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THI TH S 001 ( thi c 08 trang)

THI TH TUYN SINH I HC NM 2012 Mn: HA HC; Khi A,B Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 2012 00A

H, tn th sinh: S bo danh: Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu t cu 1 n 40) Cu 1: Cho axit salixylic phn ng vi anhirit axetic, thu c axit axetylsalixylic dng lm thuc cm (aspirin). phn ng hon ton vi 58,68 gam axetylsalixylic cn va V lt KOH 1M. Gi tr ca V l: A. 0,978 lt B. 0,625 lt C. 0,326 lt D. 1,304 lt Cu 2: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l: A. 4 : 3 B. 3 : 4 C. 7 : 4 D. 4 : 7 Cu 3: Thy phn hon ton 143,45 gam hn hp A gm hai Tetrapeptit thu c 159,74 gam hn hp gm cc aminoaxit (cc aminoaxit ch cha 1 nhm COOH v 1 nhm NH 2). Cho ton b X tc dng vi dung dch HCl d, sau c cn dung dch th nhn c m gam mui khan. Khi lng nc phn ng v gi tr ca m ln lt l: A. 8,145 gam v 203,78 gam B. 16,29 gam v 10,15 gam C. 8,145 gam v 10,15 gam D. 16,29 gam v 203,78 gam Cu 4: Trong cc th nghim sau : (a) Cho SiO2 tc dng vi axit HF. (b) Cho kh SO2 tc dng vi kh H2S. (c) Cho kh NH3 tc dng vi CuO un nng. (d) Cho CaOCl2 tc dng vi dung dch HCl c. (e) Cho Si n cht tc dng vi dung dch NaOH. (f) Cho kh O3 tc dng vi Ag. (g) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. (h) O3 tc dng vi dung dch KI. (i) KClO3 tc dng vi dung dch HCl c, un nng. (j) Axit HF tc dng vi SiO2. (k) un nng dung dch bo ha gm NH4Cl v NaNO2. (m) MnO2 tc dng vi dung dch HCl c, un nng. (n) Cho kh NH3 qua CuO nung nng. (o) Kh SO2 tc dng vi nc Cl2. S th nghim to ra n cht l: A. 11 B. 12 C. 10 D. 9 Cu 5: un hn hp hai axit n chc vi 6,2 gam etylenglycol, chng tc dng va vi nhau c hn hp B gm ba este trung tnh X, Y, Z xp theo th t khi lng phn t tng dn. Thy phn ton b este Y cn va dung dch cha 2,4 gam NaOH. Lng mui sinh ra em nung vi hn hp NaOH v CaO ti hon ton thu c hn hp kh c M = 9. Bit tng khi lng ca ba este l 13,06. Khi lng ca este X v Y l: A. mX = 4,38 gam; mY = 3,69 gam B. mX = 4,72 gam; mY = 3,96 gam C. mX = 4,38 gam; mY = 4,72 gam D. mX = 4,72 gam; mY = 4,38 gam Trang 1/8 M thi 2012 00A

Cu 6: Khi iu ch C2H4 bng cch un nng ( 1700C) hn hp C2H5OH v H2SO4 c, nu cho kh thot ra i qua dung dch KMnO4 ta khng thy xut hin kt ta MnO2 nh khi cho etilen tinh khit i qua dung dch KMnO4. Tp cht X gy nn hin tng . Mun loi b n thu c C2H4 nguyn cht, c th dung dung dch no trong cc dung dch di y: A. K2CO3 B. Br2 C. BaCl2 D. KOH Cu 7: Cho s phn ng sau: + H2 A X+D + O2 X B Y+Z + Y hoc Z C A+G + Fe Vi X l S. Cho cc cp cht sau: (1) HCl v FeCl2; (2) HCl v FeSO4; (3) H2SO4 v FeCl2; (4) H2SO4 v FeSO4; (5) HBr v FeBr2; (6) HBr v FeSO4; (7) H2SO4 v FeBr2; (8) H2SO4 v Fe2(SO4)3; (9) HCl v FeBr2. S cp cht ph hp vi cc cht Y v G (theo th t) l: A. 7 B. 6 C. 5 D. 8 Cu 8: Cho cc pht biu sau: (a) Trong nhm IA (t Li n Cs), khi lng ring tng dn, nhit nng chy gim dn. (b) Trong nhm IIA, tnh kh tng dn t Be n Ba. (c) Photpho trng c cu trc mng tinh th phn t cn photpho c cu trc polime. (d) Kh than t c sn xut bng cch cho hi nc i qua than nung . (e) Hai phng php ch yu ch ha du m l rifominh v crckinh. (f) Anehit va th hin tnh oxi ha va th hin tnh kh.. (g) Cc dung dch: etylen glicol, glixerol, glucoz u ha tan c Cu(OH) 2. (h) Este c nhit si thp hn so vi axit v ancol c cng s nguyn t C. (i) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh ( v ). (j) Trong phn t saccaroz khng c nhm OH hemiaxetal. (k) Tinh bt v xenluloz u thuc loi polisaccarit. (l) Cc ng v ca mt nguyn t ha hc c tnh cht vt l v ha hc u ging nhau. (m) Lu hunh v photpho u bc chy khi tip xc CrO3 S pht biu sai l: A. 1 B. 2 C. 3 D. 4 Cu 9: Trong mi chn s X, Y, Z ng mt mui nitrat. Nung cc chn nhit cao trong khng kh n khi cc phn ng xy ra hon ton. Sau khi lm ngui chn nhn thy. - Trong chn X khng cn li du vt g. - Trong chn Y cn li cht rn mu trng. - Trong chn Z cn li cht rn mu en tan trong dung dch HCl to dung dch c mu xanh. Cc mui nitrat trong chn ln lt l: A. NH4NO3, Zn(NO3)2, AgNO3 B. Hg(NO3)2, Ca(NO3)2, Fe(NO3)3 C. NH4NO2, NaNO3, Cu(NO3)2 D. NH4NO3, KNO3, Fe(NO3)2 Cu 10: Trn ln phn st-amoni (NH4)2SO4.Fe2(SO4)3.24H2O. Dung dch Al2(SO4)3 v H2SO4 c 400ml dung dch X. Chia X lm hai phn bng nhau. Cho phn 1 tc dng vi BaCl2 thu c 13,98 gam kt ta. Cho Ba(OH)2 t t n d vo phn 2 v un nng c kh duy nht. Khi lng kt ta ln nht v nh nht thu c l 16,61 gam v 15,05 gam. Gi tr ca pH ca dung dch X l: A. 1 B. 11 C. 2 D. 10 2+ + Cu 11: Dung dch X cha cc ion: Ca , Na , HCO3 v Cl trong s mol ca ion Cl- l 0,1 mol. Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m: A. 8,79 gam B. 9,21 gam C. 9,26 gam D. 7,47 gam Cu 12: Cho DFe = 7,87 (g/cm3); MFe = 55,85 (vC); DAu = 19,32 (g/cm3); MAu = 196,97 (vC). Bit rng c kht ca mng li tinh th nguyn t t 75% (nguyn t ch chim 75% tng th tch cc khi cu). Bn knh cc nguyn t (cm) ca Fe v Au ln lt l: A. 1,06.10-8 v 1,40.10-8 B. 1,06.10-8 v 1,45.10-8 -8 -8 C. 1,10.10 v 1,45.10 D. 1,10.10-8 v 1,40.10-8 Trang 2/8 M thi 2012 00A

Cu 13: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch NaOH 0,75M thu c dung dch Y. C cn Y thu c 10,83 gam cht rn khan. Gi tr ca m l: A. 8,51 gam B. 6,9 gam C. 8,88 gam D. 8,44 gam Cu 14: Cho cc cp cht sau: (a) Kh Cl2 v kh O2 (b) Kh H2S v kh SO2 (c) Kh H2S v dung dch Pb(NO3)2 (d) Kh Cl2 v dung dch NaOH (e) Kh NH3 v dung dch AlCl3 (f) Dung dch KMnO4 v kh SO2 (g) Hg v S (h) Kh CO2 v dung dch NaClO (i) Dung dch AgNO3 v dung dch Fe(NO3)2 (j) CuS v dung dch HCl S cp cht xy ra phn ng ha hc nhit thng l: A. 8 B. 7 C. 9 D. 10 Cu 15: Ha tan hon ton FeS2 vo cc cha dung dch HNO3 long c dung dch X v kh NO thot ra. Thm bt Cu d vo dung dch X, sau thm tip dung dch H2SO4 vo, thu c dung dch Y c mu xanh, nhng khng c kh thot ra. Cc cht tan c trong dung dch Y l: A. Cu(NO3)2, Fe(NO3)2, H2SO4 B. Cu(NO3)2, Fe2(SO4)3 , H2SO4 C. CuSO4 , FeSO4 , H2SO4 D. Cu(NO3)2, Fe(NO3)3, H2SO4 Cu 16: Cc cht u b thu phn trong dung dch NaOH long, nng l: A. nilon-6, protein, nilon-7, anlyl clorua, vinyl axetat. B. nilon-6, tinh bt, saccaroz, t visco, anlyl clorua, poliacrilonitrin. C. vinyl clorua, glyxylalanin, poli(etylen-terephtalat), poli(vinyl axetat), nilon-6,6. D. mantoz, protein, poli(etylen-terephtalat), poli(vinyl axetat), tinh bt. Cu 17: Cho kh CO i qua ng s ng 0,04 mol hn hp A gm FeO v Fe2O3 t nng. Sau khi kt thc th nghim thu c 4,784 gam hn hp rn B gm 4 cht. Kh thot ra khi ng s cho hp th hon ton vo dung dch Ba(OH)2 d thu c 9,062 gam kt ta. Mt khc ha tan B bng dung dch HCl d thy thot ra 0,6272 lt H2 (iu kin tiu chun). Phn trm % khi lng Fe2O3 trong A v B ln lt l (bit trong B s mol Fe3O4 bng 1/3 tng s mol ca FeO v Fe2O3). A. 68,96% v 20,07% B. 67,78% v 20,07% C. 68,96% v 18,06% D. 67,78% v 18,06% Cu 18: Cho cn bng : N2 (k) + 3H2 (k) 2NH3 (k) Khi tng nhit th t khi ca hn hp kh thu c so vi H2 gim. Pht biu ng v cn bng ny l: A. Phn ng nghch thu nhit, cn bng chuyn dch theo chiu thun khi tng nhit . B. Phn ng thun thu nhit, cn bng chuyn dch theo chiu thun khi tng nhit . C. Phn ng nghch ta nhit, cn bng chuyn dch theo chiu nghch khi tng nhit . D. Phn ng thun ta nhit, cn bng chuyn dch theo chiu nghch khi tng nhit . Cu 19: Ha tan 26,64 gam mt mui sunfat kim loi M, ngm nc (M c ha tr x) trong nc c dung dch A. - Dung dch A tc dng va vi dung dch NH3 c kt ta B, un B nhit cao n khi lng khng i cn 4,08 gam cht rn. - Dung dch A tc dng va vi dung dch BaCl2 thu c 27,84 gam kt ta. Cng thc phn t ca mui ? A. FeSO4.7H2O B. Fe2(SO4)3.10H2O C. Al2(SO4)3.18H2O D. CuSO4.5H2O Cu 20: Tng h s cn bng ca cc cht tham gia trong phn ng sau l: Zn + H2SO4 ZnSO4 + S + H2S + SO2 + H2O Bit t l mol ca S : H2S : SO2 = a : b : c A. 4a + 5b + 2c B. 7a + 9b + 3c C. 9a + 11b + 4c D. 10a + 13b + 5c Cu 21: Cho hn hp X gm CH2=CHOCH3; CH2=CHCH2OH v CH3CH2CHO (s mol mi cht u bng nhau) phn ng vi lng d dung dch AgNO 3 trong NH3, kt thc phn ng thu c 5,4 gam Ag. Mt khc, nu cho ton b lng X trn tc dng ht vi dung dch KMnO 4 (d) th khi lng cht hu c sinh ra l: A. 7,08 gam. B. 6,45 gam. C. 7,40 gam. D. 4,60 gam Trang 3/8 M thi 2012 00A

Cu 22: Cho cc pht biu sau: (a) Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l 3. (b) Cc cht u khng b thy phn trong dung dch H2SO4 long, nng l polietylen; cao su buna; polistiren. (c) Trong cc polime sau: nilon-7, poli(etylen-terephtalat), nilon-6,6, cc polime ny l sn phm ca phn ng trng ngng. (d) 1,1,2,2-tetrafloeten, propilen, t nilon 6 l cc cht u c kh nng tham gia phn ng trng hp. (e) Polime to thnh sau phn ng khu mch l nha rezit. (f) Lipit bao gm nhiu loi este phc tp. (g) Metyl metacrylat dng iu ch thy tinh hu c. S pht biu ng l: A. 7 B. 6 C. 4 D. 5 Cu 23: Trong mt bnh kn cha mt hn hp 2,24 lt kh H2, C2H4, C3H6 ( iu kin tiu chun, vi t l mol C2H4, C3H6 l 1 : 1) v bt Ni. t nng bnh mt thi gian sau a v nhit ban u th thy t khi hi so vi hiro ca hn hp kh trong bnh trc v sau phn ng l 7,6 v 8,445. Gii thch ti sao t khi tng ?. A. Sn phm to ra (ankan) c khi lng ln hn khi lng cht ban u (anken) B. Hn hp cc kh sau phn ng nng hn. C. Tng s mol cc kh trong bnh sau phn ng tng. D. Tng s mol cc kh trong bnh sau phn ng gim. Cu 24: Ha hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (38.nX = 117.nY), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o cng trong iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO 2 (iu kin tiu chun) . Cng thc cu to ca X, Y ln lt l: A. (COOH)2 v CH3CH2CH2CH2-COOH B. CH3CH2-COOH v (COOH)2 C. H-COOH v HOOC-CH2-CH2-COOH D. (COOH)2 v CH3CH2CH2CH2CH2-COOH Cu 25: Hn hp kh X gm etylamin v hai hirocacbon ng ng lin tip. t chy hon ton V ml hn hp X bng mt lng oxi va , thu c V1 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) cn li V 2 ml kh (cc th tch kh v hi o cng iu kin). Bit V = V1 2V2. Vy cng thc phn t ca hai hirocacbon l: A. C3H2 v C3H4 B. C3H6 v C4H8 C. CH4 v C2H6 D. C2H4 v C3H6 Cu 26: Hn hp A gm Al2O3, MgO, Fe3O4, CuO. Cho kh CO d qua A nung nng c cht rn B. Ha tan B vo dung dch NaOH d c dung dch C v cht rn D. (a) B gm c MgO v Al2O3. (b) Dung dch C gm c NaAlO2 v NaOH. (c) Nh vi git dung dch C thy c kt ta keo trng xut hin ngay nhng sau b tan dn. (d) Cho D tc dng vi HNO3 long thy c kh thot ra b ha nu trong khng kh. ng trong cc sau y l: A. a, b B. a, c C. b, c D. b, d Cu 27: t chy hon ton 11,3 gam cht hu c A c hn hp X ch gm CO2, hi nc v kh HCl. Dn ton b X qua bnh ng dung dch AgNO 3 d thy khi lng bnh tng 10,9 gam v xut hin 28,7 gam kt ta. Kh thot ra khi bnh dn tip qua bnh nc vi trong d thy xut hin 30 gam kt ta. Tng s ng phn cu to ca A l: A. 4 B. 5 C. 6 D. 7 Cu 28: X l hn hp gm axit cacboxylic n chc Y v ancol no Z, tt c u mch h v c cng s C trong phn t. t chy hon ton 0,4 mol X cn va 43,2 gam O2, sau phn ng thu c 52,8 gam CO2 v 19,8 gam H2O. Este ha cng 0,4 mol X trn thu c khi lng este ln nht l: A. 19,50 gam B. 23,00 gam C. 21,33 gam D. 11,00 gam Trang 4/8 M thi 2012 00A

Cu 29: T 1 tn pirit cha 75,3% FeS2, 13,1% CuFeS2 v 11,6% tp cht tr c th iu ch c bao nhiu lt dung dch H2SO4 78,04% (d = 1,71 g/ml) bit lng SO2 b mt khi nung l 1,5% v lng axit b mt mt l 0,2%. A. 1008,6 lt B. 787,13 lt C. 733,92 lt D. 2017,2 lt Cu 30: X l hn hp gm axit cacboxylic n chc A, ancol n chc B v este D to bi A, B. Cho 0,3 mol X tc dng va vi dung dch cha 0,25 mol NaOH un nng, sau c cn c m gam ancol B v 23,5 gam mui khan. Oxi ha ht m gam B thnh anehit, ri cho ton b lng anehit ny tc dng vi lng d dung dch AgNO 3 trong NH3 c 75,6 gam Ag. Vy khi lng hn hp X dng trong th nghim l: A. 21,35 gam B. 24 gam C. 31,2 gam D. 19,75 gam Cu 31: Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c + nng) c) Al2O3 + HNO3 (c, nng) d) Cu + dung dch FeCl3
Ni ,t e) CH3CHO + H2 f) glucoz + AgNO3 trong dung dch NH3 g) C2H4 + Br2 h) glixerol (glixerin) + Cu(OH)2 i) FeCO3 + HNO3 (c, nng) m) AgNO3 + dung dch Fe(NO3)2 t n) CH3OH + CuO o) metanal + AgNO3 trong dung dch NH3 MnO , t p) KClO3 q) anilin + Br2 (dd) C bao nhiu dy gm cc phn ng u thuc loi phn ng oxi ha kh l: A. 10 B. 12 C. 11 D. 13 Cu 32: un nng 32,1 gam hn hp X gm hai cht hu c X, Z cng nhm chc vi dung dch NaOH d, thu c hn hp mui natri ca hai axit cacboxylic no, n chc k tip nhau trong dy ng ng v mt cht lng A (t khi hi ca A so vi metan bng 3,625). Cht A phn ng vi CuO un nng cho sn phm c phn ng trng bc. Cho 1/10 lng A phn ng vi Na c 0,015 mol H2. Nhn nh no sau y l sai: A. Nung 1 trong 2 mui thu c vi NaOH ( c vi ti) s to metan. B. Tn gi ca A l ancol anlylic C. Trong hn hp X hai cht Y, Z c s mol bng nhau D. t chy hon ton hn hp X trn s thu c s mol CO 2 tr s mol H2O bng 0,02 mol. Cu 33: T butan, cc cht v c, bng phng php ha hc iu ch c ankanal A (mch C ngn hn). T A iu ch hai cht tng ng ankanol B, ankanoic D, t B v D iu ch c este E tng ng. - Khi thc hin phn ng x phng ha ca m gam este E trong dung dch KOH va to m1 gam mui kali. Nu thc hin trong dung dch Ca(OH)2 va to m2 gam mui canxi v m2 < m < m1. - Khi nung m1 gam mui kali vi hn hp KOH v CaO va to 2,24 lt kh G ( iu kin tiu chun). Khi lng m gam este l: A. 9,8 gam B. 8,8 gam C. 12,6 gam D. 7,4 gam Cu 34: Hn hp kh A gm H2 v hai olefin ng ng lin tip. Cho 19,04 lt hn hp kh A ( iu kin tiu chun) i qua bt Ni nung nng ta thu c hn hp kh B (gi s hiu sut phn ng t 100%) v tc phn ng ca hai olefin nh nhau. Cho mt t hn hp kh B i qua nc brom thy brom b nht mu. Mt khc, t chy 1/2 hn hp kh B th thu c 43,5 gam CO 2 v 20,43 gam nc. Cng thc phn t v phn trm th tch cc kh trong hn hp A l: A. C3H6 v C4H8. %C3H6 = 29,43%; %C4H8 = 35,99% B. C2H4 v C3H6. %C2H4 = 29,43%; %C3H6 = 35,99% C. C3H6 v C4H8. %C3H6 = 28,55%; %C4H8 = 71,45% D. C2H4 v C3H6. %C2H4 = 28,55%; %C3H6 = 71,45% Cu 35: C hp cht M2X. Trong tng s ht proton, ntron v electron l 116. S ht mang in nhiu hn s ht khng mang in l 36. Khi lng nguyn t ca X ln hn M l 9. Tng ba loi ht trn trong X2- ln hn trong M+ l 17. Hp cht M2X c th tc dng c vi bao nhiu cht trong s cc dung dch sau: HCl, FeCl3, HNO3, CuSO4, NaOH, PbSO4, H2SO4 ?. A. 4 cht B. 3 cht C. 5 cht D. 6 cht
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0 0 2

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Cu 36: Cho dy cc cht v ion: SO2, Fe2+, Cr3+, S2-, Cl2, NO2, HCl, FeCl3, Al3+, S, Br-, HCHO, H2O, KMnO4, K2Cr2O7, HNO3, NH3, S, FeO, NO2, C, N2, KI, H2S, F2, Mn2+, Zn, Na+, Ca2+,Fe3+, Al3+, Mg2+, S cht v ion va c tnh oxi ha, va c tnh kh l: A. 22 B. 25 C. 24 D. 23 Cu 37: Cho m gam cht rn X gm Cu v Fe (t l khi lng tng ng 3: 7) vo 400ml dung dch HNO3 2M. Sau phn ng xy ra xong c 5,6 lt (iu kin tiu chun) hn hp NO, NO 2 v cn li 0,8m gam rn cha tan. Cho bit phn ng ch xy hai qu trnh kh N 5+. Vy khi lng mui to thnh sau phn ng l: A. 49,5 gam B. 77,0 gam C. 21,6 gam D. 67,9 gam Cu 38: C cc dung dch khng mu: HCOOH, CH3COOH, glucoz, glixerol, C2H5OH, CH3CHO. Thuc th nhn bit c c 6 cht trn l: A. Qu tm B. Cu(OH)2 C. Qu tm v [Ag(NH3)]OH D. [Ag(NH3)]OH Cu 39: Cho cc pht biu sau: (a) A l anehit (C2H3O)n. Cng thc phn t ca A l: C4H6O2. (b) A l axit cacboxylic (C3H4O3)n. Cng thc phn t ca A l C6H8O6. (c) A l amino axit c cng thc (C5H9O4N)n. Cng thc phn t ca A l: C5H9O4N. (d) A l axit cacboxylic mch khng phn nhnh, cng thc (CHO) n. Cng thc phn t ca A l: C4H4O4. (e) A l amin bc mt, cng thc (CH4N)n. A c cng thc phn t l C2H8N2. (f) Axit no a chc c cng thc n gin l (C3H4O3)n. Cng thc phn t ph hp vi cng thc ny l C3H5(COOH)3. S pht biu ng l: A. 5 B. 4 C. 6 D. 2 Cu 40: Cho cc pht biu sau: (a) Khi cho ozon tc dng ln giy c tm dung dch KI v tinh bt thy xut hin mu xanh. Hin tng ny l do s oxi ha kali. (b) nhit thng, nit phn ng c vi Li, khng phn ng vi Pb, F 2, Cl2. (c) Ozon v hiro peoxit c nhng tnh cht ha hc ging nhau l u c tnh oxi ha. (d) iu ch Fe trong cng nghip nn dng phng php kh Fe2O3 bng Al. (e) Trong hin tng n mn in ha, xy ra phn ng oxi ha kh. (f) Tam hp propin trong iu kin thch hp s to ra iso propyl benzen. (g) Nguyn t phi kim c huynh hng c trng l nhn electron v to thnh ion m. (h) Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l Cu(OH)2 trong mi trng kim. (i) Ion Cr3+ c cu hnh electron l [Ar]3d5 S pht biu ng l: A. 8 B. 7 C. 6 D. 5 II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh chun (10 cu, t cu 41 n 50)

Cu 41: Nung m gam hn hp A gm Fe v Cu (trong Fe chim 36,84% v khi lng) trong oxi thu c 36,8 gam hn hp cht rn Y. Ha tan hon ton Y trong V ml dung dch HNO3 2M ly d 25% so vi lng phn ng, thu c 0,2 mol hn hp NO, NO 2 c t khi so vi H2 bng 19. Gi tr ca m v V ln lt l: A. 30,4 v 875 B. 30,4 v 375 C. 29,5 v 875 D. 29,5 v 375 Cu 42: Ch dng dung dch HCl c th phn bit c ti a bao nhiu l trong s 10 l mt nhn cha: dung dch Na[Al(OH)4], dung dch KCl, dung dch K2CO3, dung dch BaCl2, dung dch K2SO3, dung dch K2S, dung dch K2SO4, C6H5NH2 (anilin), dung dch C6H5ONa (natri phenolat) v benzen ?. A. 7 B. 10 C. 8 D. 6
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Cu 43: Thy phn hn hp gm m gam saccaroz v n gam mantoz mt thi gian thu c dung dch X (hiu xut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th khi lng Ag thu c l T gam. Gi tr ca T l (bit s mol saccaroz ln hn s mol mantoz), tnh T theo m, n 3,5m 3n 6m 7 n A. T .108 gam B. T .108 gam 342 342 7 m 6n 3m 3,5n C. T .108 gam D. T .108 gam 342 342 Cu 44: Cho phng trnh phn ng ha hc sau: aFexOy + bHNO3 cFe(NO3)3 + dNnOm + eH2O Nu b = 2(9xn 3m yn) th a bng: A. (7n 3m) B. (7n + 3m) C. (5n + 2m) D. (5n 2m) Cu 45: T etilen v benzen, cht v c v iu kin phn ng c . Tng s phn ng t nht c th iu ch c polibutaien, polistiren, poli (butaien - stiren), poli (vinyl clorua) l: A. 11 B. 12 C. 13 D. 10 Cu 46: Cho qu tm vo ln lt cc dung dch: CH3COOK, FeCl3, NH4NO3, K2S, Zn(NO3)2, Na2CO3. S dung dch lm i mu giy qu l: A. 3 B. 6 C. 4 D. 5 Cu 47: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau c xc tc, s cp cht c phn ng xy ra l: A. 11 B. 8 C. 9 D. 10 Cu 48: Cho mt lung kh CO i qua ng ng 0,01 mol FeO v 0,03 mol Fe 2O3 (hn hp A) t nng. Sau khi kt thc th nghim thu c 4,784 gam cht rn B gm 4 cht. Ha tan cht rn B bng dung dch HCl d thy thot ra 0,6272 lt H2 (iu kin tiu chun). Tnh s mol st t trong hn hp B. Bit rng trong B s mol st t bng 1/3 tng s mol st (II) oxit v st (III) oxit. A. 0,006 B. 0,008 C. 0,01 D. 0,012 Cu 49: C bao nhiu cht hu c C4H12N2O4 l ng phn cu to ca nhau, khi tc dng vi NaOH u gii phng c ng thi 2 kh khc nhau, cng c kh nng lm xanh giy qu m ?. A. 2 B. 3 C. 4 D. 5 Cu 50: Trong th nghim chun dung dch HCl bng dung dch chun NaOH, vi cht ch th mu l phenolphtalein (th nghim 1) v th nghim chun dung dch NaOH bng dung dch chun HCl, cng vi cht ch th mu l phenolphthalein (th nghim 2) th: A. im cui th nghim 1 n trc im tng ng. B. im cui th nghim 2 n trc im tng ng. C. im cui c 2 th nghim u n sau im tng ng. D. pH ca im tng ng 2 th nghim l khc nhau. B. Theo chng trnh nng cao (10 cu, t cu 51 n 60) Cu 51: Nung m gam hn hp A gm KMnO4 v KClO3 thu c cht rn A v oxi, lc KClO3 b thy phn hon ton, cn KMnO4 b phn hy khng hon ton. Trong A1 c 0,894 gam KCl chim 8,132% khi lng. Trn lng oxi thu c trn vi khng kh theo t l th tch l 1/3 (khng kh cha th tch 0,2 l oxi, cn li 0,8 l nit) trong mt bnh kn thu c hn hp A2. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon thu c hn hp A3 gm ba kh trong c CO2 chim 22,92% th tch. Gi tr ca m l: A. 12,5 gam hoc 74,5 gam B. 11,65 gam hoc 74,5 gam C. 12,5 gam hoc 11,65 gam D. 11,65 gam hoc 12,5 gam Cu 52: Hp cht hu c X cha mt loi nhm chc c cng thc phn t C8H14O4. Khi thy phn X trong dung dch NaOH thu c mt mui v hn hp hai ancol A, B. Phn t ancol B c s nguyn t C gp i phn t ancol A. Khi un nng vi H2SO4 c iu kin thch hp, A cho mt olefin v B cho ba olefin ng phn. Cng thc thu gn ca X l: A. CH3OOCCH2CH2COOCH2CH3 B. C2H5OCO-COOCH2CH2CH3 C. HOCOCH2CH2CH2CH2COOCH3 D. C2H5OCO-COOCH2CH(CH3)2 Trang 7/8 M thi 2012 00A

Cu 53: C bao nhiu phn ng di y to ra n cht. (a) Nhit phn kali nitrat. (b) Nhit phn amoni icromat. (c) Nhit phn amoni nitrit. (d) Nhit phn kali pemanganat. (e) Nhit phn kali clorat (xc tc MnO2). (h) Nhit phn natri hirocacbonat. (g) Nhit phn amoni clorua. (i) Nhit phn km hiroxit. (j) Cho SiO2 tc dng vi axit HF. (m) Cho kh SO2 tc dng vi kh H2S. (n) Cho kh NH3 tc dng vi CuO un nng. (l) Cho CaOCl2 tc dng vi dung dch HCl c. (o) Cho Si n cht tc dng vi dung dch NaOH. (x) Cho kh O3 tc dng vi Ag. (y) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. A. 10 B. 9 C. 11 D. 12 Cu 54: Hn hp A gm KClO3, Ca(ClO2)2, Ca(ClO3)2, CaCl2 v KCl nng 83,68 gam. Nhit phn hon ton A ta thu c cht rn B gm CaCl2, KCl v mt th tch oxi va oxi ha SO2 thnh SO3 iu ch 191,1 gam dung dch H2SO4 80%. Cho cht rn B tc dng vi 360 ml dung dch K2CO3 0,5M (va ) thu c kt ta C v dung dch D. Lng KCl trong dung dch D nhiu gp 13,2/1,8 ln lng KCl c trong A. Tnh s mol kt ta ca C l: A. 16 gam B. 17 gam C. 0,18 mol D. 19 gam Cu 55: X l hn hp hai este n chc (to bi cng mt axit cacboxylic vi hai ancol ng ng lin tip). Chia mt lng X lm hai phn bng nhau. - t chy hon ton phn 1 cn va 10,08 lt O 2 (iu kin tiu chun). Sn phm chy hp th ht vo nc vi trong d c 38 gam kt ta. - X phng ha hon ton phn 2 cn va 60ml dung dch NaOH 1M. Cng thc phn t 2 este trn l: A. C4H6O2 v C5H8O2 C. C6H8O2 v C7H10O2 C. C5H6O2 v C6H8O2 D. C6H10O2 v C7H12O2 Cu 56: t chy hon ton 11,3 gam cht hu c A c hn hp X ch gm CO 2 hi nc v kh HCl. Dn ton b X qua bnh ng dung dch AgNO 3 d thy khi lng bnh tng 10,9 gam v xut hin 28,7 gam kt ta. Kh thot ra khi bnh dn tip qua bnh nc vi trong d thy xut hin 30 gam kt ta. Tng s ng phn cu to ca A l: A. 4 B. 5 C. 6 D. 7 Cu 57: Cho bt Fe vo dung dch NaNO3 v H2SO4. n phn ng hon thu c dung dch A, hn hp kh X gm NO v H2 c v cht rn khng tan. Bit dung dch A khng cha mui amoni. Trong dung dch A cha cc mui: A. FeSO4, Fe(NO3)2, Na2SO4, NaNO3 B. FeSO4, Fe2(SO4)3, NaNO3, Na2SO4 C. FeSO4, Na2SO4 D. FeSO4, Fe(NO3)2, Na2SO4 Cu 58: Ha tan hon ton m gam hn hp ba kim loi cha r ha tr bng dung dch HNO 3 thu c V lt hn hp kh A (iu kin tiu chun) gm NO 2 v NO (khng sinh ra mui NH4NO3). T khi hi ca A so vi H2 bng 18,2. Tng s gam mui khan to thnh theo m v V l: A. m + 6,0893V B. m + 3,2147V C. m + 2,3147V D. m + 6,1875V Cu 59: Cho s chuyn ha sau: 1/LiAlH4; 2/H+ PBr3 Mg, ete khan 1/CO2; 2/H+ CH3(CH2)14COOH X Y Z T Cht T c th l: A. CH3(CH2)14CH2OH C. CH3(CH2)14CH2COOH C. CH3(CH2)15CH2OH D. CH3(CH2)15COOH Cu 60: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l: A. 1 B. 3 C. 2 D. 4

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