BENZEN Cu 1 (A-07): Pht biu khng ng l A.

Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi HCl li thu c phenol. B. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. C. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. D. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi NaOH li thu c anilin. Cu 2 (B-07): khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. OHCH2C6H4COOH. B. C2H5C6H4COOH. C. HOC6H4CH2OH. D. C6H4(OH)2. Cu 3 (B-07): Cho cc cht: etyl axetat, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3. B. 5. C. 6. D. 4. Cu 4 (B-07): Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen), c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dung c vi dung dch NaOH. S lng ng phn tho mn tnh cht trn l A. 2. B. 4. C. 3. D. 1. Cu 5 (B-07): S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 2. B. 3. C. 1. D. 4. Cu 6: Dy gm cc cht c th dng tch ring phenol v anilin t hn hp ca chng l A. dung dch NaOH v dung dch Br2. B. dung dch NaOH v dung dch HCl. C. dung dch HCl v nc. D. dung dch NaCl v dung dch Br2. Cu 7: Anilin v phenol u c phn ng vi dung dch A. NaCl. B. NaOH. C. HCl. D. Br2. Cu 8: Anilin d dng tham gia phn ng th vi dung dch brom l do A. phn t anilin c cha vng benzen nn d tham gia phn ng th nh phenol. B. phn t anilin c cha nhm amino. C. nhm amino y electron vo vng bezen nn vng bezen d th hn. D. vng benzen trong phn t anilin vn cn nguyn t hiro. Cu 9: Cu khng nh no sau y khng ng khi ni v anilin? A. Anilin t tan trong nc do gc C6H5- l gc k nc. B. Anilin tc dng c vi dung dch brom do n c tnh baz. C. Anilin c tnh baz yu hn NH3 do nhm -NH2 y electron. D. Anilin khng lm i mu giy qu m. Cu 10: Vng benzen trong phn t anilin c nh hng n nhm amino, dn n A. lm tng tnh kh. B. lm tng tnh axit. C. lm tng tnh baz. D. lm gim tnh baz. Cu 11: Tnh cht ca benzen l cht kh khng mu (1), c mi nh (2), khng tan trong nc (3), chy cho ngn la khng mu (4), tham gia phn ng th (5), tham gia phn ng kt hp (6), d dng b oxi ho (7), d trng hp (8). Nhng tnh cht ng l A. (1), (2), (3), (4), (5). B. (3), (4), (5), (8). C. (2), (4), (5), (6). D. (2), (3), (5), (6). Cu 12: Khi cho phenol tc dng vi lng d dung dch Br2 th thu c sn phm l A. 2,4,6-tribrom phenol. B. 2,6-ibrom phenol. C. 4-bromphenol. D. 2,4,4,6-tetrabrom xiclohexaienon. Cu 13: Nitro ho benzen bng HNO3 c trong H2SO4 c nhit cao thu c sn phm chnh l A. 1,2-initrobenzen. B. 1,3-initrobenzen. C. 1,4-initrobenzen. D. 1,3,5-trinitrobenzen. Cu 14: Khi oxi ho isopropylbenzen thu c cc sn phm l A. B. OH v CH C CH OH v CH CH CH
3 3 3 3

OH O v CH3 CH CH3 OH

O O v CH3 C CH3 O

C.

D.

Cu 15: Khi cho isopropylbenzen tc dng vi Br2 vi t l mol 1:1 (xc tc Fe, un nng) th thu c sn phm chnh l A. 2-brom-2-phenylpropan. B. 1-brom-2-isopropylbenzen. C. 1-brom-4-isopropylbenzen. D. 1-brom-3-isopropylbenzen. Cu 16: Cho cc cht: benzen, toluen, phenol, metyl phenyl ete. Cht phn ng d dng nht vi dung dch Br2 l A. benzen. B. toluen. C. phenol. D. metyl phenyl ete. Cu 17: Khi cho n-propylbenzen tc dng vi Br2 vi t l mol 1:1 (nh sng, nhit ) th thu c sn phm chnh l A. 1-brom-1-phenylpropan. B. 2-brom-1-phenylpropan. C. 1-brom-3-phenylpropan. D. 1-brom-4-(n-propyl)benzen. o Cu 18: Khi brom ho p-nitrophenol (Fe, t ) th thu c sn phm chnh l A. 2-brom-4-nitrophenol. B. 3-brom-4-nitrophenol. C. 2,3-ibrom-4-nitrophenol. D. 2,6-ibrom-4-nitrophenol. Cu 19: Cho cc cht: axit benzoic (X), axit p-nitrobenzoic (Y), axit p-metylbenzoic (Z) v axit phiroxibenzoic (T). Th t gim dn tnh axit ca cc cht trn l A. X > Y > Z > T. B. Y > X > T > Z. C. Y > X > Z > T. D. T > X > Z > Y. Cu 20: Khi brom ho o-metyl nitrobenzen (Fe, to) vi t l mol 1:1 th thu c sn phm chnh l A.

Br

CH3 NO2

B.

CH3 Br NO2

C.

Br CH3

D.

CH2Br NO2

Cu 21: Trong cng nghip, iu ch stiren ngi ta lm nh sau: cho etilen phn ng vi benzen c xc NO2 tc axit, thu c etylbenzen ri cho etylbenzen qua xc tc ZnO nung nng, thu c stiren. Nu hiu sut mi qu trnh l 80% th t 7,8 tn benzen s thu c lng stiren l A. 8320 kg. B. 6656 kg. C. 8230 kg. D. 6566 kg. Cu 22: Axit phtalic C8H6O4 dng nhiu trong sn xut cht do v dc phm. N c iu ch nh sau: oxi ho naphtalen bng oxi vi xc tc V2O5 450oC, thu c anhirit phtalic ri cho sn phm tc dng vi nc, thu c axit phtalic. Nu hiu sut mi qu trnh l 80% th t 12,8 tn naphtalen s thu c lng axit phtalic l A. 13,280 tn. B. 13,802 tn C.10,624 tn. D. 10,264 tn. Cu 23: Hirocacbon X c cng thc phn t C8H10 khng lm mt mu dung dch Br2. Khi ung nng X trong dung dch KMnO4 to thnh C7H5KO2 (Y). Axit ho Y c hp cht C7H6O2. Tn gi ca X l A. 1,2-imetylbenzen. B. 1,3-imetylbenzen. C. 1,4-imetylbenzen. D. etylbenzen. Cu 24: S lng ng phn ng vi cng thc phn t C8H10O l dn xut ca benzen, tc dng c vi NaOH l A. 3. B. 7. C. 8. D. 9