cng n tp lp 11 hc k I nm hc 2009 2010 Ban nng cao I. L thuyt 1. S in li: Khi nim v s in li, cht in li.C ch ca qu trnh in li.

. in li, cn bng in li, cht in li mnh, cht in li yu. 2. Axit, baz, mui: Cc nh ngha, vit phng trnh cc cht in li, hng s axit baz. S in li ca nc, cht ch th axit baz. pH, cc cht ch th axit baz. 3. Phn ng trao i trong dung dch: Bn cht v iu kin xy ra phn ng trao i. Vit phng trnh phn ng trao i di dng phn t, ion. 4. Nit: V tr, tnh cht c bn, s bin i tnh cht ca cc nguyn t trong nhm nit; tnh cht ca nit v hp cht, cu to, phng php iu ch nit v hp cht. 5. Photpho: Cu to, tnh cht vt l, tnh cht ha hc, phng php iu ch photpho v hp cht ca photpho. Phn bn ha hc: Cc loi phn bn, cng thc, phng php iu ch. 6. Cacbon, silic: Cu to nguyn t, v tr, tnh cht vt l, tnh cht ha hc ca cacbon, silic v hp cht ca chng. II. Bi tp Bi 1: Nhn bit cc dung dch sau: a. N2, O2, NH3, HCl, Cl2. b. NH4NO3, NH4NO2, (NH4)2SO4, NH4Cl, (NH4)2CO3 c. HNO3, H2SO4, H3PO4 Bi 2: Tnh pH ca cc dung dch sau: a. Dung dch cha NaOH 0,01M, KOH 0,03M Ba(OH)2 0,03M b. Dung dch cha NH4Cl 0,02M v NH3 0,1M. Cho Kb ca NH3 bng 1,8.10-5. c. Dung dch cha CH3COOH 0,05M v CH3COONa 0,01M. Cho Ka ca CH3COOH bng 1,75.10-5 d. Dung dch thu c khi trn 2 dung dch: 200ml dung dch NaOH 0,01M vo 300ml dung dch HCl 0,05M. e. Dung dch thu c khi trn 500ml dung dch KOH 0,1M vo 500 ml dung dch cha ng thi H2SO4 0,05M v HCl 0,05M. Bi 3: Vit phng trnh in li ca cc cht sau trong nc. Cho bit mi trng c to ra do cc cht l g? NH4Cl, NaNO3, Na2CO3, K3PO4, Mg(OH)2, H2SO4, H3PO4, KClO4, NaNO2, Cu(NO3)2, NaHCO3 Bi 4: Hp th hon ton 8,96 lt kh CO2 vo 500 ml dd gm NaOH 0,5M v Ca(OH)2 0,35M. a.Tnh khi lng ca kt ta thu c sau phn ng hp th. b.Tnh nng ca cc ion cn li trong dung dch. c.Nu cho thm Ca(OH)2 d vo dung dch thu c trn th thu c thm bao nhiu gam kt ta. Bi 5: Cho 500 ml dung dch hn hp gm NaOH 0,5M v KOH 0,5M vo 500 ml dung dch gm Ca(HCO3)2 1,2M. Tnh khi lng kt ta to thnh sau phn ng.

Bi 6: Hy cho bit vai tr ca cc ion sau trong dung dch: SO42-, NH4+, NO3-, SO32-, Cu2+, Fe3+, BrO-, Ag+, Fe2+, Al3+, HS-, ClBi 7: Cho hn hp A gm KNO3 v Fe(NO3)2. Nhit phn hon ton hn hp A sau dn ton b sn phm qua dung dch NaOH va th thy thu c dung dch c pH = 7 v khng thy c kh thot ra. Tnh phn trm khi lng cc cht trong hn hp ban u. Bi 8: Cho hn hp A gm AgNO3 v Fe(NO3)2 c nung nng n khi phn ng xy ra hon ton. Dn hn hp kh thu c sau phn ng vo H2O d th thy khng c kh thot ra v c 1 lt dung dch HNO3 c pH = 1. Tnh % khi lng cc cht trong hn hp ban u. Bi 9: Cho m gam mt kim loi M tc dng vi HNO3 th thu c 4,48 lit kh khng mu, ha nu trong khng kh. Sau phn ng thy cn (m-16,8) gam kim loi khng tan. Tm kim loi. Bi 10: Cho hn hp gm N2 v H2 c t l s mol l 1:4 c p sut l p. Tin hnh phn ng tng hp NH3 t hn hp trn sau a hn hp sau phn ng v iu kin ban u th p sut trong bnh l 0,9p. Tnh hiu sut ca phn ng tng hp amoniac trn. Bi 11: Cho mt oxit st tc dng vi HNO3 long d th thu c 217,8 gam mui v 2,24 lt kh NO duy nht. Tm cng thc ca oxit st. Bi 12: Cho hn hp A gm 50 gam Al, Fe, Cu tc dng vi HNO3 c nng th thu c 44,8 lt kh duy nht. a. Tm khi lng ca dung dch HNO3 60% cn dng cho phn ng trn. b. C cn dung dch sau phn ng th thu c bao nhiu gam mui khan. Bi 13: Cho 24,8 gam hn hp gm Fe, Cu tc dng vi HNO3 long va th thu c 6,72 lit NO duy nht. a. Tnh th tch ca dung dch HNO3 1M cn dng ha tan hon ton lng hn hp trn. b. Tnh khi lng mui to thnh sau phn ng. Bi 14: Ha tan 3,61 gam hn hp gm Fe v mt kim loi M c ha tr khng i trong dung dch HNO3 d th thu c 1,792 lit kh NO duy nht. Cn nu cng ha tan lng kim loi nh trn vo dung dch HCl th thu c 2,128 lit H2. Xc nh tn kim loi v phn trm khi lng ca chng trong hn hp ban u. Bi 15: Cho hn hp gm Zn v Mg c khi lng m gam tc dng va vi 500 ml dung dch HNO3 1M th thu c 1,12 lt mt cht kh duy nht v dung dch A. a. Tm cng thc ca kh trn. b. Cho dung dch A tc dng vi NOH d th thu c kt ta B. Lc ly B ri em nung trong khng kh n khi lng khng i th thu c bao nhiu gam cht rn. Cho m = 8,9 gam.