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Cu I. 1. Theo nh ngha mi v axitbaz ca Bronsted, cc ion : Cu III. Hn hp A l hp kim AlCu.
HCO3 dch NaOH nng a mol/l cho ti khi kh ngng thot

Na

NH + , 4

2 CO3 ,

CH3COO ,

HSO , 4

K , Cl ,

Ly m gam hn hp A ha tan bng 500 ml dung

l axit, baz, lng tnh hay trung tnh ? Ti sao ? Trn c s hy d an cc dung dch cho di y c gi tr pH ln hn hay nh hn 7 : Na 2 CO3 , KCl,

CH3COONa, NH 4 Cl, NaHSO 4 .

2. Hon thnh cc phng trnh phn ng di dng phn t v dng ion : a) Fex O y + HCl b) CuCl2 + H2 S c) Kim loi R ha tr n + HNO3 NO + ... + ... d) NaCl + H 2 O 3. A, B l 2 nguyn t cng mt phn nhm v thuc 2 chu k lin tip trong h thng tun hon. Tng s proton trong hai ht nhn nguyn t ca A v B bng 32. Hy vit cu hnh electron ca A, B v ca cc ion m A v B c th to thnh. Cu II. 1. Xc nh cng thc cu to ca C 6 H14 , bit rng khi tc dng vi Cl2 theo t l mol 1 : 1 ta ch thu c 2 ng phn. Gi tn 2 ng phn .
pmn c tr

ra, thu c 6,72 lt H2 ( iu kin tiu chun) v cn li m1 gam kim loi khng tan. Mt khc ly m gam hn hp A ha tan bng 500 ml dung dch HNO3 nng b mol/l cho ti khi kh ngng thot ra th thu c 6,72 lt kh NO duy nht ( iu kin tiu chun) v cn li m 2 gam kim loi khng tan. Ly ring m1 v m 2 gam kim loi khng tan trn em oxi ha hon ton thnh oxit th thu c 1,6064 m1 gam v 1,542 m2 gam oxit. 1. Tnh nng mol ca cc dung dch NaOH v HNO3 . 2. Tnh khi lng m. 3. Tnh % khi lng ca Cu trong hp kim. Cho : O = 16, Al = 27, Cu = 64. Cu IV. Cho hp cht hu c A cha cc nguyn t C, H, O. 1. t chy ht 1,88 gam cht A cn lng va l 1,904 lt oxi (iu kin tiu chun) , thu c CO2 v hi nc vi t l th tch VCO : Vhoi nc = 4 2 : 3. Xc nh cng thc phn t ca A, bit rng khi lng phn t ca A nh hn 200. 2. Cho 1,88 gam cht A tc dng ht vi dung dch NaOH, sau c cn th thu c mt ru v 2,56 gam cht rn X gm NaOH d v 2 mui ca 2 axt hu c n chc. t chy hon ton X trong oxi d, thu c hi nc, CO2 v Na 2 CO3 . Ha tan Na 2 CO3 trong dung dch HCl d thy thot ra 0,448 lt CO2 ( iu kin tiu chun). Hy vit cng thc cu to ca A (khng cn vit cc ng phn axit). Cho H = 1, C = 12, O = 16, Na = 23.

2. Hon thnh s bin ha :

C (etilenglicol iaxetat). 2HCHO
+X t
o

trng hp + H2 A B+ (xt) (xt)

D (poliete). CuO
E
+O

trngngng

2 (n chc) (xt)

F (axit a

chc)

2 G ().

+ Ca(OH) d

Vit cc phng trnh phn ng. 3. Cng thc n gin nht ca mt axit hu c A l (CHO)n. Khi t chy 1 mol A ta thu c di 6 mol CO2. Hy bin lun tm cng thc phn t ca A v vit cng thc cu to ca cc ng phn axit ca A.