I HC QUC GIA TP.

H CH MINH TRNG I HC KHOA HC T NHIN

CNG HA X HI CH NGHA VIT NAM c lp T do Hnh Phc

Faculty of Physics & Engineering Physics

Applied Physics Department
Phone: (84.8) 38324461 Fax: (84.8) 8350096 http://www.phys.hcmuns.edu.vn

Head Dr. Le Vu Tuan Hung Vive Head Dr. Lam Quang Vinh Email:lthung@phys.hcmuns.edu.vn Email: lqvinh@hcmuns.edu.vn

CNG CHI TIT HC PHN

1. Thng tin chung Tn hc phn: QUANG PH HC o Tn ting Anh: SPECTROSCOPY M hc phn: Thuc khi kin thc: Chuyn ngnh B mn Khoa ph trch: Khoa Vt L Ging vin ph trch: TS. L V Tun Hng Khoa Vt L TS. Lm Quang Vinh Khoa Vt L PGS.TS Hunh Thnh t HQG Tp.HCM S tn ch: 3 tn ch o o o o o o S tit l thuyt: 30 tit S tit thc hnh, thc tp: S tit bi tp trn lp: S tit tho lun: S tit lm vic nhm: 15 tit S tit t hc:

Hc phn:
o Bt buc: cho ngnh: B mn Vt L ng Dng Khoa Vt L

o T chn: -

iu kin ng k hc phn:

o Hc phn tin quyt (cc hc phn SV phi ng k hc trc v thi t): Vt L Nguyn T, Vt L Thng k. o Hc phn hc trc (cc hc phn SV phi ng k hc trc): o Hc phn song hnh (SV phi ng k hc trong cng hc k): o Cc yu cu v kin thc, k nng ca SV (nu c):

2. Mc tiu ca hc phn Sinh vin s c trang b mng kin thc v Quang ph hc: quang ph nguyn t v quang ph phn t. Sinh vin c kh nng ng dng cc phng php phn tch quang ph pht x nguyn t, phng php hp thu nguyn t, phng php hp thu hng ngoi phn tch vt cht v cu trc ca chng.ng thi sinh vin cng c ci thin kh nng nghin cu v thc nghim. 3. Tm tt ni dung hc phn Ni dung gm 2 phn chnh: Quang ph nguyn t v quang ph phn t Quang ph nguyn t: L thuyt quang ph nguyn t, s hp th v bc x nh sng. Tm hiu v cng vch quang ph v cc nguyn nhn dn n m rng ca cc vch quang ph. ng dng ca quang ph nguyn t bao gm hai phng php phn tch ca quang ph pht x nguyn t v quang ph hp thu nguyn t. Quang ph phn t: Nghin cu s tng tc nh sng vi phn t. Thit lp mi quan h gia cu trc phn t vi cc c trng ph xut hin cc dng chuyn ng ca phn t: s quay, s dao ng, v dch chuyn in t. Nhng ng dng ph phn t trong vic phn tch cu trc vt liu.

4. Ni dung chi tit hc phn PHN 1: QUANG PH NGUYN T Chng 1: L THUYT QUANG PH NGUYN T (4 tit) 1.1. L thuyt v cu to nguyn t 1.2.S bc x v hp thu nng lng theo c in . 1.3.S bc x v hp thu nng lng theo quan im lng t 1.3.1.Qa trnh dch chuyn trng thi, cc h s Einstein. 1.3.2. Lin h gia cc i lng c in v lng t. 1.4.Cng vch quang ph 1.4.1.nh ngha cng , t s cng cc vch quang ph: cc vch kp c cng mc trn, cc vch kp c cng mc di, cc vch kp vi mc trn v mc di u l mc bi. 1.4.2.nh hng ca s hp th ln cng vch quang ph: hin tng t hp thu v cc th d c th. Chng 2: S KCH THCH CC VCH QUANG PH (3 tit) 2.1. S kch thch nhit 2.2. S kch thch do va chm: qu trnh dng ca h nguyn t va chm, s kch thch do va chm ca nguyn t i vi in t, s kch thch do va chm ca nguyn t vi nguyn t hoc ion, l thuyt lng t ca va chm khng n hi. 2

Chng 3: S M RNG CC VCH QUANG PH (3 tit) 3.1. S m rng t nhin: Theo quan im c in v lng t. 3.2. S m rng Doppler, S tc dng ng thi ca hai hiu ng m rng t nhin v m rng Doppler. 3.3. S m rng do va chm, m rng Lorentz. 3.4. S m rng do hiu ng Stark. Chng 4: NH HNG CA TNG TC IN T LN PH NGUYN T (6 tit) 4.1. Cc c trng ca lin kt (L,S): S phn b cc s hng, cc s hng quang ph trong s cu to c hn hai in t, nguyn l chn lc. 4.2. Cc c trng ca lin kt (J,J). Chng 5: NG DNG CA QUANG PH NGUYN T (6 tit) 5.1 . Phng php phn tch quang ph pht x nguyn t: Gii thiu my quang ph, cc phng php phn tch quang ph: phn tch nh tnh, bn nh lng v nh lng. 5.2. Phn tch quang ph hp thu nguyn t: Gii thiu my quang ph hp thu nguyn t, phng php phn tch: c tnh ca phng php, phng php x l mu, phng php v ng cong ly mu. PHN 2: QUANG PH PHN T Chng 6: TNG TC GIA NH SNG V MI TRNG VT CHT (3 tit) 6.1. Tng tc bn trong v tng tc bn ngoi: s tng tc, dch chuyn gia cc mc nng lng 6.2. Cc dng chuyn ng v trng thi nng lng tng ng ca phn t: chuyn ng in t, dao ng ca phn t, s quay ca phn t, phng trnh Schrodinger. 6.3. S phn chia vng ph v n v, n v o, cng hp thu. 6.4. S phn b cc trng thi nng lng. 6.5. Bc x lng cc in, xc sut chuyn di, quy tc la chn Chng 7: PH QUAY CA PHN T (3 tit) 7.1. Bc t do quay. 7.2. S quay ca ph quay ca phn t 2 nguyn t: mu quay t rn, mu quay t khng rn, s i xng ca cc hm sng quay. 7.3. Ph quay thun ty: Nguyn tc lc la, s xut hin ph quay. 7.4. ng dng ca ph quay: ng dng trong phn tch, tnh khong cch gia cc nguyn t. Chng 8: PH DAO NG CA PHN T 2 NGUYN T (6 tit) 8.1. phn loi dao ng: Dao ng iu ha, ph hng ngoi ca dao ng iu ha, dao ng khng iu ha, ph hng ngoi ca dao ng khng iu ha. 8.2. Dao ng quay ca phn t: Trng thi nng lng, ph dao ng quay kt hp. 8.3. Cng hp thu trong ph hng ngoi: Cng ph dao ng ca phn t, cng ph quay ca phn t. Ph Raman 8.4. Hin tng tn x t hp, m t cc loi tn x t hp 8.5. L thuyt tn x t hp: Theo quan im lng t, theo in ng lc hc. 3

8.6. Ph tn x t hp: Ph tn x dao ng, ph tn x quay, ph tn x dao ng quay. 8.7. ng dng ca ph tn x t hp. PH DAO NG CA PHN T NHIU NGUYN T 8.8. S dao ng ca phn t: Bc t do dao ng, dao ng trong phn t, phn loi dao ng thng, dao ng suy bin. 8.9. Nng lng ca dao ng: S i xng ca cc mc nng lng c bn v cc mc nng lng kch thch. 8.10. Ph dao ng: Quy tc la chn v s xut hin ph, ph dao ng ca mt s phn t, cc c trng ca ph dao ng. 8.11. Cng ph dao ng, s phn cc ca ph dao ng. 8.12. Ph dao ng ca phn t nhit thp Chng 9: L THUYT NHM V S I XNG CA PHN T (5 tit) 9.1. Cc phn t i xng: Trc i xng, mt phng i xng, kt hp trc v mt phng i xng, tm i xng 9.2. Lp i xng, cc loi nhm im i xng, tnh cht i xng ca cc loi nhm im. Chng 10. PH IN T CA PHN T. (3 tit) 10.1. Trng thi in t ca phn t 2 nguyn t: Nng lng, cc trng thi, lp v in t ca phn t, xc nh trng thi in t theo cu hnh in t. 10.2. Ph in t ca phn t 2 nguyn t: Nng lng ton phn ca phn t, quy tc la chn v cc loi chuyn di in t, cng ph m in t, ph lin tc, chuyn di khng bc x. 10.3. Trng thi in t ca phn t nhiu nguyn t: Phn loi trng thi in t, cu hnh in t, trng thi in t dao ng. 10.4. Ph in t ca nguyn t nhiu nguyn t: c im, cc loi chuyn di, cng trong ph in t dao gn, ph hp thu v ph pht quang. Chng 11. Gii thiu quang ph Laser (3 tit) 5. Phng php dy v hc : Dy tp trung trn ging ng

6. Phng php, hnh thc kim tra, nh gi kt qu hc tp:Kim tra t lun hoc trc nghim vo gia v cui hc k.

7. Ti liu hc tp, tham kho 1. Nguyn Vn n, Quang ph nguyn t v ng dng, NXB Trng H Quc Gia Tp.HCM. 2. inh Vn Hong (1974), Cu trc ph nguyn t, NXB H Ni. 3. E.U. Condon & G.H. Shortley, The theory of atomic spectra, Cambridge University. 4. Offenhartz, Atomic and molecular orbital theory, Mc. Graw Hill. 5. L Ha, Cu trc ph phn t, NXB Tp.HCM. 6. ng dng mt s phng php ph nghin cu cu trc phn t, Nguyn Hu inhTrn Th , NXB Gio Dc. 4

7. Nguyn Vn n, Cc phng php nghin cu bng quang ph hng ngoi, NXB HQG. 8. Dng i Phng, Quang ph phn t v ng dng, NXB HQG. Duyt Hiu trng Trng Khoa/B mn (K, ghi r h v tn) Ging vin (K, ghi r h v tn)

PGS.TS. Chu Vn To

TS. L V Tun Hng (TS. Lm Quang Vinh)

Vietnam National University Ho Chi Minh City University of Science SYLLABUS

1. General information Name: SPECTROSCOPY Code: Level (General education, specialization): specialization Department: Physics Faculty Instructor in charge: Le Vu Tuan Hung, PhD. Physics Faculty, University of Science, HCMC. Lm Quang Vinh, PhD. Physics Faculty, University of Science, HCMC. Huynh Thanh Dat, Ass.Prof. , National University of HCMC. Number of hours: 45h o o o o o o Theory: 30h Experiments-Practice: Problems sessions: Discussions: Group works: 15h Self-study: Mandatory: for specialization: Students in Applied Physics Department Optional: for specialization: . . .

This course is for:

o o
-

Requirements: o Courses which students must have passed: Atomic Physics, Statistical Physics 5

o Courses which students must have registered: o Courses which students must register simultaneously: o Other requirements: 2. Objects of the course Student who have successfully completed this module/subject will be able to increasing their fundamental knowledge of atomic and molecular spectroscopy.Use these spectroscopy to analyse materials and their structures. Furthermore, they can improve their experimental skill. 3. Brief contents The course has two main parts: atomic spectroscopy and molecular spectroscopy. Atomic spectroscopy, this part focuses on the emission and absorption of light; the intensities of spectral lines; the excite of spectral lines; spectral line widths; influence of electronic interaction on actomic spectrum; influence of external magnetic field on the atomic emitted spectroscopy . Molecular spectroscopy, this course is to provide an advanced level undergraduate student in Chemistry or Physics with a general overview of molecular spectroscopy. Specifically, the underlying principles of spectroscopy are examined using quantum mechanics, the interaction of light and matter, and group theory as starting points. The main focus of this course is the various forms of optical spectroscopy, including rotational, vibrational and electronic spectroscopy, as well as a brief look at photoelectron spectroscopy and lasers. The course finishes with an introduction to its application. 4. Detail contents PART 1: ATOMIC SPECTROSCOPY Chapter 1 : Theory of the atomic spectroscopy (4h) 1.1. Theory of atomic composition. 1.2. Emission and absorption in classical theory 1.3. Emission and absorption in quantum theory 1.3.1.Transition probabilities, coefficients of Einstein. 1.3.2. The relationship between classical theory and quantum theory. 1.4. The intensity of spectral lines 1.4.1. Definition, ratio of intensity of spectral lines. 1.4.2. The effect of self-absorption on intensity of spectral line. Chapter 2: Exciting of spectral lines (3h) 2.1. Exciting by heat. 2.2. Exciting by collision. Chapter 3: spectral lines widths (3h) 3.1. The factors influencing of widths. 3.2. The natural line widths Doppler broadining 3.3. Pressure broadining The line widths in electric field and magnetic field. 3.4. Stark effect. 6

Chapter 4: Influence of electronic interaction on atomic spetrum (6h) 4.1. Systematics of atomic states Russell-Saunders coupling Pauli principle . 4.2. (j,j) coupling. Chapter 5: The application of atomic spectroscopy (6h) 5.1. Atomic emission spectroscopy ( AES ). Revision of the principles of atomic emission spectroscopy Flame emission spectroscopy Analysis methods - Applications. 5.2. Atomic absorption spectroscopy ( AAS ) The relationship between light absorption and concentration Spectrometer: the light source, the atom cell, the light detection system Applications. Chapter 6:Interaction of Electromagnetic Radiation with Matter (3h) 6.1. Electromagnetic Radiation 6.2. Electromagnetic Spectrum 6.3. 6.4. 6.5. 6.6. 6.7. 6.8. 6.9. 6.10. 6.11. 6.12. Absorption and Emission of Radiation Line Intensity, Line Width, Broadening & the Doppler Effect Absorption experiments Dispersing elements: Prisms and Gratings Fourier transform spectroscopy (lower frequencies) Interferometers (higher frequencies) Summary of Absorption Experiments over the EM Spectrum Scattering (Raman techniques) Other experimental techniques (ATR, AAS, ICP-AES, photolysis) Magnetic resonance techniques

Chapter 7: Rotational Spectroscopy (3h) 7.1. Moments of Inertia for differently shaped molecules 7.2. Rotational IR, Millimetre Wave and Microwave Spectra 7.2.1. Diatomic & Linear Polyatomic Molecules 7.2.2. Symmetric Rotors 7.2.3. Stark Effect 7.4.4. Asymmetric Rotors and Spherical Molecules 7.5.5. Applications in Astronomy 7.3. Rotational Raman Spectroscopy 7.4. Structure Determination from Rotational Spectroscopy Chapter 8: Vibrational Spectroscopy (6h) 8.1. Molecular Vibrations 8.2. Diatomic molecules 8.2.1. IR Spectra 8.2.2. Raman Spectra 8.2.3. Anharmonicity 8.2.4. Vibration-Rotation (Rovibrational) Spectroscopy 8.3. Polyatomic molecules 8.3.1. Vibrational Selection Rules 7

8.4.

8.3.2. Vibration-Rotation (Rovibrational) Spectroscopy 8.3.3. Raman Spectra 8.3.4. Anharmonicity Applications

Chapter 9 :Molecular Symmetry (5h) 9.1. Symmetry elements 9.2. Point Groups 9.3. Character Tables 9.4. Consequences of Symmetry: Dipole Moments and Chirality 9.5. Molecular orbitals and symmetry 9.6. Selection rules and symmetry

Chapter 10: Electronic Spectroscopy (3h) 10.1. Diatomic Molecules 10.1.1. Molecular Orbital Theory 10.1.2. Classification of Electronic States 10.1.3. Vibrational Course Structure 10.1.4. Franck-Condon Principle 10.1.5. Transitions, Fluorescence and Phosphorescence 10.1.6. Rotational Fine Structure 10.2. Polyatomic Molecules 10.2.1. Some examples 10.2.2. Crystal field and ligand field Molecular Orbital Theory 10.2.3. Selection Rules Chapter 11: Photoelectron Spectroscopy, Related Techniques and Lasers 11.1. Photoelectron Spectroscopy 11.2. Introduction to Lasers

5. Method of assessment: Mid-term and final term exam.

6. References 9. Nguyn Vn n, Quang ph nguyn t v ng dng, NXB Trng H Quc Gia Tp.HCM. 10. inh Vn Hong (1974), Cu trc ph nguyn t, NXB H Ni. 11. E.U. Condon & G.H. Shortley, The theory of atomic spectra, Cambridge University. 12. Offenhartz, Atomic and molecular orbital theory, Mc. Graw Hill. 13. L Ha, Cu trc ph phn t, NXB Tp.HCM. 14. ng dng mt s phng php ph nghin cu cu trc phn t, Nguyn Hu inhTrn Th , NXB Gio Dc. 15. Nguyn Vn n, Cc phng php nghin cu bng quang ph hng ngoi, NXB HQG. 16. Dng i Phng, Quang ph phn t v ng dng, NXB HQG.

Approval by University President

Department Chair

Instructor

(Signature and Name) (Signature and Name)

Prof. Chau Van Tao Le Vu Tuan Hung, PhD