cc kh c th cng tn ti trong mt hn hp l A. Cl2 v O2. B. H2S v Cl2. C. NH3 v HCl. D. HI v O3. thi TSC 2007 Cu 418: Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dung dch l: + 23A. Al3+, NH 4 , Br-, OH-. B. M g 2 + , K+, SO 4 , PO 4

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 thi TSC 2009 Trng hp no sau y khng xy ra phn ng ho hc? A. Sc kh Cl2 vo dung dch FeCl2. B. Sc kh H2S vo dung dch CuCl2. C. Sc kh H2S vo dung dch FeCl2. D. Cho Fe vo dung dch H2SO4 long, ngui. thi TSHC khi A 2009 Cu 420: C cc th nghim sau: (I) Nhng thanh st vo dung dch H2SO4 long, ngui. (II) Sc kh SO2 vo nc brom. (III) Sc kh CO2 vo nc Gia-ven. (IV) Nhng l nhm vo dung dch H2SO4 c, ngui. S th nghim xy ra phn ng ho hc l A. 2. B. 1. C. 3. D. 4. thi TSHC khi B 2009 Cu 421: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l A. hn hp gm BaSO4 v FeO. B. hn hp gm Al2O3 v Fe2O3. C. hn hp gm BaSO4 v Fe2O3. D. Fe2O3. thi TSHC khi B 2009 Cu 422: Cho cc phn ng sau : 0 H2S + O2 (d) t Kh X + H2O

2C. H+, Fe 3 + , NO 3 , SO 4

D. Ag + , Na + , NO 3 , Cl - .

Cu 419:

850 NH3 + O2 C,Pt Kh Y + H2O NH4HCO3 + HCl long Kh Z + NH4Cl + H2O Cc kh X, Y, Z thu c ln lt l A. SO3, NO, NH3 B. SO2, N2, NH3 C. SO2, NO, CO2 D. SO3, N2, CO2 thi TSHC khi B 2008 Cu 423: Cho s chuyn ho (mi mi tn l mt phng trnh phn ng):
+ dd X + dd Y + dd Z NaOH Fe(OH) 2 Fe 2(SO 4) BaSO 3 4

Cc dd (dung dch) X, Y, Z ln lt l: A. FeCl3, H 2 SO 4 (c, nng), Ba(NO3)2. B. FeCl3, H 2 SO 4 c nng, BaCl 2 . C. FeCl2, H 2 SO 4 c nng, BaCl 2 . D. FeCl3, H 2 SO 4 c nng, Ba(NO 3 ) 2 . thi TSC 2008 Cu 424: Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s mol mui tng ng. t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu vng. Hai mui X, Y ln lt l: A. KMnO4, NaNO3. B. Cu(NO3)2, NaNO3. C. CaCO3, NaNO3. D. NaNO3, KNO3. thi TSHC khi B 2009 Cu 425: Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l A. Mg. B. Al. C. Zn. D. Fe. thi TSC 2007 Cu 426: Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y. Sc kh CO2 n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l A. Al(OH)3. B. Fe(OH)3. C. K2CO3. D. BaCO3. (TSC 2010) Cu 427: Thuc th dng phn bit 3 dung dch ring bit: NaCl, NaHSO4, HCl l A. BaCO3. B. NH4Cl. C. BaCl2. D. (NH4)2CO3. (TSC 2010) Cu 428: Tin hnh cc th nghim sau (1) Sc kh H2S vo dung dch FeSO4 (2) Sc kh H2S vo dung dch CuSO4 (3) Sc kh CO2 (d) vo dung dch Na2SiO3 (4) Sc kh CO2 (d) vo dung dch Ca(OH)2 (5) Nh t t dung dch NH3 n d vo dung dch Al2(SO4)3 (6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3 Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l: A. 3 B. 6 C. 4 D. 5 (C 2011) Cu 429: C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha mt trong cc dung dch AgNO 3, ZnCl2, HI, Na2CO3. Bit rng: - Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh. - Dung dch trong ng nghim 2 v 4 khng phn ng c vi nhau. Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l: A. AgNO3, Na2CO3, HI, ZnCl2 B. ZnCl2, HI, Na2CO3, AgNO3 C. ZnCl2, Na2CO3, HI, AgNO3 D. AgNO3, HI, Na2CO3, ZnCl2 (C 2011) Cu 430: Thc hin cac thi nghim sau : (I) Suc khi SO2 vao dung dich KMnO4 (II) Suc khi SO2 vao dung dich H2S

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(III) Suc hn hp khi NO2 va O2 vao nc (IV) Cho MnO2 vao dung dich HCl c, nong (V) Cho Fe2O3 vao dung dich H2SO4 c, nong (VI) Cho SiO2 vao dung dich HF S thi nghim co phan ng oxi hoa - kh xay ra la A. 3 B. 6 C. 5 D. 4 (H A 2010) Cu 431: Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc dng c vi c 4 dung dch trn l A. KOH. B. BaCl2. C. NH3. D. NaNO3. (H A 2010) Cu 432: Cc cht va tc dng c vi dung dch HCl va tc dng c vi dung dch AgNO3 l: A. CuO, Al, Mg. B. Zn, Cu, Fe. C. MgO, Na, Ba. D. Zn, Ni, Sn. (H A 2010) Cu 433: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng l A. 2,016 lt. B. 0,672 lt. C. 1,344 lt. D. 1,008 lt. (H A 2010) Cu 434: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch A. Pb(NO3)2. B. NaHS. C. AgNO3. D. NaOH. (H B 2010) Cu 435: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 4. B. 7. C. 5. D. 6. (H B 2010) Cu 436: Pht biu no sau y khng ng? A. Trong cc dd: HCl, H2SO4, H2S c cng nng 0,01M, dd H2S c pH ln nht. B. Nh dd NH3 t t ti d vo dd CuSO4, thu c kt ta xanh. C. dd Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng. D. Nh dd NH3 t t ti d vo dd AlCl3, thu c kt ta trng. (H B 2010) Cu 437: Hn hp X gm CuO va Fe2O3. Hoa tan hoan toan 44 gam X bng dd HCl (d), sau phan ng thu c dd cha 85,25 gam mui. Mt khac, nu kh hoan toan 22 gam X bng CO (d), cho hn hp khi thu c sau phan ng li t t qua dd Ba(OH)2 (d) thi thu c m gam kt tua. Gia tri cua m la A. 76,755 B. 73,875 C. 147,750 D. 78,875(H B 2010) Cu 438: Hn hp bt X gm Cu, Zn. t chay hoan toan m gam X trong oxi (d), thu c 40,3 gam hn hp gm CuO va ZnO. Mt khac, nu cho 0,25 mol X phan ng vi mt lng d dd KOH loang nong, thi thu c 3,36 lit khi H 2 (ktc). Phn trm khi lng cua Cu trong X la A. 19,81% B. 29,72% C. 39,63% D. 59,44% (H B 2010) Cu 439: Tin hnh cc th nghim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO3)2. (2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (3) Sc kh H2S vo dung dch FeCl2. (4) Sc kh NH3 ti d vo dung dch AlCl3. (5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (6) Sc kh etilen vo dung dch KMnO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 3. B. 4. C. 6. D. 5. (H khi A 2011) Cu 440: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau. - Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc). - Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ha tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp X ln lt l: A. 0,39; 0,54; 1,40. B. 0,78; 0,54; 1,12. C. 0,39; 0,54; 0,56. D. 0,78; 1,08; 0,56. (H khi A 2011) Cu 441: Trong c th nghim sau : (1) Cho SiO2 tc dng vi axit HF. (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. S th nghim to ra n cht l: A. 4 B. 7 C. 6 D. 5(H khi A 2011) Cu 442: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO 4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d). sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l:

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A. 58,52% B. 51,85% C. 48,15% D. 41,48%(H khi A 2011) Cu 443: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta: A. Fe(OH)3 v Zn(OH)2 B. Fe(OH)2, Cu(OH)2 v Zn(OH)2 . C. Fe(OH)2 D. Fe(OH)2 v Cu(OH)2(H khi A 2011) Cu 444: Pht biu no sau y l sai? A. Nhm l kim loi dn in tt hn vng. B. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x. C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh eczema, bnh nga D. Thic c th dng ph ln b mt ca st chng g. Cu 445: Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH? A. 2 B. 3 C. 4 D. 5(H khi B 2011) Cu 446: Thc hin cc th nghim sau: (a) Nhit phn AgNO3 (b) Nung FeS2 trong khng kh (c) Nhit phn KNO3 (d) Cho dung dch CuSO4 vo dung dch NH3 (d) (e) Cho Fe vo dung dch CuSO4 (g) Cho Zn vo dung dch FeCl3 (d) (h) Nung Ag2S trong khng kh (i) Cho Ba vo dung dch CuSO4 (d) S th nghim thu c kim loi sau khi cc phn ng kt thc l A. 3 B. 5 C. 2 D. 4(H khi B 2011) Cu 447: Ha tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y. Thm H2SO4 (d) vo 20ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l A.13,68% B. 68,4% C. 9,12% D. 31,6%(H khi B 2011) Cu 448: Cho m gam bt Cu vo 400 ml dung dch AgNO 3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A.3,84 B. 6,40 C. 5,12 D. 5,76(H khi B 2011)

9. Ha hc v vn pht trin kinh t, x hi, mi trng: 1 Cu 449: T l s ngi cht v bnh phi do ht thuc l gp hng chc ln s ngi khng ht thuc l.
Cht gy nghin v gy ung th c trong thuc l l A. aspirin. B. cafein. C. moocphin. D. nicotin. thi TSC 2007 Cu 450: Dy gm cc cht v thuc u c th gy nghin cho con ngi l A. cocain, seduxen, cafein. B. heroin, seduxen, erythromixin. C. ampixilin, erythromixin, cafein. D. penixilin, paradol, cocain. thi TSHC khi A 2009 Cu 451: Tc nhn ch yu gy ma axit l A. SO2 v NO2. B. CH4 v NH3. C. CO v CH4. D. CO v CO2. thi TSHC khi A 2008 Cu 452: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc ln thu ngn ri gom li l A. mui n. B. ct. C. vi sng. D. lu hunh. thi TSHC khi B 2008 Cu 453: Dn mu kh thi ca mt nh my qua dung dch Pb(NO3)2 d th thy xut hin kt ta mu en. Hin tng chng t trong kh thi nh my c kh no sau y? A. SO2 B. CO2 C. H2S D. NH3 (C 2011) Cu 454: Trong s cc ngun nng lng: (1) thy in, (2) gi, (3) mt tri, (4) ha thch; nhng ngun nng lng sch l: A. (1), (3), (4). B. (2), (3), (4). C. (1), (2), (4). D. (1), (2), (3). (H A 2010) Cu 455: Cho mt s nhn inh v nguyn nhn gy nhim mi trng khng khi nh sau : (1) Do hoat ng cua nui la (2) Do khi thai cng nghip, khi thai sinh hoat (3) Do khi thai t cac phng tin giao thng (4) Do khi sinh ra t qua trinh quang hp cy xanh (5) Do nng cao cua cac ion kim loai : Pb2+, Hg2+, Mn2+, Cu2+ trong cac ngun nc Nhng nhn inh ung la : A. (1), (2), (3) B. (2), (3), (5) C. (1), (2), (4) D. (2), (3), (4) (H B 2010) Cu 456: nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t nc, c c ri thm dd Na2S vo thy xut hin kt ta mu vng. Hin tng trn chng t nc thi b nhim bi ion A. Fe2+. B. Cu2+. C. Pb2+. D. Cd2+. (H B 2010) Cu 457: Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi nng ca chng trong kh quyn vt qu tiu chun cho php? A. N2 v CO B. CO2 v O2 C. CH4 v H2O D.CO2 v CH4(H khi A 2011)

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Cu 458: Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt vo khng kh dd no sau y? A. Dung dch NH3 B. Dung dch NaCl C.Dung dch NaOH D. Dung dch H2SO4 long(H khi A 2011)

C. HA HC HU C 10. i cng ha hc hu c, hirocacbon: 2

Cu 459: Cht no sau y c ng phn hnh hc? A. CH2=CH-CH=CH2 B. CH3-CH=CH-CH=CH2 C. CH3-CH=C(CH3)2 D. CH2=CH-CH2-CH3 (C 2011) Cu 460 : Trong s cac cht : C3H8, C3H7Cl, C3H8O va C3H9N; cht co nhiu ng phn cu tao nht la A. C3H7Cl B. C3H8O C. C3H8 D. C3H9N (H A 2010) Cu 461: S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l: A. 4; 3; 6. B. 5; 3; 9. C. 3; 5; 9. D. 4; 2; 6. Cu 462: Cht no sau y c ng phn hnh hc? A. 2-clopropen. B. 1,2-icloetan. C. But-2-in. D. But-2-en. (TSC 2010) Cu 463: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 4. B. 3. C. 2. D. 5. thi TSHC khi A 2008 Cu 464: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CHCH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 3. B. 2. C. 1. D. 4. thi TSHC khi A 2008 Cu 465: Cho cc cht sau: CH2=CH-CH=CH2; CH3-CH2-CH=C(CH3)2; CH3-CH=CH-CH=CH2; CH3CH=CH2; CH3-CH=CH-COOH. S cht c ng phn hnh hc l A. 4. B. 3. C. 2. D. 1. thi TSC 2009 Cu 466: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankaien. B. ankin. C. anken. D. ankan. thi TSHC khi B 2008 Cu 467: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. ankan. B. ankin. C. ankaien. D. anken. thi TSC 2008 Cu 468: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc o cht sau khi phn ng vi H2 (d, xc tc Ni, t ), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. thi TSC 2009 Cu 469: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. thi TSHC khi A 2009 Cu 470: kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l A. 2,240. B. 2,688. C. 4,480. D. 1,344. thi TSC 2009 Cu 471: Cho phn ng : 3 C6H5-CH=CH2 + 10 KMnO4 3C6H5-COOK + 3K2CO3 + 10 MnO2 + KOH + 4H2O Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ha hc ca phn ng trn l: A. 27 B. 31 C. 24 D. 34(H khi B 2011)

- Phn ng chy Cu 472:

Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l A. 20. B. 40. C. 30. D. 10. thi TSHC khi A 2007 Cu 473: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. etan. C. 2,2-imetylpropan. D. 2-Metylpropan. thi TSC 2008 Cu 474: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh (ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 56,0 lt. B. 78,4 lt. C. 70,0 lt. D. 84,0 lt. thi TSC 2007 Cu 475: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 20,40 gam. B. 18,96 gam. C. 16,80 gam. D. 18,60 gam. thi TSHC khi A 2008 Cu 476: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. C3H8. C. C2H6. D. CH4. thi TSHC khi B 2008

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t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 75% v 25%. B. 20% v 80%. C. 35% v 65%. D. 50% v 50%. thi TSC 2008 Cu 478: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H 2 SO 4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H8. B. C3H6. C. C4H8. D. C3H4. thi TSHC khi A 2007 Cu 479: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 12,9. B. 25,8. C. 22,2. D. 11,1. thi TSC 2008 Cu 480: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C2H4O2. B. C3H6O2. C. C4H8O2. D. CH2O2. thi TSHC khi B 2007 Cu 481: t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY > MX), thu c 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l A. C2H6. B. C2H2. C. CH4. D. C2H4. (TSC 2010) Cu 482: Hn hp khi X gm imetylamin va hai hirocacbon ng ng lin tip. t chay hoan toan 100 ml hn hp X bng mt lng oxi va u, thu c 550 ml hn hp Y gm khi va hi nc. Nu cho Y i qua dung dich axit sunfuric c (d) thi con lai 250 ml khi (cac th tich khi va hi o cung iu kin). Cng thc phn t cua hai hirocacbon la A. C2H6 va C3H8 B. C3H6 va C4H8 C. CH4 va C2H6 D. C2H4 va C3H6 (H A 2010) Cu 483: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH) 2 ban u. Cng thc phn t ca X l A. C3H4. B. C2H6. C. C3H6. D. C3H8. (H A 2010) Cu 484: t chay hoan toan m gam hn hp 3 ancol n chc, thuc cung day ng ng, thu c 3,808 lit khi CO 2 (ktc) va 5,4 gam H2O. Gia tri cua m la A. 4,72 B. 5,42 C. 7,42 D. 5,72 (H A 2010) Cu 485: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en. (H A 2010) Cu 486: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6.D. CH4 v C4H8. (H B 2010) Cu 487: Hn hp M gm anhit X (no, n chc, mach h) va hircacbon Y, co tng s mol la 0,2 (s mol cua X nho hn cua Y). t chay hoan toan M, thu c 8,96 lit khi CO2 (ktc) va 7,2g H2O. Hircacbon Y la A. CH4 B. C2H2 C. C3H6 D. C2H4 (H B 2010) Cu 488: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hh X cho qua cht xc tc nung nng, thu c hh Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dd brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hh kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 44,8 lt. C. 26,88 lt. D. 33,6 lt. (H khi A 2011) Cu 489: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l: A. 5,85 B. 3,39 C. 6,6 D. 7,3(H khi B 2011)

Cu 477:

- Phn ng cng v tch

Cu 490: Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, to), thu c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l A. C5H8. B. C2H2. C. C4H6. D. C3H4. (TSC 2010) Cu 491: un nong hn hp khi X gm 0,02 mol C2H2 va 0,03 mol H2 trong mt binh kin (xuc tac Ni), thu c hn hp khi Y. Cho Y li t t vao binh nc brom (d), sau khi kt thuc cac phan ng, khi lng binh tng m gam va co 280 ml hn hp khi Z (ktc) thoat ra. Ti khi cua Z so vi H2 la 10,08. Gia tri cua m la A. 0,328 B. 0,205 C. 0,585 D. 0,620 (H A 2010) Cu 492: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. thi TSHC khi A 2009 Cu 493: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). thi TSHC khi A 2007 Cu 494: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l A. C3H6. B. C3H4. C. C2H4. D. C4H8. thi TSHC khi A 2007

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Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. thi TSHC khi B 2009 Cu 496: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam. thi TSHC khi A 2008 Cu 497: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 20%. B. 25%. C. 50%. D. 40%. thi TSC 2009 Cu 498: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3. thi TSHC khi B 2009 Cu 499: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0. thi TSC 2009 Cu 500: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. C2H6 v C3H6. B. CH4 v C3H6. C. CH4 v C3H4. D. CH4 v C2H4. thi TSHC khi B 2008 Cu 501: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l A. C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. thi TSHC khi A 2007 Cu 502: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng A. 11,2. B. 13,44. C. 8,96. D. 5,60. thi TSC 2007 Cu 503: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C5H12. B. C3H8. C. C4H10. D. C6H14. thi TSHC khi A 2008 Cu 504: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. thi TSHC khi B 2009 Cu 505: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohecxan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng uc vi dung dch brom l: A. 4. B. 3. C. 5. D. 6. (C 2011) Cu 506: Cho buta-1,3 - ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l: A. 3 B. 1 C. 2 D. 4(H khi A 2011) Cu 507: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CH C-CH3, CH2=CH-C CH. B. CH C-CH3, CH2=C=C=CH2. C. CH2=C=CH2, CH2=C=C=CH2. D. CH2=C=CH2, CH2=CH-C CH. (H khi A 2011) Cu 508: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l: A. 8 B. 9 C. 5 D. 7(H khi B 2011) Cu 509: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6, H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,48 mol B. 0,36 mol C. 0,60 mol D. 0,24 mol(H khi B 2011)

Cu 495:

- Phn ng th Cu 510:
A. 2. B. 4.

Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l C. 3. D. 5. thi TSHC khi A 2008

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Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l A. 3,3-imetylhecxan. B. isopentan. C. 2,2-imetylpropan. D. 2,2,3-trimetylpentan. thi TSHC khi B 2007 Cu 512: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l A. 2,3-imetylbutan. B. butan. C. 3-metylpentan. D. 2-metylpropan. thi TSC 2007 Cu 513: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 4. C. 5. D. 2. thi TSHC khi B 2008 Cu 514: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. o-bromtoluen v p-bromtoluen B. benzyl bromua C. p-bromtoluen v m-bromtoluen D. o-bromtoluen v m-bromtoluen (C 2011) Cu 515: Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 5. B. 4. C. 6. D. 2. (H khi A 2011)

Cu 511:

11. Dn xut halogen, ancol, phenol: 2 + 1

Cu 516: Trong s cac phat biu sau v phenol (C6H5OH): (1) Phenol tan it trong nc nhng tan nhiu trong dung dich HCl (2) Phenol co tinh axit, dung dich phenol khng lam i mau quy tim (3) Phenol dung san xut keo dan, cht dit nm mc (4) Phenol tham gia phan ng th brom va th nitro d hn benzen Cac phat biu ung la A. (1), (2), (4) B. (2), (3), (4) C. (1), (2), (3) D. (1), (3), (4) (H A 2010) Cu 517: Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c xp theo chiu tng dn t tri sang phi l: A. anlyl clorua, phenyl clorua, propyl clorua. B. phenyl clorua, anlyl clorua, propyl clorua. C. anlyl clorua, propyl clorua, phenyl clorua. D. phenyl clorua, propyl clorua, anlyl clorua. (TSC 2010) Cu 518: S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc dng viCuO un nng sinh ra xenton l: A. 4 B. 2 C. 5 D. 3 (C 2011) Cu 519: un si hn hp propyl bromua, kali hiroxit v etanol thu c sn phm hu c l A. propin. B. propan-2-ol. C. propan. D. propen. (C 2011) Cu 520: S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A. 4. B. 6. C. 7. D. 5. (C 2011) Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); CH2-CH2-CH2OH (Y); HOCH2CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T. thi TSC 2007 Cu 522: Cho cc hp cht sau: (a) HOCH2-CH2OH. (b)HOCH2CH2CH2OH. (c)HOCH2-CH(OH)-CH2OH. (d)CH3CH(OH)CH2OH (e) CH3-CH2OH. (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l: A. (a), (b), (c). B. (c), (d), (f). C. (a), (c), (d). D. (c), (d), (e). thi TSHC khi B 2009 Cu 523: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? A. 2. B. 5. C. 3. D. 4. thi TSC 2007 Cu 524: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. thi TSHC khi A 2009 Cu 525: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. thi TSHC khi A 2009 Cu 526: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l

Cu 521:

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A. 2.

C. 4. D. 1. thi TSHC khi A 2008 Dy gm cc cht u tc dng vi ancol etylic l: o o A. HBr (t ), Na, CuO (t ), CH3COOH (xc tc). o B. Ca, CuO (t ), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). o D. Na2CO3, CuO (t ), CH3COOH (xc tc), (CH3CO)2O. thi TSC 2009 Cu 528: Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nha rezit, cht dit c 2,4-D v thuc n TNT. thi TSC 2009 Cu 529: Dy gm cc cht u phn ng vi phenol l: A. nc brom, anehit axetic, dung dch NaOH. B. dung dch NaCl, dung dch NaOH, kim loi Na. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, anhirit axetic, dung dch NaOH. thi TSHC khi B 2007 Cu 530: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH B. Na kim loi. D. H2 (Ni, nung nng). thi TSHC khi B 2008 C. . nc Br2.

B. 3.

Cu 527:

2 Cho s C6 H 6 X Y Z Fe, t o t o cao,P cao Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. thi TSHC khi A 2007 Cu 532: Cho cc phn ng :

Cu 531:

+ Cl (1:1)

+ NaOH, du

+ HCl

t HBr + C2H5OH

C2H4 + Br2

C2H4 + HBr S phn ng to ra C2H5Br l : A. 1 B.2 Cu 533: Cho s chuyn ho:

askt(1:1mol) C2H6 + Br2

C. 3

D. 4. thi TSHC khi B 2008

H 2 SO4 + HBr + Mg, Butan - 2 - ol tc X(anken) Y etekhan Z o

Trong X, Y, Z l sn phm chnh. Cng thc ca Z l A. (CH3)3C-MgBr. B. CH3-CH2-CH2 -CH2-MgBr. C. CH3-CH(MgBr)-CH2-CH3. D. (CH3)2CH-CH2-MgBr. thi TSHC khi B 2009 Cu 534: Cho s chuyn ho sau : Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm : A. m-metylphenol v o-metylphenol B. benzyl bromua v o-bromtoluen C. o-bromtoluen v p-bromtoluen D. o-metylphenol v p-metylphenol thi TSHC khi B 2008
+ Br2 (1:1mol),Fe,t +NaOH (d ),t ,p + HCl(d ) Toluen X Y Z
0 0

- Phn ng chy
Cu 535: Cho 10 ml dung dch ancol etylic 46o phn ng ht vi kim loi Na (d), thu c V lt kh H 2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l A. 3,360. B. 0,896. C. 2,128. D. 4,256. (TSC 2010) t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l A. C2H6O2. B. C2H6O. C. C3H8O2. D. C4H10O2. thi TSC 2008 Cu 537: Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? A. 2. B. 4. C. 3. D. 5. thi TSC 2007 Cu 538: t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O2, C3H8O2. B. C2H6O v CH4O. C.C3H6OvC4H8O. D.C2H6OvC3H8O. thi TSC 2008 Cu 539: t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l

Cu 536:

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A. C3H8O.

B. C3H8O3. C. C3H4O. D. C3H8O2. thi TSC 2007 t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. thi TSHC khi A 2009 Cu 541: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H7OH. B. C3H6(OH)2. C. C3H5(OH)3. D. C2H4(OH)2. thi TSHC khi B 2007 Cu 542: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: A. m = 2a V/22,4 B. m = 2a + V/11,2 C. m = a + V/5,6 D. m = a V/5,6 thi TSHC khi A 2009 Cu 543: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. C. C2H4(OH)2 v C4H8(OH)2. D. C2H4(OH)2 v C3H6(OH)2. thi TSHC khi A 2009 Cu 544: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H 2 SO 4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k) A. C4H9OH v C5H11OH. B. C2H5OH v C4H9OH. C. C3H7OH v C4H9OH. D. C2H5OH v C3H7OH. thi TSC 2007 Cu 545: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H4COOH. B. C6H4 (OH)2. C. HO C6H4CH2OH. D. C2H5C6H4OH. thi TSHC khi B 2007 Cu 546: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,36. C. 0,54. D. 0,45. (H B 2010) Cu 547: t chay hoan toan mt lng hn hp X gm 2 ancol (u no, a chc, mach h, co cung s nhom -OH) cn va u V lit khi O2, thu c 11,2 lit khi CO2 va 12,6 gam H2O (cac th tich khi o ktc). Gia tri cua V la A. 14,56 B. 15,68 C. 11,20 D. 4,48 (H B 2010) Cu 548: Co bao nhiu cht hu c mach h dung iu ch 4-metylpentan-2-ol chi bng phan ng cng H 2 (xuc tac Ni, t0)? A. 3 B. 5 C. 2 D. 4 (H B 2010) Cu 549: Cho cac cht : (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cac cht thuc loai phenol la: A. (1), (3), (5), (6) B. (1), (2), (4), (6) C. (1), (2), (4), (5) D. (1), (4), (5), (6) (H B 2010) Cu 550: Hp cht hu c X cha vng benzen c CTPT trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hir bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 9. B. 3. C. 7. D. 10. (H khi A 2011)

Cu 540:

Phn ng Na
Cu 551: Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H 2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l: A. 7,0 B. 14,0 C. 10,5 D.21,0 (C 2011) Cu 552: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 3. B. 1. C. 4. D. 2. thi TSHC khi B 2007 Cu 553: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 2. B. 4. C. 1. D. 3. thi TSHC khi B 2007 Cu 554: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. HOC6H4CH2OH. B. CH3C6H3(OH)2. C. CH3OC6H4OH. D. C6H5CH(OH)2. thi TSC 2007 Cu 555: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu

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cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3. B. CH3-C6H3(OH)2. C. HO-CH2-C6H4-OH. D. HO-C6H4-COOH. thi TSHC khi B 2009 Cu 556: t chy han tan m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l A. 7,85 gam. B. 7,40 gam. C. 6,50 gam. D. 5,60 gam. (H B 2010) Cu 557: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4. B. 3. C. 6. D. 5. (H khi A 2011)

- Phn ng tch nc Cu 558: Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4 c, 140oC) th
s ete thu c ti a l B. 2. C. 1. D. 3. thi TSC 2008 Cu 559: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l A. 2-metylbuten-3 (hay 2-metylbut-3-en). B. 2-metylbuten-2 (hay 2-metylbut-2-en). C. 3-metylbuten-2 (hay 3-metylbut-2-en). D. 3-metylbuten-1 (hay 3-metylbut-1-en). thi TSHC khi A 2008 Cu 560: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. (CH3)3COH. B. CH3OCH2CH2CH3. C. CH3CH(OH)CH2CH3. D. CH3CH(CH3)CH2OH. thi TSHC khi A 2007 Cu 561: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ancol trn l A. C3H5OH v C4H7OH. B. CH3OH v C2H5OH. C. C2H5OH v C3H7OH. D. C3H7OH v C4H9OH. thi TSHC khi B 2008 Cu 562: X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung o dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 4,05. B. 8,10. C. 18,00. D. 16,20. thi TSHC khi A 2009 Cu 563: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l A. C4H8O. B. C3H8O. C. CH4O. D. C2H6O. thi TSHC khi B 2008 Cu 564: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH2=CH-CH2-OH. B. C2H5OH v CH3OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. thi TSHC khi A 2009 Cu 565: t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu c 6,72 lt kh CO 2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H 2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l: A. 6,45 gam B. 5,46 gam C. 7,40 gam D. 4,20 gam (C 2011) Cu 566: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l A. CH3-CH2-CH(OH)-CH3. B. CH3-CH2-CH2-CH2-OH. C. CH3-CH2-CH2-OH. D. CH3-CH(OH)-CH3. (H A 2010) Cu 567: Phat biu nao sau y ung? A. Khi un C2H5Br vi dd KOH chi thu c etilen B. dd phenol lam phenolphtalein khng mau chuyn thanh mau hng C. Day cac cht : C2H5Cl, C2H5Br, C2H5I co nhit si tng dn t trai sang phai D. un ancol etylic 1400C (xuc tac H2SO4 c) thu c imetyl ete (H B 2010) Cu 568: Chia hn hp gm hai n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. - un nng phn 2 vi H2SO4 c 1400C to thnh 1,25 gam hn hp ba ete. Ha hi hon ton hn hp ba ete trn, thu c th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Hiu sut ca phn ng to ete ca X, Y ln lt l: A. 30% v 30% B. 25% v 35% C. 40% v 20% D. 20% v 40%(H khi B 2011) - Phn ng OXH A. 4.

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Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l A. CH3-CHOH-CH3. B. CH3-CH2-CHOH-CH3. C. CH3-CO-CH3. D. CH3-CH2-CH2-OH. thi TSC 2008 Cu 570: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hpsn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 15,3. B. 13,5. C. 8,1. D. 8,5. thi TSHC khi B 2009 Cu 571: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l A. 0,64. B. 0,46. C. 0,32. D. 0,92. thi TSHC khi B 2007 Cu 572: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 9,2. B. 7,8. C. 7,4. D. 8,8. thi TSHC khi A 2008 Cu 573: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. thi TSC 2009 Cu 574: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 65,5%.B. 80,0%. C. 76,6%. D. 70,4%. thi TSHC khi B 2008 Cu 575: S ancol ng phn cu to ca nhauc cng thc phn t C5H12O, tc dng vi CuO un nng sinh ra xenton l: A. 4 B. 2 C. 5 D. 3 (C 2011)

Cu 569:

12. Anehit, xeton, axit cacboxylic: 2 + 2

Cu 576: Hiro ha cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l A. metyl isopropyl xetol. B. 3-metylbutan-2-on. C. 3-metylbutan-2-ol. D. 2-metylbutan-3-on. (H A 2010) Cu 577: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H 2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ha t hiu sut 100%). Hai axit trong hn hp X l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH. C. C2H5COOH v C3H7COOH. D. C2H7COOH v C4H9COOH. (H A 2010) Cu 578: Cho s chuyn ha: CH3CH2Cl X K N C H Y ,t Trong s trn, X v Y ln lt l A. CH3CH2CN v CH3CH2OH B. CH3CH2NH2 v CH3CH2COOH C. CH3CH2CN v CH3CH2COOH D. CH3CH2CN v CH3CH2COOH (C 2011) Cu 579: Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l: A. HCOOH, CH3COOH, CH3CH2COOH B. CH3COOH, HCOOH, (CH3)2CHCOOH C. C6H5OH, CH3COOH, CH3CH2OH D. CH3COOH, CH2ClCOOH, CHCl2COOH (C 2011) Cu 580: Anehit no mch h X c cng thc n gin nht C2H3O. Cng thc phn t ca X l A. C6H9O3. B. C8H12O4. C. C2H3O. D. C4H6O2. (TSC 2010) Cu 581: ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi kh H 2 (xc tc Ni, to) sinh ra ancol? A. 2. B. 3. C. 4. D. 1. (TSC 2010) Cu 582: Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 2. B. 4. C. 1. D. 3. thi TSHC khi A 2007 Cu 583: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. CH3COOH, C2H2, C2H4. B. C2H5OH, C2H4, C2H2. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH. thi TSHC khi A 2009 Cu 584: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. thi TSC 2009 Cu 585: Qu trnh no sau y khng to ra anehit axetic? o o A. CH2=CH2 + H2O (t , xc tc HgSO4). B. CH2=CH2 + O2 (t , xc tc).
+ 0

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o o C. CH3COOCH=CH2 + dung dch NaOH (t ). D. CH3CH2OH + CuO (t ). thi TSC 2009 Cu 586: Trong cng nghip, axeton c iu ch t A. cumen. B. propan-1-ol. C. xiclopropan. D. propan-2-ol. thi TSC 2007 Cu 587: S ng phn xeton ng vi cng thc phn t C5H10O l A. 3. B. 5. C. 6. D. 4. thi TSHC khi A 2008 Cu 588: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C9H12O9. B. C12H16O12. C. C6H8O6. D. C3H4O3. thi TSHC khi B 2008 Cu 589: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l A. 50%. B. 60%. C. 70%. D. 80%. thi TSHC khi B 2007 Cu 590: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. khng no (cha mt ni i C=C), n chc. D. no, n chc. thi TSHC khi A 2008 Cu 591: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2COCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. thi TSC 2009 Cu 592: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HOCH(CH3)CHO v HOOCCH2CHO. D. HCOOCH3 v HCOOCH2CH3. thi TSHC khi B 2009 Cu 593: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dd AgNO 3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 65,2%. B. 16,3%. C. 48,9%. D. 83,7%. (H B 2010) Cu 594: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) va este Z c tao ra t X va Y. Cho mt lng M tac dung va u vi dd cha 0,2 mol NaOH, tao ra 16,4 gam mui va 8,05 gam ancol. Cng thc cua X va Y la A. HCOOH va CH3OH B. CH3COOH va CH3OH C. HCOOH va C3H7OH D. CH3COOH va C2H5OH (H B 2010) Cu 595: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tha mn s chuyn ha sau:
+ H2 + CH X Y 3COOH Este c mi mui chn. H 2 SOa c Ni , t 0 4,

Tn ca X l A. pentanal C. 2,2 imetylpropanal.

+H O

B. 2 metylbutanal D. 3 metylbutanal. (H B 2010)

+ CuO Br +

2 Cu 596: Cho s phn ng: Stiren H + 2t0 X Y Z , t0 H +

Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l: A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br. B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH. C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3. (H B 2010) Cho cc hp cht hu c: (1) ankan;(2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken;(6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10).

- Phn ng chy Cu 597:

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C. (3), (5), (6), (8), (9).

D. (2), (3), (5), (7), (9). thi TSHC khi B 2009 t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. khng no c mt ni i, n chc. B. no, n chc. C. khng no c hai ni i, n chc. D. no, hai chc. thi TSHC khi B 2007 Cu 599: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CH2-CH2-CHO. thi TSHC khi B 2009 Cu 600: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 8,96. B. 6,72. C. 4,48. D. 11,2. thi TSHC khi B 2007 Cu 601: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. O=CH-CH=O. B. CH2=CH-CH2-OH. C. CH3COCH3.D. C2H5CHO. thi TSHC khi B 2009 Cu 602: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 50,56%. B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%. thi TSC 2009 Cu 603: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 17,8. B. 24,8. C. 10,5. D. 8,8. thi TSHC khi B 2009 Cu 604: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 46,15%. B. 35,00%. C. 53,85%. D. 65,00%. thi TSHC khi A 2009 Cu 605: Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c X. Tn gi ca X l A. metyl phenyl xeton. B. metyl vinyl xeton. C. imetyl xeton. D. propanal. (TSC 2010) Cu 39: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l: A. 20% B. 50% C. 40% D. 30%(H khi B 2011) - Phn ng OXH Cu 606: Hn hp G gm hai anehit X v Y, trong Mx < My < 1,6 Mx. t chy hn hp G thu c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO3 trong NH3 thu c 0,25 mol Ag. Tng s cc nguyn t trong mt phn t Y l A. 10 B. 7. C. 6. D. 9. (C 2011) Cu 607: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. thi TSC 2008 Cu 608: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. thi TSC 2008 Cu 609: t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. HCHO. B. CH3CHO. C. (CHO)2. D. C2H5CHO. thi TSC 2008 Cu 610: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. CH3CHO. C. OHC-CHO. D. CH3CH(OH)CHO. thi TSHC khi A 2007 Cu 611: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu o c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t ) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n+1CHO (n 0). C. CnH2n-1CHO (n 2). D. CnH2n-3CHO (n 2). thi TSHC khi A 2009 Cu 612: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l

Cu 598:

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A. CH2=CH-CHO.

B. OHC-CHO. C. HCHO. D. CH3CHO. thi TSC 2007 Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l A. CH3CHO. B. HCHO. C. CH3CH2CHO. D. CH2 = CHCHO. thi TSHC khi A 2007 Cu 614: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. C4H9CHO. C. HCHO. D. C2H5CHO. thi TSHC khi A 2008 Cu 615: Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. thi TSC 2009 Cu 616: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l A. C2H5CHO. B. CH3CHO. C. HCHO. D. C2H3CHO. thi TSHC khi B 2007 Cu 618: Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH Phn ng ny chng t C6H5-CHO A. va th hin tnh oxi ha, va th hin tnh kh. B. ch th hin tnh oxi ha. C. ch th hin tnh kh. D. khng th hin tnh kh v tnh oxi ha. (H B 2010) Cu 619: t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l

Cu 613:

A. V =

28 ( x 30 y ) . 55

B. V =

28 ( x 62 y ) 95

C. V =

28 ( x + 30 y ) . 55

D. V =

28 ( x + 62 y ) . (H khi A 2011) 95

Cu 620: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO 3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,3. B. 0,8. C. 0,2. D. 0,6. (H khi A 2011) Cu 621: Pht biu no sau y v anehit v xeton l sai? A. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. B. Axeton khng phn ng c vi nc brom. C. Axetanehit phn ng c vi nc brom. D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn. (H khi A 2011) Cu 622: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X t/d vi mt lng d dd AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit fomic. B. anehit no, mch h, hai chc. C. anehit axetic. D. anehit khng no, mch h, hai chc. (H khi A 2011) Cu 623: hiro ha hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H 2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO 3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l: A. OHC-CH2-CHO v OHC-CHO B. H-CHO v OHC-CH2-CHO C. CH2=C(CH3)-CHO v OHC-CHO D. CH2=CH-CHO v OHC-CH2-CHO(H khi B 2011) Cu 624: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l: A. anehit propionic B. anehit butiric C. anehit axetic D. anehit acrylic Cu 625: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l: A. 2,67 B. 4,45 C. 5,34 D. 3,56(H khi B 2011)

- Td Na, NaOH, Na2CO3 Cu 626: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi
NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit aipic. C. ancol o-hiroxibenzylic. D. axit 3-hiroxipropanoic. thi TSHC khi B 2009 Cu 627: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l

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A. HOOC-CH2-CH2-COOH. B. C2H5-COOH. C. CH3-COOH. D. HOOC-COOH. thi TSHC khi A 2007 Cu 628: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-COOH. B. HCOOH, HOOC-CH2-COOH. C. HCOOH, C2H5COOH. D. HCOOH, CH3COOH. thi TSHC khi A 2009 Cu 629: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 4,90 gam. B. 6,84 gam. C. 8,64 gam. D. 6,80 gam. thi TSHC khi A 2008 Cu 630: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l A. CH3COOH. B. C3H7COOH. C. C2H5COOH. D. HCOOH. thi TSHC khi B 2007 Cu 631: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH2=CH-COOH. B. HC C-COOH. C. CH3-CH2-COOH. D. CH3COOH. thi TSC 2007 Cu 632: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. HCOOH. C. CH3COOH. D. C3H7COOH. thi TSHC khi B 2008 Cu 633: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l A. 0,56 gam. B. 1,44 gam. C. 0,72 gam. D. 2,88 gam. thi TSHC khi B 2009 Cu 634: Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn gi ca X l A. axit acrylic. B. axit propanoic. C. axit etanoic. D. axit metacrylic. thi TSC 2009 Cu 635: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc).t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 70,87%. B. HOOC-CH2-COOH v 54,88%. C. HOOC-COOH v 60,00%. D. HOOC-COOH v 42,86%. thi TSHC khi B 2009 Cu 636: Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l A. C3H6O2 v C4H8O2. B. C2H4O2 v C3H6O2. C. C2H4O2 v C3H4O2. D. C3H4O2 v C4H6O2. (TSC 2010) Cu 637: Axit cacboxylic X c cng thc n gin nht l C3H5O2. Khi cho 100 ml dung dch axit X nng 0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V ml kh CO2 (ktc). Gi tr ca V l A. 336. B. 112. C. 448. D. 224. (TSC 2010) Cu 638: Hai cht X v Y c cng cng thc phn t C 2H4O2. Cht X phn ng c vi kim loi Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO3. Cng thc ca X, Y ln lt l: A. HOCH2CHO, CH3COOH. B. HCOOCH3, CH3COOH. C. CH3COOH, HOCH2CHO. D. HCOOCH3, HOCH2CHO. (TSC 2010) Cu 639: t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH3, CH3OH thu c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l A. CH3COOH. B. C3H5COOH. C. C2H3COOH. D. C2H5COOH. (TSC 2010) Cu 640: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (M X < MY < 82). C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO3 sinh ra kh CO2. T khi hi ca Y so vi X c gi tr l: A. 1,47 B. 1,61 C. 1,57 D. 1,91 (C 2011) Cu 641: Oxi hoa ht 2,2 gam hn hp hai ancol n chc thanh anehit cn va u 4,8 gam CuO. Cho toan b lng anehit trn tac dung vi lng d dung dich AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol la : A. C2H5OH, C2H5CH2OHB. C2H5OH, C3H7CH2OH C. CH3OH, C2H5CH2OH D. CH3OH, C2H5OH (H A 2010) Cu 642: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO 3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l A. 10,9. B. 14,3. C. 10,2. D. 9,5. (H A 2010)

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Cu 643: Axeton c iu ch bng cach oxi hoa cumen nh oxi, sau o thuy phn trong dung dich H 2SO4 loang. thu c 145 gam axeton thi lng cumen cn dung (gia s hiu sut qua trinh iu ch at 75%) la A. 300 gam B. 500 gam C. 400 gam D. 600 gam (H A 2010) Cu 644: Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi km c tng khi lng l 15,8 gam. Tn ca axit trn l A. axit propanoic. B. axit metanoic. C. axit etanoic. D. axit butanoic. (H A 2010) Cu 645: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,015. B. 0,010. C. 0,020. D. 0,005. (H B 2010) Cu 646: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dd NaOH, thu c dd cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dd AgNO 3 trong NH3, thu c 21,6 gam Ag. CT v % khi lng ca X trong Z l A. C3H5COOH v 54,88%. B. C2H3COOH v 43,90%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12%.(H B 2010) Cu 647: Dy gm cc cht u tc dng vi H2 (xc tc Ni, t0) to ra sn phm c kh nng phn ng vi Na l: A. C2H3CH2OH, CH3COCH3, C2H3COOH. B. C2H3CHO, CH3COOC2H3, C6H5COOH. C. C2H3CH2OH, CH3CHO, CH3COOH. D. CH3OC2H5, CH3CHO, C2H3COOH. (H B 2010) Cu 648: Trung ha 3,88 gam hh X gm hai axit cacboxylic no, n chc, mch h bng dd NaOH, c cn ton b dd sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l A. 4,48 lt. B. 3,36 lt. C. 2,24 lt. D. 1,12 lt. (H khi A 2011) Cu 649: t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi z = y x). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l A. axit acrylic. B. axit oxalic. C. axit aipic. D. axit fomic. (H khi A 2011) Cu 650: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COOC6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,72. B. 0,48. C. 0,96. D. 0,24. (H khi A 2011)

13. Este, lipit: 1 + 1

Cu 651: Tng s cht hu c mach h, co cung cng thc phn t C2H4O2 la A. 3 B. 1 C. 2 D. 4 (H A 2010) Cu 652: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 7,20. B. 6,66. C. 8,88. D. 10,56. (H A 2010) Cu 653: Cng thc ca triolein l: A. (CH3[CH2]16COO)3C3H5 B. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5 C. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5 D. (CH3[CH2]14COO)3C3H5 (C 2011)

- Phn ng chy
Cu 654: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M x < MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng thc ca Y l : A. CH3COOC2H5 B. CH3COOCH3 C. CH2=CHCOOCH3 D. C2H5COOC2H5 (C 2011) Cu 655: Mnh khng ng l: A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. thi TSHC khi A 2007 Cu 656: S ng phn este ng vi cng thc phn t C4H8O2 l A. 6. B. 5. C. 2. D. 4. thi TSHC khi A 2008 Cu 657: S hp cht l ng phn cu to, c cng cng thc phn t C4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 3. B. 2. C. 4. D. 1. thi TSC 2009 Cu 658: Pht biu ng l: A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. B. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v (ancol). D. Khi thy phn cht bo lun thu c C2H4(OH)2. thi TSHC khi A 2008 Cu 659: Pht biu no sau y sai? A. Nhit si ca este thp hn hn so vi ancol c cng phn t khi. B. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.

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D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol. thi TSC 2009 Cu 660: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 4. B. 2. C. 3. D. 5. thi TSHC khi A 2008 Cu 661: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. O=CH-CH2-CH2OH. B. HOOC-CHO. C. CH3COOCH3. D. HCOOC2H5. thi TSHC khi B 2009 Cu 662: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l A. C2H5COOCH3 v HCOOCH(CH3)2. B. HCOOC2H5 v CH3COOCH3. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOCH2CH2CH3 v CH3COOC2H5. thi TSHC khi B 2007 Cu 663: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2. B. C2H4O2 v C3H6O2. C. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2. thi TSHC khi B 2009 Cu 664: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomiat. B. etyl axetat. C. metyl axetat.D. n-propyl axetat. thi TSHC khi B 2008 Cu 665: Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. (HCOO)2C2H4 v 6,6. B. CH3COOCH3 v 6,7. C. HCOOCH3 v 6,7. D. HCOOC2H5 v 9,5. (TSC 2010) Cu 666 : t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Tng 2,70 gam. B. Gim 7,74 gam. C. Tng 7,92 gam. D. Gim 7,38 gam. (H khi A 2011) Cu 667: t chy hon ton 0,11 gam mt este X ( to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l: A. 2 B. 5 C. 6 D.4 (H khi A 2011) Cu 668: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l: A. 25% B. 27,92% C. 72,08% D. 75%(H khi B 2011)

- Phn ng este ha
Cu 669: Hn hp M gm ancol no, n chc X va axit cacboxylic n chc Y, u mach h v co cung s nguyn t C, tng s mol cua hai cht la 0,5 mol (s mol cua Y ln hn s mol cua X). Nu t chay hoan toan M thi thu c 33,6 lit khi CO2 (ktc) va 25,2 gam H2O. Mt khac, nu un nong M vi H2SO4 c thc hin phan ng este hoa (hiu sut la 80%) thi s gam este thu c la A. 34,20 B. 27,36 C. 22,80 D. 18,24 (H A 2010) Cu 670: Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l A. 50,00%. B. 62,50%. C. 40,00%. D. 31,25%. (TSC 2010)

- Phn ng thy phn: H+, OHCu 671: Este X c cc c im sau:

- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. Cht X thuc loi este no, n chc. B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. C. Cht Y tan v hn trong nc. D. un Z vi dung dch H2SO4 c 170oC thu c anken. thi TSHC khi A 2008 Cu 672: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2. thi TSHC khi A 2007

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Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic. thi TSHC khi B 2007 Cu 674: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A.CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B.HCOONa, CHC-COONa v CH3-CH2-COONa. C.CH2=CH-COONa, HCOONa v CHC-COONa. D.CH3-COONa, HCOONa v CH3-CH=CH-COONa. thi TSHC khi A 2009 Cu 675: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? A. 5. B. 4. C. 3. D. 2. thi TSC 2007 Cu 676: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH3. B. HCOOCH=CH2. C. CH3COOCH=CH-CH3. D. CH3COOCH=CH2. thi TSC 2007 Cu 677: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. HCOOC(CH3)=CHCH3. B. CH3COOC(CH3)=CH2. C. HCOOCH2CH=CHCH3. D. HCOOCH=CHCH2CH3. thi TSHC khi A 2009 Cu 678: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. thi TSC 2008 Cu 679: Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 44 vC. B. 58 vC. C. 82 vC. D. 118 vC. thi TSC 2008 Cu 680: Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l A. mt este v mt axit. B. hai axit. C. hai este. D. mt este v mt ancol. thi TSC 2009 Cu 681: Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ru (ancol). Cho ton b lng ru thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm A. mt axit v mt este. B. mt este v mt ru. C. hai este. D. mt axit v mt ru. thi TSC 2008 Cu 682: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7. thi TSHC khi B 2009 Cu 683: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 400 ml. B. 300 ml. C. 150 ml. D. 200 ml. thi TSC 2008 Cu 684: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. thi TSHC khi A 2007 Cu 685: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 27,75. B. 24,25. C. 26,25. D. 29,75. thi TSHC khi B 2009 Cu 686: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung

Cu 673:

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dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l A. HCOOCH2CH2CH3. B. HCOOCH(CH3)2. C. C2H5COOCH3. D. CH3COOC2H5. thi TSHC khi B 2007 Cu 687: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. etyl axetat. B. metyl propionat. C. isopropyl axetat. D. etyl propionat. thi TSC 2007 Cu 688: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-CH2-COO-CH3. B. CH2=CH-COO-CH2-CH3. C. CH3 -COO-CH=CH-CH3. D. CH3-CH2-COO-CH=CH2. thi TSC 2008 Cu 689: Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5. thi TSC 2009 Cu 690: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3OOC(CH2)2COOC2H5. B. CH3OOCCH2COOC3H7. C. CH3COO(CH2)2OOCC2H5. D. CH3COO(CH2)2COOC2H5. thi TSHC khi B 2008 Cu 691: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 18,24 gam. B. 16,68 gam. C. 18,38 gam. D. 17,80 gam. thi TSHC khi B 2008 Cu 692: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. CH3COOCH3 v CH3COOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5. thi TSHC khi A 2009 Cu 693: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. thi TSHC khi A 2007

- Phn ng este ha Cu 694: Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s
loi trieste c to ra ti a l B. 5. C. 3. D. 4. thi TSHC khi B 2007 Cu 695: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l A. 6,0 gam. B. 4,4 gam. C. 8,8 gam. D. 5,2 gam. thi TSC 2008 Cu 696: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l A. 10,12. B. 6,48. C. 8,10. D. 16,20. thi TSHC khi A 2007 Cu 697: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l A. 55%. B. 50%. C. 62,5%. D. 75%. thi TSC 2007 Cu 698: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. thi TSHC khi A 2007 Cu 699: trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gam NaOH. Gi tr ca a l A. 0,200. B. 0,280. C. 0,075. D. 0,150. (TSC 2010) Cu 700: Pht biu ng l: A. Phenol phn ng c vi dung dch NaHCO3. B. Thu phn benzyl clorua thu c phenol. C. Vinyl axetat phn ng vi dung dch NaOH sinh ra ancol etylic. D. Phenol phn ng c vi nc brom. (TSC 2010) Cu 701: Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui v ancol etylic. Cht X l A. 6.

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A. CH3COOCH2CH2Cl. B. CH3COOCH2CH3. C. ClCH2COOC2H5. D. CH3COOCH(Cl)CH3(TSC 2010) Cu 702: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l: A. CH3COOC2H5 B. C2H5COOCH3 C. CH2=CHCOOCH3 D. CH3COOCH=CH2 (C 2011) Cu 703: x phng ho hon ton 52,8 gam hn hp hai este no, n chc , mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. CH3COOC2H5 v HCOOC3H7 B. C2H5COOC2H5 v C3H7COOCH3 C. HCOOC4H9 v CH3COOC3H7 D. C2H5COOCH3 v CH3COOC2H5 (C 2011) Cu 704: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH) 2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l: A. 43,24% B. 53,33% C. 37,21% D. 36,36% (C 2011) Cu 705: Thuy phn hoan toan 0,2 mol mt este E cn dung va u 100 gam dung dich NaOH 24%, thu c mt ancol va 43,6 gam hn hp mui cua hai axit cacboxylic n chc. Hai axit o la A. HCOOH va CH3COOH B. CH3COOH va C2H5COOH C. C2H5COOH va C3H7COOH D. HCOOH va C2H5COOH (H A 2010) Cu 706: Cho s chuyn ha: 0 0 HCl + H2 + NaOH Triolein du ( Ni, t ) X du, t Y + Z. Tn ca Z l A. axit linoleic. B. axit oleic. C. axit panmitic. D. axit stearic. (H A 2010) Cu 707 : Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7. D. CH3OCO-CH2-CH2-COOC2H5. (H B 2010) Cu 708: Thuy phn este Z trong mi trng axit thu c hai cht hu c X va Y (MX < MY). Bng mt phan ng co th chuyn hoa X thanh Y. Cht Z khng th la A. metyl propionat B. metyl axetat C. etyl axetat D. vinyl axetat(H B 2010) Cu 709: Tng s hp cht hu c no, n chc, mach h, co cung cng thc phn t C5H10O2, phan ng c vi dd NaOH nhng khng co phan ng trang bac la A. 4 B. 5 C. 8 D. 9(H B 2010) Cu 710: Trong cac cht : xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht co kha nng lam mt mau nc brom la A. 5 B. 4 C. 6 D. 3(H B 2010) Cu 711: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 14,5. B. 17,5. C. 15,5. D. 16,5. (H khi A 2011) Cu 712: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 4 B. 2 C. 5 D. 3(H khi B 2011) Cu 713: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gam(H khi B 2011) Cu 714: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn cc tnh cht trn l: A. 4 B. 5 C. 6 D. 2(H khi B 2011) Cu 715: Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng) B. Cu(OH)2 ( iu kin thng) C. Dung dch NaOH (un nng) D. H2 (xc tc Ni, un nng) (H khi B 2011) Cu 716: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l A. 46,67% B. 40,00% C. 25,41% D. 74,59%(H khi B 2011)

- Xc nh ch s cht bo Cu 717: trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH
A. 5,5. 0,1M. Ch s axit ca mu cht bo trn l B. 4,8. C. 6,0. D. 7,2. thi TSC 2007

14. Amin, amino axit v protein: 3 + 1

Cu 718: Ancol v amin no sau y cng bc?

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A. (C6H5)2NH v C6H5CH2OH B. C6H5NHCH3 v C6H5CH(OH)CH3 C. (CH3)3COH v (CH3)3CNH2 D. (CH3)2CHOH v (CH3)2CHNH2(H khi B 2011) Cu 719: Cho ba dung dch c cng nng mol : (1) H 2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (3), (1), (2) B. (1), (2), (3) C. (2) , (3) , (1) D. (2), (1), (3) (H khi B 2011) Cu 720:Pht biu khng ng l A.Etylamin tc dng vi axit nitr nhit thng to ra etanol B.Protein l nhng polopeptit cao phn t c phn t khi t vi chc nghn n vi chc triu C.Metylamin tan trong nc cho dung dch c mi trng baz D.ipeptit glyxylalanin (mch h) c 2 lin kt peptit(H khi B 2011) Cu 721: S amin thm bc mt ng vi cng thc phn t C7H9N l A. 3. B. 5. C. 2. D. 4. (TSC 2010) Cu 722: Phat biu ung la A. Khi thuy phn n cung cac protein n gian se cho hn hp cac -aminoaxit B. Khi cho dung dich long trng trng vao Cu(OH)2 thy xut hin phc mau xanh m C. Enzim amilaza xuc tac cho phan ng thuy phn xenluloz thanh mantoz D. Axit nucleic la polieste cua axit photphoric va glucoz (H A 2010) Cu 723: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun l cht hu c no. B. protit lun cha chc hiroxyl. C. protit c khi lng phn t ln hn. D. protit lun cha nit. thi TSHC khi B 2007 Cu 724: Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-. B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. C. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). D. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. thi TSHC khi A 2008 Cu 725: C cc dung dch ring bit sau: C6H5NH3Cl (phenylamoni clorua), NH2 CH2 CH2 CH(NH2) COOH, ClNH3 CH2 COOH, HOOC CH2 CH2 CH(NH2) COOH, NH2 CH2 COONa S lng cc dung dch c pH < 7 l A. 2. B. 4. C. 5. D. 3. thi TSHC khi A 2008 Cu 726: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH(CH3)-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH2-CH2-COOH. thi TSHC khi B 2008 Cu 727: S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 2. C. 5. D. 3. thi TSC 2009 Cu 728: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 1. C. 2. D. 4. thi TSHC khi B 2009 Cu 729: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. thi TSHC khi A 2009 Cu 730: Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. B. axit -aminopropionic. C. axit -aminopropionic. D. amoni acrylat. thi TSC 2009 Cu 731: Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. D. H2NCH2COOC2H5 v ClH3NCH2COOH. thi TSC 2009 + CH 3I + HONO + CuO Cu 732: Cho s phn ng: NH 3 X Y Z (1:1) to Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, CH3CHO. B. C2H5OH, HCHO. C. CH3OH, HCHO. D. CH3OH, HCOOH. thi TSHC khi B 2007

- Chy
Cu 733:
Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch

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kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. thi TSHC khi A 2007 Cu 734: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-CH3. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-C2H5. thi TSHC khi A 2007 Cu 735: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH2=CH-NH-CH3. B. CH3-CH2-NH-CH3. C. CH3-CH2-CH2-NH2. D. CH2=CH-CH2-NH2. (H A 2010) Cu 736: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO 2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. (H B 2010) Cu 737: t chay hoan toan 0,1 mol mt amin no, mach h X bng oxi va u thu c 0,5 mol hn hp Y gm khi va hi. Cho 4,6g X tac dung vi dd HCl (d), s mol HCl phan ng la A. 0,1 B. 0,4 C. 0,3 D. 0,2(H B 2010) Cu 738: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 2. B. 3. C. 4. D. 1. (H khi A 2011) Cu 739: Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch alanin B. Dung dch glyxin C. Dung dch lysin D. Dung dch valin(H khi A 2011) Cu 740: Khi ni v peptit v protein, pht biu no sau y l sai? A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. B. Tt c cc protein u tan trong nc to thnh dung dch keo. C. Protein c phn ng mu biure vi Cu(OH)2. D. Thy phn hon ton protein n gin thu c cc -amino axit. (H khi A 2011) Cu 741: S ng phn amino axit c cng thc phn t C3H7O2N l A. 2. B. 4. C. 3. D. 1. (H khi A 2011) Cu 742: Hn hp X gm O2 v O3 c t khi so vi H2 l 22 . Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l: A. 3 : 5 B. 5 : 3 C. 2 : 1 D. 1 : 2(H khi B 2011)

- Td HCl v NaOH Cu 743: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este
caaminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. thi TSHC khi B 2007 Cu 744: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. thi TSHC khi A 2007 Cu 745: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 4. B. 8. C. 5. D. 7. thi TSHC khi A 2009 Cu 746: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 4. C. 2. D. 3. thi TSC 2008 Cu 747: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. thi TSHC khi A 2009 Cu 748: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H7N. B. C3H7N. C. C3H5N. D. CH5N. thi TSC 2007 Cu 749: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc

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ca X l A. H2NC3H6COOH.

B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. thi TSC 2008 Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH.TSHC khi B 2009 Cu 751: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NC2H4COOH. C. H2NCOO-CH2CH3. D. H2NCH2COO-CH3. thi TSC 2007 Cu 752: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NCH2CH2COOH. C. HCOOH3NCH=CH2. D. H2NCH2COOCH3. thi TSHC khi B 2008 Cu 753: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH3CH2CH3. B. CH3COONH3CH3. C. CH3CH2COONH4. D. HCOONH2(CH3)2. thi TSC 2009 Cu 754: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. thi TSHC khi A 2007 Cu 755: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6. thi TSHC khi A 2009 Cu 756: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 46. B. 85. C. 68. D. 45. thi TSHC khi B 2008 Cu 757: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v NH3. B. CH3OH v CH3NH2. C. CH3NH2 v NH3. D. C2H5OH v N2. thi TSHC khi B 2009 Cu 758: Ngi ta iu ch anilin bng s sau:

Cu 750:

+ HNO3 c Fe + HCl Benzen Nitrobenzen Anilin H 2SO 4 c to

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam. B. 55,8 gam. C. 93,0 gam.D. 111,6 gam. thi TSHC khi B 2009 Cu 759: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,3 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,2 mol thi TSHC khi B 2008 Cu 760: Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 4. B. 2. C. 3. D. 1. (TSC 2010) Cu 761: ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 1. B. 3. C. 4. D. 2. (TSC 2010) Cu 762: Dung dch no sau y lm qu tm chuyn mu xanh? A. Phenylamoni clorua. B. Glyxin. C. Etylamin. D. Anilin. (TSC 2010)

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Cu 763: Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C2H5NH2 v C3H7NH2. B. CH3NH2 v C2H5NH2. C. CH3NH2 v (CH3)3N. D. C3H7NH2 v C4H9NH2. (TSC 2010) Cu 764: Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l: A. phenylalanin B. alanin C. valin D.glyxin (C 2011) Cu 765: Pht biu no sau y l ng? A. Amino axit l hp cht c tnh lng tnh. B. Trong mi trng kim, ipetit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm. C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit. D. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit (C 2011) Cu 766: Cho cc dung dch : C6H5NH2 (amilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 3 B. 2 C. 4 D. 5 (C 2011) Cu 767: Hai cht no sau y u tc dng uc vi dung dch NaOH lang? A. ClH3NCH2COOC2H5. v H2NCH2COOC2H5. B. CH3NH2 v H2NCH2COOH. C. CH3NH3Cl v CH3NH2. D. CH3NH3Cl v H2NCH2COONa. (C 2011) Cu 768: Amin X c phn t khi nh hn 80. Trong phn t X nit chim 19,18% v khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng? A. Tch nc Y ch thu c mt anken duy nht. B. Trong phn t X c mt lin kt . C. Tn thay th ca Y l propan-2-ol. D. Phn t X c mch cacbon khng phn nhnh. (C 2011) Cu 769: Co bao nhiu tripeptit (mach h) khac loai ma khi thuy phn hoan toan u thu c 3 aminoaxit: glyxin, alanin va phenylalanin? A. 3 B. 9 C. 4 D. 6 (H A 2010) Cu 770: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5. (H A 2010) Cu 771: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,50. B. 0,65. C. 0,70. D. 0,55. (H A 2010) Cu 772: Thuy phn hoan toan 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) va 1 mol Phenylalanin (Phe). Thuy phn khng hoan toan X thu c ipeptit Val-Phe va tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X co cng thc la A. Gly-Phe-Gly-Ala-Val B. Gly-Ala-Val-Val-Phe C. Gly-Ala-Val-Phe-Gly D. Val-Phe-Gly-Ala-Gly(H B 2010) Cu 773: Trung ha han tan 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2 D. H2NCH2CH2CH2NH2. (H B 2010) Cu 774: Hai hp cht hu c X v Y c cng CTPT l C 3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dd NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. (H B 2010) Cu 775: Hn hp X gm alanin va axit glutamic. Cho m gam X tac dung hoan toan vi dd NaOH (d), thu c dd Y cha (m+30,8) gam mui. Mt khac, nu cho m gam X tac dung hoan toan vi dd HCl, thu c dd Z cha (m+36,5) gam mui. Gia tri cua m la A. 112,2 B. 165,6 C. 123,8 D. 171,0(H B 2010) Cu 776: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam AlaAla v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 90,6. B. 111,74. C. 81,54. D. 66,44. (H khi A 2011) Cu 777: Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho (d), c cn cn thn dung dch, th lng mui khan thu c l : A. 7,09 gam. B. 16,30 gam C. 8,15 gam

1 hn hp X tc dng vi dung dch HCl 10

D. 7,82 gam. (H khi A 2011)

15. Cacbohirat: 1 + 1
Cu 778: Cac dung dich phan ng c vi Cu(OH)2 nhit thng la

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A. glixerol, axit axetic, glucoz B. long trng trng, fructoz, axeton C. anhit axetic, saccaroz, axit axetic D. fructoz, axit acrylic, ancol etylic(H B 2010) Cu 779: Cht X c cc c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lam mt mau nc brom. Cht X la A. xenluloz B. mantoz C. glucoz D. Saccaroz. (H B 2010) Cu 780: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. kim loi Na. B. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. C. Cu(OH)2 trong NaOH, un nng. D. Cu(OH)2 nhit thng. thi TSHC khi A 2007 Cu 781: Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. xeton. C. amin. D. anehit. thi TSHC khi A 2009 Cu 782: Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (2), (3), (4) v (5). B. (3), (4), (5) v (6). C. (1), (2), (3) v (4). D. (1), (3), (4) v (6). thi TSHC khi B 2009 Cu 783: Pht biu khng ng l A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. B. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng gng. C. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt monosaccarit. D. Dung dch fructoz ho tan c Cu(OH)2. thi TSHC khi B 2007 Cu 784: Pht biu no sau y khng ng? A. Glucoz tc dng c vi nc brom. B. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH. C. Glucoz tn ti dng mch h v dng mch vng. D. dng mch h, glucoz c 5 nhm OH k nhau. thi TSHC khi B 2009 Cu 785: Pht biu no sau y l ng? A. Saccaroz lm mt mu nc brom. B. Xenluloz c cu trc mch phn nhnh. C. Amilopectin c cu trc mch phn nhnh. D. Glucoz b kh bi dung dch AgNO3 trong NH3. thi TSHC khi B 2009 Cu 786: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. thy phn. B. trng gng. C. trng ngng. D. ho tan Cu(OH)2. thi TSHC khi A 2008 Cu 787: Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. tinh bt. B. mantoz. C. xenluloz. D. saccaroz. thi TSHC khi A 2008 Cu 788: Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong dy tham gia phn ng trng gng l A. 3. B. 4. C. 2. D. 5. thi TSC 2008 Cu 789: Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dung dch X. Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 43,20. B. 4,32. C. 2,16. D. 21,60. (TSC 2010) Cu 790: Cp cht no sau y khng phi l ng phn ca nhau? A. Glucoz v fructoz. B. Saccaroz v xenluloz. C. 2-metylpropan-1-ol v butan-2-ol. D. Ancol etylic v imetyl ete. (TSC 2010) Cu 791: Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l: A. 60% B. 40% C. 80% D. 54% (C 2011) Cu 792: Mt phn t saccaroz co A. mt gc -glucoz va mt gc -fructoz B. mt gc -glucoz va mt gc -fructoz C. hai gc -glucoz D. mt gc -glucoz va mt gc -fructoz (H A 2010) Cu 793: Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X. Cho X phn ng vi kh H2 (xc tc Ni, to), thu c cht hu c Y. Cc cht X, Y ln lt l: A. glucoz, sobitol. B. glucoz, fructoz. C. glucoz, etanol. D. glucoz, saccaroz. (TSC 2010) Cu 794: Xenluloz trinitrat c iu ch t phn ng gia axit nictric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 2,97 tn. B. 3,67 tn. C. 2,20 tn. D. 1,10 tn. (H khi A 2011)

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Cu 795: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%, Hp th ton b lng CO2, sinh ra khi ln men m gam tinh bt vo nc vi trong , thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l: A. 405 B. 324 C. 486 D.297(H khi A 2011) Cu 796: Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit (c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam. (d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l: A. 6 B. 3 C. 4 D. 5(H khi B 2011) Cu 797: Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO 3 trong NH3 th lng Ag thu c l A.0,090 mol B. 0,095 mol C. 0,12 mol D. 0,06 mol(H khi B 2011) Cu 798: Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz (b) Trong mi trng axit, glucoz v fructoz c th chuyn ha ln nhau (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3 (d) Trong dung dch, glucoz v fructoz u ha tan Cu(OH)2 nhit thng cho dung dch mu xanh lam (e)Trong dung d ch, fructoz tn ti ch yu dng mch h (f) Trong dung dch, glucoz tn ti ch yu dng mch vng 6 cnh (dng v ) S pht biu ng l A.5 B. 3 C. 2 D. 4(H khi B 2011)

- Tc ca nhm CHO
Cu 799: Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH)2 iu kin thng l : A. 3 B. 2 C. 4 D. 5 (C 2011) Cu 800: C mt s nhn xt v cacbonhirat nh sau: (1) Saccaroz, tinh bt v xenluloz u c th b thy phn (2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia phn ng trng bc (3) Tinh bt v xenluloz l ng phn cu to ca nhau (4) Phn t xenluloz c ccu to bi nhiu gc -glucoz (5) Thy phn tinh bt trong mi trng axit sinh ra fructoz Trong cc nhn xt trn, s nhn xt ng l A.2 B. 5 C. 4 D. 3 (C 2011) Cu 801: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 trong dung dch NH3 thu c 2,16 gam Ag kt ta. Nng mol/l ca dung dch glucoz dng l A. 0,01M. B. 0,02M. C. 0,20M. D. 0,10M. thi TSC 2007 Cu 802: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 1,44 gam. B. 2,25 gam. C. 1,80 gam. D. 1,82 gam. thi TSHC khi A 2008

- Tng hp cc cht t cacbohirat Cu 803: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l
A. CH3CH2OH v CH2=CH2. B. CH3CHO v CH3CH2OH. C. CH3CH(OH)COOH v CH3CHO. D. CH3CH2OH v CH3CHO. thi TSC 2007 Cu 804: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,0 kg. B. 5,4 kg. C. 6,0 kg. D. 4,5 kg. thi TSHC khi B 2008 Cu 805: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l A. 60. B. 58. C. 30. D. 48. thi TSC 2009 Cu 806: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l A. 550. B. 810. C. 650. D. 750. thi TSHC khi A 2007 Cu 807: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch

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nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 20,0. B. 30,0. C. 13,5. D. 15,0. thi TSHC khi A 2009 Cu 808: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l A. 26,73. B. 33,00. C. 25,46. D. 29,70. thi TSC 2008 Cu 809: Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg xenluloz trinitrat (hiu sut 80%) l A. 42,34 lt. B. 42,86 lt. C. 34,29 lt. D. 53,57 lt. thi TSC 2009 Cu 810: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l A. 30 kg. B. 42 kg. C. 21 kg. D. 10 kg. thi TSHC khi B 2007 Cu 811: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 81 lt. B. 55 lt. C. 49 lt. D. 70 lt. thi TSHC khi B 2008 Cu 812: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ha 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ha hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 80%. B. 10%. C. 90%. D. 20%. (H A 2010)

15. Polime v vt liu polime: 1

Cu 813: Cho cac loai t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp la A. 3 B. 4 C. 2 D.5 (H A 2010) Cu 814: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylen-terephtalat); (5) nilon-6,6; (6) poli (vinyl axetat), cc polime l sn phm ca phn ng trng ngng l: A. (1), (3), (6). B. (3), (4), (5). C. (1), (2), (3). D. (1), (3), (5). (H A 2010)

Cu 815: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. thi TSHC khi B 2009 Cu 816: Pht biu no sau y l ng? A. T visco l t tng hp. B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. D. Trng hp stiren thu c poli(phenol-fomanehit). thi TSHC khi B 2009 Cu 817: Nilon6,6 l mt loi A. t axetat. B. t poliamit. C. polieste. D. t visco. thi TSHC khi A 2007 Cu 818: Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=CH-CH=CH2, C6H5CH=CH2. B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, CH3-CH=CH2. thi TSHC khi B 2007 Cu 819: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. CH2=CH-COO-C2H5. B. CH2=CH-COO-CH3. C. C2H5COO-CH=CH2. D. CH3COO-CH=CH2. thi TSC 2007 Cu 820: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. C6H5CH=CH2. C. CH3COOCH=CH2. D. CH2 =CHCOOCH3. thi TSC 2007 Cu 821: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T visco v t axetat. B. T tm v t enang. C. T nilon-6,6 v t capron. D. T visco v t nilon-6,6. thi TSC 2007 Cu 822: Polime c cu trc mng khng gian (mng li) l A. nha bakelit. B. PVC. C. PE. D. amilopectin. thi TSHC khi B 2008 Cu 823: Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. thi TSHC khi A 2009 Cu 824: T nilon - 6,6 c iu ch bng phn ng trng ngng A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. Trang 55/59 Cc dng bi tp Ha hc n thi H, C t 2007 n 2011

C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. D. H2N-(CH2)5-COOH. thi TSC 2008 Cu 825: Cac cht u khng bi thuy phn trong dung dich H2SO4 loang, nong la A. t capron; nilon-6,6, polietylen B. poli (vinyl axetat); polietilen, cao su buna C. nilon-6,6; poli(etylen-terephtalat); polistiren D. polietylen; cao su buna; polistiren(H B 2010) Cu 826: Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng hp vinyl xianua. B. Trng ngng axit -aminocaproic. C. Trng hp metyl metacrylat. D. Trng ngng hexametyleniamin vi axit aipic. (H khi A 2011) Cu 827: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 2 B. 1 C. 4 D. 3(H khi B 2011)

- Hiu sut phn ng, s tng hp

Cu 828: Cho cc polime : (1) polietilen , (2) poli(metyl metacrylat), (3) polibutaien, (4) polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch kim l: A. (2),(3),(6) B. (2),(5),(6) C. (1),(4),(5) D. (1),(2),(5) (C 2011) Cu 829: Polime no sau y c tng hp bng phn ng trng ngng? A. poliacrilonitrin. B. poli(metyl metacrylat). C. polistiren. D. poli(etylen terephtalat). (TSC 2010) Cu 830: Cho s chuyn hoa sau
+ H ,t xt,t + Z C 2 H 2 X 2 Y ,p Cao su buna N Pd,PbCO t 0 ,xt
3 0 0

Cac cht X, Y, Z ln lt la : A. benzen; xiclohexan; amoniac C. vinylaxetilen; buta-1,3-ien; stiren Cu 831 : Cho s phn ng:
+HCN

B. axetanehit; ancol etylic; buta-1,3-ien D. vinylaxetilen; buta-1,3-ien; acrilonitrin (H B 2010)

ng trng hp

trng hp CH CH X; X polime Y; X + CH2=CH-CH=CH2 polime Z Y v Z ln lt dng ch to vt liu polime no sau y? A.T capron v cao su buna. B. T nilon-6,6 v cao su cloropren. C. T olon v cao su buna-N. D. T nitron v cao su buna-S. (H khi A 2011)

- H s polime ha Cu 832:

Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 453. B. 382. C. 328. D. 479. thi TSC 2009 Cu 833: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l A. 3. B. 6. C. 4. D. 5. thi TSHC khi A 2007 Cu 834: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 121 v 114. B. 121 v 152. C. 113 v 152. D. 113 v 114. thi TSHC khi A 2008

- Hiu sut phn ng, s tng hp Cu 835: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s
A. 224,0. trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) B. 286,7. C. 358,4. D. 448,0. thi TSHC khi A 2008

17. Tng hp ni dung cc kin thc ha hu c thuc chng trnh ph thng: 6 - P, tnh cht ha hc Cu 836: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l:
A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen. thi TSHC khi A 2007 Cu 837: Dy gm cc dung dch u tham gia phn ng trng bc l: A. Glucoz, mantoz, axit fomic, anehit axetic. B. Fructoz, mantoz, glixerol, anehit axetic. C. Glucoz, glixerol, mantoz, axit fomic. D. Glucoz, fructoz, mantoz, saccaroz. thi TSHC khi A 2009 Cu 838: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 3. C. 5. D. 4. thi TSHC khi B 2007 Cu 839: Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy

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phn ng c vi NaOH (trong dung dch) l B. 2. C. 1. D. 4. thi TSC 2008 Cu 840: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. thi TSC 2008 Cu 841: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 4. B. 5. C. 3. D. 6. thi TSHC khi B 2008 Cu 842: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 5. B. 6. C. 8. D. 7. thi TSHC khi B 2008 Cu 843: Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 2. B. 1. C. 4. D. 3. thi TSHC khi B 2008 Cu 844: Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3COOH. B. CH3OH. C. CH3NH2. D. CH3COOCH3. thi TSHC khi B 2008 Cu 845: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l A. 4. B. 3. C. 5. D. 6. thi TSC 2007 Cu 846: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 3. B. 4. C. 5. D. 2. thi TSHC khi A 2009 Cu 847: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 3. B. 1. C. 4. D. 2. thi TSC 2007 Cu 848: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 6. B. 4. C. 5. D. 3. thi TSHC khi B 2007 Cu 849: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung o o dch NaOH (t ) v vi dung dch HCl (t ). S phn ng xy ra l A. 3. B. 6. C. 4. D. 5. thi TSC 2009 Cu 850: Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l: A. (2), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (1), (3), (4). thi TSC 2008 A. 3.

- Lin kt H, tnh axit baz, nhn bit Cu 851: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc

cht c sp xp theo tnh axit tng dn (t tri sang phi) l: A. (T), (Y), (X), (Z). B. (X), (Z), (T), (Y). C. (Y), (T), (Z), (X). D. (Y), (T), (X), (Z). thi TSC 2009 Cu 852: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. T, X, Y, Z. B. T, Z, Y, X. C. Z, T, Y, X. D. Y, T, X, Z. thi TSHC khi B 2007 Cu 853: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l: A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. CH3COOH, C2H6, CH3CHO, C2H5OH. C. C2H6, C2H5OH, CH3CHO, CH3COOH. D. C2H6, CH3CHO, C2H5OH, CH3COOH. thi TSHC khi A 2008 Cu 854: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3COOH, C2H5OH, HCOOH, CH3CHO. B. CH3CHO, C2H5OH, HCOOH, CH3COOH. C. CH3COOH, HCOOH, C2H5OH, CH3CHO. D. HCOOH, CH3COOH, C2H5OH, CH3CHO. thi TSHC khi B 2009 Cu 855: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. thi TSHC khi B 2007 Cu 856: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. dung dch NaOH. C. nc brom. D. giy qu tm. thi TSHC khi B 2007 Cu 857: Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau:

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A. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic. B. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic. C. lng trng trng, glucoz, fructoz, glixerin (glixerol). D. glucoz, mantoz, glixerin (glixerol), anehit axetic. thi TSC 2007 Cu 858: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. thi TSHC khi A 2009

- Tng hp, s Cu 859:

Pht biu ng l: A. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp. B. Tnh baz ca anilin mnh hn ca amoniac. C. Cao su thin nhin l sn phm trng hp ca isopren. D. Tnh axit ca phenol yu hn ca ru (ancol). thi TSHC khi A 2008 Cu 860: Pht biu khng ng l: A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. thi TSHC khi A 2007 Cu 861: Pht biu no sau y l ng? A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. C. Benzen lm mt mu nc brom nhit thng. D. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. thi TSHC khi A 2009 Cu 862: Cho s chuyn ho sau: C3H4O2 + NaOH X + Y X + H2SO4 long Z + T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l: A. CH3CHO, HCOOH. B. HCOONa, CH3CHO. C. HCHO, CH3CHO. D. HCHO, HCOOH. thi TSHC khi A 2008 Cu 863: Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. C2H5OH, CH3COOH. B. CH3COOH, CH3OH. C. CH3COOH, C2H5OH. D. C2H4, CH3COOH. thi TSC 2008 Cu 864: Cho s chuyn ho sau:
+X +NaOH d Phenol phenyl axetat o Y(h p cht th m) t

Hai cht X, Y trong s trn ln lt l: A. axit axetic, phenol. C. anhirit axetic, natri phenolat. Cu 865: Cho cc chuyn ho sau:
xt, t X + H 2 O Y Ni Y + H 2 Sobitol to
o

B. anhirit axetic, phenol. D. axit axetic, natri phenolat. thi TSHC khi A 2009

Y + 2AgNO3 + 3NH3 + H2 O Amoni gluconat + 2Ag + NH4 NO3

xt Y E + G
di lc p Z + H 2 O X + G nh sng

X, Y v Z ln lt l: A. xenluloz, fructoz v kh cacbonic. C. xenluloz, glucoz v kh cacbon oxit.

B. tinh bt, glucoz v ancol etylic. D. tinh bt, glucoz v kh cacbonic. thi TSC 2009
+CH 3I +HNNO +CuO

Cho s phn ng: NH 3 X Y Z (1:1) to Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, CH3CHO. B. C2H5OH, HCHO. C. CH3OH, HCHO. D. CH3OH, HCOOH. thi TSHC khi B 2007 Cu 867: Cho s chuyn ha: Cu 866:
+ H 3O + KCN CH 3CH 2Cl X Y to
+

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Cng thc cu to ca X, Y ln lt l: A. CH3CH2NH2, CH3CH2COOH. B. CH3CH2CN, CH3CH2COOH. C. CH3CH2CN, CH3CH2CHO. D. CH3CH2CN, CH3CH2COONH4. thi TSHC khi A 2009 Cu 868: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. D.CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. thi TSHC khi B 2008 Cu 869: iu kin thch hp: cht X phn ng vi cht Y to ra anehit axetic; cht X phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l: A. C2H4, O2, H2O. B. C2H2, H2O, H2. C. C2H2, O2, H2O. D. C2H4, H2O, CO. (TSC 2010) Cu 870: Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2 gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung dch AgNO 3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 10,8. B. 16,2. C. 43,2. D. 21,6 (TSC 2010) Cu 871: Hp cht hu c X c cng thc phn t l C 4H8O3. X c kh nng tham gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thu phn ca X trong mi trng kim c kh nng ho tan Cu(OH) 2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l: A. CH3CH(OH)CH(OH)CHO B. HCOOCH2CH(OH)CH3 C. CH3COOCH2CH2OH. D. HCOOCH2CH2CH2OH (C 2011)

- Tng hp, s
+ X( xt,t ) + Z(xt ,t ) + M(xt,t ) Cu 872: Cho s phn ng: CH 4 Y T CH 3COOH (X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng). Cht T trong s trn l: A. C2H5OH B. CH3COONa C. CH3CHO D. CH3OH (C 2011) Cu 873: Cho s chuyn ha: CH 3OH , t 0 , xt CuO ,t 0 C3H6 dung X NaOH Y Z O2 , xt T E (Este a chc). dich Br2 Tn gi ca Y l A. propan-1,3-iol. B. propan-1,2-iol. C. propan-2-ol. D. glixerol. (H A 2010) Cu 874: X, Y ,Z l cc hp cht mch h, bn c cng cng thc phn t C 3H6O . X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng vi Na nhng c phn ng trng bc, Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3. B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO. C. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH. D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH. (H khi A 2011) Cu 875: Cho dy chuyn ha sau o o o

Benzen

+C2H4

+Br2, as

xt.t0

t l mol 1:1

KOH/C2H5OH t0 Z

(trong X, Y, Z l sn phm chnh)

Tn gi ca Y, Z ln lt l A. benzylbromua v toluen B. 1-brom-1-phenyletan v stiren C. 2-brom-1pheny1benzen v stiren D. 1-brom-2-phenyletan v stiren. (H khi A 2011) Cu 876: Ha tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat B. natri phenolat, axit clohiric, phenol C. phenylamoni clorua, axit clohiric, anilin D. anilin, axit clohiric, phenylamoni clorua(H khi B 2011) Cu 878: Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh (g) Hp cht C9H14BrCl c vng benzen trong phn t S pht biu ng l A. 4 B. 3 C. 2 D. 5(H khi B 2011) Cu 879: Pht biu no sau y l ng? A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng thuc th l nc brom.

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B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. C. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. D. Trong phn ng este ha gia CH3COOH vi CH3OH, H2O to nn t -OH trong nhm -COOH ca axit v H trong nhm -OH ca ancol. (H khi B 2011) Cu 880: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (ktc). Gi tr ln nht ca V l A. 22,4 B. 5,6 C. 11,2 D. 13,44(H khi B 2011) Cu 881: Cho cc pht biu sau: (a) Anehit va c tnh oxi ha va c tnh kh (b) Phenol tham gia phn ng th brom kh hn benzen (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt (d) Dung dch axit axetic tc dng c vi Cu(OH)2 (e) Dung dch phenol trong nc lm qu tm ha (f) Trong cng nghip, axeton c sn xut t cumen S pht biu ng l A. 5 B. 4 C. 3 D. 2(H khi B 2011) Cu 882: Cho s phn ng: (1)CH3CHO (2)C2H5Br
+HCN + Mg ete +H2O

X1 Y1

H+ , t o + CO2

X2 Y2 Y3
+ HCl

Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l A. axit 3-hirxipropanoic v ancol propylic. B. axit axetic v ancol propylic. C. axit 2-hirxipropanoic v axit propanoic. D. axit axetic v axit propanoic. (H khi B 2011) Cu 883: Trong qu gc chn rt giu hm lng: A.ete ca vitamin A B. este ca vitamin A C. -caroten D. vitamin A(H khi B 2011)

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