1) Hon thnh chui bin ha sau:

a i vo

(1) (2)

vosog i n

xiclohexan
(7) (8) (9)

(10) (12) (14) (16)

toluen

(11)

TNT (thuo no c )

canxicacbua (3) axetilen (6) benzen

(5)

nitrobenzen (13) 1-clo-3-nitrobenzen clobenzen (15) 1-clo-2-nitrobenzen etylbenzen

(17)

natriaxetat (4)
CH3

metan Thuo tr u 666 c sa

CH3 CH3

stiren (18) poly stiren

CH3 CH3 NO2

2) c tn cc hp cht sau: CH3 CH2

CH2 CH3

CH3 CH2 H 3C CH3 H3C CH3 H 3C

CH3

CH3 CH3 O2N NO2 O2N

CH3 OH NO2

CH3

NO2 CH3 CH2 CH3

NO2

CH2 CH3 CH3 NO2 3) Nhn bit cc cht mt nhn sau: - Benzen, toluen v stiren - Benzen, Toluen, stiren - Xiclohexan, stiren, axetilenbenzen 4.1. t chy hon ton 13.8 gam cht hu c X l ng ng ca benzen th thu c 23.52 lt CO 2 (ktc). Hy xc nh cng thc phn t X? 4.2. t chy hon ton 9,2 gam cht hu c X l ng ng ca benzen th thu c 15,68 lt CO2 (ktc). Hy xc nh cng thc phn t X? 4.3. t chy hon ton 5,3 gam ankylbenzen Y th thu c 4,5 gam H2O. Hy xc nh cng thc phn t ca Y? 4.4. t chy hon ton 6,0 gam ankylbenzen Z th cn va 13,44 lt oxi (ktc). Hy xc nh cng thc phn t ca Z? 5.1. t chy hon ton mt lng ankyl benzen A th thu c 7,056 lt CO2 (ktc) v 3,78 gam H2O. Hy xc nh cng thc phn t A Cl

5.2. t chy hon ton mt lng ankyl benzen A th thu c 14,112 lt CO2 (ktc) v 7,56 gam H2O. Hy xc nh cng thc phn t A 6.1. t chy hon ton 18,2 gam hn hp gm benzen v stiren phn ng kt kt thc thu c 12,6 gam nc. Hy xc nh thnh phn phn trm v khi lng ca mi cht. 6.2. Hn hp X gm 2 cht stiren v benzen, t chy hon ton 26 gam hn hp X th thu c 44,8 lt CO2 (ktc). Hy xc nh thnh phn phn trm v khi lng ca mi cht trong hn hp ban u. 7.1. t chy hon ton 18,2 gam hn hp gm benzen v stiren phn ng hon ton vi dung dch Brom 1M. Phn ng kt thc thy c 100 ml dung dch brom mt mu. Hy xc nh thnh phn phn trm v khi lng ca mi cht. 7.2. Hn hp Y gm 2 cht stiren v hex-1-in, Cho 18,6 gam hn hp Y tc dng vi lng d dung dch Brom 2M. Khi phn ng kt thc thy c 150 ml dung dch Brom mt mu hon ton. Hy xc nh thnh phn phn trm v khi lng ca mi cht trong hn hp ban u. 7.3. Hn hp A gm 2 cht stiren v benzen, 26 gam hn hp A tc dng va vi 100 ml dung dch Brom 1M (nhit thng, khng c sc tc). Hy xc nh thnh phn phn trm v khi lng ca mi cht trong hn hp A. 7.4. Hn hp B gm 2 cht stiren v toluen, Cho 34 gam hn hp B cho qua lng d dung dch Brom 4M. Khi phn ng kt thc thy c 25 ml dung dch Brom mt mu hon ton. Hy xc nh thnh phn phn trm v khi lng ca mi cht trong hn hp B. 8.1. t chy hon ton 14,5 gam hn hp gm ankyl benzen A v B l ng ng ca nhau, phn ng kt kt thc thu c 24,64 lt CO2 (ktc). Hy xc nh cng thc phn t A v B 8.2. t chy hon ton mt lng hn hp gm hai cht A v B l hai ng ng k tip nhau ca dy ng ng benzen th thu c 114,4 gam CO2 v 27,9 gam H2O. Hy xc nh cng thc phn t A v B. 8.3. t chy hon ton 33,2 gam hn hp gm hai cht A v B l hai ng ng k tip nhau ca dy ng ng benzen th thu c 28,9 gam H2O. Hy xc nh cng thc phn t A v B.