KHO ST CHT LNG NM 2010, Mn: HA HC Thi gian lm bi: 90 pht, khng k thi gian pht M thi 132

32 H, tn th sinh:.......................................................................... S bo danh:............................................................................... Cho khi lng nguyn t ca cc nguyn t: H = 1; He = 4; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Ag = 108; Zn = 65; Ni = 59; Br = 80; Ba = 137; Pb = 207; P = 31; I = 127 v Cl = 35,5 I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho hn hp A gm Al, Fe vo dung dch B c cha Cu(NO3)2 v AgNO3. Sau khi phn ng xy ra hon ton thu c dung dch C; Cho dung dch NaOH d vo C c kt ta D gm hai hiroxit kim loi. Trong dung dch C c cha A. Al(NO3)3 , Fe(NO3)2 v Cu(NO3)2 B. Al(NO3)3 v Fe(NO3)2 C. Al(NO3)3 v Fe(NO3)3 D. Al(NO3)3 v Fe(NO3)3 v Cu(NO3)2 Cu 2: Cho cc cht: CH3CH2OH (1), H2O (2), CH3COOH (3), C6H5OH (4), HCl (5). Th t tng dn tnh linh ng ca nguyn t hiro trong cc cht l A. (4), (1), (2), (5), (3) B. (1), (2), (4), (3), (5) C. (1), (2), (3), (4), (5) D. (2), (1), (4), (5), (3) Cu 3: Cho cc cht sau: FeO, Fe2O3, HI, SO2, SiO2, CrCl2, HNO3, Br2. S cht va c tnh oxi ha va c tnh kh l A. 3 B. 5 C. 4 D. 6 Cu 4: Kh hon ton 4,8 gam oxit ca mt kim loi nhit cao, cn dng 2,016 lt kh hiro ( ktc). Cng thc phn t ca oxit dng l A. FeO B. Fe3O4 C. CuO D. Fe2O3 Cu 5: Hn hp X gm mt axit no, n chc, mch h v 2 este no, n chc mch h. phn ng ht vi a gam X cn 400ml dung dch NaOH 0,75M. Cn t chy hon ton a gam X th thu c 20,16 lt CO2 (ktc). Gi tr ca a l A. 14,8 gam B. 22,2 gam C. 46,2 gam D. 34,2 gam Cu 6: Trong bnh kn dung tch 5 lt khng i cha 12,8 gam SO 2 v 3,2 gam oxi (c mt t xc tc V2O5 th tch khng ng k) nung nng. Sau khi tin hnh phn ng oxi ha SO 2 t trng thi cn bng th phn trm th tch oxi cn li trong bnh chim 20%. Hng s cn bng ca phn ng: 2SO2 + O2 = 2SO3 ti iu kin trn l A. 50 B. 20 C. 100 D. 10 Cu 7: Ln men 45 gam ng glucoz thy c 4,48 lt CO2 (ktc) bay ra v cn hn hp cht hu c X gm C2H5OH, CH3COOH v glucoz d. t chy hon ton X th s mol CO2 thu c l A. 1,3 mol B. 1,15 mol C. 1,5 mol D. 1,2 mol Cu 8: Khi trng ngng 13,1 gam axit -amino caproic vi hiu sut 80%, ngoi amino axit d ngi ta cn thu c m gam polime v 1,44 gam nc. Gi tr ca m lA. 11,02 gam B. 8,43 gam C. 10,41 gam D. 9,04 gam 2+ 2+ 2+ Cu 9: Dung dch A c cha 5 ion: Ba ; Ca ; Mg ; 0,3 mol NO3 v 0,5 mol Cl-. kt ta ht cc ion c trong dung dch A cn dng ti thiu V ml dung dch cha hn hp K2CO3 1M v Na2CO3 1,5M. Gi tr ca V l A. 600 ml B. 320 ml C. 300 ml D. 160 ml Cu 10: Cho 4,291 gam hn hp A gm Fe3O4 , Al2O3 v CuO tc dng va vi 179 ml dung dch HCl 1M. C cn dung dch thu c khi lng mui khan lA. 9,1415 gam B. 9,2135 gam C. 9,5125 gam D. 9,3545 gam Cu 11: S ng phn este, mch khng phn nhnh ng vi cng thc phn t C 6H10O4 m khi thu phn cho mt axit v mt ancol l A. 2 B. 3 C. 4 D. 5 Cu 12: Ha cht phn bit 3 cc cha: nc nguyn cht, nc cng tm thi, nc cng vnh cu l A. Na2CO3 B. HCl v Na2CO3 C. Na2CO3 v Na3PO4 D. Na3PO4 Cu 13: un nng a gam mt hp cht hu c cha C; H; O mch khng phn nhnh vi dung dch cha 11,2 gam KOH n khi phn ng xy ra hon ton, thu c dung dch B, trung ho dung dch KOH d trong B cn dng 80 ml dung dch HCl 0,5M. Lm bay hi hn hp sau khi trung ho mt cch cn thn, ngi ta thu c 7,36 gam hn hp hai ancol n chc v 18,34 gam hn hp hai mui. Gi tr ca a lA. 14,86 gam B. 16,64 gam C. 13,04 gam D. 13,76 gam Cu 14: phn bit 2 dung dch AlCl3 v ZnSO4 c th dng bao nhiu dung dch trong s cc dung dch sau: dung dch NaOH, dung dch Ba(OH)2, dung dch NH3, dung dch BaCl2, dung dch Na2S A. 2 dung dch B. 3 dung dch C. 4 dung dch D. c 5 dung dch Cu 15: Pht biu no sau y ng A. Phn t peptit mch h c s lin kt peptit bao gi cng nhiu hn s gc -amino axit B. Phn t peptit mch h to bi n gc -amino axit c cha (n 1) lin kt peptit C. Cc peptit u c phn ng vi Cu(OH)2 to thnh phc cht c mu tm c trng D. Phn t tripeptit c ba lin kt peptit Cu 16: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h. Gi tr ca m l A. 22,10 gam B. 23,9 gam C. 20,3 gam D. 18,5 gam Trang 1/4 - M thi 132

Cu 17: Cho cc kim loi v ion sau: Cr, Fe2+, Mn, Mn2+, Fe3+. Nguyn t v ion c cng s electron c thn l A. Cr v Mn B. Mn2+, Cr, Fe3+ C. Mn, Mn2+ v Fe3+ D. Cr v Fe2+ Cu 18: in phn c mng ngn 200 gam dung dch X cha KCl v NaCl n khi t khi kh ant bt u gim th dng li. Trung ha dung dch sau in phn cn 200 ml dung dch H 2SO4 0,5M, c cn dung dch thu c 15,8 gam mui khan. Nng phn trm mi mui c trong dung dch X ln lt l A. 18,625% v 14,625% B. 7,5% v 5,85 % C. 3,725% v 2,925% D. 37,25% v 29,25% Cu 19: t chy hon ton 7,3 gam mt axit no, a chc mch h thu c 0,3 mol CO 2 v 0,25 mol H2O. Cho 0,2 mol axit trn tc dng vi ancol etylic d c xc tc H2SO4 c. Tnh khi lng este thu c (gi s hiu sut phn ng t 100%). A. 40,4 gam B. 37,5 gam C. 28,6 gam D. 34,7 gam Cu 20: Trung ho hon ton 16,6 gam hn hp X gm axit axetic v axit fomic bng dung dch NaOH, sau phn ng thu c 23,2 gam hn hp Y gm hai mui. Phn trm theo khi lng ca axit axetic trong X v ca natri fomiat trong Y ln lt l A. 72,3% v 58,6% B. 72,3% v 29,3% C. 27,7% v 58,6% D. 27,7% v 29,3% Cu 21: Cho 0,1 mol cht X (CTPT C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh qu m v dung dchY (ch cha cc cht v c). C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l A. 8,5 gam B. 21,8 gam C. 5,7 gam D. 12,5 gam Cu 22: Hn hp X gm hiro v mt hirocacbon. Nung nng 14,56 lt hn hp X (ktc), c Ni xc tc n khi phn ng hon ton thu c hn hp Y c khi lng 10,8 gam. Bit t khi ca Y so vi metan l 2,7 v Y c kh nng lm mt mu dung dch brom. Cng thc phn t ca hirocacbon l A. C3H6 B. C4H6 C. C3H4 D. C4H8 Cu 23: Cho s d sau:
B A
+ NaOH

Cao su Buna

Poli metyl acrylat

Cht A trong s trn l A. CH2=CHCOOC2H5 B. CH2=C(CH3)COOCH3 C. CH2=CHCOOC4H9 D. CH2=C(CH3)COOC2H5 Cu 24: Mt loi than dng cho mt nh my nhit in c cha 2% lu hunh. Nu nh my t ht 100 tn than mt ngy m th lng kh SO2 do nh my thi ra kh quyn trong mt nm (c 365 ngy) l A. 1250 tn B. 1420 tn C. 1530 tn D. 1460 tn Cu 25: Cho Ba (d) ln lt vo cc dung dch sau: NaHCO 3, CuSO4, (NH4)2SO4, Al2(SO4)3, MgCl2. Tng s cc cht kt ta thu c l A. 6 B. 5 C. 7 D. 4 Cu 26: C bao nhiu cht trong cc cht sau lm qu tm chuyn mu xanh: phenol, natri phenolat, alanin, anilin, imetyl amin, phenylamoni clorua, natri axetat.A. 6 B. 3 C. 5 D. 4 Cu 27: Trong cc tn gi di y, tn no khng ph hp vi cht c cng thc (CH3)2CHCH(NH2)COOH A. axit -amino isovaleric B. axit 2-amino-3-metyl butanoic C. Valin D. axit 2-metyl-3-amino butanoic Cu 28: Ha tan ht 17,84 gam hn hp Fe, Cu, Ag bng 203,4 ml dung dch HNO3 20% (d=1,115 g/ml) ti thiu va . Sau phn ng thu c 4,032 lt kh NO duy nht (ktc) v dung dch X. C cn dung dch X thu c s gam mui khan l A. 60,27 gam B. 51,32 gam C. 54,28 gam D. 45,64 gam Cu 29: Ho tan ht 7,8 gam hn hp bt Mg, Al bng 400 ml dung dch hn hp HCl 0,5M v H2SO4 0,75M thu c dung dch X v 8,96 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l A. 35,9 gam B. 43,7 gam C. 100,5 gam D. 38,5 gam Cu 30: Ha tan hn hp Fe v FeCO3 trong dung dch HNO3 thu c hn hp 2 kh c t khi so vi H 2 l 22,5. Hai kh l A. CO2 v NO2 B. CO2 v N2O C. NO2 v N2O D. NO v NO2 Cu 31: Cho cc ng phn anken mch nhnh ca C5H10 hp nc (xc tc H+). S sn phm hu c thu c l A. 6 B. 7 C. 5 D. 4 Cu 32: Dy cc ion sp xp theo chiu tnh oxi ha gim dn l A. Fe3+, Ag+, Cu2+, Fe2+, Al3+, Mg2+ B. Fe3+, Ag+, Fe2+, Cu2+, Al3+, Mg2+ + 3+ 2+ 2+ 3+ 2+ C. Ag , Fe , Cu , Fe , Al , Mg D. Ag+, Cu2+, Fe2+, Fe3+, Al3+, Mg2+ Cu 33: t chy hon ton 0,08 mol hn hp 2 ancol bc mt, sau phn ng thu c 6,16 gam CO2. Nu oxi ho 0,08 mol hn hp 2 ancol trn bng oxi, xc tc Cu, un nng (gi s hiu sut 100%). Sau cho sn phm tc dng vi dung dch AgNO3/NH3 d, thu c m gam Ag. Gi tr ca m l A. m = 34,56 gam B. 17,28 gam < m < 34,56 gam C. m = 17,28 gam D. 21,6 gam m < 34,56 gam Cu 34: So snh khi lng Cu tham gia phn ng trong hai trng hp sau: - Ha tan m1 gam Cu cn va 200 ml dung dch hn hp HNO3 1,2M v H2SO4 0,3M - Ha tan m2 gam Cu cn va 200 ml dung dch hn hp NaNO3 1,2M v H2SO4 0,8M. Trang 2/4 - M thi 132

Bit rng c 2 trng hp sn phm kh u l kh NO duy nht. T l m1 : m2 c gi tr bng A. m1 : m2 = 9 : 8 B. m1 : m2 = 8 : 9 C. m1 : m2 = 1 : 1 D. m1 : m2 = 10 : 9 Cu 35: Thy phn hon ton mt cht bo bng dung dch NaOH, sau phn ng thu c 2,78 gam C 15H31COONa; m2 gam C17H31COONa v m3 gam C17H35COONa. Gi tr ca m2 v m3 ln lt l A. 3,02 gam v 3,05 gam B. 6,04 gam v 6,12 gam C. 3,02 gam v 3,06 gam D. 3,05 gam v 3,09 gam Cu 36: Ha tan 19,5 gam hn hp gm Na2O v Al2O3 trong nc thu c 500 ml dung dch A trong sut. Thm dn dung dch HCl 1M vo dung dch A n khi xut hin kt ta th dng li thy th tch dung dch HCl cn dng l 100 ml. Phn trm s mol mi cht trong A ln lt lA. 45% v 55% B. 25% v 75% C. 30% v 70% D. 60 % v 40% Cu 37: Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H +) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,60 lt B. C4H8, C5H10, 5,6 lt C. C2H4, C3H6, 4,48 lt D. C3H6, C4H8, 4,48 lt Cu 38: Trong s cc dung dch sau: K2CO3, KHCO3, Al2(SO4)3, FeCl3, Na2S, C6H5ONa, K2HPO3 s dung dch c pH>7 l A. 3 B. 5 C. 2 D. 4 Cu 39: iu khng nh no sau y l ng A. Pha long dung dch axit yu th hng s Ka khng i B. Pha long dung dch axit yu th in li khng i C. Pha long dung dch axit yu th hng s Ka gim D. Pha long dung dch axit yu th pH ca dung dch khng i Cu 40: Cho 11,2 lt hn hp X gm axetilen v anehit axetic ( ktc) qua dung dch AgNO 3/NH3 d. Sau khi phn ng hon ton thu c 112,8 gam kt ta. Dn lng hn hp X nh trn qua dung dch nc brom d, s gam brom tham gia phn ng l (gi s lng axetilen phn ng vi nc l khng ng k) A. 64 gam B. 112 gam C. 26,6 gam D. 90,6 gam II. PHN T CHN [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh chun (10 cu, t cu 41 n cu 50) Cu 41: phn bit phenol, anilin, benzen, stiren ngi ta s dng cc thuc th l A. qu tm, dung dch brom B. dung dch brom, qu tm C. dung dch NaOH, dung dch brom D. dung dch HCl, qu tm Cu 42: Dung dch nc ca cht A lm xanh qu tm, cn dung dch nc ca cht B khng lm i mu qu tm. Trn ln dung dch ca hai cht li th xut hin kt ta. A, B ln lt l A. Na2CO3 ; FeCl3 B. NaOH ; K2SO4 C. KOH; FeCl3 D. K2CO3; Ba(NO3)2 Cu 43: Hn hp kh X gm 0,1mol vinylaxetilen v 0,4 mol H2. Nung nng hn hp X (c xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi hiro bng 10. Nu dn hn hp Y qua dung dch Brom th khi lng Brom tham gia phn ng l A. 24 gam B. 0 gam (khng phn ng) C. 8 gam D. 16 gam Cu 44: Chia 23,6 gam hn hp gm HCHO v cht hu c X l ng ng ca HCHO thnh 2 phn bng nhau. Phn 1, cho tc dng vi H2 d (t0C, xc tc), sau phn ng thu c 12,4 gam hn hp ancol. Phn 2, cho tc dng vi dung dch AgNO3/NH3 d thu c108 gam bc. Cng thc phn t ca X l A. CH3CHO B. (CHO)2 C. C2H5CHO D. C2H3CHO Cu 45: Ha tan 20 gam mui sunfat ngm nc ca kim loi M (cha r ha tr) vo nc ri em in phn hon ton, thy catot tch ra 5,12 gam kim loi, anot thot ra 0,896 lit kh ( ktc). Cng thc ca mui ngm nc l A. Al2(SO4)3 B. CuSO4.5H2O C. CuSO4.3H2O D. FeSO4.7H2O Cu 46: Cn bao nhiu tn qung hematit cha 5% tp cht sn xut 1 tn gang c cha 95% Fe (Bit rng hiu sut ca qu trnh luyn gang l 90%) A. 1,537 tn B. 1,457 tn C. 1,587 tn D. 1,623 tn Cu 47: Nh t t 300 ml dung dch HCl 1M vo 100 ml dung dch cha NaHCO 3 2,5M v Na2CO3 1M. Th tch kh (ktc) thu c sau phn ng l A. 6,72 lt B. 5,6 lt C. 4,48 lt D. 2,24 lt Cu 48: Cho V lt dung dch A cha ng thi FeCl3 1M v Fe2(SO4)3 0,5M tc dng vi dung dch Na2CO3 d, phn ng kt thc thy khi lng dung dch sau phn ng gim 69,2 gam so vi tng khi lng ca cc dung dch ban u. Gi tr ca V l A. 0,2 lt. B. 0,24 lt. C. 0,237 lt. D. 0,336 lt. Cu 49: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc l axit sunfuric c nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng l 90%). Gi tr ca m l A. 21 kg B. 30 kg C. 42 kg D. 10 kg

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Cu 50: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1, cho tc dng vi Na d, thu c 6,272 lt H 2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120ml. Hiu sut phn ng oxi ho ancol etylic l A. 42,86% B. 66,7% C. 85,7% D. 75% B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60) Cu 51: Trong cu mui ca pin in ha Zn-Cu c s di chuyn ca A. Cc ion B. Cc electron C. Cc nguyn t Zn D. Cc nguyn t Cu Cu 52: Cho sut in ng ca cc pin in ha: E0(Fe-Cu) = 0,78V E0(Cu-Ag) = 0,46V . Sut in ng ca pin Fe - Ag l A. 1,24V B. 0,34V C. 0,8V D. 0,44V Cu 53: Hn hp X cha glixerol v mt ancol no, n chc mch h Y. Cho 20,3 gam X tc dng vi Na d thu c 5,04 lt H2 (ktc). Mt khc 8,12 gam X ho tan va ht 1,96 gam Cu(OH)2. Cng thc phn t ca Y v thnh phn phn trm khi lng ca Y trong hn hp l A. C3H8O v 77,34% B. C5H12O v 65,94% C. C4H10O v 54,68% D. C2H6O v 81,87% Cu 54: Nguyn liu iu ch axeton trong cng nghip l A. isopropylbenzen B. propan 2 ol C. propan 1 ol D. propin Cu 55: Cho a gam hn hp bt gm Ni v Cu vo dung dch AgNO 3 (d). Sau khi kt thc phn ng thu c 54 gam cht rn. Mt khc cng cho a gam hn hp 2 kim loi trn vo dung dch CuSO 4 (d), sau khi kt thc phn ng thu c cht rn c khi lng (a + 0,5) gam. Gi tr ca a l A. 15,5 gam B. 42,5 gam C. 33,7 gam D. 53,5 gam Cu 56: Nung 39,3 gam Na2Cr2O7, sau mt thi gian thu c 34,5 gam cht rn. Phn trm ca Na 2Cr2O7 b nhit phn l A. 33,33% B. 66,67% C. 55% D. 45% Cu 57: Cp ancol v amin c cng bc l A. C6H5NHCH3 v C6H5CH(OH)CH3 B. (CH3)2CHOH v (CH3)2CH-NH2 C. (C6H5)2NH v C6H5CH2OH D. (CH3)3COH v (CH3)3CNH2 Cu 58: Thuc gim au Paracetamol c cha lin kt peptit trong phn t v c to thnh bng cch cho axit axetic tc dng vi p- amino phenol. Cng thc ca thuc l

CH3 - C - N A.

CH3 - C - O OH
OH
B.

O H

NH2

O
CH3 - C - N O H

CH3 - C - N O H

OH C. D. Cu 59: Trong cc cht sau: C2H5OH, CH3CHO, CH3COONa, HCOOC2H5, CH3OH. S cht t iu ch trc tip c CH3COOH (bng mt phn ng) l A. 5 B. 4 C. 3 D. 6 Cu 60: Cho cc dung dch sau: NaOH, BaCl2, KHSO4, Al2(SO4)3, (NH4)2SO4. phn bit cc dung dch trn, dng thuc th no trong s cc thuc th sau th s cn tin hnh t th nghim nht A. H2SO4 B. KOH C. qu tm D. Ba(OH)2
--------------------------------------------------------- HT ----------

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