Bi tp HIRCACBON tng hp

Dng 1: Hon thnh mt s chui phn ng CH4 C2H2C2H4C2H5Cl CH3COONa CH4 C2H2 C2H6C2H5Cl CaC2C2H2C2H3ClPVC Al4C3 CH4 C2H2 C2H2Br4 C2H2 C2Ag2 C2H6C2H4C2H4Br2 C2H4 C2H5OH C4H10 C2H4 C2H3Cl CH4 C2H2 C2H4 C2H6 C2H5Cl C3H8C2H4 C2H2 vinylaxetilen buta -1,3 ien polibutadien C2H5OH C2H4 C2H4Br2C2H2A PVC C4H10 C3H6 C3H6Br2 C3H4 C3H3Ag Dng 2:iu ch mt s cht t cht ban u Cu 1: T t n v cc cht v c cn thit iu ch C2H5OH, PVC, buta -1,3 ien, vinylclorua, clometan, brometan. Cu 2: t kh thin nhin v cc cht v c cn thit hy iu ch : PVC, PE, divinyl, benzen, andehit axetic. Cu 3: T mui natriaxetat v cc cht v c cn thit khc hy iu ch cc cht sau:Polibutadien, etyl clorua; 1,2 icloetan, PP(polipropen),1,2 ibrompropan, 2,2 dibrompropan. Cu 4: T than v kh H2 hy iu ch: PVC, vinylclorua, buta-1,3- dien, propen, etan, butan. Dng 3: Mt s bi tp tng hp Cu 1: Mt hn hp gm hai kh ankan v ankin. Dn 3,36 lt hn hp trn i qua dung dch AgNO3/NH3 d th thy c th tch kh b gim 2,24 lit. Nu t chy ton b lng trn, ri cho ton b kh sinh ra i qua dung dch Ca(OH)2 d th thy c 60g kt ta. Xc nh hai HC trn, v hon thnh cc phn ng trn?s:C3H4 v C2H6 Cu 2: Mt hn hp gm anken v ankin. t chy a gam hn hp trn, ri cho i qua bnh ng CuSO4 kha, ri bnh ng KOH d th thy bnh 1 tng 5,4g, bnh 2 tng 17,6g. Mt khc cng a gam trn, tc dng va vi 48g brom. Xc nh 2 HC trn v tnh a. p n: C2H2 v C2H4 Cu 3: Dn hn hp gm mt ankan v mt anken i qua dung dch brom d th thy bnh brom tng 4,2g,v thot ra 3,36 lt kh. Nu t chy hon ton hn hp trn th ta cn 16,8 lt. Bit Vankan :Vanken =3:2. Xc nh CTPT v thnh phn phn trm v khi lng ca chng p n: C3H6 v CH4 Cu 4: Ly 4,48 lt hn hp gm mt anken v mt ankin cho i qua dung dch AgNO3/NH3 d th thy c 2,24 lt kh bay ra. Nu t chy hon ton 4,48 lt kh trn th ta thu c 13,44 lt CO2. Xc nh cc HC trn? A: (C2H2, C4H8); ( C3H6, C3H4); ( C2H4, C4H6) Xc nh CTCT ng bit rng anken tc dng vi HBr th sinh ra 2 sn phm Cu 5: t chy hon ton x gam hn hp gm 1 anken v 1 ankan u th kh, ri cho sn phm i qua bnh ng P2O5 d , ri bnh ng Ba(OH)2 d th ta thy bnh 1 tng 10,8g, cn bnh 2 tng 22g. Bit rng hai cht trn ng mol. Xc nh hai cht trn? p n: (C2H4, C3H8); ( C3H6, C2H6); ( C4H8, CH4) b.Xc nh CTCT ng bit, ankan tc dng vi clo sinh ra mt sn phm th monoclo, cn anken tc dng vi Hcl th sinh ra 1 sn phm duy nht? Cu 6: Dn 6,72 lt hn hp gm 1 anken v 1 ankan vo dung dch Brom d th thy c 24g brom tham gia phn ng. Cn khi t chy ton b 6,72 lt hn hp trn, ri dn ton b hn hp trn i qua bnh ng Ca(OH)2 d th thy bnh tng ln 49,2g. Xc nh hai hc trn bit rng chng hn km nhau 3 nguyn t cacbon(C4H8, CH4) Cu 7: Dn a gam mt hn hp gm ankan v ankin th kh i qua dung dch brom d th thy c 32g brom tham gia phn ng v thot ra 2,24 lt kh. Nu t chy ton b a gam hn hp trn th thy khi lng CO2 ln hn khi lng nc l 30,4g. Xc nh hai hc trn v tnh phn trm v khi lng ca chng p n:C3H8 v C4H6