Trang 1/4 - M d thi 143

SO GD-DT BAC NINH

TRUNG THPT CHUYN BN
THI DJNH K LAN I, NM 2009-2010
thi c 04 trang)
DE THI THU DAI HC
Mn thi: HO HC, khi A,B lp 12
Thi gian lm bi: 90 pht
M d thi 143
Ho, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit s khi cua cc nguyn t:
H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32;
Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137
(Th sinh khng duc su dng BANG TUAN HON CC NGUYN T HA HC)
Cu 1: Trong tu nhin, nito c 2 dng vi bn l
14
N v
15
N ; oxi c 3 dng vi bn l
16 17
; O O v
18
O. Hoi c
ti da bao nhiu loai phn tu nito dioxit c khi luong phn tu trng nhau?
A. 3. B. 2. C. 1. D. 4.
Cu 2: Ha tan hon ton st vo dung dich H
2
SO
4
(l) vua du thu duoc 4,48 lt kh (dktc). C can dung dich
trong diu kin khng c oxi thu duoc 55,6g mui voi hiu sut 100%. Cng thuc cua mui
A. FeSO
4
. B. Fe
2
(SO
4
)
3
.7H
2
O. C. FeSO
4
.7H
2
O. D. FeSO
4
.9H
2
O.
Cu 3: C cc dung dich mui: K
2
HPO
4
(1), NaHCO
3
(2), NaHSO
4
(3), Ba(NO
3
)
2
(4), KNO
2
(5). Cc dung dich
c pH > 7 l
A. (2) v (5). B. (1) v (2). C. (1), (2) v (5). D. (1) v (5).
Cu 4: Cho FeCO
3
tc dung voi dung dich H
2
SO
4
dc nng thu duoc hn hop kh A . Ti khi hoi cua A so
voi hidro l a . Gi tri cua a l
A. 25,333. B. 27,000. C. 26,000. D. 28,667.
Cu 5: Theo so d phan ung: C
4
H
7
ClO
2
+ NaOH mui huu co + C
2
H
4
(OH)
2
+ NaCl
Cu tao cua C
4
H
7
ClO
2
l
A. CH
3
COOCH
2
CH
2
Cl. B. CH
3
COOCHCl-CH
3
.
C. HCOOCH
2
CHCl-CH
3
. D. ClCH
2
COOCH
2
CH
3
.
Cu 6: Ha tan hon ton hn hop gm Na
2
O, BaCl
2
, NaHCO
3
, KHCO
3
c s mol mi cht bng nhau vo
nuoc ri dun nng nhe. Sau khi kt thc th nghim duoc dung dich A . Dung dich A c pH
A. > 7. B. = 7. C. < 7. D. khng xc dinh.
Cu 7: Cho so d phan ung sau: FeS
2
2
1
O +
A
2
2
O +
B
2 4
( )
3
H SO d +
C
2
4
H O +
D
0
(5)
Cu
t
+
E
Cc phan ung l phan ung oxi ha - khu l
A. 1, 2, 3, 5. B. 1, 2, 5. C. 1, 2. D. 1, 2, 4, 5.
Cu 8: Hn hop X gm 9,6g Cu v 8,4g st. D ha tan hon ton X cn ti thiu V(l) dung dich HNO
3
1M
thu duoc san phm khu NO duy nht. Gi tri cua V l
A. 0,8. B. 1,0. C. 0,7. D. 1,2.
Cu 9: D nhn bit 3 lo mt nhn: phenol, stiren, ancol benzylic, nguoi ta dng mt thuc thu duy nht l:
A. Nuoc brom. B. dd NaOH. C. Na D. Ca(OH)
2
.
Cu 10: Diu ch oxi trong phng th nghim bng cch nhit phn cc cht sau: KNO
3
, KMnO
4
, KClO
3
,
HgO. Nu nhit phn hon ton mi cht trn, cht cho th tch kh oxi thu duoc (dktc) lon nht l
A. KMnO
4
. B. KClO
3
. C. HgO. D. KNO
3
.
Cu 11: Mt aminoaxit no X tn tai trong tu nhin (chi chua mt nhm - NH
2
v mt nhm - COOH). Cho
0,89g X phan ung vua du voi HCl tao ra 1,255g mui. Cng thuc cu tao cua X l:
A. H
2
NCH
2
CH
2
COOH. B. H
2
NCH
2
COOH.
C. CH
3
CH(NH
2
)COOH. D. B, C du dng.
Cu 12: Cho 100ml dung dich H
3
PO
4
0,5M vo 100ml dung dich hn hop gm: NaOH 0,8M v Ca(OH)
2
0,4M thu duoc m gam kt tua . Gi tri cua m l
A. 12,4. B. 4,13. C. 15,5. D. 7,75.
Cu 13: Cho cc pht biu sau:
Trang 2/4 - M d thi 143
1) Hat vi m c 10 electron o lop ngoi cng l nguyn tu Ne
2) Nguyn tu c lop electron o lop ngoi cng bo ha l kh him
3) Nguyn tu natri c 11 electron o lop vo; 11 proton v 12 notron o hat nhn
4) Nguyn tu c 3 lop electron v 1 electron o lop ngoi cng l nguyn tu Na
Cc pht biu dng l
A. 2; 3; 4. B. 1; 2; 4. C. 1; 2; 3; 4. D. 4.
Cu 14: Dun nng hn hop etanol v propan-2-ol voi axit oxalic c xc tc H
2
SO
4
dm dc c th thu duoc
ti da bao nhiu este huu co da chuc?
A. 5. B. 2. C. 3. D. 4.
Cu 15: Cho nuoc brom du vo 100 gam dung dich phenol thu duoc 9,93 gam kt tua trng. Gia su phan ung
hon ton, nng d % phenol trong dung dich l:
A. 1,88%. B. 3,76%. C. 0,94%. D. 2,82%.
Cu 16: Cho cc tinh th sau: nuoc d kh; mui n; bng phin; thach anh; silic; iot v st. S tinh th thuc
loai tinh th nguyn tu v thuc loai tinh th phn tu ln luot l
A. 2 v 4. B. 2 v 3. C. 3 v 2. D. 3 v 3.
Cu 17: Cho cc phan ung ha hoc sau: Cl
2
+ H
2
O HCl +HClO
Cl
2
+ 2NaOH NaClO+H
2
O + NaCl 3Cl
2
+6NaOH
0
t

5NaCl +NaClO
3
+3H
2
O
2Cl
2
+ H
2
O +HgO HgCl
2
+2HClO 2Cl
2
+ HgO HgCl
2
+ Cl
2
O
Trong cc phan ung trn, clo dng vai tr
A. l cht oxi ha B. L cht khu.
C. Vua l cht oxi ha, vua l cht khu. D. Tt ca du sai.
Cu 18: Qu trnh thuy phn tinh bt bng enzim khng xut hin cht no duoi dy?
A. Glucozo. B. Mantozo. C. Saccarozo. D. Dextrin.
Cu 19: Cho cc hop cht huu co: (1) ankan (2) ancol no, don chuc, mach ho. (3) xicloankan.
(4) ete no, don chuc, mach ho. (5) anken. (6) axit no don chuc, mach ho
(7) andehit no don chuc, mach ho. (8) ankin. (9) ancol khng no,(c mt lin kt di C=C) mach ho.
(10) axit khng no (c mt lin kt di C=C) don chuc .
Dy gm cc cht khi dt chy hon ton du cho s mol CO
2
= s mol H
2
O l
A. (3),(4),(8),(9),(10). B. (3),(5),(6),(7),(9). C. (2),(3),(5),(6),(8). D. (1),(3),(5),(7),(9).
Cu 20: Cho 3,38g hn hop X gm CH
3
OH, CH
3
COOH, C
6
H
5
OH tc dung vua du voi Na thy thot ra 672
ml kh (dktc) hn hop rn Y. Khi luong Y s l:
A. 3,61 gam. B. 4,76 gam. C. 4,04 gam. D. 4,7 gam.
Cu 21: Cho cc ion: Na
+
, Mg
2+
, Cl
-
, F
-
, O
2-
. Thu tu tng dn bn knh cua cc ion l
A. Mg
2+
, Na
+
, F
-
, O
2-
, Cl
-
B. Na
+
, Mg
2+
, F
-
, O
2-
, Cl
-
C. Cl
-
, Mg
2+
, Na
+
, F
-
, O
2-
D. O
2-
, F
-
, Na
+
, Mg
2+
, Cl
-
Cu 22: Dy gm cc cht duoc sp xp theo chiu tng dn nhit d si tu tri sang phai l:
A. HCOOH, CH
3
COOH,C
2
H
5
OH, CH
3
CHO. B. CH
3
COOH, HCOOH, C
2
H
5
OH, CH
3
CHO.
C. CH
3
COOH, C
2
H
5
OH, HCOOH, CH
3
CHO. D. CH
3
CHO,C
2
H
5
OH, HCOOH, CH
3
COOH .
Cu 23: Dung dich A gm 0,1 mol Na
+
; 0,2 mol Ca
2+
; 0,2mol Cl
-
v x mol HCO
3

. C can dung dich A thu

duoc m gam mui khan. Gi tri cua m l
A. 34,4g. B. 43,7g. C. 35,7g. D. 26,4g.
Cu 24: D phn bit glucozo v fructozo th nn chon thuc thu no duoi dy?
A. Dung dich AgNO
3
trong NH
3
. B. Dung dich CH
3
COOH/H
2
SO
4
dc
C. Dung dich nuoc brom. D. Cu(OH)
2
trong mi truong kim.
Cu 25: C hn hop gm Na v Al, trong d ti l s mol cua Al v Na tuong ung l 4:5. Cho hn hop vo cc
nuoc ly du thu duoc 1,904 lt kh(dktc). Vy:
1) Hn hop kim loai d tan ht
2) S gam kim loai d dng l 2,23g
3) Thnh phn % theo khi luong cua Al v Na tuong ung l 48,43 v 51,57
Cc kt lun dng l
A. 1) v 2). B. 2) v 3). C. 1), 2) v 3). D. 1) v 3).
Trang 3/4 - M d thi 143
Cu 26: Xt phan ung: FeSO
4
+ KMnO
4
+ H
2
SO
4
Fe
2
(SO
4
)
3
+ MnSO
4
+ K
2
SO
4
+ H
2
O. Nu sau phan
ung thu duoc 20g Fe
2
(SO
4
)
3
th s mol electron d duoc trao di giua cc cht trong phan ung l
A. 0,5. B. 0,05. C. 0,1. D. 0,25.
Cu 27: Dun 12,00 gam axit axetic voi 13,80 gam ancol etylic (c axit H
2
SO
4
dc lm xc tc). Dn khi phan
ung dung lai thu duoc 11,00 gam este. Hiu sut cua phan ng este ho l
A. 60,0%. B. 62,5%. C. 75,0%. D. 41,67%.
Cu 28: D ha tan ht mt hn hop gm 0,02 mol kim loai A (ha tri II) v 0,01 mol kim loai B (ha tri III)
cn m gam dung dich HNO
3
20%. Sau phan ung thu duoc dung dich X khng chua NH
4
NO
3
v 0,16128
lt(dktc) hn hop gm N
2
v N
2
O. Gi tri cua m l
A. 26,586. B. 24,318. C. 22,145. D. 11,718.
Cu 29: Hai hop cht huu co X,Y l dng dng k tip, du tc dung voi Na v c phan ung trng bac . Bit
% khi luong oxi trong X, Y ln luot l : 53,33% v 43,24%. Cng thuc cu tao cua X,Y tuong ung l:
A. HOCH
2
CH
2
CHO v HOCH
2
CH
2
CH
2
CHO. B. HOCH(CH
3
)CHO v HOOCCH
2
CHO.
C. HOCH
2
CHO v HOCH
2
CH
2
CHO. D. HCOOCH
3
v HCOOC
2
H
5
.
Cu 30: Cho cc bnh kh mt nhn dung ring bit tung kh: O
2
, O
3
, H
2
S, SO
2
, CO
2
. Thuc thu d nhn bit
nm bnh kh trn l
A. d
2
KI/ h tinh bt, d
2
Br
2
, d
2
Ca(OH)
2
. B. tn dm, d
2
Br
2
, d
2
Ca(OH)
2
.
C. tn dm, d
2
KI/ h tinh bt, d
2
Br
2
. D. Ca A, B, C du dng.
Cu 31: Dt chy hon ton mt hop cht huu co X, thu duoc 0,351 gam nuoc v 0,4368 lt kh CO
2
(dktc).
Bit X c phan ung voi Cu(OH)
2
trong mi truong kim khi dun nng. Cht X l
A. O=HC-CH=O. B. CH
2
=CH-CH
2
-OH. C. C
2
H
5
CHO. D. CH
3
-CO-CH
3
.
Cu 32: Trong dung dich CH
3
COOH 0,1M c cn bng: CH
3
COOH + H
2
O CH
3
COO
-
+H
3
O
+
K
a
Pht biu KHNG DNG l
A. D din li cua CH
3
COOH s tng khi thm CH
3
COONa
B. Khi thm vi giot dung dich HCl vo dung dich, hng s axit
a
K khng thay di
C. Khi pha long dung dich bng nuoc, cn bng s chuyn dich sang phai
D. Khi tng nhit d cua dung dich, d din li cua CH
3
COOH s thay di
Cu 33: Cho dy cc cht : CH
4
, C
2
H
2
, C
2
H
4
, C
2
H
5
OH, CH
2
=CH-COOH, C
6
H
5
NH
2
(anilin), C
6
H
5
OH
(phenol) , C
6
H
6
(benzen). S cht trong dy phan ung duoc voi nuoc brom l
A. 8. B. 5. C. 7. D. 6.
Cu 34: Xt cc phan ung:(1) CH
3
COOH + CaCO
3
(3) C
17
H
35
COONa + H
2
SO
4
(2) CH
3
COOH + NaCl (4) C
17
H
35
COONa + Ca(HCO
3
)
2
Phan ung no khng xay ra duoc:
A. (2) v (4). B. (3)v (4). C. (2). D. (1) v (2).
Cu 35: Dng c 2 dng vi:
63
Cu v
65
Cu . Nguyn tu khi trung bnh cua dng l 63,54. Thnh phn % v
khi luong cua dng vi
63
Cu c trong Cu(NO
3
)
2
(Bit N =14; O= 16) l
A. 9,36. B. 9,15. C. 24,73. D. 24,52.
Cu 36: X l mt -aminoaxit no chi chua mt nhm NH
2
v mt nhm -COOH. Cho 23,4 g X tc dung voi
dung dich HCl du thu duoc 30,7 g mui. Cng thuc cu tao thu gon cua X l:
A. H
2
N-CH
2
CH
2
-COOH B. CH
3
CH(CH
3
)CH(NH
2
)COOH
C. CH
3
-CH(NH
2
)-COOH D. H
2
N-CH
2
-COOH
Cu 37: Xenlulozo trinitrat l cht d chy, n manh . Mun diu ch 29,7 kg xenlulozo trinitrat tu xenlulozo
v axit nitric voi hiu sut 90% th th tch HNO
3
96% (d = 1,52 g/ml) cn dng l
A. 1,439 lt. B. 15,000 lt. C. 24,390 lt. D. 14,390 lt.
Cu 38: Cho 4 gam mt ancol don chuc bc 1 tc dung voi CuO dun nng, sau phan ung thu duoc 5,6 gam
hn hop long. Cho ton b hn hop thu duoc tc dung voi dung dich [Ag(NH
3
)
2
]OH du. Khi luong Ag thu
duoc l
A. 32,4g. B. 10,8g. C. 43,2g. D. 21,6g.
Cu 39: Tnh bazo cua cc cht tng dn theo thu tu:
A. NH
3
< CH
3
CH
2
NH
2
< CH
3
NHCH
3
< C
6
H
5
NH
2
B. C
6
H
5
NH
2
< NH
3
< CH
3
CH
2
NH
2
< CH
3
NHCH
3
Trang 4/4 - M d thi 143
C. NH
3
< C
6
H
5
NH
2
< CH
3
NHCH
3
< CH
3
CH
2
NH
2
D. C
6
H
5
NH
2
< NH
3
< CH
3
NHCH
3
< CH
3
CH
2
NH
2
Cu 40: Tnh cht dc trung cua saccarozo l : 1. tham gia phan ung hidro ha
2. cht kt tinh khng mu. 3. khi thuy phn tao ra glucozo v fructozo
4. tham gia phan ung trng guong. 5. phan ung voi Cu(OH)
2
.
Nhung tnh cht no dng?
A. 1,2,3,4. B. 3,4,5. C. 2,3,5. D. 1,2,3,5.
Cu 41: Dung dich axit HA 0,1M o 25
0
C c pH = 2,88. Hng s axit cua HA o 25
0
C l
A. 2,25.10
-5
. B. 1,76.10
-4
. C. 2,25.10
-4
. D. 1,76.10
-5
.
Cu 42: Trong mt bnh kn chua hoi cht huu co X(c dang CnH
2n
O
2
) mach ho v O
2
(s mol O
2
gp di s
mol cn cho phan ung chy) o 139,9
0
C, p sut trong bnh l 0,8 atm. Dt chy hon ton X sau d dua v
nhit d ban du, p sut trong bnh lc ny l 0,95 atm. X c cng thuc phn tu l :
A. CH
2
O
2
. B. C
3
H
6
O
2
. C. C
2
H
4
O
2
. D. C
4
H
8
O
2
.
Cu 43: Dt chy hon ton 1 mol hop cht huu co X, thu duoc 4 mol CO
2
. Cht X tc dung duoc voi Na,
tham gia phan ung trng bac v phan ung cng Br
2
theo ti l mol 1:1. Cng thuc cu tao cua X l:
A. HOCH
2
CH
2
CH=CHCHO. B. HOOC-CH=CHCOOH.
C. HOCH
2
CH
2
CH
2
OH. D. HOCH
2
-CH=CHCHO.
Cu 44: Phan ung no sau dy khng dng ?
A. C
6
H
5
NH
2
+ 2Br
2
3,5-Br
2
-C
6
H
3
NH
2
+ 2HBr
B. 3CH
3
NH
2
+ 3H
2
O + FeCl
3
Fe(OH)
3
+ 3CH
3
NH
3
Cl
C. 2CH
3
NH
2
+ H
2
SO
4
(CH
3
NH
3
)
2
SO
4
D. C
6
H
5
NO
2
+ 3Fe + 7HCl C
6
H
5
NH
3
Cl + 3FeCl
2
+ 2H
2
O
Cu 45: Cho 0,92 gam hn hop gm axetilen v andehit axetic phan ung hon ton voi dung dich AgNO
3
(NH
3
) thu duoc 5,64 gam hn hop rn. Thnh phn % cc cht trong hn hop du ln luot l:
A. 28,74% v 71,26%. B. 28,71% v 74,26%. C. 26,28% v 74,71%. D. 28,26% v 71,74%.
Cu 46: Cc kh thai cng nghip v cua cc dng co t, xe my...l nguyn nhn chu yu gy ra mua axit.
Nuoc mua axit c pH < 5,6 lm cho ma mng tht bt, ph huy cc cng trnh xy dung....Hy cho bit
nhung thnh phn ha hoc chu yu no trong cc kh thai trn l nguyn nhn truc tip gy ra mua axit ?
A. NO, NO
2
, SO
2
. B. NO
2
, CO
2
, CO. C. SO
2
, CO, NO
2
. D. SO
2
, CO, NO.
Cu 47: Cho cc hop cht sau: (a). HOCH
2
CH
2
OH (b). HOCH
2
CH
2
CH
2
OH
(c). HOCH
2
CH(OH)CH
2
OH (d). CH
3
CH(OH)CH
2
OH (e). CH
3
CH
2
OH
(f) CH
3
OCH
2
CH
3
. Cc cht du tc dung duoc voi Na v Cu(OH)
2
l:
A. (c),(d),(e). B. (a),(b),(c), (d). C. (b),(c),(d). D. (a),(c),(d).
Cu 48: Cho cc cht: HNO
3
, HCl, HBr, HI, HF v H
2
SO
4
. Cht no c th diu ch duoc bng phuong php
sunfat
A. HCl, HF, H
2
SO
4
. B. HCl, HF. C. HCl, HBr, HF. D. HCl, HF, HNO
3
.
Cu 49: Cho cc dung dich: Cu(NO
3
)
2
, AlCl
3
, AgNO
3
, ZnSO
4
, NaCl, FeCl
3
. S dung dich tao kt tua voi
dung dich NH
3
du l
A. 5. B. 2. C. 3. D. 4.
Cu 50: Cho cc phn tu sau:
2 2 2 2 4 3 2
; ; ; ; ; H O CO SO CH NH BeF . S phn tu khng phn cuc l
A. 1. B. 3. C. 4. D. 2.
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