M thi: 017

K THI KSCL I HC NM 2012 LN TH 1

THI MN: HA HC-KHI A
Thi gian lm bi: 90 pht,khng k thi gian giao
thi gm: 7 trang

H, tn th sinh:.......................................................................
S bo danh:............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca
= 40; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba = 137;Mn = 55.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Khi in phn mt dung dch mui,gi tr pH khu vc gn mt in cc gim
xung.Dung dch mui em in phn l :
A. KCl
B. CuSO4
C. K2SO4.
D. CuCl2
Cu 2: Trong s cc cht sau: HCOOH, CH3CHO, CH3CH2OH, CH3COOH cht va c
kh nng tham gia phn ng trng bc, va c kh nng tc dng vi Na gii phng H2 l:
A. CH3COOH.
B. CH3CHO.
C. HCOOH.
D. CH3CH2OH.
Cu 3: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy
hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu
c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l :
A. C4H8.
B. C3H6.
C. C3H8.
D. C3H4.
Cu 4: Thm t t tng git H2SO4 vo dung dch Ba(OH)2 n d th dn in ca h
s bin i nh sau:
A. lc u tng, sau gim.
B. gim dn.
C. lc u gim, sau tng.
D. tng dn.
Cu 5: T anehit no n chc A c th chuyn trc tip thnh ancol B v axit D tng
ng iu ch este E t B v D. Hy xc nh t s d = ME / MA.
A. 2 /1
B. 2/3
C. 3/2
D. 1/2
Cu 6: Trong cc loi phn bn sau: NH4Cl, (NH2)2CO, (NH4)2SO4, NH4NO3; loi c hm
lng m cao nht l
A. NH4NO3.
B. NH4Cl.
C. (NH2)2CO.
D. (NH4)2SO4.
Cu 7: Mt loi thu tinh cha 13,0% Na2O; 11,7% CaO v 75,3% SiO2 v khi lng.
Thnh phn ca loi thu tinh ny biu din di dng cc oxit l
A. Na2O.6CaO.SiO2.
B. Na2O.CaO.6SiO2.
C. 2Na2O.CaO.6SiO2.
D. 2Na2O.6CaO.SiO2.
Cu 8: Tch nc hn hp 2 ru thu c 2 anken. Ete ha hon ton hn hp 2 ru
trn th thu c 3 ete, trong c 1 ete l C5H12O. Ete c khi lng phn t ln nht thu
c l:
A. 74
B. 88
C. 102
D. 130
Cu 9: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 100 ml dung dch hn hp gm
NaOH 1,5 M v Ba(OH)2 1M, sinh ra m gam kt ta. Gi tr ca m l
A. 19,70.
B. 39,40.
C. 11,82.
D. 9,85.
Trang 1/7 - M thi 017

Cu 10: Cho 1,38 gam X c cng thc phn t C2H6O5N2 ( l mui ca -amino axit vi
HNO3 ) phn ng vi 150 ml dung dch NaOH 0,2 M . Sau phn ng c cn thu c m
gam rn Y. Gi tr ca m l:
A. 2,14
B. 2,22
C. 1,13
D. 1,01
Cu 11: Cho cc cht lng sau:axit axetic,glixerol,triolein. phn bit cc cht lng
trn,c th ch cn dng:
A. nc v qu tm
B. nc v dd NaOH
C. dd NaOH
D. nc Br2
Cu 12: Chia dung dch X gm CuSO4 v Al(NO3)3 thnh 2 phn bng nhau. Phn 1 cho
tc dng vi dung dch BaCl2 d thu c 6,99 gam kt ta. Phn 2 cho tc dng vi dung
dch NaOH d, ri ly kt ta nung n khi lng khng i thu c m gam cht rn.
Gi tr ca m l
A. 12,6.
B. 4,4.
C. 3,2.
D. 2,4.
Cu 13: Hp cht hu c X cha cc nguyn t(C,H,Cl) c %Cl=84,53% v khi lng.X
tc dng va vi dd NaOH thu c cht hu c Y.Khi lng phn t Y c gi tr
A. 60
B. 98
C. 44
D. 82
Cu 14: thu c CO2 tinh khit t hn hp CO2 b ln kh HCl v hi nc ta cho
hn hp qua ln lt cc bnh cha lng d
A. dd NaHSO4, dd H2SO4 c.
B. dd H2SO4 c, dd Na2CO3.
C. dd Na2CO3, dd H2SO4 c.
D. dd H2SO4 c, NaHCO3.
Br (1:1)
N aO H
Cu 15: Cho s sau: C3H6 X Y Cu O HCO-CH2-CHO
2

CTCT ca X l:
A. CH2Br-CH=CH2
B. CH3CH2CH2OH
C. BrCH2CH2CH2Br
D. CH3CH(Br)CH2Br
Cu 16: Chn pht biu ng v O2 v O3?
A. O2 v O3 c s proton v ntron trong phn t nh nhau.
B. O2 v O3 l cc dng th hnh ca nguyn t oxi.
C. O2 v O3 c tnh oxi ho manh nh nhau.
D. C O2 v O3 u phn ng c vi cc cht Ag, KI, PbS nhit thng.
Cu 17: Cho lung kh CO i qua ng s ng m(g) Fe2O3 nhit cao mt thi gian
ngi ta thu c 6,72(g) hn hp 4 cht rn khc nhau.em ha tan hn hp ny vo
dung dch HNO3 d to thnh 0,672(l) NO duy nht(ktc).Gi tr ca m l:
A. 6,80(g)
B. 6,72(g)
C. 8,80(g)
D. 7,44(g)
Cu 18: Cho V lt Cl2 (ktc) tc dng vi dd NaOH long, ngui d thu c m1 gam
tng khi lng 2 mui. Cho 2V lt kh Cl2 (ktc) tc dng vi dd NaOH c, nng d thu
c m2 gam tng khi lng 2 mui. T l m1: m2 bng:
A. 1 : 1.
B. 1 : 1,5.
C. 2 : 1.
D. 1 : 2.
Cu 19: Cho bit s hiu nguyn t ca cc nguyn t: ZH = 1, ZB = 5, ZC = 6, ZN = 7, ZO
= 8, ZAl =13, ZP = 15, ZS = 16. Nhm no sau y cha ton cc cht khng tun theo qui
tc bt t?
A. BH3, NO2, PCl5.
B. CO2 , C2H6, HNO3.
C. CH4, CO2, Al2S3.
D. CH4, H2O2, CS2.

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Cu 20: Cho 0,05 mol cht hu c X tc dng hon ton vi dd Br2,thu c cht hu c
Y(cha 3 nguyn t).Khi lng dd Br2 tng ln 2,1 gam.Thy phn cht Y c cht Z
khng c kh nng ha tan Cu(OH)2.Cht X l:
A. axit fomic
B. ancol etylic
C. propen
D. xiclo propan
Cu 21: Cho a (mol) hp cht hu c X c cng thc phn t C7H8O2 tc dng vi natri
d thu c a (mol) kh H2(ktc). Mt khc, a (mol)X ni trn tc dng va vi a (mol)
Ba(OH)2. Trong phn t X c th cha:
A. 1 nhm OCH2OH lin kt vi nhn thm.
B. 2 nhm OH lin kt trc tip vi nhn thm.
C. 1 nhm cacboxyl COOH lin kt vi nhn thm.
D. 1 nhm CH2OH v 1 nhm OH lin kt vi nhn thm.
Cu 22: Cho 14,2 gam P2O5 vo 100 ml dung dch cha NaOH 1M v KOH 2M thu c
dung dch X. Tng khi lng mui tan c mt trong X l:
A. 28,6 gam
B. 27,2 gam
C. 29,4 gam
D. 29,1 gam
Cu 23: t chy hon ton a gam este X to bi ancol no,n chc,mch h v axit
khng no(c mt lin kt i),n chc,mch h thu c 8,96 lt CO2 (kc) v 5,4 gam
H2O.Gi tr ca a l:
A. 5,6 gam
B. 5,4 gam
C. 8,6 gam
D. 8,8 gam
Cu 24: Np 2 kh N2 v H2 vo bnh kn thc hin phn ng: N2 + 3H2
2NH3. Sau
mt thi gian, nng cc cht trong bnh nh sau:[N2] = 2M; [H2] = 3M; [NH3] = 2M.
Nng mol/l ca N2 v H2 ban u ln lt l
A. 4 v 8.
B. 2 v 3.
C. 2 v 4.
D. 3 v 6.
Cu 25: Trong cng nghip, andehit fomic c iu ch trc tip t
A. ru metylic
B. ru etylic
C. metyl axetat
D. axit fomic
Cu 26: Cho 5,9 gam hirocacbon thm A ( c vng benzen ) bc hi trong bnh kn dung
tch 5,6 lt ti nhit 136,50C th p sut trong bnh lc ny l 0,3 atm.S ng phn cu
to tha mn A l:
A. 6
B. 12
C. 8
D. 10
Cu 27: Xt cc loi hp cht hu c, mch h sau : Ru n chc no ( X), anehit n
chc no (Y), ru n chc khng no 1 i i (Z); andehit n chc, khng no 1 ni i
(T). ng vi cng thc tng qut CnH2nO ch c 2 cht sau :
A. X, T
B. Z, T
C. X, Y
D. Y, Z
Cu 28: X phng ha 2,76 gam mt este X bng dung dch NaOH va ,thu c 4,44
gam hn hp 2 mui ca Na.Nung nng 2 mui ny trong O2 d,sau khi phn ng hon
ton,thu c 3,18 gam Na2CO3;2,464 lt kh CO2 (kc) v 0,9 gam nc.Cng thc n
gin cng l CTPT ca X.Vy CTCT thu gn ca X l:
A. C6H5COOCH3
B. HCOOC6H5
C. CH3COOC6H5
D. HCOOC6H4OH
Cu 29: Dn t t n d kh H2S qua dung dch X cha NaCl, NH4Cl, CuCl2 v FeCl3
thu c kt ta Y gm
A. CuS v FeS.
B. CuS.
C. CuS v S.
D. Fe2S3 v CuS.
Cu 30: S nguyn t m nguyn t c tng s 4 electron trn phn lp s l:
A. 2.
B. 7.
C. 1.
D. 6.

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Cu 31: t chy hon ton m gam mt amin X bng mt lng khng kh va thu
c 17,6g CO2,12,6 g H2O v 69,44 lt kh N2 (KTC).Gi thit khng kh ch gm
(%VN2 =80 v %VO2=20).Gi tr m v s ng phn cu to ca amin X ln lt l:
A. 9 v 6
B. 6 v 9
C. 9 v 2
D. 8 v 1
Cu 32: Ho tan hon ton mt lng kim loi ho tr II bng dung dch HCl 14,6% va
c mt dung dch mui c nng 24,15%.Kim loi cho l:
A. Fe
B. Ba
C. Zn
D. Mg
Cu 33: Kh hon ton 4,06 gam mt oxit kim loi bng CO nhit cao thnh kim
loi. Dn ton b kh sinh ra vo bnh ng dung dch Ca(OH) 2 d thy to thnh 7 gam
kt ta.Nu ly kim loi sinh ra ha tan ht vo dung dch HCl d th thu c 1,176 lt
hiro.Vy lng mui kim loi thu c khi cho 34,8 gam oxit trn tc dng hon ton
vi dung dch HCl d l
A. 43,425 gam
B. 70,6875 gam
C. 67,80 gam
D. 61,38 gam
Cu 34: Hn hp X gm axit Y n chc v axit Z hai chc(Y,Z c cng s nguyn t
cacbon).Chia X thnh 2 phn bng nhau.
-P1: tc dng vi Na d sinh ra 4,48 lt kh H2(kc)
-P2: t chy hon ton to 26,4 gam CO2
CTCT thu gn v % khi lng ca Z trong hn hp X l:
A. HOOC-CH2-COOH :70,87%
B. HOOC-CH2-COOH:54,88%
C. HOOC-COOH :60,00%
D. HOOC-COOH : 42,86%
Cu 35: Nguyn t nguyn t R c tng s cc loi ht l 115. S ht mang in nhiu
hn s ht khng mang in l 25. S khi ca R l:
A. 70.
B. 90.
C. 80.
D. 75.
Cu 36: C th dng H2SO4 c lm kh tt c cc kh trong dy no sau y?
A. CO2, N2, SO2, O2.
B. CO2, N2, H2, O2.
C. CO2, H2S, N2, O2.
D. CO2, NH3, H2 , N2.
Cu 37: iu khng nh no sau y lun ng:
A. C mt kim loi duy nht nhit thng trng thi lng .
B. Bn knh nguyn t kim loi lun ln hn bn knh nguyn t phi kim.
C. Nguyn t kim loi no cng u c 1;2 hoc 3 electron lp ngoi cng .
D. Cc kim loi u phn nhm chnh ca bng h thng tun hon.
Cu 38: Thy phn peptit :
(CH2)2COOH
CH3
CH COOH
H2N CH2 C N CH C N
O H
O H

Sn phm no di y l khng th c ?
A. Ala
B. Ala-Glu
C. Gly-Ala
D. Glu-Gly
Cu 39: Cho cc mnh :
1) cc nguyn t kim loi c th tham gia phn ng oxi ho - kh cng nh phn
ng trao i.
2) cc kim loi khi tham gia phn ng ho hc lun ng vai tr l cht kh.
3) phn ng th(trong ho v c) lun l phn ng oxi ho - kh.
4) phn ng ho hp c th l phn ng oxi ho - kh hoc khng.
5) trong phn ng oxi ho - kh khng th c qu mt nguyn t th hin tnh oxi
ho v mt nguyn t th hin tnh kh.
Trang 4/7 - M thi 017

Trong cc mnh trn th

A. tt c ng.
B. 1 v 5 sai.
C. ch c 1 sai.
D. ch c 5 sai.
Cu 40: Cho glucoz ln men thnh ru (ancol) etylic. Dn kh CO2 to thnh qua dung
dch nc vi trong d, thu c 50 gam kt ta. Bit hiu sut ca qu trnh ln men l
80%. Khi lng glucoz cn dng ban u l
A. 56,25 gam.
B. 112,5 gam.
C. 45,00 gam.
D. 36,00 gam.
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A.Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho 14,948 gam hn hp KMnO4 v MnO2 (trong MnO2 chim 6,98% v khi
lng) tc dng vi 150 ml HCl 36,8% (d = 1,19 g/ml). Lng kh clo thu c ( ktc)
l:
A. 2,016 lt
B. 5,1968 lt
C. 0,012 lt
D. 4,928 lt
Cu 42: Cho cc hp cht sau:
1) Glixerin
2) Glucoz
3) Fructoz
4) Saccaroz
5) Tinh bt
6) Xenluloz
Nhng hp cht tc dng vi Cu(OH)2 cho dung dch mu xanh lam l:
A. 1, 2, 3, 4,
B. 1, 2, 5
C. 1, 2, 3, 4
D. 1, 2, 4, 6
Cu 43: Hn hp A gm hai cht k tip nhau trong dy ng ng ca axit fomic. t
chy ht m gam hn hp A ri cho sn phm chy hp th ht vo lng d dung dch
Ca(OH)2 th thu c 23g kt ta. Cn khi cho m gam hn hp A tc dng ht vi
NaHCO3 th thu c 2,016 lt CO2 (ktc). Khi lng mi axit trong hn hp A l
A. 2,96 gam; 3 gam
B. 1,84 gam; 3 gam
C. 2,3 gam; 2,96 gam
D. 2,4 gam; 3,7 gam
Cu 44: un nng mt hn hp 2 ancol no n chc vi H2SO4 c 1400C thu c
21,6 gam nc v 72 gam hn hp 3 ete.Bit 3 ete thu c c s mol bng nhau v phn
ng xy ra hon ton.CTPT ca 2 ru l:
A. C3H7OH ; CH3OH
B. C3H7OH ; C4H9OH
C. CH3OH ; C2H5OH
D. C2H5OH ; C3H7OH
Cu 45: Nu hm lng mt kim loi trong mui cacbonat l 40% th hm lng kim loi
ny trong mui photphat l:
A. 45,00%
B. 38,71%
C. 60,00%
D. 29,50%
Cu 46: Cng thc ca amin cha 15,05% khi lng nit l:
A. C6H8N2
B. C6H7N
C. C2H8N2
D. C2H7N
Cu 47: Cng thc chung ca axit cacboxylic no, x chc, mch h l?
A. CnH2n+2Ox.
B. CnH2nO2x.
C. CnH2nO2.
D. CnH2n+2-2xO2x.
Cu 48: Nhng kim loi no sau y c th c iu ch t oxit, bng phng php
nhit luyn nh cht kh CO
A. Ba,Cu,Ca
B. Fe,Cu,Ni
C. Pb,Mg,Fe
D. Fe,Ag,Al
Cu 49: Cho 4,2g anehit A mch h phn ng vi lng d dung dch AgNO3 trong
NH3, ton b lng Ag thu c ha tan ht trong dung dch HNO3 c nng d nhn
c 3,792 lt NO2 270C v 740mmHg. Cng thc cu to ca A l:
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A. CH3CH2CHO
B. CH2=CHCH2CHO
C. HOC-CH=CH-CHO
D. CH2=CHCHO
Cu 50: Trong dung dch CH3COOH c cn bng:CH3COOH
CH3COO- + H+. in
li ca CH3COOH s nh th no khi nh vi git dung dch NaOH vo?
A. khng bin i
B. tng
C. gim
D. khng xc nh c
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Cho 0,01 mol Fe vo 50 ml dung dch AgNO31M. Khi phn ng xy ra hon ton
th khi lng Ag thu c l:
A. 3,24g
B. 2,16g
C. 4,32g.
D. 5,4g
Cu 52: Hp cht X l oxit st cha 72,41 % khi lng cu st trong phn t.Kh ht
5,22 gam A thy cn V lt hn hp kh ( H2 ; CO ).Gi tr ca V l:
A. 2,016 lt
B. 0,504 lt
C. 1,624 lt
D. 2,192 lt
Cu 53: un nng t t hn hp etanol v propan-2-ol vi xc tc l axit sunfuric c ta
c th thu c ti a bao nhiu sn phm hu c m khi t chy cc hp cht ny ch
thu c CO2 v H2O ?
A. 3.
B. 4.
C. 5.
D. 2.
Cu 54: A l hp cht hu c c cng thc C8H11NO2. Cho 0,1 mol A vo 150 ml dung
dch NaOH 1M.Sau khi phn ng xy ra hon ton em c cn dung dch thu c 17,8
gam cht rn.S hp cht tha mn A l:
A. 1
B. 3
C. 4
D. 2
Cu 55: Cho cc mui sau: NaCl, AlCl3, Na2S, KNO3, K2CO3, Fe2(SO4)3, CH3COONa.
Khi ha tan trong nc,s lng mui b thu phn l
A. 6.
B. 4.
C. 5.
D. 3.
Cu 56: Cho hn hp X gm 2 anehit no n chc. Ly 0,25 mol X cho phn ng vi
dung dch AgNO3/NH3 d thu c 86,4 gam kt ta, khi lng dung dch sau phn ng
gim 71,6 gam. Xc nh cng thc ca 2 anehit ?
A. CH3CHO v C3H7CHO
B. HCHO v CH3CHO
C. CH3CHO v C2H5CHO
D. HCHO v C2H5CHO
Cu 57: Cho hp cht hu c A c cng thc thc nghim (CH2O)n.
A tc dng vi Na d hoc NaHCO3 d u thu c s mol A bng s mol kh H 2 hoc
kh CO2.Cht A c cng thc l:
A. CH2O
B. C3H6O3
C. C2H4O2
D. C4H8O4
Cu 58: Pht biu no sau ng?
A. Trong pin in ha,anot l in cc dng,catot l in cc m
B. Trong nc, gi tr th in cc chun ca kim loi lun m
C. Trong pin in ha,kim loi c th in cc chun ln ng vai tr l in cc m
D. Trong nc, th in cc chun ca kim loi cng m, tnh oxi ha ca ion dng
kim loi cng yu
Cu 59: Trng ngng hexametyleniamin 1,232 tn H2N-(CH2)6-NH2 v 1,460 tn axit
aipic HOOC-(CH2)4-COOH thu c bao nhiu kg t nilon-6,6 (bit hiu sut p l
90%)?
A. 2196 kg
B. 2692 kg
C. 2232 kg
D. 2034 kg
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Cu 60: Cho cc cht etyl axetat, anilin, ancol etylic, axit acrylic, phenol, p-crerol
phenylamoniclorua,ancol benzylic.Trong cc cht ny ,s cht tc dng c vi dd
NaOH l:
A. 5
B. 4
C. 6
D. 3
--------------------------------------------------------- HT ---------(Th sinh khng c s dng bng h thng tun hon v cc ti liu khc))()
()-------------------------------------------

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